6th ALPS-ADRIA SCIENTIFIC WORKSHOP 30 April - 5 May, 2007 Obervellach, Austria ENVIRONMENTAL CONSEQUENCES OF SUSTAINABILITY Quality parameters of wheat. Bio-ethanol versus bread? Pál SZAKÁL1 – Rezső SCHMIDT1 – Juraj LESNY2 – Renátó KALOCSAI3 – Margit BARKÓCZI1 1 University 2 of West Hungary, Faculty of Agricultural and Food Sciences, Mosonmagyaróvár Faculty of Natural Sciences, University of SS. Cyril and Methodius in Trnava, 917 01 Trnava, SK. 3 UIS Ungarn Laboratories, Mosonmagyaróvár Decrease of fossil energy carriers Bio-ethanol is a potential replacement of oil and natural gas The increasing importance of high-starch content plants (Wheat, maize) Bio-ethanol, bio polymers, dextrin, starch syrup, D-glucose, etc. EU’s cereal production 285 million tons; Hungary’s cereal production 6 million tons 1 l bio-ethanol appr. 3.1 kg wheat, 2.8 kg maize. (Maize germ) h 6 H2O + 6 CO2 (C6H10O5)n + n H2O C6H12O6 C6H12O6 amilase nC6H12O6 2CH3 – CH2 – OH + 2CO2 CH3 CH3 CH3 C – OH + HO – CH2 – CH3 = CH3 CH3 CH3 C – O – CH2 – CH3 ETBE Why to use bio-ethanol? 1. Environmental reasons. Glasshaouse effects, climate change. 2. Ceasing the dependance on crude oil. The production of bio-ethanol Starch, cellulose, inulin Saccharose containing materials (sugar beet, sorghum, etc.) STARCH GLUCOSE Decomposition of starch (cooking with thermo stabile amylase; Hydrolysis (gluco-amilase) Fermentation ALCOHOL The alcohol production potential of different plants Plant Yield tha-1 total million t Sugar beet 38.0 143.0 Wheat 3.5 Maize Transformation efficiency % Ethanol yield lt-1 lha-1 35 95 4300 82 24 356 1200 4.5 49 32 387 2100 Potato 10.3 0.1 82 110 3050 Sugar cane 57.0 187 31 67 5300 Aim: to increase the starch content of wheat for increasing bioethanol yield STARCH RAW PROTEIN, GLUTEN Material and methods Treatment: manganese carbohydrate Plant: winter wheat Phenological phase: booting Way of application: foliar Soil type: Danube alluvial, Darnózseli, Hungary Experiment: 10 m2 plots, 4 repetitions, randomised block design Doses: 0.05, 0.1, 0.3, 0.5 kgha-1 Mn Soil analysis results. Darnózseli 2005. pH KA CaCO 3 H2O KCl 7.7 7.3 42 5.1 Humus % 2.1 AL-soluble mgkg-1 Mg mgkg- EDTA-soluble mgkg-1 1 P2O5 K2O Na 228 205 51 58 Zn Cu Mn Fe 1.2 0.9 18 19.7 The effect of the treatments on the yield 5 5 The lowest yield was measured at 0.5 kgha-1 Mn dose, the value was lower than that of the control. 4,9 Yield t/ha The Mn-complexes increased the yield generally, the highest yield was measured at the 0.05 kgha-1 dose, at the higher doses the yield decreased. 4,9 4,8 4,7 4,7 4,7 4,6 4,6 4,5 4,4 Dose kg/ha 0 0,05 0,1 0,3 0,5 There was not any significant yield increase due to the treatments (LSD5% = 0.57). The manganese treatments decreased the protein content. We measured the lowest protein content at the Mn-dose of 0.05 kgha-1. The Mn-doses higher than this increased the protein content a little, but it was still lower than the protein content of the control. Raw protein % Raw protein content 13,2 13,1 13 12,9 12,8 12,7 12,6 12,5 12,4 12,3 13,2 13,1 12,9 12,6 Dose kg/ha 0 0,05 12,7 0,1 0,3 0,5 Starch content (LSD5% = 1.5). 58,7 59 58,7 58,2 58,5 Starch % As a result of the treatments the starch content increased and at the 0.1 and 0.3 kgha-1 Mn-saccharose treatment the increase of the starch content was significant 57,8 58 57 57,5 57 56,5 56 Dose kg/ha 0 0,05 0,1 0,3 0,5 Conclusions The lower doses of Mn-saccharose increased the yield. The 0.05 kgha-1 increased the yield the most, but it still was not significant. At the same time at this dose we measured the lowest (12.63 m%) raw protein content. Due to the raising Mn-doses the starch content increased, compared to the control. This increase was significant in the case of the Mn-dose of 0.1 kgha-1 and 0,3 kgha-1. Thank you for your attention!
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