UNIT 4 (TEXTBOOK UNIT 7) PREPARED BY: MS. SHEULI MITRA, FACULTY, DEPT OF ARCHITECTURE ENVIRONMENTAL CONCERNS GLOBAL WARMING Definition Global warming is the phenomenon of increase in the average temperature of the air near the Earth's surface and oceans since the mid-20th century and its projected continuation. GLOBAL WARMING GLOBAL WARMING Key Facts Global surface temperature increased 0.74 ± 0.18 °C (1.33 ± 0.32 °F) – around a centigrade, during the last century. The average worldwide nearsurface temperature is about 14 °C. An increase of around 1°C in the average temperature near the earth’s surface makes it warmer than it was in the past 1000 years, at least. In 1995 IPCC (International Panel on Climate Change) predicted that global surface temperature will probably rise a further 3.5 – 10 °C during the twenty-first century, if present trends continue. GLOBAL WARMING Main Causes Fossil fuel burning and deforestation are responsible for most of the observed temperature increase since the middle of the 20th century, as they cause an increase in concentration of green house gases in the atmosphere, which in turn trap heat. Other causes: Solar radiation variations, volcanic eruptions were some causes of temperature increase in the pre-industrial era, but do not account for the extent of continuous temperature change resulting in global warming today. GLOBAL WARMING Green-house effect: The greenhouse effect is the heating of the surface of earth (or any other planet) due to the presence of an atmosphere containing gases that absorb and emit infrared radiation. Incident Solar radiation is largely in the visible spectrum and has small proportions of Ultra violet and infra Red rays and passes through the atmosphere surrounding the earth. The earth absorbs about 50% of solar radiation but emits it back partially as infrared radiation (heat) The infrared radiations emitted by the earth are absorbed by some gases in the atmosphere and re-emitted back as heat in all directions including towards the earth’s surface. GLOBAL WARMING Green-house effect: Without an atmosphere and the greenhouse effect it creates, the Earth's average surface temperature of 14 °C would be as low as −18 °C and life would not be supported on the surface of the earth. Green house effect in the context of Global warming, is the phenomenon of a recent increase in warming of the Earth's lower atmosphere as evidenced by the abnormal rise in global mean temperature. This is believed to be the result of an "enhanced greenhouse effect" mainly due to human-produced increased concentrations of greenhouse gases in the atmosphere. GLOBAL WARMING GLOBAL WARMING Green-house effect: Which gases mainly cause the green house effect? Water vapor, which contributes 36–70% Carbon dioxide, which contributes 9–26% Methane, which contributes 4–9% Ozone, which contributes 3–7% The major non-gas contributor to the Earth's greenhouse effect, clouds, also absorb and emit infrared radiation. GLOBAL WARMING What are the Causes? Increase in CO2 in the atmosphere due to increase in human activities producing CO2 like burning of fossil fuel for generation of electricity, and other industrial processes. Cutting of trees for urbanization and deforestation have resulted in more CO2 in the atmosphere. Increase in amounts of Methane released from marshes and bogs and animal excreta. The 2005 levels of in the atmosphere (375 ppm) are higher than the highest recorded in the last 800,000 years (in the range of 270 ppm in post industrial era) GLOBAL WARMING Adverse Effects of global warming: An increasing global average temperature causing multiple secondary effects which in turn trigger a chain of reactions: Changes in patterns of precipitation Increased extreme weather events altered patterns of agriculture, the expansion of the range of tropical diseases, Melting of ice caps and rising sea levels Threat to coastal settlements Change in the pH balance of sea water, affecting marine life GLOBAL WARMING Responses to global warming: Adaptation - dealing with the effects of global warming, Mitigation - reducing carbon emissions, Geo-engineering- directly intervening to modify the climate GLOBAL WARMING Adaptation to Global warming Initiatives and measures to reduce the vulnerability of natural and human systems against actual or expected climate change effects. Construction of flood defenses Abandoning of settlements affected by rising sea levels Water conservation Adjustments to agricultural yield abnormalities Protection of threatened species GLOBAL WARMING Mitigation of Global warming Global average temperatures would continue to rise if human activities producing increased green house gases are not controlled. Several measures are being taken across the globe to reduce green house emissions – individual, community and regional measures. International treaties to implement reduction in emissions: Rio de Janeiro Earth Summit, 1992 Kyoto Protocol GLOBAL WARMING International treaties: Rio de Janeiro “Earth Summit” 1992 The United Nations Framework Convention on Climate Change (UNFCCC) is an international treaty agreed at the Rio de Janeiro "Earth Summit" in 1992. It acknowledges the ‘climate justice principle’ that developed countries alone should take initial responsibility for the reduction of greenhouse gas emissions. These countries are known as Annex 1 countries GLOBAL WARMING International treaties: Kyoto Protocol Negotiated in 1997, it postulates that Annex 1 countries are subject to legally binding targets of reduction of green house emissions. The Kyoto Protocol was a supplement to the UNFCC and was eventually ratified in February 2005. Kyoto target: the Annex 1 countries should achieve in aggregate a 5% reduction in their green house gas emissions of 1990 by the year 2012. GLOBAL WARMING Geo-engineering Geo-engineering is the planned modification of the earth's natural environment on a large scale to suit human needs. Solar radiation management Removal of green house gases from the atmosphere Large scale geo-engineering projects have not yet been implemented but are in the research stage. ACID RAIN Definition Acid rain is rain or any other form of precipitation that is unusually acidic (Ph value significantly less than 7) When chemicals from burned fossil fuel mix with moisture in the atmosphere and fall to the ground as rain, snow, sleet, etc., acid rain occurs. ‘Acid deposition’ is a more precise name than acid rain because acid can fall to the ground as not only rain but any form of precipitation and is called ‘wet deposition’ It can also combine with dry particulate matter and fall to the ground and is then called ‘dry deposition’. ACID RAIN ACID RAIN Composition of Acid Rain “Clean” or unpolluted rain has a slightly acidic pH of about 5.2, because carbon dioxide and water in the air react together to form carbonic acid (H2CO3), a weak acid (pH 5.6 in distilled water) Distilled water, which contains no carbon dioxide, has a neutral pH of 7. Acid rain has Ph between 2 and 5.5 and has Sulphuric acid and Nitric acid content ACID RAIN Acid rain in Europe-1993, Hydrogen ion print in USA 1997 ACID RAIN Causes of Acid Rain Acid rain forms in the atmosphere from chemicals created by the burning of fossil fuels. When coal and oil are burned they release sulfur dioxide (SO2) and two nitric oxides, nitric oxide (NO) and nitrogen dioxide (NO2) designated by the symbol NOX, which are the main components of smoke emitted from factories and vehicle exhaust pipes. The sulfur dioxide and nitrogen oxides emitted, react with other chemicals in the air, water vapor, and sunlight to produce sulfuric and nitric acids, the acids in acid rain. The more sulfuric and nitric acids present, the higher the acidity of the rain. ACID RAIN Acid rain causing emissions from different sources in US ACID RAIN Adverse Effects of Acid Rain On Surface waters and aquatic animals: Both the lower pH and higher aluminum concentrations in surface water that occur as a result of acid rain can cause damage to fish and other aquatic animals. At pHs lower than 5 most fish eggs can not hatch and lower pHs can kill adult fish also. As lakes and rivers become permanently acidic Aquatic biodiversity is reduced as Acid rain has already eliminated some insect life and fish species ACID RAIN Adverse Effects of Acid Rain On Soils: Soil biology and chemistry can be seriously damaged by acid rain. Some microbes are unable to tolerate changes to low pHs and are killed. The enzymes of these microbes are denatured (changed in shape so they no longer function) by the acid. The hydronium ions of acid rain also mobilize toxins such as aluminium, and leach away essential nutrients and minerals such as magnesium. ACID RAIN Adverse Effects of Acid Rain On Forests and other vegetation High altitude forests are affected strongly as they are often surrounded by clouds and fog which are more acidic than rain. Other plants are also damaged by acid rain. ACID RAIN Adverse Effects of Acid Rain On Human health Fine particles, a large fraction of which are formed from the same gases as acid rain (sulfur dioxide and nitrogen dioxide), have been shown to cause illness and premature deaths such as cancer and other diseases. Other effects: The acid in rain corrodes the stones and cement in buildings. Some buildings have been permanently weakened beyond repair. ACID RAIN Preventive measures Technical solutions Use of Fuel gas desulfurization (FGD) in many coalburning power plants to remove sulfur-containing gases from their stack gases. Lime or limestone in slurry form is also injected into the tower to mix with the stack gases and combine with the sulfur dioxide present, to form calcium sulphate , which may be even sold as commercial gypsum Automobile emissions control reduces emissions of nitrogen oxides from motor vehicles. ACID RAIN International Treaties Sulphur Emissions Reduction Protocol under the Convention on Long-Range Transboundary Air Pollution (CLRTAP). It is intended to protect the human environment against air pollution and to gradually reduce and prevent air pollution, including long-range transboundary air pollution. The convention opened for signature on 1979 and entered into force on 1983 ACID RAIN International Treaties Sulphur Emissions Reduction Protocol under the Convention on Long-Range Transboundary Air Pollution (CLRTAP). The aim of the Convention is that countries shall endeavour to limit and, as far as possible, gradually reduce and prevent air pollution including long-range transboundary air pollution. Countries develop policies and strategies to combat the discharge of air pollutants through exchanges of information, consultation, research and monitoring. OZONE DEPLETION The Ozone Layer The ozone layer is a layer in Earth's atmosphere which contains relatively high concentrations of ozone (O3). About 90% of the ozone in our atmosphere is contained in the stratosphere, mainly in its lower portion, from approximately 10 km to 50 km above Earth, though the thickness varies seasonally and geographically The significance of the Ozone layer is that this layer absorbs 93-99% of the sun's high frequency ultraviolet light, which is potentially damaging to life on earth. OZONE DEPLETION Ozone layer in atmosphere OZONE DEPLETION The Ozone Layer Ozone concentrations are greatest between about 20 and 40 km, - about 2 to 8 parts per million. The Dobson Unit is the unit of measurement of the amount of Ozone in an air column overhead. Ozone in the earth's stratosphere is created by ultraviolet light striking oxygen molecules (O2), splitting them into individual oxygen atoms (atomic oxygen); the atomic oxygen then combines with unbroken O2 to create ozone, O3. The ozone molecule is also unstable and when ultraviolet light hits ozone it again splits into a molecule of O2 and an atom of OZONE DEPLETION What is Ozone Depletion? Ozone depletion describes two distinct, but related phenomena: A slow, steady decline of about 4% per decade in the total volume of ozone in Earth's stratosphere (ozone layer) since the late 1970s A much larger, but seasonal, decrease in stratospheric ozone over Earth's polar regions during the same period. This phenomenon is commonly referred to as the ‘ozone hole’. There is also Tropospheric ozone depletion, which occurs near the surface of the earth in polar regions during spring. OZONE DEPLETION Arctic Ozone depletion Ozone Hole Seasonal Variations in Arctic Ozone Concentration OZONE DEPLETION Causes of Ozone Depletion The catalytic destruction of ozone is caused by atomic chlorine and bromine. The main source of these halogen atoms in the stratosphere is from chlorofluorocarbon (CFC) compounds, commonly called Freons, and Bromofluorocarbon compounds known as Halons. These compounds are transported into the stratosphere after being emitted at the surface and release free radicals of chlorine and bromine on interacting with sunlight. Both mid altitude and polar ozone depletion mechanisms increased with increase in emissions of CFCs and halons. OZONE DEPLETION Total Ozone in Atmosphere CFC Emissions in Atmosphere OZONE DEPLETION Correlating chlorine concentrations in Industry products with their ozone depleting potential The HCFCs and HFCs are considered environmentally superior to CFCs because they are largely destroyed in the lowest region of the atmosphere. The HFCs do not contain chlorine and have no potential to deplete ozone. HCFCs, however, do contain chlorine, but only a small percentage of that chlorine can affect the ozone layer; Most of the HCFCs released at ground level are destroyed in the lower atmosphere before they reach the stratospheric ozone layer. OZONE DEPLETION The Magnitude of the threat: Once in the stratosphere, every chlorine atom can destroy up to 100 000 ozone molecules. The lifetime of some of these ozone depleting substances is very long, and they may continue to deplete the ozone layer long after their use has been phased out. Aircraft emissions of nitrogen oxides and water vapour add to this depletion effect by creating ice crystals that serve as a base for ozone destroying reactions. OZONE DEPLETION Effect of Ozone Depletion Since the ozone layer prevents most harmful UVB wavelengths (270–315 nm) of ultraviolet light (UV light) from passing through the Earth's atmosphere, decreases in ozone increases the penetration of UV rays through the atmosphere significantly. A one percent loss of ozone leads to a two percent increase in UV radiation. Disturbance of the thermal structure of the atmosphere may result, probably causing changes in atmospheric circulation; Efforts to tackle ozone depletion may result in increased OZONE DEPLETION Harmful Effects of Exposure to UV radiation Continuous exposure to UV radiation affects humans, animals, and can lead to: skin problems (ageing, cancer), depression of the immune system, and corneal cataracts (an eye disease that often leads to blindness). Damage to plant life Increased UV radiation may also lead to a massive die-off of photo plankton in the ocean (a CO2 "sink") and therefore further increase atmospheric CO2 enhancing global warming OZONE DEPLETION Montreal Protocol The Montreal Protocol on Substances That Deplete the Ozone Layer is an international treaty designed to protect the ozone layer by phasing out the production of a number of substances believed to be responsible for ozone depletion. The treaty was opened for signature in 1987 and entered into force in 1989 Since then it has undergone seven revisions, the last being in 1999. It is widely accepted that if the international agreement is adhered to, the ozone layer is expected to recover by 2050. OZONE DEPLETION Correlating chlorine concentrations in Industry products with their ozone depleting potential An index called the Ozone Depletion Potential (ODP) has been adopted for regulatory purposes under the Montreal Protocol. The ODP of a compound is an estimate of the total ozone depletion due to 1 Kg of the compound divided by the total ozone depletion due to 1 Kg of CFC-11.
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