Solar Radiation, Albedo, and Light Transmission in Seawater Equipment needed for each student group: 1 microscope light 1 portable ‘lux’ meter (digital light meter) 1 aquarium 1 stopwatch 1 globe 1 meter stick 1 mini secchi disk (2 cm diameter) taped to a 30 cm ruler For general class use: Powdered silica (<0.0004 cm diameter) 3 color filters (blue, green and red) 1.5 meter long tubes filled with water 4 dishes of surface types and albedo setup (overhead lights off during this laboratory; shades drawn) DISCUSSION: Solar Radiation In order to discuss solar radiation we need to first define a calorie. A calorie is the amount of heat energy required to raise the temperature of 1 gm of freshwater one degree Centigrade. We also need to establish two points about the relationship between the sun and the earth. First, the sun is so far away from the earth that its rays are essentially parallel as they reach the earth (Fig. 1). Secondly, the earth is tilted on its axis of rotation. As it revolves around the sun (once each year) this tilt causes the sun to be overhead at 23.5oN at summer solstice (June 21) and to be overhead at 23.5oS at winter solstice (December 22), and overhead at the equator on March 21 (vernal equinox) and September 23 (autumnal equinox). These two factors cause an unequal heating of the earth's surface. The solar constant is the rate at which heat energy reaches the earth's upper atmosphere and is so named because it is very constant at 2.0 cal/ cm2/min. There are several factors that affect the actual amount of energy that reaches the surface of the earth (http://oceanz.tamu.edu/~wormuth/physicalproperties/eartheatbudget.gif). During this lab exercise, we will use a light meter to measure incoming radiation. If we consider the autumnal or vernal equinox, when the sun is directly overhead at the equator, a flat surface of fixed dimensions will receive more energy than would the same surface at a higher latitude because of the curvature of the earth's surface (Fig. 1). EXERCISE 1: Measuring a ‘Solar Constant’ 1. For your first two exercises, you need to emulate the sun/earth relationship at autumnal or vernal equinox, as shown in Figure 2. To do this, put your globe in the dish provided and position it so that the equator is level and the Pacific Ocean faces the light source. Measure the height of the equator from the bench top and adjust the center of the light source to be at the same height. This should make the maximum light level fall at the equator. Move the globe away from the light source until there is a slight halo of light on the wall behind the globe. Once this distance is established, keep it constant for Exercise 1 and 2. 1 of 15 FIGURE 1 2. It will be necessary to use the lux meter (Fig. 3) to confirm this by moving it slightly north and south of the equator. If the light level is higher in either direction, adjust the height of the light source to make the maximum occur at the equator (Fig. 4). The lux meter should be set on the lowest scale (x 1). Record the light level on your forms as the solar constant and as the equator (0o) value. FIGURE 2 2 of 15 FIGURE 3 FIGURE 4 3 of 15 EXERCISE 2: Latitude Effect on the Incoming Radiation As Fig. 1 shows, the same amount of solar energy reaching the surface of the earth when the sun is directly overhead at the equator is spread out over a larger surface area at higher latitudes, and, therefore, there is less heating per unit area at higher latitudes than at lower latitudes. Ocean currents redistribute this unequal heating, carrying colder water towards the equator and warmer water toward the poles (http://oceanz.tamu.edu/~wormuth/geostrophic/pacificsurfacecurrents.gif). This exercise will allow us to make our own measurements to show this phenomenon. 1. To demonstrate the effect of latitude, measure the light levels along 180o longitude in the Pacific Ocean (the International Date Line) every 15o as indicated in Fig. 5 and record them in Table 1 on your form. Make sure your measurement is along the same line of longitude and hold the lux meter sensor tangent to (flat against) the surface of the globe at each latitude. Graph your results in Table 2. To do this, create your own scale on the y-axis based on the range of lux readings you recorded. For example, if your values we between 200 and 4, you would assign a value of 0 for the bottom, 200 for the top and each increment would increase 10. After complete the graph, answer the following questions on your forms: FIGURE 5 TABLE 1 0o 15o 30o 60o 75o 90o 4 of 15 45o TABLE 2 Answer the following questions: A. Is this a linear relationship indicating a constant change in radiation with latitude? Why or why not? B. During the northern hemisphere winter, the distance between the earth and the sun is at a MINIMUM; during the summer the distance is at a MAXIMUM, yet the summers are warmer and the winters are colder. How would you explain this? 5 of 15 DISCUSSION: Albedo A portion of the incident radiation that comes to earth is reflected back into the atmosphere (http://oceanz.tamu.edu/~wormuth/physicalproperties/eartheatbudget.gif). The ratio of the reflected radiation divided by the incident radiation is called the albedo and it varies depending on the surface material: its color, composition and texture. Exercise 3 will compare the albedo of the following common materials found on land and on the surface of the ocean: Snow covered surface (represented by light colored sand) Soil covered surface (represented by dark colored sand) Water covered surface (represented by dark colored sand in 5-10 cm of water) Glaciers or Ice sheets (represented by 5-10 cm thick ice block) If we consider the following albedo equation, which material will you expect to have the greatest albedo and why? Which should have the least and why? albedo = reflected radiation incident radiation ______________________________________________________________________________ ______________________________________________________________________________ ______________________________________________________________________________ EXERCISE 3: Albedo The overhead lights should be on for this portion of the lab 1. A small dish will be used to hold the four various earth materials over which the albedo is measured. 2. Using the ambient light in the room, measure the INCIDENT RADIATION that will hit the surface of the material by holding the lux meter face up above the center of the dish. 3. One dish will contain white sand (collected off the beach in Clearwater, Florida [not financed by your lab fees]). 4. Next measure the REFLECTED RADIATION by holding the lux meter sensor down, 5-10 cm above the center of dish. Record the maximum reflection from the surface of the white sand on your forms. Calculate the albedo according to the formula above. 5. Replace the dish containing the white sand with the dish containing the dark colored sand: repeat the albedo experiment. You need only measure the reflected light since the incident light will be the same for all four materials. The vertical distance should be the same for both meters. NOTE: IT IS VERY IMPORTANT TO TAKE READINGS FROM THE SAME SPOT FOR EACH ALBEDO! Fill in the blanks on Table 3 for the reflected light and the albedo. 6 of 15 6. Replace the cover containing the dark sand with the dish containing the dark sand and water: repeat the albedo experiment. Record the data on Table 3. Be careful not to get the lux meter wet! 7. Finally, replace the cover containing the dark sand and water with the cover containing the dark sand and ice (mimicking ice-covered shallow water) and repeat the albedo experiment. Again, record the data on Table 3 and calculate the albedo. TABLE 3 INCIDENT RADIATION CRUSHED ICE/LIGHT SAND (SNOW) reflected radiation (LUX) DARK SAND (SOIL) reflected radiation albedo albedo WATER WITH BLACK SAND (OCEAN) reflected radiation SOLID ICE (GLACIER) reflected radiation albedo albedo Answer the following questions: A. Which would be the better reflector of incident radiation - soil or water? Is this to be expected? Explain! B. From your albedo experiments, can you ‘guess’ why it took such a long time for the continental glaciers to melt once they had become established? C. How will the melting of the ice caps over the North Pole change the overall albedo of the earth? 7 of 15 DISCUSSION: Qualitative Changes of Light in Seawater As light strikes the surface of the ocean and penetrates below the surface, there are two types of changes that take place: qualitative changes and quantitative changes. In Exercise 4 we will look at the qualitative changes and in Exercise 5 we will look at the quantitative changes. Light is made up of many wavelengths. Most of these wavelengths fall in the visible part of the spectrum, which we see as ‘white light’. This light can be split into component colors by a prism or by raindrops in the atmosphere to form a rainbow. When light strikes the surface of the ocean, some wavelengths can't penetrate very far below the surface of the ocean. These wavelengths can still be important (i.e., UV light which can cause skin cancer and is affected by ozone, or lack thereof, in the atmosphere). The selective transmission of various wavelengths influences colors of organisms as they appear to us at the depths where they live, and that has had an important evolutionary influence on the photosynthetic pigments in oceanic plants. EXERCISE 4: Transmission of Visible Light as a Function of Wavelength 1. Fill a 1.5 meter tube sealed on one end with water. In the room you will find a light, colored wavelength filter, tube, stand and lux meter in the arrangement shown in Figure 6. You will be responsible for changing the colored filters out and for recording the readings. Hold the light meter sensor directly against the acrylic sealed end when making light measurements. FIGURE 6 Lamp Filter Open end NOTE: Items are not to scale Lux Meter Sealed end Support Stand 8 of 15 2. Make sure that the light source and filter are as close as possible to the top of the water surface without getting the filter wet. It is important to not move the light during all of your measurements with the tube. 3. First, measure the values for transmitted radiation, I1. Start with the white light passing through the tube when there is no filter. Record this lux meter reading on your forms in Table 4. 4. Without moving either the light source or the light sensor, slide one of the colored filters between the light source and the water. Record the reading for transmitted radiation on your forms in Table 4. Repeat this for the other color filter, making sure to record the data. 5. After finishing all the transmitted values with the tube, measure the incident radiation, I0, for each color and white light. To do this, hold the sensor at a maximum distance of 5 inches from the lamp with nothing between the filter and the sensor. Enter the results in Table 4 on your form. 6. In Table 4, calculate the percent of light transmission by comparing the light passed through the tube for each colored filter and for white light with the direct light measurement for each respectively. The percent transmission is calculated by the following equation where I1 is the measurement through the tube of water and I0 is the direct light measurement: % Transmission = I1 X 100 I0 TABLE 4 I1 I0 % Transmission white light violet light green light red light 9 of 15 7. Plot the % of the light transmission of the various colors on the bar graph below in Table 5. TABLE 5 Answer the following questions: A. From your experiments can you tell which of these three colors would be less detectable if you were looking down from a glass bottom boat at objects 10 meters deep in the water? Explain. B. If you took a flash photo at close range with an underwater camera of a red and green starfish, would the colors in the photo be the real colors? Why or why not? C. You collect a bright red shrimp in a deep sea trawl at 200m depth. It would seem that this shrimp would be very conspicuous to its predators, yet isn't. Why might this be so? 10 of 15 DISCUSSION: Quantitative Changes of Light in Seawater One of the measurements oceanographers (particularly biological oceanographers) take is that of water clarity. There is an equation that governs the vertical extinction (or loss) of light as it penetrates down into the water column. This equation allows us to estimate the light intensity at any given depth once we know the surface light intensity and a coefficient of extinction for that particular water column. The form of the equation is a negative exponential. This means the quantitative loss of light is not a linear loss, but is greater in the upper portion of the water column and becomes less as one goes deeper. The loss of light in water is due to several factors. First is the scattering of light by particles, both living and non-living. Additionally, light absorption by living particles (small plants) decreases the amount of light that reaches depths. Also, the conversion of light to heat energy contributes to light loss in water by raising the temperature of the water slightly. Many particles are vertically stratified in the water column. Plants occur only in the upper 150 m or so, and they depend on downwelling light for photosynthesis. Biologists measure the penetration of light VERTICALLY in the water column to relate it to plant growth. They sometimes use a secchi disc to accomplish this. A secchi disc is a flat disc, usually with alternating quadrants of black and white. An observer watches the secchi disc as it is lowered down into the water, recording the depth at which it just disappears from sight. Interestingly enough, studies have shown that this depth is relatively independent of the diameter of the disc or the visual acuity of observers with ‘normal’ eyesight. There are oceanographers who are interested in the HORIZONTAL transmission of light. For their measurements, they use a transmissometer, an instrument that utilizes a horizontally oriented light source and a horizontally oriented light sensor. These are usually separated by 1 m or less. Once calibrated, the transmissometer measures the % light transmission at various depths as it is lowered down through the water column. In the lab today we will use a very small secchi disc to make horizontal determinations of light transmission in different concentrations of suspended silica. Since the light meters are not waterproof, we are not able to make vertical measurements. 11 of 15 EXERCISE 5: Turbidity and Secchi Disk Measurements 1. Fill the provided aquarium with water to 19 cm depth. Measure the white light intensity (in LUX) over the 49.5 cm path length of the aquarium. Place the mini secchi disk in the aquarium and slide it from the source of light toward the far end (Fig. 7). Record the point at which the secchi disk is no longer visible when looking from the end of the aquarium with the light source (note: without silica in the water you will see it all the way back to the far side of the aquarium). Enter the light attenuation value in Table 6 on your forms. FIGURE 7 2. Add exactly 2.4 gms of powered silica to the aquarium, and mix it thoroughly. Note that the silica tends to clump on the bottom when it is first dropped in the water, so be sure to stir all the way to the bottom. Each aquarium will contain 16 liters of water (at 19 cm water depth), so the concentration of the silica suspension is 150milligrams/liter when thoroughly mixed. Wait a few seconds for the water in the aquarium to calm down. Then, using the digital lux meter, measure the light which passes through the 49.5 cm path length. Record the data in Table 6 on your forms. 3. Add an additional 1.2 gms of silica, mix, and measure the light attenuation and ‘depth of visibility’ once again. (This is equivalent to 225mg/liter or 3.6 gms). 4. Add a final 1.2 gms of silica and repeat the experiment. Record all the data in on your form. 12 of 15 TABLE 6 sediment concentration ( gms, milligrams/liter) light intensity (LUX) limit of visibility (centimeters) 49.5 cm 0 gms, 0mg/l 2.4 gms, 150mg/l 3.6 gms, 225mg/l 4.8 gms, 300mg/l 5. Plot the data on from Table 6 onto Table 7. Don’t plot the first point at zero silica concentration. Instead, you will set your own scale for the 3 different densities (150mg/l, 225mg/l, and 300mg/l). To do this, fill in the scale on the left y-axis using the range of values you recorded. For example, if your lux readings were between 200 – 350, your bottom value would be 150, the top value 400 and each increment would increase 50. You will graph 2 lines, so use two different symbols: ‘X’ for light attenuation and ‘O’ for depth of visibility. Connect the Xs with one straight line and the Os with another. TABLE 7 13 of 15 Answer the following questions: A. In your opinion, which is the more accurate measure of turbidity: measuring light loss with the lux meter or using the mini Secchi disk? Justify your choice. B. Suppose that rather than silica particles (about 40 microns), you had added the same concentration (150, 225 and 300mg/l) of sand sized particles to the aquarium. Would you expect the turbidity (i.e., light attenuation) to be the same, greater or less? Justify your answer. DISCUSSION: LIGHT ATTENUATION AND SETTLING RATES Turbidity is a physical property of seawater that changes with time. For example, if a severe coastal storm causes flooding, river systems almost immediately transport suspended sediment into the estuaries, thereby raising the turbidity of the seawater. The amount of time the suspended sediment stays in the water column is a function of the sediment size and its settling rate. In addition, the common suspended sediment size along the Texas coast is in the clay sized particles. Examples of this can be seen in the Brazos and Mississippi rivers. When clay-sized particles enter seawater, the flat, plate-like clay particles tend to clump together through a process called flocculation. Once this happens, the ‘effective particle size’ is increased and the particles settle out more rapidly than would otherwise be expected. Phytoplankton are also affected by ‘sinking’ which is a function of size and density difference between a particular species and the seawater in which it lives. This means that the same species will sink more slowly in colder water (higher latitudes) than in warmer water (lower latitudes) of the same salinity because the density difference will be less. If the phytoplankton sink out of the photic zone, productivity ceases. To combat sinking, some species have developed adaptations to decrease their settling rates (i.e., oils to reduce bulk density and spines to increase their surface area to volume ratio, thereby increasing frictional forces). EXERCISE 6: Light Attenuation and Settling (Lamp intensity same as in Exercise 5) 1. The aquarium still has 300mg/l suspended sediment from the previous experiment. Turn on the microscope light, and resuspend the sediment with the secchi. Wait a few seconds for the surface of the water to stabilize, then begin recording the light intensity (lux) along the 49.5 cm path length at one minute intervals for 0-10 minutes using the stopwatch (record your data in Table 8 on your forms). 2. Fill in the suspended sediment column by estimating the correct values from the light intensity curve you prepared in Table 7 from Exercise 5. 3. Plot the suspended sediment concentrations as a function of time from 0-10 minutes in Table 9. 14 of 15 TABLE 8 time light intensity (LUX) suspended sediment 0 1 min 2 min 3 min 4 min 5 min 6 min 7 min 8 min 9 min 10 min TABLE 9 Answer the following question: A. Examine the sedimentation concentration curve in Table 9. Explain why there is not a straight line decrease over the 10 minute period! 15 of 15
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