Bioenergy World Energy Prospects Population (billion) World's Population 12 10 8 6 4 2 0 10 6.7 Increase in Population 2008 2050 Year Source: •CIA's The World Factbook • World POPClock Projection, U.S. Census Bureau • Energy Sources, 26:1119-1129,2004 60% Energy demand 63160% Why a Crisis? Continued increase in consumption of fuels. Pollution Climate change Resource depletion Here’s a little video that will put into perspective why we need more and more energy all the time: http://www.youtube.com/watch?v=gLBE5QAYXp8 Why Do We Need Energy? Energy Energy Energy Energy Energy Energy produces light. produces heat. produces motion. produces sound. produces growth. powers technology. Measuring Thermal Energy The energy contained in gasoline, wood, or other energy sources can be measured by the amount of Btu’s it can produce. A Btu (British thermal unit) is the amount of thermal energy needed to raise the temperature of one pound of water one degree Fahrenheit. A wooden match, if allowed to burn completely, would give off about one Btu of energy. One ounce of gasoline contains almost 1,000 Btu’s of energy. Every day, the average American uses about 890,000 Btu’s. Measuring Electrical Energy Volts—the pressure that pushes electrons through a circuit. It measures the strength of the current. Current—electrons flowing between two points, measured in amps. Amps—One amp, or ampere, is 6.25 x 1018 electrons per second passing through a circuit. Watt—A watt is a standard unit of power. For electrical power, one watt is equal to one ampere of current per second. A kilowatt is a thousand watts. A 100 watt bulb left on 24 hours a day for a year will use 876 kW. Ohms—An ohm is a unit of electrical resistance. Kilowatt hour--One kilowatt hour is the amount of energy that would be used by a device with a power of 1 kilowatt which was left to operate for 1 hour. Alternatives to Fossil Fuels Wind Solar Hydro Dams for electricity Hydrogen from water as fuel Nuclear Biofuels from biomass Geothermal What Is Biomass? Biomass is biological material derived from living, or recently living organisms. In the context of biomass for energy this is often used to mean plant based material, but biomass can equally apply to both animal and vegetable derived material. Current Bio Sources Used for Energy Corn Canola Sorghum (milo, cane) Grasses Waste materials from crops Algae Manure Garbage What in Biomass Is Used for Energy? Carbohydrates Contain carbon, hydrogen, and oxygen Includes sugars and starches and cellulose Carbs already have O2 bonds so it doesn’t release as much energy as broken bonds of hydrocarbons Lipids aka “fats” Contain mostly carbon and hydrogen chains (long molecular bonds) C-H bonds are more difficult to break, thus releasing more energy when they do. That’s why we like fossil fuels! Proteins Proteins are not commonly used for energy They do not burn well and convert to toxic chemicals when combusted. Renewable Energy Sources Summary of energy resources consumption in United States, 2004 It is estimated by 2030 bio-energy will be 15-20% of our energy consumption Source: USDA-DOE, 2005, http://www.eere.energy.gov/biomass/publications.html. Global Biomass Energy Flows Carbon Lifecycle http://www.greatlakesbioenergy.org/20 09/07/14/life-cycle-assessment-ofbiofuel-energy/ http://www.greatlakesbioenergy.org/20 09/08/19/life-cycle-assessment-ofcarbon-in-biofuel-production/ Overview Bioenergy history Ag wastes and other biomass Biomass to Bioenergy Conversion processes Pros & Cons Applications Biofuels Bioheat Bioelectricity Some U.S. Bioenergy History Bioenergy is not new! 1850s: Ethanol used for lighting (http://www.eia.doe.gov/ kids/energyfacts/sources/renewable/ethanol.html#motorfuel) 1860s-1906: Ethanol tax enacted (making it no longer competitive with kerosene (a fossil fuel for lights) 1896: 1st ethanol-fueled automobile, the Ford Quadricycle (http://www.nesea.org/greencarclub/factsheets_ethanol.pdf) More Bioenergy History (photo from http://www.modelt.org/gallery/picz.asp?iPic=129) 1908: 1st flex-fuel car, the Ford Model T 1919-1933: Prohibition banned ethanol unless mixed with petroleum WWI and WWII: Ethanol used due to high oil costs Early 1960s: Acetone-Butanol-Ethanol industrial fermentation discontinued in US Today, about 110 new U.S. ethanol refineries in operation and 75 more planned Ag wastes and other biomass Waste Biomass Crop and forestry residues, animal manure, food processing waste, yard waste, municipal and C&D solid wastes, sewage, industrial waste New Biomass: (Terrestrial & Aquatic) Solar energy and CO2 converted via photosynthesis to organic compounds Conventionally harvested for food, feed, fiber, & construction materials Agricultural and Forestry Wastes Crop residues Animal manures Food / feed processing residues Logging residues (harvesting and clearing) Wood processing mill residues Paper & pulping waste slurries Municipal garbage & other landfilled wastes Municipal Solid Waste Landfill gas-to-energy Pre- and post-consumer residues Urban wood residues Construction & Demolition wastes Tree trimmings Yard waste Packaging Discarded furniture Biomass to Bioenergy Biomass: renewable energy sources coming from biological material such as plants, animals, microorganisms and municipal wastes Bioenergy Types Biofuels Liquids Methanol, Ethanol, Butanol, Biodiesel Gases Methane, Hydrogen Bioheat Wood burning Bioelectricity Combustion in Boiler to Turbine Microbial Fuel Cells (MFCs) Advantages of Biomass Widespread availability in many parts of the world Contribution to the security of energy supplies Generally low fuel cost compared with fossil fuels Biomass as a resource can be stored in large amounts, and bioenergy produced on demand Creation of stable jobs, especially in rural Environmental Benefits Drawbacks of Biomass Generally low energy content Competition for the resource with food, feed, and material applications like particle board or paper Generally higher investment costs for conversion into final energy in comparison with fossil alternatives Applications Biofuel Applications: Liquids Ethanol and Butanol: can be used in gasoline engines either at low blends (up to 10%), in high blends in Flexible Fuel Vehicles or in pure form in adapted engines Biodiesel: can be used, both blended with fossil diesel and in pure form. Its acceptance by car manufacturers is growing Process for cellulosic ethanol (ethanol made from cellulose, the fibrous material in plants) http://www1.eere.energy.gov/biomass/abcs_biofuels.html References Ezeji, T., N. Qureshi, H.P. Blaschek. 2007. Butanol production from agricultural residues: Impact of degradation products on Clostridum beijerinckii growth and butanol fermentation. Biotechnol. Bioeng. 97, 1460-1469. Jeanty, P.W., D. Warren, and F. Hitzhusen. 2004. Assessing Ohio’s biomass resources for energy potential using GIS. OSU Dept of Ag, Env., and Development Economics, for Ohio Dept of Development. http://www.puc.state.oh.us/emplibrary/files/media/biomass/bioenergyresourceassessment.pdf Klass, Donald L. 1998. Biomass for Renewable Energy, Fuels, and Chemicals. Academic Press. ISBN: 9780124109506. Perlack et al. 2005. Biomass as feedstock for a bioenergy and bioproducts industry: The technical feasibility of a billion-ton annual supply. USDOE-USDA. http://www.puc.state.oh.us/emplibrary/files/media/biomass/BiomassFeedstock.pdf Rabaey, K., Verstraete, W. 2005. Microbial fuel cells: Novel biotechnology for energy generation. Trends. Biotechnol. 23:291-298. Rismani-Yazdi, H., Christy, A. D., Dehority, B.A., Morrison, M., Yu, Z. and Tuovinen, O. H. 2007. Electricity generation from cellulose by rumen microorganisms in microbial fuel cells. Biotechnol. Bioeng. 97, 1398-1407. Skrinak, N. 2007. OSU Microbial Fuel Cell Learning Center <http://digitalunion.osu.edu/r2/summer07/nskrinak/index.html> USDOE Biomass Program. ABCs of Biofuels <http://www1.eere.energy.gov/biomass/abcs_biofuels.html>. Accessed April 2008.
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