Reaction in a Bag An exothermic reaction occurs when the energy used to break the bonds in the reactants (the starting stuff) is less than the energy released when new bonds are made in the products (the stuff you end up with). This extra energy is given off as heat and there is a temperature rise around the surroundings of the reaction. Combustion is an example of an exothermic reaction- you can feel the heat given off if you get too close! The reactants have more energy than the end products. It also indicates that the enthalpy change is negative as heat is lost to the surroundings resulting in a temperature increase. Investigation 1 What might happen if you put calcium chloride, baking soda, and water in a zip bag? CaCl2 + 2NaHCO3 + H2O CaCO3 + 2NaCl + 2H2O + CO2 Reactants Products Procedure 1. Person 1, at the table measure one level spoonful of calcium chloride and one level spoonful of baking soda into the zip bag on one side and seal that side of the baggie. 2. Person 2, measure 50mL of water in the graduated cylinder. 3. Person 3, use your finger to dent in the middle of the baggie so that the calcium chloride and baking soda mixture are on one side. 4. Person 4, slowly pour the water in the baggie on the opposite side trying to keep it separate from the CaCl2 and NaHCO3. 5. Person 1, immediately zip the bag closed. 6. All students observe as the group members take turns holding and gently shaking the bag. Observe what happens and answer the questions below. Questions 1. What are the reactants in this investigation? 2. What are the products in this investigation? 3. Is matter conserved in this reaction? 4. Was this reaction a physical or chemical reaction? Explain how you know. 5. Was this reaction an endothermic or exothermic reaction? Explain how you know. 6. What did you find out by doing the reaction in the bag that you couldn’t find out if the reaction occurred in a cup? Reaction in a Bag An endothermic reaction occurs when the energy used to break the bonds in the reactants is greater than the energy given out when bonds are formed in the products. This means that overall the reaction takes in energy, therefore there is a temperature decrease in the surroundings. Electrolysis is an example of an endothermic reaction but you can create one easily in the kitchen just by dissolving salt or sugar in water. If you use cold water and lots of salt you can even make ice-cream. Similarly, this endothermic chart shows that the reactants start off with less energy this time and the end products have absorbed energy. Clearly shown in the diagram, enthalpy change of the reaction is positive because energy is being taken in from the surroundings which results in a temperature decrease. Investigation 2 What might happen if you put citric acid, baking soda, and water in a zip bag? C6H8O7 + 3NaHCO3 + H2O Na3C6H5O7 + 4H2O + 3CO2 Reactants Products Procedure 1. Person 1, at the table measure one level spoonful of citric acid and one level spoonful of baking soda into the zip bag on one side and seal that side of the baggie. 2. Person 2, measure 50mL of water in the graduated cylinder. 3. Person 3, use your finger to dent in the middle of the baggie so that the citric acid and baking soda mixture are on one side. 4. Person 4, slowly pour the water in the baggie on the opposite side trying to keep it separate from the C6H8O7 and NaHCO3. 5. Person 1, immediately zip the bag closed. 6. All students observe as the group members take turns holding and gently shaking the bag. Observe what happens and answer the questions below. Questions 1. What are the reactants in this investigation? 2. What are the products in this investigation? 3. Is matter conserved in this reaction? 4. Was this reaction a physical or chemical reaction? Explain how you know. 5. Was this reaction an endothermic or exothermic reaction? Explain how you know. 6. What did you find out by doing the reaction in the bag that you couldn’t find out if the reaction occurred in a cup?
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