Journal of Environmental Management 119 (2013) 36e46 Contents lists available at SciVerse ScienceDirect Journal of Environmental Management journal homepage: www.elsevier.com/locate/jenvman Selection of remedial alternatives for mine sites: A multicriteria decision analysis approach Getnet D. Betrie a, *, Rehan Sadiq a, Kevin A. Morin b, Solomon Tesfamariam a a b School of Engineering, University of British Columbia, Kelowna, BC, Canada Minesite Drainage Assessment Group, Vancouver, BC, Canada a r t i c l e i n f o a b s t r a c t Article history: Received 9 August 2012 Received in revised form 21 January 2013 Accepted 27 January 2013 Available online The selection of remedial alternatives for mine sites is a complex task because it involves multiple criteria and often with conflicting objectives. However, an existing framework used to select remedial alternatives lacks multicriteria decision analysis (MCDA) aids and does not consider uncertainty in the selection of alternatives. The objective of this paper is to improve the existing framework by introducing deterministic and probabilistic MCDA methods. The Preference Ranking Organization Method for Enrichment Evaluation (PROMETHEE) methods have been implemented in this study. The MCDA analysis involves processing inputs to the PROMETHEE methods that are identifying the alternatives, defining the criteria, defining the criteria weights using analytical hierarchical process (AHP), defining the probability distribution of criteria weights, and conducting Monte Carlo Simulation (MCS); running the PROMETHEE methods using these inputs; and conducting a sensitivity analysis. A case study was presented to demonstrate the improved framework at a mine site. The results showed that the improved framework provides a reliable way of selecting remedial alternatives as well as quantifying the impact of different criteria on selecting alternatives. 2013 Elsevier Ltd. All rights reserved. Keywords: Multicriteria decision analysis PROMETHEE Probabilistic PROMETHEE Remedial alternatives Mine sites 1. Introduction Acid Rock Drainage (ARD) from mine wastes that contains elevated metals and metalloids poses human and environmental risks (Gray, 1996; Azapagic, 2004). ARD is produced when sulfidebearing material is exposed to oxygen and water during mining activities (Morin and Hutt, 1997; Price, 2009). Examples of human health risks include increased chronic diseases and various types of cancer. On the other hand, examples of ecological risks range from the elimination of species to a significant reduction of ecological stability, and to the bioaccumulation of metals in the flora and fauna (Gray, 1996). In the eastern and western U.S., between 7000 and 16,000 km of streams are affected by acid generating waste rocks and between 8000 and 16,000 by ARD (USEPA, 1994). In Canada, an estimated 351 million tonnes of waste rock, 510 million tonnes of sulfide tailings, and more than 55 million tonnes of other mining sources have the potential to cause ARD (Minewatch, 2006). Liability costs of potentially acid-generating wastes at mining sites are estimated to be US$ 530 million in Australia, between US$ 1.2 and 20.6 billion in USA, and between US$ 1.3 and 3.3 billion in * Corresponding author. Tel.: þ1 250 807 9013; fax: þ1 250 807 9850. E-mail addresses: [email protected], [email protected] (G.D. Betrie). 0301-4797/$ e see front matter 2013 Elsevier Ltd. All rights reserved. http://dx.doi.org/10.1016/j.jenvman.2013.01.024 Canada (USEPA, 2006). Therefore, it is important to use remedial technologies to control the impacts of ARD caused by the considerable amounts mine waste rocks. ARD remedial technologies are categorized into source control and water treatment technologies (USEPA, 2006). The source control technologies chemically stabilize reactive rocks, or physically isolate waste rocks from water or oxygen, while water treatment technologies reduce contaminants in mine waters. However, selecting the optimal technology for a mine site is quite complex (USEPA, 2006). This is because most environmental decisionmaking (i.e., the selection process) involves multiple and conflicting objectives (e.g., minimizing risk and cost, maximizing benefit, and maximizing stakeholder preferences) (Kiker et al., 2005; Sadiq and Tesfamariam, 2009). Moreover, input information for each objective is often obtained in different forms (i.e., quantitative and qualitative), which are non-commensurable and thus exacerbate the decision making process (Tesfamariam and Sadiq, 2008). It is worth noting that there is a move away from decision-making based on single objective (e.g., cost or technical feasibility) toward selecting a sustainable remediation technology by considering multiple objectives such as environmental, economical and social objectives. A framework for selecting remedial alternatives at mine sites, which is recommended by USEPA (1988), is shown in Fig. 1. This G.D. Betrie et al. / Journal of Environmental Management 119 (2013) 36e46 framework consists of series of steps: scoping, site characterization, treatability investigations, development and screening of alternatives, detailed analysis of alternatives, and selection of optimum alternative. The scoping step consists of collecting existing data, identifying the boundary of a study area, identifying the remedial action objectives, assembling a “technical advisory committee,” and preparing the project plan. The site characterization step involves conducting field investigation, defining the nature and extent of the contamination, identifying regulatory standards and requirements, and conducting a baseline risk assessment. If there is no adequate data to evaluate technologies, the treatability investigation step is followed, where the evaluation of bench or pilot-scale technologies is performed. In the next step, Development and Screening of Alternatives, potential technologies are identified and screened. These, technologies are then assembled into potential alternatives and screened. Next, in the Detailed Analysis of Alternatives, the developed alternatives are analyzed against established criteria, and then, using the results of this analysis, compared with each other. In the final step, Select Optimum Alternative, the optimum alternative is selected based on information obtained from the 37 detailed analysis of alternatives. In this framework, experts conduct remedial selection analysis without multiple criteria decision analysis (MCDA) aids. However, the literature shows that humans are not capable of solving multiple objectives unaided. When they attempt to do so, opposing views are often discarded (McDaniels et al., 1999). MCDA methods deal with a problem whose alternatives are predefined and decision-makers rank available alternatives based on the evaluation of multiple criteria (Tesfamariam and Sadiq, 2006; Sadiq and Tesfamariam, 2009). There are many MCDA methods, most of which consist of four steps e (i) structuring the decision problem, (ii) articulating and modeling preferences, (iii) aggregating the alternative evaluations (preferences); and (iv) making recommendations (Guitouni and Martel, 1998). The main differences between these methods lie in the type of algorithm used to aggregate alternative evaluations, the types of input data required, and their final results (i.e., a single alternative vs. rank of alternatives). The literature classifies the MCDA methods into elementary, utility theory, and outranking (Belton and Stewart, 2002; Figueria et al., 2005). The elementary methods identify a non- Fig. 1. The USEPA (1988) framework for selecting remedial alternatives at mine sites. 38 G.D. Betrie et al. / Journal of Environmental Management 119 (2013) 36e46 dominated alternative based on the performance of alternatives in at least one criterion. These methods are suitable for reducing the number of alternatives into potential alternatives; however, they are not suitable for environmental problems that involve many alternatives and criteria (Kiker et al., 2005). Examples of elementary methods include maxmin, conjunctive and other methods. Utility theory methods use a utility/value function for each criterion to evaluate alternatives and to aggregate the utility/value of each criterion in order to identify the best alternative (Keeney and Raiffa, 1993). Examples of these methods include MAU/VT (multiattribute utility/value theory), AHP (analytical hierarchy process), and other methods. The outranking methods build an outranking relation (i.e., a binary relation that is used to evaluate the performance of the outranking character of one alternative over another alternative), and then exploit this relation to identify the best alternative, sort alternatives into groups, or rank them (Belton and Stewart, 2002). Examples of outranking methods include ELECTRE (elimination et choix traduisant la realite), PROMETHEE (preference ranking organization method for enrichment of evaluations), and other methods. Guitouni and Martel (1998) presented a comprehensive review of MCDA methods and their description. A comprehensive literature review of MCDA applications in the environmental decision making was conducted by Kiker et al. (2005) and Huang et al. (2011). Recently, Yang et al. (2012) has developed a simulation-based fuzzy multicriteria decision analysis to select remedial alternatives for a benzene-contaminated site. Uncertainty is an unavoidable and inevitable component of any environmental decision making process (Sadiq and Tesfamariam, 2009). MCDA methods require input data such as weights of criteria and preference of alternatives with respect to each criterion provided by decision makers. However, these data have uncertainty because of decision makers’ judgment and subjectivity. Before informed decisions can be made, this uncertainty must be quantified, through the application of available techniques. The objective of this paper is to improve the existing framework used for selecting remedial alternatives by introducing deterministic and probabilistic MCDA methods. Although there are many MCDA methods, as previously discussed, the PROMETHEE methods are implemented in this study. The PROMETHEE methods are implemented for two reasons (i) they are easy to apply compared to other outranking methods such as ELECTRE since PROMETHEE methods require fewer parameters from decision makers; and (ii) they rank alternatives as well as identify the best alternative, where as the utility theory methods only identify the best alternatives. The remainder of this paper is organized as follows. In the next section, the proposed framework and methods that are used to implement the MCDA framework are discussed. Then a case study is presented to demonstrate the proposed framework at a mine site. Finally, the results and conclusion of this study are discussed. 2. Proposed framework The proposed framework for selecting remedial alternatives is shown in Fig. 2. This framework improves the existing one by introducing deterministic and probabilistic multicriteria decision analysis methods instead of “Detailed Analysis of Alternatives” block shown in Fig. 1. Moreover, the proposed framework introduces “Result Analysis” block. The deterministic multicriteria block consists of identifying criteria to evaluate alternatives, identifying the weight of criteria using AHP, and applying the PROMETHEE I and II methods. The probabilistic multicriteria decision analysis block consists of identifying criteria to evaluate alternatives, defining the weight of criteria by using AHP, defining probability distribution for the weight of criteria, conducting Monte Carlo Simulation, applying PROMETHEE II, and conducting a sensitivity analysis. In the subsection below, the elements of the deterministic MCDA and the probabilistic MCDA blocks are presented. Since the probabilistic MCDA block contains the first two elements of the deterministic block, the elements of the probabilistic MCDA block beginning from “defining the probability distribution criteria weight” are discussed. Finally, the analysis block is discussed. 2.1. Deterministic multicriteria decision analysis 2.1.1. Preference Ranking Organization Method for Enrichment Evaluation (PROMETHEE) The PROMETHEE I and II methods are multicriteria decision making techniques developed by J. P. Brans (Brans et al., 1986). These methods build a valued outranking relation and exploit this relation to obtain a partial ranking (PROMETHEE I) or complete ranking (PROMETHEE II). When A of n alternatives (i.e., a1, a2, ., an) have to be ranked, and G of k criteria (i.e., g1, g2, ., gk) have to be maximized or minimized (shown in Fig. 3), the resulting multicriteria problem has the following form as shown in Eq. (1) (Brans et al., 1986): maxfg1 ðaÞ; g2 ðaÞ; .; gk ðaÞja˛Ag (1) The basic steps of PROMETHEE methods to solve such multicriteria problem are (Brans et al., 1986): (i) Defining a preference function for each criterion, (ii) Calculating the multicriteria preference index as a weighted average of the preference functions, (iii) Calculating a leaving flow, an entering flow, and a net flow for each alternative, and (iv) Assigning a partial or complete ranking. A preference function ðPj ða; bÞða; bÞ˛AÞ associated with criterion gi gives the degree of preference, expressed by decision-makers, for alternative a over b. In other words, the preference function takes the deviation of the preference a over b as an input and provides a normalized output as shown by Eqs. (2) and (3), respectively. Pj ða; bÞ ¼ Pj ½gi ðaÞ gi ðbÞ (2) 0 Pj ða; bÞ 1 (3) If Pj ða; bÞ ¼ 0, there is no preference a over b and if Pj ða; bÞ ¼ 1, there is a strict preference of a over b. Brans and Mareschal (2005) have provided six types of preference functions as displayed in Table 1. If a weight wj is given, which shows the relative importance of each criterion, and can be used to calculate the multicriteria preference index as defined by Eq. (4): pða; bÞ ¼ k X wj Pi ða; bÞ (4) i¼1 The leaving (outgoing) flow that shows how an alternative ai is outranking other alternatives is defined by the equation below: fþ ðaÞ ¼ X pða; xÞ (5) x˛K The incoming (leaving) flow that shows how an alternative ai is outranked by other alternatives is defined by the following equation: G.D. Betrie et al. / Journal of Environmental Management 119 (2013) 36e46 39 Fig. 2. Proposed framework for selecting remedial alternatives at mine sites. f ðaÞ ¼ X pðx; aÞ (6) x˛K PROMETHEE I is used to derive a partial ranking which is obtained by comparing the leaving and incoming flows, as defined by Eq. (7): 8 8 > > < fþ ðaÞ > fþ ðbÞ and f ðaÞ < f ðbÞ;or > > > I b iff > ap fþ ðaÞ ¼ fþ ðbÞ and f ðaÞ < f ðbÞ;or > > > > : fþ ðaÞ > fþ ðbÞ and f ðaÞ ¼ f ðbÞ; < þ > aI I b iff f( ðaÞ ¼ fþ ðbÞ and f ðaÞ ¼ f ðbÞ > > > > > fþ ðaÞ > fþ ðbÞ and f ðaÞ > f ðbÞ;or > I > : aR b iff fþ ðaÞ < fþ ðbÞ and fþ ðaÞ < fþ ðbÞ; (7) where PI, II and RI represent preference, indifference, and incomparability, respectively. PROMETHEE II is used to derive a complete ranking which is calculated as a net flow between outgoing and incoming flows, as shown in Eq. (8). If the net flow of a is greater than b, a outranks b. Otherwise, a is indifferent to b. fðaÞ ¼ fþ ðaÞ f ðaÞ (8) 2.1.2. Analytical hierarchy process (AHP) AHP is one of the MCDA methods that assists decision makers in solving complex problems by organizing thought, experiences, knowledge, and judgments into a hierarchical framework, and by guiding them through a sequence of pairwise comparison judgments (Saaty, 1982). In general, it derives the ratio scale from a pairwise comparison. In this study, AHP is used only to generate weight. The process of generating weight using AHP consists of the following steps (Saaty, 1982): (i) Identify the criteria to generate weights, 40 G.D. Betrie et al. / Journal of Environmental Management 119 (2013) 36e46 values should be modified until the CR value is within an acceptable range. 2.2. Probabilistic multicriteria decision analysis 2.2.1. Define probability distribution for criteria weight The criteria weights are generated using the AHP technique from preference information provided by actors involved in the decision process. The definition of probability distribution for criteria weight solely depends on the number of actors who are participating in the decision process. If an adequate number of actors participated in the decision process, the obtained information on preference is fitted to a probability distribution function using available techniques or software. In a situation where there are no adequate actors participating in the decision process, the type of probability distribution that is recommended is uniform distribution (Rietveld and Ouwersloot, 1992). Fig. 3. Evaluation matrix. (ii) Make a pairwise comparison for each criterion on a scale of 1e 9. Note that the relative preference of one criterion over another is obtained from decision makers, (iii) Compute Eigen values and vectors to obtain a normalized weight for each criterion, and (iv) Compute the consistency ratio (CR). If the CR is more than 10%, then the results are inconsistent. Thus, the assigned weight Table 1 Types of preference function (Brans and Mareschal, 2005). Preference function Type I: Usual Criterion Definition P 1 PðdÞ ¼ P 1 PðdÞ ¼ 0 Type III: V-shape Criterion d0 d>0 0; 1; dq d>q d q 8 0; > > > > <d ; PðdÞ ¼ >p > > > : 1; P 1 d p 0 Type IV: Level Criterion 0; 1; 8 0; > > > < 1 PðdÞ ¼ ; > 2 > > : 1; P 1 0.5 0 q p Type V: P V-Shape 1 with indifference Criterion 0 q p d d Type VI: P Gaussian 1 Criterion ( d d0 0dp P 6 ni¼ 1 d2i n n2 1 r ¼ 1 (9) d>p where di is the difference between the rank of values of alternatives and weights of criteria, and n is the total number of MCS realizations. dq q<dp d>p 8 0 > > > > <d q PðdÞ ¼ ; > pq > > > : 1 PðdÞ ¼ 0 2.2.3. Sensitivity analysis Sensitivity analysis is used to identify the contribution of each criterion in the overall ranking of alternatives. A sensitivity analysis is often carried out using MCS and a rank correlation method is applied to the results of MCS in order to identify the contribution of parameters (i.e., criteria) to the output (Tesfamariam et al., 2006). The latter method involves the determination of correlation coefficients that measure the strength of the linear relationship of two variables. In this study, the Spearman rank correlation coefficient (see Eq. (9)), which measures the linear relationship of two ranked variables, was used. d 0 Type II: U-shape Criterion 2.2.2. Conduct Monte Carlo Simulation Monte Carlo Simulation (MCS) is used to propagate uncertainties in random variables. In this technique, the weight of the criterion is represented by a probability density function that defines both the range of values which the weight can take and the likelihood that the weight has a value in any subinterval of that range (Aral, 2010). A random sampling is used to select the weight of each criterion set at different probability levels, and repeated several times. For each combination of sampled weights, the PROMETHEE II method is run. The MCS runs until sufficient sample values have been collected to approximate the input parameter distribution. dq q<dp d>p d0 0; 1e 2 d2 2s ; 2.3. Results analysis In the result analysis block, the deterministic alternative rankings and probabilistic alternative rankings are analyzed. The deterministic alternative rankings are obtained from partial and complete rankings of PROMETHEE methods. The probabilistic alternative rankings are obtained from a complete ranking of the PROMETHEE II method. These results provide probability distributions for the ranking of alternatives. In addition, the results provide the probability of given alternatives belonging to various ranks. 3. Case study d>0 In this section, the proposed framework was implemented for Mine Site B, located in British Columbia, Canada. G.D. Betrie et al. / Journal of Environmental Management 119 (2013) 36e46 3.1. Site characterization Site characterization information was obtained from the closure plan report of the mine site. The remediation objective at this mine site is to reduce environmental risk. The conceptual model for the risk assessment is shown in Fig. 4. It shows the sources of contaminants, release mechanisms, media, exposure routes, and receptors. According to the mine’s closure plan report, the chemical of concern (COC) is elevated copper concentrations from reactive waste rocks and tailings. The water quality prediction obtained using data from kinetic tests, heap leach tests, and historical water quality analysis indicates a maximum of 8 mg/l during neutral pH periods when neutralization potential was being consumed. The possible release mechanisms are leaching and erosion. The media that could be contaminated are surface water and soil. The two potential exposure routes that are considered at this site are ingestion and contact. The major ecological entity that should be protected is fish. Thus, the maximum allowable discharge criterion of Cu concentration was 0.003 mg/l CCME (1999). The fate and transport of metals in the environment are determined using an aquivalence-based model. The aquivalence/fugacity approach was developed by Mackay (1991) for the estimation of chemical distributions in multimedia based on the complexity of transport and transformation processes. The aquivalence/fugacitybased model is widely applied to predict the fate and transport of toxic substances in the environment. This model describes the fate of chemicals in any well-mixed water body for which the hydraulic and particle flows are defined. Mackay and his co-workers (Mackay et al., 1983 and Mackay and Diamond, 1989) applied a fugacity/ aquivalence-based model to rivers and lakes (e.g., Lake Ontario and Hamilton Harbor) to study the distribution of detergent chemicals, Polychloro-biphenyls and heavy metals. A steady state aquivalence-based model developed for this mine site by Betrie et al. (2012) was used in this case study to predict the fate and transport of copper in soil and water media. The mine system consists of tailings and waste rocks, a soil layer, and an aquifer as shown in Fig. 5. The tailings and waste rocks are sources of copper metal emissions. Intermedia transport, water-to-soil, and soil-to-water mass flow through diffusion and advection were considered. A conceptual model showing different mechanisms of transport and transformation in two compartments is shown in 41 Fig. 5. The intermedia D values are contaminant transfer from water-to-soil (DWS) and soil-to-water (DSW). The advection in soil (DAS) and groundwater (DAW) values in soil and water compartments were calculated based on flow rates. In this case study, a baseline risk assessment was done following ecological risk assessment guidance for superfund sites (USEPA, 1997). The ecological risk was estimated using the Hazard Quotient (HQ) approach. The HQ is a ratio that can be used to estimate if harmful effects, due to the contaminant in question, are likely (USEPA, 1997). The HQ is calculated using the equation below: HQ ¼ EEC Screening Benchmark (10) where EEC is the estimated (maximum) environmental contaminant concentration at the site (i.e., contaminant concentration in the soil, sediment, or water). The screening benchmark is generally a No-Adverse Effects Level concentration. Note that for a calculated value of HQ > 1, harmful effects cannot be ruled out; if HQ ¼ 1, contaminant alone is not likely to cause ecological risk; and if HQ < 1, harmful effects are not likely (USEPA, 1997). 3.2. Development and screening of alternatives Table 2 shows the alternatives that were considered in this study and their effectiveness to reduce contaminants. The literature review (e.g., Skousen et al., 1998; Skousen et al., 2000; USEPA, 2000; Johnson and Hallberg, 2005; USEPA, 2006) shows various remedial alternatives. These alternatives reduce exposure of reactive wastes to oxygen and water, or reduce the amount of contaminants so that any adverse effects on humans and the environment are eliminated. The potential effectiveness (in percent) of the alternatives to reduce acid generation is shown in Table 2. These values are obtained from the literature as presented in this table. Note that in this step, Development and Screening of Alternatives, potential technologies should have been identified, screened, and then assembled into alternatives as shown in Fig. 2. In this case study, however, this was not done; instead, a single technology was considered as an alternative in order to make the illustration of proposed framework simple. Fig. 4. Conceptual model for risk assessment. 42 G.D. Betrie et al. / Journal of Environmental Management 119 (2013) 36e46 Table 3 Criteria and scoring scale. Fig. 5. Schematic representation of the mine site. 3.3. Deterministic MCDA Criteria to evaluate the alternatives were identified by an expert from the mine site and the authors in order to ensure that the proposed remedial objectives are achieved. These criteria are presented below: Minimize risk posed to fish, Minimize the cost of an alternative, Maximize the short-term performance of an alternative, Maximize the long-term performance of an alternative, Maximize the implementability of an alternative, Maximize the reduction of toxicity, mobility, or volume of wastes, and Maximize the future use and aesthetic of the mine site. Table 3 shows these criteria and their respective scoring scale. Each criterion except risk was rated by experts on a scale of 1e9, as shown in Table 3. An alternative that has low cost rated as 9 and the high cost rated as 1. For short-term performance, an alternative that has immediate effect after implementation is rated as 9 and an alternative that would take a longer time to be effective is rated as 1. For long-term performance, an alternative that is effective for longer durations (e.g., over 20 years) is rated as 9; otherwise, it is rated close to 1. If an alternative is easy to implement, it is rated as 9; otherwise, it is rated at a lesser value. An alternative that has an excellent effect on the reduction, mobility, and transport of contaminants is rated as 9; otherwise, it is rated at a lesser value. An alternative that would increase future use and aesthetic of the site is rated as 9. Table 4 presents the score of the alternatives with respect to each criterion. This table shows that the cost associated with Donothing (DN) is the lowest (1), Soil cover (SC) is high (6), and Table 2 Alternatives considered and their effectiveness to reduce contaminants. Alternatives Effectiveness (%) Sources Do-nothing (DN) Soil cover (SC) Membrane system (MC) Water cover (WC) 0 33 70 99 Excavation and on-site disposal (EON) Excavation and off-site disposal (EOF) Water treatment (WT) Constructed wetland (CW) 99 e MEND, 1999a Meek, 1994 Vigneault et al., 2007; Yanful and Simms, 1997 USEPA, 1995 99 USEPA, 1995 90 30 USEPA, 2000 MEND, 1999b; Skousen et al., 1998 USEPA, 2006 Sulfate reducing bacteria (SB) 80 Criteria Score Risk Cost Short-term performance (SP) Long-term performance (LP) Implementability (IM) Reduction of toxicity (RT) Future use and aesthetic (FU) HQ 1 (Low) to 9 (Extremely high) 1 (Poor) to 9 (Excellent) 1 (Poor) to 9 (Excellent) 1 (impossible) to 9 (absolutely possible) 1 (Poor) to 9 (Excellent) 1 (Poor) to 9 (Excellent) Excavation and off-site disposal (EOF) is the highest (9). The shortterm performance of DN is poor (1) but the Water cover (WC) alternative has an excellent (9) short-term performance. The longterm performance of DN is poor (1) but the Excavation and on-site disposal (EON) and EOF alternatives have an excellent (9) long-term performance. The Membrane system (MC) alternative is difficult (2) to implement, while the DN and Sulfate reducing bacteria (SB) alternatives are the easiest (9) to implement. The DN alternative is the least effective (1) but EOF is most effective (9) in reducing toxicity. The DN and SB alternatives have the least impact (1) on improving the future use of this site, while EOF and EON have the most impact on improving the future of this site. The Hazard Quotient (HQ) value of the DN alternative was calculated using the EEC value obtained from the aquivalence model output and the screening benchmark value. The aquivalence model results showed that the EEC of water and soil was equal to 0.75 mg/l and 0 mg/l of copper, respectively. The screening benchmark value for water, which is equal to 0.003 mg/l, was obtained from CCME (1999). Note that the HQ value was calculated only for water medium since concentrations of copper in the soil were equal to zero. For the alternatives other than DN, the EEC value was adjusted by the effectiveness factor (i.e., EECadjusted ¼ EEC EEC*Effectivenes ½%) when calculating the HQ value of alternatives. In addition, the scoring shown in Table 3 is highly site specific and may not necessarily apply to other mine sites. Table 5 presents a comparison matrix of the criteria. The comparison matrix shows the relative importance of one criterion against another and reflects the preference of actors who participated in the decision making process. A pairwise comparison was done on a scale of 1e9. For instance, a decision-maker strongly prefers (9) the Risk criterion compared to the Future use and aesthetic (FU) criterion. The preference of FU over Risk (i.e., 0.11) was obtained by taking the reciprocal preference value of Risk over FU. The normalized weights of the criteria were obtained by computing eigenvectors of the matrix. The remainder values of the matrix can be explained in a similar fashion. The input information for multicriteria methods (e.g., PROMETHEE) should be provided as an evaluation table as shown in Table 6. This evaluation table consists of criteria; whether the Table 4 Alternatives and their respective score at each criterion. Criteriaa DN SC MC WC EON EOF WT CW SB Risk Cost SP LP IM RT FU 260 1 1 1 9 1 1 174 6 2 5 5 4 4 78 9 2 7 2 4 6 13 3 9 8 8 6 5 2.6 8 6 9 7 8 8 0 9 8 9 7 9 9 26 8 9 6 5 8 2 182 3 4 7 8 3 7 52 3 7 4 9 5 1 a Do-nothing (DN), Soil cover (SC), Membrane system (MC), Water cover (WC), Excavation and on-site disposal (EON), Excavation and off-site disposal (EOF), Water treatment (WT), Constructed wetland (CW), Sulfate reducing bacteria (SB), Shortterm performance (SP), Long-term performance (LP), Implementability (IM), Reduction of toxicity (RT), Future use and aesthetic (FU). G.D. Betrie et al. / Journal of Environmental Management 119 (2013) 36e46 computed by evaluating the preference of one alternative over another, using the preference function of each criterion. Next, the obtained value was multiplied by the weight of each criterion and summed. A preference index indicates the preference of an alternative over another. For instance, Do-nothing (DN) is preferred over Soil cover (SC) by 0.13, while SC is preferred over DN by 0.248. A higher preference value indicates a stronger preference for that alternative. The computed outgoing ðfþ Þ, incoming ðf Þ, and net ðfNET Þ flows for the deterministic PROMETHEE analysis are shown in the bottom of Table 7. The outgoing flow of an alternative was obtained by summing the preference indexes in that row. For example, the incoming flow of DN (0.967) was obtained by summing the preference indexes in the first row. On the other hand, the incoming flow of an alternative was obtained by summing the preference indexes in that column. For example, the incoming flow of DN (4.095) was obtained by summing the preference indexes of in the first column. The incoming and outgoing flows provide an indication of whether an alternative outranks, or is outranked, by other alternatives, respectively. If an alternative is characterized by a greater incoming flow and a smaller outgoing flow, the better this alternative dominates other alternatives. These values were used for partially ranking the alternatives. The net flow was obtained as a net difference between the incoming and the outgoing flows and it indicates whether an alternative globally outranks other alternatives. The higher the net flow of an alternative, the more this alternative dominates other alternatives. The net flow is used to completely rank the alternatives. The deterministic partial ranking (PROMETHEE I) of the alternatives is shown below: Table 5 Comparison matrix of criteria. a Risk Cost LP SP IM RT FU Risk Cost LP SP IM RT FU 1 0.14 0.25 0.17 0.13 0.33 0.11 7 1 0.2 0.14 0.12 0.17 0.33 4 5 1 0.11 0.11 0.33 0.2 6 7 9 1 3 6 5 8 8 9 0.33 1 0.33 0.33 3 6 3 0.17 3 1 0.11 9 3 5 0.2 3 9 1 43 a Long-term performance (LP), Short-term performance (SP), Implementability (IM), Reduction of toxicity (RT), Future use and aesthetic (FU). criteria have to be minimized (Min) or maximized (Max); criteria weight that shows relative importance one criterion over other criteria; the alternatives’ evaluation outcome with respect to each criterion; preference function that gives the degree of preference of an alternative against another alternative; and preference parameter value that has to be fixed. The criteria weights were obtained from the AHP computation. The obtained results of AHP show that Risk is the most prioritized (i.e., 0.41) criterion followed by Cost, Long-term performance (LP), Reduction of toxicity (RT), Implementability (IM), Future use and aesthetic (FU), and Short-term performance (SP). Type III (i.e., V-shape) preference function was selected for all criteria. This preference type was selected because it best represents the data compared to other preference functions. The parameter value of type III function that was assumed for the Risk criterion was equal to 230 and for the other criteria was equal to 8.8. 3.4. Probabilistic MCDA WCPI DN; WCPI SC; WCPI MC; WCPI EON; WCPI EOF; WCPI WT; WCPI CW; WCPI SB; A uniform probability distribution function was defined for the weights of criteria. Inputs to this distribution were defined by multiplying the original weight of each criterion by 10%. Each probability distribution was randomly sampled 5000 times using the MCS technique. For each combination of randomly sampled weight, the MCDA method (PROMETHEE II) was run. The results of criteria weights and PROMETHEE II outputs obtained from 5000 MCS run were ranked and then correlation coefficients were estimated using the Spearman rank correlation method. The estimated correlation coefficients of each alternative and criterion were normalized and multiplied by 100 to obtain the contribution (in percent) of the criteria on overall ranking of the alternatives. SBPI DN; SBPI SC; SBPI MC; SBPI EON; SBPI WT; SBPI CW; EOFPI DN; EOFPI SC; EOFPI MC; EOFPI WT; EOFPI CW; EONPI DN; EONPI SC; EONPI MC; EONPI CW; WTPI DN; WTPI SC; WTPI MC; WTPI CW; CWPI DN; CWPI SC; CWPI MC; and MCPI DN; MCPI SC; The Water cover (WC) alternative dominates all the alternatives. The Sulfate reducing bacteria (SB) alternative dominates all the alternatives except WC and Excavation and off-site disposal (EOF); the SB alternative is dominated by WC and is incomparable with EOF. The EOF alternative dominates the Do-nothing (DN), Soil cover (SC), Membrane cover (MC), Water treatment (WT) and Constructed wetland (CW) alternatives, is dominated by WC alternative, and is incomparable with the SB and Excavation and on-site 4. Results and discussion Table 7 presents the computed preference indexes of the deterministic PROMETHEE analysis. These preference indexes were Table 6 Evaluation table for deterministic PROMETHEE analysis. Criteriaa Min or max Criteria weight DN SC MC WC EON EOF WT CW SB Preference function Preference parameter Risk Cost SP LP IM RT FU Min Min Max Max Max Max Max 0.41 0.23 0.02 0.16 0.06 0.08 0.04 260 1 1 1 9 1 1 174 6 2 5 5 4 4 78 9 2 7 2 4 6 13 3 9 8 8 6 5 2.6 8 6 9 7 8 8 0 9 8 9 7 9 9 26 8 9 6 5 8 2 182 3 4 7 8 3 7 52 3 7 4 9 5 1 III III III III III III III 230 8.8 8.8 8.8 8.8 8.8 8.8 a Do-nothing (DN), Soil cover (SC), Membrane system (MC), Water cover (WC), Excavation and On-site disposal (EON), Excavation and Off-site disposal (EOF), Water Treatment (WT), Constructed Wetland (CW), Sulfate Reducing Bacteria (SB), Short-term performance (SP), Long-term performance (LP), Implementability (IM), Reduction of toxicity (RT), Future use and aesthetic (FU). 44 G.D. Betrie et al. / Journal of Environmental Management 119 (2013) 36e46 Table 7 Preference indexes, incoming, outgoing, and net flow for deterministic PROMETHEE analysis. a DN SC MC WC EON EOF WT CW SB DN SC MC WC EON EOF WT CW SB e 0.248 0.454 0.642 0.628 0.678 0.662 0.259 0.523 0.967 4.095 3.128 0.13 e 0.206 0.523 0.442 0.523 0.43 0.185 0.449 0.653 2.888 2.235 0.209 0.078 e 0.42 0.283 0.311 0.282 0.25 0.355 1.127 2.191 1.064 0.052 0.02 0.045 e 0.059 0.078 0.039 0.061 0.052 2.688 0.408 2.28 0.183 0.066 0.034 0.185 e 0.055 0.068 0.183 0.201 2.105 0.975 1.130 0.209 0.092 0.034 0.175 0.026 e 0.058 0.209 0.209 2.42 1.013 1.408 0.182 0.061 0.041 0.172 0.076 0.094 e 0.208 0.183 2.121 1.018 1.103 0 0.043 0.235 0.422 0.418 0.472 0.435 e 0.304 1.397 2.330 0.933 0 0.043 0.077 0.149 0.172 0.208 0.146 0.041 e 2.277 0.838 1.439 fþ f fNET a Do-nothing (DN), Soil cover (SC), Membrane system (MC), Water cover (WC), Excavation and on-site disposal (EON), Excavation and off-site disposal (EOF), Water treatment (WT), Constructed wetland (CW), Sulfate reducing bacteria (SB). disposal (EON) alternatives. The EON alternative dominates the DN, SC, MC and CW alternatives, is dominated by the WC and SB alternatives, and is incomparable with EOF and WT. The WT alternative dominates the DN, SC, and CW alternatives, is dominated by the WC, SB, and EOF alternatives, and is incomparable with the EON and MC alternatives. The CW alternative dominates the DN and SC alternatives, is incomparable with MC, and is dominated by the WC, SB, EOF, EON and WT alternatives. The DN and SC alternatives are incomparable. The alternatives are incomparable whenever they have conflicting relative rankings. Incomparability between the alternatives occurs if an alternative is superior according to some criteria and inferior according to other criteria compared to other alternatives. For instance, the incomparability of SB and EOF occurs because the EOF alternative performs better on the Risk, Long-term performance (LP), Reduction of toxicity (RT) and Future use and aesthetic (FU) criteria than does the SB alternative, whereas the SB alternative performs better on Cost and Implementability (IM) criteria. The deterministic complete ranking (PROMETHEE II) shows that WC ranked first followed by the SB, EOF, EON, WT, CW, MC, SC, and DN alternatives. It is interesting to note that WC and DN have the same rank in both partial and complete ranking methods. However, the incomparability information is lost in the complete ranking method which may affect decision-makers ability to make informed decision. The results of the probabilistic complete ranking of the alternatives are displayed in Table 8. This table shows the probability of an alternative obtaining a certain rank. The WC alternative obtains the first rank with a probability of 100%. The chances of the SB alternative ranking second and third are 70% and 30%, respectively, whereas the chances of the EOF alternative ranking second and third are 30% and 70%, respectively. The probability of the EON alternative obtaining fourth and fifth ranks is 67% and 33%, respectively, whereas the WT alternative has a probability of 33% and 67% of obtaining the fourth and fifth ranks, respectively. The chance of the CW alternative ranking sixth and seventh is 97% and 3%, respectively, whereas the MC alternative ranks similar to the CW alternative with the values of probability reversed. The SC and DN alternatives rank eighth and ninth with a probability of 100%. It is interesting to note that this method clearly showed the degree of conflict in relative ranking that led to incomparability in the deterministic partial ranking which is presented above. Fig. 6 shows the cumulative distribution functions of the net flow for the probabilistic PROMETHEE analysis. It shows a possible range of net flow for the alternatives. For example, the net flow of SB has a possible range of between 1.305 and 1.573, and the EOF alternative has a possible range of between 1.24 and 1.569. It is interesting to compare the probabilistic net flow values with the deterministic net flow results. The information obtained from the probabilistic analysis explains the reason for the conflicting relative ranking among alternatives (e.g., SB vs. EOF and EON vs. WT). This probabilistic output enables decision-makers to obtain net flow values at the required confidence levels and to rank the alternatives with a certain level of confidence. The contribution (in percent) of the criteria on ranking the alternatives is shown in Fig. 7. For instance, the three most sensitive criteria that impact the WC alternative are Risk, SP and Cost. Although SP has the least weight among the criteria, its effect is greater than the Cost criterion which is the second most highly weighted criterion. It is worth noting that the ranking of each alternative could be sensitive to different criteria as is seen in this figure. For instance, the SB alternative is sensitive to Cost followed by Risk, SP, FU, IM, and RT criteria, and the CW alternative is sensitive to Risk followed by Cost, RT, LP, SP, FU and IM criteria. Table 8 Probabilistic complete ranking of alternatives in percentage. Rank a 1 2 3 4 5 6 7 8 9 0 0 0 0 0 0 0 0 100 DN SC MC WC EON EOF WT CW SB 0 0 0 0 0 0 0 100 0 0 0 0 0 0 3 97 0 0 100 0 0 0 0 0 0 0 0 0 0 0 67 33 0 0 0 0 0 30 70 0 0 0 0 0 0 0 0 0 33 67 0 0 0 0 0 0 0 0 0 97 3 0 0 0 70 30 0 0 0 0 0 0 a Do-nothing (DN), Soil cover (SC), Membrane system (MC), Water cover (WC), Excavation and on-site disposal (EON), Excavation and off-site disposal (EOF), Water treatment (WT), Constructed wetland (CW), Sulfate reducing bacteria (SB). Fig. 6. Cumulative distribution function of net flow for probabilistic PROMETHEE analysis. G.D. Betrie et al. / Journal of Environmental Management 119 (2013) 36e46 45 makers will be able to leave insensitive criteria for further analysis in order to reduce the complexity of decision making. Meanwhile, they can collect more information on the most sensitive criteria in order to reduce the uncertainty associated with the criteria. The study also showed that the assigned weight of criteria has little effect on ranking the alternatives. However, a limitation of the improved framework is that it addresses the uncertainty associated with the weight of the criteria only. Future work should be done to address the uncertainty associated with input information. In its present form, this improved framework could be used by decisionmakers to select remediation alternatives for mine sites and to select alternatives for mine closures. Moreover, the improved framework could be used in other systems (e.g., contaminated sites) either in its present form or by making a little modification. In the latter case, the improved framework could be used in other systems that use multicriteria decision analysis by replacing the PROMETHEE method with the MCDA method in use to fit their systems. Fig. 7. Contribution (%) of criteria on ranking of alternatives. 5. Summary and conclusions In this paper, the existing framework used for selecting remediation alternatives at mine sites was investigated and improved. The major improvement of the framework includes an introduction of the deterministic and probabilistic multicriteria decision analysis (MCDA) methods. The multicriteria decision analysis consists of identifying criteria to evaluate alternatives, calculating criteria weight using analytical hierarchical process (AHP), defining the probability distribution of criteria weights, conducting Monte Carlo Simulation (MCS), applying Preference Ranking Organization Method for Enrichment Evaluation (PROMETHEE) I and II methods, conducting a sensitivity analysis, determining the deterministic and probabilistic rankings of alternatives, and identifying the sensitivity of the criteria. Finally, a case study was used to demonstrate the improved framework. The results of the deterministic PROMETHEE I analysis showed and ranked the comparable alternatives, and showed the incomparable alternatives. The deterministic PROMETHEE II results only showed rankings of the alternatives without incomparability information. For instance, the application of the deterministic PROMETHEE II method at Mine B showed that the WC (Water cover) alternative ranks first followed by Sulfate reducing bacteria (SB), Excavation and off-site disposal (EOF), Excavation and on-site disposal (EON), Water treatment (WT), Constructed wetland (CW), Membrane system (MC), Soil cover (SC) and Do-nothing (DN) alternatives. In both methods, the uncertainty in the ranking of the alternatives due to input information variation was not shown to decision-makers. On the other hand, the probabilistic PROMETHEE II results showed the probability level at which an alternative could yield certain rankings. For instance, the application of the probabilistic complete ranking at Mine B showed that WC ranked 1st with a probability level of 100%, SB and EOF ranked 2nd and 3rd with a probability level of 70%, EON and WT ranked 4th and 5th with a probability level of 67%, CW and MC ranked 6th and 7th with a probability level of 97%, and SC and DN ranked 8th and 9th with a probability level of 100%. Also, this method was used to rank the alternatives in the form of a cumulative distribution function that will help decision-makers rank alternatives with the required level of confidence. The sensitivity analysis showed the impact of the criteria on ranking the alternatives. For instance, the Risk and Future use and aesthetic (FU) criteria impacted the WC alternative by 44% and 2%, respectively. Based on the contribution of the criteria, decision Acknowledgments The financial support from Discovery Grant program of NSERC is highly appreciated. 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List of acronyms MCDA: multicriteria decision analysis PROMETHEE: Preference Ranking Organization Method for Enrichment Evaluation AHP: analytical hierarchical process MCS: Monte Carlo Simulation ARD: Acid Rock Drainage MAU/VT: multi-attribute utility/value theory ELECTRE: elimination et choix traduisant la realite ai: alternative i gi: criterion i COC: chemical of concern DWS: Diffusion from water-to-soil DSW: Diffusion from soil-to-water DAS: Advection in soil DAW: Advection groundwater HQ: Hazard Quotient EEC: Estimated (maximum) environmental contaminant concentration DN: Do-nothing SC: Soil cover MC: Membrane system WC: Water cover EON: Excavation and on-site disposal EOF: Excavation and off-site disposal WT: Water treatment CW: Constructed wetland SB: Sulfate reducing bacteria SP: Short-term performance LP: Long-term performance IM: Implementability RT: Reduction of toxicity FU: Future use and aesthetic Min: Minimized Max: Maximized
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