THE GALENA SPECIES – 6-SIDED CUBES GALENA – THE MARRIAGE OF LEAD ATOMS, (+) CHARGED, WITH (-) CHARGED SULFUR ATOMS, IN A 1 : 1 RATIO: This ratio proves that the metal lead atom has only one extra electron in its outer orbit that it wants to get rid of in order to complete its electrical neutrality, and likewise, each sulfur atom needs to receive only one electron to complete its - not quite full - outer orbit, and to satisfy its electrical neutrality. So, lead (Pb) and sulfur (S) must combine in a 1 : 1 ratio. SUL-GAL-1. GALENA CUBES – RARE SKELETAL CUBES ON QUARTZ – MADAN, BULGARIA: The mines near Madan city, Bulgaria produced the only good examples of skeletal Galena cubes the Proctors have seen. These skeletal cubes graphically demonstrate that the formation of cubed Galenas (as with octahedral Gold crystals) begins with the formation of only the skeletal cube corners and connecting edges as seen here with this remarkable cluster of skeletal Galena cubes growing into Quartz crystals. This cube skeleton forms first, and then the centers of the 6-cube faces form next and fill in last. If there is not enough Galena (lead and sulfur atoms) in solution, or some other geochemical condition is not right, then the six flat cube faces cannot complete, and we then see concave, so-called, hoppered crystals (as seen here). We must show this specimen before we view the other cube specimens of Galena so we can understand and get excited when we see hoppered crystals of Galena, Pyrite or Gold. Specimen measures 4” wide and 2.5” high. These crystals are pivotal to our understanding how cube and octahedral crystals form. -Lynn Sim photograph SUL-GAL-3. GALENA - CUBES WITH SMALL PRE-OCTAHEDRAL (TRIANGULAR) CORNERS SWEETWATER MINE, MISSOURI: Specimen measures 2” by 2”. -Joe Budd photograph SUL-GAL-2. GALENA – FOUR, HIGH TEMPERATURE FORMATION GALENA OCTAHEDRONS SITTING NEAR A BIGGER, LOW TEMPERATURE FORMATION CUBED GALENA CRYSTAL WHICH RARELY HAPPENS: Why? Sweetwater mine, Missouri. Specimen measures 3.75” high by 2” wide. -Joe Budd photograph 344 GALENA CUBES AND CUBO-OCTAHEDRONS SUL-GAL-4. GALENA - CUBES WITH TWISTED/CURVED/WAVY/SOFTENED CUBE FACES – MADAN, BULGARIA: Seen here is a magnificent and unique Madan, Bulgaria cubed Galena specimen (according to the miners … found very deep in a “hot” part of this mine). Looking closely we can see the eight cubes on the top of this specimen (where the biggest curved cube is visible) displaying twisted and bent cube faces – looking like they were created while in the process of hardening. The temperature conditions were so unique and intense this deep in this mine that during or after the early crystal formation stage, the cube faces could not keep a straight face. On the top right side of this specimen are four sharp cubes with small truncated (triangular), pre-octahedral cube corners, one of which has ruptured and collapsed leaving only a deep triangular dimple hole in the center of a triangle. Three other triangular cube corner faces we can see have only pin-holes that acted as a pressure cooker release vent for releasing the trapped, super heated - supersaturated - expanding - Galena-steam solution (plasma). This is another one-of-a-kind example the Proctors were able to liberate from a German/Bulgarian collection. This time-capsule specimen graphically displays what happened deep in this mine maybe 30 million years ago. However, these crystals – because they are so sharp - were not in the process of re-solution (going back and forth, into and out of solution) like SUL-GAL-5 was. Specimen measures 5.5” wide by 4” tall (with the biggest wavy cube crystal being on the top). IT IS AMAZING THAT EACH GREAT SPECIMEN HAS A STORY TO TELL IF WE ARE THE CURIOUS TYPE AND TAKE TIME TO LOOK, IMAGINE, ASK QUESTIONS AND THINK AND THEN – EACH TIME - WE MARVEL AT THESE FLOWERS OF THE MINERAL KINGDOM. -Joe Budd photograph 345 RE-SOLUTION GALENA CRYSTALS -Joe Budd photograph SUL-GAL-5. GALENA MELTED CUBES – RUPTURED DIMPLES IN THE PROCESS OF RE-SOLUTION – MADAN, BULGARIA: Seen here is one of the most geochemically interesting and important specimens Keith ever found (the only specimen of its type seen, and acquired from a Bulgarian collection). In this Family Trust collection, there are two re-solution Heliodor Beryls (GSBER-13 and 15) from the Volodarsk, Ukraine mining area. The term re-solution means that in any chemical formula describing - in symbols - a chemical reaction, there are two center placed arrows in the formula pointing in opposite directions, meaning the reaction is reversible. The two Volodarsk Heliodor Beryls went partially back into solution, and then back out of solution into crystal face formation several times until a certain unknown equilibrium was reached, and then the two Heliodors finally terminated as we see them today - with their fingerprint hourglass and rectangular – negative face – markings. Keith had never seen this process happen in an ore mineral species like Galena until he found this classic re-solution Galena specimen from Madan, Bulgaria. This is a textbook example of re-solution (melted appearing) Galena crystals. If we are observant, every great specimen has a story to tell about its formation. TO MARVEL OVER A SPECIMEN, IS A REASON TO OWN IT. Under examination, we see that this 7” wide by 3” high specimen displays many cube crystals that look like they have been melted, but in actuality, they have gone back into solution, and then back out of solution into crystal formation again – maybe several times - until they completed as much as they could, and now we see this sort of stop action, snap-shot picture of their final stages of formation. We can see that many of these cube faces are curved (but not for the same reason as in SUL-GAL-4). These are rare and classic Galena re-solution examples, and at the same time, we can compare many of what were possibly originally completed dimples to the open holes, with their melted rims, we now see = actually collapsed and ruptured dimples that started to go back into solution after having originally completed. This is an absolutely amazing specimen that tells several stories. 346 GALENA CUBO-OCTAHEDRONS: 14-SIDED CRYSTALS (IF COMPLETE AND PERFECT) SUL-GAL-6. GALENA – CLASSIC CUBO-OCTAHEDRAL CRYSTALS – NIKOLAI MINE, DAL’NEGORSK, RUSSIA: Seen here is an extreme, atypically good example of superb cubo-octahedral Galena clusters from Dal’negorsk. This heart-shaped specimen measures 5.5” wide and 4.5” high, and the Galena crystals are found intermixed with the typical cast of Nikolai mine players, such as the zinc rich Sphalerite species, which provided the base coat for the Galenas to grow on; then Chalcopyrites and thin white needle Calcites on top and the Pyrrhotites which then formed last. Even the sequence of crystal deposition is often predictable and based upon the Electromotive Force Series, which often dictates a typical and predictable sequence of depositions based upon the required electron balancing conditions of the mine, and how easily electrons are released and transferred based upon their energies. So there is a hidden reason why species appear where they do and with the Calcites and Quartzes on top. So temperatures, pressures and even cooling rates all play a role. Please study this specimen in detail. There are many collapsed and ruptured dimples which increase the beauty, interest and crystal diversity of these cubo-octahedrons. The top left crystal on this heart shape (far left as shown) has four dimples (two of them are collapsed and ruptured) to match the many crystals on the right. What caused these dimples? As these Galena crystals formed, they grew around and eventually trapped inside bubbles of super-heated, super saturated Galena = a steam Galena solution plasma, which is a fourth state of matter. As these crystals cooled, the trapped steam, Galena solution, inside condensed and formed a vacuum which eventually sucked the crystal surface in (while it was still soft), thus creating these dimples - many of which – in the process - broke open and changed the shape of the Galenas. If these dimples are pin-pricked, the primordial solution oozes out, thus proving this analysis. -Joe Budd photograph 347 GALENA CUBO-OCTAHEDRONS: 14 FACES (IF PERFECT AND COMPLETE) SUL-GAL-7. GALENA – CLASSIC 14-SIDED CUBOOCTAHEDRON ON MATRIX – NIKOLAI MINE, DAL’NEGORSK, RUSSIA: Please examine this specimen closely, and you can see that if this classic cubo-octahedral crystal were not on matrix - and if we could see all sides – then it would have fourteen faces (eight from the octahedron shape combined with six from the cube shape). This Galena cubo-octahedral crystal, with Quartz crystals at the bottom, is exceptionally perfect, except we can see on one of the corner faces on top a ruptured and collapsed dimple that is open so we can see inside, where it is also crystallized - see discussion about dimples on the SULGAL-6. Most of these dimpled or ruptured Galena crystals came either from this Russian mine or from the 9th of September Madan, Bulgaria mine. Specimen measures 2.5” wide, 1.75” high and 2” deep. -Joe Budd photograph SUL-GAL-8. (right) GALENA CUBO-OCTAHEDRAL CRYSTAL CORNERS ON A BIG GALENA CUBE – TRI-STATE REGION, U.S.A.: Fine cubooctahedral specimens from the famed tri-state region of America (the mining region where the corners of Kansas, Oklahoma and Missouri meet) are very highly prized and sought after, and are almost extinct on the market because they are so different from most worldwide Galenas. To quote American Galena collectors … “they are home-grown American specimens”. This specimen – on matrix - is one of the primo surviving examples. It consists of a 1.5” long by 1.25” wide beautifully cubed crystal, with all four of its top cube corners dominated by sculptural cubooctahedrons, which overhang all four corners thus making this crystal appear to be bigger. This magnificent assemblage is perched on the corner of a grey colored chert matrix so common to this region. Specimen measures 2.5” wide, 3” deep and 2” thick. Tristate region, U.S.A.. -Joe Budd photograph 348 GALENA (continued) BEST CUBO-OCTAHEDRAL SINGLE CRYSTAL WITH OCTAHEDRONS SUL-GAL-9. GALENA MINIATURE – MOST CLASSIC CUBO-OCTAHEDRON WITH, OCTAHEDRAL CRYSTALS ON A CORNER POINT OF A CUBE CRYSTAL - SINGLE FLOATER CRYSTAL, TRI-STATE REGION, USA: The Proctors have kept and enjoyed this most unique single Galena crystal (measuring 2” wide, 1.5” high, and 1.25” thick) for over thirty years because it is a one-of-a-kind masterpiece sculpture. This front view shows stepped octahedrons on the right and an uncommon 6-sided flat crystal on top (which is a diagnostic fingerprint crystal illustrating a perfect cubo-octahedral face), in addition to fantastic texturing on the front (cube) face. The right side shows the five stepped octahedrons from a different angle (some with flat points). This single crystal is a floater with no apparent point of contact. It reminds the Proctors a lot of a Mayan temple in Central America. Doesn’t it look like it was computer designed and machine made by an intelligent being (we might call God) or maybe an alien or two from outer space? Please compare this specimen with the previous specimen also from the same famous tri-state mining -Joe Budd photograph region (see SUL-GAL-8). 349 GALENA - SIX TYPES OF SPINEL-LAW TWIN SPECIMENS SUL-GAL-10. GALENA SPINEL TWIN WITH QUARTZ – NINTH OF SEPTEMBER MINE, MADAN, BULGARIA: This specimen exhibits a perfect and brilliant spinel-law-twinned crystal in the center of this crystal cluster, and it is surrounded by Quartz crystals on both sides – which specimen measures 4.5” wide by 2.5” high. This diagonally placed, classic Spinal-law twinned crystal goes from eight o’clock (on the bottom left) to two o’clock (on the right), with a valley between both halves, and we are looking at the top of the spinel-law twinned crystal. -Joe Budd photograph SUL-GAL-11. GALENA - SPINEL-LAWTWINNED CRYSTALS ON QUARTZ – SIXTEENTH OF SEPTEMBER MINE MADAN, BULGARIA: The best spinel twin specimens have been found at the Madan, Bulgaria mines, and the Nikolai mine in the Dal’negorsk, Russia complex of five mines. This specimen measures 6.5” wide by 5.5” high and it displays cubes, and flat spinel-law twin and highly modified. We can recognize a Madan, Bulgaria spinel-twin structure by a sort of flat assemblage of crystals with all the crystal faces being flat and triangular. The back half of the spinel-twin is usually identical to the front half – again all with triangular (octahedral faces). There are no complete – three dimensional, pyramid shaped– octahedrons in these spinel-twin structures. The bottom right spinel-twinned crystal seen here (which is an oblong oval running diagonally from eight o’clock on the bottom left to two o’clock on the top right) is unusual in that it has an obvious, classic, narrow canyon dividing the front and back halves of this twinned cluster. Please compare this bottom spinel-law twin with the twice as large top, oval-shaped, spinel twin structure which also has a canyon separating the two halves. The Madan twins don’t get any better than this example. How many spinel twin clusters can you see on this specimen? -Joe Budd photo 350 GALENA SPINEL-LAW-TWINNED TWINNED CRYSTALS = TEN HUGE CRYSTALS SUL-GAL-12. GALENA – TEN UNIQUE AND WIDE, SPINEL-LAW-TWINS = WORLD-CLASS DISPLAY/MUSEUM SPECIMEN – MADAN, BULGARIA: Deep down in one mine at the Madan, Bulgaria complex of mines, were found possibly the rarest, largest and most beautiful, completely flattened, spinel-law twinned crystals ever seen –some with 4” wide brilliant crystals flashing their hundreds of flat, narrow, elongated and highly lined faces at us. This specimen displays a type of spinel spinel-twin twin pattern found in no other mine. These twins are layered on top with no obvious canyons, and wit with fewer triangular faces these are quite different from the previous specimen. There are ten, wide and very flat sspinel-twin crystals (all at different angles to each other) other on this huge glittering museum specimen measuring 8.5” tall tall, 5.5” wide, and 4” thick. Note the ever present, diagnostic, triangular faces especially on the bottom twinned face. This amazing lead rich specimen must weigh ten pounds and is certainly one of the truly great Galena spinel spinel-law twin specimens. Some of the wide and flat spinel-twins spi have Quartzes on top which define the spinel-twin twin edges below, which add to the beauty, wonder and enjoyment of this specimen. From Madan, Bulgaria. This one mine produced only a handful of specimens with this magnificent presentation. -Joe Budd photograph 351 GALENA SPINEL-LAW TWINS SUL-GAL-13 and 14. GALENA – TWO SPINEL-LAW TWIN SINGLE CRYSTALS – BUICK MINE, MISSOURI: Here we see – side by side – two very rare, sharp, Buick mine - single crystal - Spinel-law twins. Please note the very different and rare termination shapes on the tips of these two Galena crystals. These two crystals are very similar in shape to some Spinel-law twins from the Nikolai mine at Dal’negorsk, Russia. Each specimen measures 1.5” tall. SUL-GAL-13 SUL-GAL-14 -Joe Budd photograph SUL-GAL-15. GALENA: This superb and completely different Galena spinel-law twin – from the previous examples. It is of a unique crystallography and came from Naica, Mexico. This is an exceedingly rare example of a flattened, pseudohexagonal Spinel-law twinned crystal with unbelievably detailed surface texturing. Pictured in the famous John Barlow Collection book – page 346. All these different shapes we have seen in various Spinellaw twinned specimens graphically illustrate the effects that differing pressures, temperatures and cooling rates have on a basic crystal structure from the differing geochemical environments existing in different mines. Specimen measures 1.5” high by 2” wide. -Jeff Scovil photograph 352
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