Data Repository item 2004074 A.J. Dennis, J.W. Shervais, J. Mauldin, H.D. Maher, Wright, J.E. Table DR 1: Formal Description of New Units Defined in the Publication All of the units defined here are exposed in core obtained from deep wells in and around the Savannah River Site. Core is stored at the SRS Core Repository. Well locations are shown in figure 3 of this report, and below in the Savannah River Site grid system. Crackerneck Metavolcanic Complex Cores which sample the Crackerneck metavolcanic complex were drilled to study the overlying sedimentary fill, and generally do not penetrate deeply into the underlying basement. As a result, we present two “type sections” here: one for mafic Crackerneck and one for felsic Crackerneck. Older core obtained from this unit (e.g., the “P” series wells) is 4 inches in diameter; more recent core is 1 inch. Rocks comprising the northern portion of the Crackerneck metavolcanic complex of the Savannah River Site are dominantly intermediate to felsic tuffs and lapilli tuffs. Core from the southern part of the subcrop area is dominanted by greenstone and mafic tuff. Low-grade metavolcanic rocks of the Crackerneck metavolcanic complex are penetrated by younger granitic intrusions, including the Devonian Springfield granite and the Carboniferous Graniteville granite (figure 2). Type section: Core P30; Northing: 3688762.7, Easting: 43053.53, Total Depth: 810 feet. Description, footage 780-796: Pale grey felsic tuffs with visible relict lapilli are composed of small quartz and plagioclase grains with plagioclase phenocrysts. All plagioclase grains have been metamorphosed to nearly pure albite, but relict igneous textures are well preserved. Felsic rocks may also contain small amounts of muscovite and epidote, but generally do not display the intensely chloritized or epidotized appearance. 1 Data Repository item 2004074 A.J. Dennis, J.W. Shervais, J. Mauldin, H.D. Maher, Wright, J.E. Reference section (felsic): Core MMP4; Northing 434068.64, Easting 3688771.48, Total Depth: 785.0 feet. Description, footage 785: Lapilli tuffs display large (to 1.5 x 5 cm) flattened and elongated pumice lapilli giving an appearance similar to lapilli tuffs of the Persimmon Fork Formation. Reference section (mafic): Core P6R; Northing: 3682009.2, Easting: 431351.37, Total Depth: 1042 feet. Description, footage 837-862: Dark grey-green mafic metavolcanic rock are composed of chlorite, plagioclase, epidote and opaque minerals. Lapilli vary from equant clasts to epidotized clasts to wispy, white, pumiceous (?) clasts. Deep Rock Metaigneous Complex Consists of two subunits: the Deep Rock Metavolcanic Suite and the DRB Metaplutonic suite. All DRB (Deep Rock Borehole) core is 4” in diameter. Because basement was the target of this core series, thousands of feet of core are available for study. Each suite has separate reference sections as listed below. Deep Rock Metavolcanic Suite Type section: Core DRB-5; Northing: 3683425, Easting: 438804, Total Depth: 1838 feet. Description, footage 1300-1838: Metavolcanic rocks display a wide array of textures, compositions, and mineralogy. Textures include (a) aphyric intermediate tuffs and mafic, chloritic schists, (b) plagioclase-phyric tuffs and schists, and (c) hornblende-phyric tuffs and schists.. Mafic metavolcanic rocks consist of metamorphic blue-green amphibole, plagioclase, quartz, epidote, and chlorite, with or without relict, brown igneous hornblende. Felsic and intermediate metavolcanic rocks consist of plagioclase, quartz, epidote, biotite, and chlorite, ±amphibole and rare garnet. These mineral assemblages are consistent with lower amphibolite or uppermost greenschist facies metamorphism. 2 Data Repository item 2004074 A.J. Dennis, J.W. Shervais, J. Mauldin, H.D. Maher, Wright, J.E. Plagioclase phenocrysts display various stages of metamorphism. Many plagioclase phenocrysts form subhedral to euhedral crystals that preserve primary igneous compositions and zoning. Other plagioclase grains are anhedral, albitized porphyroclasts that have been partially to extensively epidotized. Hornblende phenocrysts range from blocky, subhedral crystals to elongated, prismatic crystals. Relict igneous hornblende phenocrysts are brown in thin section. In many samples, hornblende phenocrysts and groundmass hornblende have been largely metamorphosed to bluegreen amphibole. Amphibole is commonly retrograded to chlorite in varying degrees, and some segments of core have undergone complete chloritization of the mafic minerals. Intermediate to felsic metavolcanic rocks commonly contain biotite, which is commonly partially chloritized, and a few contain garnet. Metaigneous dikes are common in core. These dikes, which crosscut the metavolcanic rocks, are generally unfoliated, but in many places exhibit the same asymmetric folding apparent in the foliated metavolcanic rocks. There are three groups of dikes: (a) aphyric mafic dikes with basaltic compositions; (b) plagioclase-phyric mafic dikes with basaltic compositions; and (c) aphyric felsic dikes with rhyolitic compositions. Plagioclase-phyric mafic dikes are characterized by large, euhedral plagioclase phenocrysts that preserve relict primary zoning, within a groundmass of amphibole, plagioclase, epidote, chlorite, and biotite. The aphyric mafic dikes are identical to the plagioclase phyric dikes, but lack the conspicuous large phenocrysts. The groundmass of these dikes contains significantly less chlorite and epidote than their metavolcanic host rocks. The felsic dikes consist of fine-grained plagioclase and quartz, with minor opaque oxides, biotite, and hornblende. 3 Data Repository item 2004074 A.J. Dennis, J.W. Shervais, J. Mauldin, H.D. Maher, Wright, J.E. All rocks have been overprinted with a penetrative fabric (foliation) that dips §40˚ to 60˚ assuming core is vertical, but the strike and dip direction are not known. Extensive transposition of layering is evident on the mescoscopic and microscopic scales. Rootless, intrafolial isoclines are commonly observed. Asymmetric folds of foliation have long limbs dipping up to 60° and short limbs that can be nearly horizontal. These folds have a typical “down dip” vergence. Fold axes are subhorizontal (assuming core is vertical). Mafic phyllonites are commonly observed that indicate dextral motion and/or “hanging wall up” motion. Chloritic fractures that have the same strike as foliation and dip less steeply than foliation are ubiquitous. Offsets of metamorphic layering are discernible, but the sense of offset is not always clear. Reference section #1: Core DRB-3; Northing: 3682954, Easting: 438181.8, Total Depth: 1928 feet. Description, footage 950-1500: Dark grey-green mafic metavolcanic rock includes porphyritic and equigranular fine-grained mafic schists, and porphyroclastic greenstones amphibolites cut by metamorphosed mafic dikes, locally, phyllonitic zones crosscut this package. Because some texturally similar black amphibolites are also dispersed throughout the section, “green rocks” are interpreted to represent heterogeneous retrogression. Approximately 20% of the section comprises a light gray felsite. Down dip vergent asymmetric folding of foliation (long limb typically dipping 50-60°) and dike is commonly observed. Dextral and hangingwall up shear sense indicators include shear bands and winged porphyroclasts. Chloritic fractures that have the same strike as foliation and dip less steeply than foliation are ubiquitous. Offsets of metamorphic layering are discernible, but the sense of offset is not always clear. Reference section #2: Core DRB-6; Northing: 3683130, Easting: 439247.2, Total Depth: 1913 feet. 4 Data Repository item 2004074 A.J. Dennis, J.W. Shervais, J. Mauldin, H.D. Maher, Wright, J.E. Description, footage 1100-1913: Mafic (25%) and intermediate to felsic (75%) schists and amphibolite facies gneisses. Mafic layers are commonly porphyritic with amphibole or plagioclase porphyroclasts. Layering is heterogeneous in these mafic and felsic rocks. Transposition of layering is evident from the mesoscopic to microscopic scales. Less sheared bands of black amphibolite are separated by mylonitic mafic schists and phyllonite. Dips of foliation are generally 70°. Detached rootless isoclinal folds are transposed into the plane of foliation. Foliation is folded into downdip vergent asymmetric folds with near horizontal hinges. Chloritized shear bands dip less steeply than foliation, and typically yield dextral or hanging wall up shear sense. Reference section #3: Core DRB-7; Northing: 3682833, Easting: 439474, Total Depth: 1868.8 feet. Description: footage 1300’-1868’: Heterolithic mafic schist interleaved with a fine grained muscovite schist. Over the length of the section approximately half is mafic and half felsic. Some of the distinctive lithic types within the mafic section are a greenstone, an amphibole porphyry, and a banded amphibolite with large (<1 cm) garnets. Black amphibolites are separated by mylonitic mafic schists. The section is extensively transposed. Rootless isoclines of layering and foliation are folded asymmetrically with subhorizontal hinges and down-dip vergence. Felsic schists commonly show a button schist texture, and shear bands indicate either hanging wall up or dextral motion typically. DRB1 Metaplutonic Suite Named for the DRB-1 well in which it occurs. Type section: Core DRB-1; Northing: 3684171, Easting: 437524.7, Total Depth: 1904 feet. Description, footage 892-1904: The protolith for metadiorite and metaquartz diorite gneiss were equigranular diorites and porphyries of hornblende phenocrysts in finer-grained, 5 Data Repository item 2004074 A.J. Dennis, J.W. Shervais, J. Mauldin, H.D. Maher, Wright, J.E. groundmass of quartz, plagioclase, amphibole, and chlorite. These rocks cut minor intercalated metavolcanic rocks, and are weakly metamorphosed with minor shear zones. Diorite and quartz diorite sheets intrude preexisting, foliated metavolcanic wallrock. The diorites were metamorphosed to epidote-amphibolite facies assemblages. These rocks are variably deformed from undeformed to gneissic. The porphyritic gneisses are characterized by large, zoned hornblende and plagioclase porphyroclasts, within a fine to medium-grained matrix of plagioclase, quartz, chlorite, blue/green amphibole, and epidote. Chloritic fractures and chloritized amphiboles may also appear sparsely. Plagioclase porphyroclasts may show relict igneous features, including oscillatory zoning and albite twinning. Metaplutonic rocks of DRB1 contain no garnet, consistent with metamorphism at relatively low temperatures and pressures (lower amphibolite to uppermost greenschist facies conditions). Biotite is rare to absent in the DRB1 metadiorites; almost all primary biotite has been metamorphosed to chlorite. Most amphibole porphyroclasts, and essentially all groundmass amphiboles, are metamorphosed to blue-green amphibole. However, many amphibole porphyroclasts preserve cores of brown hornblende, which are interpreted to represent relict igneous hornblende. Metaplutonic rocks contain xenoliths and screens of amphibolite facies metavolcanic rocks that are deformed and contain fabric elements similar to rocks of the Deep Rock Metavolcanic Suite, with which they are assumed to correlate. These metavolcanic rocks are composed of ~60% blue/green amphibole and ~40% plagioclase, epidote, and quartz. The amphibole forms small prismatic grains, plagioclase and epidote form blocky anhedral grains. Thin anastomosing mylonite zones penetrate the DRB1 metadiorites. These may be distinguished by belts of ultrafine-grained quartz, feldspar, amphibole, and epidote bounded on 6 Data Repository item 2004074 A.J. Dennis, J.W. Shervais, J. Mauldin, H.D. Maher, Wright, J.E. either side by fine to medium grained porphyritic gneisses. The mylonite zones are generally meter scale or thinner in thickness. Chloritic fractures are common in these metaplutonic rocks. Pen Branch Metaigneous Complex Consists of two subunits: the Pen Branch Metavolcanic Suite and the PBF Metaplutonic suite. Each suite has separate reference sections as listed below. Pen Branch Metavolcanic Suite Type section: Core PBF-7; Northing: 3678485, Easting: 442463.6, Total Depth: 3651 feet. Description, footage 2500 to 3500: Grey-green mafic metavolcanic rock forms rare screens between sheets of unpinked and partly pinked granodiorote gneiss (PBF Plutonic suite) . Screens are often black, but may have a conspicuous greenish cast. Description, footage 3500 to 3600: Pinked granitic gneiss (PBF Plutonic suite). Description, footage 3600 to 3648: Fine grained black amphibolite, commonly with garnet (up to 1 cm diameter) , locally retrogressed to a chlorite actinolite schist. Garnetiferous layers are generally less than 7 cm thick. Reference section #1: Seismic Attenuation Core; Northing: 3679655 Easting: 440618, Total Depth: 4002 feet (PBF Plutonic Suite in continuous core above 1118 feet; spot cores from 19594002 feet). Description: footage 1959-4002: Migmatitic amphibolite, cut by undeformed pink granite veins. PBF7 Metaplutonic Suite Named for the PBF7 and PBF well series in which it principally occurs. All PBF core is 2.5” in diameter. Type section: Core PBF-7, Northing: 3678485 Easting: 442463.6, Total Depth: Description, footage 2550 to 3100: Unpinked, foliated granodiorite gneiss. Gneissic metagranitoids are porphyroclastic gneisses with porphyroclasts of amphibole and plagioclase set in a groundmass of amphibole, plagioclase, microcline, biotite, quartz, and epidote. Amphibole 7 Data Repository item 2004074 A.J. Dennis, J.W. Shervais, J. Mauldin, H.D. Maher, Wright, J.E. porphyroclasts are unzoned blue-green amphiboles. Garnet porphyroblasts are a common accessory mineral in the metaplutonic rocks. Description, footage 3140 to 3480: Transition zone, unpinked granodiorite and diorite gneiss with some partly pinked granodiorite gneiss. Description, footage 3500 to 3600: Pinked granitic gneiss. Lower contact at 3600 feet is mylonite zone which separates PBF plutonic suite from high-grade metavolcanic rocks of the Pen Branch Metavolcanic Complex. Pinked metagranitoid: “Pinked” PBF metagranites commonly contain large plagioclase, microcline, and garnet porphyroblasts set in a finer-grained matrix of quartz, plagioclase, microcline, and chlorite. Plagioclase porphyroclasts are much less common in pinked rocks. Amphibole is almost completely chloritized, and with increasing pinking is increasingly uncommon, but some relict blue-green amphibole is preserved. Microcline in the pinked metagranitoids commonly occurs as large megacrysts up to ~5mm across, and may account for as much as 40% of the modal mineralogy. Plagioclase in the thoroughly pinked granites is completely albitized, and subsequently, partially sericitized. Biotite, like amphibole, also has been almost completely chloritized. Pinking occurs on scales from mm-scale to dozens of meters of complete alteration. Reference section #1: Seismic Attenuation Core, Northing: 3679655 Easting: 440618 Description, footage 1078-1118: Pinked granitic gneiss. Lineated garnetiferous felsic gneiss and felsic mylonite cut by coarse grained granitic veins. Large K-feldspar porphyroblasts in felsic gneiss. Gneiss and granite have a conspicuous pinkish cast. 8 D R-2. W hole rock m ajor and trace elem ent analyses by x-ray fluorescence. Crackerneck Metavolcanic Complex Core# Box SAMPLE# Rock Type P6R none 856 C1 none 570 C1 none 574 C3 none 540 Deep Rock Metavolcanic Suite P30 none 781 MMP4 none 817 Felsic Felsic Mafic Tuff Felsic Tuff Felsic Tuff Felsic Tuff Lapilli Tuff Lapilli Tuff DRB1 75 1375 DRB1 87 1438 DRB1 123 1653 DRB1 135 1727 DRB2 17M 1081M Mafic MV Mafic MV Mafic MV Mafic MV Felsic MV xenolith xenolith xenolith xenolith SiO2 TiO2 Al2O3 Fe2O3 MnO MgO CaO Na2O K2O P2O5 SUM %LOI 48.75 0.94 16.68 10.82 0.203 7.95 9.47 3.37 0.721 0.163 100.84 65.72 0.74 17.83 7.09 0.15 2.10 1.19 1.97 3.91 0.14 100.84 3.19% 68.32 0.70 16.00 5.96 0.13 1.93 2.09 2.87 2.52 0.15 100.66 1.93% 71.55 0.66 14.24 5.04 0.09 1.54 1.34 4.15 1.52 0.16 100.29 2.47% 74.29 0.23 12.40 4.29 0.14 0.71 0.62 5.16 1.31 0.03 99.18 0.86% 76.98 0.23 11.63 2.96 0.13 1.11 0.39 4.41 2.01 0.03 99.88 50.95 1.02 17.25 11.47 0.17 6.56 10.31 2.99 0.27 0.18 101.15 0.30% 49.42 0.83 16.33 11.79 0.23 9.13 9.71 2.75 0.33 0.13 100.66 2.05% 50.38 0.89 18.01 10.01 0.16 6.51 11.32 3.52 0.31 0.14 101.24 1.08% 51.06 1.45 15.96 14.15 0.21 5.34 8.67 3.96 0.31 0.19 101.28 0.51% 63.44 0.96 16.41 7.44 0.19 1.90 4.83 4.27 1.59 0.43 101.45 0.34% Nb Zr Y Sr Rb Zn Cu Ni Cr Sc V Ba 1 56 17 266 16 80 106 156 357 35 254 228 17 233 14 133 108 108 17 36 50 13 99 1357 12 206 22 350 69 88 17 34 42 14 97 1241 9 159 19 106 30 76 5 9 10 7 45 753 14 287 72 64 27 134 2 42 79 nd 7 119 9 296 65 35 32 138 2 43 160 nd 5 438 4 72 21 317 2 70 72 36 128 38 274 69 3 56 17 180 3 129 17 126 374 39 251 63 3 72 17 328 9 86 82 50 165 35 246 217 3 80 23 271 3 76 32 15 55 38 401 106 10 175 45 634 38 60 17 5 6 13 80 625 Major elements on pre-ignited fused glass beads, results in wt% oxide. Trace elements on pressed powders, results in ppm. D R-2. W hole rock m ajor and trace elem ent analyses by x-ray fluorescence. Deep Rock Metavolcanic Suite Core# Box SAMPLE# Rock Type DRB2 17 1081 DRB2 68 1415.5 DRB3 6 988 Mafic MV Mafic MV Felsic MV DRB3 41 1220 Inter MV DRB3 59 1346 DRB3 77 1468 DRB3 83 1512 Mafic MV Mafic MV Mafic MV DRB4 23 1116 DRB4 76 1450.7 Chl Schist Felsic Gneiss DRB4 127 1784 DRB4 129 1796 DRB4 131 1831 Felsite MV Felsite MV Felsite MV SiO2 TiO2 Al2O3 Fe2O3 MnO MgO CaO Na2O K2O P2O5 SUM %LOI 51.74 1.06 16.98 10.82 0.188 4.61 9.44 2.91 1.186 0.335 99.27 1.90% 49.91 1.02 20.96 11.95 0.16 9.51 3.98 2.94 0.96 0.21 101.60 4.76% 65.59 0.80 16.81 4.65 0.12 1.58 3.47 4.38 3.18 0.26 100.85 2.55% 66.24 0.76 16.29 5.01 0.11 1.51 3.93 5.40 1.70 0.20 101.16 1.85% 49.94 1.13 20.85 10.56 0.18 3.70 10.20 3.49 1.53 0.40 101.98 2.00% 49.54 1.09 17.01 12.61 0.23 7.02 8.74 3.85 0.88 0.28 101.25 2.08% 54.04 1.61 17.38 11.23 0.20 3.49 6.34 5.11 1.23 0.79 101.41 1.45% 60.97 1.17 19.82 8.93 0.06 1.23 2.20 3.88 2.21 0.15 100.63 2.14% 78.32 0.10 11.74 1.21 0.02 0.15 0.77 5.82 0.91 0.01 99.05 0.72% 68.78 0.73 14.33 5.49 0.098 1.54 4.02 3.03 1.599 0.155 99.211 1.29% 69.81 0.72 14.98 4.93 0.10 1.73 3.19 1.93 2.89 0.14 100.42 1.44% 70.98 0.74 13.98 4.20 0.11 1.60 3.44 2.05 2.37 0.14 99.59 1.17% Nb Zr Y Sr Rb Zn Cu Ni Cr Sc V Ba 6 148 31 715 52 106 174 18 47 30 309 500 7 181 39 867 64 78 75 2 13 18 199 765 11 188 35 365 62 75 4 nd 3 7 74 1440 9 174 33 410 34 59 76 6 6 10 102 744 5 102 25 782 28 94 148 18 28 20 287 607 3 65 22 431 15 119 83 41 136 35 305 301 7 182 40 450 24 125 71 9 16 19 223 429 12 249 43 402 78 85 5 15 21 17 97 603 29 190 76 48 40 30 11 3 nd 4 19 244 11 191 42 126 60 62 4 30 67 31 84 392 19 210 49 129 106 76 11 16 16 11 61 421 16 176 41 116 78 59 nd 14 48 nd 56 317 Major elements on pre-ignited fused glass beads, results in wt% oxide. Trace elements on pressed powders, results in ppm. D R-2. W hole rock m ajor and trace elem ent analyses by x-ray fluorescence. Deep Rock Metavolcanic Suite Core# Box SAMPLE# DRB4 66 1397 DRB4 82 1490 DRB4 101 1613 DRB4 103 1631 DRB4 146 1916 Rock Type Inter MV Inter MV Inter MV Inter MV Inter MV D DRB4 123 1758.4 DRB4 145 1912 DRB5 73 1802 Mafic MV Mafic MV Felsite MV DRB5 69 1776 DRB5 77 1823 DRB5 61 1723 DRB5 15M 1324 Inter MV Inter MV Inter MV Mafic MV SiO2 TiO2 Al2O3 Fe2O3 MnO MgO CaO Na2O K2O P2O5 SUM %LOI 61.36 1.28 18.03 8.86 0.16 2.22 1.06 1.35 4.38 0.40 99.10 2.74% 61.93 1.37 13.36 8.89 0.15 4.44 5.76 2.76 1.90 0.18 100.72 2.63% 68.05 0.80 13.90 5.07 0.13 1.54 5.04 1.39 2.25 0.16 98.32 1.74% 67.19 0.92 15.46 5.92 0.11 2.11 3.97 2.11 3.02 0.17 100.99 1.66% 65.85 0.97 13.97 7.61 0.11 3.10 3.84 3.46 1.69 0.16 100.77 0.75% 51.47 2.12 15.12 13.26 0.21 6.95 7.46 2.36 0.54 0.26 99.74 1.81% 54.51 1.71 14.57 11.21 0.19 6.10 7.63 2.23 1.55 0.23 99.905 1.01% 72.89 0.38 14.34 2.94 0.04 0.87 2.17 5.87 0.96 0.08 100.54 0.75% 63.05 0.86 16.74 6.24 0.10 2.62 4.60 5.21 1.42 0.21 101.06 2.99% 62.18 0.79 16.25 6.15 0.12 3.01 4.66 4.3 2.11 0.182 100.823 1.60% 64.84 0.70 15.77 6.67 0.12 2.78 4.40 4.07 1.77 0.18 101.29 1.62% 50.48 0.97 18.88 11.13 0.19 5.68 9.30 3.29 0.57 0.24 100.75 0.97% Nb Zr Y Sr Rb Zn Cu Ni Cr Sc V Ba 17 261 50 114 174 113 3 36 71 25 152 830 18 201 28 228 75 97 49 86 173 15 191 368 16 182 42 146 92 71 22 27 63 15 109 440 20 212 48 156 111 92 6 24 47 15 93 444 11 171 26 262 65 79 55 43 91 15 148 306 16 185 33 310 23 105 70 165 329 32 304 233 11 170 28 209 55 93 76 178 384 29 226 447 11 149 30 331 17 28 27 2 2 7 38 301 7 99 21 350 25 47 11 1 5 16 115 405 4 104 22 436 50 60 13 2 nd nd 116 461 10 122 26 297 34 63 1 12 40 11 107 517 4 78 21 637 11 98 120 14 22 18 221 274 Major elements on pre-ignited fused glass beads, results in wt% oxide. Trace elements on pressed powders, results in ppm. D R-2. W hole rock m ajor and trace elem ent analyses by x-ray fluorescence. Deep Rock Metavolcanic Suite Core# Box SAMPLE# Rock Type DRB5 13 1416 DRB5 63 1735 DRB6 4M 1125 Deep Rock Metavolcanics DRB6 68 1570 DRB6 92 1758 DRB6 103 1810 DRB6 107 1837 DRB7 38 1601 DRB7 2 1373 DRB7 57 1731.6 Mafic MV Mafic MV Mafic MV Mafic MV Mafic MV Mafic MV Mafic MV Felsite MV Mafic MV Mafic MV SiO2 TiO2 Al2O3 Fe2O3 MnO MgO CaO Na2O K2O P2O5 SUM %LOI 53.32 1.02 19.78 10.23 0.18 3.72 8.09 4.64 0.70 0.26 101.93 2.67% 62.14 0.74 17.27 6.82 0.11 2.44 4.39 5.38 1.42 0.20 100.91 1.52% 51.87 1.32 17.74 11.52 0.21 4.15 8.23 2.79 2.45 0.42 100.70 1.08% 50.52 1.12 18.41 12.51 0.21 5.24 8.25 2.97 1.93 0.20 101.35 1.03% 54.89 1.18 19.05 9.96 0.19 6.10 7.48 4.17 2.89 0.45 106.37 4.48% 49.44 1.29 17.68 12.39 0.23 5.03 8.90 1.73 3.94 0.39 101.01 1.67% 51.87 1.18 18.58 10.03 0.19 4.55 7.72 3.66 2.92 0.39 101.08 1.89% 70.59 0.46 15.62 3.13 0.07 0.97 2.85 5.90 0.95 0.14 100.68 0.40% 62.45 0.96 18.21 6.88 0.15 1.75 3.10 3.56 3.38 0.25 100.71 1.72% 53.79 1.17 16.86 9.65 0.17 5.08 6.39 3.36 4.02 0.61 101.10 3.53% Nb Zr Y Sr Rb Zn Cu Ni Cr Sc V Ba 4 71 20 655 10 109 113 24 51 22 251 218 6 115 23 351 29 52 40 3 4 13 82 412 7 164 33 711 59 125 230 19 35 22 283 710 3 89 22 507 45 106 131 22 56 28 363 507 6 148 29 509 70 114 167 77 191 24 229 544 6 163 28 885 108 136 150 18 38 26 316 660 7 141 26 647 67 126 83 24 76 21 226 679 8 198 24 515 22 30 76 2 nd 6 57 571 10 221 30 429 88 83 21 5 9 17 122 795 8 193 35 622 111 103 80 56 130 20 193 684 Major elements on pre-ignited fused glass beads, results in wt% oxide. Trace elements on pressed powders, results in ppm. D R-2. W hole rock m ajor and trace elem ent analyses by x-ray fluorescence. Dikes within Deep Rock Metavolcanics Core# Box SAMPLE# Rock Type DRB3 41 1225 DRB3 130 1828 DRB3 140 1896 DRB6 7F 1140 DRB6 92F 1758F DRB5 15F 1324 DRB6 4F 1125 DRB2 23 1117 DRB2 27 1137 DRB2 29 1154 DRB2 31 1170 DRB2 108 1687 Felsic Dike Felsic Dike Felsic Dike Felsic Dike Felsic Dike Felsic Dike Felsic Dike Mafic Dike Mafic Dike Mafic Dike Mafic Dike Mafic Dike SiO2 TiO2 Al2O3 Fe2O3 MnO MgO CaO Na2O K2O P2O5 SUM %LOI 58.60 1.15 16.57 9.62 0.16 2.70 5.77 4.09 2.15 0.46 101.27 2.56% 67.18 0.73 16.35 4.74 0.10 1.21 3.75 5.64 1.62 0.20 101.51 1.07% 65.69 0.68 16.44 4.03 0.10 1.62 4.29 5.36 1.53 0.19 99.94 0.97% 68.78 0.69 16.02 4.19 0.12 1.00 3.35 5.83 0.92 0.17 101.08 0.30% 67.21 0.55 16.43 4.21 0.08 1.46 4.79 5.13 1.30 0.15 101.32 1.19% 73.83 0.23 14.51 1.89 0.03 0.58 2.38 5.70 0.90 0.08 100.12 5.50% 70.82 0.49 14.96 3.34 0.06 0.89 4.13 4.63 0.66 0.11 100.09 0.48% 50.85 1.29 18.06 11.58 0.21 4.50 10.71 3.21 0.92 0.32 101.63 1.35% 51.71 1.20 18.96 11.30 0.21 3.93 10.35 2.93 0.72 0.38 101.68 1.01% 48.91 0.87 17.92 11.75 0.20 6.18 11.51 2.75 0.96 0.31 101.36 1.06% 50.71 0.98 19.04 12.07 0.22 4.87 8.76 4.03 0.72 0.27 101.68 1.18% 51.76 1.19 18.00 10.77 0.18 3.70 9.57 3.18 0.95 0.35 99.64 1.05% Nb Zr Y Sr Rb Zn Cu Ni Cr Sc V Ba 7 152 36 472 41 102 145 7 17 17 177 637 9 187 32 418 33 59 10 6 6 9 83 858 4 176 29 437 33 55 60 12 nd nd 87 nd 11 190 45 563 22 74 34 3 1 8 42 665 7 188 27 617 32 32 78 9 37 6 101 272 23 117 10 543 24 29 38 2 0 4 24 1111 10 186 39 470 17 20 80 5 26 3 61 325 5 135 32 614 24 98 249 16 54 31 330 279 6 140 32 680 18 129 199 20 37 28 311 223 1 77 21 647 23 79 33 24 97 35 275 245 4 101 24 666 17 64 28 9 16 31 303 201 5 148 34 617 21 62 178 7 12 29 273 425 Major elements on pre-ignited fused glass beads, results in wt% oxide. Trace elements on pressed powders, results in ppm. D R-2. W hole rock m ajor and trace elem ent analyses by x-ray fluorescence. Dikes DRMV DRB Plutonic Suite Core# Box SAMPLE# DRB2 8 1025.7 DRB2 12 1053.5 DRB2 18 1085.7 DRB1 18 1005 DRB1 22 1028 DRB1 25 1047 DRB1 41 1151 DRB1 51 1215 DRB1 59 1268 DRB1 60 1276 DRB1 98 1504 Rock Type Plg Porph Dike Plg Porph Dike Plg Porph Dike Quartz Diorite Tonalite Diorite Quartz Diorite Quartz Diorite Quartz Diorite Tonalite Tonalite SiO2 TiO2 Al2O3 Fe2O3 MnO MgO CaO Na2O K2O P2O5 SUM %LOI 50.90 0.72 18.38 11.02 0.25 5.91 8.67 2.90 2.15 0.16 101.05 1.01% 51.89 1.05 17.18 11.06 0.19 4.78 9.33 3.06 1.18 0.33 100.03 0.96% 58.48 1.21 16.48 9.79 0.17 2.79 6.98 2.89 2.15 0.50 101.42 0.60% 60.04 0.78 17.05 8.05 0.15 3.15 5.89 4.28 0.93 0.18 100.49 1.51% 69.38 0.53 15.16 5.66 0.08 1.25 3.41 5.06 0.53 0.11 101.18 1.07% 50.00 1.09 17.39 12.10 0.20 6.72 9.60 3.84 0.47 0.14 101.56 1.50% 54.34 1.17 16.14 12.08 0.15 4.25 8.37 3.21 1.03 0.16 100.91 0.69% 59.58 0.76 17.65 5.77 0.13 2.17 5.94 5.67 0.93 0.23 98.82 0.47% 53.50 1.05 17.69 10.37 0.18 3.77 8.26 4.69 0.26 0.25 100.03 0.75% 70.37 0.58 15.10 3.61 0.05 1.00 3.22 6.78 0.29 0.15 101.15 1.33% 70.04 0.60 15.31 3.65 0.06 1.07 2.94 7.04 0.29 0.17 101.17 0.55% Nb Zr Y Sr Rb Zn Cu Ni Cr Sc V Ba 4 85 20 574 49 109 6 29 86 29 228 499 6 132 32 645 30 98 162 19 49 30 310 388 3 75 19 423 20 122 12 8 21 13 235 360 7 141 25 316 19 81 81 12 16 15 142 579 8 171 25 236 9 33 115 3 6 12 42 170 3 65 18 263 7 91 87 41 142 38 316 126 5 107 27 297 20 69 26 6 19 30 352 346 6 181 22 373 18 85 7 7 9 16 99 442 6 91 24 403 4 72 80 7 13 25 228 156 4 85 16 381 3 59 6 24 22 24 172 106 11 202 30 225 4 24 2 2 1 11 43 245 Major elements on pre-ignited fused glass beads, results in wt% oxide. Trace elements on pressed powders, results in ppm. D R-2. W hole rock m ajor and trace elem ent analyses by x-ray fluorescence. DRB Metasediments DRB Plutonic Suite Core# Box SAMPLE# DRB1 99 1509 DRB1 124 1660 DRB1 153 1837 DRB1 156 1852 Rock Type Quartz Diorite Quartz Diorite Quartz Diorite Quartz Diorite DRB4 34 1192 DRB4 36 1203 DRB4 38 1216 Metaseds Metaseds Metaseds Wall Rock Wall Rock Wall Rock SiO2 TiO2 Al2O3 Fe2O3 MnO MgO CaO Na2O K2O P2O5 SUM %LOI 55.58 0.65 18.15 8.22 0.14 4.99 9.24 3.94 0.22 0.13 101.26 0.79% 58.46 0.96 17.63 9.11 0.11 2.74 4.71 7.93 0.13 0.14 101.92 1.86% 57.55 0.71 17.46 8.22 0.13 4.15 6.06 6.21 0.66 0.11 101.25 0.46% 59.48 0.79 17.51 7.47 0.12 2.62 6.92 4.54 0.79 0.21 100.44 0.54% 86.31 0.30 7.27 2.88 0.03 0.24 0.94 0.13 1.83 0.02 99.95 0.89% 84.88 0.50 7.80 2.54 0.03 0.43 0.43 1.14 1.86 0.02 99.63 1.14% 86.17 0.25 6.69 0.89 0.06 0.24 2.22 0.24 1.61 0.01 98.37 2.21% Nb Zr Y Sr Rb Zn Cu Ni Cr Sc V Ba 10 213 31 213 5 22 6 1 1 12 40 187 5 151 22 179 nd 52 12 12 8 20 184 64 4 84 21 199 11 55 71 28 16 25 188 222 6 149 22 407 16 39 62 10 5 15 144 327 10 84 22 32 74 9 1 3 11 1 29 290 13 132 20 33 77 38 47 8 14 6 45 260 9 78 15 52 65 9 3 2 7 5 20 432 Major elements on pre-ignited fused glass beads, results in wt% oxide. Trace elements on pressed powders, results in ppm. D R-2. W hole rock m ajor and trace elem ent analyses by x-ray fluorescence. Pen Branch Metavolcanic Suite Core# Box SAMPLE# Rock Type PBF7 101 2516 PBF7 149 3238 PBF7 161 3408 Pen Branch Metavolcanic Suite PBF7 175 3617 PBF7 175 3626 PBF7 175 3630 PBF7 177 3648 SA 1of3 1959 SA 1of3 1960 SA 2of3 2181 Mafic MV Mafic MV Mafic MV Mafic MV Mafic MV Mafic MV Mafic MV Mafic MV Mafic MV Mafic MV Wall Wall Wall Wall Wall Wall Wall Wall Wall Wall SA 3of3 3403 SA 3of3 4002 Inter Gneiss Inter Gneiss SiO2 TiO2 Al2O3 Fe2O3 MnO MgO CaO Na2O K2O P2O5 SUM %LOI 55.84 1.27 16.88 8.47 0.156 4.66 6.99 3.28 2.969 0.345 100.86 4.96% 55.56 1.33 16.68 8.17 0.188 4.45 8.27 3.53 1.21 0.265 99.66 1.15% 54.91 1.27 16.22 8.71 0.147 5.02 8.11 3.69 0.956 0.178 99.21 0.81% 56.9 0.97 17.49 10.25 0.193 3.74 6.26 4.49 0.862 0.168 101.32 0.75% 50.89 1.36 16.69 12.32 0.231 4.8 9.51 3.91 1.321 0.529 101.57 1.17% 47.8 1.47 16.88 13.37 0.234 5.29 11.08 3.59 1.025 0.612 101.35 1.27% 59.57 1.09 16.76 9.75 0.199 2.85 6.23 2.96 1.485 0.181 101.07 0.79% 48.31 0.92 18.58 10.65 0.159 6.74 10.83 3.27 1.103 0.505 101.08 0.89% 50.7 0.92 19.7 9.18 0.147 5.49 10.27 3.4 1.356 0.179 101.34 1.13% 53.72 1.28 16.7 10.8 0.179 3.85 7.28 3.5 1.946 0.318 99.58 1.73% 57.08 0.71 17.74 7.90 0.16 5.05 7.52 3.44 1.02 0.18 100.82 1.45% 59.04 0.6 18.99 6.6 0.149 2.57 6.11 4.2 0.818 0.115 99.21 0.71% Nb Zr Y Sr Rb Zn Cu Ni Cr Sc V Ba 19 335 47 347 108 84 18 49 97 20 125 1191 11 158 30 358 43 70 19 17 118 23 183 285 10 144 28 320 32 71 26 36 95 26 186 255 3 95 26 274 18 90 38 16 52 24 196 252 6 108 26 546 44 176 108 12 31 31 305 317 22 257 39 434 72 50 4 8 6 14 81 739 4 138 36 552 36 97 53 8 33 22 163 393 3 76 14 617 37 67 38 56 191 22 160 151 9 81 15 609 61 67 11 36 172 26 219 270 7 92 32 476 86 96 76 13 20 25 238 330 7 114 18 507 31 84 11 55 191 22 152 291 3 82 19 453 21 58 5 14 32 18 140 185 Major elements on pre-ignited fused glass beads, results in wt% oxide. Trace elements on pressed powders, results in ppm. D R-2. W hole rock m ajor and trace elem ent analyses by x-ray fluorescence. PBF Plutonic Suite: "Unpinked" Core# Box SAMPLE# C5 none 1077 C5 none 1084 PBF7 103 2550 PBF7 107 2602 PBF7 108 2629 PBF7 115 2726 PBF7 115T 2726 PBF7 139 3086 PBF7 159 3387 C5 none 1080 Rock Type mafic schist mafic schist Granodiorite Granodiorite Granodiorite Granodiorite Granodiorite Granodiorite Granodiorite felsic dike SiO2 TiO2 Al2O3 Fe2O3 MnO MgO CaO Na2O K2O P2O5 SUM %LOI 57.08 1.95 16.18 9.61 0.178 3.94 7.2 3.52 1.165 0.28 101.1 3.24% 56.79 1.33 16.76 8.25 0.152 4.91 6.26 3.81 1.871 0.192 100.33 2.29% 58.16 1.39 16.74 8.46 0.15 3.46 6.94 3.93 1.48 0.34 101.06 1.60% 54.69 1.76 16.54 9.93 0.18 3.52 7.69 2.84 3.15 0.60 100.90 1.26% 64.24 1.07 15.66 6.18 0.12 1.97 4.70 3.90 3.22 0.21 101.27 0.63% 58.36 1.13 15.53 7.69 0.14 4.48 7.22 3.49 1.29 0.24 99.57 2.28% 62.22 0.84 15.29 6.85 0.12 3.90 5.69 3.52 2.25 0.17 100.84 1.89% 59.30 0.83 17.54 8.37 0.18 2.97 5.82 4.11 1.69 0.13 100.97 1.78% 68.36 0.84 14.39 5.08 0.09 1.42 4.62 3.29 2.19 0.17 100.45 1.36% 73.65 0.46 13.43 2.88 0.07 0.64 1.58 3.67 3.85 0.10 100.33 1.44% Nb Zr Y Sr Rb Zn Cu Ni Cr Sc V Ba 13 271 49 425 32 94 36 25 88 25 211 293 9 192 30 458 61 72 18 35 29 19 144 1647 19 275 42 421 49 179 81 19 42 20 157 486 18 305 53 347 97 89 117 22 32 24 147 995 23 298 44 311 70 66 51 14 12 11 96 960 10 172 22 450 42 69 32 52 86 22 147 378 8 138 19 388 69 63 19 52 73 19 114 852 5 134 21 341 55 103 61 21 47 17 148 427 4 122 33 551 39 96 52 10 30 22 162 393 30 246 53 205 72 40 15 6 2 4 38 550 Major elements on pre-ignited fused glass beads, results in wt% oxide. Trace elements on pressed powders, results in ppm. D R-2. W hole rock m ajor and trace elem ent analyses by x-ray fluorescence. PBF Plutonics: "Partly Pinked" Core# Box SAMPLE# Rock Type PBF7 143 3139.6 PBF7 145 3177 PBF7 157 3352 PBF Plutonic Suite: "Pinked" PBF7 157 3355 part pinked part pinked part pinked part pinked granite granite granite granite C10A none 1734 PBF7 167 3503 PBF7 169 3541 PBF7 171 3568 PBF7 171 3570 PBF7 173 3593 PBF7 165 3467 pink granite pink granite pink granite pink granite pink granite pink granite pink granite SiO2 TiO2 Al2O3 Fe2O3 MnO MgO CaO Na2O K2O P2O5 SUM %LOI 71.57 0.51 14.06 3.50 0.07 0.56 1.68 3.58 5.00 0.11 100.63 0.85% 72.29 0.55 13.34 3.64 0.06 0.65 2.00 3.36 4.52 0.11 100.52 0.71% 72.78 0.51 13.53 3.46 0.09 0.52 2.17 3.72 3.89 0.11 100.78 1.05% 72.54 0.53 13.62 3.67 0.06 0.59 2.00 3.57 4.14 0.11 100.84 1.36% 74.16 0.35 13.93 2.39 0.06 0.45 0.81 3.82 4.89 0.08 100.94 0.71% 77.12 0.06 12.66 1.12 0.02 0.02 0.49 4.39 4.79 0.01 100.67 0.71% 75.45 0.08 13.00 1.54 0.07 0.11 0.88 5.63 3.17 0.02 99.93 0.84% 75.31 0.14 13.23 1.36 0.04 0.28 0.98 4.03 5.25 0.02 100.64 0.71% 76.84 0.09 12.96 1.30 0.03 0.07 0.59 3.90 5.25 0.02 101.04 0.51% 74.62 0.11 12.71 1.48 0.04 0.07 0.59 4.11 5.03 0.02 98.78 0.29% 71.90 0.49 13.31 3.34 0.07 0.55 1.82 3.54 4.79 0.11 99.92 0.37% Nb Zr Y Sr Rb Zn Cu Ni Cr Sc V Ba 24 242 57 135 104 50 3 5 nd 4 31 803 27 268 58 147 98 57 8 5 3 8 31 851 25 238 59 152 80 53 51 8 nd 5 31 766 25 259 56 138 79 57 12 7 nd 2 30 821 34 215 29 123 183 51 1 5 nd 2 17 798 143 138 114 6 143 53 nd 2 nd 4 nd 4 7 95 28 716 21 138 41 11 37 32 356 157 40 115 82 27 106 34 nd 5 nd 4 3 115 52 120 80 21 97 37 nd 2 nd 2 3 85 27 130 51 20 98 48 nd 3 nd 5 nd 66 24 207 48 121 127 50 5 5 nd 6 26 844 Major elements on pre-ignited fused glass beads, results in wt% oxide. Trace elements on pressed powders, results in ppm. D R-2. W hole rock m ajor and trace elem ent analyses by x-ray fluorescence. PBF Plutonic Suite: "Pinked" Core# Box SAMPLE# SA 56 1078 SA 57 1086 SA 58 1089 SA 61 1107 SA 62 1118 Rock Type pink granite pink granite pink granite pink granite pink granite C2 none 560 Springfield Granite SiO2 TiO2 Al2O3 Fe2O3 MnO MgO CaO Na2O K2O P2O5 SUM %LOI 74.66 0.24 14.22 1.86 0.04 0.50 1.13 3.16 4.52 0.06 100.38 1.20% 71.95 0.26 15.58 1.89 0.03 0.62 1.21 3.75 5.08 0.07 100.44 0.93% 73.69 0.21 13.56 1.37 0.04 0.48 1.05 3.36 4.54 0.05 98.36 0.60% 74.15 0.25 14.20 1.89 0.05 0.75 1.81 3.40 4.14 0.06 100.70 1.17% 72.72 0.24 13.72 1.74 0.04 0.65 1.38 3.20 4.69 0.06 98.43 0.79% 76.76 0.13 13.86 1.28 0.03 0.20 1.27 4.51 2.50 0.02 100.56 0.60% Nb Zr Y Sr Rb Zn Cu Ni Cr Sc V Ba 13 131 18 172 194 11 2 9 24 2 17 719 16 143 21 183 215 12 8 5 3 5 22 840 14 124 12 186 198 12 1 4 nd 3 13 800 13 125 24 223 153 20 nd 5 nd 2 17 892 10 134 12 261 146 15 2 8 3 3 23 1843 14 81 13 100 88 186 0 16 nd 2 3 473 Major elements on pre-ignited fused glass beads, results in wt% oxide. Trace elements on pressed powders, results in ppm. D R -3.W hole rock R E E ,Y ,P b,T h,and U analyses by IC P -M S. Core Box Sample# Crackerneck Volcanic Complex C1 C3 MMP4 none none none 574 540 817 P30 none 781 Deep Rock Metavolcanic Complex DRB3 DRB3 DRB3 6 21 41 988 1093 1220 Felsic Felsic Felsic MV Felsic Tuff Felsic Tuff Lapilli Tuff Lapilli Tuff Wall Mafic MV Wall Inter MV Wall DRB3 59 1346 DRB4 66 1397 DRB4 76 1450.7 DRB4 101 1613 Mafic MV Wall Inter MV Wall Felsic Gneiss Inter MV Wall La ppm Ce Pr Nd Sm Eu Gd Tb Dy Ho Er Tm Yb Lu Y Pb Th U 28.1 66.5 8.1 29.4 7.2 1.44 4.7 0.84 4.3 0.82 1.9 0.30 1.3 0.20 17.5 11.2 6.7 1.6 13.6 34.4 4.7 18.3 4.2 0.95 3.4 0.57 3.1 0.57 1.5 0.25 1.2 0.17 16.7 8.1 1.1 1.1 16.5 46.7 6.3 24.6 5.9 0.87 7.4 1.50 7.5 1.54 4.7 0.65 3.7 0.50 64.0 11.1 0.8 0.8 11.6 31.3 3.8 16.2 3.6 0.59 5.7 1.12 6.0 1.40 4.5 0.67 3.2 0.57 68.3 2.8 0.6 0.6 21.6 48.6 5.8 21.0 5.9 1.50 4.6 0.80 4.6 1.11 2.9 0.46 2.7 0.39 29.5 10.0 8.2 2.0 11.9 29.1 3.9 15.0 3.7 0.79 4.1 0.71 3.8 0.88 2.4 0.41 2.1 0.36 22.5 7.1 3.0 0.8 19.2 42.5 4.8 18.2 3.9 0.78 3.9 0.69 3.9 0.87 2.8 0.42 2.2 0.32 26.2 8.4 8.1 1.8 19.8 50.7 7.2 29.2 6.9 1.81 5.4 0.84 4.2 0.76 2.2 0.32 1.6 0.23 25.5 7.1 0.8 0.8 25.5 62.3 8.6 31.9 7.8 1.83 6.9 1.19 6.7 1.20 3.8 0.55 2.7 0.39 41.6 14.7 1.6 1.6 30.3 70.4 8.2 30.0 7.4 0.34 6.8 1.34 7.2 1.62 4.2 0.66 3.4 0.53 41.3 13.8 15.2 3.2 29.8 68.2 8.5 28.4 6.1 1.19 6.2 1.08 5.4 1.02 2.8 0.47 2.3 0.35 43.6 11.8 1.7 1.7 La /chondrite Ce Pr Nd Sm Eu Gd Tb Dy Ho Er Tm Yb Lu Y 82.5 73.1 66.6 50.6 36.8 19.6 18.6 17.7 15.1 10.5 9.9 9.3 6.6 5.8 8.3 39.9 37.9 39.2 31.6 21.4 13.0 13.4 12.0 10.9 7.3 7.8 7.7 6.2 5.0 8.0 48.4 51.3 52.0 42.3 30.2 11.9 29.0 31.5 26.1 19.7 23.9 20.3 18.5 14.7 30.5 34.0 34.4 31.3 27.9 18.4 8.1 22.5 23.7 20.9 18.0 22.9 21.1 15.8 16.8 32.5 63.6 53.4 47.8 36.1 30.3 20.6 18.2 16.8 16.2 14.2 14.8 14.5 13.3 11.6 14.0 35.0 31.9 32.1 25.9 18.9 10.8 16.0 14.9 13.2 11.3 12.5 12.8 10.7 10.5 10.7 56.4 46.7 39.6 31.4 20.2 10.7 15.5 14.4 13.5 11.2 14.5 13.2 10.8 9.4 12.5 58.3 55.8 59.9 50.4 35.5 24.8 21.3 17.7 14.8 9.7 11.2 10.0 8.0 6.9 12.1 75.1 68.4 71.2 55.0 39.8 25.0 27.0 25.0 23.4 15.4 19.3 17.2 13.5 11.4 19.8 89.2 77.4 67.8 51.6 38.2 4.7 26.6 28.1 25.3 20.8 21.4 20.6 17.2 15.7 19.6 87.7 75.0 69.9 49.0 31.1 16.3 24.2 22.8 19.1 13.1 14.6 14.6 11.4 10.2 20.8 NeoProterozoic Arc Terranes Beneath the Savannah River Site, S.C. D R -3.W hole rock R E E ,Y ,P b,T h,and U analyses by IC P -M S. Core Box Sample# DRB4 123 1758.4 DRB4 131 1831 DRB4 145 1912 Mafic MV Felsite MV Mafic MV Wall Wall Wall DRB5 15M 1324 DRB5 73 1802 DRB6 4M 1125 Mafic MV Felsite MV Mafic MV Wall Wall Wall DRB6 103 1810 DRB2 12 1053.5 DRB2 108 1687 DRB1 18 1005 DRB1 25 1047 Mafic MV Wall Plg Porph Dike Mafic Dike quartz diorite diorite La ppm Ce Pr Nd Sm Eu Gd Tb Dy Ho Er Tm Yb Lu Y Pb Th U 12.7 30.8 4.2 17.1 4.4 1.05 4.5 0.82 4.6 0.96 2.5 0.34 1.8 0.24 25.9 6.7 2.1 0.4 26.4 59.9 7.7 26.9 5.8 0.96 6.2 1.15 5.0 1.07 3.5 0.48 2.3 0.31 46.2 13.3 1.6 1.6 11.7 29.6 3.6 12.2 3.2 0.62 3.1 0.62 2.5 0.51 1.9 0.31 1.3 0.25 27.9 7.1 0.6 0.6 7.8 19.1 2.4 10.2 2.4 0.59 2.8 0.55 2.7 0.61 1.5 0.23 1.2 0.20 14.4 6.7 1.2 0.3 12.3 28.7 3.5 13.1 3.2 0.47 3.2 0.68 3.8 0.98 2.9 0.48 2.4 0.36 23.9 8.5 4.7 1.2 14.0 33.3 4.4 17.5 4.5 0.97 4.6 0.91 4.8 1.12 2.8 0.46 2.4 0.33 27.4 11.1 3.4 0.9 19.1 44.9 5.7 22.9 5.9 1.43 5.3 0.93 4.9 0.94 2.6 0.33 1.9 0.29 26.6 17.1 2.8 0.9 15.0 36.7 5.1 19.3 4.9 1.10 4.7 0.82 4.4 0.79 2.6 0.38 1.9 0.32 30.9 5.3 1.0 1.0 14.7 36.4 4.8 18.3 4.5 0.91 4.9 0.93 5.0 1.20 3.3 0.59 2.9 0.48 27.5 5.3 3.5 1.1 10.4 25.7 3.2 13.1 2.9 0.60 3.3 0.59 3.2 0.64 2.1 0.37 1.8 0.28 26.5 4.5 0.6 0.6 3.6 9.6 1.3 5.5 1.4 0.39 2.0 0.38 2.1 0.45 1.4 0.24 1.3 0.20 19.6 3.9 0.4 0.4 La /chondrite Ce Pr Nd Sm Eu Gd Tb Dy Ho Er Tm Yb Lu Y 37.3 33.9 34.8 29.5 22.5 14.4 17.5 17.2 16.2 12.4 12.9 10.7 9.2 7.0 12.3 77.8 65.8 63.6 46.4 29.6 13.1 24.1 24.3 17.7 13.7 18.0 15.0 11.5 9.0 22.0 34.4 32.5 30.2 21.1 16.5 8.5 12.2 13.1 8.8 6.5 9.6 9.7 6.4 7.3 13.3 22.9 21.0 20.0 17.7 12.4 8.1 10.8 11.6 9.3 7.8 7.8 7.2 6.1 5.8 6.8 36.2 31.5 29.2 22.5 16.5 6.4 12.6 14.4 13.4 12.5 14.6 14.9 11.9 10.7 11.4 41.1 36.6 36.0 30.2 22.9 13.3 17.9 19.2 16.8 14.3 14.3 14.3 12.2 9.8 13.1 56.1 49.4 47.3 39.5 30.5 19.6 20.7 19.5 17.1 12.0 13.4 10.3 9.4 8.4 12.7 44.2 40.3 42.0 33.3 24.9 15.1 18.6 17.2 15.4 10.1 13.2 11.7 9.4 9.4 14.7 43.3 40.1 39.5 31.5 22.9 12.5 19.2 19.7 17.6 15.3 16.7 18.3 14.7 14.1 13.1 30.6 28.3 26.6 22.6 14.8 8.2 13.0 12.4 11.3 8.2 10.8 11.4 8.9 8.2 12.6 10.6 10.6 10.8 9.5 7.2 5.3 7.9 8.0 7.4 5.7 7.2 7.5 6.5 5.9 9.4 NeoProterozoic Arc Terranes Beneath the Savannah River Site, S.C. D R -3.W hole rock R E E ,Y ,P b,T h,and U analyses by IC P -M S. Core Box Sample# DRB1 41 1151 DRB1 60 1276 PBF7 171 3568 PBF7 103 2550 PBF7 107 2602 PBF7 108 2629 PBF7 139 3086 C5 none 1084 C5 none 1080 quartz diorite tonalite pink granite granodiorite granodiorite granodiorite granodiorite pink granite felsic dike La ppm Ce Pr Nd Sm Eu Gd Tb Dy Ho Er Tm Yb Lu Y Pb Th U 7.9 21.7 3.3 14.1 4.1 0.92 4.1 0.72 4.3 0.84 2.5 0.39 2.0 0.31 27.8 16.6 0.9 0.9 6.5 15.5 1.9 7.5 1.8 0.43 2.2 0.42 2.4 0.53 1.8 0.25 1.6 0.27 14.5 3.4 1.8 0.4 17.0 48.2 7.2 26.8 8.3 0.34 9.9 2.05 11.3 2.19 6.9 1.02 5.4 0.80 82.5 14.1 1.4 1.4 25.8 63.7 8.6 32.6 7.6 1.77 7.2 1.25 6.9 1.34 4.0 0.57 3.1 0.48 42.1 16.6 1.4 1.4 29.8 69.4 8.6 34.2 9.0 2.54 7.9 1.48 8.0 1.80 4.6 0.68 3.6 0.59 46.5 12.7 4.4 1.4 22.2 51.1 5.8 22.7 5.4 1.30 5.5 1.19 6.4 1.52 4.2 0.66 3.4 0.58 40.7 13.0 6.9 1.5 11.3 28.3 3.9 15.1 4.3 1.05 3.6 0.62 3.4 0.69 2.2 0.36 1.7 0.31 24.4 14.8 1.0 1.0 11.7 26.2 3.2 13.5 10.3 4.69 3.7 0.76 4.1 0.96 2.5 0.39 2.0 0.30 24.7 19.8 4.5 1.6 32.4 79.8 10.3 38.2 10.3 2.08 8.7 1.50 8.1 1.59 5.1 0.72 3.9 0.61 58.8 18.9 2.1 2.1 La /chondrite Ce Pr Nd Sm Eu Gd Tb Dy Ho Er Tm Yb Lu Y 23.4 23.8 26.9 24.2 20.9 12.5 16.0 15.2 15.0 10.7 12.9 12.1 10.2 9.0 13.2 19.2 17.1 16.0 12.9 9.0 5.9 8.7 8.9 8.5 6.7 9.5 7.8 7.8 7.9 6.9 49.9 52.9 59.2 46.2 42.5 4.6 38.9 43.1 39.8 28.1 35.2 32.0 27.1 23.5 39.3 75.8 70.0 70.8 56.2 39.1 24.2 28.2 26.4 24.4 17.2 20.3 17.9 15.7 14.1 20.0 87.7 76.3 70.9 59.0 46.2 34.7 31.2 31.2 28.2 23.1 23.8 21.2 18.0 17.5 22.1 65.3 56.1 48.3 39.2 27.8 17.7 21.7 25.1 22.4 19.4 21.5 20.6 16.8 17.2 19.4 33.4 31.1 32.1 26.1 22.2 14.3 14.0 13.0 11.9 8.9 11.3 11.1 8.6 9.2 11.6 34.4 28.7 26.7 23.3 52.7 64.0 14.4 16.0 14.4 12.3 12.9 12.2 10.0 8.9 11.8 95.3 87.6 85.1 65.9 52.8 28.5 34.0 31.7 28.4 20.4 26.0 22.4 19.7 18.0 28.0 NeoProterozoic Arc Terranes Beneath the Savannah River Site, S.C. DR-4. Representative Plagioclase analyses. Sample # P6R P6R P6R P6R P6R P6R P6R Unit Crackerneck Crackerneck Crackerneck Crackerneck Crackerneck Crackerneck Crackerneck SiO2 69.32 69.13 68.38 67.93 67.83 68.35 66.93 TiO2 0.00 0.01 0.01 0.01 0.02 0.02 0.02 Al2O3 20.39 20.21 19.98 19.86 19.90 19.99 20.18 MgO 0.00 0.00 0.01 0.01 0.00 0.01 0.00 CaO 0.19 0.19 0.20 0.20 0.22 0.27 0.85 FeO 0.03 0.06 0.03 0.32 0.00 0.03 0.08 Na2O 10.83 10.57 10.71 10.47 10.48 10.33 9.88 K2O 0.07 0.06 0.07 0.08 0.09 0.07 0.11 Total 100.83 100.23 99.38 98.88 98.54 99.05 98.05 Mol% An 1.0 1.0 1.0 1.1 1.1 1.4 4.5 DRB-2-11 Metavolc 61.59 0.02 25.11 0.01 5.81 0.16 7.44 0.17 100.30 29.8 DRB-2-11 Metavolc 60.62 0.01 25.56 0.00 6.43 0.06 7.31 0.08 100.07 32.5 DRB-2-11 Metavolc 60.52 0.01 25.52 0.00 6.44 0.05 7.26 0.07 99.86 32.7 DRB-2-11 Metavolc 60.56 0.01 25.92 0.01 6.65 0.03 7.23 0.04 100.46 33.5 DRB-2-11 Metavolc 59.70 0.01 25.50 0.00 6.72 0.02 7.09 0.08 99.13 34.1 Sample # Unit SiO2 TiO2 Al2O3 MgO CaO FeO Na2O K2O Total Mol% An DRB-2-11 Metavolc 60.03 0.03 25.73 0.00 6.79 0.02 7.15 0.04 99.77 34.2 DRB-2-11 Metavolc 58.89 0.00 25.58 0.00 6.93 0.04 6.86 0.07 98.37 35.6 DRB-2-11 Metavolc 59.16 0.02 25.92 0.00 7.18 0.03 6.78 0.05 99.13 36.7 DRB-2-73 Metavolc 61.32 0.03 24.64 0.02 5.72 0.05 7.36 0.18 99.31 29.6 DRB-2-73 Metavolc 61.80 0.02 25.01 0.01 5.75 0.05 7.50 0.13 100.26 29.4 DRB-2-73 Metavolc 61.34 0.02 25.47 0.03 6.08 0.09 7.70 0.09 100.80 30.1 DRB-2-73 Metavolc 61.32 0.03 24.64 0.02 5.72 0.05 7.36 0.18 99.31 29.6 DRB-2-73 Metavolc 61.80 0.02 25.01 0.01 5.75 0.05 7.50 0.13 100.26 29.4 DRB-2-73 Metavolc 61.34 0.02 25.47 0.03 6.08 0.09 7.70 0.09 100.80 30.1 DRB-2-73 Metavolc 58.18 0.00 25.41 0.00 7.11 0.08 6.51 0.16 97.45 37.2 DRB-2-73 Metavolc 58.21 0.01 26.60 0.01 8.00 0.15 6.14 0.13 99.25 41.5 DRB-2-73 Metavolc 58.13 0.00 26.90 0.02 8.14 0.03 6.20 0.07 99.50 41.8 Sample # Unit SiO2 TiO2 Al2O3 MgO CaO FeO Na2O K2O Total Mol% An DRB-2-73 Metavolc 57.42 0.01 26.65 0.01 8.26 0.10 6.02 0.15 98.61 42.6 DRB-2-73 Metavolc 57.45 0.02 26.84 0.02 8.37 0.14 5.98 0.14 98.96 43.1 DRB-2-98 Metavolc 59.25 0.03 26.51 0.00 7.36 0.10 6.78 0.09 100.12 37.2 DRB-2-98 Metavolc 57.93 0.00 25.97 0.00 7.40 0.03 6.61 0.08 98.02 38.0 DRB-2-98 Metavolc 57.98 0.01 26.32 0.00 7.56 0.09 6.56 0.05 98.57 38.7 DRB-2-98 Metavolc 57.42 0.06 26.45 0.00 7.90 0.15 6.31 0.08 98.37 40.6 DRB-2-98 Metavolc 56.97 0.02 26.45 0.00 8.00 0.04 6.16 0.38 98.03 40.7 DRB-2-98 Metavolc 57.62 0.00 26.84 0.00 8.14 0.02 6.32 0.07 99.00 41.3 DRB-2-98 Metavolc 59.08 0.02 25.59 0.00 6.78 0.06 6.97 0.07 98.57 34.7 DRB-2-98 Metavolc 58.21 0.00 25.89 0.00 7.21 0.14 6.67 0.06 98.17 37.2 DRB-3-41 Metavolc 67.54 0.00 20.70 0.00 0.96 0.22 10.26 0.07 99.76 4.9 DRB-3-41 Metavolc 66.64 0.01 20.58 0.00 1.07 0.02 10.16 0.04 98.51 5.5 Neoproterozoic Volcanic Arc Terranes, Savannah River Site, SC. DR-4. Representative Plagioclase analyses. Sample # Unit SiO2 TiO2 Al2O3 MgO CaO FeO Na2O K2O Total Mol% An DRB-3-41 Metavolc 67.64 0.01 21.05 0.00 1.25 0.29 10.06 0.05 100.35 6.4 DRB-3-41 Metavolc 64.92 0.01 23.56 0.00 3.78 0.03 8.52 0.10 100.93 19.5 DRB-3-41 Metavolc 63.70 0.01 23.39 0.00 4.00 0.23 8.50 0.09 99.93 20.5 DRB-3-41 Metavolc 67.01 0.00 20.20 0.00 0.71 0.02 10.26 0.06 98.25 3.6 DRB-3-41 Metavolc 67.15 0.04 20.78 0.18 0.73 0.30 9.78 0.41 99.37 3.9 DRB-3-41 Metavolc 67.06 0.00 20.19 0.00 0.74 0.02 10.48 0.07 98.55 3.7 DRB-3-41 PBF-7-177 PBF-7-177 PBF-7-177 PBF-7-177 PBF-7-177 Metavolc Amphibolite Amphibolite Amphibolite Amphibolite Amphibolite 68.02 59.30 60.12 58.98 59.78 59.63 0.02 0.01 0.01 0.02 0.01 0.00 20.77 26.02 26.29 26.37 26.64 26.88 0.01 0.00 0.00 0.00 0.00 0.00 0.92 6.98 7.13 7.23 7.42 7.59 0.11 0.08 0.09 0.18 0.03 0.08 10.47 6.89 6.99 6.87 6.89 6.76 0.08 0.08 0.07 0.06 0.06 0.07 100.38 99.36 100.69 99.70 100.84 101.01 4.6 35.6 35.8 36.6 37.1 38.1 Sample # PBF-7-177 PBF-7-177 PBF-7-177 PBF-7-177 SA SA SA SA SA SA SA SA Unit Amphibolite Amphibolite Amphibolite Amphibolite Amphibolite Amphibolite Amphibolite Amphibolite Amphibolite Amphibolite Amphibolite Amphibolite SiO2 59.49 58.08 58.14 58.39 59.84 57.57 58.42 58.99 58.72 58.45 58.12 58.20 TiO2 0.00 0.04 0.01 0.00 0.01 0.02 0.01 0.02 0.01 0.02 0.00 0.04 Al2O3 26.89 26.64 26.94 27.35 25.87 27.29 26.81 27.13 26.87 27.04 26.99 27.25 MgO 0.00 0.00 0.00 0.00 0.00 0.03 0.01 0.00 0.01 0.00 0.00 0.01 CaO 7.60 7.94 8.11 8.25 6.86 8.66 7.89 7.94 7.95 8.06 8.14 8.27 FeO 0.08 0.13 0.12 0.20 0.07 0.16 0.08 0.07 0.02 0.07 0.03 0.23 Na2O 6.79 6.48 6.48 6.35 7.01 5.76 6.36 6.54 6.54 6.39 6.25 6.47 K2O 0.06 0.07 0.07 0.07 0.08 0.07 0.08 0.06 0.07 0.06 0.08 0.06 Total 100.91 99.39 99.88 100.60 99.73 99.56 99.67 100.76 100.19 100.09 99.60 100.53 Mol% An 38.0 40.1 40.6 41.5 34.8 45.1 40.4 39.9 39.9 40.8 41.6 41.2 Sample# Phase Rock SiO2 TiO2 Al2O3 MgO CaO FeO Na2O K2O Total An DRB-1-153 DRB-1-153 DRB-1-153 DRB-1-153 DRB-1-153 DRB-1-153 DRB-1-153 DRB-1-153 DRB-1-153 DRB-1-153 DRB-1-60 DRB-1-60 Plagioclase Plagioclase Plagioclase Plagioclase Plagioclase Plagioclase Plagioclase Plagioclase Plagioclase Plagioclase Plagioclase Plagioclase Metadiorite Metadiorite Metadiorite Metadiorite Metadiorite Metadiorite Metadiorite Metadiorite Metadiorite Metadiorite Metadiorite Metadiorite 66.125 65.898 65.935 66.251 65.782 65.728 64.960 62.564 65.059 62.810 62.173 61.765 0.009 0.016 0.013 0.000 0.005 0.007 0.002 0.024 0.002 0.005 0.000 0.002 21.323 21.409 21.674 22.221 22.236 21.992 22.604 23.997 21.177 23.597 24.718 24.465 0.006 0.001 0.000 0.000 0.000 0.000 0.001 0.002 0.002 0.003 0.001 0.009 1.691 1.843 2.185 2.409 2.446 2.547 3.165 3.502 3.527 4.289 5.504 5.527 0.133 0.121 0.033 0.028 0.085 0.129 0.035 0.036 1.325 0.179 0.105 0.019 9.976 9.872 9.463 9.626 9.549 9.436 9.142 8.284 9.246 8.624 7.145 7.730 0.062 0.074 0.070 0.055 0.055 0.068 0.057 0.747 0.056 0.092 0.063 0.069 99.327 99.234 99.373 100.590 100.158 99.907 99.966 99.160 100.395 99.599 99.719 99.591 15.72 17.03 20.25 21.60 22.00 22.89 27.59 30.61 29.57 35.31 45.84 44.00 Neoproterozoic Volcanic Arc Terranes, Savannah River Site, SC. DR-4. Representative Plagioclase analyses. Sample# Phase DRB-1-41 Plagioclase DRB-1-41 Plagioclase DRB-1-41 Plagioclase DRB-1-41 Plagioclase DRB-1-41 Plagioclase DRB-1-41 Plagioclase DRB-1-41 Plagioclase DRB-1-41 Plagioclase DRB-1-41 Plagioclase DRB-1-41 Plagioclase Rock Metadiorite Metadiorite Metadiorite Metadiorite Metadiorite Metadiorite Metadiorite Metadiorite Metadiorite Metadiorite 61.651 0.004 24.590 0.000 5.460 0.036 7.929 0.065 99.749 43.08 66.679 0.022 21.325 0.004 1.733 0.035 9.582 0.076 99.456 16.59 64.688 0.013 22.908 0.000 3.388 0.099 8.872 0.055 100.023 29.59 64.959 0.009 23.038 0.000 3.569 0.099 8.686 0.068 100.440 31.12 64.187 0.011 23.392 0.000 3.914 0.290 8.647 0.062 100.522 33.24 62.778 0.001 24.217 0.001 4.773 0.092 8.155 0.075 100.092 39.14 62.858 0.006 24.112 0.000 4.858 0.105 8.235 0.067 100.241 39.34 62.955 0.010 24.180 0.000 5.055 0.176 8.055 0.073 100.504 40.81 62.575 0.003 24.356 0.003 5.232 0.155 8.012 0.074 100.414 41.77 62.197 0.004 24.514 0.000 5.261 0.036 7.997 0.081 100.090 41.94 SiO2 TiO2 Al2O3 MgO CaO FeO Na2O K2O Total An Sample# Phase DRB-1-59 Plagioclase DRB-1-59 Plagioclase DRB-1-59 Plagioclase DRB-1-59 Plagioclase DRB-1-59 Plagioclase DRB-1-59 Plagioclase DRB-1-60 Plagioclase DRB-1-60 Plagioclase DRB-1-60 Plagioclase DRB-1-60 Plagioclase Rock Metadiorite Metadiorite Metadiorite Metadiorite Metadiorite Metadiorite Metadiorite Metadiorite Metadiorite Metadiorite 63.601 0.002 23.320 0.000 3.956 0.044 8.686 0.088 99.697 33.34 62.770 0.011 23.863 0.001 4.515 0.054 8.447 0.067 99.736 37.02 62.415 0.012 23.875 0.000 4.649 0.310 8.287 0.075 99.623 38.13 62.844 0.007 24.064 0.000 4.725 0.039 8.198 0.069 99.946 38.78 61.986 0.000 24.015 0.000 4.797 0.038 8.294 0.068 99.200 38.87 61.959 0.003 24.578 0.000 5.253 0.060 7.922 0.076 99.851 42.14 62.150 0.005 24.470 0.000 5.289 0.027 7.874 0.081 99.896 42.44 61.547 0.006 24.410 0.000 5.303 0.075 7.840 0.069 99.250 42.64 62.008 0.010 24.362 0.000 5.341 0.039 7.677 0.051 99.488 43.36 61.915 0.003 24.431 0.000 5.423 0.030 7.667 0.068 99.537 43.73 SiO2 TiO2 Al2O3 MgO CaO FeO Na2O K2O Total An Neoproterozoic Volcanic Arc Terranes, Savannah River Site, SC. PBF-7-108 PBF-7-159 Plagioclase Plagioclase Metagrano- Metagranodiorite diorite 59.678 65.648 0.003 0.014 26.159 22.596 0.000 0.006 7.323 2.964 0.213 0.035 6.851 9.188 0.125 0.109 100.364 100.560 53.86 26.13 PBF-7-159 PBF-7-159 Plagioclase Plagioclase Metagrano- Metagranodiorite diorite 63.981 64.560 0.000 0.002 22.764 23.482 0.000 0.000 3.542 3.932 0.022 0.046 9.043 8.615 0.080 0.103 99.432 100.740 30.09 33.36 DR-4. Representative Plagioclase analyses. Sample# Phase Rock SiO2 TiO2 Al2O3 MgO CaO FeO Na2O K2O Total An Sample# Phase Rock SiO2 TiO2 Al2O3 MgO CaO FeO Na2O K2O Total An PBF-7-108 PBF-7-108 PBF-7-108 PBF-7-108 PBF-7-108 PBF-7-108 PBF-7-108 PBF-7-108 PBF-7-108 PBF-7-108 PBF-7-108 PBF-7-108 Plagioclase Plagioclase Plagioclase Plagioclase Plagioclase Plagioclase Plagioclase Plagioclase Plagioclase Plagioclase Plagioclase Plagioclase Metagrano- Metagrano- Metagrano- Metagrano- Metagrano- Metagrano- Metagrano- Metagrano- Metagrano- Metagrano- Metagrano- Metagranodiorite diorite diorite diorite diorite diorite diorite diorite diorite diorite diorite diorite 59.921 60.720 60.386 60.290 59.946 60.192 60.226 61.994 61.176 60.872 60.780 60.195 0.005 0.000 0.021 0.014 0.016 0.022 0.016 0.000 0.000 0.000 0.000 0.014 25.833 25.543 25.525 25.720 25.959 26.031 25.653 24.763 25.433 25.735 25.494 25.736 0.000 0.000 0.003 0.000 0.000 0.000 0.000 0.013 0.008 0.008 0.000 0.004 6.775 6.825 6.889 6.957 6.974 7.010 7.011 1.318 6.305 6.606 6.733 7.032 0.037 0.056 0.050 0.093 0.065 0.038 0.046 0.165 0.060 0.056 0.026 0.162 7.096 7.023 7.044 7.072 6.951 7.045 6.965 5.531 7.217 7.113 7.104 7.098 0.036 0.230 0.210 0.083 0.073 0.081 0.194 5.741 0.183 0.315 0.087 0.066 99.711 100.434 100.144 100.252 99.992 100.422 100.111 99.546 100.382 100.719 100.224 100.310 51.26 51.25 51.46 51.90 52.41 52.19 52.21 13.53 48.71 49.94 50.96 52.11 PBF-7-108 PBF-7-169 PBF-7-159 PBF-7-169 PBF-7-169 PBF-7-169 PBF-7-169 PBF-7-169 PBF-7-169 Plagioclase Plagioclase Plagioclase Plagioclase Plagioclase Plagioclase Plagioclase Plagioclase Plagioclase MetagranoMetagranoPinked Pinked Pinked Pinked Pinked Pinked Pinked diorite diorite 59.656 68.634 64.051 69.527 69.351 69.721 69.190 69.867 69.801 0.000 0.003 0.000 0.004 0.006 0.013 0.007 0.009 0.000 26.104 20.228 23.596 19.815 19.889 19.730 20.136 20.062 19.972 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.002 7.082 0.537 4.146 0.434 0.438 0.455 0.468 0.484 0.489 0.108 0.021 0.056 0.040 0.061 0.079 0.102 0.064 0.122 6.874 9.686 8.484 9.739 9.784 9.868 10.026 9.503 9.627 0.111 0.102 0.089 0.098 0.094 0.076 0.102 0.098 0.112 99.935 99.211 100.429 99.678 99.657 100.046 100.043 100.200 100.136 52.98 5.74 34.91 4.66 4.69 4.83 4.88 5.30 5.28 Neoproterozoic Volcanic Arc Terranes, Savannah River Site, SC. DR-5. Representative amphibole analyses. Sample # DRB-2-11 DRB-2-11 metamorphic amphibole SiO2 TiO2 Al2O3 Cr2O3 MgO CaO MnO FeO Na2O K2O Total mg# 41.252 0.396 15.769 0.000 7.957 10.956 0.467 18.562 1.638 0.514 97.511 43.319 Sample # DRB-2-29 igneous amphibole SiO2 TiO2 Al2O3 Cr2O3 MgO CaO MnO FeO Na2O K2O Total mg# 45.544 0.399 10.535 0.002 12.089 11.690 0.331 14.697 1.018 0.390 96.695 59.457 DRB-2-11 DRB-2-29 DRB-2-29 DRB-2-29 DRB-2-29 DRB-2-29 DRB-2-29 DRB-2-29 DRB-2-29 metamorphic metamorphic metamorphic amphibole amphibole amphibole igneous amphibole igneous amphibole igneous amphibole igneous amphibole igneous amphibole igneous amphibole igneous amphibole igneous amphibole 41.542 0.421 15.826 0.000 8.002 11.378 0.342 18.306 1.425 0.536 97.778 43.799 DRB-2-73 DRB-2-11 41.791 0.490 15.788 0.009 8.301 10.982 0.449 18.786 1.496 0.648 98.740 44.065 DRB-2-73 41.224 0.489 16.256 0.000 8.078 10.832 0.424 18.425 1.522 0.614 97.864 43.873 DRB-2-73 45.590 0.563 10.382 0.051 12.240 11.777 0.313 13.953 0.968 0.357 96.194 60.998 DRB-2-73 42.252 0.479 14.400 0.000 9.751 11.688 0.325 15.889 1.325 0.637 96.746 52.248 DRB-2-73 43.971 0.541 12.345 0.000 11.238 11.657 0.341 14.868 1.245 0.444 96.650 57.403 DRB-2-73 43.594 0.542 13.211 0.003 10.463 11.623 0.318 15.659 1.320 0.493 97.226 54.365 PBF-7-177 43.581 0.499 14.218 0.000 10.361 11.651 0.323 16.239 1.320 0.590 98.782 53.217 PBF-7-177 42.663 0.544 13.821 0.011 10.009 11.618 0.341 15.895 1.199 0.652 96.753 52.890 PBF-7-177 44.546 0.412 12.199 0.013 11.076 11.722 0.313 15.392 1.146 0.323 97.142 56.197 PBF-7-177 44.173 0.564 12.506 0.000 10.971 11.754 0.350 15.293 1.231 0.517 97.359 56.121 PBF-7-177 metamorphic metamorphic metamorphic metamorphic metamorphic metamorphic metamorphic metamorphic metamorphic metamorphic metamorphic amphibole amphibole amphibole amphibole amphibole amphibole amphibole amphibole amphibole amphibole amphibole 41.647 0.282 16.820 0.000 8.677 10.280 0.385 17.219 1.627 0.299 97.236 47.325 41.138 0.301 16.490 0.000 8.383 10.957 0.499 17.208 1.542 0.340 96.858 46.482 41.075 0.305 16.661 0.010 8.513 10.582 0.554 17.118 1.600 0.366 96.784 46.996 41.190 0.356 16.573 0.016 8.580 11.125 0.534 16.878 1.498 0.362 97.112 47.543 41.301 0.304 16.792 0.001 8.534 10.731 0.558 17.036 1.554 0.324 97.135 47.177 Neoproterozoic Volcanic Arc Terranes, Savannah River Site, SC. 41.266 0.318 16.750 0.007 8.598 10.394 0.559 16.934 1.580 0.324 96.730 47.513 41.324 0.768 15.631 0.015 7.896 11.083 0.239 19.358 1.336 0.829 98.479 42.104 41.075 0.978 15.437 0.015 7.325 11.160 0.236 19.664 1.261 0.879 98.030 39.909 40.928 0.757 15.266 0.000 7.517 11.056 0.287 19.698 1.268 0.801 97.578 40.489 41.288 0.901 15.265 0.018 7.462 11.033 0.284 19.570 1.262 0.931 98.014 40.469 40.958 1.125 15.608 0.000 7.663 11.120 0.209 19.031 1.274 1.029 98.017 41.789 DR-5. Representative amphibole analyses. Sample# DRB-1-153 Metamorphic rim SiO2 TiO2 Al2O3 Cr2O3 MgO CaO MnO FeO Na2O K2O Total Sample# 46.364 2.023 8.711 0.000 12.598 11.277 0.337 15.100 1.220 0.194 97.824 DRB-1-153 DRB-1-153 DRB-1-153 DRB-1-153 DRB-1-153 DRB-1-153 DRB-1-153 DRB-1-153 DRB-1-153 DRB-1-41 Metamorphic Metamorphic Metamorphic Metamorphic Metamorphic Relict Igneous rim rim rim rim rim core 48.353 1.280 7.229 0.000 13.689 11.218 0.373 14.309 1.109 0.176 97.736 47.371 1.295 7.423 0.000 13.013 11.254 0.389 14.993 1.087 0.192 97.017 48.199 1.482 7.157 0.000 14.344 11.083 0.390 13.288 1.105 0.159 97.207 46.325 1.772 9.205 0.006 13.390 11.217 0.324 13.582 1.333 0.193 97.347 DRB-1-153 DRB-1-153 DRB-1-153 DRB-1-153 47.687 1.171 7.539 0.005 12.723 11.103 0.380 15.127 1.127 0.171 97.033 DRB-1-59 43.397 0.414 12.933 0.002 10.098 10.885 0.356 17.291 1.693 0.363 97.432 DRB-1-59 Relict actinolite 53.056 0.098 3.688 0.000 16.411 11.748 0.407 11.762 0.572 0.037 97.779 DRB-1-59 DRB-1-41 DRB-1-41 Relict Igneous Relict Igneous Metamorphic Metamorphic core core rim rim 43.646 0.392 12.282 0.000 10.242 11.158 0.355 17.437 1.633 0.372 97.517 DRB-1-59 48.590 0.972 7.028 0.003 14.181 10.952 0.366 13.640 1.182 0.154 97.068 DRB-1-60 45.861 1.329 10.111 0.000 11.853 9.571 0.303 16.556 1.342 0.177 97.103 DRB-1-41 45.984 2.820 8.759 0.000 13.988 11.112 0.335 13.320 1.199 0.238 97.755 DRB-1-60 Relict Igneous Relict Igneous Relict Igneous Relict Igneous Relict Igneous Relict Igneous Relict Igneous Relict Igneous Relict Igneous Relict Igneous Metamorphic Metamorphic core core core core core core core core core core rim rim SiO2 TiO2 Al2O3 Cr2O3 MgO CaO MnO FeO Na2O K2O Total Sample# 45.329 0.302 10.042 0.000 10.881 11.480 0.290 17.240 1.288 0.281 97.133 DRB-1-59 43.373 0.393 13.484 0.000 10.035 11.026 0.335 16.863 1.711 0.315 97.535 DRB-1-59 43.743 0.317 12.326 0.012 10.306 10.963 0.352 17.302 1.651 0.373 97.345 DRB-1-59 43.301 0.325 12.481 0.002 10.072 10.952 0.335 17.487 1.614 0.438 97.007 DRB-1-59 46.337 0.215 9.952 0.000 11.923 11.753 0.298 15.619 1.257 0.239 97.593 DRB-1-59 41.756 0.368 14.885 0.000 8.865 10.887 0.421 18.074 1.801 0.394 97.451 DRB-1-59 45.049 0.375 11.620 0.000 10.746 10.974 0.393 16.794 1.492 0.305 97.748 DRB-1-59 41.534 0.383 15.183 0.009 8.605 10.997 0.442 17.876 1.854 0.403 97.286 DRB-1-41 41.180 0.320 15.397 0.000 8.400 10.814 0.371 18.250 1.883 0.379 96.994 DRB-1-41 45.512 0.359 11.851 0.000 11.815 11.215 0.321 14.426 1.551 0.258 97.308 DRB-1-41 46.160 1.379 9.689 0.000 11.430 10.904 0.276 16.103 1.439 0.240 97.620 DRB-1-41 46.566 1.059 9.813 0.000 12.692 11.237 0.292 14.161 1.330 0.208 97.358 DRB-1-41 Relict Igneous Relict Igneous Relict Igneous Metamorphic Metamorphic Metamorphic Metamorphic Relict Igneous Relict Igneous Metamorphic Metamorphic Metamorphic core core core rim rim rim rim core core rim rim rim SiO2 TiO2 Al2O3 Cr2O3 MgO CaO MnO FeO Na2O K2O Total 41.532 0.344 15.262 0.000 8.791 10.815 0.443 18.041 1.797 0.396 97.421 42.229 0.439 15.035 0.000 8.712 10.948 0.414 18.229 1.899 0.425 98.330 42.050 0.396 15.531 0.022 8.570 10.878 0.411 17.871 1.866 0.391 97.986 46.910 1.211 8.019 0.000 12.217 10.970 0.399 16.194 1.237 0.197 97.354 42.169 7.431 9.933 0.000 10.421 10.281 0.381 15.369 1.403 0.218 97.606 45.215 2.239 9.233 0.000 12.338 11.047 0.409 14.767 1.318 0.239 96.805 Neoproterozoic Volcanic Arc Terranes, Savannah River Site, SC. 46.320 1.183 9.522 0.005 12.001 10.924 0.398 15.771 1.454 0.227 97.805 46.001 0.447 10.480 0.027 11.228 11.026 0.257 16.623 1.386 0.205 97.680 45.942 0.432 9.975 0.016 11.343 11.069 0.231 16.358 1.589 0.235 97.190 46.081 1.789 9.155 0.000 12.109 11.041 0.249 15.413 1.299 0.257 97.393 45.183 1.584 10.082 0.011 11.078 10.963 0.235 16.495 1.488 0.235 97.354 46.366 1.113 9.568 0.007 11.697 10.802 0.313 16.160 1.463 0.195 97.684 DR-5. Representative amphibole analyses. Sample# DRB-1-41 Metamorphic rim SiO2 TiO2 Al2O3 Cr2O3 MgO CaO MnO FeO Na2O K2O Total Sample# SiO2 TiO2 Al2O3 Cr2O3 MgO CaO MnO FeO Na2O K2O Total 46.571 1.891 8.433 0.000 12.531 11.084 0.299 15.176 1.204 0.227 97.416 DRB-1-60 DRB-1-60 DRB-1-60 DRB-1-60 DRB-1-60 Relict Igneous Relict Igneous Metamorphic Metamorphic Metamorphic core core rim rim rim 44.348 0.376 12.742 0.000 11.140 11.733 0.255 15.049 1.341 0.335 97.319 47.506 0.686 9.323 0.000 13.332 11.527 0.286 13.052 1.218 0.174 97.104 46.073 4.034 8.929 0.023 12.707 11.124 0.299 12.944 1.169 0.199 97.501 47.670 1.276 8.638 0.000 13.592 11.396 0.284 13.537 1.233 0.207 97.833 45.590 2.314 10.549 0.009 12.171 11.272 0.309 14.242 1.312 0.201 97.969 PBF-7-108 PBF-7-108 PBF-7-108 PBF-7-108 PBF-7-108 PBF-7-108 PBF-7-108 PBF-7-108 PBF-7-108 PBF-7-108 PBF-7-108 PBF-7-108 Meta. amphibole Meta. amphibole Meta. amphibole Meta. amphibole Meta. amphibole Metamorphic amphibole Meta. amphibole Meta. amphibole Meta. amphibole Meta. amphibole Meta. amphibole Meta. amphibole 42.264 0.921 13.460 0.041 9.479 11.902 0.477 17.050 1.113 1.576 98.283 42.157 0.924 13.268 0.021 9.550 11.777 0.497 16.905 1.088 1.660 97.847 42.606 0.788 12.788 0.031 9.764 11.847 0.500 17.289 1.144 1.524 98.281 43.650 0.719 12.094 0.033 10.228 11.978 0.504 16.778 1.097 1.316 98.397 42.622 0.772 13.125 0.049 9.848 11.758 0.470 16.778 1.122 1.514 98.058 42.135 0.966 13.692 0.041 9.778 11.917 0.453 16.472 1.154 1.514 98.122 Neoproterozoic Volcanic Arc Terranes, Savannah River Site, SC. 42.310 0.980 13.453 0.050 9.844 11.646 0.501 16.316 1.194 1.753 98.047 42.508 0.847 13.056 0.013 9.650 11.879 0.505 16.659 1.050 1.524 97.691 42.814 0.884 12.755 0.215 9.679 11.815 0.484 16.883 1.106 1.393 98.028 41.956 1.003 13.657 0.000 9.708 11.663 0.500 16.285 1.178 1.693 97.643 42.356 0.945 13.219 0.000 9.772 11.888 0.487 16.794 1.128 1.597 98.186 41.686 0.980 13.750 0.075 9.585 11.761 0.469 16.762 1.181 1.589 97.838
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