Session C8 138 Disclaimer — This paper partially fulfills a writing requirement for first year (freshman) engineering students at the University of Pittsburgh Swanson School of Engineering. This paper is a student, not a professional, paper. This paper is based on publicly available information and may not be provide complete analyses of all relevant data. If this paper is used for any purpose other than these authors’ partial fulfillment of a writing requirement for first year (freshman) engineering students at the University of Pittsburgh Swanson School of Engineering, the user does so at his or her own risk. THE FUTURE OF COMMERCIAL AVIONICS: BIOMASS—SYNTHESIZED BY THE FISCHER-TROPSCH PROCESS—AS AN ALTERNATIVE JET FUEL Trevor Devine, [email protected] , 10:00 Mahboobin, Nicholas Trinovitch, [email protected], 1:00 Mena Lora Abstract—Gasified biomass, subjected to the Fischer-Tropsch process and converted into a blended BTL (Biomass-to-liquid) fuel, is a potential new fuel substitute. In particular, it is a promising replacement for jet fuel in commercial aircraft. Biomass, with regards to energy, is municipal waste, crops, and other biological materials. This substance is rich in carbon and hydrogen, and can be sublimated through a process called gasification. The synthetic gas (syngas) is cleaned and converted in green kerosene in a Fischer-Tropsch catalytic reactor. The newly created fuel is an alternative to the traditional jet fuel found in most airplanes today, and supports eco-friendliness and sustainability. This paper will contain in-depth analyses of the FischerTropsch process, gasification, and the biofuel’s feasibility as jet fuel. The process will be reviewed in both an economic and scientific manner, to prove whether biomass fuel can be an adequate replacement for fossil-fuel based avionic fuel. Research done by organizations such as the Department of Defense and Department of Energy, along with several research groups, will be included as support. Examples of this technology already in use will be included to prove the commercial interest in BTL fuel. Graphs, formulae, and statistics will all be used to better convey the significance of the data. Key Words- Biomass, BTL, Economic, Fischer-Tropsch, Gasification, Sustainability BIOMASS: A PROMISING ALTERNATIVE TO COMMERCIAL JET-FUEL The commercial aviation industry is one of the largest sectors of the U.S. economy. Millions of people each year use this essential service. Therefore, if a problem were to arise in this market, the entire U.S. would feel its effects. We currently have no such problem. However, this will not be the case for the future. Commercial jets run on petroleum-based jet fuel, a fossil fuel. As a nonrenewable resource, fossil fuels are far from sustainable. Also, studies have found they are particularly eco-destructive. Most industries have taken steps to research and develop alternative sources of energy, such as solar farms, University of Pittsburgh Swanson School of Engineering 1 3.3.2017 wind farms, and all-electric motors. Commercial airlines, however, are yet to find a truly feasible back-up energy source. A new and upcoming innovation, using a century old process, has the potential to change this. Biomass, subjected to gasification and the Fischer-Tropsch process, serves as a viable jet fuel available for blending or complete substitution. Albeit the expenses of the synthetization are currently high, Biomass-to-Liquid (BTL) jet fuel promises increased sustainability and ecofriendliness. This fuel beats out other alternative energy sources, mainly due to its classification as a “drop-in” fuel. There is no doubt that this new jet fuel has immense potential. In fact, United Airlines and Fulcrum Bioenergy have already invested in this technology. Biomassbased jet fuel has enough potential to keep the aviation industry up and running through the near future, due to its economic and environmental sustainability. THE FISCHER-TROPSCH CYCLE AND GASIFICATION- STEP BY STEP Fischer-Tropsch Cycle and Gasification The Fischer-Tropsch cycle converts biomass into a usable fuel through a multiple step process. The first step is gasification. Gasification is vital because it creates a gas mixture of carbon monoxide, hydrogen, carbon dioxide, nitrogen, and methane that is then re-arranged into a usable fuel. To get these fuels, the process must begin with natural biomass, which contains organic compounds of carbon, hydrogen, and nitrogen (the specifics of these materials will be discussed in the next section). Before gasification occurs, however, the materials must be pre-treated to remove any extra contaminants. This ensures that the gas produced is comprised of mostly the compounds used in the later processes. While there are multiple steps to pre-treatment, drying is the most important. It was found that the dryer the biomass, the less hydrogen was produced, making the actual Fischer-Tropsch synthesis more effective [1]. Trevor Devine Nicholas Trinovitch There is a diverse assortment of gasifiers used in industry today, including the updraft fixed bed gasifier, the fixed bed gasifier, and entrained flow gasifier. Each gasification technique differs slightly, but accomplish the same goal. In an updraft gasifier, for example, the biomass goes through a few stages, as depicted in Figure 1. the raw-syngas. These need to be removed before the synthesis can begin, as they will make the process less efficient and could even drive it to a halt. For example, it is vital to remove any O from the raw syngas, since the oxygen will oxidize the catalysts, therefore slowing the reaction and decreasing the amount of product produced. Once the raw syngas is properly cleaned, the actual Fischer-Tropsch Synthesis will begin. As defined by Jin Hu and his colleges at the Department of Agricultural and Biological Engineering at Mississippi State University, the synthesis itself is a “set of catalytic processes for converting synthetic gas … into liquid hydrocarbons” [1]. Most of the reactors for this process are similar in design and functionality, but the biggest difference between one reaction to another is the catalyst used. There are four possible catalysts: Fe, Co, Ru, and Ni [1]. The differences between the four major catalysts will be described in greater detail in the following section. . The Materials Used in the Process 2 As mentioned above, the major starting material for the Fischer-Tropsch cycle is biomass. Biomass is a subcategory of municipal solid waste, or MSW for short. Municipal solid waste includes many different waste products from wood clippings to plastic bottles. Biomass, however, is specifically organic materials like wood clippings and food waste. They are comprised of carbon and hydrogen chains that become the main building block of the bio-fuel produced from the synthesis process. According to a chart found created by J. Hu, Coconut Shell, Coconut Coir, Ground Nut Shell, Wheat Straw, and Wood have the highest percent of carbon by weight [1]. This means that these materials will provide the most carbon for the synthesis of the bio-fuel. As mentioned in the previous section, the process itself is dependent on the catalyst used. The process consumes a lot of energy, so using a proper catalyst is vital to reduce the activation energy required. The four most common catalysts are Nickel (Ni), Iron (Fe), Ruthenium (Ru), and Cobalt (Co). Nickel is very rarely used commercially, even though Ni is almost just as active as the others, because it forms “too much methane …[and] volatile carbonyls under high pressure” [1] making it a danger to the process. Also, methane is too low of a weight for a carbon chain making it useless for the synthesis process, meaning material and energy is wasted [2]. Ruthenium, while similar to Cobalt in its activity, is a very rare element. Consequentially, its cost is much higher than the rest. Due to this, Cobalt and Iron are the most common catalysts. The decision of which catalyst will be used is dependent on the starting materials in the cycle. If a company were to use coal, Iron would be the catalyst of choice due to its inexpensive price and its “high water-gas-shift” activity [3]. In other words, it is better at capturing the synthetic gas if the syngas has a low hydrogen/carbon monoxide ratio, like in the coal gasification process. Cobalt wouldn’t be used for coal gasification because of its “higher sensitivity to sulfur” [3]. Therefore, Cobalt is FIGURE 1 [2] Basic Diagram of an updraft gasifier The first step is the drying stage. By drying the material any excess water is removed, allowing more of the material to be converted into syngas. The next step is the devolatilization. Devolatilization is the removal of volatile substances from the solid by grinding the solid down and separating it by parts. The final step occurs when the biomass reaches the bottom and combusts with the help of a gasifying agent to produce the syngas and any waste products [1]. Gasification, compared to the other processes of converting biomass to the desired product, is the most efficient. A generalized version of the chemical reaction is depicted below: Biomass + O2 (or H2O) CO, CO2, H2O, H2, CH4 + other CHs + tar + char + ash Gasification can have an efficiency of 98%-99% in converting the carbon into a usable form [1]. In terms of the reaction, CH4 and other CHs are produced the most, while the production of char and ash, waste products, is minimized. CH4 and CHs are the main ingredients to fully synthesizing the biomass jet fuel. Additionally, gasification also produces less pollutants in the form of CO and CO2, making it the best method for converting biomass into its component parts. No matter the amount of cleaning and pretreatment done on the starting materials, there is almost always still impurities in 2 Trevor Devine Nicholas Trinovitch most often used in synthesis of natural gas or biomass because of their low sulfur content. and gasification processes also produce excess gas that can be used to either generate power or refine the longer CH chains, (the wax depicted in Figure 2), and reform them into a usable liquid fuel. Products of the Fischer-Tropsch Cycle As described above, the temperature, pressure, and feed composition play an influential role in determining what is produced from the cycle. While the product composition may vary from cycle to cycle, the four general products are light oils, heavy oils, carbon chains of five and above, and carbon of one to four carbons in length [4]. The larger carbon chains are what compose the finished bio-fuel, but the shorter carbon chains serve a much different purpose. These short chains can either be used to refine the larger chains, or they can be utilized to make electricity. If these carbon chains were to be redirected into a turbine, because of their high temperature and velocity following the gasification process, they will be able to generate electricity. This is important because this energy can be used to push the final synthesis process along. By combining the cycles parts into a single loop, it can help make a plant “energetically self-sufficient” [5]. There was a study that found that the net energy of the system itself is a positive 3831 MJ/FU, ‘FU’ being a fixture unit representing one cubic foot of water [5]. This self-sufficiency is important for the future of the product, since it can reduce overall costs. Even though the Fischer-Tropsch fuels are produced from biomass comprised of waste, they can create a fuel that rivals traditional jet fuel. Fischer-Tropsch fuel not only has a high cetane number, meaning it has a bigger energy density, ignition, and thrust, but it also has a low aromatic content. This means that when it is combusted, it will produce less CO and NO , both of which are greenhouse gases that contribute to global warming [6]. FISCHER-TROPSCH CYCLE: BENEFITS AND CONSEQUENCES The Fischer-Tropsch Cycle: The Economic Assessment Before a discussion of what effect a Fischer-Tropsch fuel will have on the economy, its economic feasibility needs to be considered. The cycle itself involves multiple steps as mentioned above, similarly to its kerosene counterpart. The question, then, is whether the Fischer-Tropsch cycle can even compete with the current jet fuel cost wise. Two professors at the Lappeenranta University of Technology created an in-depth study of the economic possibilities of bio-fuel. Figure 3 contains the costs that a company would face if they were to convert a plant to be able to produce Fischer-Tropsch fuel. Costs: Purchasing Equipment: Physical Plant Costs: Investment Costs: Total Fixed Operating Costs: Total Variable Operating Costs Total: Dollars ($): $1,196,350.40 $3,225,813.00 $5,233,935.00 $751,977.60 $7,477.05 $10,575,753.15 Figure 3 [4] A table displaying average costs for various aspects of producing Bio-Fuel 2 x The total investment cost, according to the study at Lappeenranta, can be split up into two major components: equipment cost, and operation cost. The equipment cost is the price tag associated with the initial purchase of all the necessary machines. It is estimated that the total equipment fee for a single plant would fall around $1,196,350.40. Considering the design cost of the plant along with the construction labor cost, the total investment rises to about $5,233,935 [4]. This high initial price is what will make it difficult for a lot of companies to switch from fossil jet fuel to a new fuel that requires them to replace all their equipment. On top of the equipment cost, there is also the total operating cost. The first factor of operation cost is the fixed cost. The fixed cost includes static figures like worker salary, labor costs like health insurance, maintenance costs, and plant overhead costs. It is estimated that this will total to around $751,977.6 [4]. The second component of operation cost is the variable costs. The cost of electricity, air, water, and starting materials like wood, coal, or natural gas all fall under variable costs and total about $7,477.05 for a single cycle [4]. If it’s sold at a price of around $619/ton, it is estimated it will only FIGURE 2 [2] Outline of the Fischer-Tropsch Synthesis Figure 2 depicts the general overview of the FischerTropsch cycle. In this case coal is being used as the fuel for gasification, but any biomass material can be substituted above. As a summary of what was discussed above, the process begins with a fuel undergoing gasification, which produces raw syngas. This syngas is then cleaned and undergoes the Fischer-Tropsch synthesis. From here the final fuel is produced and sent to be stored and transported. The synthesis 3 Trevor Devine Nicholas Trinovitch take a year before the initial investment is payed back [4]. This shows that an investment in BTL fuel is economically sound. The biggest part of the cost of the production of the Fischer-Tropsch fuel is not the numbers themselves, but how they compare to the current market of jet fuel. Per a fuel price analysis by IATA, the current jet fuel price falls around $528.3/ton [7]. Because of this there isn’t too large of a market for biofuel in today’s economy. According to a journal article in Global Change Biology, which is a monthly scientific journal concerning conservation biology and environmental sciences, “the cost of bio jet fuel … could be competitive with fossil jet fuel by 2035” [8]. Because of the rising price of jet fuel, caused by the diminishing supply of fossil fuels, the price will eventually rise to that of biofuel. Bio fuel could be competitive now if the carbon price were to rise, but it is predicted that by 2035, bio fuel will be competitive with jet fuel, regardless of the cost of carbon at the time. [8]. Consequentially, investments should be made now, so that the transition to BTL fuel can occur smoothly by around 2035. The final issue in implementing biomass-based jet fuel is the approval process. A new jet fuel must first go through rigorous testing before it can be approved for commercial use. Pure Fischer-Tropsch Bio fuel is still being improved and tested so that it can stand on its own. Currently, however, there have been multiple airline companies that have performed flights using fuels that are a blend of the newer bio fuel and the traditional jet fuel. The higher end of the mix seen has been 50% biomass-based jet fuel [10]. Because it has not been used very often, most people are not very trusting of the new fuel. Therefore, it's slowly being integrated through mixtures until a foothold is found and be used on a full commercial scale. Sustainability of Fischer-Tropsch Jet Fuel Sustainability is the quintessential advantage of biomassbased jet fuels over their petroleum-based counterparts. Sustainability is defined by UCLA to be “development that meets the needs of the present without compromising the ability of future generations to meet their own needs” [10]. Currently, the U.S. commercial aviation industry is not meeting this standard, due to the use of non-renewable jet fuel. Within the next 50 years, the availability of fossil fuels will drop substantially as demand for them continues to grow. Supply will not match demand, and there will be a shortage created, hurting the global economy for generations to come. Consequentially, provided three key requirements are met, biomass-based jet fuel has remarkable potential to replace petroleum jet fuel. First, for proper sustainability to occur, the land used to grow the crop-based feedstock must be managed conservatively, and with carful regard for the environment. As SkyNRG, a sustainable biofuel company, states, “In order to achieve the high biomass potential deployment levels, …land must be properly managed and agricultural and forestry yields must increase substantially.” [12]. Proper management of land includes not overusing the soil, banning slash-and-burn farming, and making use of all available land space. U.S. farming techniques currently employ each of these, but many third-world countries do not. Therefore, implementation should begin in the U.S. and other developed countries, until proper farming is taken up by impoverished countries. As long as effective land management is practiced, BTL fuels are adequately sustainable to fuel the commercial aviation industry. Without these techniques, however, BTL fuels can be even more unsustainable than fossil fuels, as they carry the risk of conflict with food supplies and biodiversity. The second aspect of a sustainable biomass jet fuel is a second generation crops feedstock. Second generation crops, as explained before, consist of Lignocellulosic materials, agricultural residues, and cultivated grasses and trees. Each of these feedstocks share one common attribute—they are not designed for human consumption. This essential trait prevents a conflict of interests with mankind’s need for food. Due to this, the food and biofuel industry can operate side by side, without competition between the two. Furthermore, according What Problems are Stopping its Implementation While this bio-fuel may be a possibly great alternative to the modern jet fuel, due to its low sulfur content and high density of energy, there are multiple reasons why it is still not being fully implemented. One of the most challenging to solve is also one of its benefits. Depending on the catalyst and materials used, most Fischer-Tropsch fuels have a low sulfur content [3]. The fact that there is little sulfur in the fuel means that there is no production of sulfur dioxide upon combustion, making the fuel better for the environment. Sulfur, however, acts as a lubricant for many other types of jet fuel. For this fuel to be usable then, a synthetic lubricant would have to be added after production. By adding a synthetic lubricant, the fuel can lose its energy density due to this new material, or, depending on the lubricant added, it can produce harmful chemicals when burned. Furthermore, another major issue is the lack of a market. As mentioned above, the fuel is currently more expensive than the modern jet fuel. This alone is enough to push a company away from trying to integrate this fuel into their company. To make matters worse, before the fuel will even reach these commercial plane companies, the plants making it first must buy all new equipment and completely change their systems. This high initial price is discouraging most companies from even attempting to produce the fuel, meaning less supply will reach the market. Also, the success or failure of this fuel in the market is too dependent of the cost of regular jet fuel. It’s dangerous for a company to put their faith in something as new and as unreliable at bio-fuel when the price of oil can change at any time, causing fluctuation in the price of modern jet fuel [9]. If, for example, the price of jet fuel was to suddenly plummet due to a drop in the price of oil, most companies would switch from biofuel to jet fuel, eliminating the biomass fuel market. 4 Trevor Devine Nicholas Trinovitch to the UK Biofuel.org site, “second generation feedstock should grow on …land that cannot be used for “arable” crops, meaning it cannot be used to effectively grow food.” [13]. Using normally nonarable land ensures that the feedstock will not take away from the food supply, which would remove biomass from the alternative fuel list. The last factor in a sustainable biomass fuel deals with the diversity of the bio stock. As mentioned previously, biomass-based jet fuel can be produced from a wide variety of carbon-based materials. Depicted in table 2 is the potential feedstock, based on geographical location. Type of Biomass Forest residues Agricultural Residues Organic Waste streams Components Primary forest fuels Wood Whole stems Rice Husk Bagasse Straw streams Corn Stover Demolition wood MSW Green wastes luxury, and, consequently, is not sustainable. Biomass’ variety and widespread availability is essential to its potential success as a fuel source. Biomass-based jet fuel also offers strong economic sustainability, another result of the diversity of its feedstock. Unlike petroleum-based jet fuel, BTL fuel prices will not drastically change if one type of biomass is somehow made unavailable; there are several other substitutes that can take its place. Such market stability is particularly valuable to commercial airlines, since it provides a form of economic safety. This economic safety extends to future generations, as the commercial aviation industry will continue to thrive, even if draughts and disasters affect one of the feedstocks. Prices will remain low, and air travel will remain commercialized, available to all. Diversity in bio stock, along with proper land use and second generation crops, will allow biomass-based fuel to surpass fossil fuels in sustainability, with respect to the commercial aviation industry. This sustainability, as will be discussed, complements biomass’ other key advantage— ecofriendliness. Regions Canada N. Asia S. USA E. Europe S. Asia N.E. USA W. Europe India E. Asia Ecofriendliness One of the most crucial factors in an alternative fuel’s feasibility is the potential benefit—or harm—it brings to the environment. As a form of sustainability, ecofriendliness is another essential characteristic of biomass-based jet fuel. Compared to other fuel sources, BTL fuel is not perfectly clean. However, it has two distinct improvements over traditional kerosene jet fuel. Most notably, biomass-based jet fuel has an eco-friendlier carbon dioxide life cycle. The National Academy of Science analyzed the life cycle of BTL fuel, taking into account, “all emissions associated with producing the final fuel from its initial form, as well as aircraft emissions,” and determined that this biofuel could reduce the life-cycle emissions, in comparison to petroleum-based jet fuel [15]. This scientific article further explained that “biomassbased hydrocarbons …[absorb]… CO2 from the atmosphere when they …[grow]… and the CO2 emitted during fuel combustion is equal to that absorbed during its growth” [15]. The net effect, then, on the environment due to carbon dioxide emissions is essentially zero. Fossil fuels, on the other hand, have a positive emission status, as they release CO2 previously kept from the atmosphere. Carbon dioxide emission has been proven to negatively harm the environment, and the commercial airline industry is one of the largest CO2 emitters in the country. Consequently, with an improvement in the lifecycle of carbon dioxide through a switch to biomass-based jet fuel, less harm will be done to the environment by commercial planes. BTL jet fuel has another benefit that allows it to surpass kerosene jet fuel, in terms of ecofriendliness. A biomass jet fuel has much lower emissions of the oxides of Sulphur (SOx) and other particulate matter. Specifically, a Purdue research study found that BTL jet fuel has a 100% decrease in SOx emissions, and releases 50%-90% less particulate matter [9]. Managed grass lands Commercial wood S. America plantations Africa Cultivated Energy grasses Indonesia biomass Agroforestry systems Australia Saline and semi-arid conditions FIGURE 4 [14] The regions and components of several types of Biomass As shown, at least one major type of biomass is located on every inhabited continent. For example, Canada and Northern Asia both have ample supplies of whole stems, in the form of Mountain pine wood and underutilized forest resources, respectively. South America and Africa have ample grasslands, providing a sustainable, regionally sourced biomass [14]. Densely populated regions and cities, mainly in Western Europe, Northeastern USA, and Eastern Asia produced an enormous load of MSW [14]. MSW itself is very sustainable, since garbage is constantly produced at a high rate. Finally, in regions with large farms and plantations, biomass feedstock consists of rice husks, straw streams, and corn stover, which are all unused waste products of agriculture [14]. The feedstock for biomass is incredibly diverse and widely available. This characteristic is what truly makes biomass a sustainable fuel source. The current generation can develop and grow, using biomass as fuel, without compromising the needs of the future generations. Even if one of the feedstocks becomes unusable, there are ample substitutes to create the same exact fuel. Petroleum-based jet fuel does not have this 5 Trevor Devine Nicholas Trinovitch SOx is a known polluter that taints the quality of water and soil, due to acid deposition [16]. By reducing the amount of SOx produced, commercial airlines can greatly help global ecosystems maintain a healthy balance of pH. Biomass jet fuel offers a viable option for airlines to drastically lower Sulphur production on a large scale. Continued use of petroleum-based will only exacerbate the problems associated with SOx production, and lower the general condition of the environment. Biomass has obvious benefits to the environment, notably a better carbon life-cycle, and lowered SOx production, which can be best utilized in the commercial aviation industry as a replacement to eco-destructive petroleum jet fuel. they want to use on a flight-by-flight basis. For example, an airline may decide to use a biomass-petroleum jet fuel mixture for domestic flights, and continue using traditional jet fuel for long international flights. Such fuel flexibility has the potential to improve the entire aviation industry as prices will be less likely to fluctuate in response to a price change of one fuel. Moreover, if a more efficient drop-in biofuel is produced, BTL jet fuel will not obstruct its implementation. The biomass fuel could simply be removed from production, and replaced with the better jet fuel, without any added cost. BTL jet fuel, since it is a drop-in fuel, is much more advantageous in the commercial aviation industry than other alternative energy sources. AN ALTERNATIVE JET FUEL FOR COMMERCIAL AVIATION- THE IDEAL APPLICATION Why the Commercial Aviation Sector? Biomass-based fuel is certainly a viable alternative to fossil fuels in several different applications. However, BTL fuel would be most effectively utilized as a jet fuel, especially in the commercial aviation industry. Traditional jet fuel was originally favored for its somewhat unique properties, as opposed to land transportation fuels, such as gasoline or diesel. Per the National Academy of Science, jet fuel specifically has a “high energy per unit mass, high energy per unit volume, stability, nonvolitity, …and low toxicity” [4]. These characteristics allow commercial air travel to be both safe and effective, which gave rise to the booming industry today. Consequentially, an alternative jet fuel must share these stringent characteristics, and not many fuel sources do. Biomass-based jet fuel, however, has only a slightly smaller energy density, which is one reason why it has so much potential. As research conducted by a Purdue team found, biomass jet fuel ranks first and second in energy per unit volume and per unit weight, respectively, as compared to ethanol and hydrogen based fuels [9]. This explains why BTL fuel outpaces its competition, at least in regards to jet fuel. Such a high-energy density means that biomass fuel can be mixed in with traditional jet fuel, without a major reduction in energy output. This is essential in making a smooth transition away from petroleum-based jet fuels, as the industry will be affected less. Furthermore, BTL fuel is most applicable to commercial aviation due to harsh competition in other sectors. For example, the consumer car market is currently being dominated by fully-electric cars. With Tesla’s growing popularity, the electric car market is at an all-time high. Almost all car manufacturers have an electric car as part of their fleet. Therefore, any introduction of biomass fuel as an energy source for cars could be rejected, since consumers would tend to prefer their counterpart electric cars. Just like with fossil fuels, people tend to only trust technology to which they have constant exposure. Electric cars have recently made the jump into consumer trust, so they pose a serious threat to a potential BTL fueled car. Thus, a BTL fuel must enter an industry where no other alternative fuels have taken a dominant role, unlike most of the land-based transportation today. The commercial BTL Jet Fuel vs Other Energy Sources The market for alternative fuels consists of a wide and diverse set of clean biofuels, fully-electric motors, and other promising innovations. Each fuel has its strengths and weaknesses, based on how and where it is used. In regard to the commercial aviation industry, biomass-based jet fuel is superior, as compared to other power sources such as ethanol, electricity, and hydrogen. This superiority arises from several differences between these energy sources. Foremost of all, however, is BTL jet fuels’ classification as a “drop-in” fuel. According to the FAA’s website, “drop-in fuels mimic the chemistry of petroleum jet fuel, and can be used in today’s aircraft and engines without modification and provide the same level of performance and safety as today’s petroleum-derived jet fuel.” [17]. As a drop-in fuel, Biomass jet fuel can be substituted directly in for traditional jet fuel, with little to no consequences. Additionally, BTL fuel can be mixed with kerosene jet fuel to produce a cleaner-burning jet fuel with similar characteristics, in terms of energy produced. The dropin nature of biomass jet fuel is valuable to commercial aviation companies, as they can reduce research and development costs other fuels require. Specifically, per a Purdue analysis on BTL jet fuel, planes that run on either hydrogen or ethanol must be redesigned entirely, along with their engines [9]. These fuels are more appropriate for land-based transportation, which already have the specific engines being designed. Furthermore, diversity is needed in fuel sources, across all industries and sectors. A drop-in fuel only broadens this diversity. As Dr. Andre Faaij of Utrecht University explains, companies making aircraft will not restrict their technology to using only one type of fuel or operation. [12] Companies want to make as much money as possible, so they always try and keep a wide range of options available to them. Employing a drop-in fuel, then, gives a commercial airline much more security than other energy sources that change the airline technology itself. An airline company can choose which fuel 6 Trevor Devine Nicholas Trinovitch airline sector absolutely fits this requirement. No other alternative fuel has dominated the industry like electric cars have for transportation. BTL jet fuel, then, has less competition which could drive it out of usage. With few choices for alternative fuels, the commercial aviation is the ideal application of biomass-based jet fuel. Fischer-Tropsch cycle to synthesize the energy dense bio jet fuel. The finished product is resold to commercial airlines alongside petroleum jet fuel, to be used in a mixture, or as a stand-alone fuel. The future dynamic between traditional jet fuel and biomass jet fuel would be akin to the diesel/gasoline relationship seen in the transportation sector. They are different fuels, yet share the industry almost evenly. Eventually, BTL and petroleum jet fuels would become perfect substitutes for one another, benefiting the industry and the environment, due to biomass’ sustainability. While no company has truly introduced biomass jet fuel, two airline companies have shown a strong interest in biofuels, including biomass-based jet fuels. One of them, United, has already teamed with a biofuel company to fuel their jets in Los Angeles Airport with a 30/70 blend ratio of biomass jet fuel, according to their corporate website [19]. United’s push for ecofriendly fuel shows airline companies’ desire to reduce fossil fuel consumption. Their choice in biomass-based jet fuel also proves that companies take BTL fuel seriously, and view it as a potential replacement for traditional jet fuel. Since United has already laid the groundwork, other airlines may soon start to utilize BTL jet fuel in their own aircraft, increasing the demand for this fuel. This then leads to more Fischer-Tropsch plants being created, and an expansion in the entire market for biomass-based jet fuel. Symbiotic relationships will develop between manufacturers and airline companies, creating jobs and growing the economy. For example, Fulcrum Bioenergy has also signed a deal with Cathay Pacific Airways for a 375-million-gallon deal [18]. Such cooperation between companies displays the interest both manufactures and airlines have in this fuel, and reinforce its viability as an alternative jet fuel. FISCHER-TROPSCH PLANTS AND BIOMASS JET FUEL IN USE TODAY Current Fischer-Tropsch Plants An alternative fuel can only be introduced in an industry if companies show an interest in it. Governments and scientists may research and discover a new source of energy, but companies must be the ones to invest in and use this technology. For biomass-based jet fuel, there must be a corporate interest on two levels. Both the fuel itself and the Fischer-Tropsch cycle must be commercialized together, otherwise a BTL jet fuel could never be produced. Due to this, a manufacturer’s interest in creating a Fischer-Tropsch fuel plant is essential to introducing biomass-based jet fuel to airline companies. Luckily, several companies have already invested in a Fischer-Tropsch plant to convert biomass into jet fuels. One such company, Fulcrum Bioenergy, is paving the way to creating a multimillion dollar plant in the United States. According to the European Biofuels Technology Platform, Fulcrum has given a $200m contract to Abengoa to create a facility to synthesize bio jet fuel by using gasification and the Fischer-Tropsch cycle to convert municipal solid waste into syngas [18]. Fulcrum Bioenergy has displayed a committed interest in producing bio jet fuel, which proves there is a market and desire for such a technology. If this plant becomes an economic success, Fulcrum may build even more plants to expand their investment in biomass jet fuel. This will drive other companies to enter the market, potentially creating a booming industry, which would lower the economic impact of a transition to BTL jet fuel. Companies’ interest in creating Fischer-Tropsch plants is a strong indicator of biomass-based jet fuel’s potential to become the dominant alternative fuel in the commercial airline industry. CONCLUSION: BIOMASS-BASED JET FUEL IS THE FUTURE OF COMMERCIAL AIRLINES An industry based solely on a dwindling resource is doomed to fail eventually. The commercial airline sector, relying on petroleum-based jet fuel, needs its own alternative fuel source to maintain its economic success. Biomass-based jet fuel, created through the Fischer-Tropsch process, offers such an option. Although it initially is much more expensive than traditional jet fuel, it offers a better hope for future stability. This stability is a result of the biofuel’s high sustainability, along with its eco-friendly nature. Furthermore, as a drop in fuel, BTL jet fuel can be put into any commercial plane flying today, with few consequences. Such flexibility in fuel provides safety for airline companies, and profits in the future. Fossil fuels are known to be problematic for the environment, and are bound to run out in the future. Consequently, investments in biomass jet fuel must be made soon, to allow adequate time for the technology to develop further, and enter the commercial market in the coming years. BTL fuel is far from perfect, but it offers an alternative to Progressive Airlines- Beginning the Fuel Switch Now Fischer-Tropsch plant development is only half of the two steps necessary for BTL jet fuel to be produced commercially. Airlines themselves must show a desire to use these fuels in their aircraft, otherwise the fuel would never sell. Currently, there is no company who has fully switched over to biomass-based jet fuel, but this does not limit its potential. Hypothetically, biomass and petroleum jet fuels can be used interchangeably in the future. The process could begin in New York city at a local municipal waste center, where garbage is bought by a company with Fischer-Tropsch facilities. This garbage would be cleaned and gasified, then subjected to the 7 Trevor Devine Nicholas Trinovitch traditional jet fuel, something currently lacking. Petroleum reserves will eventually run out, and when they do, airlines need a backup or else the entire industry may crash. Biomassbased jet fuel may only one possible alternative, but it absolutely shows the most promise for sustaining the future of commercial aviation. https://www.iata.org/pressroom/facts_figures/fact_sheets/Doc uments/fact-sheet-alternative-fuels.pdf. [11] “What is Sustainability?” UCLA Sustainability. Accessed 2.22.2017. https://www.sustain.ucla.edu/about-us/what-issustainability/ [12] A. Faaij. “White Paper on Sustainable Jet Fuel.” SkyNRG. 6.2012. Accessed 2.24.2017. http://skynrg.com/wpcontent/uploads/2013/11/White-paper-on-sustainable-jet-fuelJune-2012-Faaij-van-Dijk-copy.pdf [13] “Second Generation Biofuels.” Biofuel. 2010. Accessed 2.25.2017. http://biofuel.org.uk/second-generationbiofuels.html [14] “Sustainable Feedstocks for Drop-In Fuels: Residues, Waste, Energy Crops.” Emerging Markets Online. Accessed 2.27.2017. http://www.emerging-markets.com/dropinfuels/ [15] “Commercial Aircraft Propulsion and Energy Systems Research: Reducing Global Carbon Emissions.” National Academies of Sciences, Engineering, and Medicine. 2016. Accessed 2.25.2017. DOI: 10.17226/23490. https://www.nap.edu/catalog/23490/commercial-aircraftpropulsion-and-energy-systems-research-reducing-globalcarbon. pp. 71-87 [16] “Air Emissions.” European Maritime Safety Agency. 2017. Accessed 2.25.2017. http://www.emsa.europa.eu/main/air-pollution.html [17] “Sustainable Alternative Jet Fuels.” Federal Aviation Administration. 6.4.2014. Accessed 2.26.2017. https://www.faa.gov/about/office_org/headquarters_offices/a pl/research/alternative_fuels/ [18] “Biomass to Liquids” European Biofuels Technology Platform. 9.9.2016. Accessed 2.8.2017. http://www.biofuelstp.eu/btl.html [19] “Alternative Fuels.” United. Accessed 2.25.2017. Https://www.united.com/web/enUS/content/company/globalcitizenship/environment/alternati ve-fuels.aspx SOURCES [1] J. Hu, Y. Lu, F. Yu. “Application of Fischer-Tropsch Synthesis in Biomass to Liquid Conversion.” Catalysts. 2012. DOI: 10.3390/catal2020303. http://www.mdpi.com/20734344/2/2/303. [2]“Fischer-Tropsch Synthesis.” U.S. Department of Energy. Accessed 2.28.2017. https://www.netl.doe.gov/research/coal/energysystems/gasification/gasifipedia/ftsynthesis. [3]“The Fischer Tropsch Process.” AZoCleantech. 5.15.2013. Accessed 3.1.2017. http://www.azocleantech.com/article.aspx?ArticleID=385. [4] I. Turunen, E. Vakkilainen. “Production of Biofuels by Fischer Tropsch Synthesis.” Lappeenranta University of Technology. 2011. Accessed 3.1.2017. https://www.doria.fi/bitstream/handle/10024/71973/nbnfife201109275595.pdf?sequence=3. [5] D. Iribarren, A. Susmozas, Javier Dufour. “Life-cycle Assessment of Fischer-Tropsch products from biosyngas.” ELSEVIER. 8.6.2012. Accessed 3.2.2017. http://ac.elscdn.com/S0960148113002073/1-s2.0-S0960148113002073main.pdf?_tid=1aca2a6a-ffc1-11e6-8d9d00000aacb35f&acdnat=1488511732_313fa673437e4c667918 7064a1f23ef7. [6] “Fischer-Tropsch Diesel.” Elobio. Accessed 3.1.2017. http://www.elobio.eu/biofuels/fischer-tropsch-diesel/. [7]“Fuel Price Analysis.” IATA. 2017. Accessed 3.2.2017. http://www.iata.org/publications/economics/fuelmonitor/Pages/price-analysis.aspx. [8] J. Howard, et al. “The economics of producing sustainable aviation fuel: a regional case study in Queensland, Australia.” Global Change Biology. 2015. Accessed 3.1.2017. http://onlinelibrary.wiley.com/doi/10.1111/gcbb.12159/pdf. [9] W. Harrison III. “The Role of Fischer Tropsch Fuels for the US Military.” OSD Assured Fuels Initiative. 8.30.2006. Accessed 2.25.2017. https://www.purdue.edu/discoverypark/energy/assets/pdfs/Ha rrison08-30-06.pdf. [10]“Fact Sheet Alternative Fuels.” IATA. 11.2016. Accessed 3.1.2017. ACKNOWLEDGEMENTS We would like to thank our co-chair Emelyn Haft for helping us format our paper and choose how to present our information. Also we would like to thank Josh Zelesnick for providing helpful insight to help us make our paper the best it can be. Without their help, this paper may not have been completed to the degree it currently is. 8
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