Emittance & Absorptance for Cryo Testing • Goal: To better understand emittance and absorptance and how they vary at cryo temperatures • Sample problem • Emittance & absorptance of non-conductors – Effects of wavelength (spectral dependencies and trends) – Effects of low temperatures – Effects of thickness (paints and films) – Honeycomb enhancements Example: SIRTF Thermal Testing • SIRTF Cryo Telescope Assembly – On orbit, CTA passively cooled to 40 K by radiation to space – 40 K well below typical LN2-cooled thermal-vac chambers at 80 K • Initial plans for thermal balance test – Simulate space environment – Add helium-cooled shroud inside existing LN2-cooled thermal-vac chamber – Helium-cooled shroud at 4 K – Painted honeycomb on shroud for absorptance close to 1.0 • Concerns about test – – – – Validity (see next chart) Feasibility Cost Time SIRTF CTA (40 K) Helium-cooled shroud (4 K) (painted honeycomb) Nitrogen-cooled coldwall (80 K) Vacuum chamber walls (293 K) Example: Basis for Conclusion • Emittance of paint at 4 K hard to predict – At 40 K, epaint = 0.70 ± 0.15 uncertainty (Goddard data) – No data at 4 K, but emittance much lower (at 0 K, emittance 0.00) – Even with painted honeycomb shroud, emittance at 4 K could be < 0.50 • Test vs space: too different – Tsink = 4 K vs 2.7 K – esink = 0.48 vs 1.0 (OK) (not OK) • Heat reflected back to CTA – CTA won’t get cold enough – Gradients won’t be realistic – Heat balance unpredictable • Thermal balance in 4 K shroud not meaningful – Omit 4 K shroud – Cool CTA with direct liquid helium lines – Make do with questionable thermal balance Goddard Paint Data Extrapolated From model What’s wrong with this picture? Example: Revised Solution • Helium-cooled shroud gives meaningful test 1. Absorptivity of the paint is relative to 40 K, not 4 K – Paint’s absorptivity depends on wavelength distribution of incident radiation – Paint’s absorptivity at a given wavelength is independent of paint’s temperature – Effective absorptance = emittance of paint at 40 K = 0.70 2. At 40 K, absorptance of painted honeycomb can be > 0.90 – Some variation with paint thickness and paint process – Some variation with cell size and honeycomb thickness – Use specular paint – Calorimeter uncertainties increase at cryo temperatures 98% 3. Helium-cooled shroud could mimic space to within 1% – Grow shroud from 2X to 10X the area of SIRTF CTA Additional cost for liquid helium to cool larger shroud 99.5% – Concentric spheres: RadK12 = A1/[1/e1 + (A1/A2)(1/e2 – 1) 1/ 2 1/ 10 Spectral Intensity of a Blackbody • Planck’s Radiation Law – I(l,T) = (2phc2/l5)/(ehc/lkT – 1) • Flux (Qbb) = area under curve • Qbb,T = sT4 s = 5.6697 X 10-8 W/m2-K4 • Curves have similar shapes – Imax is proportional to T5 lmax is proportional to 1/T lmax & Imax 0.004 inches Spectral Intensity: Log Plot lT = 1148m-K lmaxT = 2897m-K lT = 22917m-K • Everything shifts proportional to 1/T • Max power occurs at longer wavelengths at lower temperatures • Curve for a lower temperature is less than curve for a higher temperature at all wavelengths • At low temperatures, power spreads over wider range of wavelengths 98% of power Absorptance = Emittance: Kirchhoff’s Law • Absorptance = emittance, if the same… – Surface a+r+t=1 a + r = 1 (opaque) – Temperature – Wavelength – Angle of incidence al,T,q,f= el,T,q,f (rest of presentation omits effects of angle of incidence) • Total absorptance = total emittance at the same temperature – Emittance Total hemispherical emittance Surface at the given temperature – Absorptance Surface is at the given temperature Surface is surrounded by blackbody at the same temperature – Must be true, else violates the 2nd Law of Thermodynamics Conclusions So Far • Emittance varies with wavelength for real surfaces – Some surfaces have a fairly constant emittance over a range of wavelengths • Emittance at a given wavelength can also change with temperature • The blackbody intensity changes non-linearly with temperature – Increases with temperature to the 4th power – At lower temperatures, the distribution shifts towards longer wavelengths – At lower temperatures, the power spreads out more • Therefore, effective emittance changes with temperature, if… – Emittance varies with wavelength, or if… – Emittance at a given wavelength changes with temperature – For the range of wavelengths of importance at the given temperature Emittance of Non-Conductors • For non-metals, el and al is essentially independent of temperature • 2-step absorption process 1. 2. • • Surface reflectance depends on index of refraction Reflectance = [( - 1)/( + 1)]2 = index of refraction = 1/relative light speed ≈ [dielectric constant]½ (normal) Volumetric absorptance sometimes limited by thickness Dielectrics are partially transparent Absorptance within material increases with thickness: a = 1 – e-kx Free-standing film, or backed by metal layer No significant difference beyond certain thickness (1 to 10 mils typically) 1 2 At low temperatures, emittance of paints and films decreases – Energy shifts to longer wavelengths – When wavelengths exceed thickness, paint or film becomes more transparent – No decrease for non-conductive substrate—if thick enough Surfaces becomes more specular at low temperatures – As more wavelengths exceed roughness of surface and substrate Spectral Emittance of a Paint • Emittance/absorptance at a given wavelength doesn’t vary with temperature • Total emittance may vary with temperature as the range of wavelengths shifts • Changing temperature of emitting source may shift the absorptance of an absorbing surface • Changing temperature of absorbing surface does not change its absorptance Emittance of Non-Conductors: Films • For non-conductors, radiation transfer is more of a volumetric phenomenon – Many thin films are partially transparent – Absorptance (and emittance) varies exponentially vs thickness – Films are volume-limited • At low temperatures, wavelengths are longer and films are more transparent – Different paints or films show a decrease in emittance at different temperatures – Emittance of FEP Teflon films drops off at higher temperatures than most films or paints – Paints or OSRs are better on cryo radiators – Painted honeycomb gives highest emittance • If material is thick enough, emittance stays constant to much lower temperature – Emittance of 35-mil fused silica constant from 25 K to 300 K Honeycomb Blackbodies • Open, painted honeycomb cells increase emittance or absorptance – Cavity offers several chances for absorptance – Each cavity approximates a blackbody – Absorptance still equals emittance Multiple bounces in a honeycomb hex cell • Not too sensitive to honeycomb geometry – Aspect ratio: cell width versus cell height – Aluminum honeycomb minimizes DT to base At cryo temperatures, DT not a factor – Obtaining uniform paint may be driver – Recommend larger cell honeycomb Allows thicker paint Paint process less critical • Specular paint increases effective emittance – Diffuse paint: – Specular paint: 0.9773125 K, 0.929180 K 0.9984125 K, 0.985780 K Simplified model • Same hemispherical emittance • 100% diffuse vs 100% specular Percent Power vs Wavelength for Cryo 40 mils • 1% of power at l less than 1448/T • Maximum power at l of 2897/T – Also 25%/75% split • 50% of power either side of l of 7393/T • 99% of power at l less than 22,917/T 4 mils • Typical paint thickness = 2 to 8 mils – Paint have reduced emittance when wavelengths exceed thickness • ¼” (honeycomb cell) = 6,350 microns – Cell size well beyond significant wavelength effects Conclusions / Recommendations • For radiation between hot and cold surfaces, the hot surface dominates • Temperature of hot emitter determines cold non-conductor’s absorptance • – Absorptance depends on distribution of incident wavelengths – Most of the incident radiation originates at the hot surface – For non-conductors, al does not vary with temperature Total emittance varies with temperature if … 1. 2. Emittance varies with wavelength For paints and films, emittance drops off at longer wavelengths (cryo temperatures) Thicker substrates of non-conductors will not show this effect Emittance at a given wavelength varies with temperature Typical non-conductors do not show such an effect • Thicker paint has higher absorptance at low temperatures • Use specular paints for honeycomb or multi-bounce blackbodies
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