METO 621 Lesson 16 Transmittance • For monochromatic radiation the transmittance, T, is given simply by T ( ; ) e / and dT ( ; ) 1 e / d • The solution for the radiative transfer equation was: Transmittance I ( , , ) I ( *, , )e ( * ) / * 1 S e ( ' ) / d ' Which is equivalent to * I ( , , ) I ( *, , )T ( * , ; ) dT ( ' , ; ) S d ' d ' similarly dT ( , ' ; ) S d ' d ' 0 I ( , , ) I (0, , )T ( ; ) Transmittance • If we switch from the optical depth coordinate to altitude, z, then we get dT ( z, z ' ; ) I ( z, , ) I (0, , )T (0, z; ) S dz ' dz ' 0 z dT ( z , z ' ; ) I ( z , , ) I ( zT , , )T ( zT , z; ) S dz ' dz ' z zT • The change of sign before the integral is because the integral range is reversed when moving from to z Transmission in spectrally complex media • So far we have defined the monochromatic transmittance, T(). We can also define a beam absorptance ab() , where ab() =1- T(). • But in radiative transfer we must consider transmission over a broad spectral range, D. (Often called a band) • In this case the mean band absorptance is defined as 1 a b D (1 e k u )d D • Here u is the total mass along the path, and k is the monochromatic mass absorption coefficient. Schematic for A Transmission in spectrally complex media • Similarly for the transmittance TD 1 1 a D D k u e d D Transmission in spectrally complex media • If in the previous equation we replace the frequency with wavenumber then the product W a b D is called the equivalent width • The relationship of W to u is known as the curve of growth Absorption in a Lorentz line shape Transmission in spectrally complex media • Consider a single line with a Lorentz line shape. • As u gets larger the absorptance gets larger. However as u increases the center of the line absorbs all of the radiation, while the wings absorb only some of the radiation. • At this point only the wings absorb. • We can write the band transmittance as; TD 1 D S a u L d exp 2 D (( 0 ) a L ) Transmission in spectrally complex media • Let D be large enough to include all of the line, then we can extend the limits of the integration to ±∞. • Landenburg and Reichle showed that 1 x TD 1 e J 0 (ix ) iJ 1 (ix ) D Su where x J 0 and J1 are Bessel functions 2aL Transmission in spectrally complex media • For small x , known as the optically thin condition, Su T 1 D for large x, optically thick, 2 Su 2 T 1 1 a L Su D D 2x Elsasser band model Elsasser Band Model • Elsasser and Culbertson (1960) assumed evenly spaced lines (d apart) of equal S that overlapped. They showed that the transmittance could be expressed as T exp ycoth( )J 0 (iy sinh( )) dy 2aL Su where and y d d sinh( ) optically thin optically thick Su T 1d 2 T 1a L Su d Statistical Band Model (Goody) • Goody studied the water-vapor bands and noted the apparent random line positions and band strengths. • Let us assume that the interval D contains n lines of mean separation d, i.e. D=nd • Let the probability that line i has a line strength Si be P(Si) where P(S )dS 1 i 0 • P is normally assumed to have a Poisson distribution Statistical Band Model (Goody) • For any line the most probable value of S is given by 0 SP(S )dS S P(S )dS 0 • The transmission T over an interval D is given by 1 Ti D d P(S )e i D 0 ki u dSi Statistical Band Model (Goody) • For n lines the total transmission T is given by T=T1T2T3T4…………..Tn 1 T (D ) n d d ................. d 1 D 1 D n D 0 0 0 x P( S1 )e k1u dS1 P( S 2 )e k2u dS 2 ........ P( S n )e k nu dS1 1 ku T d P( S )e dS n (D ) D 0 1 1 D d P(S )(1 e D 0 ku n )dS n Statistical Band Model (Goody) n x The equation has the form 1 which in n the limit equals e x 1 ku T exp d P( S )(1 e )dS d D o assuming a Lorentz line shape, one gets 1 / 2 Su Su 1 T exp d aL where S is the mean line strength. Statistical Band Model (Goody) • We have reduced the parameters needed to calculate T to two S d and aL d • These two parameters are either derived by fitting the values of T obtained from a line-by-line calculation, or from experimental data. weak line Su T exp d strong line a S u L T exp d Summary of band models K distribution technique K distribution technique
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