1. INTRODUCTION Every living being on earth needs water to live, hence, it is called, “Elixir of life”. Water is essential for life forms including humans, right from the birth through all stages of life, until it diminishes from earth. Life certainly cannot exist without water. According to Routeledge (1998), 25% of the human body is made up of solid matter while the remaining 75% is water. Therefore if our bodies are not continuously supplied with water, our bodies become dehydrated and the vital organs will deteriorate until they are no longer viable for human life (De Kok, 2001). Water resources comprising of surface water (river and lakes) and ground water support all living beings in various ways. Though water is available on earth in huge quantity in the order of 1.4x109 km3, only 3% of the water is fresh water. Only about 5% of the fresh water (or 0.15% of the total waters in the world) is readily available for beneficial use (www.safewater.org). Fresh water is present on the surface of the earth as in lakes, ponds, rivers, some bodies of underground water and many kind of man – made fresh water bodies such as canals, ditches and reservoirs (Asthana and Asthana, 2003). Fresh water is a renewable resource, yet the world's supply of clean, fresh water is steadily decreasing. The demand for water already exceeds supply in many parts of the world and as the world population continues to rise, it is expected that this situation will continue to get worsen. A shortage of water in the future would be detrimental to the human population as it would affect everything from sanitation, to overall health and the production of food grain(Gleeson, 2012). 1.1. Surface Water Water that exists on surface of the earth is called surface water. Surface water includes the streams (of all sizes from large creeks), ponds, lakes, reservoirs and canals and fresh water wet lands. The definition of fresh water is water containing less than 1000 mg/L of dissolved solids. The amount of water in rivers and lakes is always changing due to inflows and outflows. Inflows are from precipitation, surface run-off, ground water seepage and tributary inflows. Outflows from surface water bodies include evaporation, infiltration and percolation and withdrawals by people (http://ga.water.usgs.gov). 1 1.2. Ground Water Under the earth‟s surface, water exists as ground water and it can be brought out through wells and bore wells. It is rich in dissolved minerals especially calcium and magnesium salts. Ground water comes from rain, snow, sleet that soaks into the ground. The water moves down into the ground due to gravity, pass between particles of soil, sand, gravel or rock until it reaches a depth where the ground is filled or saturated with water. The area that is filled with water just underneath the ground water table is called as shallow groundwater and hundreds of feet below, is called as deep ground water (Gray, 2006). The major portion of fresh water which goes in to the earth‟s crust is retained by its upper layers as soil moisture (about 1,650 km3). Only 500 km3 percolate down to the ground water deposits. A large portion (about 120 km3) moves down to the ground water table while 50 km3 of surface flow also end up as ground water. Therefore, a total of about 670 km3 of fresh water enters the ground water annually. It is up to this amount that we can withdraw fresh water from our sub- surface deposits (Asthana and Asthana 2003). 1.2.1. Ground water quality The quality of ground water is of great importance in determining its suitability for a certain use (public water supply, irrigation, industrial applications, power generation etc.). The quality of ground water varies from place to place, with the depth of water table, and from season to season and is primarily governed by the extent and composition of dissolved solids present in it (Gleeson et al., 2012). 1.2.2. Uniqueness of ground water Ground water is highly valued because of certain properties:1. It doesn‟t suffer evaporative loss, 2. It‟s free from sediments, mud and is biologically clean (if not polluted by human activities). 3. The absorption capacity is high during rainy season, which can be utilized during summer season. 1.3. Water Resources in India The total water resources available in India are 1850 km3, which is roughly 4% of the world's fresh water resources. India receives about 4,000 km3 of fresh water as precipitation every year. About 700 km3 of water thus received evaporate immediately 2 and are lost to the atmosphere. About 2,150 km3 reaches the soil, about 1,650 km3 retained as soil moisture while about 500 km3 permeate through the soil surface into underground water deposits. Only 1,150 km3 of fresh water received annually are retained on land surface (Sharma and Sharma, 1997). To 1,150 km3 of fresh water which appear as surface water within India, 200 km3 of surface flow which comes from outside which may be added. The surface flow is further enlarged by addition of 450 km3of fresh water from ground water flow while about 50 km3s are added as run-off from irrigated areas. The surface loses almost 50 km3of its water which percolates down to the ground water deposits. The total surface flow per year is about 18,000 km3, which are distributed along a number of river basins (Asthana and Asthana, 2003). 1.4. Water Resources of Tamil Nadu Tamil Nadu, the southernmost state of India, accounts for 4 per cent of the land area and 6 per cent of the population, but only 3 per cent of the water resources of the country. Most of Tamil Nadu is located in the rain shadow region of the Western Ghats and hence receives limited rainfall from the south-west monsoon. The total surface water potential of the state is 36 km3.There are 17 major river basins in the State with 61 reservoirs and about 41,948 tanks. The annual water potential is of 46540 million cubic meters (MCM).The utilizable groundwater recharge is 22,423 MCM. The current level of utilization expressed as net ground water draft of 13.558 MCM (which is about 60 percent of the available recharge), while 8875 MCM (40 percent) is the balance available for use (TNDR, 2005). 1.5. Water Resources of Ariyalur District: Ariyalur district is 29th district in Tamil Nadu. The Ariyalur Town is the headquarters of Ariyalur. The district has Vellar River in the north and Kollidam River in the South. The Marudaiyur River originates in Perambalur district and flows through Ariyalur district and finally joins the River Kollidam. The river flows in the southern boundary of Ariyalur district through Ariyalur and Udayarpalam Taluks. The Ponnar main canal starts from Kollidam left bank at mile 47/6 of Lalgudi and runs through Ariyalur and Udayarpalam Taluks. The total length of the Ponnar main canal is 317 kms and 1,900 hectares of lands is irrigated by canal. The Siddhamalli reservoir is situated in Karkudy village of Udayarpalam Taluk in Ariyalur district. The main 3 canal runs for a length of 9.8 km and an extent of 2,057 hectares, of lands are benefited by this reservoir (District Census Hand Book: Ariyalur, 2001). 1.5.1. Drinking water in Ariyalur Taluk In Ariyalur Taluk, a major share of drinking water supply is met by ground water. In many villages, the ground water is the one and only source of water for drinking, irrigation, domestic and industrial uses. In these villages, the ground water is pumped and stored in common over-head tanks for supply. As, the quality of the drinking water greatly determines the health of the people, it is imperative to protect the water from contamination. 1.5.2. Drinking water in Ariyalur Town Before 1987, Cetti lake water was the one and only source for domestic usage as well as for commercial use in Ariyalur Town. Two wells were constructed in Cetti Lake and the water of those wells was pumped and supplied through the overhead tanks. The municipality takes care of the lake. Since 1987, the people of Ariyalur Town are dependent on the municipal water supply and ground water for their domestic needs. People in Ariyalur Town are supplied with water from Kollidamriver through Thirumanur Combined Drinking Water Supply Scheme (TCDWSS). However, TCDWSS meets their drinking demand only. As a result, people depend largely on ground water for other uses (Municipal office in AriyalurTaluk, 2010). 1.5.3. Surface water bodies in the Ariyalur Town In Ariyalur Town, surface water bodies are used only for irrigation. In the southern region of the Town, people depend on the Chittheri lake and in the western region on the Arasattaneri lake and Kurinjankula Eari for irrigation. These lakes receive rain water during the rainy season (mainly from northeast monsoon). 4 Map-1.1: Ariyalur Township water bodies 1.5.4. Drinking water in the rural area of the Ariyalur Taluk A tank is constructed centrally in Kollidamriver at Thirumazhapaddi. Totally 14 sumps are set from Thirumazhapaddi to Rayamburam village. Some part of the study area that include, Sathyanagar, Ammenabath, Thamaraikulam, Venkataramanapuram, Ottakovil, Kallamedu, Poyyadanallur, Rayampuram are covered under the Thirumazhapadi Combined Drinking Water Supply Scheme. But, people say that this combined water is available only in nominal amounts. In villages people use the water from thelakes, wells and hand pumps for domestic purposes including drinking and irrigation in Ariyalur district. But,many ponds and lakes are found dry mostly except during rainy season. The information on drinking water sources of rural areas in Ariyalur Taluk was collected from village Panchayat offices and compiled which is presented in table-1.1. 5 Table-1.1: Drinking water sources of rural area in Ariyalur Union Rural areas Numbers of sources in Ariyalur union Numbers of sources spread in study area Numbers of sources – considered in the present study Overhead tanks for storage of ground water 192 125 40 2 Hand pumps 288 189 - 3 Power pumps 195 133 - 4 Low power pumps 55 35 - Total 730 482 40 Sl. No. Ground water sources 1 The information on drinking water sources of Ariyalur Town was collected from Municipality office and compiled which is presented in table-1.2. Table-1.2: Drinking water sources from municipal supply in Ariyalur Town Urban areas (Municipality) Numbers of sources in Ariyalur union Numbers of sources spread in study area Numbers of sources–considered in the present study Overhead tanks (TCDWSS) 5 5 5 2 Private 3 3 2 3 Sintex (Kollidam) 6 6 2 Total 14 14 9 Sl.No. Water sources 1 1.5.5. Water withdrawal level in Ariyalur Taluk Almost all the people of rural area in Ariyalur Taluk use ground water for their daily requirements. Each village has two bore wells with tanks. However, from questionnaire survey and field survey, the following inadequacies were observed: No proper maintenance of the storage tank (regular cleaning is not done) 6 Pipe lines are damaged either fully or partially There are no head pipes Water leakages occurs from tank Stagnation of water around the taps Solid wastes are dumped near the drinking water supply outlets Quality of drinking water is a powerful determinant of health. When the quality deteriorates, it affects the people‟s health. According to WHO, 3.4 million people die due to water related diseases, making it the leading cause of disease and death around the world. According to a study by UN, 4000 children die each day due to ingestion of contaminated water. The report further says that 4 out of every 10 in the world, particularly those in Africa and Asia do not have clean water to drink (voanews.com, 2009). Despite increased access to drinking water, 21% of communicable diseases in India were water related. 7,00,00 Indians died in 1999 due to diarrhea alone. Highest mortality from India was seen in children under the age below 5 (WHO, 2002). In the questionnaire survey, people reported that they were suffering from a number of water-borne diseases including diarrhea in Ariyalur Taluk. Due to the above two reasons, (ill maintenance of the community water supply facilities and incidence of water-borne diseases), the assessment of drinking water quality in Ariyalur Taluk gained importance. The awareness rally organized in Ariyalur Taluk about water-borne diseases and the importance of safe drinking water on July 14, 2011 (www.thehindu.com, 2011), also strengthened the need for drinking water quality assessment in Ariyalur Taluk. 7 1.6. Aim and Objectives In view of the above, the present study was undertaken with the aim of assessing drinking water quality in Ariyalur Taluk and its compliance with drinking water quality standards with the following objectives:1. To determine the water consumption rate by different users and especially for drinking purposes. 2. To identify the source of water for domestic use at various places in Ariyalur Taluk. 3. To determine water quality by analyzing water samples for physico-chemical and microbiological characteristics and comparing with the standards and by computing WQI. 4. To prepare GIS maps for spatial distribution water quality parameters in four seasons. 5. To establish the relationship among parameters by analyzing correlation coefficients of various parameters. 6. To find out the incidence of water-borne diseases in Ariyalur Taluk. 7. To ascertain variations in water quality spatially and seasonally using multivariate analysis. The findings of the present study with the above mentioned objectives may be of great help to the authorities in protecting water from contamination and ensuring safe water supply. The findings could be used to create awareness among public to protect water and use safe drinking water. 8 2. REVIEW OF LITERATURE A large number of studies on water quality covering community water supply, surface water and ground water with special emphasis on potability have been carried out by several workers and various Government Agencies around the world including India. Describing all of them may not be required and even, if described, it will make this work a voluminous one. Hence, the review of literature is limited to the studies that were deemed more relevant. Availability of several studies in literature led to the publication of several text books and reference books on water chemistry, water quality, water pollution etc. (Varshney, 1981; Warren, 1985; James, 1985; Murty, 1994; Sharma, 2007; Venkateswaralu, 1996; Gurjar, 1998; Pandey, 2000; Kudesia, 2000; Mishra, 2005; Goel, 2010; Rastogi, 2010; John, 2012; Sinha, 2012). Several studies on water quality of Rivers, Lakes, Watershed etc. in countries outside India are available in literature (Damann, 1960; Hohn, 1969; Lack, 1971; William, 1978; Starzecka, 1979; Marshall, 1980; Cushing, 1984; Golterman and Meyers, 1985; Biney, 1987; Eyre et al., 1999; Dabyet al., 2002; Little et al., 2003; Iwashita et al., 2003; Roussellier et al., 2003; Olia et al., 2004; Woli et al., 2004). In India, Central Pollution Control Board (CPCB) established a nation-wide network of water quality monitoring stations, called National Water Quality Monitoring Network (NWMP) under the scheme, Global Environmental Monitoring Stations / Monitoring of Indian National Aquatic Resource since 1977-78. It started with 18 stations initially and grew to 2500 stations in 2011-12 in 28 States and 6 Union Territories. It covers 445 Rivers, 154 Lakes, 12 Tanks, 78 Ponds, 41 Creeks / Seawater, 25 Canals, 45 Drains, 10 Water Treatment Plants, and 807 Wells. The monitoring is done on monthly or quarterly basis in surface waters and on half-yearly basis in case of ground water. The results are available with CPCB and published in its website (www.cpcb.nic.in). According to Allen et al (1980), urban water had been found to be safer than rural water for drinking in many parts of the world. China (2008) found in his study that Harbin, China affected by water shortage problems and hence, it was suggested to use water sparingly and / or use domestic appliances that use less water. Ajadi (2010) reported that metropolis in Nigeria received inadequate water supply with poor water quality (without better treatment). 9 In Jaipur, India, it was found that the portion of population with middle income and high income consumed greater amounts of water than people with low income (Jethoo, 2011). 2.1. Water Pollution-Surface and Ground Water Growth and development activities of society cause many changes including housing, development of road networks, expansion of services etc. All these changes are found to impact the precious water resources with water pollution (ENVIS, 2005). The main cause for fresh water pollution is attributed to discharge of untreated sewage, industrial effluent and agricultural runoff (Mullai, 2010). Such discharges increase the nutrient levels (phosphorous and nitrogen) to eutrophication of lakes and rivers (Nair et al., 2005). Eutrophication due to pollution was reported in ponds of Canchipur, Manipur by Devi et al., (2004). Mixing of sewage with water pipes at leaky water pipe joints is the common cause of drinking water getting contaminated in urban areas (Allen et al., 1980). Water pollution caused due to discharge of sewage/ industrial effluent/ agricultural runoff and miscellaneous sources have been studied and reported by several workers. Release of industrial effluents in a haphazard and unplanned manner without any treatment is one of the major causes of water pollution in urban industrial environment of India. These effluents, which are released on to land and into various surface water bodies, not only affect the water quality and soil, but also pollute the ground water due to seepage (Rao and Prapurna,2005). Disposal of treated and untreated industrial effluents containing hazardous metals and inorganic and organic matter of toxic nature on land is most widely practiced method in Indian cities (Wagh and Shrivastava, 2005). Keshavarzi et al., (2006) reported that the water consumption level dependent on the rural households, garden size, greenhouse size and garden watering times per month with tap treated water in Ramjerd area, Iran. Pushpendra (1994) and Chatarjee et al., (2007) reported that accumulation of organic matter in fresh water bodies was high during summer in Western India. Continuous discharge of sewage deteriorated water quality of lake. Singh et al., (1999) reported that the Damodar River upstream of Nalkari confluence was clean, but the water quality gradually deteriorated after joining Nalkari and running further through the urban-industrial areas. 10 Bhosle (2001) found that the copper level of the river water exceeded the standard in the river water Godavari at Nanded, Maharastra due to pollution. Increased concentration of heavy metals (Cd, Cr, and Pb) at discharge points in a river in Bihar was reported by Sandwar et al., (2006). Sharma (1999) concluded that the water of River Yamuna at Agra was unsuitable for domestic use and harmful for aquatic life due to pollution. Bhuvaneswaran et al., (1999) found that the Adyar river was highly polluted at certain stations which may likely affect the ground-water table. Prakash et al., (2005) by comparing water quality at Krishnarajasagar Dam and Dasanapura gauging station of River Cauvery reported that the river at both stations received pollutants continuously during dry and monsoon season Dash et al., (2010) reported that immersion of Durga Idol in Bramhani River polluted the river with bio-degradable and non-biodegradable substance that include clay, cardboard, bamboo, polyethylene, clothes, paper, wood, coconut, colors, paints etc. Umamaheshwari (2004) evaluated the water quality of River Thamirabarani and found that downstream site was highly polluted due to various municipal and agricultural farm wastes. Rizwanreza (2010) reported that the water quality of Brahmani River was bad and pose serious health hazards due to discharge of industrial waste water. Jayasree (1999) reported that Noyyal river water quality parameters values were greater than the standards due to pollution. Saxena et al.,(2005) studied physico–chemical pollution on River Sengar at district Etawah (U.P). They revealed that both during summer and rainy seasons, the BOD was high due to organic pollution. Yogeshpatil (2006) studied physico–chemical quality of Tapati River at Deepanagar area, Maharastra. It revealed that the Tapati River widely fluctuated in physico-chemical factors. Vidhyarani et al., (2006) reported that Nambul River at Imphal, Manipur was highly polluted by untreated domestic and household waste water. Khapekar et al., (2006) investigated of Kanhan River at Nagpur, Maharastra and found that the pollution level increased when compared to that of past. Sreenivas et al., (2006) reported that the River Godavari at Bhadrachalam in south India was polluted by untreated industrial effluents and sewage. 11 Rajamanickam et al., (2009)by monitoring the water quality of Amaravathy River basin and ground water in Karur district reported that the river and ground water quality deteriorated by bleaching and dyeing industries. Harikumar (2006) estimated that the water pollution and assimilative capacity of river Pamba, Kerala. Every year, during October to January increased pollution was noticed in Pamba river basin at Kakkinada and Kochupamba. Dwivedi (2003) reported that the river of Arunachal Pradesh, in hill region was unpolluted and fit for drinking as it was natural stream water. Khatavkar (1992) examined the river water quality of Maharastra India and found that the Kolhapur site – 3 and Ichalkaranjini site – 5 were highly polluted. Bath (1997) studies the pollution of Sutlej River and found that the downstream of Nagal lake site II was polluted by domestic and industrial waste; Garhshankar bridge site III and Ropar reservoir site IV were moderately polluted; and site 1 at Nangal reservoir was not polluted due to absence of industrial waste. Devi et al., (2005) studied water quality of Nambol River, Manipur with a note on its aquatic bio-resources and declared that the downstream water quality was poor. Jayaraman et al., (2003) reported that the water quality of Karamana River, Thiruvananthapuram was good due to the proper water quality management practices. Rajendran et al., (2001) conducted comparative study on pollution load of temple ponds at Puthur, Vayaloor, and Rockfort in Trichirappalli and found that all ponds were highly contaminated. Yogeshshastri et al., (2004) by analyzing physico–chemical characteristics of Nasik village pond concluded that the pond water was polluted and unfit for drinking purposes. Vikel (2006) found that the Lake Pichhola in Rajastan was in eutrophic condition and hence, the water was not suitable for drinking purposes. Nagargoje et al., (2012) analyzed water quality parameters of the Nazari dam of Maharashtra and found that the COD was higher during pre- monsoon and lower during summer. Kumar (2006) monitored water quality of tropical lake of Udaipur city, Rajasthan by analyzing physico – chemical characteristics for two years and concluded that the water samples were fit for drinking and other purposes. Hedge et al.,(2005) reported that the pond at Guruvayanakere and pond at Belthengady, Karnataka were polluted by the sewage and agriculture run off. 12 Sathyanarayana (1998) estimated eutrophication factors (sulphates, phosphate and nitrate) in the deterioration of water quality in Kakatiya canal- a drinking water resources of Warangal, Andra Pradesh. The study revealed that the sulphate was low during summer and high during winter; the phosphate was high throughout study period; and nitrate was low throughout the study period. Sirsath et al., (2006) found that the concentration of ions was minimum during winter and the maximum during summer in a fresh water pond in Dharmapuri District, Tamil Nadu, India. Udayakumar et al., (2006) analyzed physico–chemical and bacteriological characteristics of water from Namakkal and Erode districts, Tamil Nadu, India and found that the most of the physico–chemical parameters were within the limits except in Orathapalayam dam; the bacteriological population was high in all the samples. Maniraju et al., (2006) determined fluoride concentration of water in Vrishabharathi river basin and declared that surface water was found unfit for drinking purpose. 2.1.1. Ground water Lokanand et al., (2007) reported that ground water in Mumai was highly polluted due to industrial effluents. Isaiah et al., (2003) correlated dental fluorosis with fluoride concentration in ground water in Salem district and they found that 69.33% children were affected by dental fluorosis. Dasgupta (2003) analyzed water samples from pond, open well, tube well and tap water near Rajgangpur railway station and Rajgangpur Industrial area. The results revealed that the tap and tube well water was good, but the open well and pond water was moderately polluted. Chauhan et al., (1999) found that in ground water of Agra city, iron, zinc and lead were maximum during winter; cadmium and nickel during summer and copper during rainy season. Prasad (1997) studied the ground water quality in an industrial zone and found that high amount of minerals was present in water from most of the wells Jameel (2006) reported that heavy metals concentrations of ground water in Pettavaithalai area in Trichirapalli slightly exceeded limit, but not very bad. 13 Das et al., (2000) reported the fluoride hazards in ground water of Orissa and the origin of fluoride was attributed to geological source. Gupta (2010) evaluated the ground water quality around Kamadgiriparikrama at Citrakoot and found that Ca++ and Mg++ were above the WHO and BIS standards. Somasekhar et al., (1999) examined the ground water chemistry of Channapatana Taluk by Regression and cluster analysis. The results revealed that the Quality of 80% of wells were unsuitable for drinking in terms of hardness, 50% in terms of magnesium and 20% in terms of nitrates and calcium. Purandara et al., (2003) observed that increased salinity in ground water was caused by the improper drainage treatment and sewage disposal. Garget al., (1999) evaluated ground water quality in some villages of Jind, Haryana and found that the groundwater was heavily loaded with inorganics to pose serious health hazards if used for longer periods. Tripathy (2003) determined the ground water quality in and around Bhanjabihar area, Orissa and found that the samples were good and fit for drinking and agricultural activities. Suthar et al., (2005) reported that ground water at many places in Sri Ganga Nagar, Rajastanwas unfit for drinking and domestic purposes. Kumaravel et al., (2003) evaluated ground water contamination due to municipal garbage based on age of dumping sites and types of soils and concluded that the ground water was highly contaminated near the dumping site in sandy soil while less contaminated near the dumping site located in clay soil. Prajatpathi (2005) analyzed ground water quality in rural areas of Madya Pradesh during summer, winter and rainy season using statistical tools. Most of the samples were within the desirable limits except parameters like calcium during winter. Mariyappan et al., (2004) analyzed of physico–chemical characteristics of ground water in and around Sivakasi using water quality index and concluded that twenty water samples were not fit for drinking purposes. Rao et al., (2005) analyzed ground water quality of Nellore coast and reported that the study area was saline and consists of high sodium chloride, magnesium bicarbonate and sodium sulphate. Singh et al., (2006) investigated a general survey of ground water for physicochemical parameters in Churu, Rajastan and found that the fluoride and nitrate 14 exceeded the standards. Vajpai et al., (2007)reported that the fluoride and nitrate exceeded the WHO‟s standards in ground water of Korba. Murugesan et al.,(2007) analyzed ground water quality in Madurai and found that BOD values were higher than permissible limit. Dhash et al., (2007) examined the ground water quality in rural areas around Angul–Talcher industrial zone, Orissa. The results revealed that the dug well water samples were not fit for the drinking purposes. Tambekar et al., (2007) analyzed physico-chemical characteristics of ground water in Amaravati city and computed water quality index that revealed that the water samples were of fair quality. Basvaraddi et al.,(2012) characterized ground water quality in and around Tiptur Town, Karnataka by correlation and regression analysis. The results revealed that the high degree correlation was found between EC & Chloride and TDS & Chloride while low degree correlation was found between EC & Ca, TDS & Ca, and Chloride & Ca. They concluded that ground water was free from contamination. Singh et al., (1999) analyzed the contamination of ground water from industrial effluents which were disposed of largely in open without proper treatment and found that the presence of chromium and cyanide in groundwater was beyond permissible limits. Dexit (2003) reported high heavy metals concentration (Cd, Cu, Mn and Se) in surface and ground water supply of an urban city in Delhi. Shahnawaz et al., (2009) examined ground water quality of some blocks in Bihar and found that all the parameters were within the permissible limit except arsenic. Prakash et al., (2006) analyzed ground water quality of Anekal Taluk, Bangalore urban district and the samples were found to contain calcium, chloride, iron and sulphate. Adekunle (2007) analyzed ground water quality in a typical rural settlement in southwest Nigeria and found that all the water samples were contaminated by municipal waste dumps. Hence, it was concluded that well water samples were not fit for human consumption before treatment. Sohu et al., (2007) had examined ground water quality of villages of Sanganer Tehsil with reference to fluorosis and found that the fluoride ranged from 0.4 to 6.4 mg/l and caused fluorosis (dental and skeletal). 15 Kodapanah et al., (2009) examined the ground water quality for different purpose in Eshtehard district, Tehran, Iran. Based on sodium adsorption ratio (SAR), they reported that all the samples were not fit for drinking and other household purposes and some samples were not fit for irrigation purpose. Kavitha (2010) analyzed the ground water quality in Erode district, Tamil Nadu, India and computed WQI. The WQI results revealed that most of the samples were moderately polluted. Rani (2006) studied the hydrochemistry of ground water of Thirumanur area, Tamil Nadu, India. The results revealed that the excess amount of hardness and nitrate affected the village people. The discharge of wastewater from urban environment was attributed to the contamination. Jain et al., (1997) studied the quality of ground water in a Town in the East Godavari District of Andhra Pradesh to evaluate its suitability for irrigation and domestic applications. The higher values of certain parameters at various locations indicated the influence of sea water and they made the water unsuitable for domestic applications. A study was carried out by Garode et al., (1997) to recorded fecal indicator bacteria of several groundwater samples collected from different regions of Chikhali Town Akola city. Higher MPN Counts were recorded in some samples. Elampooranam and Rengaraj (1998 and 1999) collected ground water samples from about 46 wells located in Nagapattinam and Thanjavur district and analyzed. The result showed that in 20 wells, the recommended limits for drinking water quality exceeded in one or the other parameters. Only a few water samples were found unsuitable for irrigation. Chauhan et al., (1999) monitored the seasonal concentration and speciation studies of heavy metals in ground water drawn from various areas of Agra city. The results indicated that iron, zinc and lead were found maximum during winter; copper in rainy season; and cadmium and nickel in summer. Dash et al., (1999) assessed the physico-chemical characteristics of groundwater in the Hemgiri block of Sundargarh district and concluded that the ground water was suitable for both domestic and irrigation use. Buragohain et al., (2009) found out that the concentrations of aluminium, lead and cadmium in ground water were significantly elevated. High concentrations of all the metals were recorded in the dry seasons rather than in the wet season. Statistical 16 analysis of the data revealed non-uniform distribution of the metals in the area. The metal contamination of ground water in the district followed the trend Al>Pb>Cd>As in both of the seasons. Singh and Chandel (2004) collected the ground water samples from various hand pumps of eight adjacent localities of various industrial areas in Jaipur. The values were compared with standards of ISI, ICMR and WHO. It was observed that the pH, EC, Ca2+, Na+, K+, Mg2+, SO4- ,CO3-, HCO3- , Cl-, DO and BOD values were within permissible limits of ISI, ICMR and WHO but NO3-, TDS, COD and WQI values revealed poor water quality in most of the groundwater samples. Rani and Babu (2008) carried out hydrochemical investigation of the coastal area between Kollamkode and Kanyakumari. The groundwater of this area up to a distance of 250m was found to be brackish to saline in nature. Concentration of anions like nitrate, nitrite and sulphate were within the limit prescribed by WHO and the phosphate concentration was above the limits, which may be due to saline water mixing. Na+ and Cl- were fairly high, and so it could be deduced that for most of the groundwater samples Na+ and Cl- originated from a common source. Buragohain et al., (2009) carried out a study with respect to chromium, manganese, zinc, copper and nickel contamination of groundwater in Dhemaji district of Assam, India. Twenty groundwater samples were collected from tube well and ring well in both dry and wet seasons. It was ascertained that a sizeable number of groundwater samples contained chromium, manganese and nickel at toxic level. Copper and zinc content of groundwater was found to be within the guideline value of WHO. High concentrations of all the trace metals except for chromium were recorded in the dry season than in the wet season. Statistical analyses of the data revealed that the distribution of various metals in the study area was widely off normal. The metal concentration of groundwater in the district followed the trend Zn>Mn>Cr>Cu>Ni in both the seasons. 2.2. Drinking Water The major sources of drinking water supply in our country are rivers streams, wells, tube wells and bore well. About 10-15% of India‟s population gets piped, filtered, clean drinking water and the rest have to depend upon unfiltered natural water from rivers, ponds and tube wells. Even in those metropolitan cities and big Towns, where people get piped filtered water from municipalities and corporations, the quality 17 of water is not good due to sewage contamination. Consequently, the majority of people suffer from water borne diseases, especially in rainy seasons (Latif et al., 1997). Ramakrishnan et al., (1991)studied the physico-chemical parameters of five drinking water sources at Thiruvannamalai. All parameters were found to be in the permissible limit except Calcium and Magnesium. Nagarajanand Priya (1999) had conducted ground water quality in Thiruverambur village in Trichy district. Ten different water samples were collected from hand pump, well water and pond water. The results revealed that TSS, Iron and Magnesium values were higher than permissible limits. Sangeetha (2000) studied ground water quality of seven villages around Udaiyarpalayam, Tamil Nadu. The results revealed that some of the samples exceeded the standard values. Rani et al., (2003) had analyzed the drinking water quality of five rural places in and around Thitakudi in Tamil Nadu. Most of the samples had high values of TDS &alkalinity. Dhankar (2004) had collected water samples from different sources like well water, tank water, hand pumps and government canals in different regions of Mahendergarh, Haryana. The results revealed that the tap water and hand pump water were suitable for drinking purpose compared with other sources. Rajan (2005) evaluated drinking water quality in Dindigul, Tamil Nadu. The study revealed that all the water samples were not fit for drinking purpose. The reason was due to high level of electrical conductivity and inorganic salts. Kumar et al., (2006) carried out the physico-chemical and bacteriological analysis of drinking water in Tiruchirappalli and found that nine water samples were fit for drinking purpose. Narayana et al., (2005) investigated of drinking water quality of Basavanahole tank with reference to physico-chemical characteristics. The results revealed that the water quality parameters were within the permissible limit and hence, water samples were fit for drinking and irrigation purposes. Ranjana et al., (1997) reported that Darbhanga tube well drinking water was good and safe drinking water in Bihar. Panda et al., (1998) found that Chandai reservoir water quality was good and fit for drinking and domestic purposes. 18 Drusilla et al., (2005) reported that the Harihara stream water can be used for irrigation, bathing, washing, but not for drinking. Pandian et al., (2005) examined physico-chemical characteristics of drinking water in selected areas of Namakal Town, Tamil Nadu, India. Physico-chemical parameters and bacterial quality of coliform count varied in drinking water widely. Subramani et al., (2005) analyzed ground water quality for drinking and agricultural use in Chithar river basin Tamil Nadu, India. This analysis revealed that the ground water was slightly alkaline and highly saline in nature. They concluded that water was not fit for drinking and irrigation due to high hardness and TDS. Devi and Belagali (2005) evaluated the water quality from different districts of southern Karnataka. The results revealed that the physico-chemical parameters were within the permissible limit, but the bacterial coliforms were excess in some samples. Tambekar et al., (2005) carried out multiple anti biotic Resistance (MAR) indexing to discriminate the source of fecal contamination in drinking water. The study revealed that the non- human sources was low, but human sources was high. Prajatpathi (2005) had done comparative study of drinking water of Sheopur Town and adjacent villages. The bacteriological quality of ground waters in sheopur and adjacents areas from hand pumps were suitable for drinking purpose, while open well water was highly contaminated with fecal coliform. Agarkar (2005) evaluated the status of drinking water quality in school in Buldana district of Maharastra. The results revealed that the physico-chemical parameters were within the permissible limit, but the microbiological parameters exceeded the limits. Peter (2002) estimated and projected deaths from water related diseases during 2000–2020. This paper exposed that the safe drinking water and adequate sanitation were not provided to all people. He projected that there would be 76 million deaths from water related diseases by 2020. Mahananda et al., (2010) analyzed physico–chemical characteristics of surface and ground water of Bargarh district, Orissa, India. The results revealed that the surface water quality was above the permissible limit, but the ground water was below the pollution level. So the ground water was fit for drinking, agriculture and industrial purposes. Wagh (2005) analyzed the impact of heavy metals on soils and ground water. The heavy metals (Cu, Zn, & Fe) exceeded level in industrial area. 19 As bacterial contamination of water is common in many parts of the world, especially in developing countries, Antipchuk et al., (1977) emphasized the need for microbial investigation of water in order to ascertain the quality of water. Patralekh (1991) reported that due to drinking of untreated pond water with bacterial contamination caused intestinal disorders and water-borne diseases in Bihar, India. Bharat (1991) reported that the ground water and pond was contaminated by bacteria from sewage in Aligarh. It was suggested that proper sewage treatment and sterilization of vegetables before market were must. Gowrishankar et al., (1998) from their evaluation of bacterial quality of rural drinking water systems in Alwarkuruchi Town Panchayat situated at the foothills of Western Ghats, declared that the total coliform and fecal coliform contamination was very high in the pond water while it was very low in Town Panchayat water supply. Kannan et al., (2001), proved bacterial contamination of potable water in Rasipuram and Thiruchengode Taluks, Tamil Nadu, India, by isolating of Vibrio sp., Escheriachia coli, Salmonellasp.and Shigella sp.in many samples. They also found that bacterial contamination was very high in open wells while it was low in bore wells. Chhabra (2003) established contamination of drinking water by coliforms in Bikaner, Rajasthan, India and it was major cause for occurrence of water-borne diseases. Natural water body is not simply body of water alone. It is a system of living organisms and their interactions and inter-relations among themselves and with nonliving components of water, soil, sediments, etc. This system is called “aquatic ecosystem”. The planktons are the minute living organisms that form the base for the food chain and food web of any aquatic ecosystem. Therefore, their presence, their diversity and abundance indicate the quality of water. Polluted waters normally have less types and numbers of these organisms (Sinha and sinha. 1993). Sinha et al (1993), from the analysis of pond water in Bihar, established a relationship between physic-chemical parameters such as temperature, pH, DO, chloride and phosphate and zooplankton density. Murugan (1994) reported that zooplankton density varied diurnally with high density at 6 a.m. and midnight in Maduranthakam Tank. Guptha (1993) reported that 20 zooplankton density was very high during night hours in a shallow pond in Udaipur, Rajasthan, India. Mruthunjaya (2004) found that plankton population dominated due to high phosphate levels in Mysore Lake. Pushpendra (1994) reported that zooplankton diversity varied seasonally (low in September and high November, February and April) in a pond in Manglaore, India. This variation was attributed to variation in acidity values of pond water. Abdussaboor (1995) reported that zooplankton density was high during rainy season (267/L) and low during summer (71/L) in a tropical pond. Sedamkar and Angadi (2003), from their comparative study between two fresh water bodies in Gulberga, India, established a relationship between the concentration of certain physic-chemical parameters and the growth of phytoplankton. Prasad (2003) used various algal indices to determine the organic pollution level in a fresh water body in Thiruvannamalai, India and concluded that the water body was highly polluted. Sobha et al., (2006) found that water pollution due to saline water intrusion and husk retting activity affected the rotifer‟s (zooplankton) population in Kadnamkulam Lake in Southern Kerala. 2.3. Geology of Ariyalur It has been estimated that 16250 ha were under minig in Tamil Nadu of which 3285 ha were in the district of salem followed by 3155 ha in cuddalore district. The other districts which had fairly substantial area under this category include Namakkal, Tirunelveli, Sivagangai and perambalur (Tonapi, 1980).Ariyalur is famous for its cement industries in and around it. This is possible due to its immense limestone store which is the potential raw material for cement industries. In particular Arasu, Birla, Sakthi, Dalmia, Ramco, Chettinadu, Dalmia, Tamil Nadu cements etc. are situated in Ariyalur. So Ariyalur is one of the busiest transport cities(District census 2011). The rocks of the Ariyalur group are mainly sandstones and shell banks and occupied a large area compared to the other two groups. Cuddalore sandstone (younger tertiary rocks) are showing largely over the Ariyalur group of rocks which are indeed responsible for the preservation of the cretaceous rocks. The cretaceous rocks of the Ariyalur area in the Cauvery basin have been classified both lithostratigraphically and biostratigraphically. Lithologically, they are divided into three groups, viz. Uttatur, 21 Trichinopoly and Ariyalur groups in the ascending order and these groups include many formations. Department of geology, Anna University in Chennai, studied on targeting limestone and bauxite deposits in southern India by spectral un mixing of Hyperspectral image data. This study revealed that to identified the bauxite deposited area in the Kolli hills and the limestone deposited area in the Ariyalur in south India. Sundaram and Rao (1984) recognized new formational units for the Uttatur and Trichinopoly groups and they were Arogyapuram, Dalmiapuram and Karai formation for the Uttatur group, Kulakkanatham and Anaipadi formations for the Trichinopoly group. They retained the classification of Ariyalur group (Sillakudi, Kallankurichi & Kallamedu formations – clubbing Ottakoil formation and Kallamedu formation into one formation). Sundaram et al., (2001) gave a detailed description of the lithostratigraphy of the cretaceous rocks of Ariyalur, Vriddachalam and Pondicherry. ONGC has classified the cretaceous rocks based only on the lithographic characters. 22 3. MATERIALS AND METHODS 49 villages and one Town (Ariyalur Town) in Ariyalur Taluk of Ariyalur District were selected for the present study. The details of Ariyalur district and Ariyalur Taluk are described in the following sections. 3.1. Geographical Location of Ariyalur District: Ariyalur district is the 29th district in Tamil Nadu, India. This district is surrounded by Nagapattinam in east, Trichirappalli in the southwest, Thanjavur in south and southeast, Cuddalore in north and northeast and Perambalur in the west. (http://www.ariyalur.tn.nic.in/Distt/Profile/DisttProfileGenl.html) Map-3.1: Ariyalur district map As per the Government G.O.MS.No. 657 Revenue (Ra-1(1)) Department dated, 29.12.2000, Ariyalur district was formed from the composite Perambalur District which was bifurcated from Trichirappalli in 1995. Ariyalur district was declared as a separate district from 1.01.2001. It occupies an area of 1949 km2. It has 3 Taluks (Ariyalur, Sendurai and Jayankondam), 6 Unions (Ariyalur, Andimadam, Sendurai, Thirumannur, T.Palur and Jayankondam), 4 Towns (Ariyalur, Jayankondam, Udaiyarpalayam and Varadarajanpettai), 212 villages and 165,569 Households. The administrative offices are located at the headquarters, Ariyalur Town. The details of Ariyalur District are presented in table-3.1. 23 Table-3.1: Details of Ariyalur District Sl. No 1 Taluk Town Panchayats Sendurai Urban/Rur al Houses Total 24,858 Rural 24,858 Urban 0 Total 83,463 Rural 72,218 Urban 11,245 Urban 7,022 31,268 Urban 2,440 11,320 Population Block Villages Sendurai 28 Jayankondam 36 Andimadam 37 102,741 3,58,467 Udaiyar 2 Jayankondam Palayam Udaiyarpalayam Varadarajanpettai 3 44 T.Palur Urban 1,783 8,575 Total 57,248 234,316 Rural 50,943 206,494 Urban 6,305 27,822 6,305 27,822 Ariyalur 32 Ariyalur Ariyalur Total Urban Total 165,569 Rural 148,019 Urban 17,550 Thirumanur 35 695,524 212 3.2. Geology of Ariyalur Geologically, Ariyalur is fairly rich in limestone deposits. About 600 million years ago, Ariyalur was under the sea and sea receded during late cretaceous period resulting in the terrestrial ecosystem (Rani, 2005). Mineral deposits (celeste, limestone, shale, sandstone, canker and phosphate nodules) occur at various places in the district (Plate-3.1). Mineral and mining details are presented in table-3.2. 24 Plate-3.1: Mineral deposits in Ariyalur Taluk (Source: Arasu cements museum) Table-3.2: Mineral and mining details for the year 1999-2000 Sl.No Name of the mineral Quantity mined Royalty/ Seigniorage fee collected in Rs. 1 Limestone 38,80,325 Tones 70,25,39,000 2 Fire Clay 41,000 32,80,000 Lateritic 900 Lorry 3 62,175 Gravel Loads+5 tractor loads 4 Kankar - - 5 River sand - - Total Revenue 70,58,81,175 Source: (District Census Hand Book: Ariyalur, 2001) 3.2.1. Soil types in Ariyalur District: The district consists of red sandy soil with scattered pockets of block soil. The soil testing laboratory found that the major types of soil in the district are black cotton soil (45,648 hectares), red soil (3,802 hectares) and clay soil (20.142 hectares) (District Census Hand Book: Ariyalur, 2001). 3.2.2. Land use pattern in Ariyalur District: The forest resources of this district are meager as compared to the state as a whole. While 16.64% of the total geographical area of the state is under forest, this district has only 6.85%. In this district forests are not only small in area but also poor in quality. The chief forest product is fire wood (Caesuarians, bamboo, eucalyptus 25 hybrid) and to a lesser extent sandalwood and timber such as teak and rosewood are the common trees. Land use pattern in Ariyalur District is presented in Table-3.3. Table-3.3: Land use pattern of Ariyalur district Classification District (Area in Hectares) 1 Forest 739.495 2 Barren and Uncultivable uses 8523.395 3 Land put to Non-Agricultural uses 32321.425 4 Cultivable Waste 3223.045 5 Permanent Pastures and Other Grazing Land 1291.285 6 Land Under Various Tree Crops and Woods not included 19222.505 in Net Area Sown 7 Current Fallow 11501.560 8 Other Fallow Lands 8367.750 9 Net Area Sown 107607.690 10 Geographical Area According to Village Papers 193398.150 11 Total Cropped Area 115120.525 12 Area sown more than once 7512.835 3.3. Agriculture Agriculture is the major activity in this district. The principal crop is paddy. Maize and cotton are grown as rain fed crops. Oil seeds such as groundnut and sunflower and pulses like black gram, green gram and red gram are grown considerably. The area under cultivation and the production are presented in table-3.4 and Agricultural products are presented in Table-3.5. Table-3.4: Agricultural land in Ha. 2010-11 in Ariyalur District Total Cultivated Area 115121 Net Area 107608 Area Sown more than once 7513 26 Table-3.5: Agricultural products in Ariyalur district Sl.No Crops Area in ‘000’ Production in ‘000’ Tonne (2010-11) 1 Rice 25.211 92292.316 2 Sugarcane (cane) 7.500 2122537.500 3 Groundnut 12.058 29592.489 4 Ginelly 1.228 239.006 5 Cotton (Bales of 170 Kg lint each) 5.684 5.134 6 Onion 0.053 52331.393 7 Tapioca 0.245 92332.217 8 Cashew 30.458 7237.291 9 Chillies 1.214 1.573 10 Maize 9.996 14.674 3.3.1. Irrigation of Ariyalur district Table-3.6: Major irrigation tanks in Ariyalur district Sl.No. Name of the Tanks 1 Rayampuram big tank, 2 Nakkambady tank 3 Kulumur big tank 4 Ponneri tank 5 Sengal tank 6 Sundakuli tank 7 Vannankkuliodai tank 8 Sripuranthan tank 9 Kokvaithattai tank 27 The major area in this district has only rain fed crop. Thirumanur and T.Palur are only wet areas under the Cauvery delta. So, the cultivation depends mainly on the wells and tanks. As per the 1999-2000 Censes, there were total number of tanks - 544, open wells -10,274; and tube wells -7,059. Totally 24,594 hectares of land was irrigated through these sources. In Ariyalur District, 63 tanks are situated in Ariyalur, Udayapalayam and Sendurai Taluks. An extent of 2,582 hectares of land is being irrigated by these tanks. The major tanks haveay acuts. Sources of water for irrigation are presented in table-3.7 and important lake and ponds of Ariyalur district presented in table-3.8. Table-3.7: Sources of water for irrigation Irrigated Area (in Ha.) Gross NET Government Canals 7840 7430 Tanks 4018 3943 Tube Wells 21225 18535 Other Wells 5817 4701 Total Area Irrigated 38900 34609 Table-3.8: Important Lakes and ponds of Ariyalur district 1 Ariyalur Block NagamangalamAndiEari, KallankurichiEari, Ariyalur Sitheri, VilankudiPeriyaEari, VellurPeriyaEari, ThelurPeriyaEari, RayampuramEari, AgaramPeriyaEari, UppuodaiPeriyaEari. 2 ThirumanurBlock ArasanEari, Andiodai, VettakudiEari, ThoothurEari, ManodaiEari, SukkiranEari, VannanEari. 3 Jayankondam Block PonEari, ValavanEari, PandianEari, VeeramangudiOdaiEari. 4 T.Palur Block SripuranthanPeriyaEari, SundakudiEari. 5 Andimadam Block KallankuliEari, KattathurPeriyaEari, Anikuthichan, SathanapattuEari, VilanthaiPeriyaEari, Periya KrishnapuramPeriyaEari. 6 Sendurai Block NakkampadiPeriyaEari, KulumurPeriyaEari, SenduraiPeriyaEari, NallanayagapuramEari, EachankattuPeriyaEari, ThalavaiPeriyaEari. KaraikurichiKovathattaiEari, 28 Table-3.9: Details of surface water resources and their present position Sl. No 1 2 3 4 5 6 Name of the panchayat Thavuthaikulam Subrayapuram Pudupalaiyam Melakarupur Valajanagaram Venkadakrishnsp uram Name of the lake Ayac ut in acre Details in Under the irrigation area Irrigation lake Supply in m Last conservat ion process Kalyanasellappattueri 3.69 Ammakulam 3.69 2009-2010 Thorattieri 42.33 Thavuthaikulam 42.33 17.6.2010 Udaiyaneri 9.16 Ammakulam 9.16 Still processing Kumaradieri 23.79 Rengasamuthira m 23.79 2009-2010 Subbrayapurameri 12.66 Subrayapuram 12.66 2009-2010 Krishna puraththaneri 1.81 Pallkrishnapuram 1.81 March 88 Aadhithiravidareri 18.12 Pudupalaiyam 18.12 April 90 Palayaththueri 27.30 Pudupalaiyam 27.30 Still processing Chinneri 1.22 Karuppurpoyyur 1.22 April 87 Kallareri 3.73 Karuppurpoyyur 3.73 March 88 Kumarasamypillaieri 2.62 MelaKaruppur 2.62 April 89 Pudueri 8.53 Karuppurpoyyur 8.53 March 88 Narayanasamyeri 17.00 Valajanagaram 17 March 88 Sarvaikuttai 2.00 Valajanagaram 2 March 89 Sarvaikkaraneri 5.67 Valajanagaram 5.67 April89 Vadakkaiyaarueri 0.43 Valajanagaram 0.43 April89 Kaliyugavaradharajap erumaleri 9.79 Valajanagaram 9.79 March 88 Ravuthanpattiperiyank uttai 3.58 Ravuthanpatti 3.58 March 90 Sandhaanaeri 10.2 Ravuthanpatti 10.2 August 88 Venkadakrishnspuram eri 0.24 venkadakrishnsp uram 0.24 March 87 29 Marudhappaudaiyaane ri 1.50 venkadakrishnsp uram 1.50 April 88 Aalangudiyaaneri 6.63 venkadakrishnsp uram 6.63 2008-2009 7 Siruvaloor Perumaal redid eri 22.75 siruvaloor 22.75 2009-2010 8 Asthinapuram Vellamuththueri 1.05 Asthinapuram 1.05 2008-2009 9 Periyanagalur Alagappaudaiyareri 5.23 kattupiringiyam 5.23 2008-2009 China arunaachalapadaiyachi eri 5.94 kattupiringiyam 5.94 2009-2010 Melakaruppudaiyaarer i 1.34 kattupiringiyam 1.34 March 87 Moongileri 1.71 Periyanagalur 1.71 April 87 Muniyankulam 0.92 kattupiringiyam 0.92 March 86 Muthupadiyachieri 1.47 Kattupiringiyam 1.47 April 87 Periyaarunachalapadai yachieri 3.22 kattupiringiyam 3.22 March 87 Periyaeri 26.04 Periyanagalur 26.04 April 88 Ponnambalapadaiyach ieri 0.70 kattupiringiyam 0.70 March 86 Pudhueri 1.83 periyanagalur 1.83 March 86 Pudhueri 2.30 kattupiringiyam 2.30 April 88 Kolaikuzhieri 19.86 Thelur 19.86 March 87 Nallaudaiyaneri 0.63 kudisal 0.63 March 88 Muthumoopaneri 2.56 kudisal 2.56 April 89 Periyaeri 39.16 mannuzhi 39.16 2009-2010 Alagappapadaiyachieri 2.01 reddipalayam 2.01 2010-2011 Appasamypadaiyachie ri 2.01 reddipalayam 2.01 2011-2012 Aarumugamooppaneri 1.71 reddipalayam 1.71 2009-2010 China eri 10.68 reddipalayam 10.68 2011-2012 10 11 Thelur Reddippalayam 30 12 13 14 Kayarlabath Srinivasapuram Kallangurichy Ganapathimooppaneri 1.70 reddipalayam 1.70 April 88 Periyaeri 4.44 reddipalayam 4.44 2009-2010 Kakkarukuttai 9.81 Kayarlabath 9.81 March 88 Konaareri 5.34 Kayarlabath 5.34 2011-2012 Pukudaiyaaneri 3.41 Kayarlabath 3.41 March 88 China eri 3.32 Srinivasapuram 3.32 2009-2010 Paalaiyaneri 8.93 Srinivasapuram 8.93 2009-2010 Pudhueri 6.67 Srinivasapuram 6.67 March 90 Muniseeperi 2.97 Kallangurichy 2.97 March 88 Samberi 1.83 Kallangurichy 1.83 April 89 15 Manakkudi Periyaeri 46.55 Manakkudi 46.55 2009-2010 16 Kaduhoor Beemaneri 42.96 Kaduhoor 42.96 2010-2011 Konaarkulam 2.33 Kaduhoor 2.33 March 88 Muthukaruppupadaiya chieri 1.12 Kaduhoor 1.12 March 89 Pudhueri 6.14 Kaduhoor 6.14 April 88 Pudhukalaareri 3.13 nuraiyur 3.13 Processing Vannimudaiyaaneri 22.92 tlaiyarikudukadu 22.92 2010-2011 Ayanaathurpudueri 11.43 Ayanaathur 11.43 March 88 Alangarankuttai 1.71 Eruthukkaranpatt i 1.71 March 88 Appakannueri 2.58 Mahalingapuram 2.58 March 89 Panchavarthasekavarth aneri 6.1 Mahalingapuram 6.1 April 88 Vellarikuttai 2.89 Thamaraikulam 2.89 proccesing Morakkarankuttai 3.16 Thamaraikulam 3.16 March 87 Kaanavaayankuttai 2.44 Thamaraikulam 2.44 March 87 Muthuveludaiyankutta i 3.14 Thamaraikulam 3.14 April 88 17 18 Eruthukkaranpatt i Thamaraikulam 31 19 20 21 22 23 Ottakovil Iluppaiyur Rayampuram Sennivanam Govindhapuram Nallappaudaiyankuttai 5.83 Thamaraikulam 5.83 March 89 Dhuraieri 0.68 Thamaraikulam 0.68 March 90 theluraaneri 0.66 venkadaramanap uram 0.66 March 90 Karuppuudaiyaneri 3.82 kallamedu 3.82 March 89 Nallamuthupadaiyachi eri 5.90 salaiyakurichi 5.90 April 87 Madhaarsahiperi 3.63 salaiyakurichi 3.63 March 87 Chinnaiyanudaiyareri 3.72 kallamedu 3.72 March 88 Vathiyalingudaiyareri 4.10 Ottakovilkuthur 4.10 April 87 Ottakoothurperiyaeri 3.80 Ottakovilkuthur 3.80 Processing Karuppaiyaudaiyareri 2.86 Iluppaiyur 2.86 March 88 Kumarapudaiyaneri 1.51 Iluppaiyur 1.51 March 88 Poyyadhanallurperiyae ri 44.78 Iluppaiyur 44.78 14.8.08 Vengurueri 51.86 Iluppaiyur 51.86 30.7.09 Aadhikudikadunaachi muthueri 25.02 Aadhikudikadu 25.02 Processing Chinnaiyaudaiyareri 2.33 kaveripalayam 2.33 March 86 Idaiyankulam 44.93 rayampuram 44.93 30.7.2009 Arasukulam 53.19 Sennivanam 53.19 April 88 Kulambankuttai 21.24 Sennivanam 21.24 13.8.09 Sellakuttaieri 18.10 mettupalayam 18.10 Processing Sisayanganeri 0.73 Sennivanam 0.73 March 88 Letchumanapadaiyach ieri 1.12 Govindhapuram 1.12 March 89 Parayankuttai 5.65 Govindhapuram 5.65 April 88 Rayampurathaaneri 5.92 Govindhapuram 5.92 5.3.09 Sekkapadaiyachieri 8.5 Jeyaramapuram 8.5 22.04.201 0 32 Udaiyareri 4.25 Govindhapuram 4.25 10.06.201 0 Karuppuudaiyareri 0.64 Jeyaramapuram 0.64 April 88 Ramasamyudaiyareri 2.05 Jeyaramapuram 2.05 March 89 Pachamuthuudaiyareri 1.0 mahalingapuram 1.00 processing Rainfall details in Ariyalur District are presented in Table-3.10. Table-3.10: Rain fall in Ariyalur district 2010-11 Monsoon Normal(in mm) 1043.0 Actual(in mm) 1210.8 North East 514.4 759.1 South West 349.3 329.4 Winter Period 32.5 29.3 Hot Weather Period 101.8 93.0 3.4. Ground Water Resources at Ariyalur District: In Ariyalur district, a major share of drinking water supply is met by ground water. In many villages, ground water is one and the only source for drinking, domestic, irrigation and industrial uses. Figure-3.1 shows the ground water levels in Ariyalur District from 1991 to 2010. The ground water level increases in the Premonsoon season (http://www.twadboard.gov.in/twad/ariyalur_dist.aspx). 33 20 18 16 14 M 12 10 PreM 8 PostM 6 4 2 0 year Figure-3.1: Average Ground water level in Ariyalur district 3.4.1. Geological features and their intrusion on the water quality The entire Ariyalur district is covered by sedimentary formations of Cretaceous and Tertiary age with alluvial formations mainly in the south. 3.4.1.1. Occurrence of ground water: Alluvial formations The maximum thickness of ground water occurring under water table is 37 meters and the average thickness of the aquifer is between 12 and 15 meters, which have good water bearing zones. 3.4.1.2. Tertiary formations The tertiary formations occur on the eastern half of the district and have good storage capacity. This area acts as the catchment for the Veearnam lake, situated in Cuddalore district. In monsoon periods, areas around Veeranam lake experience repeated flooding due to rapid surface water run-off form the catchment area. Most of this flood water drains into the sea. The ground water occurs in semi-confined conditions and confined conditions with good ground water potentials in these aquifers the specific capacity in the tertiary formations range from 40 to 1627 lpm/m/dd. 3.4.1.3. Cretaceous formation Cretaceous formations comprises white sandy limestone and sand stones with fossils, calcareous mottled sand stones with fossils, shell lime stones, clays, sand stones with fossils, basal lime stones, clays and sand beds with fossils. Ground water 34 in the sandy clay lenses and fine sands underlain by white and black clay bed constitutes phreatic aquifers in the depth which ranges 10.0 to 15.0 meters below ground water level. Phreatic aquifers in the lime stone have more potential. The specific capacity in the cretaceous formation ranges from 18.77 to 90.66 lmp/m/dd. Ground water occurs in clay bound soil, sand lenses and fine sands. Apart from these formations, the intrusions by limestone constituents the major aquifer. These formations have good storage capacity due to porous nature and presence of cavities. But in many locations this ground water is not utilized because of poor quality due to the limestone deposition. The calcium carbonate are dissolution in the water tends to increase the hardness (IWMP – IV- Project report Perambalur, 2010). 3.5. Population The rate of growth of the population in Ariyalur district is very fast. It has increased from 2,71,501 lakhs (1901) to 6,95,524, lakhs (2001), as per the Census 2001. Ariyalur‟s current population is 752,481 as per the next Census. 800000 752481 695524 636381 700000 572498 513704 600000 500000 437692 398231 400000 348381 308837 294621 306764 300000 271501 Persons 200000 100000 0 1901 1911 1921 1931 1941 1951 1961 1971 1981 1991 2001 2011 Figure-3.2: Population growth in Ariyalur district (1991 to 2011) (District Census Hand Book: Ariyalur, 2001; http://www.ariyalur.tn.nic.in/) 3.6. Flora and Fauna The flora and fauna of this district are fairly rich and varied. The fruit trees widely spread over are tamarind, mango and coconut. In the hilly tracts, jack and oranges are grown. The varieties of timber found in the hilly region are teak, vanni, 35 malaivembu, manjakadambu and Bamboos. In Udayarpalam Taluk cashew trees grow well. As regards to fauna, big animals like elephants, bisons and tigers are not found anywhere. All the game birds of the south are found in this district, though not in plenty. The Vettakkudi Karaivetti tank situated at 52 kms East of Perambalur Town in Thirumanur block near Ariyalur, is a water flow refuge for many migratory birds over 30 species. Many rare species like coke, bareheaded goose (endangered), spoon bills, pintail ducks, grey pelican, teals and other locally migratory species such as open billed storks, painted storks, grey heron, darter, cormorants etc. visit this tank every year between December-March in large congregation(District Census Hand Book: Ariyalur, 2001). 3.7. Ariyalur Taluk The Ariyalur Taluk one of the three Taluks of Ariyalur district occupies an area of 67,650 ha and consist of two blocks viz., Ariyalur and Thirumanur. There are 96 revenue villages consisting of 238 villages in both the blocks. Map-3.2: Location map of sampling sites 36 3.8. Study Area In the present study, Ariyalur Town and 49 villages were randomly selected out of 67 revenue villages of Ariyalur Taluk. These villages distributed within approximately 19km radius from Ariyalur Town. Ariyalur Town occupies an area of 7.62 km2 with a population of 68,125. The study area comprising 49 villages occupies an area of approximately 450 km2 with a population of 2,34,316 and of 57, 248 households (Census, 2001). After 1987, People in Ariyalur Taluk depend on the available ground water for their diverse daily uses. However, people in the Ariyalur Town supplied with the water from the “Thirumanur Combined Drinking Water Supply Scheme” for drinking purposes. The municipality water supplied from Thirumanur is exclusively supply to Ariyalur Town. It is located in Kollidam River bed of Manchamedu village in Thirumanoor Taluk in Ariyalur district. In addition to this, the “Thirumazhapaddi Combined Drinking Water Supply Scheme” is providing water to 525 inhabitants for village people located in Thirumazhapaddi (CDP, 2009). Bore well is centrally located in Kollidam River; 14 sumps were constructed in Kollidam River from Thirumazhapadi to Rayamburam. 3.8.1. Sampling Sites Water samples were collected from 93 sampling points which covered municipal water supply, water from public places, educational institutions, individual houses from the Town and the villages. Samples were collected during all the four seasons viz., winter (February), summer (May), SW Monsoon (August), and NE Monsoon (October). Samples were grouped 6 categories as follows: 1. Municipal water supply in Ariyalur Town– Samples were collected from the drinking water outlets of the storage tanks 2. Public water supply in Ariyalur Town – Samples were collected from the drinking water outlets found in public places 3. Water from educational institutions in Ariyalur Town – Samples were collected from drinking water outlets in educational institutions 4. Random samples in Ariyalur Town – Samples from randomly selected households 37 5. Drinking water samples from selected 49 villages – Samples from the drinking water outlets of the storage tanks 6. Surface water in villages of Ariyalur Taluk–Surface water meant for drinking The details of sampling locations in each category presented in table-3.11 to 3.16. Table:-3.11: Description of municipal water samples collected in Ariyalur Taluk S.No. Location Latitude Longitude Sources 1 Sambasivam street 11o08‟14.307”N 79o04‟24.473”E Kollidam, G.W & KS 2 Municipality office 11o08‟08.622”N 79o04‟37.873”E Kollidam 3 Melaagraharam 11o07‟01.020”N 79o04‟14.740”E Kollidam 4 Rajajinagar 11o08‟41.505”N 79o04‟27.174”E Kollidam 5 Anna nagar tank 11o08‟00.525”N 79o04‟22.962”E Kollidam& G.W Table-3.12: Details of public water sampling in Ariyalur Taluk S.No. Location Latitude Longitude Sources 1 Multipurpose building 2 Bus stand Kollidam 11o08‟11.010”N 79o04‟38.251”E (Ariyalur) (TN) 3 Cetti lake 11o08‟08.828”N 79o04‟39.665”E G.W 4 Taluk office 11o08‟11.516”N 79o04‟36.742”E Kollidam (TN) 5 GH 11o08‟33.315”N 79o04‟09.764”E Kollidam (TN) 6 Railway station 11o08‟56.102”N 79o04‟07.377”E G.W 7 GH road tank 11o08‟37.444”N 79o04‟07.127”E 8 Bharathiyarnagar 11o08‟13.441”N 79o04‟51.630”E G.W tank 11o08‟57.348”N 79o04‟42.694”E Kollidam (TN) Kollidam& G.W, KS 38 Table-3.13: Details of Educational Institutions water sampling in Ariyalur Taluk S.No. 1 Location Govt. Primary School Latitude 11o08‟07.942”N Longitude 79o04‟16.328”E Sources Kollidam 2 St. Marry‟s School 11o08‟05.573”N 79o04‟16.285”E Kollidam 3 Nirmala Girls HSS 11o07‟56.139”N 79o04‟15.233”E Kollidam 4 R.C. Nirmala Gandhi 11o08‟45.668”N Midd. School 79o04‟18.912”E Kollidam 5 C.S.I. HSS 11o08‟10.615”N 79o04‟29.348”E G.W 6 Govt. HSS 11o08‟11.230”N 79o04‟32.453”E Kollidam 7 Monfort Matriculation 11o08‟53.601”N HSS 79o04‟42.626”E G.W 8 Arasunagar Matriculation HSS 11o08‟22.468”N 79o05‟54.972”E G.W 9 Govt. Arts College 11o08‟46.276”N 79o04‟31.686”E Kollidam (TN) 10 Govt. I.T.I. 11o07‟44.704”N 79o05‟26.868”E Kollidam& G.W High Table-3.14: Description of Random water sampling details in Ariyalur Taluk S.No. Location Latitude Longitude Sources 1 Milk Society 11 08‟25.273”N 79 04‟05.428”E G.W 2 Alagappanagar 11o08‟21.679”N 79o04‟34.052”E G.W 3 Vandikkara street 11o08‟17.838”N 79o04‟22.609”E G.W 4 KaliammanKovil street 11o08‟27.776”N 79o04‟11.022”E Open Well 5 Rajajinagar house 11o08‟36.714”N 79o04‟28.679”E G.W 6 Min nagar 11o07‟40.647”N 79o04‟52.292”E G.W 7 Sadaiyappar street 11o07‟57.838”N 79o04‟38.916”E G.W 8 Kallakudi street 11o07‟51.865”N 79o04‟21.869”E G.W 9 Melaagraharam 11o07‟58.139”N 79o04‟08.297”E Bore well 10 Kurinchankula street 11o08‟11.040”N 79o04‟12.166”E Open Well o o 39 11 West street 11o08‟22.196”N 79o04‟08.570”E G.W 12 Arundhathiyar street 11o08‟30.799”N 79o04‟07.960”E G.W 13 Ethirajnagar 11o08‟47.921”N 79o04‟05.626”E G.W 14 K.K. nagar house 11o08‟52.672”N 79o04‟21.324”E G.W 15 Sathyanagar 11o08‟53.266”N 79o04‟47.186”E G.W 16 Periyarnagar 11o08‟30.487”N 79o04‟44.334”E G.W 17 Bharathiyarnagar house 11o08‟16.173”N 79o04‟52.127”E G.W Table-3.15: Description of Rural water samples in Ariyalur Taluk S.No. 1 Location Thavuthaikulam Latitude 11o06‟39.937”N Longitude 79o04‟20.960”E Sources Kollidam, G.W 2 Varanavasi 11o05‟18.324”N 79o04‟38.943”E Kollidam, G.W 3 Samathuvapuram 11o04‟38.914”N 79o04‟20.219”E Kollidam, G.W 4 Keelapazhur 11o02‟35.040”N 79o04‟12.222”E G.W 5 Ammakulam 11o06‟44.567”N 79o04‟51.867”E Kollidam 6 Rengasamuthiram 11o05‟37.331”N 79o05‟30.348”E G.W 7 Suprayapuram 11o05‟17.832”N 79o06‟00.820”E G.W 8 Pallakrishnaram 11o04‟58.724”N 79o06‟06.198”E G.W 9 Pudupalaiyam 11o05‟17.536”N 79o07‟56.118”E G.W 10 Melakarupur 11o03‟46.463”N 79o06‟16.015”E G.W 11 Valajanagaram 11o07‟29.494”N 79o05‟34.650”E G.W 12 Venkada Krishna puram 11o07‟29.942”N 79o05‟59.961”E G.W 13 Kurichinatham 11o05‟32.790”N 79o07‟44.151”E G.W 14 Asthinapuram 11o06‟58.180”N 79o07‟23.517”E G.W 15 k.kaikatti 11o07‟20.052”N 79o08‟14.669”E G.W 16 Chinnanagalur 11o07‟30.604”N 79o09‟14.800”E G.W 17 Periyanagalur 11o07‟42.554”N 79o09‟36.460”E G.W 18 Mannuzhi 11o08‟19.055”N 79o09‟58.604”E G.W 40 19 V.kaikatti 11o06‟46.290”N 79o10‟13.652”E G.W 20 Reddippalayam 11o06‟35.114”N 79o09‟47.207”E G.W 21 Ravuthampatti 11o08‟27.296”N 79o05‟11.437”E G.W 22 Manaleri 11o07‟58.050”N 79o06‟11.975”E G.W 23 Usean bath 11o09‟06.920”N 79o06‟13.761”E G.W 24 MettuKudial 11o09‟51.070”N 79o06‟05.757”E G.W 25 Srinivasapuram 11o09‟37.750”N 79o06‟49.139”E G.W 26 Kallangurichy 11o08‟57.001”N 79o07‟15.636”E G.W 27 Chinnamanakudi 11o08‟45.258”N 79o08‟12.367”E G.W 28 Periyamanakudi 11o08‟58.850”N 79o08‟16.584”E G.W 29 K.Poyyur 11o10‟06.283”N 79o08‟10.408”E G.W 30 Poombadaiyanpatti 11o10‟10.563”N 79o08‟25.692”E G.W 31 Thalaiyerikudikadu tank 11o10‟28.253”N 79o08‟15.748”E G.W 32 Kaduhoor 11o10‟09.716”N 79o09‟05.283”E G.W 33 Ayanathur 11o10‟09.831”N 79o10‟17.776”E G.W 34 Koppiliyankudikadu tank 11o09‟18.414”N 79o09‟01.790”E G.W 35 Kurumanchavadi 11o08‟58.826”N 79o04‟54.682”E G.W 36 Ammenabath 11o10‟12.743”N 79o05‟28.388”E G.W 37 Thamaraikulam 11o10‟29.785”N 79o06‟20.495”E G.W 38 Venkataramanapuram 11o10‟33.331”N 79o06‟44.674”E G.W 39 Ottakovil 11o11‟21.687”N 79o06‟41.446”E G.W 40 Kallamedu 11o11‟12.129”N 79o07‟52.307”E G.W 41 Salaiyakurichi 11o10‟56.754”N 79o07‟52.510”E G.W 42 Poyyadanallur 11o12‟59.784”N 79o07‟29.245”E G.W 43 Rayampuram 11o13‟06.998”N 79o09‟34.638”E G.W 44 Sennivanam 11o12‟29.624”N 79o09‟44.517”E G.W 45 Aadhikudikadu tank 11o13‟31.210”N 79o10‟35.416”E G.W 41 46 Eruthukaranpatti 11o09‟12.251”N 79o04‟18.783”E G.W 47 Mahalingapuram 11o09‟57.792”N 79o04‟37.782”E G.W 48 Jeyaramapuram 11o10‟45.385”N 79o04‟35.604”E G.W 49 Govindapuram 11o10‟58.366”N 79o04‟44.389”E G.W Table-3.16: Description of surface water samples in Ariyalur Taluk Sl. No. 1 2 3 4 Location Latitude Longitude Sources Thalaiyeri kudikadu 11o08‟50.861”N 79o06‟53.981”E Pond Mines 11 10‟21.104”N 79 08‟28.312”E Pond Koppiliyan kudikadu 11 09‟18.294”N 79 09‟07.074”E Pond Aadhikudikadu 11 13‟23.141”N 79 10‟26.317”E Pond o o o o o o 3.9. Samples collection and analytical methods A total of 93 drinking water samples were collected from the above selected locations in the Ariyalur Taluk within Ariyalur district. The sampling sites are listed in table-3.12.Samples were collected in pre-cleaned polypropylene bottles with necessary precautions (Brown et al.,1974). Parameters like pH, and EC were immediately determined and DO was fixed immediately after collection. Samples were analyzed for physico-chemical and microbiological characteristics using the standard methods (APHA, 1998). Details of parameters analyzed and the methods followed are presented in table-3.17. 42 Table-3.17: Details of estimation method of water quality parameters Sl. No. Parameter Method Instruments/Equipment A. Physico-chemical 1 pH Electrometric pH Meter 2 Conductivity Electrometric Conductivity Meter 3 TDS Boiling& Filtration - 4 Alkalinity Titration by Hcl - 5 Hardness Titration by EDTA - 6 Chloride Titration by AgNO3 - 7 Fluoride SPADNS 8 Sulphate Turbidimetric UV-VIS Spectrophotometer Turbidity Meter 9 Nitrate Ultraviolet screening 10 Phosphate 11 Iorn Molybdophosphoric acid Colorimetry 12 Calcium Titration by EDTA UV-VIS Spectrophotometer UV-VIS Spectrophotometer UV-VIS Spectrophotometer - 13 Magnesium Titration by EDTA - 14 Sodium Flame emission Flame Photometer 15 Potassium Flame emission Flame Photometer 16 BOD 17 COD 5 days incubation at BOD Incubator 20oC followed by titration Digestion followed by COD Digester titration B. Microbiological 18 Fecal coliform Multiple fermentation technique tube Bacteriological Incubator C. Heavy Metals 20. Nickel 21 Lead 22 Cadmium 23 Chromium Digestion followed by Atomic Atomic spectrometry Spectrometer Adsorption 43 3.10. Water Quality Index Water quality index is one of the most effective tools to communicate information on the quality of any water body. WQI is a mathematical equation used to transform large number of water quality data into a single number (StambukGilijanovic, 1999). It is simple and easy to understandable for decision makers about quality and possible uses of any water body (Bordalo et al., 2001). It serves the understanding of water quality issues by integrating complex data and generating a score that describes water quality status. 3.10.1. Calculating NSF Water Quality Index Water Quality Index for all the samples was computed using National Sanitation Foundation water quality index, (NSF WQI) (http://www.waterresearch.net/waterqualindex.htm). 3.11. Global Positioning System The Global Positioning System (GPS) is a space based satellite navigation system that provides location and time information in all weather, anywhere on or near the Earth, where there is an unobstructed line of sight to four or more GPS satellites. GPS (Trimble Juno SB) was used to locate the latitude and longitude of the sampling sites. GIS map plated by using that the latitude and longitude (map-3.2). 3.12. Geographic Information System Geographic information system (GIS) is a system designed to capture, store, manipulate, analyze, manage, and present all types of geographical data. In the simplest terms, GIS is the merging of cartography, statistical analysis and database technology.in the present study, the spatial distribution of water quality parameters with their concentrations were platted on Ariyalur Taluk map using GIS technology by the software ARCMAP-9.3. It was used to made map of sampling site location and also plated to which location have exceeded parameters. 3.13. Statistical Analysis Karl pearson correlation coefficient were computed to correlate different water quality parameters (Zar, 2004). Multivariate analysis (Zar, 2004) was carried out to find out existence of variation in water quality among the 6 categories and away 4 seasons. 44 3.14. Questionnaire People were interviewed by questionnaire method to collect information an details about various aspects the questionnaire used in the presented in appendix – to -. 17 houses were randomly interviewed; in each village, 3 houses were randomly interviewed; the heads of the institutions (8 schools,1 college and 1 ITI) were interviewed. The questionnaire survey was also carried out in industries. Water supply and sanitation details were collected from water supply inchargers in Ariyalur Taluk. Details about prevalence of water – borne and water related diseases were collected from primary health care center in villages and from major hospitals in Ariyalur Town. 45 4. RESULTS AND DISCUSSION The drinking water quality totally depends on the geological conditions, the soil quality and ground water and surface water pollution of the area if any. Water consumption by different users in Ariyalur Taluk has been estimated using questionnaire survey. As already mentioned in materials and methods, the drinking water samples were collected from 93 places covering the entire Ariyalur Taluk and analyzed. These samples were grouped into 6 categories. 4.1 Water Consumption in Ariyalur Taluk Using questionnaire survey method, the amount of water used by industries, farmers for irrigation, educational institutions for drinking and other purposes and households for domestic use were determined. 4.1.1. Industrial use A total of 46,50,000 liter/ day of water is used by two industries in Ariyalur Taluk. The average water consumption by one industry comes to be 23,25,000 liter/ day. There are 8 industries in Ariyalur Taluk of different sizes. If the average water consumption of 2 industries is assumed as the average for all the industries, a total of 1,86,00,000 L/day is consumed by all the industries in Ariyalur Taluk approximately. 4.1.2. Agricultural use Ground water is the major source for irrigation in villages in Ariyalur Taluk. Water consumption for irrigation was estimated from the capacity of the pump set and duration of running per day by a single farmer. From the questionnaire survey, for calculation purpose, it has been assumed that on average, 10 farmers in each village runs the pump set per day for 4 hours of duration for six months for wetland crops. Table-4.1: water consumption for irrigation in Ariyalur Taluk Amount of water For 49 villages For entire Taluk (67) Liters per farmer For 10 farmers in average 1 day 14,400 1,44,000 70,56,000 96,48,000 6 months 25,92,000 2,59,20,000 1,27,00,80,000 1,73,66,40,000 Duration The quality of ground water is determined comparing with water quality standards IS: 2296 for irrigation (annexture-IV). All the water samples conformed to 46 the standard for irrigation for all the parameters except for pH in few samples. More number of samples exceeded the standard for pH in northeast monsoon only. 4.1.3. Domestic water use From the questionnaire survey, water consumption rate and different uses of water in households of 49 villages and Ariyalur Town in Ariyalur Taluk were estimated. The results are presented in table-4.2. Table-4.2: Water consumption in Ariyalur Taluk Place Water consumption, L/ day/ household Avg. No. of persons/ Household drinking Cooking bathing House cleaning Gardening Cloths washing 5 11 15 93 34 59 79 (1.48) (3.09) (5.5) (37.8) (13.9) (19.63) (28.72) 5 13 15 89 28 Village Total 291 Town 63 - (1.80) (5.30) (7.84) (31.6) (10.6) 208 (18.04) Average Percapita consumption for drinking =2.4 L/day Population details of Census-2011 are available only for the whole of Ariyalur district. Taluk-wise details are not available in Census, 2011. Hence, details from Census 2001 has been used in the present study. In Ariyalur Taluk, the total population was 2,34,316 with the total houses of 57,248 (Census, 2001). An average of 250 L/day/house of water is required in Ariyalur Taluk. As there were 57,248 houses, total water requirement comes to be 1,43,12,000 L/day in entire Ariyalur Taluk. From questionnaire survey, water consumption in educational institutions was determined and presented in table-4.3. An average of 11,229 L/day/institution is required in Ariyalur Taluk. There are 117 educational institutions in Ariyalur Taluk. The total water requirement comes to be 13,13,793 L/day. 47 250 Table-4.3: Water consumption details of educational institutions in Ariyalur Taluk No. of institution 10 Avg. No. of staff per institution 46 (26.27) Avg. No. of students per institution 1236 (814.12) Avg. water consumption, L/ day/ institution Drinking 1910 (1564.5) Gardening 1130 (1695.8) Other purposes 79 (36.3) Toilet use 8110 (8648.2) Total 11229 Avg. waste water generation, L/ day/ institution 2710 (2143.4) For drinking alone, 6,86,976 L/day is required in houses of Ariyalur Taluk; 2,23,470 L/day is required in educational institutions in Ariyalur Taluk. Thus a total of 9,10,446L /day of water is required for drinking purpose in Ariyalur. Percapita drinking water consumption comes to be 2.4 L/day. The average water consumption per day by various sector is presented in figure-4.1. Industry Agriculture Water usage Domestic Drinking 0 5000000 10000000 15000000 20000000 L/day Figure-4.1: Daily water consumption for various uses in Ariyalur Taluk 48 It reveals that industry has a very large share of water usage followed by domestic sector. Quite surprisingly, lesser amount of water use for irrigation than that for domestic sector was noticed. 4.2. Drinking Water Characteristics Physico-chemical and microbiological characteristics of water samples in Ariyalur Taluk are presented in figures-4.2a to-4.25j. From the results, permissible limits for water quality parameters, the number of samples below and above of permissible limits are presented in table-4.4 to-4.27. 4.2.1 Water from municipality supply pH of water samples varied from 7.2 to 8.6. All samples had pH within the prescribed range in all seasons except one sample in SWM. pH of this sample was 8.6, i.e.,only 0.1 unit higher than the range. Turbidity, chloride, nitrate, phosphate, sulphate and sodium of all samples in all seasons were within the prescribed limits. The EC ranged from 580 to 1180 µS/cm. There is no limit for electrical conductivity for water. The TDS of water samples ranged from 380 to 800 mg/L. As per BIS standards for drinking water, 500mg/L is the desirable limit for TDS. Above this level, palatability decreases and may cause gastro intestinal irritation (BIS: 10500, 1991). Of the 5 samples of municipality water, one sample in winter, one sample in summer, two samples in SWM and three samples in NEM exceeded the standard. BIS standards prescribe 300mg/L, 75mg/L and 30mg/L as the desirable limits for total hardness, calcium ion and magnesium ion respectively. Excess of these values, may cause encrustation in water supply and adverse effect on domestic use (BIS: 10500, 1991). Total hardness ranged from 122 to 830 mg/l. Four samples in winter, 2 samples in summer, 3 in south west monsoon and all the samples in northeast monsoon exceeded the desirable limit for total hardness. Calcium ranged from 22 to 196.4 mg/L. Two samples in winter, 4 samples in summer and 1 sample in southwest monsoon exceeded the desirable limit for calcium. Magnesium ranged from 21.4 to 138.5mg/L. Two samples in winter, 3 in summer and all the samples in southwest monsoon exceeded the desirable limit for magnesium 49 The total alkalinity values ranged from 110 to 550 mg/l. As per BIS, 200mg/L is the desirable limit for alkalinity. Four samples in winter, all in summer, 3 in SWM and 3 in NEM exceeded the desirable limit. Potassium ranged from 1.6 to 13.8 mg/L. There is no limit prescribed for potassium. DO ranged from 3.9 to 7.7 mg/L. CPCB prescribed the standard for DO is >6.0 mg/L. All samples except one sample in winter and one in summer and one in northeast monsoon met this condition. COD ranged from 4 to 52 mg/L. Prescribed limit for COD is 10mg/L (WHO, 2004). Four samples in winter, all samples in summer, four samples in SWM and four in NEM exceeded this limit. BOD ranged from 1.2 to 13.4 mg/l. CPCB prescribes 2mg/L as the limit for drinking water. Except one sample in SWM all the samples were found to exceed the limit. Fluoride ranged from 0 to 1.58 mg/l. Most of the samples had fluoride below the standard. One sample in summer and one in winter slightly exceeded the standard. Iron ranged from 0.01 to 1 mg/L. Desirable limit for iron is 0.3mg/L (BIS, 1991).One sample in summer and one sample in SWM exceeded this level. Fecal coliform of all samples in all seasons were within prescribed limit (50/100ml) as per water quality criteria prescribed by CPCB (2008). However, majority of water samples did not conform to drinking water quality standards (BIS, 1991). Lead and cadmium were found to be within the limits. Chromium exceeded the standard in one sample in winter and one sample in summer. Water quality index: The water quality index results revealed that the 3 samples were of “Medium” and 2 samples were of “Bad” quality. 4.2.2. Water from Public Supplies pH of water samples varied from 7.4 to 8.8. All samples had pH within the prescribed range in all seasons. Two samples in NE monsoon and one sample in winter slightly exceeded the range. Turbidity, nitrate, phosphate, sulphate, sodium, potassium and iron of all samples in all seasons were within the prescribed limits. 50 The EC ranged from 552 to 1547 µS/cm. The TDS values of water samples ranged from 410 to 950mg/l. Of the 8 samples of public water, 5 samples in winter, 4 samples in summer, 7 samples in SWM and 5 samples in NEM exceeded the standard. Total hardness ranged from 175 to 675mg/L. Seven in winter, 6 in summer and 7 in SW monsoon and all in northeast monsoon exceeded the standard (300mg/L). Calcium ranged from 14 to 282.6 mg/L. All samples exceeded the desirable limit except one in winter, 2 in SW monsoon and 4 in NE monsoon. Magnesium ranged from 19 to 279.5 mg/L. Five samples in winter, 4 in summer, 6 in SW monsoon and all in NE monsoon exceeded the standard for magnesium. Total alkalinity ranged from 180 to 580 mg/L. All samples exceeded the desirable limit in all seasons except one in NE monsoon. The Chloride values ranged from 23.4 to 262.3 mg/l. All the samples were within the permissible limit (250mg/L). One sample in winter and one sample in SW monsoon slightly exceeded the limit. DO ranged from 4.8 to 7.6 mg/L. Two samples in winter, 3 in summer, 4 samples in southeast monsoon and 2 samples in northeast monsoon did not conform with the standard (>6 mg/L). COD ranged from 8 to 67.2mg/L. Except 2 samples in summer and 1 in northeast monsoon, all samples exceeded the prescribed limit of COD is 10mg/L (WHO, 2004). BOD ranged from 1.6 to 16.2 mg/l. Except one sample in winter, all samples were found to exceed in all the seasons. Fluoride ranged from 0 to 1.62mg/l. Two samples in winter, 4 samples in summer and 3 samples in SW monsoon slightly exceeded the standard. Fecal coliform of all samples in all seasons were within prescribed limit (50/100ml) as per water quality criteria prescribed by CPCB (2008). However, majority of the samples did not conform to drinking water quality standards (BIS, 1991). Lead, Chromium and cadmium were found to be within the limits except 2 samples in SW monsoon that slightly exceeded the limit for chromium. Water quality index: The water quality index results revealed that the 5 samples were of “Medium” and 3 samples were of “Bad” quality. 51 4.2.3. Water from Educational institutions pH of water samples varied from 7.2 to 8.7. All samples had pH within the prescribed range in all seasons. One sample in SW monsoon and one sample in NE monsoon slightly exceeded the range. Turbidity, nitrate, phosphate, sulphate, sodium and iron of all samples in all seasons were within the prescribed limits. The EC ranged from 630 to 1580 µS/cm. The TDS values of water samples ranged from 410 to 960mg/l. Of the 10 samples, 8 samples in winter, 4 samples in summer, 9 samples in SWM and all samples in NEM exceeded the standard. Total hardness ranged from 75 to 1040 mg/L. One sample in winter, 4samplesin summer, 3 samples SW monsoon and all samples in NE monsoon had total hardness below the standard value (300mg/L). Calcium ranged from 14 to 282.6 mg/L. All samples exceeded the desirable limit except 1 in winter, 2 in summer, 2 in SW monsoon and 7 in NE monsoon. Magnesium ranged from 3.6 to 212.1 mg/L. Of 10 samples, nine samples in winter, 1 sample in summer, 9 in SW monsoon and all in NE monsoon exceeded the standard for magnesium (30mg/L). The total alkalinity values ranged from 130 to 580 mg/L.As per BIS, 200mg/L is the desirable limit for alkalinity. All samples exceeded the desirable limit in all seasons except one in SW monsoon. The Chloride values ranged from 51.5 to 457.3 mg/L. All the samples were within the permissible limit (250mg/L) except two samples in winter, one sample in SW monsoon and three samples in NE monsoon. Potassium ranged from 2.3 to 16.6 mg/l. DO values ranged from 5.2 to 7.5 mg/L. All samples except 1 in winter, 4 in summer and 4 in northeast monsoon conformed with standard. COD ranged from 8 to 52 mg/l. Of 10 samples, only two samples in summer and one sample in SW monsoon were found to be below permissible limit. BOD ranged from 2.4 to 14.5 mg/L. All samples were found to exceed in all the seasons. Fluoride ranged from 0 to 1.92 mg/L. Two samples in winter, 2 samples in summer and 1 sample in SW monsoon slightly exceeded the standard. 52 Fecal coliform of all samples in all seasons were within prescribed limit (50/100ml) as per water quality criteria prescribed by CPCB (2008). However, majority of the samples did not conform to drinking water quality standards (BIS, 1991). Lead, Chromium and cadmium were found to be within the limits except one sample in winter and one sample in SW monsoon for chromium which slightly exceeded the limit. Water quality index: The water quality index results revealed that the 7 samples were of “Medium” and 3 samples were of “Bad” quality. 4.2.4. Random water samples pH of water samples varied from 7.1 to 8.8. All samples had pH within the prescribed range in all seasons. Two samples in summer, one sample in SW monsoon and two samples in NE monsoon slightly exceeded the range. Turbidity, nitrate, phosphate, sulphate and iron of all samples in all seasons were within the prescribed limits. The EC ranged from 695 to 1574 µS/cm. The TDS values of water samples ranged from 420 to 970 mg/l. Of the 17 samples, 13 samples in winter, 16 samples in summer, 16 samples in SWM and 16 samples in NEM exceeded the standard. Total hardness ranged from 115 to 950 mg/L. Sixteen samples in winter, 11 samples in summer, 15 samples in SW monsoon and all samples in NE monsoon exceeded the standard value (300mg/L). Calcium ranged from 14 to 242.2 mg/l. Number of samples that had exceeded the desirable limit were 14 in winter, 14 in summer, 10 in SW monsoon and 5 in NE monsoon. Magnesium ranged from 6 to 261.2 mg/L. Out of 17 samples, 11 samples in winter, 7 samples in summer, 16 in SW monsoon and all samples in NE monsoon exceeded the standard value for magnesium (30mg/L). Total alkalinity ranged from 190 to 580 mg/L. All samples exceeded the desirable limit in all seasons except one sample in summer. The Chloride values ranged from 54.7 to 475 mg/l. Most of the samples were within the permissible limit (250mg/L). Three samples in winter, six samples in 53 summer, seven sample in SW monsoon and four samples in NE monsoon exceeded the limit. Sodium ranged from 52.4 to 215.1 mg/l. WHO guideline‟s limit for sodium in drinking water is 200mg/L (WHO, 2004). All samples were within this value except one sample in NE monsoon. Potassium ranged from 2.8 to 18.1mg/l. DO values ranged from 2.3 to 7.2 mg/L. Six samples in winter, 16 samples in summer, 12 samples in southwest monsoon and 12 samples in northeast monsoon did not conform the standard value. COD ranged from 4 to 52 mg/l. Except one sample in summer, 2 samples in southwest monsoon and 4 in northeast monsoon, all samples were beyond the prescribed limit for COD (10mg/L). BOD ranged from 1.1 to 17.8 mg/L. All the samples were found to exceed in all the seasons except one sample in SW monsoon and one sample in NE monsoon. Fluoride ranged from 0 to 1.86 mg/l. One sample in winter, one sample in summer and five samples in southwest monsoon slightly exceeded the standard. Iron ranged from 0 to 0.31 mg/L. All the samples were within the permissible value (0.3mg/L). One sample in SW monsoon slightly exceeded. Fecal coliform of all samples in all seasons were within prescribed limit (50/100ml) as per water quality criteria prescribed by CPCB. However, majority of the water samples did not confirm to drinking water quality standards (BIS, 1991). Lead, Chromium and cadmium were found to be within the limits. One sample in winter slightly exceeded the limit for cadmium and one sample in summer and one sample in SW monsoon slightly exceeded the limit for chromium. Water quality index: The water quality index results revealed that the 12samples were found to be of “Medium” and 5samples were found to be of “Bad” quality. 4.2.5. Water samples from rural areas pH of water samples varied from 7.1 to 9.1. All samples had pH within the prescribed range in all seasons. Two samples in winter, four in summer, one sample in SW monsoon and 20 samples in NE monsoon slightly exceeded the range. Turbidity, nitrate, phosphate, sulphate of all samples in all seasons were lower than the prescribed limits. 54 The EC ranged from 549 to 1909 µS/cm. The TDS values of water samples ranged from 340 to 1450 mg/L. Of the 49 samples, 39 samples in winter, 29 samples in summer, 31 samples in SWM and 44 samples in NEM exceeded the standard. Total hardness ranged from 48.3 to 950 mg/L. Forty four samples in winter, 35 samples in summer, 27 samples in SW monsoon and 48 samples in NE monsoon exceeded the standard value (300mg/L). Calcium ranged from 20.04 to 260.2 mg/l. Forty four samples in winter, 42 in summer, thirty one in SW monsoon and thirty samples in NE monsoon exceeded the prescribed limit. Magnesium ranged from 1.2 to 216.4 mg/L. Out of 49 samples, 36 samples in winter, 15 samples in summer, 36 in SW monsoon and 45 samples in NE monsoon exceeded the standard value for magnesium (30mg/L). The total alkalinity values ranged from 100 to 1500 mg/L. All samples exceeded the desirable limit in all seasons except 4 samples in summer, 2 in SW monsoon and 3 in NE monsoon. The Chloride anged from 14.2 to 382.9 mg/L. Seven samples in winter, seven samples in summer, four samples in SW monsoon and ten samples in NE monsoon exceeded the limit. Sodium ranged from 22.8 to 290.5 mg/l. WHO guideline‟s limit for sodium in drinking water is 200mg/L (WHO, 1996). Rural water samples were within this limit except two samples in winter and two samples in summer. Potassium ranged from 1.6 to 31.2mg/l. DO values ranged from 1.8 to 8.7 mg/L. Many samples except 15 in winter, 34 in summer, 8 in southwest monsoon and 20 in northeast monsoon met the standard for DO. COD ranged from 4 to 84mg/l. Most of the samples were beyond the prescribed limit for COD. Four samples in winter, one sample in summer, eleven samples in southwest monsoon and eight samples in NE monsoon had COD below the standard value. BOD ranged from 1.0 to 18.7 mg/L. Rural samples were found to exceed the standard in all the seasons except 7 samples in SW monsoon and 3 samples in NE monsoon. 55 Fluoride ranged from 0 to 1.86 mg/L. One sample in winter, one sample in summer and five samples in SW monsoon slightly exceeded the standard. Iron ranged from 0.0 to 0.65mg/l. Majority of water samples were within the permissible value (0.3mg/L). One sample in summer and one sample in NE monsoon exceeded the standard. Fecal coliform of all samples in all seasons were within prescribed limit (50/100ml) as per water quality criteria prescribed by CPCB. However, majority of the water samples did not confirm to drinking water quality standards (BIS, 1991). Lead, cadmium and chromium were found to be within the limits. Thirty one samples each in winter, summer and SW monsoon slightly exceeded the limit for cadmium. Two in winter, 5 in summer and 9 in SW monsoon slightly exceeded the standard for chromium. Water quality index: The water quality index results revealed that the 29 samples were of “Medium” and 20 samples were of “Bad” quality. 4.2.6. Surface water pH of water samples varied from 7.4 to 8.8.Two samples in winter and 2 samples in northeast monsoon exceeded the range. Turbidity, nitrate, phosphate, sulphate, fluoride and sodium of all samples in all seasons were lower than the prescribed limits. The EC ranged from 610 to 1470 µS/cm. The TDS values of water samples ranged from 400 to 820 mg/L. Of the 4 samples of surface water, 3 samples in winter, 3 samples in summer, 2 samples in SWM and 3 samples in NEM exceeded the standard. Total hardness ranged from 105 to 780 mg/L. Two samples in winter, 4 samples in summer, 3 in south west monsoon and 3 samples in northeast monsoon exceeded the desirable limit for total hardness. Calcium ranged from 14 to 228.4 mg/L. Two samples in winter, 3 samples in summer, 3 samples in southwest monsoon and 2 samples in northeast monsoon exceeded the desirable limit for calcium. Magnesium ranged from 8.5 to 116.2 mg/l. Three samples in winter, 2 samples in southwest monsoon and 3 samples in northeast monsoon exceeded the desirable limit for magnesium. 56 The total alkalinity values ranged from 100 to 470 mg/l. Two in winter, 3 in summer, all samples in SWM and 2 samples in NEM exceeded the desirable limit (200mg/L). The Chloride values ranged from 31.9 to 487.1 mg/l. One sample in winter, one sample in summer and one sample in northeast monsoon exceeded the permissible limit (250mg/L). Potassium ranged from 2.5 to 13.1mg/l. DO values ranged from 4.3 to 5.8 mg/L. All samples did not meet the standard (>6.0 mg/L). COD ranged from 8 to 68 mg/l. All the water samples exceeded the limit except one in southwest monsoon. BOD ranged from 2.5 to 12.1 mg/l. All the samples were found to exceed in all the seasons. Iron ranged from 0.018 to 0.6 mg/L. Iron content was within the permissible limit in all the seasons except one in northeast monsoon. Fecal coliform of all samples in all seasons were within prescribed limit (50/100ml) as per water quality criteria prescribed by CPCB. However, majority of the water samples did not confirm to drinking water quality standards (BIS, 1991). Lead content of water samples were found to be within the limit. Chromium content exceeded the standard in 1 sample in winter, 2 samples in summer and 2 samples in southeast monsoon. Cadmium content exceeded the standard in 3 samples in winter and 4 samples in southwest monsoon. Water quality index: The water quality index results revealed that the 3 samples were of “Medium” and 1 sample was of “Bad” quality. 57 9 9 8 7 8.5 6 Winter 5 Winter 8 Summer Summer 4 7.5 SWM 3 NEM 2 SWM 7 NEM 1 6.5 0 1 2 3 4 5 6 7 8 9 11 10 12 13 14 15 16 17 18 19 20 Stations Stations Figure 4.2a: pH of drinking water samples in Ariyalur Taluk Figure 4.2b: pH drinking water samples in Ariyalur Taluk 9 9 8 8 7 7 6 6 5 Winter 4 5 Winter 4 Summer 3 SWM 2 NEM 1 0 3 Summer 2 SWM 1 NEM 0 21 22 23 24 25 26 27 28 29 30 Stations Figure 4.2c: pH of drinking water samples in Ariyalur Taluk 31 32 33 34 35 36 37 38 39 40 Stations Figure 4.2d: pH drinking water samples in Ariyalur Taluk 58 9 9 8 8.5 7 Winter 8 7.5 7 6 5 Winter Summer 4 Summer SWM 3 SWM NEM 2 NEM 1 6.5 0 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 Stations 56 57 58 59 60 Stations Figure 4.2e: pH of drinking water samples in Ariyalur Taluk 9 8 7 6 5 4 3 2 1 0 Figure 4.2f: pH drinking water samples in Ariyalur Taluk 10 8 Winter Summer SWM NEM 61 62 63 64 65 66 67 68 69 70 Stations Figure 4.2g: pH of drinking water samples in Ariyalur Taluk 6 Winter Summer 4 SWM NEM 2 0 71 72 73 74 75 76 77 Stations 78 79 80 Figure 4.2h: pH drinking water samples in Ariyalur Taluk 59 9 9 8 7 6 5 8.5 Winter SWM 8 Winter mg/l Summer 4 3 2 Summer 7.5 SWM NEM NEM 7 1 0 81 82 83 84 85 86 87 88 6.5 89 90 91 Stations Figure 4.2i: pH of drinking water samples in Ariyalur Taluk 93 Figure 4.2j: pH drinking water samples in Ariyalur Taluk EC 1400 EC 1600 1400 1200 1200 800 Winter Summer SWM NEM 600 400 200 µS/cm 1000 µS/cm 92 Stations 1000 Winter 800 Summer 600 SWM 400 NEM 200 0 0 1 2 3 4 5 6 7 8 9 10 Stations Figure 4.3a: EC of drinking water samples in Ariyalur Taluk 11 12 13 14 15 16 17 18 19 20 Stations Figure 4.3b: EC drinking water samples in Ariyalur Taluk 60 EC 1400 1400 1200 1200 1000 1000 Winter 800 600 Summe r SWM 400 200 µS/cm 1600 µS/cm 1600 22 23 24 25 26 27 28 29 800 Winter 600 Summe r SWM 400 200 0 21 EC 0 30 31 32 33 34 Figure 4.3c: EC of drinking water samples in Ariyalur Taluk 37 38 39 40 Figure 4.3d: EC drinking water samples in Ariyalur Taluk EC EC 1400 1400 1200 1200 1000 1000 Winter 800 Summer 600 SWM 400 NEM 200 0 µS/cm µS/cm 36 Stations Stations 1600 35 Winter 800 Summer 600 SWM 400 NEM 200 0 41 42 43 44 45 46 47 48 49 50 Stations Figure 4.3e: EC of drinking water samples in Ariyalur Taluk 51 52 53 54 55 56 57 58 59 60 Stations Figure 4.3f: EC drinking water samples in Ariyalur Taluk 61 EC EC 2500 2000 2000 1500 1000 Summer 500 SWM 61 62 63 64 65 66 67 68 69 Summer 1000 SWM 500 NEM 0 Winter 1500 µS/cm µS/cm Winter NEM 0 70 71 72 73 74 Stations 75 76 77 78 79 80 Stations Figure 4.3g: EC of drinking water samples in Ariyalur Taluk Figure 4.3h: EC drinking water samples in Ariyalur Taluk EC EC 2000 1600 1400 1500 1200 1000 Summer SWM 500 NEM winter 1000 µS/cm µS/cm Winter summer 800 SWM 600 NEM 400 200 0 0 81 82 83 84 85 86 87 88 89 Stations Figure 4.3i: EC of drinking water samples in Ariyalur Taluk 90 91 92 93 Station Figure 4.3j: EC drinking water samples in Ariyalur Taluk 62 1000 800 800 600 Summer 400 SWM 400 2 3 4 5 6 7 8 9 SWM NEM 200 0 1 Winter Summer NEM 200 TDS 600 Winter mg/l mg/l TDS 1000 0 10 11 12 13 14 16 17 18 19 20 Stations Stations Figure 4.4a: TDS of drinking water samples in Ariyalur Taluk Figure 4.4b: TDS drinking water samples in Ariyalur Taluk TDS TDS 1000 1000 800 800 Summer 400 SWM NEM 200 mg/l Winter 600 mg/l 15 Winter 600 Summer 400 SWM 200 NEM 0 0 21 22 23 24 25 26 27 28 29 30 Stations Figure 4.4c: TDS of drinking water samples in Ariyalur Taluk 31 32 33 34 35 36 37 38 39 40 Stations Figure 4.4d: TDS drinking water samples in Ariyalur Taluk 63 TDS 1000 1000 800 800 mg/l Summer 400 SWM 200 NEM mg/l Winter 600 42 43 44 45 46 47 48 49 Winter 600 Summer 400 SWM NEM 200 0 41 TDS 0 50 51 52 53 54 Stations 57 58 59 60 Figure 4.4f: TDS drinking water samples in Ariyalur Taluk TDS TDS 1400 1000 1200 800 Winter 600 Summer 400 1000 mg/l mg/l 56 Stations Figure 4.4e: TDS of drinking water samples in Ariyalur Taluk 1200 55 Winter 800 Summer SWM 600 SWM NEM 400 NEM 200 200 0 0 61 62 63 64 65 66 67 68 69 70 Stations Figure 4.4g: TDS of drinking water samples in Ariyalur Taluk 71 72 73 74 75 76 77 78 79 80 Stations Figure 4.4h: TDS drinking water samples in Ariyalur Taluk 64 TDS 1600 TDS 1400 900 1200 800 700 800 600 Winter 600 Summer 500 SWM 400 mg/l mg/l 1000 Summer 400 SWM 300 NEM 200 Winter NEM 200 0 100 81 82 83 84 85 86 87 88 89 0 90 Stations Figure 4.4i: TDS of drinking water samples in Ariyalur Taluk 91 92 93 Figure 4.4j: TDS drinking water samples in Ariyalur Taluk Turbidity 3.5 Stations Turbidity 3 3 2.5 2.5 summer 1.5 SWM 1 NTU NTU 2 winter 2 Winter Summer 1.5 SWM 1 NEM NEM 0.5 0.5 0 0 1 2 3 4 5 6 7 8 9 10 Stations Figure 4.5a: Turbidity of drinking water samples in Ariyalur 11 12 13 14 15 16 17 18 19 20 Stations Figure 4.5b: Turbidity of drinking water samples in Ariyalur 65 Turbidity Turbidity 3.5 3.5 3 3 2.5 2.5 Winter Summer 1.5 2 NTU NTU 2 Winter 1.5 Summer 1 SWM 1 SWM 0.5 NEM 0.5 NEM 0 0 21 22 23 24 25 26 27 28 29 30 31 32 33 34 Figure 4.5c: Turbidity of drinking water samples in Ariyalur 37 38 39 40 Figure 4.5d: Turbidity of drinking water samples in Ariyalur Turbidity Turbidity 4 3.5 2 3 2.5 Summer 1 SWM 0.5 NEM NTU Winter 1.5 NTU 36 Station Station 2.5 35 Winter 2 Summer 1.5 SWM 1 NEM 0.5 0 0 41 42 43 44 45 46 47 48 49 50 Stations Figure 4.5e: Turbidity of drinking water samples in Ariyalur 51 52 53 54 55 56 57 58 59 60 Stations Figure 4.5f: Turbidity of drinking water samples in Ariyalur 66 Turbidity Turbidity 5 4 3.5 4 3 2 Summer 1.5 SWM 1 NEM Winter 3 Winter NTU NTU 2.5 Summer 2 SWM NEM 1 0.5 0 0 61 62 63 64 65 66 67 68 69 71 70 72 73 74 Stations Figure 4.5g: Turbidity of drinking water samples in Ariyalur 77 78 79 80 Figure 4.5h: Turbidity of drinking water samples in Ariyalur Turbidity Turbidity 4 3 3.5 2.5 3 Winter 2.5 2 winter Summer 2 SWM 1.5 1 NEM 0.5 NTU NTU 75 76 Stations 1.5 summe r SWM 1 0.5 0 81 82 83 84 85 86 87 88 89 Stations Figure 4.5i: Turbidity of drinking water samples in Ariyalur 0 90 91 92 93 Stations Figure 4.5j: Turbidity of drinking water samples in Ariyalur 67 Total hardness 1000 800 Winter Summer mg/l mg/l Total hardness 900 800 700 600 500 400 300 200 100 0 Winter 600 Summer 400 SWM SWM NEM 200 NEM 0 1 2 3 4 5 6 stations 7 8 9 10 11 Figure 4.6a: T.hardness of drinking water samples in Ariyalur 12 13 15 16 Stations 17 18 19 20 Figure 4.6b: T.hardness of drinking water samples in Ariyalur Total hardness Total hardness 1000 1000 800 800 Winter Summer SWM NEM 400 200 0 21 22 23 24 25 26 27 28 29 30 Stations Figure 4.6c: T.hardness of drinking water samples in Ariyalur 600 mg/l 600 mg/l 14 Winter Summer 400 SWM 200 NEM 0 31 32 33 34 35 36 Stations 37 38 39 40 Figure 4.6d: T.hardness of drinking water samples in Ariyalur 68 Total hardness Total hardness 800 900 700 800 700 600 500 Winter 400 Summer 300 SWM 300 NEM 200 200 mg/l mg/l 600 100 500 Winter Summer SWM NEM 400 100 0 41 42 43 44 45 46 47 48 49 0 50 51 52 53 54 Stations Figure 4.6e: T.hardness of drinking water samples in Ariyalur 57 58 59 60 Figure 4.6f: T.hardness of drinking water samples in Ariyalur T.Hardness Total hardness 900 800 800 700 700 600 500 500 600 Winter Summer SWM NEM 400 300 200 100 mg/l mg/l 55 56 Stations Winter 400 Summer 300 200 SWM 100 NEM 0 0 71 61 62 63 64 65 66 Stations 67 68 69 72 73 74 75 76 77 78 79 80 70 Figure 4.6g: T.hardness of drinking water samples in Ariyalur Stations Figure 4.6h: T.hardness of drinking water samples in Ariyalur 69 Total hardness Total hardness 1000 800 700 800 600 Winter Summer SWM NEM 400 200 500 mg/l mg/l 600 Winter Summer SWM NEM 400 300 200 100 0 0 81 82 83 84 85 86 Stations 87 88 89 90 91 Figure 4.6i: T.hardness of drinking water samples in Ariyalur 93 Figure 4.6j: T.hardness of drinking water samples in Ariyalur Total alkalinity Total alkalinity 600 600 500 500 400 Winter 300 Summer SWM 200 NEM 100 0 1 2 3 4 5 6 Stations 7 8 9 10 Figure 4.7a: T.Alkalinity of drinking water samples in Ariyalur mg/l 400 mg/l 92 Stations Winter Summer SWM NEM 300 200 100 0 11 12 13 14 15 16 Stations 17 18 19 20 Figure 4.7b: T.Alkalinity of drinking water samples in Ariyalur 70 Total alkalinity 500 500 400 400 Winter Summer SWM NEM 300 200 100 22 23 24 25 26 27 28 29 Winter 300 Summer 200 SWM 100 NEM 0 21 Total alkalinity 600 mg/l mg/l 600 0 30 31 32 33 34 35 Stations 36 37 38 39 40 Stations Figure 4.7c: T.Alkalinity of drinking water samples in Ariyalur Figure 4.7d: T.Alkalinity of drinking water samples in Ariyalur Total alkalinity Total alkalinity 500 450 400 350 300 250 200 150 100 50 0 600 500 400 Summer SWM NEM mg/l mg/l Winter Winter 300 Summer SWM 200 NEM 100 41 42 43 44 45 46 Stations 47 48 49 50 Figure 4.7e: T.Alkalinity of drinking water samples in Ariyalur 0 51 52 53 54 55 56 Stations 57 58 59 60 Figure 4.7f: T.Alkalinity of drinking water samples in Ariyalur 71 Total alkalinity Toatal alkalinity 900 600 800 700 500 600 400 mg/l Winter Summer SWM NEM 400 300 200 Winter mg/l 500 300 Summer 200 SWM 100 NEM 100 0 0 61 62 63 64 65 66 Stations 67 68 69 71 70 72 73 74 75 76 77 78 79 Stations Figure-4.7g: T.Alkalinity of drinking water samples in Ariyalur Figure-4.7h: T.Alkalinity of drinking water samples in Ariyalur Total alkalinity Total alkalinity 600 500 500 400 400 Winter 300 Summer SWM 200 NEM 100 Winter 300 mg/l mg/le 80 Summer 200 SWM NEM 100 0 0 81 82 83 84 85 86 Stations 87 88 89 Figure-4.7i: T.Alkalinity of drinking water samples in Ariyalur 90 91 92 93 Stations Figure-4.7j: T.Alkalinity of drinking water samples in Ariyalur 72 8 7 7 6 6 DO 5 Winter 4 Summer SWM 3 SWM NEM 2 NEM 5 Winter 4 Summer 3 2 mg.l mg/l DO 8 1 1 0 0 1 2 3 4 5 6 7 8 9 11 10 12 13 14 Stations 15 17 18 19 20 Stations Figure-4.8a: DO of drinking water samples in Ariyalur Taluk Figure-4.8b: DO of drinking water samples in Ariyalur Taluk DO DO 8 7 6 5 4 3 2 1 0 8 7 6 Winter Summer SWM NEM mg/l mg/l 16 5 4 Winter 3 Summer 2 SWM 1 NEM 0 21 22 23 24 25 26 27 28 29 30 Stations Figure-4.8c: DO of drinking water samples in Ariyalur Taluk 31 32 33 34 35 36 37 38 39 40 Station Figure-4.8d: DO drinking water samples in Ariyalur Taluk 73 DO DO 10 8 Winter Summer 4 SWM 2 mg/l mg/l 6 NEM 0 41 42 43 44 45 46 47 48 49 9 8 7 6 5 4 3 2 1 0 50 Winter Summer SWM NEM 51 52 53 54 Stations 55 57 58 59 60 Stations Figure 4.8e: DO of drinking water samples in Ariyalur Taluk Figure 4.8f: DO drinking water samples in Ariyalur Taluk DO DO 8 8 7 7 6 6 5 Winter Summer 4 Summer 3 SWM 3 SWM 2 NEM 2 NEM 5 Winter 4 1 mg/l mg/l 56 1 0 0 61 62 63 64 65 66 67 68 69 70 Stations Figure 4.8g: DO of drinking water samples in Ariyalur Taluk 71 72 73 74 75 76 77 78 79 80 Stations Figure 4.8h: DO drinking water samples in Ariyalur Taluk 74 DO 8 DO 6 7 5 Winter 5 4 Summer 4 SWM 3 NEM 2 1 mg/l mg/l 6 winter summer 3 SWM 2 NEM 1 0 81 82 83 84 85 86 87 88 0 89 90 91 Stations Figure 4.8i: DO of drinking water samples in Ariyalur Taluk COD 60 60 50 50 Winter 40 Summer 30 SWM 20 NEM 10 mg/l mg/l 93 Figure 4.8j: DO drinking water samples in Ariyalur Taluk COD 70 92 Stations 40 Winter 30 Summer SWM 20 NEM 10 0 0 1 2 3 4 5 6 7 8 9 10 Stations Figure 4.9a: COD of drinking water samples in Ariyalur Taluk 11 12 13 14 15 16 17 18 19 20 Stations Figure 4.9b: COD drinking water samples in Ariyalur Taluk 75 COD COD 50 60 40 50 mg/l 10 Winter 30 Summer SWM 20 SWM NEM 10 NEM Summer 20 40 mg/l Winter 30 0 0 21 22 23 24 25 26 27 28 29 31 30 32 33 34 Stations 35 37 38 39 40 Stations Figure-4.9c: COD of drinking water samples in Ariyalur Taluk Figure-4.9d: COD drinking water samples in Ariyalur Taluk COD COD 90 80 70 60 50 40 30 20 10 0 50 40 Winter Summer mg/l mg/l 36 Winter 30 Summer 20 SWM 10 NEM SWM NEM 0 41 42 43 44 45 46 47 48 49 50 Stations Figure-4.9e: COD of drinking water samples in Ariyalur Taluk 51 52 53 54 55 56 57 58 59 60 Stations Figure-4.9f: COD drinking water samples in Ariyalur Taluk 76 COD COD 70 60 60 50 50 Winter 40 Summer 30 mg/l mg/l 70 SWM 20 Winter 40 Summer 30 SWM 20 NEM NEM 10 10 0 0 61 62 63 64 65 66 67 68 69 71 70 72 73 74 75 76 77 78 79 80 Stations Stations Figure-4.9g: COD of drinking water samples in Ariyalur Taluk Figure-4.9h: COD drinking water samples in Ariyalur Taluk COD COD 50 60 40 50 Winter Summer 20 SWM NEM 10 Winter 40 mg/l mg/l 30 Summer 30 SWM NEM 20 10 0 81 82 83 84 85 86 87 88 89 0 90 Stations Figure-4.9i: COD of drinking water samples in Ariyalur Taluk 91 92 93 Stations Figure-4.9j: COD drinking water samples in Ariyalur Taluk 77 BOD BOD 18 14 16 12 14 12 8 Winter 6 Summer 4 2 mg/l mg/l 10 Winter 10 Summer 8 SWM 6 SWM NEM 4 NEM 2 0 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 Stations 15 17 18 19 20 Stations Figure-4.10a: BOD of drinking water samples in Ariyalur Taluk Figure-4.10b: BOD drinking water samples in Ariyalur Taluk BOD BOD 18 16 16 14 14 12 Summer 10 8 SWM 6 NEM 4 2 mg/l Winter 12 mg/l 16 Winter 10 Summer 8 6 SWM 4 NEM 2 0 0 21 22 23 24 25 26 27 28 29 30 Stations Figure-4.10c: BOD of drinking water samples in Ariyalur Taluk 31 32 33 34 35 36 37 38 39 40 Stations Figure-4.10d: BOD drinking water samples in Ariyalur Taluk 78 BOD BOD 16 20 14 12 15 Summer 10 SWM NEM 5 Winter 10 mg/l mg/l Winter 8 Summer 6 SWM 4 NEM 2 0 0 41 42 43 44 45 46 47 48 49 50 51 52 53 54 Stations 57 58 59 60 Figure-4.10f: BOD drinking water samples in Ariyalur Taluk BOD 16 56 Stations Figure-4.10e: BOD of drinking water samples in Ariyalur Taluk BOD 16 14 14 12 12 Winter 8 Summer 6 SWM 4 NEM 2 Winter 10 mg/l 10 mg/l 55 Summer 8 SWM 6 NEM 4 2 0 61 62 63 64 65 66 67 68 69 70 Stations Figure-4.10g: BOD of drinking water samples in Ariyalur Taluk 0 71 72 73 74 75 76 77 78 79 80 Stations Figure-4.10h: BOD drinking water samples in Ariyalur Taluk 79 BOD BOD 16 16 14 14 Winter 10 Summer 8 SWM 6 NEM 4 12 Winter 10 mg/l mg/l 12 Summer 8 SWM 6 NEM 4 2 2 0 81 82 83 84 85 86 87 88 0 89 90 91 Stations Figure-4.10j: BOD of drinking water samples in Ariyalur Chloride Chloride 300 200 Winter 150 Summer 100 SWM 50 NEM 0 3 4 5 6 7 Stations 8 9 10 Figure-4.11a: Chloride of drinking water samples in Ariyalur Units mg/l Units mg/l 250 2 93 Stations Figure-4.10i: BOD of ground water samples in Ariyalur Taluk 1 92 450 400 350 300 250 200 150 100 50 0 Winter Summer SWM NEM 11 12 13 14 15 16 17 Stations 18 19 20 Figure-4.11b: Chloride of drinking water samples in Ariyalur 80 Chloride Winter Summer SWM NEM 21 22 23 24 25 26 27 28 29 30 mg/l mg/l Chloride 500 450 400 350 300 250 200 150 100 50 0 500 450 400 350 300 250 200 150 100 50 0 Winter Summer SWM NEM 0 41 42 43 44 45 46 47 48 49 50 Stations Figure-4.11e: Chloride of drinking water samples in Ariyalur Units mg/l 250 Units mg/l 33 34 35 36 37 38 39 40 Chloride 300 50 32 Figure-4.11d: Chloride of drinking water samples in Ariyalur Chloride 100 NEM Stations Figure-4.11c: Chloride of drinking water samples in Ariyalur 150 Summe r SWM 31 Stations 200 Winter 400 350 300 250 200 150 100 50 0 Winter Summer SWM NEM 51 52 53 54 55 56 57 58 59 60 Stations Figure-4.11f: Chloride of drinking water samples in Ariyalur 81 Chloride Chloride 400 350 250 Winter 200 Summer 150 SWM 100 NEM mg/l mg/l 300 50 0 61 62 63 64 65 66 67 68 69 70 500 450 400 350 300 250 200 150 100 50 0 Winter Summer SWM NEM 71 72 73 74 Stations 76 77 78 79 80 Stations Figure-4.11g: Chloride of drinking water samples in Ariyalur Figure-4.11h: Chloride of drinking water samples in Ariyalur Chloride Chloride 500 75 300 250 300 Summer 200 SWM 100 NEM winter summer 200 Winter mg/l mg/l 400 SWM 150 NEM 100 50 0 81 82 83 84 85 86 87 88 89 0 90 Stations Figure-4.11i: Chloride of drinking water samples in Ariyalur 91 92 93 Stations Figure-4.11j: Chloride of drinking water samples in Ariyalur 82 Fluoride Fluoride 1.6 2 1.4 1.5 1 Winter 0.8 Summer 0.6 SWM 0.4 Winter mg/l mg/l 1.2 1 Summer SWM 0.5 NEM NEM 0.2 0 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 Stations 15 16 17 18 19 20 Stations Figure-4.12a: Fluoride of drinking water samples in Ariyalur Taluk Figure-4.12b: Fluoride of drinking water samples in Ariyalur Flouride Fluoride 1.8 2 1.6 1.4 1.5 1 summer 0.5 1.2 mg/l mg/l winter winter 1 summer 0.8 SWM 0.6 NEM 0.4 SWM NEM 0.2 0 21 22 23 24 25 26 27 28 29 30 Stations Figure-4.12c: Fluoride of drinking water samples in Ariyalur Taluk 0 31 32 33 34 35 36 37 38 39 40 Stations Figure-4.12d: Fluoride of drinking water samples in Ariyalur 83 Fluoride 1.8 Fluoride 1.6 1.6 1.4 1.4 1.2 winter 1 summer winter 1 0.8 summer 0.6 SWM 0.4 NEM 0.4 0.2 0.2 0.8 SWM 0.6 mg/l mg/l 1.2 NEM 0 0 41 42 43 44 45 46 47 48 49 51 50 52 53 54 Stations 56 57 58 59 60 Stations Figure-4.12e: Fluoride of drinking water samples in Ariyalur Taluk Figure-4.12f: Fluoride of drinking water samples in Ariyalur Fluoride Fluoride 1.6 1.6 1.4 1.4 1.2 1.2 winter 0.8 summer 0.6 0.4 winter 1 mg/l 1 mg/l 55 0.8 summer SWM 0.6 SWM NEM 0.4 NEM 0.2 0.2 0 0 61 62 63 64 65 66 67 68 69 70 Stations Figure-4.12g: Fluoride of drinking water samples in Ariyalur 71 72 73 74 75 76 77 78 79 80 Stations Figure-4.12h: Fluoride of drinking water samples in Ariyalur 84 Fluoride 1.8 Fluoride 1.6 1.6 1.4 1.4 1.2 summer 0.8 SWM 0.6 1 mg/l 1 mg/l 1.2 winter NEM 0.4 winter summer SWM NEM 0.8 0.6 0.4 0.2 0.2 0 81 82 83 84 85 86 87 88 0 89 90 91 Figure-4.12i: Fluoride of drinking water samples in Ariyalur Taluk 93 Figure-4.12j: Fluoride of drinking water samples in Ariyalur Sulphate 100 92 Stations Stations Sulphate 50 80 40 Winter Summer SWM 40 Winter mg/l mg/l 60 30 Summer SWM 20 NEM NEM 10 20 0 0 1 2 3 4 5 6 7 8 9 10 Stations Figure-4.13a: Sulphate of drinking water samples in Ariyalur 11 12 13 14 15 16 17 18 19 20 Stations Figure-4.13b: Sulphate of drinking water samples in Ariyalur 85 Sulphate Sulphate 70 60 60 50 50 Summer 30 SWM 20 mg/l mg/l Winter Winter 40 NEM 10 40 Summer 30 SWM 20 NEM 10 0 21 22 23 24 25 26 27 28 29 0 30 31 32 33 34 Stations Sulphate 40 30 Winter 25 Summer 20 SWM 15 NEM 10 5 0 44 45 46 Stations 47 48 49 50 Figure-4.13e: Sulphate of drinking water samples in Ariyalur mg/l mg/l 35 43 37 38 39 40 Figure-4.13d: Sulphate of drinking water samples in Ariyalur 45 42 36 Stations Figure-4.13c: Sulphate of drinking water samples in Ariyalur 41 35 Sulphate 45 40 35 30 25 20 15 10 5 0 Winter Summer SWM NEM 51 52 53 54 55 56 57 58 59 60 Stations Figure-4.13f: Sulphate of drinking water samples in Ariyalur 86 Sulphate 70 60 60 50 40 Winter 30 Summer mg/l mg/l 50 SWM 20 40 Winter 30 Summer SWM 20 NEM 10 Sulphate NEM 10 0 0 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 Stations Stations Figure-4.13g: Sulphate of drinking water samples in Ariyalur Figure-4.13h: Sulphate of drinking water samples in Ariyalur Sulphate Sulphate 50 30 40 25 Summer SWM 20 NEM winter 20 mg/l mg/l Winter 30 summer 15 SWM 10 NEM 10 5 0 81 82 83 84 85 86 87 88 89 Stations Figure-4.13i: Sulphate of drinking water samples in Ariyalur 0 90 91 92 93 Stations Figure-4.13j: Sulphate of drinking water samples in Ariyalur 87 Phophate 0.4 0.35 0.35 0.3 0.3 Summer 0.2 SWM 0.15 Winter 0.2 mg/l mg/l 0.25 Winter 0.25 Summer 0.15 SWM 0.1 NEM 0.1 Phosphate NEM 0.05 0.05 0 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 16 17 18 19 20 Stations Stations Figure-4.14a: Phosphate of drinking water samples in Ariyalur Figure-4.14b: Phosphate drinking water samples in Ariyalur Phosphate Phosphate 0.35 0.35 0.3 0.3 0.25 0.25 Winter 0.2 Summer mg/l mg/l 15 Winter 0.2 Summer 0.15 SWM 0.15 SWM 0.1 NEM 0.1 NEM 0.05 0.05 0 0 21 22 23 24 25 26 27 28 29 30 Stations Figure-4.14c: Phosphate of drinking water samples in Ariyalur 31 32 33 34 35 36 37 38 39 40 Stations Figure-4.14d: Phosphate drinking water samples in Ariyalur 88 Phophate Phophate 0.35 0.5 0.3 0.4 0.25 Summer 0.2 SWM 0.2 mg/l 0.3 mg/l Winter Winter NEM 0.1 Summer 0.15 SWM 0.1 NEM 0.05 0 41 42 43 44 45 46 47 48 49 0 50 51 52 53 54 Stations Figure-4.14e: Phosphate of drinking water samples in Ariyalur 58 59 60 Phosphate 0.4 0.3 0.35 0.25 0.3 0.2 Summer 0.15 SWM 0.1 NEM 0.05 mg/l Winter mg/l 57 Figure-4.14f: Phosphate drinking water samples in Ariyalur Phosphate 0.35 55 56 Stations Winter 0.25 Summer 0.2 SWM 0.15 NEM 0.1 0.05 0 61 62 63 64 65 66 67 68 69 70 Stations Figure-4.14g: Phosphate of drinking water samples in Ariyalur 0 71 72 73 74 75 76 Stations 77 78 79 80 Figure-4.14h: Phosphate drinking water samples in Ariyalur 89 Phosphate Phosphate 0.35 0.35 0.3 0.3 0.25 0.25 0.2 Summer 0.15 SWM 0.1 NEM mg/l mg/l Winter winter 0.2 summer SWM 0.15 NEM 0.1 0.05 0.05 0 81 82 83 84 85 86 87 88 0 89 90 91 Stations Figure-4.14i: Phosphate of drinking water samples in Ariyalur Summer SWM NEM 3 4 5 6 7 8 9 10 Stations Figure-4.15a: Nitrite of drinking water samples in Ariyalur Taluk mg/l mg/l Nitrite Winter 2 93 Figure-4.14j: Phosphate drinking water samples in Ariyalur Nitrite 4.5 4 3.5 3 2.5 2 1.5 1 0.5 0 1 92 Stations 0.9 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0 Winter Summer SWM NEM 11 12 13 14 15 16 17 18 19 20 Stations Figure-4.15b: Nitrite drinking water samples in Ariyalur Taluk 90 Nitrite 1.8 1.6 1.4 1.2 1 0.8 0.6 0.4 0.2 0 Winter Summer SWM Units mg/l Units mg/l Nitrite NEM 21 22 23 24 25 26 27 Stations 28 29 1.8 1.6 1.4 1.2 1 0.8 0.6 0.4 0.2 0 Winter Summer SWM NEM 31 30 Figure-4.15c: Nitrite of drinking water samples in Ariyalur Taluk 32 33 34 38 39 40 Figure-4.15d: Nitrite drinking water samples in Ariyalur Taluk Nitrite Nitrite 1 1.2 0.8 1 Winter 0.6 Summer 0.4 SWM 0.2 NEM Units mg/l Units mg/l 35 36 37 Stations 0.8 Winter 0.6 Summer 0.4 SWM 0.2 NEM 0 0 41 42 43 44 45 46 47 Stations 48 49 50 Figure-4.15e: Nitrite of drinking water samples in Ariyalur Taluk 51 52 53 54 55 56 57 Stations 58 59 60 Figure-4.15f: Nitrite drinking water samples in Ariyalur Taluk 91 Nitrite 0.8 1.2 0.7 1 Nitrite 0.5 Winter 0.8 Winter 0.4 Summer 0.6 Summer 0.3 SWM mg/l mg/l 0.6 NEM 0.2 SWM 0.4 NEM 0.2 0.1 0 61 62 63 64 65 66 67 68 69 0 70 71 72 73 74 Stations Figure-4.15g: Nitrite of drinking water samples in Ariyalur Taluk 77 78 79 80 Figure-4.15h: Nitrite drinking water samples in Ariyalur Taluk Nitrite Nitrite 0.6 0.7 0.5 0.6 Winter 0.4 0.5 Summer 0.3 SWM 0.2 mg/l mg/l 75 76 Stations 0.4 Winter Summer SWM NEM 0.3 NEM 0.2 0.1 0.1 0 81 82 83 84 85 86 87 88 89 Stations Figure-4.15i: Nitrite of drinking water samples in Ariyalur Taluk 0 90 91 92 93 Statoins Figure-4.15j: Nitrite drinking water samples in Ariyalur Taluk 92 Nitrate Nitrate 14 12 Winter 8 Summer 6 mg/l mg/l 10 SWM 4 NEM 2 0 1 2 3 4 5 6 7 8 9 18 16 14 12 10 8 6 4 2 0 10 Winter Summer SWM NEM 11 12 13 14 Stations Figure-4.16a: Nitrate of drinking water samples in Ariyalur Taluk 17 18 19 20 Figure-4.16b: Nitrate drinking water samples in Ariyalur Taluk Nitrate Nitrate 16 16 14 14 12 12 Summer 8 mg/l Winter 10 mg/l 15 16 Stations 10 Winter 8 6 SWM 6 4 NEM 4 Summer SWM NEM 2 2 0 0 21 22 23 24 25 26 27 28 29 30 Stations Figure-4.16c: Nitrate of drinking water samples in Ariyalur Taluk 31 32 33 34 35 36 37 38 39 40 Stations Figure-4.16d: Nitrate drinking water samples in Ariyalur Taluk 93 Nitrate 18 16 14 12 Winter Summer SWM mg/l mg/l Nitrate 20 18 16 14 12 10 8 6 4 2 0 Winter 10 Summer 8 SWM 6 NEM NEM 4 2 0 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 Stations Stations Figure-4.16e: Nitrate of drinking water samples in Ariyalur Taluk Figure-4.16f: Nitrate drinking water samples in Ariyalur Taluk Nitrate Nitrate 20 18 16 15 12 Winter 10 Summer 8 SWM 6 NEM 4 mg/l mg/l 14 Winter Summer 10 SWM NEM 5 2 0 0 61 62 63 64 65 66 Stations 67 68 69 70 Figure-4.16g: Nitrate of drinking water samples in Ariyalur Taluk 71 72 73 74 75 76 77 78 79 80 Stations Figure-4.16h: Nitrate drinking water samples in Ariyalur Taluk 94 Nitrate Nitrate 18 12 16 10 14 Summer 8 SWM 6 summer 6 SWM NEM 4 NEM 4 winter 8 Winter 10 mg/l mg/l 12 2 2 0 81 82 83 84 85 86 87 88 0 89 90 91 Stations Figure-4.16i: Nitrate of drinking water samples in Ariyalur Taluk Calcium 250 250 200 200 Winter 150 Summer SWM 100 mg/l mg/l 93 Figure-4.16j: Nitrate drinking water samples in Ariyalur Taluk Calcium 300 92 Stations Winter 150 Summer 100 SWM NEM NEM 50 50 0 0 1 2 3 4 5 6 7 8 9 10 Stations Figure-4.17a: Calcium of drinking water samples in Ariyalur Taluk 11 12 13 14 15 16 17 18 19 20 Stations Figure-4.17b: Calcium drinking water samples in Ariyalur Taluk 95 Calcium 250 Calcium 200 mg/l Summer 100 SWM mg/l Winter 150 NEM 50 0 21 22 23 24 25 26 27 28 29 30 500 450 400 350 300 250 200 150 100 50 0 Winter Summer SWM NEM 31 32 33 34 Stations Figure-4.17c: Calcium of drinking water samples in Ariyalur Taluk 37 38 39 40 Figure-4.17d: Calcium of drinking water samples in Ariyalur Calcium Calcium 300 300 250 250 Winter 150 Summer 100 SWM 200 mg/l 200 mg/l 35 36 Stations Winter 150 Summer 100 SWM NEM 50 NEM 50 0 0 41 42 43 44 45 46 47 48 49 50 Stations Figure-4.17e: Calcium of drinking water samples in Ariyalur Taluk 51 52 53 54 55 56 57 58 59 60 Stations Figure-4.17f: Calcium of drinking water samples in Ariyalur 96 Winter Summer SWM mg/l mg/l Calcium 200 180 160 140 120 100 80 60 40 20 0 NEM 61 62 63 64 65 66 67 68 69 Calcium 200 180 160 140 120 100 80 60 40 20 0 70 Winter Summer SWM NEM 71 72 73 74 Stations 76 77 78 79 80 Stations Figure-4.17g: Calcium of drinking water samples in Ariyalur Figure-4.17h: Calcium of drinking water samples in Ariyalur Calcium Calcium 250 250 200 200 Winter 150 winter Summer SWM 100 NEM 50 150 mg/l mg/L 75 summer SWM NEM 100 50 0 81 82 83 84 85 86 87 88 89 0 90 Stations Figure-4.17i: Calcium of drinking water samples in Ariyalur Taluk 91 92 93 Stations Figure-4.17j: Calcium of drinking water samples in Ariyalur 97 Magnesium Magnesium 140 300 120 250 80 60 200 summer 150 SWM 100 NEM SWM 40 Winter winter Summer mg/l mg/l 100 NEM 50 20 0 0 1 2 3 4 5 6 7 8 9 11 10 12 13 14 15 Stations 17 18 19 20 Stations Figure-4.18a: Magnesium of drinking water samples in Ariyalur Figure-4.18b: Magnesium of drinking water samples in Ariyalur Magnesium Magnesium 300 250 250 200 Winter 200 Summer 150 SWM NEM 100 Winter mg/l mg/l 16 150 Summer SWM 100 NEM 50 50 0 0 21 22 23 24 25 26 27 28 29 30 Stations Figure-4.18c: Magnesium of drinking water samples in Ariyalur 31 32 33 34 35 36 37 38 39 40 Stations Figure-4.18d: Magnesium of drinking water samples in Ariyalur 98 Magnesium 140 120 200 100 Winter 80 Summer 60 SWM 40 NEM mg/l mg/l Magnesium 250 Winter 150 Summer SWM 100 NEM 50 20 0 0 41 42 43 44 45 46 47 48 49 51 50 52 53 54 56 57 58 59 60 Stations Stations Figure-4.18e: Magnesium of drinking water samples in Ariyalur Figure-4.18f: Magnesium of drinking water samples in Ariyalur Magnesium 140 140 120 120 80 SWM 60 NEM 40 mg/l Summer Magnesium 100 Winter 100 mg/l 55 Winter 80 Summer 60 SWM 40 NEM 20 20 0 0 61 62 63 64 65 66 67 68 69 70 Stations Figure-4.18g: Magnesium of drinking water samples in Ariyalur 71 72 73 74 75 76 77 78 79 80 Stations Figure-4.18h: Magnesium of drinking water samples in Ariyalur 99 Magnesium Magnesium 160 100 90 80 70 60 50 40 30 20 10 0 140 120 mg/l 80 Summer 60 SWM 40 NEM 20 0 81 82 83 84 85 86 87 88 winter summe r SWM mg/l Winter 100 89 90 Stations 92 93 Stations Figure-4.18i: Magnesium of drinking water samples in Ariyalur Sodium Figure-4.18j: Magnesium of drinking water samples in Ariyalur 160 180 140 160 Sodium 140 120 120 Summer 100 80 60 SWM 40 NEM 20 mg/l Winter 100 mg/l 91 Winter Summer 80 SWM 60 NEM 40 20 0 0 1 2 3 4 5 6 7 8 9 10 Stations Figure-4.19a: Sodium of drinking water samples in Ariyalur 11 12 13 14 15 16 17 18 19 20 Stations Figure-4.19b: Sodium of drinking water samples in Ariyalur 100 Sodium Sodium 180 250 160 200 140 Winter 100 Summer 80 SWM 60 Winter 150 Summer mg/l mg/l 120 SWM 100 NEM 40 NEM 50 20 0 0 21 22 23 24 25 26 27 28 29 31 30 32 33 34 Stations 120 Winter 80 Summer 60 SWM 40 NEM 20 0 45 46 47 48 49 50 Stations Figure-4.19e: Sodium of drinking water samples in Ariyalur mg/l mg/l 100 44 38 39 40 Sodium 140 43 37 Figure-4.19d: Sodium of drinking water samples in Ariyalur Sodium 42 36 Stations Figure-4.19c: Sodium of drinking water samples in Ariyalur 41 35 200 180 160 140 120 100 80 60 40 20 0 Winter Summer SWM NEM 51 52 53 54 55 56 57 58 59 60 Stations Figure-4.19f: Sodium of drinking water samples in Ariyalur 101 Sodium 250 200 Summer mg/l Winter 150 mg/l Sodium 300 250 200 Winter 150 Summer SWM 100 SWM 100 NEM 50 NEM 50 0 61 62 63 64 65 66 67 68 69 0 70 71 72 73 74 76 77 78 79 80 Stations Stations Figure-4.19g: Sodium of drinking water samples in Ariyalur Figure-4.19h: Sodium of drinking water samples in Ariyalur Sodium Sodium 300 75 180 250 160 140 Winter Summer 150 SWM 100 NEM 50 winter 120 mg/l mg/l 200 summer 100 SWM 80 NEM 60 40 20 0 81 82 83 84 85 86 87 88 89 Stations Figure-4.19i: Sodium of drinking water samples in Ariyalur 0 90 91 Stations 92 93 Figure-4.19j: Sodium of drinking water samples in Ariyalur 102 18 16 16 14 14 12 12 Winter 10 Summer 8 6 4 mg/l mg/l Pottasium Pottasium 18 Winter Summer 10 8 SWM SWM 6 NEM NEM 4 2 2 0 0 1 2 3 4 5 6 7 8 9 11 10 12 13 14 15 16 17 18 19 20 Stations Stations Figure-4.20a: Potassium of drinking water samples in Ariyalur Figure-4.20b: Potassium of drinking water samples in Ariyalur Pottasium Pottasium 35 20 30 15 Summer 10 SWM NEM 5 mg/l mg/l Winter 25 Winter 20 Summer 15 SWM 10 NEM 5 0 21 22 23 24 25 26 27 28 29 30 Stations Figure-4.20c: Potassium of drinking water samples in Ariyalur 0 31 32 33 34 35 36 37 38 39 40 Stations Figure-4.20d: Potassium of drinking water samples in Ariyalur 103 25 20 20 Winter 15 Summer 10 mg/l mg/l Pottasium 25 Winter 15 Summer 10 SWM SWM NEM NEM 5 Pottasium 5 0 0 41 42 43 44 45 46 47 48 49 50 51 52 53 54 Stations 55 56 57 58 59 60 Stations Figure-4.20e: Potassium of drinking water samples in Ariyalur Figure-4.20f: Potassium of drinking water samples in Ariyalur Pottasium Pottasium 25 30 20 25 Winter Summer SWM 10 NEM 5 mg/l mg/l 15 Winter 20 Summer 15 SWM 10 NEM 5 0 0 61 62 63 64 65 66 67 68 69 70 Stations Figure-4.20g: Potassium of drinking water samples in Ariyalur 71 72 73 74 75 76 77 78 79 80 Stations Figure-4.20h: Potassium of drinking water samples in Ariyalur 104 Pottasium Potassium 35 14 12 25 Winter 20 Summer 15 SWM NEM 10 winter 10 mg/l mg/l 30 summer 8 SWM 6 NEM 4 5 2 0 81 82 83 84 85 86 87 88 0 89 90 91 Stations Figure-4.20i: Potassium of drinking water samples in Ariyalur 93 Figure-4.20j: Potassium of drinking water samples in Ariyalur Fecal Colirform Fecal Colirform 25 40 35 20 Winter 15 Summer 10 SWM NEM 5 N/100ml N/100ml 92 Stations 30 Winter 25 Summer 20 SWM 15 NEM 10 5 0 0 1 2 3 4 5 6 7 8 9 10 Stations Figure-4.21a: F.Coliform of drinking water samples in Ariyalur 11 12 13 14 15 16 17 18 19 20 Stations Figure-4.21b: F.Coliform of drinking water samples in Ariyalur 105 Fecal Coliform Fecal Coliform 40 30 35 25 Summer 15 SWM 10 N/100ml N/100ml 30 Winter 20 NEM 25 Winter 20 Summer 15 SWM 10 NEM 5 5 0 21 22 23 24 25 26 27 28 29 0 30 31 32 33 34 Stations 35 36 37 38 39 40 Stations Figure-4.21c: F.Coliform of drinking water samples in Ariyalur Figure-4.21d: F.Coliform of drinking water samples in Ariyalur Fecal Coliform Fecal Coliform 40 30 35 25 30 Winter Summer 20 SWM 15 NEM 10 Winter 20 N/100ml N/100ml 25 Summer 15 SWM 10 NEM 5 5 0 0 41 42 43 44 45 46 47 48 49 50 Stations Figure-4.21e: F.Coliform of drinking water samples in Ariyalur 51 52 53 54 55 56 57 58 59 60 Stations Figure-4.21f: F.Coliform of drinking water samples in Ariyalur 106 Fecal Coliform Fecal Colrform 40 50 35 30 Winter 30 Summer 20 SWM N/100ml N/100ml 40 Winter 20 Summer 15 SWM 10 NEM 10 25 NEM 5 0 0 61 62 63 64 65 66 67 68 69 71 70 72 73 74 75 Stations 77 78 79 80 Stations Figure-4.21g: F.Coliform of drinking water samples in Ariyalur Figure-4.21h: F.Coliform of drinking water samples in Ariyalur Fecal Coliform Fecal coliform 50 35 40 30 winter Winter 30 Summer SWM 20 NEM 10 N/100ml N/100ml 76 25 summer 20 SWM 15 NEM 10 5 0 81 82 83 84 85 86 Stations 87 88 89 0 90 91 92 93 Stations Figure-4.21i: F.Coliform of drinking water samples in Ariyalur Figure-4.21j: F.Coliform of drinking water samples in Ariyalur 107 Iorn Iorn 0.3 0.3 Winter 0.25 Summer SWM 0.15 NEM 0.2 mg/l 0.2 mg/l 0.25 Winter Summer 0.15 SWM 0.1 0.1 0.05 NEM 0.05 0 1 2 3 4 5 6 7 8 9 0 10 11 12 13 14 Stations 16 17 18 19 20 Stations Figure-4.22a: Iron of drinking water samples in Ariyalur Taluk Figure-4.22b: Iron of drinking water samples in Ariyalur Taluk Iron Iron 0.14 0.35 0.12 0.3 0.1 0.25 Winter mg/l mg/l 15 Winter 0.08 Summer 0.06 SWM 0.15 SWM 0.04 NEM 0.1 NEM 0.2 Summer 0.05 0.02 0 0 21 22 23 24 25 26 27 28 29 30 Stations Figure-4.22c: Iron of drinking water samples in Ariyalur Taluk 31 32 33 34 35 36 37 38 39 40 Stations Figure-4.22d: Iron of drinking water samples in Ariyalur Taluk 108 Iron Iron 0.4 0.3 0.35 0.25 0.3 Winter Summer 0.15 SWM 0.1 winter 0.25 mg/l mg/l 0.2 NEM 0.05 summer 0.2 0.15 SWM 0.1 NEM 0.05 0 41 42 43 44 45 46 47 48 49 0 50 51 52 53 54 Stations 55 56 57 58 59 60 Stations Figure-4.22e: Iron of drinking water samples in Ariyalur Taluk Figure-4.22f: Iron of drinking water samples in Ariyalur Taluk Iron Iron 0.7 0.5 0.6 0.3 winter 0.5 summer 0.4 SWM 0.2 NEM 0.1 mg/l mg/l 0.4 winter summer 0.3 SWM 0.2 NEM 0.1 0 0 61 62 63 64 65 66 67 68 69 70 Stations Figure-4.22g: Iron of drinking water samples in Ariyalur Taluk 71 72 73 74 75 76 77 78 79 80 Stations Figure-4.22h: Iron of drinking water samples in Ariyalur Taluk 109 Iron Iron 0.4 0.2 0.35 0.3 winter 0.15 summer 0.2 SWM 0.15 NEM 0.1 winter mg/l mg/l 0.25 0.1 summer SWM 0.05 NEM 0.05 0 81 82 83 84 85 86 87 88 0 89 90 91 Stations Figure-4.22i: Iron of drinking water samples in Ariyalur Taluk 93 Figure-4.22j: Iron of drinking water samples in Ariyalur Taluk Lead Lead 0.03 92 Staions 0.02 0.025 mg/l Winter Summer 0.015 mg/l 0.015 0.02 Winter 0.01 Summer SWM 0.01 NEM SWM 0.005 NEM 0.005 0 0 1 2 3 4 5 6 7 8 9 10 Stations Figure-4.23a: Lead of drinking water samples in Ariyalur Taluk 11 12 13 14 15 16 17 18 19 20 Stations Figure-4.23b: Lead of drinking water samples in Ariyalur Taluk 110 Lead 0.02 0.015 0.015 Winter Winter Summer 0.01 SWM mg/l mg/l Lead 0.02 SWM NEM 0.005 NEM 0.005 Summer 0.01 0 0 21 22 23 24 25 26 Stations 27 28 29 31 30 32 33 34 36 37 38 39 40 Stations Figure-4.23c: Lead of drinking water samples in Ariyalur Taluk Figure-4.23d: Lead of drinking water samples in Ariyalur Taluk Lead Lead 0.02 0.02 0.015 0.015 Winter Summer 0.01 SWM 0.005 NEM 0 41 42 43 44 45 46 47 48 49 50 Stations Figure-4.23e: Lead of drinking water samples in Ariyalur Taluk Winter mg/l mg/l 35 Summer 0.01 SWM NEM 0.005 0 51 52 53 54 55 56 57 58 59 60 Stations Figure-4.23f: Lead of drinking water samples in Ariyalur Taluk 111 Lead 0.03 Lead 0.02 0.025 0.015 Winter Winter Summer 0.015 SWM 0.01 Summer 0.01 mg/l mg/l 0.02 SWM NEM 0.005 NEM 0.005 0 0 61 62 63 64 65 66 67 68 69 71 70 72 73 74 76 77 78 79 80 Stations Stations Figure-4.23g: Lead of drinking water samples in Ariyalur Taluk Figure-4.23h: Lead of drinking water samples in Ariyalur Taluk Lead 0.01 75 Lead 0.03 0.025 Winter 0.006 0.02 Summer SWM 0.004 NEM mg/l mg/l 0.008 winter 0.015 summer SWM 0.01 0.002 NEM 0.005 0 81 82 83 84 85 86 87 88 89 Stations Figure-4.23i: Lead of drinking water samples in Ariyalur Taluk 0 90 91 92 93 Stations Figure-4.23j: Lead of drinking water samples in Ariyalur Taluk 112 Cadmium 0.06 0.03 0.05 0.025 Winter Summer 0.03 SWM 0.02 Winter 0.02 mg/l mg/l 0.04 Cadmium Summer 0.015 SWM 0.01 NEM 0.01 NEM 0.005 0 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 Stations 17 18 19 20 Figure-4.24b: Cadmium of drinking water samples in Ariyalur Cadmium Cadmium 0.06 0.04 0.05 Winter Summer SWM 0.02 NEM Winter 0.04 mg/l 0.03 mg/l 16 Stations Figure-4.24a: Cadmium of drinking water samples in Ariyalur 0.05 15 Summer 0.03 SWM 0.02 NEM 0.01 0.01 0 21 22 23 24 25 26 27 28 29 30 Stations Figure-4.24c: Cadmium of drinking water samples in Ariyalur 0 31 32 33 34 35 36 37 38 39 40 Stations Figure-4.24d: Cadmium of drinking water samples in Ariyalur 113 Cadmium Cadmium 0.04 0.05 0.035 0.04 0.03 mg/l Summer 0.02 0.015 SWM 0.01 NEM mg/l Winter 0.025 Winter 0.03 Summer 0.02 SWM NEM 0.01 0.005 0 0 41 42 43 44 45 46 47 48 49 51 50 52 53 54 Stations Cadmium Winter 0.03 Summer 0.02 SWM NEM 0.01 0 65 66 67 68 69 70 Stations Figure-4.24g: Cadmium of drinking water samples in Ariyalur mg/l mg/l 0.04 64 58 59 60 Cadmium 0.05 63 57 Figure-4.24f: Cadmium of drinking water samples in Ariyalur 0.06 62 56 Stations Figure-4.24e: Cadmium of drinking water samples in Ariyalur 61 55 0.05 0.045 0.04 0.035 0.03 0.025 0.02 0.015 0.01 0.005 0 Winter Summer SWM NEM 71 72 73 74 75 76 77 78 79 80 Stations Figure-4.24h: Cadmium of drinking water samples in Ariyalur 114 Cadmium 0.03 Cadmium 0.025 Winter Summer 0.015 SWM 0.01 mg/l mg/l 0.02 NEM 0.005 0 81 82 83 84 85 86 87 88 89 0.05 0.045 0.04 0.035 0.03 0.025 0.02 0.015 0.01 0.005 0 winter summer SWM NEM 90 91 Stations Figure-4.24i: Cadmium of drinking water samples in Ariyalur Chromium 0.06 0.05 0.05 Winter 0.04 0.04 Winter 0.03 Summer Summer 0.03 SWM 0.02 NEM 0.01 mg/l mg/l 93 Figure-4.24j: Cadmium of drinking water samples in Ariyalur Chromium 0.06 92 Stations SWM 0.02 NEM 0.01 0 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 Stations Stations Figure-4.25a: Cromium of drinking water samples in Ariyalur Figure-4.25b: Cromium of drinking water samples in Ariyalur 115 Chromium Chromium 0.06 0.06 0.05 0.05 mg/l Summer 0.03 SWM 0.02 mg/l Winter 0.04 0.04 Winter 0.03 Summer SWM 0.02 NEM NEM 0.01 0.01 0 0 21 22 23 24 25 26 27 28 29 31 30 32 33 34 Stations 37 38 39 40 Figure-4.25d: Cromium of drinking water samples in Ariyalur Chromium Chromium 0.09 0.08 0.05 0.07 0.03 Winter 0.06 Winter Summer 0.05 Summer 0.04 SWM SWM 0.02 NEM 0.01 mg/l 0.04 mg/l 36 Stations Figure-4.25c: Cromium of drinking water samples in Ariyalur 0.06 35 0.03 NEM 0.02 0.01 0 0 41 42 43 44 45 46 47 48 49 50 Stations Figure-4.25e: Cromium of drinking water samples in Ariyalur 51 52 53 54 55 56 57 58 59 60 Stations Figure-4.25f: Cromium of drinking water samples in Ariyalur 116 Chromium 0.06 0.05 0.05 0.04 0.04 Winter 0.03 Summer Winter 0.03 Summer 0.02 mg/l mg/l Chromium 0.06 SWM 0.01 SWM 0.02 NEM 0.01 NEM 0 0 61 62 63 64 65 66 67 68 69 70 71 72 73 74 Stations 76 77 78 79 80 Stations Figure-4.25g: Cromium of drinking water samples in Ariyalur Figure-4.25h: Cromium of drinking water samples in Ariyalur Chromium Chromium 0.06 0.08 0.05 0.07 0.03 Winter 0.06 Summer 0.05 SWM 0.02 NEM mg/l 0.04 mg/l 75 winter 0.04 summer 0.03 SWM 0.02 0.01 NEM 0.01 0 81 82 83 84 85 86 87 88 89 Stations Figure-4.25i: Cromium of drinking water samples in Ariyalur 0 90 91 92 93 Stations Figure-4.25j: Cromium of drinking water samples in Ariyalur 117 Table-4.4: Conformity of number of water samples from municipal water supply with standards in winter Sl.No. Parameters Desirable limit Below desirable limit Above desirable limit 1 pH 6.5-8.5 5 0 2 DO >6.0 mg/l 5 0 3 Turbidity 5.0 NTU 5 0 4 TDS 500 mg/l 4 1 5 T.Hardness 300 mg/l 1 4 6 T.Alkalinity 200 mg/l 1 4 7 Nitrate 45 mg/l 5 0 8 Phosphate 25 mg/l 5 0 9 COD 10 mg/l 1 4 10 BOD 2.0 mg/l 0 5 11 Cl- 250 mg/l 5 0 12 SO4- 400 mg/l 5 0 13 Ca++ 75 mg/l 3 2 14 Mg++ 30 mg/l 2 3 15 Na++ 200 mg/l 5 0 16 F- 1.0-1.5 mg/l 5 0 17 Iorn 0.3-1.0 mg/l 5 0 18 Fecal coliform <50/ 100ml 5 0 19 Lead 0.05 mg/l 5 0 20 Cadmium 0.01 mg/l 0 5 21 Chromium 0.05 mg/l 4 1 118 Table-4.5: Conformity of number of water samples from municipal water supply with standards in summer Desirable Below Above Sl.No. Parameters limit desirable limit desirable limit 1 pH 6.5-8.5 5 0 2 DO >6.0 mg/l 5 0 3 Turbidity 5.0 NTU 5 0 4 TDS 500 mg/l 4 1 5 T.Hardness 300 mg/l 3 2 6 T.Alkalinity 200 mg/l 0 5 7 Nitrate 45 mg/l 5 0 8 Phosphate 25 mg/l 5 0 9 COD 10 mg/l 1 4 10 BOD 2.0 mg/l 0 5 11 Cl- 250 mg/l 5 0 12 SO4- 400 mg/l 5 0 13 Ca++ 75 mg/l 1 4 14 Mg++ 30 mg/l 2 3 15 Na++ 200 mg/l 5 0 16 F- 1.0-1.5 mg/l 4 1 17 Iron 0.3-1.0 mg/l 5 0 18 Fecal coliform <50/ 100ml 5 0 19 Lead 0.05 mg/l 5 0 20 Cadmium 0.01 mg/l 5 0 21 Chromium 0.05 mg/l 4 1 119 Table-4.6: Conformity of number of water samples from municipal water supply with standards in southwest monsoon Desirable Below Above S.No. Parameters limit desirable limit desirable limit 1 pH 6.5-8.5 4 1 2 DO >6.0 mg/l 5 0 3 Turbidity 5.0 NTU 5 0 4 TDS 500 mg/l 3 2 5 T.Hardness 300 mg/l 2 3 6 T.Alkalinity 200 mg/l 2 3 7 Nitrate 45 mg/l 5 0 8 Phosphate 25 mg/l 5 0 9 COD 10 mg/l 0 5 10 BOD 2.0 mg/l 1 4 11 Cl- 250 mg/l 5 0 12 SO4- 400 mg/l 5 0 13 Ca++ 75 mg/l 4 1 14 Mg++ 30 mg/l 0 5 15 Na++ 200 mg/l 5 0 16 F- 1.0-1.5 mg/l 5 0 17 Iron 0.3-1.0 mg/l 5 0 18 Fecal coliform <50/ 100ml 5 0 19 Lead 0.05 mg/l 5 0 20 Cadmium 0.01 mg/l 1 4 21 Chromium 0.05 mg/l 5 0 120 Table-4.7: Conformity of number of water samples from municipal water supply with standards in northeast monsoon Desirable Below Above S.No. Parameters limit desirable limit desirable limit 1 pH 6.5-8.5 5 0 2 DO >6.0 mg/l 5 0 3 Turbidity 5.0 NTU 5 0 4 TDS 500 mg/l 2 3 5 T.Hardness 300 mg/l 0 5 6 T.Alkalinity 200 mg/l 2 3 7 Nitrate 45 mg/l 5 0 8 Phosphate 25 mg/l 5 0 9 COD 10 mg/l 1 4 10 BOD 2.0 mg/l 0 5 11 Cl- 250 mg/l 5 0 12 SO4- 400 mg/l 5 0 13 Ca++ 75 mg/l 5 0 14 Mg++ 30 mg/l 0 5 15 Na++ 200 mg/l 5 0 16 F- 1.0-1.5 mg/l 5 0 17 Iorn 0.3-1.0 mg/l 5 0 18 Fecal coliform <50/ 100ml 5 0 19 Lead 0.05 mg/l 5 0 20 Cadmium 0.01 mg/l 5 0 21 Chromium 0.05 mg/l 5 0 121 Table-4.8: Conformity of number of water samples from public places with standards in winter season Desirable Below Above S.No. Parameters limit desirable limit desirable limit 1 pH 6.5-8.5 8 0 2 DO >6.0 mg/l 8 0 3 Turbidity 5.0 NTU 8 0 4 TDS 500 mg/l 3 5 5 T.Hardness 300 mg/l 1 7 6 T.Alkalinity 200 mg/l 0 8 7 Nitrate 45 mg/l 8 0 8 Phosphate 25 mg/l 8 0 9 COD 10 mg/l 0 8 10 BOD 2.0 mg/l 1 7 11 Cl- 250 mg/l 7 1 12 SO4- 400 mg/l 8 0 13 Ca++ 75 mg/l 1 7 14 Mg++ 30 mg/l 3 5 15 Na++ 200 mg/l 8 0 16 F- 1.0-1.5 mg/l 6 2 17 Iron 0.3-1.0 mg/l 8 0 18 Fecal coliform <50/ 100ml 8 0 19 Lead 0.05 mg/l 8 0 20 Cadmium 0.01 mg/l 1 7 21 Chromium 0.05 mg/l 8 0 122 Table-4.9: Conformity of number of water samples from public places with standards in summer season Desirable Below Above S.No. Parameters limit desirable limit desirable limit 1 pH 6.5-8.5 7 1 2 DO >6.0 mg/l 8 0 3 Turbidity 5.0 NTU 8 0 4 TDS 500 mg/l 4 4 5 T.Hardness 300 mg/l 2 6 6 T.Alkalinity 200 mg/l 0 8 7 Nitrate 45 mg/l 8 0 8 Phosphate 25 mg/l 8 0 9 COD 10 mg/l 2 0 10 BOD 2.0 mg/l 0 8 11 Cl- 250 mg/l 8 0 12 SO4- 400 mg/l 8 0 13 Ca++ 75 mg/l 0 8 14 Mg++ 30 mg/l 4 4 15 Na++ 200 mg/l 8 0 16 F- 1.0-1.5 mg/l 4 4 17 Iorn 0.3-1.0 mg/l 8 0 18 Fecal coliform <50/ 100ml 8 0 19 Lead 0.05 mg/l 8 0 20 Cadmium 0.01 mg/l 8 0 21 Chromium 0.05 mg/l 8 0 123 Table-4.10: Conformity of number of water samples from public places with standards in southwest monsoon Desirable Below Above S.No. Parameters limit desirable limit desirable limit 1 pH 6.5-8.5 8 0 2 DO >6.0 mg/l 8 0 3 Turbidity 5.0 NTU 8 0 4 TDS 500 mg/l 1 7 5 T.Hardness 300 mg/l 1 7 6 T.Alkalinity 200 mg/l 0 8 7 Nitrate 45 mg/l 8 0 8 Phosphate 25 mg/l 8 0 9 COD 10 mg/l 0 8 10 BOD 2.0 mg/l 0 8 11 Cl- 250 mg/l 7 1 12 SO4- 400 mg/l 8 0 13 Ca++ 75 mg/l 2 6 14 Mg++ 30 mg/l 2 6 15 Na++ 200 mg/l 8 0 16 F- 1.0-1.5 mg/l 5 3 17 Iron 0.3-1.0 mg/l 8 0 18 Fecal coliform <50/ 100ml 8 0 19 Lead 0.05 mg/l 8 0 20 Cadmium 0.01 mg/l 1 7 21 Chromium 0.05 mg/l 6 2 124 Table-4.11: Conformity of number of water samples from public places with standards in northeast monsoon Desirable Below Above S.No. Parameters limit desirable limit desirable limit 1 pH 6.5-8.5 5 3 2 DO >6.0 mg/l 8 0 3 Turbidity 5.0 NTU 8 0 4 TDS 500 mg/l 3 5 5 T.Hardness 300 mg/l 0 8 6 T.Alkalinity 200 mg/l 1 7 7 Nitrate 45 mg/l 8 0 8 Phosphate 25 mg/l 8 0 9 COD 10 mg/l 1 7 10 BOD 2.0 mg/l 0 8 11 Cl- 250 mg/l 7 1 12 SO4- 400 mg/l 8 0 13 Ca++ 75 mg/l 4 4 14 Mg++ 30 mg/l 0 8 15 Na++ 200 mg/l 8 - 16 F- 1.0-1.5 mg/l 8 0 17 Iorn 0.3-1.0 mg/l 8 0 18 Fecal coliform <50/ 100ml 8 0 19 Lead 0.05 mg/l 8 0 20 Cadmium 0.01 mg/l 8 0 21 Chromium 0.05 mg/l 8 0 125 Table-4.12: Conformity of number of water samples from educational institutions with standards in winter season Desirable Below Above S.No. Parameters limit desirable limit desirable limit 1 pH 6.5-8.5 7 1 2 DO >6.0 mg/l 10 0 3 Turbidity 5.0 NTU 10 0 4 TDS 500 mg/l 2 8 5 T.Hardness 300 mg/l 1 9 6 T.Alkalinity 200 mg/l 0 10 7 Nitrate 45 mg/l 10 0 8 Phosphate 25 mg/l 10 0 9 COD 10 mg/l 0 10 10 BOD 2.0 mg/l 0 10 11 Cl- 250 mg/l 7 3 12 SO4- 400 mg/l 10 0 13 Ca++ 75 mg/l 1 9 14 Mg++ 30 mg/l 1 9 15 Na++ 200 mg/l 10 0 16 F- 1.0-1.5 mg/l 8 2 17 Iron 0.3-1.0 mg/l 10 0 18 Fecal coliform <50/ 100ml 10 0 19 Lead 0.05 mg/l 10 0 20 Cadmium 0.01 mg/l 3 7 21 Chromium 0.05 mg/l 9 1 126 Table-4.13: Conformity of number of water samples from educational institutions with standards in summer season Desirable Below Above S.No. Parameters limit desirable limit desirable limit 1 pH 6.5-8.5 9 1 2 DO >6.0 mg/l 10 0 3 Turbidity 5.0 NTU 10 0 4 TDS 500 mg/l 7 3 5 T.Hardness 300 mg/l 4 6 6 T.Alkalinity 200 mg/l 0 10 7 Nitrate 45 mg/l 10 0 8 Phosphate 25 mg/l 10 0 9 COD 10 mg/l 2 8 10 BOD 2.0 mg/l 0 10 11 Cl- 250 mg/l 10 0 12 SO4- 400 mg/l 10 0 13 Ca++ 75 mg/l 2 8 14 Mg++ 30 mg/l 9 1 15 Na++ 200 mg/l 10 0 16 F- 1.0-1.5 mg/l 8 2 17 Iorn 0.3-1.0 mg/l 10 0 18 Fecal coliform <50/ 100ml 10 0 19 Lead 0.05 mg/l 10 0 20 Cadmium 0.01 mg/l 10 0 21 Chromium 0.05 mg/l 10 0 127 Table-4.14: Conformity of number of water samples from educational institutions with standards in southwest monsoon Desirable Below Above S.No. Parameters limit desirable limit desirable limit 1 pH 6.5-8.5 10 0 2 DO >6.0 mg/l 10 0 3 Turbidity 5.0 NTU 10 0 4 TDS 500 mg/l 1 9 5 T.Hardness 300 mg/l 3 7 6 T.Alkalinity 200 mg/l 1 9 7 Nitrate 45 mg/l 10 0 8 Phosphate 25 mg/l 10 0 9 COD 10 mg/l 1 0 10 BOD 2.0 mg/l 0 10 11 Cl- 250 mg/l 9 1 12 SO4- 400 mg/l 10 0 13 Ca++ 75 mg/l 2 8 14 Mg++ 30 mg/l 1 9 15 Na++ 200 mg/l 10 0 16 F- 1.0-1.5 mg/l 9 1 17 Iorn 0.3-1.0 mg/l 10 0 18 Fecal coliform <50/ 100ml 10 0 19 Lead 0.05 mg/l 10 0 20 Cadmium 0.01 mg/l 2 8 21 Chromium 0.05 mg/l 9 1 128 Table-4.15: Conformity of number of water samples from educational institutions with standards in northeast monsoon Desirable Below Above S.No. Parameters limit desirable limit desirable limit 1 pH 6.5-8.5 10 0 2 DO >6.0 mg/l 10 0 3 Turbidity 5.0 NTU 10 0 4 TDS 500 mg/l 1 9 5 T.Hardness 300 mg/l 0 10 6 T.Alkalinity 200 mg/l 1 9 7 Nitrate 45 mg/l 10 0 8 Phosphate 25 mg/l 10 0 9 COD 10 mg/l 0 10 10 BOD 2.0 mg/l 0 10 11 Cl- 250 mg/l 7 3 12 SO4- 400 mg/l 10 0 13 Ca++ 75 mg/l 7 3 14 Mg++ 30 mg/l 1 9 15 Na++ 200 mg/l 10 0 16 F- 1.0-1.5 mg/l 10 0 17 Iron 0.3-1.0 mg/l 10 0 18 Fecal coliform <50/ 100ml 10 0 19 Lead 0.05 mg/l 10 0 20 Cadmium 0.01 mg/l 10 0 21 Chromium 0.05 mg/l 10 0 129 Table-4.16: Conformity of number of water samples from random sources with standards in winter season Desirable Below Above S.No. Parameters limit desirable limit desirable limit 1 pH 6.5-8.5 17 0 2 DO >6.0 mg/l 17 0 3 Turbidity 5.0 NTU 17 0 4 TDS 500 mg/l 4 13 5 T.Hardness 300 mg/l 1 16 6 T.Alkalinity 200 mg/l 0 17 7 Nitrate 45 mg/l 17 0 8 Phosphate 25 mg/l 17 0 9 COD 10 mg/l 0 17 10 BOD 2.0 mg/l 0 17 11 Cl- 250 mg/l 14 3 12 SO4- 400 mg/l 17 0 13 Ca++ 75 mg/l 3 14 14 Mg++ 30 mg/l 6 11 15 Na++ 200 mg/l 17 0 16 F- 1.0-1.5 mg/l 16 1 17 Iron 0.3-1.0 mg/l 17 0 18 Fecal coliform <50/ 100ml 17 0 19 Lead 0.05 mg/l 17 0 20 Cadmium 0.01 mg/l 3 14 21 Chromium 0.05 mg/l 17 0 130 Table-4.17: Conformity of number of water samples from random sources with standards in summer season Desirable Below Above S.No. Parameters limit desirable limit desirable limit 1 pH 6.5-8.5 13 3 2 DO >6.0 mg/l 17 0 3 Turbidity 5.0 NTU 17 0 4 TDS 500 mg/l 2 15 5 T.Hardness 300 mg/l 6 11 6 T.Alkalinity 200 mg/l 1 16 7 Nitrate 45 mg/l 17 0 8 Phosphate 25 mg/l 17 0 9 COD 10 mg/l 1 16 10 BOD 2.0 mg/l 0 17 11 Cl- 250 mg/l 10 7 12 SO4- 400 mg/l 17 0 13 Ca++ 75 mg/l 3 14 14 Mg++ 30 mg/l 10 7 15 Na++ 200 mg/l 17 0 16 F- 1.0-1.5 mg/l 13 4 17 Iron 0.3-1.0 mg/l 17 0 18 Fecal coliform <50/ 100ml 17 0 19 Lead 0.05 mg/l 17 0 20 Cadmium 0.01 mg/l 17 0 21 Chromium 0.05 mg/l 16 1 131 Table-4.18: Conformity of number of water samples from random sources with standards in southwest monsoon Desirable Below Above S.No. Parameters limit desirable limit desirable limit 1 pH 6.5-8.5 16 1 2 DO >6.0 mg/l 17 0 3 Turbidity 5.0 NTU 17 0 4 TDS 500 mg/l 1 16 5 T.Hardness 300 mg/l 2 15 6 T.Alkalinity 200 mg/l 0 17 7 Nitrate 45 mg/l 17 0 8 Phosphate 25 mg/l 17 0 9 COD 10 mg/l 2 15 10 BOD 2.0 mg/l 1 16 11 Cl- 250 mg/l 9 8 12 SO4- 400 mg/l 17 0 13 Ca++ 75 mg/l 7 10 14 Mg++ 30 mg/l 1 16 15 Na++ 200 mg/l 17 0 16 F- 1.0-1.5 mg/l 9 8 17 Iron 0.3-1.0 mg/l 16 1 18 Fecal coliform <50/ 100ml 17 0 19 Lead 0.05 mg/l 17 0 20 Cadmium 0.01 mg/l 3 14 21 Chromium 0.05 mg/l 16 1 132 Table-4.19: Conformity of number of water samples from random sources with standards in northeast monsoon Desirable Below Above S.No. Parameters limit desirable limit desirable limit 1 pH 6.5-8.5 15 2 2 DO >6.0 mg/l 17 0 3 Turbidity 5.0 NTU 17 0 4 TDS 500 mg/l 2 15 5 T.Hardness 300 mg/l 0 17 6 T.Alkalinity 200 mg/l 0 17 7 Nitrate 45 mg/l 17 0 8 Phosphate 25 mg/l 17 0 9 COD 10 mg/l 4 13 10 BOD 2.0 mg/l 1 16 11 Cl- 250 mg/l 13 4 12 SO4- 400 mg/l 17 0 13 Ca++ 75 mg/l 12 5 14 Mg++ 30 mg/l 0 17 15 Na++ 200 mg/l 17 0 16 F- 1.0-1.5 mg/l 17 0 17 Iron 0.3-1.0 mg/l 17 0 18 Fecal coliform <50/ 100ml 17 0 19 Lead 0.05 mg/l 17 0 20 Cadmium 0.01 mg/l 17 0 21 Chromium 0.05 mg/l 17 0 133 Table-4.20: Conformity of number of water samples from rural area with standards in winter monsoon Desirable Below Above S.No. Parameters limit desirable limit desirable limit 1 pH 6.5-8.5 47 2 2 DO >6.0 mg/l 49 0 3 Turbidity 5.0 NTU 49 0 4 TDS 500 mg/l 12 37 5 T.Hardness 300 mg/l 5 42 6 T.Alkalinity 200 mg/l 1 48 7 Nitrate 45 mg/l 49 0 8 Phosphate 25 mg/l 49 0 9 COD 10 mg/l 4 45 10 BOD 2.0 mg/l 0 0 11 Cl- 250 mg/l 39 10 12 SO4- 400 mg/l 49 0 13 Ca++ 75 mg/l 7 42 14 Mg++ 30 mg/l 11 38 15 Na++ 200 mg/l 47 0 16 F- 1.0-1.5 mg/l 15 34 17 Iron 0.3-1.0 mg/l 48 1 18 Fecal coliform <50/ 100ml 49 0 19 Lead 0.05 mg/l 49 0 20 Cadmium 0.01 mg/l 18 31 21 Chromium 0.05 mg/l 47 2 134 Table-4.21: Conformity of number of water samples from rural area with standards in summer monsoon Desirable Below Above S.No. Parameters limit desirable limit desirable limit 1 pH 6.5-8.5 45 4 2 DO >6.0 mg/l 49 0 3 Turbidity 5.0 NTU 49 0 4 TDS 500 mg/l 20 29 5 T.Hardness 300 mg/l 14 34 6 T.Alkalinity 200 mg/l 5 44 7 Nitrate 45 mg/l 49 0 8 Phosphate 25 mg/l 49 0 9 COD 10 mg/l 1 48 10 BOD 2.0 mg/l 0 49 11 Cl- 250 mg/l 39 10 12 SO4- 400 mg/l 49 0 13 Ca++ 75 mg/l 8 41 14 Mg++ 30 mg/l 33 16 15 Na++ 200 mg/l 49 0 16 F- 1.0-1.5 mg/l 40 7 17 Iron 0.3-1.0 mg/l 47 2 18 Fecal coliform <50/ 100ml 49 0 19 Lead 0.05 mg/l 49 0 20 Cadmium 0.01 mg/l 49 0 21 Chromium 0.05 mg/l 44 5 135 Table-4.22: Conformity of number of water samples from rural area with standards in southwest monsoon Desirable Below Above S.No. Parameters limit desirable limit desirable limit 1 pH 6.5-8.5 48 1 2 DO >6.0 mg/l 49 0 3 Turbidity 5.0 NTU 49 0 4 TDS 500 mg/l 18 31 5 T.Hardness 300 mg/l 21 27 6 T.Alkalinity 200 mg/l 2 47 7 Nitrate 45 mg/l 49 0 8 Phosphate 25 mg/l 49 0 9 COD 10 mg/l 11 38 10 BOD 2.0 mg/l 7 42 11 Cl- 250 mg/l 45 4 12 SO4- 400 mg/l 49 0 13 Ca++ 75 mg/l 18 31 14 Mg++ 30 mg/l 13 36 15 Na++ 200 mg/l 49 0 16 F- 1.0-1.5 mg/l 45 4 17 Iron 0.3-1.0 mg/l 49 0 18 Fecal coliform <50/ 100ml 49 0 19 Lead 0.05 mg/l 49 0 20 Cadmium 0.01 mg/l 10 39 21 Chromium 0.05 mg/l 39 10 136 Table-4.23: Conformity of number of water samples from rural area with standards in northeast monsoon Desirable Below Above S.No. Parameters limit desirable limit desirable limit 1 pH 6.5-8.5 31 18 2 DO >6.0 mg/l 49 0 3 Turbidity 5.0 NTU 49 0 4 TDS 500 mg/l 6 43 5 T.Hardness 300 mg/l 1 48 6 T.Alkalinity 200 mg/l 3 45 7 Nitrate 45 mg/l 49 0 8 Phosphate 25 mg/l 49 0 9 COD 10 mg/l 8 41 10 BOD 2.0 mg/l 3 46 11 Cl- 250 mg/l 37 12 12 SO4- 400 mg/l 49 0 13 Ca++ 75 mg/l 19 30 14 Mg++ 30 mg/l 3 46 15 Na++ 200 mg/l 49 0 16 F- 1.0-1.5 mg/l 49 0 17 Iron 0.3-1.0 mg/l 49 0 18 Fecal coliform <50/ 100ml 49 0 19 Lead 0.05 mg/l 49 0 20 Cadmium 0.01 mg/l 49 0 21 Chromium 0.05 mg/l 49 0 137 Table-4.24: Conformity of number of water samples from surface water bodies with standards in winter season Desirable Below Above S.No. Parameters limit desirable limit desirable limit 1 pH 6.5-8.5 4 0 2 DO >6.0 mg/l 4 0 3 Turbidity 5.0 NTU 4 0 4 TDS 500 mg/l 2 2 5 T.Hardness 300 mg/l 0 4 6 T.Alkalinity 200 mg/l 0 0 7 Nitrate 45 mg/l 4 0 8 Phosphate 25 mg/l 4 0 9 COD 10 mg/l 0 4 10 BOD 2.0 mg/l 0 4 11 Cl- 250 mg/l 4 0 12 SO4- 400 mg/l 4 0 13 Ca++ 75 mg/l 1 3 14 Mg++ 30 mg/l 1 3 15 Na++ 200 mg/l 4 0 16 F- 1.0-1.5 mg/l 4 0 17 Iron 0.3-1.0 mg/l 4 0 18 Fecal coliform <50/ 100ml 4 0 19 Lead 0.05 mg/l 4 0 20 Cadmium 0.01 mg/l 1 0 21 Chromium 0.05 mg/l 3 1 138 Table-4.25: Conformity of number of water samples from surface water bodies with standards in summer season Desirable Below Above S.No. Parameters limit desirable limit desirable limit 1 pH 6.5-8.5 4 0 2 DO >6.0 mg/l 4 0 3 Turbidity 5.0 NTU 4 0 4 TDS 500 mg/l 1 3 5 T.Hardness 300 mg/l 0 4 6 T.Alkalinity 200 mg/l 1 3 7 Nitrate 45 mg/l 4 0 8 Phosphate 25 mg/l 4 0 9 COD 10 mg/l 0 4 10 BOD 2.0 mg/l 0 4 11 Cl- 250 mg/l 3 1 12 SO4- 400 mg/l 4 0 13 Ca++ 75 mg/l 1 3 14 Mg++ 30 mg/l 4 0 15 Na++ 200 mg/l 4 0 16 F- 1.0-1.5 mg/l 3 1 17 Iron 0.3-1.0 mg/l 4 0 18 Fecal coliform <50/ 100ml 4 0 19 Lead 0.05 mg/l 4 0 20 Cadmium 0.01 mg/l 4 0 21 Chromium 0.05 mg/l 2 2 139 Table-4.26: Conformity of number of water samples from surface water bodies with standards in southwest monsoon Desirable Below Above S.No. Parameters limit desirable limit desirable limit 1 pH 6.5-8.5 4 0 2 DO >6.0 mg/l 4 0 3 Turbidity 5.0 NTU 4 0 4 TDS 500 mg/l 2 2 5 T.Hardness 300 mg/l 0 4 6 T.Alkalinity 200 mg/l 0 4 7 Nitrate 45 mg/l 4 0 8 Phosphate 25 mg/l 4 0 9 COD 10 mg/l 1 3 10 BOD 2.0 mg/l 0 4 11 Cl- 250 mg/l 4 0 12 SO4- 400 mg/l 4 0 13 Ca++ 75 mg/l 1 3 14 Mg++ 30 mg/l 2 2 15 Na++ 200 mg/l 4 0 16 F- 1.0-1.5 mg/l 3 1 17 Iron 0.3-1.0 mg/l 4 0 18 Fecal coliform <50/ 100ml 4 0 19 Lead 0.05 mg/l 4 0 20 Cadmium 0.01 mg/l 0 4 21 Chromium 0.05 mg/l 2 2 140 Table-4.27: Conformity of number of water samples from surface water bodies with standards in northeast monsoon S.No. Parameters Desirable limit Below desirable limit Above desirable limit 1 pH 6.5-8.5 2 2 2 DO >6.0 mg/l 4 0 3 Turbidity 5.0 NTU 4 0 4 TDS 500 mg/l 1 3 5 T.Hardness 300 mg/l 0 4 6 T.Alkalinity 200 mg/l 2 2 7 Nitrate 45 mg/l 4 0 8 Phosphate 25 mg/l 4 0 9 COD 10 mg/l 0 4 10 BOD 2.0 mg/l 0 4 11 Cl- 250 mg/l 3 1 12 SO4- 400 mg/l 4 0 13 Ca++ 75 mg/l 2 2 14 Mg++ 30 mg/l 1 3 15 Na++ 200 mg/l 4 0 16 F- 1.0-1.5 mg/l 4 0 17 Iron 0.3-1.0 mg/l 4 0 18 Fecal coliform <50/ 100ml 4 0 19 Lead 0.05 mg/l 4 0 20 Cadmium 0.01 mg/l 4 0 21 Chromium 0.05 mg/l 4 0 141 4.3. Exposition of Drinking Water Quality The above results revealed that many water quality parameters exceeded the standards in many of the samples. A parameter lower than the standard in one season in a sample exceeded the standard in other season(s) in the same sample. Hence, a definite pattern of these differences could not be ascertained. The pH of all water samples were found to be alkaline and mostly within the prescribed range in all the seasons. In general several water samples were found to be hard; and hardness were due to both calcium and magnesium salts. Quite surprisingly, surface water samples were also found to be hard. As the Ariyalur area is a place of limestone deposits, the water under the ground would be naturally hard due to dissolution of calcium and magnesium salts during infiltration. The soil/ sediment of the bottom of the surface water could be rich in calcium and magnesium salts which would have caused hardness in surface water. A total of 680 cases from Ariyalur Taluk with renal calculus were reported (Table-4.28). Both ground and surface water samples in this present study were found to have high values of total hardness. This could be the reason for incidence of cases with renal calculus in Ariyalur Taluk. However, further in-depth study is needed to establish the relationship between the hardness and prevalence of renal calculus in Ariyalur Taluk. Alkalinity, COD and BOD also exceeded in many samples. Table-4.28: Renal calculus report from major hospitals in Ariyalur Taluk (2011) Number of affected people Male Female Child Sl. No. Name of the Hospital 1 S.R. Hospital 169 115 2 2 Golden Hospital 86 68 - 3 A.S.Speciality Hospital 232 147 - 4 GH 15 25 - 5 PHC 6 4 - Total 508 359 2 Fecal coliforms were within the limit in all the samples as per CPCB water quality criteria. However, BIS (1991) specifies „nil‟ in 95% of the samples. Accordingly 32 samples each in winter and summer, 42 in southeast monsoon and 52 142 in northeast monsoon violated this condition. Hence it is concluded that as per BIS standard, almost all water samples were contaminated by human wastes. Excessive COD and BOD values indicate organic pollution of these water samples. In many of the water samples, cadmium and chromium were found exceeding the standard. This could be attributed to natural origin. WQI values of the samples of 6 types are presented in Table-4.29. More than 64% of the total samples fell under “Medium” quality while about 35% of total samples fell under “Bad” quality categories. Individual type samples varied between 59 to 100% under “Medium” quality and 0 to 41% under “Bad” quality categories. It is sad to note that none of the drinking water available in Ariyalur Taluk was of “Good” quality and above. This indicates that the water is contaminated by natural sources and /or anthropogenic sources. Table-4.29: Details of water quality index Type of water samples No. of Samples No. of samples in WQI category Medium Bad Municipality supply 5 3 2 Public places 8 5 3 Educational Institutions 10 7 3 Random 17 12 5 Rural areas 49 29 20 Surface water bodies 4 4 - Incidence of water-borne/ water related diseases in Ariyalur Taluk are presented in figure-4.26 to 4.33. 143 14 12 10 8 Cases Cholera 6 4 2 0 M F C M F GH C M F PHC C M F ASNH SRH C M F C M F Golden H C ABC H Figure-4.26: Incidence of Cholera in Ariyalur Taluk 60 50 Cases 40 30 Typhoid 20 10 0 M F C M F GH PHC C M F ASNH C M F SRH C M F C M F Golden H C ABC H Figure-4.27: Incidence of Typhoid in Ariyalur Taluk 180 160 140 Cases 120 100 80 Dysentery 60 40 20 0 M F C M F C M F C M F C M F C M F C GH PHC ASNH SRH Golden H ABC H Figure-4.28: Incidence of Dysentery in Ariyalur Taluk 144 140 120 100 Cases 80 Diarrhea 60 40 20 0 M F C M F C M F C M F C M F C M F C GH PHC ASNH SRH Golden H ABC H Figure-4.29: Incidence of Diarrhea in Ariyalur Taluk 30 25 Cases 20 15 Jaundice 10 5 0 M F C M F C M F C M F C M F C M F C GH PHC ASNH SRH Golden H ABC H Figure-4.30: Incidence of Jaundice in Ariyalur Taluk 60 50 Cases 40 30 Denghue 20 10 0 M F C M F C M F C M F C M F C M F C GH PHC ASNH SRH Golden H ABC H Figure-4.31: Incidence of Dengue in Ariyalur Taluk 145 Cases 50 45 40 35 30 25 20 15 10 5 0 Chikungunia M F C M F C M F C M F C M F C M F C GH PHC ASNH SRH Golden H ABC H Figure-4.32: Incidence of Chikungunia in Ariyalur Taluk 1400 1200 1000 Cases 800 Other Disease 600 400 200 0 M F C M F C M F C M F C M F C M F C GH PHC ASNH SRH Golden H ABC H Figure-4.33: Incidence of other water-borne diseases in Ariyalur Taluk In this study, according to BIS standard, MPN values indicated the pollution of water samples with human wastes. WQI values also indicated that all water samples were either „medium‟ or „bad‟ category. COD, BOD and TDS values were also found to exceed the standards. High BOD and COD values may encourage the growth and multiplication of pathogens during storage which would have caused the water-borne/ water related diseases. High TDS may also cause gastrointestinal irritation (BIS, 1991). Here too, further in depth study is required to establish the relationship between water quality and water-borne diseases. Annual mean values for certain physico-chemical and microbiological parameters were calculated and presented in figure-4.34a to-4.40h. 146 From the results, it may be concluded that the water from municipal supply which from Thirumanur Combined Drinking Water Supply Scheme (TCDWSS) was found to be better in quality when compared to quality of water from other places. However, it does not warrant that the water from TCDWSS (municipality water) safe for drinking. 8.6 8.4 8.2 8 pH 7.8 7.6 7.4 7.2 1 2 3 Station 4 5 Figure- 4.34a: Annual average pH of Municipality water supply samples 8.8 8.6 8.4 8.2 8 7.8 7.6 7.4 7.2 7 pH 6 7 8 9 Station 10 11 12 13 Figure-4.34b: Annual average pH of public place water samples 8.6 8.4 8.2 8 pH 7.8 7.6 7.4 7.2 14 15 16 17 18 19 20 21 22 23 Station Figure-4.34c: Annual average pH of Educational institutions water samples 147 8.5 8 7.5 pH 7 6.5 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 Station Figure- 4.34d: Annual average pH of Random water samples 8.4 8.2 8 7.8 7.6 7.4 7.2 7 6.8 pH 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 Station Figure- 4.34e: Annual average pH of rural water samples 8.1 8 7.9 7.8 7.7 7.6 7.5 7.4 7.3 pH 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 Station Figure-4.34f: Annual average pH of rural water samples 8.6 8.4 8.2 8 7.8 7.6 7.4 7.2 7 pH 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 89 station Figure-4.34g: Annual average pH of rural water samples 148 8.6 8.4 8.2 8 7.8 pH 7.6 7.4 7.2 7 90 91 Station 92 93 Figure-4.34h: Annual average pH of surface water samples 600 500 400 mg/L 300 TDS 200 100 0 1 2 3 Station 4 5 Figure-4.35a: Annual average TDS of Municipality water supply samples mg/L 800 700 600 500 400 300 200 100 0 TDS 6 7 8 9 10 Station 11 12 13 Figure-4.35b: Annual average TDS of public places water samples mg/L 800 700 600 500 400 300 200 100 0 TDS 14 15 16 17 18 19 Station 20 21 22 23 Figure-4.35c: Annual average TDS of educational institutions water samples 149 1000 800 mg/L 600 TDS 400 200 0 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 Station Figure-4.35d: Annual average TDS of random water samples mg/l 800 700 600 500 400 300 200 100 0 TDS 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 Station Figure-4.35e: Annual average TDS of rural water samples 1000 mg/L 800 600 TDS 400 200 0 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 Station Figure-4.35f: Annual average TDS of rural water samples 1000 800 mg/L 600 TDS 400 200 0 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 89 Station Figure-4.35g: Annual average TDS of rural water samples 150 800 700 600 mg/L 500 TDS 400 300 200 100 0 90 91 Station 92 93 Figure-4.35h: Annual average TDS of surface water samples 600 500 mg/L 400 300 T.H 200 100 0 1 2 Station 3 4 5 Figure-4.36a: Annual average Total hardness of municipal supply water samples 500 400 mg/L 300 T.H 200 100 0 6 7 8 9 10 Station 11 12 13 Figure-4.36b: Annual average Total hardness of public places water samples 600 500 mg/L 400 300 T.H 200 100 0 14 15 16 17 18 19 Station 20 21 22 23 Figure-4.36c: Annual average Total hardness of educational institutions water samples 151 1000 800 mg/L 600 T.H 400 200 0 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 Station Figure-4.36d: Annual average Total hardness of random water samples 700 600 500 mg/L 400 300 T.H 200 100 0 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 Station Figure-4.36e: Annual average Total hardness of rural water samples 600 500 mg/L 400 300 T.H 200 100 0 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 Station Figure-4.36f: Annual average Total hardness of rural water samples 600 500 mg/L 400 300 T.H 200 100 0 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 89 Station Figure-4.36g: Annual average Total hardness of rural water samples 152 500 mg/L 400 300 TH 200 100 0 90 91 Station 92 93 Figure-4.36h: Annual average Total hardness of surface water samples 500 400 mg/L 300 TA 200 100 0 1 2 Station3 4 5 Figure-4.37a: Annual average Total alkalinity of municipal supply water samples 500 400 mg/L 300 TA 200 100 0 6 7 8 9 10 Station 11 12 13 Figure-4.37b: Annual average Total alkalinity of public places water samples 500 mg/L 400 300 TA 200 100 0 14 15 16 17 18 19 Station 20 21 22 23 Figure-4.37c: Annual average T.Alkalinity of educational institutions water samples 153 600 500 400 300 mg/L TA 200 100 0 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 Station Figure-4.37d: Annual average Total alkalinity of random water samples 500 mg/L 400 300 200 TA 100 0 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 Station Figure-4.37e: Annual average Total alkalinity of rural water samples 600 500 mg/L 400 300 TA 200 100 0 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 Station Figure-4.37f: Annual average Total alkalinity of rural water samples 500 400 mg/L 300 TA 200 100 0 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 89 Station Figure-4.37g: Annual average Total alkalinity of rural water samples 154 400 350 300 mg/L 250 200 TA 150 100 50 0 90 91 Station 92 93 Figure-4.37h: Annual average Total alkalinity of surface water samples 5.4 mg/L 5.2 5 DO 4.8 4.6 4.4 1 2 3 Station 4 5 Figure-4.38a: Annual average DO of municipal supply water samples 5.6 5.4 mg/L 5.2 5 DO 4.8 4.6 4.4 4.2 6 7 8 9 10 Station 11 12 13 Figure-4.38b: Annual average DO of public places water samples 5.6 5.4 5.2 mg/L 5 4.8 DO 4.6 4.4 4.2 4 14 15 16 17 18 19 Station 20 21 22 23 Figure-4.38c: Annual average DO of educational institutions water samples 155 6 5 mg/L 4 3 DO 2 1 0 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 Station Figure-4.38d: Annual average DO of random water samples 5.4 5.2 5 mg/L 4.8 DO 4.6 4.4 4.2 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 Station Figure-4.38e: Annual average DO of rural water samples 6 5 mg/L 4 3 DO 2 1 0 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 Station Figure-4.38f: Annual average DO of rural water samples 5.4 5.2 mg/L 5 4.8 DO 4.6 4.4 4.2 4 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 89 Station Figure-4.38g: Annual average DO of rural water samples 156 5.3 5.2 mg/L 5.1 5 DO 4.9 4.8 4.7 4.6 90 91 Station 92 93 Figure-4.38h: Annual average DO of surface water samples 30 25 mg/L 20 15 COD 10 5 0 1 2 3 Station 4 5 Figure-4.39a: Annual average COD of municipal supply water samples 35 30 mg/L 25 20 COD 15 10 5 0 6 7 8 9 10 Station 11 12 13 Figure-4.39b: Annual average COD of public places water samples 35 30 mg/L 25 20 COD 15 10 5 0 14 15 16 17 18 19 Station 20 21 22 23 Figure-4.39c: Annual average COD of educational institutions water samples 157 40 35 30 25 mg/L 20 COD 15 10 5 0 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 Station Figure-4.39d: Annual average COD of random water samples 50 40 mg/L 30 COD 20 10 0 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 Station Figure-4.39e: Annual average COD of rural water samples 50 40 mg/L 30 COD 20 10 0 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 Station mg/L Figure-4.39f: Annual average COD of rural water samples 40 35 30 25 20 15 10 5 0 COD 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 89 Station Figure-4.39g: Annual average COD of rural water samples 158 40 mg/L 30 20 COD 10 0 90 91 Station 92 93 Figure-4.39h: Annual average COD of surface water samples 10 8 mg/L 6 BOD 4 2 0 1 2 Station3 4 5 Figure-4.40a: Annual average BOD of municipal supply water samples 10 8 mg/L 6 BOD 4 2 0 6 7 8 9 10 Station 11 12 13 Figure-4.40b: Annual average BOD of public places water samples 12 10 mg/L 8 6 BOD 4 2 0 14 15 16 17 18 19 Station 20 21 22 23 Figure-4.40c: Annual average BOD of educational institutions water samples 159 mg/L 16 14 12 10 8 6 4 2 0 BOD 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 Station Figure-4.40d: Annual average BOD of random water samples 14 12 10 mg/L 8 BOD 6 4 2 0 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 Station Figure-4.40e: Annual average BOD of rural water samples 12 10 mg/L 8 6 BOD 4 2 0 57 58 59 60 61 62 63 Station 64 65 66 67 68 69 70 71 72 Figure-4.40f: Annual average BOD of rural water samples 12 10 mg/L 8 6 BOD 4 2 0 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 89 Station Figure-4.40g: Annual average BOD of rural water samples 160 10 8 mg/L 6 BOD 4 2 0 90 91 Station 92 93 Figure-4.40h: Annual average BOD of surface water samples 4.3.1. Correlation among the water quality parameters Karl Pearson correlation coefficient for water quality parameters were calculated and presented in table-4.30 to 4.35. A summary of correlation coefficient values are presented in table-4.36. Correlation coefficient values revealed the following: High positive correlation (0.7 to 0.9 and above) existed between COD and BOD. It suggests that COD and BOD were due to organic pollution of same origin. Correlation coefficient between chlorides and TDS ranged from 0.653 to 0.76. TDS also had positive correlation with either sodium or potassium which ranged from 0.535 to 0.606. However, chlorides had positive correlation either with sodium or potassium or both in samples from three categories (Public Places, Rural Places and Surface Water) only. The above facts suggest that chlorides in the form of sodium/potassium chlorides contributed to TDS to a large extent. High positive correlation between total hardness and magnesium existed in water samples from Municipal supply (0.853), and from surface water (0.712). Medium positive correlation (0.55) between total hardness and magnesium existed in water samples from “Random samples” category. Municipality water supply is mainly from „Thirumanur Combined Drinking Water Supply Scheme‟ which is from Kollidam River bed. Though this water is pumped from underground of the river bed, may have influence of surface water flowing in the river. Thus, its quality may be to some extent on par with that of surface water. By considering the above facts, it may be concluded that total hardness of surface water in Ariyalur is mainly from dissolution of magnesium ions. 161 Table-4.30: Correlation co-efficient of municipality water samples in Ariyalur Town 1 pH 2 3 4 5 6 7 8 9 11 12 13 14 15 16 17 1 TDS -.291 1 T.H -.169 .020 1 T.A -.203 -.203 .417 1 COD .107 .128 -.176 .083 1 BOD .109 .203 -.087 .049 .979** 1 -.362 .653** .039 .158 -.078 -.069 1 * * .317 1 Cl 10 CAL -.192 .412 .295 .018 .494 .505 Mg -.168 .036 .853** .354 -.242 -.193 .022 .044 1 NA+ -.184 .174 .009 -.092 -.291 -.308 .274 .221 -.071 1 K+ -.263 .606** -.161 -.411 .152 .158 .312 .495* -.211 .493* 1 Fl .195 -.484* -.310 -.026 -.010 -.101 -.484* -.604** -.008 -.231 -.239 1 Fe .219 -.355 -.006 .381 -.034 -.087 -.085 -.059 -.084 -.245 -.311 .031 1 F.C -.211 .242 .057 .014 .034 .064 -.045 .045 .177 -.072 .344 .086 -.388 1 Pb -.066 -.198 -.110 .413 .292 .174 .139 .216 -.141 -.115 .096 .191 .612** -.057 1 Cd .094 .082 -.106 -.200 .158 .224 -.299 .184 -.316 -.007 -.030 -.331 .045 -.195 -.392 1 Cr -.146 .088 .027 -.309 -.443 -.440 .291 .074 -.094 .114 .049 -.265 .088 -.094 -.108 .025 162 1 Table-4.31: Correlation co-efficient of public water samples Ariyalur Town 1 pH 2 3 4 5 6 7 8 9 10 11 .007 1 T.H .129 .401* 1 T.A .345 -.153 -.044 1 COD -.336 .219 .116 -.439* 1 BOD -.369* .303 .224 -.544** .748** 1 .198 ** .183 .201 -.101 .016 1 -.134 .236 * -.169 -.188 -.151 .174 1 .327 .382* .194 .028 -.192 -.075 .481** .051 1 * ** .114 .156 -.213 -.194 ** .163 ** 1 CAL Mg 13 14 15 16 17 1 TDS Cl 12 .684 NA+ .363 K+ -.163 .578** .000 -.189 .168 .222 .625** .126 .196 .602** 1 Fl .052 .083 .134 .274 -.049 .105 .284 .095 .017 .218 .276 1 Fe -.148 .046 -.009 -.263 .034 .103 -.256 .206 -.029 -.196 -.197 -.103 1 F.C .278 .200 -.230 -.075 .096 -.021 .348 -.064 .256 .075 .166 -.243 .061 1 -.176 .535 ** -.347 -.330 .127 -.001 -.275 .015 .185 * -.191 .045 1 -.559 ** * .289 -.045 .302 -.066 .127 .251 -.201 .151 -.135 -.410* 1 .077 .271 .038 .129 -.156 .041 .067 -.076 -.139 -.002 .204 Pb .106 .535 .439 -.319 Cd -.332 .335 -.083 Cr -.099 .006 .022 -.250 .383 .682 .483 .362 .216 163 1 Table-4.32: Correlation co-efficient of educational institutions water samples in Ariyalur Town 1 pH 2 3 4 5 6 7 8 9 10 11 12 -.003 1 T.H .235 .654** 1 T.A .020 -.034 .256 1 COD -.123 .204 .130 .174 1 BOD Cl -.145 -.008 .244 .760** .155 .627** .209 .313* .942** .409** 1 .401* 1 CAL -.038 -.043 -.123 -.126 .134 .082 -.116 1 .181 .499** .585** -.031 -.091 -.010 .430** -.184 1 -.072 * .287 * .172 .078 -.273 1 ** 1 NA+ K+ 14 15 16 17 1 TDS Mg 13 -.235 -.436 ** -.019 .149 -.252 .348 -.095 .236 .367 .236 .157 .115 -.282 * -.124 -.080 -.063 1 .139 .098 .353* .245 -.191 1 * .263 1 Fl .181 .105 -.016 .153 .073 .071 .104 Fe .049 -.010 -.094 .149 .126 .195 .040 -.319 .595 F.C .034 -.214 -.134 -.084 .074 .111 -.206 .288 .115 -.057 -.047 Pb -.139 -.428** -.240 .273 .234 .104 .020 -.109 -.368* -.019 -.049 .127 -.141 -.010 1 Cd .019 .046 -.250 -.429** -.144 -.189 -.355* .241 -.212 -.111 -.066 -.102 -.050 -.053 -.341* 1 -.143 * * .029 -.015 -.258 -.005 -.196 .016 -.051 .071 .082 .007 -.109 .572** Cr .018 -.330 -.343 -.376 164 1 Table-4.33: Correlation co-efficient of Random water samples in Ariyalur Town 1 pH 2 3 4 5 6 7 8 9 10 11 -.167 1 T.H -.043 .239* 1 T.A .035 -.181 .222 1 -.061 .379 ** .027 -.122 1 .362 ** .141 -.085 ** 1 .004 .730** .377** .070 .276* .342** 1 .007 * * .008 ** ** .163 1 .056 -.123 .209 -.113 1 ** -.028 ** 1 BOD Cl CAL 13 14 15 16 -.046 .277 .246 .955 .392 .409 -.068 .086 .550** NA+ -.072 .294 * ** .075 -.063 -.010 .374 K+ -.051 .539** -.064 -.388** .293* .266* .386** .286* -.032 .347** 1 ** .141 .175 .157 -.096 .011 -.023 .110 1 -.070 .004 -.059 .046 .024 -.129 -.185 -.169 -.172 1 -.225 * -.011 .010 .226 .016 -.120 .038 .172 1 .094 * -.117 .170 -.111 -.053 -.147 1 ** Mg .401 Fl .055 .192 .043 Fe .057 .025 .048 F.C Pb 17 1 TDS COD 12 .115 .019 -.337 .085 .074 * .205 .069 .037 ** ** ** -.151 .026 -.166 -.182 .101 .077 .151 -.232 .394** .111 .088 -.292* -.311** .160 .146 -.044 -.218 Cd -.186 .051 -.074 Cr -.004 .073 -.142 -.491 -.306* .337 .446** -.240 .498 .067 -.251 .046 -.231 .318 .194 -.243 -.373 .168 165 1 .349** 1 Table-4.34: Correlation co-efficient of village water samples in Ariyalur Taluk 1 pH 2 3 4 5 6 7 8 .033 1 T.H .181* .132 1 T.A .193** .180* .465** 1 COD -.241** .053 -.067 .002 1 BOD ** .032 -.060 .053 ** 1 Cl .066 ** ** ** .077 .062 1 CAL .087 NA+ K+ Fl 10 11 12 13 14 15 16 17 1 TDS Mg 9 -.200 .739 .290 .399 .889 .124 .175* .139 .057 .091 .238** 1 * -.027 ** * -.074 -.048 .132 .013 1 -.104 ** .064 ** * .115 ** ** -.040 1 .575** -.083 .018 .243** .169* .457** .142* -.181* .693** 1 -.070 * ** ** .058 -.006 -.029 .037 .072 1 .150 -.152* -.028 .531 .133 .373 Fe -.070 .006 -.004 F.C .063 .000 .022 Pb -.095 .177 .206 -.175 .152 .201 .189 .110 .079 .040 -.045 -.075 .063 .033 .080 1 -.088 -.017 .039 -.003 -.122 .031 -.097 -.098 .001 .077 1 ** ** .109 * ** * ** .036 .125 -.182* 1 ** -.126 -.080 -.117 -.060 .130 -.143 .036 ** 1 -.188* -.064 -.092 -.004 .086 .177* -.040 -.030 -.032 .409** .196 -.087 .105 Cd -.156 * -.087 ** ** -.134 -.084 Cr -.325** -.129 -.408** .103 .028 -.162* .232 ** .007 -.286 .612 -.475 .313 .196 -.309 .152 -.229 .160 .190 -.355 166 1 Table-4.35: Correlation co-efficient of surface water samples in Ariyalur Taluk 1 pH 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 1 TDS -.404 1 T.H -.345 .466 1 T.A -.325 .079 .500* 1 COD -.448 .460 .094 -.207 1 BOD -.353 .524* .311 -.175 .856** 1 Cl -.308 .673** .507* .300 .248 .484 1 CAL -.086 .135 .300 -.019 .089 .051 .231 1 Mg -.242 .200 .712** .259 -.201 -.018 .236 .509* 1 NA+ -.214 * * .379 .086 .259 ** .488 .523* 1 K+ -.101 .493 .360 .306 .135 .126 .558* .540* .390 .863** 1 Fl -.085 .112 .376 .084 .126 .093 -.101 .190 .313 -.090 -.186 1 Fe .016 .463 .334 .215 -.030 .174 .306 -.311 .053 .189 -.041 .319 1 * * .235 -.040 1 .575 .549 .799 F.C .302 -.298 -.013 -.265 -.357 -.132 -.480 -.255 .111 -.511 -.581 Pb -.155 -.131 -.184 .414 .057 -.049 .006 -.152 -.236 -.139 -.165 -.021 .069 -.309 1 Cd -.126 -.336 -.004 .196 -.040 -.079 -.334 .092 -.123 -.166 -.090 -.074 -.127 .129 -.237 1 Cr -.327 .303 -.149 -.042 .315 .233 .177 .133 -.144 .188 .246 -.084 .216 -.351 .000 .101 167 1 Table-4.36: Summary of Correlation coefficient of water quality parameters Correlation coefficient Municipality supply Public places Educat. Institutions Random samples Rural areas Surface water 0.9 and above BOD & COD(0.979) - BOD & COD(0.942) BOD & COD(0.955) - - Chloride & TDS(0.730) BOD & COD(0.889); chloride & TDS(0.739); Potassium & sodium(0.863); BOD & COD(0.856); sodium & chloride(0.799); Magnesium & T.H(0.712) chloride & TDS(0.673); sodium & TDS(0.575); sodium & chloride(0.558); sodium & T.H(0.549); sodium & calcium(0.540); BOD & TDS(0.524); sodium & magnesium(0.523) magnesium & calcium(0.509); chloride & T.H(0.507); T.A & T.H(0.500); 0.7 – 0.9 0.5 – 0.7 Magnesium & T.H(0.853) BOD & COD (0.748) Chloride & TDS(0.760) Chloride & TDS(0.653); Lead &Fecal coliform(0.612) ; potassium & TDS(0.606) Chloride& TDS(0.684); sodium & chloride(0.682); potassium & chloride(0.625); potassium & sodium(0.602); sodium &TDS(0.535); lead &T.Alk.(0.535) T.H & TDS(0.654); chloride & T.H(0.627); sodium & potassium(0.595); magnesium & TDS(0.585); chromium & cadmium(0.572) Magnesium & T.H(0.550); potassium & TDS(0.539) potassium & sodium(0.693); sodium & chloride(0.612); potassium & TDS(0.575); sodium & TDS(0.531) Sodium & magnesium(0.483); Magnesium & chloride(0.481); calcium &T.hardness(0.439);Cal cium & TDS (0.401) Magnesium & TDS(0.499); magnesium & chloride(0.430); chloride & COD(0.409); chloride & BOD(0.401) Sodium & magnesium(0.498); chromium & COD(0.446); calcium & COD(0.409); chromium & BOD(0.394) T.A & T.H(0.465); potassium & chloride(0.457); chromium & cadmium(0.409); chloride & T.A(0.399) Potassium & calcium(0.495); < 0.5 Potassium & sodium(0.493) 168 4.3.2. Alkalinity/Hardness Ratio In some groups, about 40% of the samples and in others about 20% the samples had the ratio above 1.0. Majority of the samples (60-80%) had the ratio below 1. The part of the total hardness that is chemically equivalent to bicarbonate plus carbonate alkalinities present in water is considered to be carbonate hardness. This indicates that when total hardness is greater than alkalinity, the water may contain noncarbonate hardness which is due to calcium and magnesium salts of sulphates, chlorides and nitrate ions (Sawyer et al., 2003). In 60 - 80% of water samples, the total hardness was greater than total alkalinity; hence the ratio was less than 1. Thus it is concluded that 60-80% of samples contained both carbonate and non-carbonate harness while others had only carbonate harness. 2.500 2.000 Winter 1.500 Summer 1.000 SWM NEM 0.500 0.000 1 2 3 4 5 6 Station 7 8 9 10 Figure-4.41: Total Alkalinity/ Harness ratio of drinking water in Ariyalur Taluk 8.000 7.000 6.000 5.000 Winter 4.000 Summer 3.000 SWM 2.000 NEM 1.000 0.000 11 12 13 14 15 16 Station 17 18 19 20 Figure-4.42: Total Alkalinity/ Harness ratio of drinking water in Ariyalur Taluk 169 2.500 2.000 Winter 1.500 Summer 1.000 SWM NEM 0.500 0.000 21 22 23 24 25 26 Station 27 28 29 30 Figure-4.43: Total Alkalinity/ Harness ratio of drinking water in Ariyalur Taluk 6.000 5.000 4.000 Winter 3.000 Summer 2.000 SWM NEM 1.000 0.000 31 32 33 34 35 36 station 37 38 39 40 Figure-4.44: Total Alkalinity/ Harness ratio of drinking water in Ariyalur Taluk 3.000 2.500 2.000 Winter 1.500 Summer SWM 1.000 NEM 0.500 0.000 41 42 43 44 45 46 Station 47 48 49 50 Figure-4.45: Total Alkalinity/ Harness ratio of drinking water in Ariyalur Taluk 170 2.000 1.800 1.600 1.400 1.200 Winter 1.000 Summer 0.800 SWM 0.600 NEM 0.400 0.200 0.000 51 52 53 54 55 56 Station 57 58 59 60 Figure-4.46: Total Alkalinity/ Harness ratio of drinking water in Ariyalur Taluk 10.000 9.000 8.000 7.000 6.000 Winter 5.000 Summer 4.000 SWM 3.000 NEM 2.000 1.000 0.000 61 62 63 64 65 66 Station 67 68 69 70 Figure-4.47: Total Alkalinity/ Harness ratio of drinking water in Ariyalur Taluk 4.000 3.500 3.000 2.500 Winter 2.000 Summer SWM 1.500 NEM 1.000 0.500 0.000 71 72 73 74 75 76 Station 77 78 79 80 Figure-4.48: Total Alkalinity/ Harness ratio of drinking water in Ariyalur Taluk 171 5.000 4.500 4.000 3.500 Winter 3.000 2.500 Summer 2.000 SWM 1.500 NEM 1.000 0.500 0.000 81 82 83 84 85 Station 86 87 88 89 Figure-4.49: Total Alkalinity/ Harness ratio of drinking water in Ariyalur Taluk 3.500 3.000 2.500 Winter 2.000 Summer 1.500 SWM NEM 1.000 0.500 0.000 90 91 Station 92 93 Figure-4.50: Total Alkalinity/ Harness ratio of drinking water in Ariyalur Taluk 4.4. Spatial Distribution of Drinking Water Quality Spatial distributions of various parameters of drinking water during four seasons are depicted in GIS maps (Plate-4.1a to 4.7b). 4.4.1. pH In winter, pH greater than 7.9 and greater than 8.0 found in many pockets, while pH below 7.6 were found in few pockets. Otherwise the pH was in the order of 7.8 to 7.9 in the majority of the area. In summer, in majority of the area, the pH was between 7.8 and 8.1. pH less than 7.5 was found in very few pockets. pH between 7.5 and 7.8 were found in the areas around the areas with pH of 7.5. pH greater than 8.7 was found in very few pockets. These pockets were surrounded by areas with pH between 8.41 and 8.7. 172 In southwest monsoon, pH less than 7.5 was observed in north of Ariyalur Taluk, while pH greater than 8.3 was observed in south of Ariyalur Taluk. The area with pH less than 7.5 was surrounded by areas with pH 7.51, and 7.7 and above 7.71, which covers larger area. Similarly in south, majority of the areas had pH between 7.91 and 8.1. In northeast monsoon, pH < 7.4 was seen only in very few pockets which were surrounded by the area with pH above 7.41 and subsequently by pH above 7.71. pH greater than 8.6 was also observed in very few pockets that to in north of Ariyalur Taluk. These pockets were surrounded by areas with pH between 8.31 and 8.6. The remaining areas had the pH between 8.1 and 8.3 which covers a large area of Ariyalur Taluk. pH in almost all the places, were within the standard. Only during summer, pH greater than 8.7 was found in few pockets. 4.4.2. TDS In winter months, the majority of the pockets had TDS between 600 and 700mg/L. TDS greater than 800 mg/L was found in few pockets. TDS less than 500 mg/L was found in few pockets. During summer season, TDS less than 550 mg/L was found in south west of Ariyalur Taluk. Most of the pockets had TDS between 550 and 700mg/L. Very few pockets had TDS greater than 850mg/L. During southwest monsoon, in most of the pockets, TDS values ranged from 600 - 650mg/L followed by 550 - 600mg/L. TDS greater than 650 mg/L was found only in some places. During northeast monsoon, majority of the packets had TDS between 550 and 650mg/L. In northeast part of Ariyalur Taluk, TDS greater than 650mg/L was found over a large area. Only few pockets had TDS less than 550mg/L. In all the seasons, the TDS in the entire study area was above the standard (500 mg/L). Quite surprisingly, in winter season, the TDS recorded the highest range (600 – 700 mg/L) covering a large area. 4.4.3. Total Alkalinity During winter, alkalinity in majority of the pockets was found between 300 and 400mg/L. Alkalinity greater than 400mg/L was found in several small pockets. Alkalinity less than 100mg/L was found in only one place. 173 In summer, alkalinity in most of the pockets, it was between 300 and400 mg/L. Alkalinity less than 210mg/L was found in few packets; and greater than 450 mg/L in few pockets. During southwest monsoon, the alkalinity between 400 and 600mg/L was observed over a large area. Alkalinity less than 200mg/L was found in southwest region of the study area. Quite surprisingly, alkalinity > 800 mg/L was found in 2 pockets and > 1000 mg/L in 3 pockets. In northeast monsoon, most of the area had alkalinity between 350 and 450mg/L. Alkalinity less than 350mg/L was found in southwest of the study area. Very few pockets had alkalinity greater than 450mg/L. Alkalinity exceeded the standard in the study area in all the seasons except in southwest region of the Taluk during southwest monsoon. 4.4.4. Total Hardness In winter, majority of the area in south and southeast of Ariyalur Taluk had total hardness ranging from 450 - 600 mg/L. In north and northwest regions, the hardness was between 300 and 450 mg/L. One pocket had hardness greater than 700 mg/L and two pockets had hardness ranging from 600 and 750 mg/L. hardness less than 300 mg/L was found in few pockets. In summer season, most of the area was found with hardness between 300 and 450mg/L. Hardness between 450 and 600mg/L was found in two large pockets in north and east of the Taluk and few small pockets in other places. Only two packets were found with less than 150mg/L of hardness. During southwest monsoon, almost, the entire Taluk had hardness between 300 and 450mg/L. Hardness greater than 450mg/L and less than 150mg/L were found in very few packets. In northeast monsoon, almost the entire Taluk had hardness ranging from 450 – 600mg/L. Few small packets had hardness between 600 and 750 mg/L while very few pockets of small size were found to have hardness greater than 750mg/L. In all the seasons, the ground water of Ariyalur Taluk had hardness exceeding the standard (300 mg/L). Of the four seasons, winter and northeast monsoon had higher hardness values (450 – 600 mg/L). 174 4.4.5. Chloride In winter, most of the area was found to have chlorides between 125 and 175mg/L followed by 175 and 225mg/L. Many pockets with small area had chlorides greater than 225mg/L. Few pockets had chlorides less than 75mg/L. During summer, chloride concentration between 150 and 225mg/L was found in most of the pockets. Chloride concentration between 75 and 150mg/L was found in southeast part of the study area while chloride concentration between 225 and 300mg/L was found in north of the study area. Chloride exceeding 375mg/L was found in ground water samples in 2 pockets in the north. During southwest monsoon, in most of the areas, the chloride concentration was either between 50 and 100mg/L or 100 and 150mg/L. Both these ranges were found almost equally spreading in the study area. Quite surprisingly, few pockets had chloride concentration less than 50mg/L. In northeast monsoon, most of the area was found with chloride concentration between 150 and 200mg/L. Chloride concentration ranging from 200 and 250mg/L was found in the north region of study area. Chloride concentration less than 100mg/L were found in few pockets. Chloride was within the standard in the study area in all seasons except in few places in summer. 4.4.6. COD In winter season, COD less than 20mg/L was found in very few pockets. COD between 20 and 30mg/L followed by 30 and 40 mg/L were found in almost in the entire area. COD greater than 50mg/L was found in 4 pockets. In summer months, COD in majority of the places was found between 30 and 40mg/L. COD less than 20 mg/L as well as greater than 60 mg/L were found in few pockets. During southwest monsoon, COD in most of the area was between 20 and 30mg/L. COD between 30 and 40 mg/L was found in few pockets. Some pockets had COD between 10 and 20 mg/L. In northeast monsoon, COD less than 10mg/L was found in few pockets. In majority of the places, it was found between 15 and 25mg/L. Only two packets were found to have COD greater than 40mg/L. COD above 60 mg/L was found in only one pocket in winter and in 5 pockets in summer. 175 4.4.7. BOD During winter, BOD in majority of the area was between 8 and 12mg/L. The BOD values between 4 and 8mg/L were found spreading from east to west of Ariyalur Taluk. BOD < 4mg/L was found in 5 pockets only and >16mg/L was found in few pockets. During southwest monsoon, major part of Taluk had BOD between 4 and 8mg/L. In west and north, the BOD ranged between 8 and 12mg/L. BOD less than 4mg/L was found in few pockets; BOD between 12 and 16mg/L was found in few pockets. In summer, the BOD values between 8 and 12mg/L were found in almost entire Taluk except few pockets. The BOD values from 4 – 8mg/L were found in northeast monsoon and in few pockets at west and at the centre. Greater than 12mg/L of BOD was found in a small area at the west. In northeast monsoon, most of the area was found with BOD between 6 and 9mg/L. BOD ranging from 3 – 6mg/L was observed in north area of Ariyalur Taluk. The BOD value from 9 – 12mg/L was seen in many isolated pockets. BOD >12mg/L was observed in 4 pockets within the pockets of 9 – 12mg/L. 4.5. Multivariate Analyses – Variations in water Quality The following multivariate tools were used to compare the water quality parameters of samples collected from 6 categories of places elaborated already: 1. Cluster analysis 2. MDS (Multi Dimensional Scaling) 3. ANOSIM (Analysis of Similarities). 4.5.1. Cluster analysis Initially all the samples were input into the analysis and the dendrogram was drawn (Figure-4.51). Due to higher number of samples, there was clutter in the dendrogram and the pattern of association of stations from where the samples were collected could not be seen clearly. Therefore the data were averaged category-wise and the dendrogram was drawn using the resultant data. To have clarity in the dendrogram, the categories were given numbers 1-6(1 for Municipality, 2 for public places, 3 for educational institutions, 4 for Random samples, 5 for village samples and 6 for surface water). The dendrogram showed only one group formed by stations (2) Public places and (3) 176 educational institutions at the distance of 0.85. Station (5)village samples joined the above group at the distance of 1.15 followed by station (6)Surface water at 1.57, station (4) Random samples at 2.07 and finally station (1) Municipality at 2.35 (Figure-4.52). Dendrogram was also drawn for the various seasons during which the samples were collected (Figure-4.53). Here also only one group was found in the dendrogram. Seasons (1) winter and (3) Southwest monsoon formed a group at an Euclidean distance of 2.8. To this season (2) Summer joined at the distance of 3.65 followed by station (4) Northeast monsoon at a distance of 3.76. Figure-4.51: Dendrogram representing all the samples collected from the Study areaAriyalur Taluk 177 Figure-4.52: Dendrogram representing the average values of samples collected from the study area-Ariyalur Taluk 1–Municipality; 2–Public places; 3-Educational institutions; 4-Random; 5-Rural and 6-Surface water body Figure-4.53: Dendrogram representing the samples collected during various seasons 1–Winter; 2–Summer; 3-Southeast monsoon; 4-Northeast monsoon 178 4.5.2. MDS As in cluster analysis here also MDS was drawn by inputting all the water samples (Figure-4.54). Due to higher number of samples and overlapping between the water samples collected from all the places, there was cluttering of the samples. As a result no trend could be seen. Therefore the data were averaged station-wise and the MDS was drawn using the resultant data (Figure-4.55).The MDS showed that stations (2) Public places and (3) Educational institutions were closer. All the other stations were lying apart. Station (1) municipality was on the right hand side and stations 24(extreme left) were lying to the left of station 1. From stations 4, the other stations (5 and 6) started moving on the right hand side. The trend more or less reflected that found in the dendrogram. The stress value of MDS for all the samples was on the higher side (0.27). However for the average data stress was found to be nil (O). MDS was drawn season-wise (Figure-4.56) where all the samples fell apart. The stress value here was also nil (0). 4.5.3. ANOSIM Analysis of similarity was carried out to find out whether significant variations were there between the 6 categories from where water samples were collected. The results of ANOSIM are presented in Table 1 and also in histogram (Figure-4.57). The „R‟ values in the histogram ranged from -0.10 to +0.12. The global „R‟ value 0.08 showed significant differences in the quality of the water collected from the 6 stations(P=0.03%). Pair-wise test was also done to compare one station with the other and the results are given in Table 1. Water quality in category 1 (municipal) differed significantly with all the other categories; water quality in category 2 (public places) differed significantly with categories 4-6. However it did not significantly differ from category 3 (educational institutions); category 3 differed significantly with category 4 and 6; category (random) 4 with category 5 (rural area) and 6 (surface water) and category 5 with 6. The above analysis was also done to compare the quality of the water samples between the seasons. The „R‟ values in the histogram ranged from -0.05 to +0.4 (Figure-4.58). The global „R‟ value 0.399 showed significant differences in the quality of the water collected from the (6) surface water stations (P= 0.01%). For different season Pair-wise test was also done to compare one season with the other and the 179 results are given in Table 2. Season 1 (winter) differed significantly with seasons 2-4; season 2 (summer) with season 3 (SWM) and 4 (NEM) and season 3 with season4. Figure-4.54: MDS representing all the samples collected from the study area Figure-4.55: MDS representing the average values of samples collected from the study area 180 Figure-4.56: MDS drawn representing the seasons for the water samples collected from the study area Table-4.38: R values of ANOSIM (pair-wise tests between the seasons) R Significance Possible Actual Number >= Groups Statistic Level % Permutations Permutations Observed 1, 2 0.358 0.01 Very large 9999 0 1, 3 0.317 0.01 Very large 9999 0 1, 4 0.338 0.01 Very large 9999 0 2, 3 0.485 0.01 Very large 9999 0 2, 4 0.404 0.01 Very large 9999 0 3, 4 0.534 0.01 Very large 9999 0 181 Table-4.37: R values of ANOSIM (pair-wise tests between the stations) R Significance Possible Actual Number >= Groups Statistic Level % Permutations Permutations Observed 1, 2 0.162 1.2 Very large 9999 120 1, 3 0.178 0.5 Very large 9999 46 1, 4 0.319 0.01 Very large 9999 0 1, 5 0.16 0.8 Very large 9999 79 1, 6 0.205 0.7 252047376 9999 64 2, 3 0.06 7.2 Very large 9999 721 2, 4 0.156 0.1 Very large 9999 12 2, 5 0.091 4.8 Very large 9999 478 2, 6 0.182 2.2 Very large 9999 215 3, 4 0.136 0.07 Very large 9999 6 3, 5 -0.032 75.8 Very large 9999 7576 3, 6 0.352 0.01 Very large 9999 0 4, 5 0.072 1.3 Very large 9999 132 4, 6 0.349 0.01 Very large 9999 0 5, 6 0.146 2.7 Very large 9999 266 182 Figure-4.57: Histogram showing the results of ANOSIM test (stations) Figure-4.58: Histogram showing the results of ANOSIM test (seasons) 183 5. CONCLUSION The following facts were ascertained and deduced from the present study: 1. Industries were found to be the major consumer of water followed by households (domestic sector) in Ariyalur Taluk. 2. The ground water in villages was used for irrigation and the water was found fit for irrigation as IS: 2296. 3. On average 250 L/day/house of water is consumed in Ariyalur Taluk for various uses; an average of 2.4 L/day/person is used for drinking alone. 4. In major part of Ariyalur Taluk, ground water was one and only source of water for domestic use including for drinking. 5. Majority of the water samples including surface water were found to be hard. Presence of limestone deposits could be attributed for the hardness. This could be the possible reason for renal calculus cases in Ariyalur Taluk. 6. High COD, BOD, TDS and MPN indicated organic pollution as well as fecal contamination. This could be the reason for water-borne diseases. WQI values also supported this fact. All the samples fell under either medium or bad category based on WQI. 7. Of the 6 categories of community water supplies, water supplied through Thirumanur Combined Drinking Water Supply Scheme was found to be better in water quality. However, it did not warrant that this water was safe. 8. From correlation coefficients it was deduced that COD and BOD were from same source of pollution; TDS could be mainly due to chlorides; and magnesium could the main contributor for hardness of water from Thirumanur Combined Drinking Water Supply Scheme (municipal water supply in Ariyalur Town) and surface water in Ariyalur Taluk. 9. From total alkalinity/ total hardness, it was found that 60-80% of samples contained both carbonate and non-carbonate hardness. 10. From GIS maps of spatial distribution of water quality parameters, the places of high pollution could be identified to take remedial measures. 11. Multivariate analysis indicated that water quality differed significantly both among the categories and among the seasons. In nutshell, it may be concluded that at present, water supplied/ available for drinking did not meet the required quality for drinking. Ingestion of water available/ supplied in Ariyalur Taluk may cause water-borne diseases especially in children. 184 Hence, it is recommended that the government agencies should ensure supply of safe drinking water. Until then, the people must either boil or treat the available water before drinking. 185
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