10000 Dry Bacterial gases 1000 C1 /C2 Mixtures of bacterial and thermal gases 100 K103 ROSLU K103 ZE K103A RB Thermal gases K103B ROCLA 10 K103B DC Kerogenous origin K103B ROSLU Humic origin K103A ROSLU Up. Part Wet K103A ROSLU Lo. Part 1 -80 -60 Gas classification diagram d13 C(CH4 ) -40 -20 Exploration Europe Along borehole Geological Interpretation – Xline 7912 -30,1 Additional Rotliegend K15-FB-South gas leg -36,4 -30 K15K103 -31 -30,5 Triassic -35,4 should be @ ZE/ROSL boundary -31,6 -31 Depth (m TVSS) GDT @ 4002 m TVSS -36,6 June 28th 2004 -31 K15K103A -33,1 -34,7 K15-FBS -36,7 -33 K15K103B Zechstein -28,8 ‘Top’ Rotliegend K15-Oscar K15-Oscar -34 Basal Zechstein Rotliegend Carboniferous Exploration Europe 100.00 Mole % 10.00 1.00 0.10 O 2 C 2 N C Component 1/ C2 6+ C nC 5 iC 5 nC 4 iC 4 3 C 2 C C 1 0.01 FB South Prod. FB Prod. FB South Prod. HC only FBSouth Isotubes Upper Part ROSLU FBSouth Isotubes Lower Part ROSLU K15FK103 Isotube Zechstein Molecular Composition K15FK103 Gas FB Prod. HC only Exploration Europe -40.00 -35.00 -30.00 d13C -25.00 -20.00 -15.00 -10.00 -5.00 FB South Isotubes Upper Part ROSLU FB South Isotubes Lower Part ROSLU 2d1 3C 5 2d1 8O CO FB Production CO Component FB South Production nC 5 iC 4 nC 4 iC C3 C2 C1 0.00 K15FK103 Isotube Zechstein Isotopic Composition K15FK103 Gas Exploration Europe Wetness C1/C2 0 5 10 15 20 25 30 35 “Wet” 40 3800 0 “Dry” Wetness C1/C2 5 10 15 20 25 30 35 40 4300 3900 4000 4400 ZE 4100 4200 Depth (m AHRT) 4300 RBSHL ROSLU K15 FB South RBSHM Depth (m AHRT) Excellent match 4500 4600 4400 ZE 4500 4700 ROSLU 4600 4700 ROCLA 4800 ROCLA 40 35 30 25 20 15 10 0 -5 -10 -15 -20 -25 -30 -35 -40 “Heavy” 4800 DC 5 d13C CO2: Production Gas Isotubes d13C CH4: Production Gas Isotubes d13C (ppm) “Light” 4900 C1/C2: Production Gas 5000 40 35 30 25 20 15 10 5 0 Gas Readings Isotubes -5 -10 -15 -20 -25 -30 -35 -40 d13C (ppm) Gas Geochemistry K15-FK-103A Exploration Europe Wetness C1/C2 0 5 10 15 20 25 30 35 “Wet” 40 3800 0 “Dry” Wetness C1/C2 5 10 15 20 25 30 35 40 Log Porosity 0 5 10 15 20 2 4300 3900 4000 4400 ZE 4100 4200 Depth (m AHRT) 4300 RBSHL ROSLU K15 FB South RBSHM Depth (m AHRT) Excellent match 4500 4600 4400 ZE 4500 4700 ROSLU 4600 4700 ROCLA 4800 ROCLA 40 35 30 25 20 15 10 0 -5 -10 -15 -20 -25 -30 -35 -40250 “Heavy” 4800 DC 5 d13C CO2: Production Gas Isotubes d13C CH4: Production Gas Isotubes d13C (ppm) 200 “Light” 150 4900 C1/C2: Production Gas 5000 40 35 30 25 20 15 10 5 0 Gas Readings Isotubes -5 -10 -15 -20 -25 -30 -35 -40 d13C (ppm) Gas Geochemistry K15-FK-103A 10 Gamma Ra Exploration Europe “Wet” Wetness C1/C2 0 5 10 15 20 25 30 35 40 0 “Dry” Wetness C1/C2 5 10 15 20 25 30 35 40 4500 4300 RBSHL Depth (m AHRT) Depth (m AHRT) ZE ROSLU K15 FB South 4400 ZE 4500 4600 ROSLU 4600 0 -5 -10-15-20-25-30-35-40 d13C (ppm) 40 35 30 25 20 15 10 5 0 -5 -10 -15 -20 -25 -30 -35 -40 “Heavy” d13C (ppm) d13C CO2: Production Gas Isotubes d13C CH4: Production Gas Isotubes C1/C2: Production Gas Gas Geochemistry K15-FK-103 Gas Readings “Light” Isotubes Exploration Europe Wetness C1/C2 Wetness C1/C2 0 5 10 15 20 25 30 35 0 40 5 10 15 20 25 30 35 40 5250 4800 Depth (m AHRT) 4900 Depth (m AHRT) 5000 5100 5350 5200 5300 40 35 30 25 20 15 10 5 0 -5 -10 -15 -20 -25 -30 -35 -40 d13C (ppm) 5400 40 35 30 25 20 15 10 5 0 -5 -10 -15 -20 -25 -30 -35 -40 d13C (ppm) d13C CO2: Production Gas Isotubes d13C CH4: Production Gas Isotubes C1/C2: Production Gas Gas Geochemistry K15-FK-103B Gas Readings Isotubes Exploration Europe No Cutoffs FIS Log K15FK103 Exploration Europe No Cutoffs FIS Log K15FK103 Exploration Europe No Cutoffs FIS Log K15FK103A Exploration Europe No Cutoffs FIS Log K15FK103B (Oscar) Exploration Europe
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