Double Pipe - Final Report ChE 201, Thursday B-4 Andrew Rabeneck, Ross Giglio, Michael Hensler, Krishna Gnanavel, Kevin Jonovich, David Forcey 2 Table of Contents Page Number Nomenclature ...................................................................................................................................3 1.0 Introduction and Background ....................................................................................................4 2.0 Experimental Methodology .......................................................................................................7 3.0 Results ......................................................................................................................................10 4.0 Analysis and Discussion ..........................................................................................................18 5.0 Summary and Conclusion ........................................................................................................21 6.0 References……………………………………………………………………………...…….22 Appendix A-1: Experimental Data ................................................................................................23 Appendix A-2: Example Calculations ...........................................................................................25 3 Nomenclature Symbol QEG MEG CpEG ΔTLM U A T1 T9 T2 T11 Qw Mw Cpw ρEG Ρw Term Heat duty of ethylene glycol mixture Mass flow rate of ethylene glycol mixture Heat capacity of ethylene glycol mixture Log mean temperature difference Heat transfer coefficient Heat Transfer Surface Area Ethylene glycol inlet temperature to the heating section Ethylene glycol outlet temperature from first heating section Ethylene glycol outlet temperature from second heating section Ethylene glycol outlet temperature from the last heating section Heat duty of water Mass flow rate of water Heat capacity of water Density of ethylene glycol mixture Density of water Units and Value (if applicable) W (J/s) kg/s 139.48 J/mol*K K W/m2K m2 K or C, as specified K or C, as specified K or C, as specified K or C, as specified W (J/s) kg/s 75.268 J/mol*K 1069 kg/ m3 993.1 kg/ m3 4 1.0 Introduction and Background The transfer of heat between two fluids is an important process in the field of engineering. A heat exchanger allows thermal energy to be transferred efficiently and controllably. Double pipe heat exchangers are closed system heat exchangers consisting of concentric inner and outer pipes. Two fluids of different temperatures travel through the pipes, and heat is transferred from the hot fluid to the cold fluid without mixing or direct contact. Double pipe heat exchangers can be used in a wide variety of industries and applications. This setup is often used when flow rates of reacting fluids are relatively low. Simple metal piping can be used as the framework for the system. In general, the double pipe heat exchanger is favored in industrial applications because of its pure simplicity and cost effectiveness. Its disadvantages lie primarily in its relatively low operation capacity, low thermal efficiencies, and the possible requirement of a large physical space to build the system. Regardless of the minor variations, double pipe heat exchangers remain a simple, effective method of achieving heat transfer between fluids [1]. The system reaches steady state when the rate of change of inlet temperatures, outlet temperatures, and pressure is approximately zero. Figure 1 shows the basic setup of a countercurrent double pipe heat exchanger. Figure 1: Double Pipe Layout (Source: Bengtson) The outer fluid in the double pipe system can flow either concurrently or countercurrently to the inner fluid. In concurrent, or parallel flow, both fluids travel in the same direction, while in countercurrent, or counter flow, the fluids flow in opposite directions. Countercurrent flow is more efficient at transferring energy and has a higher overall heat transfer coefficient [3]. In concurrent flow, the hot fluid temperature decreases as the cold fluid temperature increases, which causes a decrease in temperature difference between the two fluids. 5 The decrease in temperature difference causes less heat to be transferred. In countercurrent flow, the difference in temperature of the fluids across the heat exchanger remains close to constant, which allows for more heat to be transferred, increasing the efficiency of the system. Figure 2 compares the inlet and outlet temperature of both fluids in concurrent and countercurrent flow using temperature-position graphs. Figure 2: Concurrent vs. Countercurrent Flow (Source: Peyman) The technical objectives of this experiment were to calculate the overall heat transfer coefficients in both the heating and cooling sections with varying ethylene glycol flow rates, water flow rates, and steam pressure. The LabVIEW program was used to set the flow rates and steam pressure and record the temperature of the ethylene glycol as it exited both the heating and cooling section. Each time the flow rates of the fluids were manipulated, the system remained untouched until it reached steady state, at which point the exit temperatures of ethylene glycol and the steam or water (respectively) were measured. First, the ethylene glycol flow rate was changed, and the steam pressure and water flow rate remained constant as temperatures were measured. Next, the steam pressure was manipulated while the flow rates were held constant, and the temperatures were once again recorded. Finally, only the water flow rate was manipulated as steam pressure and EG flow rate remained constant to calculate the overall heat 6 transfer coefficient for the cooling section. The heat duty of the ethylene glycol was calculated using the equation QEG=mEG*Cp*ΔT (1) where QEG is the heat duty of the ethylene glycol mixture, mEG is the mass flow rate of the ethylene glycol, Cp is the heat capacity at constant pressure, and ΔT is the change in temperature between the ethylene glycol inlet and outlet. Using the heat duty, the overall heat transfer coefficient was calculated with the equation U = QEG / (A*ΔTLM) (2) where U is the overall heat transfer coefficient, A is the heat transfer surface area, and ΔTLM is the log mean temperature difference. 7 2.0 Experimental Methodology 2.1 Equipment and Apparatus Figure 3: Flowchart of the Double Pipe Figure 3 depicts the layout of the double pipe heat exchanger, a system of eight horizontal pipes. Each pipe in the series has a length of 2.82 meters. The inner pipe has an inner diameter of 0.0260 meters and an outer diameter 0.0286 meters. The inner diameter of the outer pipe in the heating section is 0.0504 meters, and the outer diameter is 0.054 meters. The inner diameter of the outer pipe in the cooling section is 0.0382 meters, and the outer diameter is 0.0413 meters. A solution consisting of 50% ethylene glycol and 50% water enters through the inner pipe of the top pipe on its left side, and flows through the double pipe in a snake-like pattern. After leaving the final pipe, the ethylene glycol is pumped back into the ethylene glycol storage container, which stores 80 liters of the mixture. The top three pipes in the series contains steam in the outer pipe to heat the ethylene glycol. The steam enters from the left side of the pipe and flows to the right. This means in the first and third pipes from the top of the system, the steam is flowing concurrent with the ethylene glycol stream, while the steam is flowing 8 countercurrent to the ethylene glycol in the second pipe. The bottom five outer pipes consist of water, which is used to cool the ethylene glycol solution. The water enters through the bottom pipe on the left side, and moves in a snake-like pattern through the five bottom pipes, so the water is always countercurrent to the ethylene glycol in the cooling section. 2.2 Experimental Procedures Technical Objective 1 To begin, a data file recording was started in the LabVIEW program. Then, the ethylene glycol flow rate was set to 10 liters per minute (LPM); the water flow rate was set to its maximum value of 20 LPM; and the steam pressure was initially set to approximately 2 volts. The pressure in psig corresponding to this voltage was recorded, as LabVIEW only allows for setting the voltage. T1, the ethylene glycol inlet temperature to the heating section, T9, the exiting temperature of the ethylene glycol from the first heating section, T2, the exiting temperature of the ethylene glycol from the second heating section, and T11, the ethylene glycol outlet temperature from the last heating section, were monitored and recorded in LabVIEW. Once each of these temperatures reached steady-state values, represented by a horizontal line on the LabVIEW graph, the ethylene glycol flow rate was increased to 20 LPM, while every other parameter remained constant. T1, T9, T2, and T11 at a flow rate of 20 LPM changed from the values at a flow rate of 10 LPM. As a result, each of these temperatures had to again reach steady-state values on the LabVIEW graph before increasing the ethylene glycol flow rate two more times to 30 LPM and then to 35 LPM. After the four temperatures at an ethylene glycol flow rate of 35 LPM stabilized, the steam pressure was varied at the 35 LPM flow rate for ethylene glycol. The first steam pressure was set at approximately 5 volts. The four heating section temperatures for ethylene glycol changed and were allowed to reach steady-state values. When these values stabilized, the steam pressure was increased to about 8 volts. After the four temperatures stabilized, the data file recording was stopped. Technical Objective 2 For this technical objective, the ethylene glycol flow rate was set to 30 LPM; the water flow rate was initially set to 5 LPM; and the steam pressure was set to approximately 2 volts. As 9 in the first technical objective, the pressure in psig corresponding to this voltage was recorded. The ethylene glycol inlet and outlet temperatures in the cooling section, denoted by T11 and T7 in Figure 3, respectively, as well as T8 and T10 from Figure 3, the water inlet and outlet temperatures in the cooling section, were monitored in LabVIEW. When each of these temperatures reached steady-state, the process was repeated at water flow rates of 10 LPM, 15 LPM, and 20 LPM. After the temperatures stabilized at the final water flow rate of 20 LPM, the data file recording was stopped. 10 3.0 Results The first technical objective was to analyze the heat duty (Q) and heat transfer coefficient (U) of all three heating sections. In order to calculate these, the inlet and outlet temperatures of the ethylene glycol mixture as well as the inlet steam temperature needed to be collected during the experiment; these values were all obtained when the system reached steady state. Table 1 in the Appendix A-1 shows the system at steady state at the various EG flow rates and steam pressures needed to calculate Q and U. The equation for heat duty for ethylene glycol is QEG = mEG*Cp*∆T. (1) The heat capacity of EG was determined at 56.55°C, the average temperature of the mixture throughout the experiment. At this temperature, the heat capacity was 139.5 J/mol*K (this was divided by the molar mass in order to give the units J/kg*K) [4]. The mass flow of the EG mixture and the difference in temperature from the inlet to the outlet were calculated. The mass flow rate of the ethylene glycol mixture was calculated using the volumetric flow rate and the density at the average temperature. The volumetric flow rate varied during the experiment, and the density at 56.55°C was 1069 kg/m3 [5]. Using these values and Equation (1), QEG was calculated, and the values are presented in Table 1. For further illustration, QEG versus EG flow rate is shown graphically in Figure 4 while QEG versus steam pressure is shown in Figure 5. The steam pressure was originally in volts, but the manual readings were recorded in Table 7 of Appendix A-1. Table 1: Heat Duty for Three Heating Sections Steam Pressure (psig) EG Flow Rate (L/min) 1st Section Heat Duty (W) 2nd Section Heat Duty (W) 3rd Section Heat Duty (W) 1.6 10 6,666.62 5,884.26 5,718.09 1.6 20 11,079.02 9,967.90 9,579.75 1.6 30 13,791.72 12,819.90 12,380.08 1.6 35 15,865.49 14,276.55 13,680.97 4.5 35 17,806.56 15,674.21 14,774.32 8.0 35 19,475.93 16,778.42 16,778.42 11 Figure 4: EG Heat Duty in the Heating Sections v. EG Flow Rate (Steam Pressure 1.6 psig) Heat Duty for Three Heating Sections 17,500.00 Heat Duty (W) 15,000.00 12,500.00 10,000.00 7,500.00 5,000.00 2,500.00 0.00 10 20 30 35 EG Flow Rate (L/min) Heating Section 1 Heating Section 2 Heating Section 3 Figure 5: EG Heat Duty in the Heating Sections v. Steam Pressure (EG Flow Rate 35 L/min) Heat Duty for Three Heating Sections 25,000.00 Heat Duty (W) 20,000.00 15,000.00 10,000.00 5,000.00 0.00 1.6 4.5 8 Steam Pressure (psig) Heating Section 1 Heating Section 2 Heating Section 3 12 As noted earlier, the equation for the overall heat transfer coefficient for ethylene glycol is given by U = QEG/(A*ΔTLM). (2) The heat duty for EG values presented in Table 1 were used to calculate U. In addition, the logarithmic mean temperature difference and the surface area of the inner pipe were needed; these values are directly related to heat transfer. The surface area was calculated using the basis that the outer diameter of the inner pipe was 0.0286 m and the length of one section was 2.82 m. The outer diameter of the inner pipe was used because that was where the heat transfer took place as it was in contact with the heating and cooling agents. Thus, the surface area of one pipe section was 0.2533 m2. The log mean temperature difference, a logarithmic average of the temperature differences at each end of the pipe, was calculated separately for each section. The equation for the logarithmic mean temperature difference is ∆TLM = (∆T2-∆T1)/ln(∆T2/∆T1) (3) where ∆T2 = T(steam) - T(EG, in) (4) and ∆T1 = T(steam) – T(EG, out). (5) Using these values, U was calculated, and the data is presented in Table 2. U versus EG flow rate is shown in Figure 6 while U versus steam pressure is shown in Figure 7. 13 Table 2: Heat Transfer Coefficient for Three Heating Sections Steam Pressure (psig) EG Flow Rate (L/min) 1st Section Heat Transfer Coefficient (W/m²K) 2nd Section Heat Transfer Coefficient (W/m²K) 3rd Section Heat Transfer Coefficient (W/m²K) 1.6 10 420.25 442.34 523.28 1.6 20 746.54 785.33 895.84 1.6 30 970.28 1,035.87 1,161.18 1.6 35 1,135.54 1,168.59 1,292.25 4.5 35 1,202.30 1,218.61 1,334.08 8.0 35 1,252.49 1,248.27 1,452.55 Figure 6: EG Heat Transfer Coefficient in the Heating Sections v. EG Flow Rate (Steam Pressure 1.6 psig) Heat Duty for Three Heating Sections 17,500.00 Heat Duty (W) 15,000.00 12,500.00 10,000.00 7,500.00 5,000.00 2,500.00 0.00 10 20 30 EG Flow Rate (L/min) Heating Section 1 Heating Section 2 Heating Section 3 35 14 Figure 7: Heat Transfer Coefficient of EG in the Heating Sections v. Steam Pressure (EG Flow Rate 35 L/min) Heat Duty for Three Heating Sections 25,000.00 Heat Duty (W) 20,000.00 15,000.00 10,000.00 5,000.00 0.00 1.6 4.5 8 Steam Pressure (psig) Heating Section 1 Heating Section 2 Heating Section 3 The second technical objective was to analyze the heat duty (Q) of the EG mixture as well as the cooling water and heat transfer coefficient (U) of the EG mixture in the cooling section. The cooling section treated all five pipe sections as one continuous system and the calculations accounted for this. The inlet temperatures of the EG was the outlet EG temperature from the last heating section. The inlet and outlet temperatures for the ethylene glycol mixture and the cooling water at steady state used for calculations are presented in Table 6 found in Appendix A-1. The mass flow rate of ethylene glycol was calculated the same way as before using the volumetric flow rate and the density at the average temperature. However, the volumetric flow rate of EG was not changed during the second technical objective, so the mass flow rate of EG stayed constant at 0.535 kg/s. The heat duty for EG was found using Equation (1). The volumetric flow rate of the countercurrent water stream was varied. In order to calculate the volumetric flow rate of the cooling water, the density at 37.67°C (the average temperature of water in this experiment) was found. The density was 993.1 kg/m3 at 37.67°C [6]. The heat capacity of water varied at different temperatures, but at the average temperature, the heat capacity of water was 4.178 kJ/kg*K [7]. More specifically, using its molar mass, the heat 15 capacity of water is 75.268 J/mol*K. Therefore, the variables needed to calculate the heat duty for the cooling water were found and used in the equation QW = mW*Cpw*∆T (6) where QW is the water heat duty, mW is the mass flow rate of water, Cpw is the heat capacity of water, and ∆T is the change in temperature between the water inlet and outlet. The heat duties of both the EG mixture and the cooling water are presented in Table 3 below. QEG versus water flow rate is shown in Figure 8. Table 3: Heat Duty of Ethylene Glycol Mixture and Water in the Cooling Section EG Flow Rate (L/min) Water Flow Rate (L/min) EG Heat Duty (W) Water Heat Duty (W) 30 5 -28,748.33 21,593.12 30 10 -31,869.91 38,945.13 30 15 -36,323.98 44,932.89 30 20 -39,557.37 41,468.27 16 Figure 8: Heat Duty of EG in the Cooling Section v. Water Flow Rate (EG Flow Rate 30 L/min) Heat Duty of EG (Absolute Value) in the Cooling Section 45,000.00 Heat Duty (Q) 40,000.00 35,000.00 30,000.00 25,000.00 20,000.00 15,000.00 10,000.00 5 10 15 20 Water Flow Rate (L/min) Cooling Section The equation for the heat transfer coefficient is the same as for the first technical objective. However, there are differences in calculating the values used in Equation (2). The first difference is in the surface area of the pipe. The outer diameter of the inner pipe in the cooling section was again 0.0286 m. The length of each pipe was the same at 2.82 m, but all five were added together because the experiment assumed one continuous cooling section. Using this data, the surface area was calculated to be 1.267 m2. Next, the logarithmic mean temperature difference for the cooling section was calculated. While Equation (3) stays consistent, Equations (4) and (5) change in the cooling section. In this section of the system, ∆T2 and ∆T1 are calculated using different inlet and outlet temperatures, where ∆T2 = T(EG, in) - T(water, out) (7) and ∆T1 = T(EG, out) - T(water, in). (8) Therefore, the logarithmic mean temperature difference varied with the volumetric flow rate of water. With these values, the heat transfer coefficient was calculated, and these values are presented in Table 4. U versus water flow rate is shown in in Figure 9. 17 Table 4: Heat Transfer Coefficient for the Cooling Section EG Flow Rate (L/min) Water Flow Rate (L/min) Heat Transfer Coefficient (W/m K) 2 30 5 -1,008.90 30 10 -1,036.59 30 15 -934.07 30 20 -1,035.43 Figure 9: Heat Transfer Coefficient of EG in the Cooling Section v. Water Flow Rate (EG Flow Rate 30 L/min) Heat Transfer Coefficient (W/m²K) Heat Transfer Coefficient of EG (Absolute Value) in the Cooling Section 2,000.00 1,800.00 1,600.00 1,400.00 1,200.00 1,000.00 800.00 600.00 400.00 200.00 0.00 5 10 15 20 Water Flow Rate (L/min) Cooling Section Sample calculations can be found in Appendix A-2 for any data presented in this section. 18 4.0 Analysis and Discussion The main variables calculated in this experiment were heat duty (Q) and the heat transfer coefficient (U). Calculating these variables utilizes the quantitative data that was collected and transforms them into meaningful trends presented in the tables above. The fundamental goal of both of the experiment was to calculate the heat duty and the heat transfer coefficients for both the heating section and the cooling section of the double pipe system at different flow rates and steam pressures. The first major component of this experiment involved increasing the ethylene glycol flow rate while holding the steam pressure constant and examining the heat duty and heat transfer coefficient in the heating section. It was found that the amount of heat that was transferred increased as the flow rate of the ethylene glycol increased. For example, with a steam pressure constant at 1.6 psig, the heat duty increased from 6667 W at an ethylene glycol flow rate of 10 L/min to 11079 W at 20 L/min, and 15865 W at 35 L/min. This trend is shown in Figure 4 and Figure 6 as well with each heating section heat duty and heat transfer coefficient showing increasing activity. The next major component of this experiment involved investigating the effect of changing the pressure of the steam while keeping the flow rate of the ethylene glycol constant. As the steam pressure was increased, the heat duty also increased. As seen in Table 1, keeping the ethylene glycol flow rate constant at 35 L/min, the heat duty increased from 15865 W at 1.6 psig to 19476 W at 8.0 psig. It is worth noting that the heat duty increased at a decreasing rate in this part of the experiment. This trend is shown in Figure 5 and Figure 7 where trends for both heat duty and heat transfer coefficient show increasing values at increasing steam pressures. These two trends -- the increase of the heat duty as both the steam pressure and the volumetric flow are increased -- can be explained by the fact that as the flow rate of the ethylene glycol or steam is increased, more mass of either steam or ethylene glycol can be in the exchanger, allowing for greater heat transfer to occur. But as the volumetric flow rate of ethylene glycol increases, it also causes a decrease in contact time between the fluids. This ultimately results in decreased temperature changes of the inner ethylene glycol fluid. With an increased mass flow rate, the quantitative heat duty is increased because mass and heat duty are related through the relationship described in Equation (1): QEG = mEG*Cp*∆T (1) 19 Although the temperature changes (∆T) decrease with the increase of ethylene glycol flow, the overall quantitative heat transfer increases due to the increase in mass flow rate. These conclusions are supported by the data in Appendix A1. After the heat duty was calculated, the heat transfer coefficient was also calculated for the heating section. The trend in the heat transfer coefficient followed a similar pattern to that of the heat duty. The heat transfer coefficient increased as both the ethylene glycol flow rate and the steam pressure increased. After the heating section was analyzed, the cooling section was also examined. The central ideas in the cooling section are similar to that of the heating section, except instead of using steam, the cooling section utilizes liquid water to cool the ethylene glycol. The magnitude of the heat duty for ethylene glycol and water increased as the water flow rate increased. The heat duty of ethylene glycol started at -28,748 W for an ethylene glycol flow rate of 30 L/min and a water flow rate of 5 L/min. When the water flow rate was increased to 20 L/min, the heat duty for ethylene glycol increased to -39,557 W. At a constant ethylene glycol flow rate of 30 L/min and a water flow rate of 5 L/min, the heat duty for the water started at 21593 W. The heat duty of water increased to 41,468 W when the water flow rate was changed to 20 L/min. The magnitude of the heat shows increasing trends, as shown in Figure 8. This increase in the amount of heat transferred from the ethylene glycol to the cooling water can be explained by the same ideas utilized in the heating section. As the volumetric flow rate of the water increased, the mass flow rate of the water also increased. This essentially allowed more mass to be in the exchanger over a given time and allowed more heat to be exchanged between the ethylene glycol and the water. Theoretically, the heat duty for the ethylene glycol and the heat duty for the water should be equivalent. These differences can be explained by the fact that not all of the heat is being transferred since perfect efficiency is not possible -- some of the heat was lost to the surrounding environment. In addition to the heat duty for the cooling section, the heat transfer coefficient was also calculated. There was no significant upwards or downwards trend in the data for the heat transfer coefficient. The heat transfer coefficient with the highest magnitude occurred at 10 L/min with a value of -1037 W/(m2K) and the heat transfer coefficient with the lowest magnitude occurred at 15 L/min with a value of -934. W/(m2K). The remaining data fell between these 20 values with no specific trend. These values are found in Table 4, and the stagnant trend is better illustrated in Figure 9 of the Results section. 21 5.0 Summary and Conclusions The purpose behind the double pipe heat exchanger experiment was to study the effects of flow direction and rate of flow on a fluid of interest that is being heated or cooled by external fluids. In this experiment, a mixture of 50% Ethylene Glycol and 50% water was analyzed. Two trials were performed to examine the changes of inlet and outlet temperatures. The first trial focused on the heating section, while the second session focused on the cooling section. After steady state was reached for all fluids, recording and variation of flow rates began. This is the core of the experiment. By varying the flow rates of the liquids and gases involved, the engineer can tweak the system to produce the desired results. The first set of data focused on the heating of ethylene glycol. A larger heat transfer coefficient and heat duty was achieved by either increasing the flow rate of ethylene glycol or increasing the steam pressure surrounding it. However, the temperature of the EG mix would rise only with the increasing of the steam pressure. The temperature of the EG mix decreased with the increasing of EG flow rate, even though a greater heat transfer was shown. This can be explained through a greater mass flow rate of EG being able to absorb more heat from the steam with lesser changes in temperature. The next set of data focused on the cooling of the ethylene glycol mix. The trends found are similar to those found for the heating section. The heat exchange between fluids increased as their mass flow rates increased, but a different trend was discovered with the behavior the heat transfer coefficient. In the cooling section, there was no significant increasing or decreasing in the value of the heat transfer coefficient as flow rates were varied. This trend may have been observed partially because of energy loss to the surroundings, as the cooling sections were not insulated as well as the heating sections. It may also be that this is the correct observed trend for the cooling section due to the mathematical calculations involving the use of log mean temperature differences. 22 6.0 References [1] K. Bartecki, “Transfer function-based analysis of the frequency-domain properties of a double pipe heat exchanger,” vol. 51, issue 2, July, 2013. [Online serial]. [Accessed Mar. 21, 2016]. [2] H. Bengtson, “Double Pipe Heat Exchanger Design,” Bright Hub Engineering, para. 3, February 21, 2010. [Online], Available: http://www.brighthubengineering.com/hvac/64548-double-pipe-heat-exchanger-design/ [Accessed Mar. 21, 2016]. [3] J. Peyman, “Double Pipe Heat Exchanger Design, part 1,” Scope We, para. 3, July 10, 2013. [Online], Available: http://scopewe.com/double-pipe-heat-exchanger-design-part-1/. [Accessed Mar. 21, 2016]. [4] “Ethylene Glycol Heat-Transfer Fluid,” The Engineering Toolbox. (2015). [Online]. Available:http://www.engineeringtoolbox.com/ethylene-glycol-d_146.html [Accessed March 21, 2016] [5] T. Sun & A.S. Teja, “Density, Viscosity, and Thermal Conductivity of Aqueous Ethylene, Diethylene, and Triethylene Glycol Mixtures between 290 K and 450 K,” School of Chemical Engineering, Georgia Institute of Technology. (2003). [Online]. Available: http://pubs.acs.org/doi/pdf/10.1021/je025610o [Accessed March 21, 2016] [6] M. Garcia, “Density and Viscosity of Water 0°C-40°C” ASCE. 2008. [Online], Available: http://ascelibrary.org/doi/pdf/10.1061/9780784408230.ap02 [Accessed March 21, 2016] [7] “Heat Capacity of Liquid Water from 0°C-1000°C,” Vaxa Software. (2016). [Online]. Available: http://www.vaxasoftware.com/doc_eduen/qui/caloresph2o.pdf [Accessed March 21, 2016] 23 Appendix A-1: Experimental Data Table 5: Steady State Data of the Heating Section Steam Pressure (psig) Steam Temperature (°C) EG Flow Rate (L/min) 1st Section Inlet (°C) 1st Section Outlet (°C) 2nd Section Inlet (°C) 2nd Section Outlet (°C) 3rd Section Inlet (°C) 3rd Section Outlet (°C) 1.6 102.903 10 34.746 45.498 45.498 54.988 54.988 64.210 1.6 101.596 20 38.427 47.361 47.361 55.399 55.399 63.124 1.6 100.508 30 40.482 48.129 48.129 55.008 55.008 61.651 1.6 100.190 35 41.301 48.600 48.600 55.168 55.168 61.462 4.5 106.407 35 43.745 51.937 51.937 59.148 59.148 65.945 8.0 111.770 35 45.792 54.752 54.752 62.471 62.471 69.675 Table 6: Steady State Data for the Continuous Cooling Section EG Flow Rate (L/min) Water Flow Rate (L/min) EG Inlet (°C) EG Outlet (°C) Water Inlet (°C) Water Outlet (°C) 30 5 75.526 60.100 6.446 68.895 30 10 72.713 55.612 6.669 62.992 30 15 67.009 47.518 6.543 49.856 30 20 62.258 41.032 6.287 36.273 Table 7, The Original vs. Manually Read Steam Pressures for Experiment Sessions 1 and 2 LabView Steam Pressure (V) Actual Steam Pressure (psig) 2 1.6 5 4.5 8 8.0 2 (Second Experiment) 1.75 24 Note: The data exported from LabView includes temperatures when the system has not reached steady state. The date found in Tables 5 and 6 only show the temperatures of the relevant inlet and outlet streams at steady state, not data on its way to steady state. 25 Appendix A-2: Example Calculations Average temperature EG (for looking up density): (45.79 + 67.303)/2 = 56.5465 C = 329.55 K Average temperature Water (for looking up density): (6.45 + 68.897)/2 = 37.6735 C = 310.67 K Density Water (@ 37.67 C) = 0.9931 g/cm^3 = 993.1 kg/m^3 Density Ethylene Glycol (mixture) (@ 329.55 K = 56.55 C) = 1069 kg/m^3 Heat Capacity (Cp) Water (@ 37.67 C) = 4.178 kJ/kg*K * 1 kg/1000g * 1000J/kJ * 18.02 g/mol = 75.268 J/mol*K Heat Capacity (Cp) Ethylene Glycol (@56.55 C) = 3.48 kJ/kg*K * 1kg/1000g * 1000J/kJ * 40.042 g/mol = 139.48 J/mol*K Molar Weight of 1:1 EG/Water Mixture = 0.5(62.07) + 0.5(18.02) = 40.042 g/mol Technical Objective 1 m = V * density @ 10 L/min m = 10L/min * 1069 kg/m^3 * 1m^3/1000L * 1min/60sec = 0.178 kg/sec EG EG A = 2 * pi * Diameter/2 * Length pi = 3.1415 Diameter = 0.0286 m Length = 2.82 m A = 0.2533 m^2 ∆Tlm = log mean temperature difference = (∆T2-∆T1)/ln(∆T2/∆T1) ∆T2 = T(steam) - T(EG, in) ∆T1 = T(steam) – T(EG, out) @ 10 L/min 1. ∆T = 45.498 - 34.746 = 10.752 K QEG = .178 kg/sec * 1000g/kg * 1/40.042 g/mol * 139.48 J/mol*K * 10.752 K QEG = 6666.62 W 2. ∆T2 = T16 - T1 = 102.903 - 34.746 = 68.157 K ∆T1 = T16 - T9 = 102.903 - 45.498 = 57.405 K ∆Tlm = (68.157 - 57.405)/ln(68.157/57.405) = 62.627 K U = 6666.62 J/s * 1/0.2533 m^2 * 1/62.627K = 420.251 W/m²K Technical Objective 2 m = V * density 5 L/min m = 5 L/min * 993.1 kg/m^3 * 1m^3/1000L * 1min/60sec =0.08276 kg/sec W W A = 2 * pi * Diameter/2 * Length pi = 3.1415 Diameter = 0.0286 m Length = 2.82 m * 5 pipes = 14.1 m 26 A = 1.267 m^2 ∆Tlm = log mean temperature difference = (∆T2-∆T1)/ln(∆T2/∆T1) ∆T2 = T(EG, in) - T(water, out) ∆T1 = T(EG, out) - T(water, in) @ 5 L/min Water 1. ∆T = T10 - T8 = 68.895 - 6.446 = 62.449 K QW = 0.08276 kg/sec * 1000g/kg * 1/18.01528 g/mol * 75.268 J/mol*K * 62.449K QW = 21593.12 W = 21.59312 kW 2. ∆T2 = T11 - T10 = 75.526 - 68.895 = 6.631 ∆T1 = T7 - T8 =60.1 - 6.446 = 53.654 ∆Tlm = (6.631-53.654)/ln(6.631/53.654) = 22.490K U = -28748.33 J/s * 1/1.267 m^2 * 1/22.490K = -1008.896 W/m²K
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