Session A9 Paper 184 Disclaimer—This paper partially fulfills a writing requirement for first year (freshman) engineering students at the University of Pittsburgh Swanson School of Engineering. This paper is a student, not a professional, paper. This paper is based on publicly available information and may not provide complete analyses of all relevant data. If this paper is used for any purpose other than these authors’ partial fulfillment of a writing requirement for first year (freshman) engineering students at the University of Pittsburgh Swanson School of Engineering, the user does so at his or her own risk. SELF-HEALING CONCRETE: USING BACTERIA TO EXTEND THE LIFE OF CONCRETE Ivan Menz, [email protected], Mena 1:00, Duncan Clear, [email protected], Sanchez 5:00 Abstract—Concrete is the backbone of our nation’s infrastructure and is the most widely used construction material in the world. However, this highly versatile material has a major weakness: it is very brittle in tension and will inevitably crack. Rebar is added to increase the tensile strength of concrete, but when these micro-cracks form, water and other harmful substances corrode the reinforcement bars. Concrete infused with a limestone-producing bacterium, from the genus Bacillus, can fix these small fissures, sealing off the concrete and extending its life by decades. The bacteria, which are contained in small clay pellets with calcium lactate, can seal cracks up to 0.8 mm wide with limestone in just three weeks. They are also very hardy and are able to lie dormant for up to 200 years. This additive will greatly improve the sustainability of general concrete by increasing its strength and lifespan significantly, lessening its need for repair, and reducing both its financial and environmental costs. The sustainability discussed in this paper is defined as, reducing both the environmental and life cycle costs of a product by extending its service life, thus, improving the lives of future generations. This paper will research and evaluate the effectiveness and sustainability of Bacillus-based, self-healing concrete using sources primarily from scholarly articles and studies done on this topic by other engineers and scientists in the field. These resources will be used to discuss the future of this product, including its economic practicality and its potential for mass production. Key Words—Bacillus, Bacteria, Encapsulation, Repair, Self-Healing. Concrete, has a massive range of applications from building houses to skyscrapers, sidewalks to superhighways, and swimming pools to hydroelectric dams. Other reasons include that concrete has a high thermal capacity, which makes it especially good for building houses. It can be produced almost anywhere in the world. Also, it is durable and has a high compressive strength. In fact, even when subjected to adverse conditions such as “carbonation or chloride ingress, concrete structures can reach a service life of 50 years or longer if properly maintained” [4]. However, traditional concrete has a major imperfection that significantly decreases its overall lifespan. In tension, concrete is extremely brittle and cracks easily. Thus, steel reinforcement is added to supply the necessary tensile strength for the concrete when cracks begin to form. As seen in the picture, when a reinforced concrete beam is subjected to excessive loading, microcracks begin to form. This particular beam is undergoing a load test, so the cracks formed in a very short amount of time. Usually, the cracks would form over a much longer period of time and initially look more like the ones branching out towards the end of the beam. As shown, most of the cracks tend to form on the underside of the beam, which is the side subjected to the tensile stress. Cracks, A SUSTAINABLE SOLUTION TO THE PROBLEMS WITH CONVENTIONAL CONCRETE Concrete is the most widely used construction material in the world because of its remarkable structural qualities and affordable price [1]. In 2016, 4.2 billion metric tons of cement were produced globally, which translates to roughly between 28 and 42 billion metric tons of concrete, as the average mix of concrete contains 10 to 15 percent cement [2][3]. One reason concrete is such a popular building material is that it University of Pittsburgh Swanson School of Engineering 1 03.31.2017 FIGURE 1 [5] Reinforced concrete beam undergoing a load test In the next picture, the underside of a bridge is shown that has had excessive cracking without repair. These cracks have allowed pieces of concrete to break off and expose the rebar reinforcements. This consequently leads to the corrosion of the rebar. Ivan Menz Duncan Clear is heated to 2,600 degrees Fahrenheit along with other feedstock materials that contain silicates, such as clay [9] [10]. At this temperature, the two compounds break down and then recombine to produce clinker (calcium silicate), and carbon dioxide (CO2). Finally, gypsum is added to the clinker (to prevent flash setting) and ground into a fine dust to make cement [9]. This final product is what provides concrete with its strength and durability. The cement is then mixed together with water and aggregates such as sand and gravel to form a slurry. The water and cement then undergo a hydration reaction that “releases highly alkaline hydroxyl ions which help form calcium silicate hydrates that bind the aggregates together” [8]. This reaction fuses the materials together in a bond that is very strong under compression and continues to grow stronger as the concrete ages. The fact that concrete can be produced so easily on-site and can cure in nearly any set of conditions, makes it an extremely valuable and convenient material that is used on nearly every construction project. FIGURE 2 [6] Formation of cracks in concrete According to H. M. Jonkers, a professor at Delft University of Technology in the Netherlands, the “cracking of concrete structures is triggered by temperature and humidity fluctuations, mainly at an early age, and by external loading, mainly at a later age” [7]. This is because when concrete is curing, the chance of it cracking is increased when it is subjected to external stresses caused by fluctuations in humidity and temperature. Furthermore, when a structure ages, it becomes more brittle due to its low moisture content and is damaged more easily by tensile and flextural forces. Microcracks are necessary so that the tension in the concrete can be passed on to the reinforcement, but damage occurs when they provide a pathway for corrosive substances that can “lead to the premature corrosion of the reinforcements and early failure of the structure” [4]. Cracking also causes several other problems including frost damage and leakage of water. Frost damage occurs when a crack, filled with water, freezes and is forced open further by the expansion of the water as it freezes. Water leakage is the most severe for structures built to retain water, such as dams and some foundations. This results in concrete structures needing continual maintenance, as Prachi Patel writes in an article for Chemical and Engineering News, “Our seemingly resilient infrastructure would crumble without routine, and costly, patching” [8]. However, there is a sustainable solution to this problem: selfhealing concrete. Concrete can be made self-healing by adding an agent that uses bacteria to seal off the cracks as soon as they form, preventing these cracks from growing and weakening the structure. This agent can effectively make general concrete more sustainable by reducing both its environmental and life cycle costs by extending its service life, thus, improving the lives of future generations. OVERVIEW OF SELF-HEALING CONCRETE The idea of self-healing concrete was first researched by Carolyn Dry, an architecture professor at the University of Illinois, Urbana-Champaign, in the early 1990s [8]. Dry tried embedding glass capsules in the concrete that would break when the concrete cracked, releasing methyl methacrylate glues. Two major problems that prevented this technology from being successful were: the glues were too viscous to flow out of the capsules once they were broken and the capsules were not strong enough to survive the concrete mixing process [8]. Nevertheless, despite the failure of Dry’s idea, the concept of a self-healing concrete was born. Since then, numerous scientists have worked on this elusive material that poses two major obstacles. The first is that the amount of healing agent that can be put into the concrete is limited as the concrete needs to be able to maintain its density and strength [8]. The second is that encapsulating the healing agent has proven to be very tricky because the capsules need to be flexible during the mixing process to avoid breaking, but then as the concrete hardens they need to become brittle so that they crack with the concrete and release the healing agent [8]. According to Prachi Patel, many effective healing agents have been produced, including “minerals, polymers, resins, and even bacteria,” but “making the capsule itself has been a stumbling block says Kevin A. Paine, a professor of civil engineering at the University of Bath” [8]. However, within the last decade, tremendous progress has been made using bacteria as the healing agent. Starting in 2006, H. M. Jonkers pioneered a bacteriabased self-healing agent [11]. It took several years to perfect the product because the bacteria used needed to be able to survive the alkaline environment of concrete for decades [11]. Eventually, H. M. Jonkers found a limestone-producing OVERVIEW OF CONCRETE According to the Portland Cement Association, a typical mix of concrete is made up of “10 to 15 percent cement, 60 to 75 percent aggregate and 15 to 20 percent water” [3]. Cement is the most important ingredient in the mixture and is what binds the aggregates together. To produce cement, limestone 2 Ivan Menz Duncan Clear the limestone that eventually repairs the cracks” [13]. The fact that the healing process occurs under the conditions that are the most harmful to concrete is the reason that this technology is so effective. As soon as the crack forms, the bacteria are activated and begin to seal it with limestone while it is still small and easy to repair. This ingenious technology has tremendous potential in the construction industry and provides many economic and environmental benefits. bacterium that is found in extremely alkaline lakes near volcanoes and is “able to lie dormant for up to 200 years” [12]. The bacteria are contained in small clay pellets with calcium lactate, and “when the pellets crack with the concrete, moisture in the air triggers the spores to germinate” [8]. In the space of just three weeks, the bacteria, feeding on the calcium lactate, can seal up cracks up to 0.8 mm wide with limestone [8]. Shown in the pictures below is a crack in a piece of self-healing concrete, before and after the healing process. SCIENCE OF BACILLUS BASED SELFHEALING CONCRETE The Chemistry of the Healing Process When concrete is subjected to fluctuations in temperature and humidity or experiences excessive tensile stresses, it develops microscopic fissures that lead to larger cracks and greater structural damage. It is inside these tiny cracks that the self-healing process takes place. This self-healing process is made possible by microbial-induced carbonate precipitation (MICP) [4]. MICP is the process in which limestone (calcium carbonate, CaCO3) is produced as the result of the metabolic activity of bacteria. This MICP process is relatively complicated and involves multiple metabolic pathways to produce the sealant: limestone. The most commonly used system, according to H. M. Jonkers, is the enzymatic hydrolysis of urea (CO(NH2)2) to form carbonate (CO2− 3 ). This whole process occurs within the bacterium. The following set of chemical equations represents this pathway: FIGURE 3 [8] Before the healing process. Capsules containing the bacteria are the black circles. System of equations: CO(NH2)2 +H2O → NH2COOH + NH3 NH2COOH + H2O → NH3 + H2CO3 − 2NH3 + 2H2O → 2NH+ 4 + 2OH − + H2CO3 + H2O → HCO3 + H3O 2− + HCO− 3 + H2O → CO3 + H3O − + 2H3O + 2OH → 4H2 O Net reaction: + CO(NH2)2 +2H2O → CO2− 3 + 2NH4 FIGURE 5 [14] Equations for the first pathway During the reactions shown above, the cell wall of the bacterium is negatively charged, causing cations to be attracted from the surroundings [14]. In a calcium rich environment, calcium ions (Ca2+) are deposited on the cell’s surface. This leads to a subsequent reaction between the carbonate and the calcium ions, resulting in a precipitation of limestone on the cell’s surface [14]. Unfortunately, after the crack has been filled, the surface of the bacterium is coated with limestone, resulting in the death of the microorganism [6]. The following chemical equation shows this final step of this process: FIGURE 4 [8] After the healing process. Cracks and holes are sealed with limestone. R. Spinks, in an article for the Guardian, comments on the interesting nature of this healing process: “It is only with the arrival of concrete’s nemesis – rainwater or atmospheric moisture seeping into cracks – that the bacteria start to produce 3 Ivan Menz Duncan Clear Ca2+ + CO2− 3 → CaCO3 Jonkers explains what bacteria spores are, and why they are so effective: FIGURE 6 [14] Final equation for the first pathway Spores are dormant bacterial cells with characteristic compact round shape, typically in the size range of 0.8–1 μm. Spores can remain viable up to 200 years. When environmental conditions are favorable (presence of water, nutrients, and oxygen) these spores germinate and grow into vegetative active bacterial cells [4]. However, the first pathway has shown evidence of causing problems as it produces ammonium ( NH+ 4 ) as a byproduct which can have negative effects on the concrete [4]. Fortunately, the pathway used by H. M. Jonkers’ bacteriabased healing agent does not have this negative side effect. This system uses the carbon dioxide that is produced through bacterial respiration, to form carbonate ions. In a reaction identical to the one explained above, the carbonate ions limestone carbonate precipitate. The second pathway is represented by the following equations: The fact that these spores stay viable for so long and are so well suited to the environment of concrete made this bacterium the obvious choice for the agent. The alkali-resistant sporeforming bacteria that H. M. Jonkers eventually chose are in the genus Bacillus. Several of the species from this genus were found to be “able to convert organic calcium salt to calciumbased mineral upon activation of crack ingress water in hydrated cement paste specimens” [4]. With these bacteria in the healing agent, the one thing left was to provide it with the necessary nutrients and calcium salt to undergo the reaction when activated. CO2(g) ↔CO2(aq) CO2(aq) + H2O ↔ H2CO3 H2CO3 + H2O ↔ HCO3− + H3O+ 2− + HCO− 3 + H2O ↔ CO3 + H3O 2− Ca2+ + CO3 → CaCO3 FIGURE 7 [4] Equations for the second pathway Selection of the Nutrients For the MICP process to take place there must be proper sustenance for the bacteria. Choosing the correct food source was difficult because it must not negatively affect the strength of the concrete when mixed. H. M. Jonkers tried many different organic compounds and tested their effect on the strength of the produced concrete. Most of the compounds resulted in a decrease in strength development; calcium lactate, however, resulted in an increase in compressive strength [4]. For this reason, along with the fact that the calcium lactate provides the necessary calcium ions to precipitate with the carbonate ions, it is a great choice for a food source for the bacteria. The chemical process of metabolic conversion by the bacteria of calcium lactate results in the formation of limestone through the following equation: This specific set of reactions must take place in a calcium rich environment with an alkaline pH [4]. The reason an alkaline environment is necessary is because the first four reactions are in equilibrium. This means that once there is a certain amount of product present in the solution, the forward reaction will stop. The only way to continue the forward reaction is by removing some of the product. As a weak acid, carbonic acid (H2CO3) produces hydronium (H3O+) when it disassociates. Thus, in order for the forward reaction to occur, the hydronium must be removed by reacting with hydroxide (OH-) to form water. In an acidic solution, this will not occur because of the high levels of hydronium already present. However, an alkaline solution has high levels of hydroxide that will react with the hydronium, making the forward reaction spontaneous. This will make the whole system of equations spontaneous because each reaction consumes the products of the previous one. The result is a reduction in the pH of the concrete and the production of limestone. Therefore, concrete is an excellent environment for this reaction because of its high pH. Ca(C3H4O3)2 + 6O2 → CaCO3 + 5CO2 + 5H2O FIGURE 8 [4] Equations for the formation of limestone. H. M. Jonkers goes on to state that because concrete is a calcium rich environment, the CO2 resulting from the bacterial respiration can react with the portlandite(Ca(OH) 2) present in the cement, producing even more limestone [4]. This can be seen with the following chemical equation: Selection of the Bacteria The most important factor that allows this reaction to take place is the presence of a bacteria that will activate it. The selection of this bacteria was no easy matter, as they had to be able to survive the extremely alkaline pH (~12.8) of concrete and had to be viable as a healing agent for a long time [6]. The spore-forming alkaline-resistant bacteria H. M. Jonkers eventually used had both of these characteristics [4]. H. M. 5CO2 + 5Ca(OH)2 → 5 CaCO3 + 5H2O FIGURE 9 [4] Equations for the second formation of limestone. 4 Ivan Menz Duncan Clear These two equations show that for each mole of calcium lactate reacted, one mole of limestone can be produced and that for every 5 moles of carbon dioxide reacted with the portlandite in the concrete, another 5 moles of limestone can be produced. Because of the large amount of possible limestone product, the healing process of small cracks is quite effective. times their own weight [6]. This encapsulating method has several beneficial properties as described in an article from Ghent University: When cracks occur, SAP are exposed to the humid environment and swell. This swelling reaction partly seals the crack from intruding potentially harmful substances. After swelling, SAP particles desorb and provide the fluid to the surrounding matrix for internal curing, further hydration and the precipitation of CaCO3. In this way, cracks may close completely [6]. Encapsulating the Bacteria For the healing process to take place, however, the bacteria and calcium lactate must first be safely implanted into the concrete mix and be evenly distributed throughout. To keep the bacteria safe in the rigorous cement mixing process, the capsules in which the bacteria are stored must have certain qualities. First, the capsule must be strong enough to survive the mixing process and then become brittle so that they break when a crack forms. Next, the capsule must have a good bond with the surrounding hydrated cement paste. Lastly, the capsule must be able to release the bacteria and nutrients into the crack when broken. H. M. Jonkers has found that the resolution of these requirements is to immobilize the bacterial spores and calcium lactate in clay particles before adding them to the concrete mixture. According to H.M. Jonkers, these clay particles not only represent an internal reservoir but also constitute both a structural element of concrete as well as a protective matrix for the self-healing agent [4]. These clay particles are a lightweight, expanded clay aggregate, typically less than 2 mm across. They are created by heating clay to over 1000˚C in a rotary kiln. This process causes the clay to expand, and form many small bubbles in it. These small bubbles are the reservoirs that H. M. Jonkers spoke of because they are a great location for the bacteria and calcium lactate to be implanted. Breakage of the capsule while mixing the cement is not a problem because the bacteria and nutrients are enclosed in the tiny bubbles in the clay and will not be damaged or lost if the capsule breaks. The capsules are also very small which ensures an even distribution throughout the mix. When the clay particles get wet during the production of the cement, the bacterium spores do not prematurely germinate and die. This is because the bacterium spores need water as well as oxygen over an extended period of time in order to germinate, which the mixing process does not provide. A few other beneficial characteristics of these expanded clay particles are: they have good thermal insulation, a low conductivity, are moisture impermeable, fire resistant, and have a nearly neutral pH. Because of these factors, these expanded clay particles are a great material to encapsulate the bacteria in for the self-healing concrete. Though this clay encapsulation process is being used by H. M. Jonkers and his team, there have been multiple other propositions as to how the bacteria could be safely stored in the concrete. A second container being proposed is a superabsorbent polymer (SAP), also known as hydrogel. These hydrogels are capable of holding large quantities of fluid, even up to 500 Like the clay particles, the bacterium and nutrients are encapsulated in the SAP and only germinate when they come in contact with water and oxygen. This method adds the unique ability for particles to immediately seal the crack off from the ingress of water and then slowly release the stored water for the use of the bacterium. The article continues to state that these polymers could even be created to only absorb water when there is a change in pH. This could be very useful because the when a crack occurs, there is a drop-in pH from 12.8 to between 9 and 10 [6]. This could potentially be a new way to trigger the healing process because the SAP capsules would only swell when a crack occurs. Unlike the clay particle method which is in production, the SAP method is still being tested and designed so not as much is known about its effectiveness and cost. THE PRODUCT AND ITS APPLICATIONS The technology has come far enough that this healing agent is already being produced for commercial consumption in the Netherlands. Basilisk Self-Healing Concrete, a spinoff company of TU Delft, sells three distinct products that enable concrete to become self-healing and thus, more sustainable. They include a self-healing repair mortar, a spray on selfhealing solution and a self-healing agent for mixing into concrete [15]. The first two products use the same bacterial technology (described in this paper), but the last one is what could really change the construction industry because it is added into the concrete mix, pre-construction. This healing agent uses both the bacterial and the encapsulating processes invented by H. M. Jonkers (described above) and “can be applied in ready mixes, prefabricated applications, or added directly to the truck mixer on site” [15]. The recommended application calls for 5 kilograms of expanded clay healing agent per cubic meter of concrete. This ensures a sufficient density of agent throughout the mixture, allowing for the concrete to crack in more than once in the same location [15]. A sample of the clay pellets embedded with the bacterium and nutrients is shown in the picture below. 5 Ivan Menz Duncan Clear roughly 9.5% of global carbon emissions, according to a recent European Commission report,” second only to coal-powered electricity [8][9]. Furthermore, the fossil fuels used during the production of US cement, account for 2.4% of US energy consumption, according to the US Department of Energy [10]. Each ton of cement produced “requires 4.7 million BTUs of energy, equivalent to about 400 pounds of coal” [17]. Clearly, something must be done to lessen the environmental impact of the production of cement. One major way to make cement more sustainable, and consequently concrete, is to extend the life of concrete, reducing the need for cement and improving its overall impact on the environment. Self-healing concrete would do just that, by preventing the concrete from deteriorating nearly as fast as traditional concrete. Although no conclusive testing has been done to determine exactly how much longer self-healing concrete will last than traditional concrete, evidence from H. M. Jonkers’ experiments show that it will greatly decrease the need for repair and consequently extend its life by decades. Most cracks in concrete start extremely small and can be easily healed by the bacteria. This is sufficient to protect the concrete from nearly all cracking except for where the structure is especially weak and cracks form too fast. When this occurs, there is most likely a design flaw causing the excessive cracking that is beyond the capability of the self-healing agent to fix. Also, the bacteria spores remain viable long enough that if the structure is built right, it could have a lifespan of up to two centuries without the need for extensive repair done on the concrete [8]. When compared to traditional concrete that needs maintenance to be able to last 50 years, this is a substantial increase in the service life of a concrete structure. With an increased lifespan of anywhere up to 150 years depending on the stress the structure undergoes, self-healing concrete would be significantly better for the environment and greatly improve the sustainability general concrete. This would not only reduce CO2 emissions from the production of cement, but it would also greatly reduce the energy and material needed to maintain the structures. It would also significantly reduce the need to demolish buildings because they were deemed structurally unsafe. This, in turn, would decrease the cement and aggregate needed to replace old buildings, which would positively affect the environment. Overall, self-healing concrete is more environmentally friendly and thus more sustainable than traditional concrete. FIGURE 10 [15] The expanded clay self-healing agent Because this agent is most effective in wet environments, the recommended applications include, “tunnel elements, liquid-containing reservoirs, basement walls, subsurface constructions, marine constructions, and bridges and parking decks” [15]. Not only can water easily damage all these structures, but they are all very costly to repair. Construction life cycle costs are the major reasons that lead companies to add this agent to their concrete even though it increases the initial cost of the structure. One reason that makes some of these structures especially expensive to repair is that they are heavily depended on and can’t be taken out of commission for long periods of time. For instance, tunnels, bridges, and reservoirs are depended on daily. Others are expensive to repair because of their inaccessible locations, like basement walls, tunnels, and marine structures. As this agent becomes more affordable, it will become easier to justify including it in the concrete mixes for structures with large estimated life cycle costs. THE SUSTAINABILITY OF SELF-HEALING CONCRETE Environmental While concrete is a great construction material, one of its most significant downfalls is its negative impact on the environment. Two of its biggest environmental problems occur during the production of cement (detailed in a previous section). The problems with this process are that it releases carbon dioxide (CO2, the primary greenhouse gas contributing to global warming) and uses a massive amount of energy [16]. For every ton of cement produced, one ton of CO 2 is released into the atmosphere [9]. The chemical reaction during the process is responsible for 70% of the CO2 and the fossil fuels burned produce the other 30% [9]. This industry alone “creates Economic The deterioration of concrete structures caused by microcracking has many economic consequences, causing traditional concrete to not be very sustainable. According to H. M. Jonkers, “The average annual costs for maintenance and repair accounts for 30%–50% of the money spent in the building industry” [4]. This is because so much of our infrastructure is made of concrete and most of it is getting old and needs repair. This is a major problem in the United States, made evident in the last infrastructure report card issued by the 6 Ivan Menz Duncan Clear American Society of Civil Engineers this year, in which our country earned a D+ [18]. Two of the areas that received the worst scores were our nation’s roads and bridges, both of which are made predominantly out of concrete [18]. The report says that over 56,000 American bridges are structurally deficient with that number only increasing as the bridges get older, as depicted in the graph below [18]. service life of a tunnel, then the higher price would definitely be justified. For structures that are very costly to repair, like dams, even just a reduction in the number of repairs needed over its life cycle, would make self-healing concrete a more economically sustainable material than general concrete. Once H. M. Jonkers and his team are able to develop a less expensive nutrient for the bacteria, the material would become sustainable for a much wider segment of the infrastructure. When strictly looking at the costs of self-healing concrete over its life time it is hard to justify it as a sustainable alternative to general concrete across the industry. However, there are certain structures that are more prone to deterioration or are costlier to fix for which self-healing concrete is an economically sustainable alternative. OVERALL SUSTAINABILITY AND FUTURE OF THE TECHNOLOGY When looking at the overall sustainability of self-healing concrete compared to general concrete, the only thing against it is its initial price. Bacillus-based self-healing concrete has definite potential for future mass production and use in the construction industry. The process uses bacteria to seal up cracks in concrete structures with limestone as soon as they form. The bacteria are very compatible with the alkaline environment of concrete because they create spores that can survive for centuries. The major benefit of this is that it prevents the ingress of harmful substances into the concrete, increasing its sustainability by extending the life of the structure by decades. Environmentally, bacillus-based self-healing concrete has many superior qualities compared to traditional concrete, including lower overall carbon emissions and lower energy consumption. These two assets make this concrete increasingly attractive as environmental issues become more of a concern in the construction industry. Also, when buildings last longer because of the self-healing concrete, the demand for aggregate should be less than what it would have been because fewer buildings will need to be demolished for structural reasons. This would also be beneficial to the environment because it would reduce the mining of aggregate. From an environmental point of view, the sustainability of concrete is greatly increased by adding a self-healing agent. Economically, bacillus-based self-healing concrete does not have as strong a case because it is still roughly twice as expensive to produce as traditional concrete. However, it is reasonable to assume that the price of this self-healing agent will drop in the future as more technological breakthroughs occur in the field. One big step to reducing its cost would be to invent a cheaper food source for the bacteria, which H. M. Jonkers and his team seem close to achieving. Still, in many cases, the high initial cost is justified considering the structure’s estimated life cycle. Thus, for certain projects, selfhealing concrete can prove to be economically sustainable. FIGURE 11 [18] Age of bridges in the US Roads are in similar disrepair and the estimated backlog of highway and bridge capital needs is $836 billion. It is clear from these reports that traditional concrete is a very costly material to maintain for the service life of any structure, but does self-healing concrete provide a more sustainable and cheaper alternative even with its initially higher price tag? The main hurdle that the producers of self-healing concrete have yet to overcome is the materials price. For H. M. Jonker’s method, which is the closest to production, The production cost is still twice the cost of regular concrete manufacture (€80/m3). A large part of the cost is the expensive calcium lactate nutrient for the bacteria, but Jonkers and his team are well underway to creating a sugar-based nutrient, which would reduce the cost to a level far closer to that for regular concrete (e.g. between €85/m3 and €100/m3), making it a viable additive and sustainable prevention method [12]. The fact that the current price of the self-healing agent doubles the cost of traditional concrete definitely weakens its financial sustainability. Without the advanced testing that would tell us exactly how much money self-healing concrete would save over its lifespan, it would be more difficult to justify its initial cost for its future savings. However, the higher price might be justified if building something that has a high life cycle cost. For instance, if the self-healing concrete would double the 7 Ivan Menz Duncan Clear When considering both factors, self-healing concrete is sustainable when used for structures that are prone to crack and for companies that place a high value on green products. Concerning the future of the technology itself, it seems likely that it will continue to get more advanced and effective. This technology began in the early 1990s with simple glass capsules containing glue. Today, this technology has advanced to an entirely new level. Currently, the glass capsule has been replaced with expanded clay particles or innovative polymer and hydrogel technology, and the healing agent has been upgraded to limestone producing bacterium. Adding a bacillus-based self-healing agent to general concrete is a sustainable method of preventing the cracks that form in concrete from damaging the whole structure. By extending the service life of structures, reducing the money spent on maintaining them, and lessening their negative environmental impact, this product will improve the lives of future generations. _Netherlands/links/54ee2e4b0cf2e55866f231e2.pdf#page=67 4. [8] P. Patel. “Helping Concrete Heal Itself.” Chemical and Engineering News. 2.8.2016 Accessed 1.11.2017. http://cen.acs.org/articles/94/i6/Helping-Concrete-HealItself.html. [9] “Is Concrete Bad for the Environment?” TheGreenAge. 6.18.2014. Accessed 1.28.2017 http://www.thegreenage.co.uk/article/concrete-is-bad-for-theenvironment/ [10] C. 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Accessed 2.25.2017. http://sphinxsai.com/2016/ch_vol9_no2/1/(182188)V9N2CT.pdf [15] “Basilisk Self-Healing Concrete”. Basilisk website. Accessed 3.3.2017. http://www.basiliskconcrete.com/?lang=en [16] “Emissions from the Cement Industry.” State of the Planet. 5.09.2012. Accessed 10.28.2016 http://blogs.ei.columbia.edu/2012/05/09/emissions-from-thecement-industry/ [17] “Can Concrete be Eco Friendly?” Green Living Ideas. 2008. Accessed 10.29.2016 http://greenlivingideas.com/2008/12/21/can-concrete-be-ecofriendly/ [18] “Infrastructure Report Card.” American Society of Civil Engineers. 2017. Accessed 3.26.2017. http://www.infrastructurereportcard.org/ SOURCES [1] P. Abigail. “Does the Future of Sustainable Construction Lie in Self-Healing Concrete?” Global Construction. 6.29.2015 Accessed 2.22.2017. http://www.constructionglobal.com/majorprojects/476/Doesthe-future-of-sustainable-construction-lie-in-self-healingconcrete. [2] “United States and World Cement Production in 2010 and 2016.” Statista. Accessed 2.8.2017. https://www.statista.com/statistics/219343/cement-production -worldwide/. [3] “How Concrete is Made.” Portland Cement Association. Accessed 2.8.2017. http://www.cement.org/cement-concretebasics/how-concrete-is-made. [4] H. M. Jonkers, V Wiktor. “Bacteria-Based Concrete: From Concept to Market.” IOP Science. 7.16 2016. Accessed 1.26.2017. http://iopscience.iop.org.pitt.idm.oclc.org/article/10.1088/096 4-1726/25/8/084006/pdf. [5] “Beams in Flexure: Cracking Patterns in Beams.” Cement, Concrete, and Aggregates Australia. Accessed 3.25.2017. http://59.167.233.142/rcaus/module4_beams_in_flexure_03.p hp [6] E. Gruyaert. D Snoek. K. V. Tittelboom. J. Wang. “Selfhealing of concrete.” Ghent University. Accessed 3.2.2017. http://www.ugent.be/ea/structuralengineering/en/research/magnel/research/research3/selfhealin g [7] H. M. Jonkers, E. Schlangen, E. Tziviloglou. “BacteriaBased Self-Healing Concrete to Increase Liquid Tightness of Cracks.” Aging of Materials and Structures Conference. 5.28.2014. Accessed 1.11.2017. https://www.researchgate.net/profile/Eduardus_Koenders/pu blication/272789747_Full_Proceedings_Ageing_of_Material s_Structures_1st_International_Conference_2014_Delft_The ADDITIONAL SOURCES P. Lopez, K. Reynolds, S. Sedgwick, J. Wilkening. “Industrial Scale Production of Self-Healing Concrete.” The University of Arizona. 5.2016. Accessed 1.10.2017. http://arizona.openrepository.com/arizona/handle/10150/6132 56. p.6 8 Ivan Menz Duncan Clear ACKNOWLEDGMENTS Thank you to our co-chair, Emily Adelsohn, for encouraging us to get working on this paper, even though we didn’t want to start. Getting started was the hardest part and once we did, things started to fly. Many thanks to Michael Cornelius, our writing instructor, for the helpful revising tips on our draft. Thanks also to our two chairs, Louis Gualtieri and Nicholle Piper, for their expert advice on our outline and first draft and how best to write this paper professionally. 9
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