Journal of Earth Science, Vol. 25, No. 2, p. 397–406, April 2014 Printed in China DOI: 10.1007/s12583-014-0423-9 ISSN 1674-487X The Reconnaissance of Mineral Resources through ASTER Data-Based Image Processing, Interpreting and Ground Inspection in the Jiafushaersu Area, West Junggar, China Lei Liu1, 2, Jun Zhou1, 2, Fang Yin1, Min Feng*3, Bing Zhang4 1. Key Laboratory of Western Mineral Resources and Geological Engineering of Ministry of Education, School of Earth Sciences and Resources, Chang’an University, Xi’an 710054, China 2. Lanzhou AuriferouStone Mining Services Co. Ltd., Lanzhou 730030, China 3. Global Land Cover Facility, Department of Geographical Sciences, University of Maryland, College Park 20740, USA 4. Geological Brigade 7 of Xinjiang Bureau of Geology and Mineral Resources, Wusu 833000, China ABSTRACT: Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) data covering the Jiafushaersu area in Xinjiang were used for mapping lithology and hydrothermal alteration. The study area situates at a potential mineralization zone in relation to small hypabyssal granodiorite or quartz monzonite intrusions along the margin of granitoid batholiths of Darbut foot wall. The false colour composition of bands 521 and the first three principal component analyses (PCA1, PCA2, PCA3) in RGB identify the lithological units and discriminate the small intrusions very well from the adjacent granitoid batholiths. PCA and spectral angle mapper (SAM) algorithm were employed to discriminate alteration minerals. The results indicate that the hydroxyl-bearing or ferric and less commonly carbonate types show good correlation with the quartz monzonite porphyry and aplite. Field verification led to finding of the Jiafushaersu molybdenum mineralization. The lithological and geochemical features imply that the molybdenum mineralization is close to the porphyry type. This study further verified that the foot wall of the Darbut suture could have served as a more important metallogenic district for the porphyry copper and molybdenum deposits. It is concluded that the ASTER data-based methods can be used as a powerful tool for small intrusion-type mineral resources targeting. KEY WORDS: ASTER, Darbut, false colour combination, principal component analysis, SAM. 1 INTRODUCTION The Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER), launched on board NASA’s TERRA spacecraft in December 1999, have provided a finer spectral resolution. ASTER consists of three separate subsystems with a total of 14 spectral bands across the visible—near infrared (VNIR), short wave infrared (SWIR) and thermal infrared (TIR) with three, six and five bands in each part of the spectrum respectively (Tangestani et al., 2008; Rowan et al., 2006, 2005; Rowan and Mars, 2003). With the spectral resolution of ASTER, identification of specific alteration assemblages becomes feasible (Abrams, 2000). Therefore, ASTER multispectral data have been extensively used in mineralogical and lithological studies (Amer et al., 2012, 2010; Pour and Hashim, 2011; Tangestani et al., 2011; Mars and Rowan, 2010, 2006; Di Tommaso and Rubinstein, 2007; Zhang et al., 2007; Rowan et al., 2005; Crosta et al., *Corresponding author: [email protected] © China University of Geosciences and Springer-Verlag Berlin Heidelberg 2014 Manuscript received July 29, 2013. Manuscript accepted Feburary 12, 2014. 2003; Rowan and Mars, 2003), largely enhancing the alteration mineral mapping effect or compensating for the limited spectral resolution of Landsat TM and ETM+ data in the shortwave infrared region. West Junggar is bounded on the southeast by the Darbut suture from the Junggar block or basin (Fig. 1). This northwestern most orogenic belt of China is of a big potential in mineral resources, identified by many ore deposits (mostly gold) like Hatu (Yu, 1998) and Saertuohai (Gan et al., 1996) in the hanging wall (northwestern side) of Darbut. However, Baogutu (Cheng and Zhang, 2006) and Tuketuke (Zhang et al., 2009) copper deposits (gold and molybdenum act as by-products in Baogutu and the pertinent mineralization also exists in Tuketuke), porphyry type, were owed to the recent success of mineral exploration in the foot wall (southeastern side), which has strongly challenged the well-known subduction-related or orogenic mineralization model (Groves et al., 1998; Chen, 1996) that limited the prospecting zone for hydrothermal gold and porphyry copper-gold deposits to the hanging wall of a subduction zone. Importantly, the onset of the mineral exploration in Tuketuke was related to the alteration mineral mapping of ETM+ data and pertinent ground inspection (Zhang et al., 2009), which led to the discovery of tens of mineralization points. The Jiafushaersu molybdenum Liu, L., Zhou, J., Yin, F., et al., 2014. The Reconnaissance of Mineral Resources through ASTER Data-Based Image Processing, Interpreting and Ground Inspection in the Jiafushaersu Area, West Junggar, China. Journal of Earth Science, 25(2): 397–406, doi:10.1007/s12583-014-0423-9 398 Lei Liu, Jun Zhou, Fang Yin, Min Feng and Bing Zhang mineralized points are 35 km (straight) east of Tuketuke (Fig. 1), lying at the margin of similar granitoid batholiths, and its finding was also attributed to the reconnaissance of Tuketuke surroundings by ASTER data-based remote sensing studies and the following ground inspection (Zhang et al., 2009). Conspicuously, the achievements of this study may contribute to the better understanding of orogeny-related mineralization, outline a potential mineralization zone (ca. 40 km span from Tuketuke to Jiafushaersu) in relation to small hypabyssal granodiorite or quartz monzonite intrusions along the margin of granitoid batholiths, reveal the alteration and mineralization characteristics of the relevant intrusions and show the synthetic studies or ore prospecting under the guidance of ASTER data-based image processing and interpreting in Jiafushaersu, a sparsely vegetated arid region. 2 GEOLOGIC AND TECTONIC SETTINGS 2.1 Tectonic Framework The Darbut suture separates the Kazakhstan plate from the Junggar Basin (Coleman, 1989), which was interpreted as a trapped oceanic basin of Late Paleozoic age (Carroll et al., 1990). The suture, SW-NE-orientated and dipping toward NW (Gan et al., 1996), is marked by an ophiolite zone (mostly dismembered serpentinized harzburgite and dunite tectonites) continually extending about 100 km (Feng et al., 1989), suggesting a B-type subduction (the oceanic crust northwestwards underplating the continent) along the Kazakhstan margin. The major evolution age was confined to the Early–Middle Devonian by the radiolaria from the relevant cherts (Xiao et al., 1992) and the gabbros radiometric dating (395±12 Ma, Sm-Nd isochrone; Zhang and Huang, 1992). Both of the hanging wall and foot wall of Darbut are dominated by the shallow-marine tuffaceous siltstone, tuff and intermediate-basic lava (toward the upper) of Carboniferous age, manifesting a gradual closure of the basin at that time. But the orogeny is mainly identified by the large-scale imbricate thrusting of Upper Carboniferous rocks (the Tailegula Formation) in the hanging wall (Feng et al., 1989) and the extensive granite intrusion of Late Carboniferous age (Fig. 1). The continental molasses of Early Permian age clearly marks the final closure of the suture (Carroll et al., 1990). 2.2 Regional Mineralization in the Suture Hanging Wall The known mineral deposits in the region are basically clustered in the hanging wall of the suture (Fig. 1). Accordingly, Chen (1996) proposed a metallogenic model with zonation, i.e., the zone in the proximity of the suture was defined as a favorable mineralization site for the hydrothermal type ore deposits, next to it for the granite-related tungsten-tin deposits along the batholith-dominated area, and further away from the suture for the porphyry type ore deposits. This model is analogous to the veining proposal of Groves et al. (1998) for certain gold deposits, in which the so-called orogenic type was presumed to have formed in the vicinity of the subduction zone (accreted terranes adjacent to continental magmatic arcs), whereas epithermal veins and gold-rich porphyry and skarn deposits in the distal island or continental arcs toward the continent. Figure 1. (a) Generalized geological map of the western Junggar, NW China, showing the distribution of the intrusions, ophiolite belts and main faults; (b) geological map of the study area (modified after Cheng and Zhang, 2006; Xiao et al., 1992; GBXBGMR, 1966). Mineralization types: Hatu, magmatic hydrothermal Au quartz vein; Qiqiu, Au quartz vein or altered rock related to volcanic edifice; Saertuohai, ultrabasic rock-related Au; Baogutu, Tuketuke and Baobei, porphyry Cu-Au; Kuogeshaye, Au quartz vein related to intermediate-basic dikes. 2.3 Recent Achievements in the Suture Foot Wall In essence, some granitoid batholiths and stocks also emplaced in the Carboniferous shallow-marine sediments of Darbut foot wall (Fig. 1). The discovery of the Baogutu copper-gold deposit has casted doubts on the above modeling. It was developed along the contact zone, with 300–400 m thick drill-penetrated ores (Cu 0.1%–0.5%; Au 0.1–0.2 g/t as by-product), between tuffaceous siltstones and a small granodiorite porphyry body (0.84 km2) (Cheng and Zhang, 2006). This success is followed by the Tuketuke copper deposit (Zhang et al., 2009), which, though under drilling and tunneling, The Reconnaissance of Mineral Resources through ASTER Data-Based Image Processing similarly correlate with the small granodiorite porphyry intrusions (mostly several thousand square meters) at granitoid batholith margins. It was the small intrusions with distinct lithology and their apparent wall-rock alteration in Tuketuke that made us reconnoiter the surrounding area through ASTER data-based imagery features and relevant ground inspection, resulting in the finding of the Jafushaersu molybdenum mineralization, although the alteration in Tuketuke does not match the ideal zoning of a porphyry copper deposit (e.g., Hall et al., 1974) and is typified by extensive propylitization, relatively stronger chloritization toward the ores, intensely chloritized and silicified ores, overall ferric stains and slight sericitization, and notable potash-feldspar enrichment in the depth. 1 2 3 399 ASTER Bands 4 56 7 8 9 Reflectance (offset for clarity) Kaolinite Muscovite Calcite Chlorite Limonite 0.5 3 METHODOLOGY 3.1 Preprocessing of ASTER Data A cloud-free L1B-ASTER scene of the Jiafushaersu area, acquired on 31 May 2001 was reprojected to UTM 45N, Krasovsky. The 15 m VNIR data were re-sampled to 30m to fit with SWIR data which could preserve the spectral characteristics of the SWIR data (Galvão et al., 2005). ASTER SWIR crosstalk effects were corrected using the crosstalk software provided by ERSDAC (ERSDAC, 2003). The internal average relative reflectance (IARR) method (Ben-Dor and Kruse, 1994) was applied in this study to convert radiance data to reflectance images. 1 2 (a) 2.5 2.0 1.5 Wavelength (µm) ASTER Bands 4 56 7 8 9 1.0 3 Reflectance (offset for clarity) Kaolinite Muscovite Calcite Chlorite Limonite 3.2 Reflectance Spectra Analysis According to the geologic setting and mineralization characteristics, the alteration in the study area might be composed of hydroxyl-bearing (kaolinization, chloritization, sericitization), ferric stains (mainly limonitization) and carbonates (calcitization). Figure 2 shows the laboratory reflectance spectra of relevant minerals and the corresponding resampled ASTER spectra. The hydroxyl-bearing or carbonate minerals exhibit distinct absorption features centered near 2.20 μm (band 6) or 2.32 μm (band 8), with relatively stronger reflectance around bands 4 and 7 (Hunt, 1977). For the ferric-iron minerals, a distinct absorption feature locates around band 1 and band 3 (Hunt, 1977). These spectral absorption features provide the basis for identifying lithology and mapping alteration minerals. Therefore, a series of procedures were adopted in the image processing and unknown mineral resources targeting. First of all, false colour composition (FCC) and principal component analysis (PCA) were used in enhancing the lithological differences. Secondly, PCA and spectral angle mapper (SAM) algorithm were employed to discriminate alteration minerals. 3.3 False Colour Composition Lithology discrimination using remote sensing data is mainly based on certain factors, such as chemical and mineral composition, colour or tone, grain-size or roughness, weathering characteristics, soil and vegetation (Xiong et al., 2011; Kenea, 1997). Different bands could be selected according to reflectance spectroscopy data of the rocks to (b) 0.5 1.0 2.0 1.5 Wavelength (µm) 2.5 Figure 2. Five pairs of laboratory reflectance spectra of some common minerals which are important in the study area. (a) USGS Spectral Library pattern; (b) spectra re-sampling to ASTER bandpass (modified after USGS Spectral Library). compose false colour composite images to determine the lithology (Xiong et al., 2011; Di Tommaso and Rubinstein, 2007; Moghtaderi et al., 2007; Kenea, 1997). Therefore, FCC was used on VNIR and SWIR bands to separate the main lithological groups especially the small intrusions exposed in the study area. 3.4 Principal Component Analysis Principal components analysis (PCA) is an image enhancement technique for displaying the maximum spectral contrast from multispectral bands, while the resultant components are often more interpretable than the original images (Tangestani et al., 2008; Singh and Harrison, 1985). PCA has been applied widely to multispectral remote sensing images with the purposes of enhancing the spectral differences and extracting specific spectral responses (Amer et al., 2012, 2010; Liu et al., 2011; Moore et al., 2008; Tangestani et al., 2008; Crosta et al., 2003). Standard PCA has been applied to outline the lithological differences and map alteration minerals. Lei Liu, Jun Zhou, Fang Yin, Min Feng and Bing Zhang 3.5 1 2 Spectral Angle Mapper The spectral angle mapper (SAM) algorithm treats spectra as multidimensional vectors and calculates angles of similarity between them, operated by comparing image spectra with reference spectra (either library or from endmember derivation), with smaller SAM angles indicating greater similarity (Amer et al., 2012; Galvão et al., 2005; Kruse et al., 1993). This method is independent of illumination conditions (i.e., topographic shading) and widely used for spectral matching (Bishop et al., 2011). In this work, image-derived endmembers were used as reference spectra which were collected based on the standard methodology developed by Kruse et al. (2003). Firstly, minimum noise fraction transformation (MNF) (Green et al., 1988), pixel-purity index (PPI) and n-Dimensional Visualizer techniques (Kruse et al., 2003; Green et al., 1988) were applied consecutively to the ASTER data to locate the purest pixels. Secondly, the regions with highest DN values in the PCA images were adopted to filter and identify endmember spectra. Eventually, four image end-members were selected (Class 1 to Class 4 in Fig. 3). Although the image endmembers do not match the laboratory reflectance spectra ideally due to the influences such as the presence of variable mineral-mineral mixtures, mineral-vegetation mixtures and grainsize variations (Mars and Rowan, 2006; Rowan et al., 2005; Rowan and Mars, 2003), they still retain the key absorption features centered near bands 1, 3, 6 and 8 (Fig. 3). The Class 1 displays absorption features in bands 6 and 8 which are caused by muscovite, chlorite, carbonate minerals and slight kaolinite (Fig. 3). The absorption in band 6 indicates that the Class 2 is composed of muscovite and slight kaolinite. The special spectra shape of Class 3 is mainly dictated by kaolinite and ferric-iron oxides. Furthermore, the Class 4 is characterized by the absorption in bands 1 and 3, which is caused by absorption in ferric-iron oxides. 4 RESULTS AND DISCUSSION 4.1 Lithological Map The best compositions were achieved using the ASTER composite of bands 521 (RGB) that provide good discrimination of lithologies especially the small intrusion comprises certain different phases (Fig. 4a). The lithological difference in the intrusive rocks of the study area is clearly outlined in different colour. Potash-feldspar granites have carroty colour, hornblende or biotite granites have orange with greyish colour. The quartz monzonite and tonalite have charcoal grey colour roughly predominate in the southwestern part of the batholith. Some small intrusions are identified by light grey and carroty colour which occur in the south part of the study area. The nine principal components resulting from analysis of 9-band ASTER images were used to outline the lithological differences. The image eigenvectors and eigenvalues obtained from PCA, using covariance matrix on all nine bands of ASTER of the Jiafushaersu area are indicated in Table 1. The first three principal components (PCA1, PCA2, PCA3) are used in lithological mapping because they contain 99.33% of the spectral information. The results show that lithological units Reflectance (offset for clarity) 400 0.5 3 ASTER Bands 5 67 8 9 4 Class 4 Class 3 Class 2 Class 1 1.0 1.5 Wavelength (µm) 2.0 Figure 3. Four representative endmember spectra extracted from ASTER image. Class 1, muscovite, chlorite, carbonate minerals and slight kaolinite; Class 2, muscovite and slight kaolinite; Class 3, kaolinite and ferric-iron oxides; Class 4, ferric-iron oxides. especially the small intrusions in the Jiafushaersu area were discriminated on the false colour composite imagery (PCA1, PCA2, PCA3) in R, G, B (Fig. 4b). The small intrusions are identified by white, pink and red colour. The small intrusions in white colour are interpreted as potash-feldspar granites. Field inspection indicates that the small intrusions in pink and red colour are aplite (pink) and small quartz monzonite porphyry bodies (red). Geological interpretation of the area studied has been principally based on the processed images referred to a geological map of this area produced by GBXBGMR (1966) at a scale of 1 : 200 000. A lithological map of Jiafushaersu area has been generated from the ASTER band composition and PCA images (Fig. 5). Field validation was carried out to map the small intrusions and contacts supporting the results obtained from ASTER-based method. Two SW-NE orientated granitoid intrusions, probably united below the surface or in depth, are developed in the foot wall of Darbut and extend eastwards about 40 km from Tuketuke to Jiafushaersu (Fig. 1). Ground inspection shows that the intrusion comprises certain different phases: the major part is formed by the potash-feldspar granite (carroty on RGB521) and the hornblende or biotite granite (orange with greyish tone), the quartz monzonite and tonalite (grey) roughly predominate in the middle part of the batholith, and some small quartz monzonite porphyry bodies (light grey) occur around the batholith margin (Figs. 1, 4). Aplite is also present in the proximity of the batholith. 4.2 Principal Component Analysis PCA was applied to all nine bands of ASTER imagery to highlight alteration minerals. The covariance eigenvalues and eigenvector matrix of the PCA using all nine bands is given in Table 1. The methodology used here mainly followed the studies of Pour and Hashim (2011). The first principal component (PCA1) is composed of a positive weighting from all nine bands. Overall scene The Reconnaissance of Mineral Resources through ASTER Data-Based Image Processing brightness, or albedo, is responsible for the strong correlation between the nine bands (Pour and Hashim, 2011). Eigenvector loadings for PCA2 indicate the difference of the VNIR bands with SWIR bands. PCA3 is a comprehensive reflection of all nine bands. This transformation also indicates a moderate eigenvector loadings for ASTER bands 3 and 2 with opposite sign (+0.487 and -0.036), which probably indicate the enhancement of the vegetation. The eigenvector loadings show that PCA4, PCA5 and PCA6 contain the alteration information according to the position of characteristic absorption features of alteration minerals. PCA7, PCA8 and PCA9 are noisy and uninformative. The simple methodology for iron oxides mapping by PCA on ASTER data is meant to examine the eigenvector loadings for bands 1, 2 and 4 in PCA4, PCA5 and PCA6 in order to find the component with a moderate or strong loading with opposite signs from both bands (Pour and Hashim, 2011). Iron oxides can be mapped as bright pixels in PCA4 because of the positive contribution from band 4 (0.560), while negative contributions from band 1 (-0.454) and band 2 (-0.105) (Table. 1). Eigenvector loadings of bands 4, 5, 6 and 7 in PCA5 are -0.429, 0.479, 0.511 and -0.219, respectively (Table 1). Considering the magnitude and sign of the eigenvector loadings in PCA5, PCA5 highlights the Al-OH bearing minerals as dark pixels. Therefore, PCA5 image was inversed in order to show altered areas in bright pixels. Eigenvector loadings in PCA6 indicate similar results with moderate or strong eigenvector loadings in bands 8 (-0.229) and 9 (0.651) (Fe, Mg-OH bearing minerals, carbonates), respectively (Table 1). Therefore, PCA6 can be indicator of propylitic alteration zones with bright pixels. Figure 6 shows RGB colour composite of PCA4 (iron oxides), inversed PCA5 (Al-OH bearing minerals), and PCA6 (Fe, Mg-OH bearing minerals and carbonates) image of the study area. Alteration minerals are depicted as white to yellow colour (iron oxides), green to yellow colour (sericite/muscovite and kaolinite), and blue to white colour (chlorite and carbonate), which are easily recognizable from surrounding rocks (Fig. 6). Spectral Angle Mapper Alteration Zones The four image-derived endmembers shown in Fig. 3 for the identified alteration minerals were used as reference spectra to perform SAM supervised classifications of visible and shortwave infrared 9-band ASTER image. The threshold value of 0.05 radians was used to represent the smaller angle that matches the pixels spectra to the reference spectra. The results of SAM processing based on the ASTER image-derived endmembers (classes 1 to 4 in Fig. 3) are shown in Fig. 7. The SAM results indicate that the dominance of kaolinite and ferric-iron oxides (blue colour) in the aplite and in some locations in the small quartz monzonite porphyry bodies (Fig. 7). The small quartz monzonite porphyry intrusions in are highly altered with muscovite, chlorite, carbonate minerals and slight kaolinite (red colour). The southernmost quartz monzonite porphyry intrusion has strong alteration of sericitization and kaolinization (green colour). The ferric-iron 401 oxides mainly occur in the southeast part of the study area (cyan colour). 4.4 Ground Inspection and Studies The lithological difference in the intrusive rocks of Jiafushaersu (Figs. 4, 5) is clearly outlined by certain false colour composites (using VNIR and SWIR) and PCA imagery. Some alteration minerals (Fig. 6) are also highlighted by the PCA-based discrimination, which belong to primarily hydroxyl-bearing (chlorite, sericite and kaolinite) or ferric (limonite) and less commonly carbonate types (minor calcites growing on the greisenized quartz veinlet walls and dispersed on the surface by weathering). The SAM mapping results basically correspond to the PCA ones (Figs. 6, 7). The alteration zones discriminated by the image processing techniques were verified through ground inspection. The in situ field work led to the discovery of the mineralized quartz monzonite porphyry in Jiafushaersu (points 1, 2 and 3 in Fig. 7), 0.72 km2. Three other similar bodies, scattered to the northeast, only show slight mineralization and 4.3 Figure 4. (a) ASTER colour composition (5, 2 and 1) and (b) (PCA1, PCA2 and PCA3) in RGB showing the intrusive rocks in different colour. 402 Lei Liu, Jun Zhou, Fang Yin, Min Feng and Bing Zhang Table 1 Eigenvector matrix of principal components analysis on VNIR+SWIR bands of ASTER data for Jiafushaersu area Input bands Band 1 Band 2 Band 3 Band 4 Band 5 Band 6 Band 7 Band 8 Band 9 Eigen values (%) PC1 0.269 0.337 0.322 0.352 0.317 0.335 0.357 0.377 0.322 94.681 PC2 -0.560 -0.506 -0.373 0.112 0.245 0.261 0.213 0.227 0.232 4.206 PC3 -0.292 -0.036 0.487 -0.465 -0.367 -0.104 -0.029 0.268 0.492 0.444 PC4 -0.454 -0.105 0.587 0.560 -0.010 -0.063 -0.126 -0.220 -0.238 0.301 PC5 0.060 -0.154 0.293 -0.429 0.479 0.511 -0.219 -0.406 0.002 0.133 PC6 0.200 -0.100 -0.157 0.369 -0.079 0.000 -0.554 -0.229 0.651 0.099 PC7 0.526 -0.759 0.238 0.073 -0.157 -0.062 0.208 0.085 -0.075 0.060 PC8 -0.027 0.003 0.035 -0.057 0.358 -0.573 0.464 -0.467 0.323 0.042 PC9 -0.034 0.092 -0.082 0.067 -0.562 0.459 0.444 -0.494 0.103 0.035 22%–38% (27.75%), potash-feldspar 19%–31% (27.50%) and biotite 9%–12% (11.0%), though the thin section failed to cut hornblendes, falling into the granite district of the International Union of Geological Sciences (IUGS) classification (http://www.iugs.org/), but being closer to the granodiorite. It is thus named quartz monzonite porphyry (molybdenum mineralized) considering the presence of quartz phenocrysts and on account of its notable difference from the granodiorite porphyry (copper mineralized) in Tuketuke, which contains 24% quartz, 47% plagioclase, 16% potash-feldspar and 13% biotite plus hornblende on the basis of sixteen thin section statistics. On the other hand, the granodiorite porphyry in Baogutu, which was related to the mineralization, was re-defined as the diorite porphyry by a recent petrographic study (Shen et al., 2009). In any event, the parent porphyry for the molybdenum mineralization petrologically resembles that in Climax in being silica- and alkali-rich with abundant quartz, potash feldspar and albite (Hendry et al., 1988). The surface observation or the shallow denudation at the apex exhibited that the molybdenite with minor chalcopyrite was clustered in the greisenized quartz veinlet (mostly 1–2 cm Figure 5. Detailed lithological map of the Jiafushaersu area based on interpretation of the FCC and PCA images. are 0.075, 0.050 and 0.145 km2 (in the order toward the northeast) in area. Sparsely-distributed hornblendes (needle-shaped) and biotites imply a feature slightly toward the intermediate, but considerable quartz phenocrysts connote somewhat closer to the acid despite a relative scarcity of potash-feldspar phenocrysts (Figs. 8a, 8b), grossly resembling the specimen from Jinduicheng (Zhu et al., 2010), a giant size molybdenum porphyry deposit at the south margin of the North China Block. The petrological composition, based on four thin sections, of the mineralized porphyry in Jiafushaersu consists mainly of quartz 30%–37% (avg. 33.75%), plagioclase Figure 6. RGB colour composite of PCA4, PCA5 (inversed), and PCA6 images, showing hydrothermal alteration halos corresponding with the identified small intrusions. The Reconnaissance of Mineral Resources through ASTER Data-Based Image Processing wide) that was formed mainly by coarse transparent quartzes and had some large flake of white micas and fine calcites on the wall (Fig. 8c). Only certain chalcopyrite was seen to be disseminated in the porphyry during the inspection. Fluorite, topaz, magnetite and huebnerite were not found at this stage, although those were common in the molybdenum stockwork of Climax (Stein and Hannah, 1985). Additionally, the veinlet in Jiafushaersu strictly occurs in four sets of fractures rather than forms the stockwork (Fig. 8d). Their attitudes are recognized as (1) dipping SE130° with a 25° angle; (2) trending NW325°, nearly vertical; (3) dipping SE140° with a 63° angle; and (4) trending NE35°, nearly vertical. The wall is straight and flat, indicating a very stable extension toward the depth, although the third set (dipping SE140°, angle 63°) is not so steady. 403 Among them the first set (dipping SE130°, angle 25°) is the major molybdenum-bearing structure with a space between 30 and 50 cm. Nevertheless, the structural relation between those fractures and the large-scale sinistral strike-slipping fault (Fig. 7b) is uncertain. Only in the southwestern corner of the mineralized porphyry were trenches and open pits available during the studies. An investigation through the limited excavation revealed that the immediate host rock of veinlets was typified by the intensive silicification plus chloritization and calcitization (dense, hard and dark greyish), whereas sericitization, kaolinization and limonite or ferric stains were ubiquitous in the porphyry. Thin sections further detailed that chloritization mainly took place in both biotite and basic Figure 7. (a) Result of SAM mapping method overlain on bands 521 (RGB) and (b) enlargement of the exploration target in (a). Classes 1 to 4 refer to Fig. 3. plagioclase, calcitization was primarily developed along the veinlet wall, kaolinization was mostly related to potash feldspar while sericitization to plagioclase. Certain kaolins were doubtless originated from the surface weathering, especially those with ferric stains. But the distinguishable features based on various image processes (Figs. 6 and 7) suggest that the mineralized porphyry is notably different from its neighboring rocks in the lithology and wall-rock alteration as a whole. In the mineral exploration sense, the differential weathering, even if present, just reflects an essential disparity and can be also used for locating a target. At this stage, it is difficult for us to generalize macroscopically the zoning pattern of the wall-rock alteration due to the limited exploration. 4.5 Discussion The known porphyry or porphyry-like coppermolybdenum-gold mineralization points or deposits in West Junggar have been mostly located at the foot wall of the suture or at the subducted side to date, notably challenging the previous well-known metallogenic model (Groves et al., 1998; Chen, 1996), which postulated these types of mineral deposits to have been originated from a far-off zone at the hanging wall or toward the continent. It led us not only to think over the metallogenic theory, but also to revalue how to target the mineral resources of this kind. Furthermore, the mineral exploration in both Tuketuke (Zhang et al., 2009) and Jiafushaersu (this study) commenced with a remote sensing-orientated study. The mineralization characteristics combined with the image processing and interpreting are substantiated as follows. The small intrusions with distinct lithology are clearly outlined by false colour composites of bands 521 in R, G, B) and PCA images (PCA1, PCA2, PCA3) in R, G, B (Fig. 4). Among the newly documented small intrusions, the quartz monzonite porphyry appears in red colour on the PCA image (Fig. 4b) due to the high reflectance in VNIR. Potash-feldspar granite bodies have been separated from the dominantly hornblende or biotite granite due to their white colour on the PCA image which is attributed to the major spectral feature of potash feldspar. The hornblende or biotite granite as well has been separately mapped based on the processed images (Fig. 4b) in pink colour, with rough texture. Additionally, the aplite is present in the proximity of the batholiths in yellow with red tone. Both PCA and SAM methods received satisfactory alteration mineral mapping results. The PCA results indicate 404 the dominance of iron oxides, sericite and kaolinite, and chlorite and calcite in the quartz monzonite porphyry, aplite and in some locations in the potash-feldspar granite. The SAM results outline the alteration mineral assemblages basically correspond to the PCA ones, but more explicitly. Some of the mapped alteration zones in PCA and SAM agree very well with the GPS locations of ground inspection in the Jiafushaersu area (Points 1 to 11 in Fig. 7). The results Lei Liu, Jun Zhou, Fang Yin, Min Feng and Bing Zhang reveal new alteration zones in the four small quartz monzonite porphyry intrusions within the hornblende or biotite granite. The ground inspection led to the discovery of the mineralized quartz monzonite porphyry. Results indicate that the workflow of the image processing, interpretation and ground inspection is a powerful mineral targeting method for the reconnaissance stages of mineral exploration in a regional scale. Figure 8. (a) Thin sections of quartz phenocrysts and plagioclase in quartz monzonite porphyry; (b) quartz phenocrysts and potash-feldspar in quartz monzonite porphyry; (c) polished section of molybdenite in the greisenized quartz veinlet; (d) four sets of fractures control veinlets and mineralization in Jiafushaersu. The analogousness of the mineralization in Tuketuke and Jiafushaersu to the porphyry type mineral deposit can be also corroborated by relevant geochemical facts, although the size of them is limited at this stage, especially for Jiafushaersu, because the exploration is ongoing. As we know, a genetic correlation between adakites and porphyry copper-gold deposits has been elucidated by many studies (e.g., Oyarzun et al., 2001), and the general criteria for adakites are: SiO2>56%, Al2O3>15%, Sr>400 ppm and Y<16 ppm. The assays of the copper-mineralized granodirite porphyry in Tuketuke (two samples) yielded a similar result: (1) SiO2 67.37%, Al2O3 15.14%, Sr 270 ppm and (2) SiO2 66.73%, Al2O3 14.97%, Sr 300 ppm and the relative depletion of strontium was interpreted as being not so fresh for the samples (Zhang et al., 2009). Moreover, the molybdenum-mineralized porphyry in Jiafushaersu spatially correlates with a tungsten anomaly (2.5 ppm) on the basis of the geochemical survey result at a scale of 1 : 200 000, implying an intimate relation between molybdenum and tungsten as it is in Climax (Hall et al., 1974) notwithstanding tungsten minerals have not been found yet in Jiafushaersu. 5 CONCLUSION Eventually, combined with the achievements in previous studies of the regional mineralization in West Junggar, the recognition of both remote sensing and geology in Jiafushaersu by this study can result in drawing the following conclusions. First, the successful exploration of the Baogutu porphyry copper-gold deposit (Shen et al., 2009; Song et al., 2007; Cheng and Zhang, 2006) intensified the targeting of similar mineral deposits in the same tectonic setting. The new addition or the recent progress of ore prospecting in Tuketuke (Zhang et al., 2009) and Jiafushaersu (this study), together with the many newly-found similar mineralization points, further verified that the foot wall of the Darbut suture could have served as a more important metallogenic district for the porphyry copper and molybdenum deposits. This may contribute to forming a better metallogenic theory later. Second, the Jiafushaersu molybdenum-mineralization site is about 35 km (straight line) east of the Tuketuke porphyry copper-gold deposit and this is a granitoid batholith-dominated zone (Fig. 1). The batholith is formed by certain intrusive phases and identified by many small granodiorite or quartz monzonite-porphyry stocks around its margin. This implies that The Reconnaissance of Mineral Resources through ASTER Data-Based Image Processing the relevant zone is of a big potential in the porphyry type copper-gold resources due to its size. Third, the different intrusive phases are clear in multispectral or PCA false colour composite. The ASTER bands 521 (RGB) is one of the best composites that provide good discrimination of the small intrusions (Fig. 4). The quartz monzonite porphyry is rounded, in light grey colour and occurs around the batholith margin. These similar small intrusions, despite often omitted by the geological map at a scale of 1 : 200 000, are clearly outlined by ASTER images and very useful for prospecting. Fourth, PCA and SAM algorithm were employed to discriminate alteration minerals. For the PCA results, the hydroxyl-bearing (chlorite, sericite and kaolinite) or ferric (limonite) and less commonly carbonate types (minor calcite) show good correlation with the quartz monzonite porphyry and aplite in the south (Fig. 6). The SAM mapping results basically correspond to the PCA ones (Fig. 7). Fifth, the workflow of ASTER images processing, interpretation and ground inspection, together with synthetic analysis with geologic data, is an efficient and powerful mineral targeting method, which can be applied in the sparsely vegetated arid region in northwestern China. Last, the features of lithology, alteration minerals and tungsten-rich geochemical signature of the molybdenum-mineralized intrusion in Jiafushaersu imply that the molybdenum mineralization is close to the porphyry type. ACKNOWLEDGMENTS The study was supported by the Special Fund for Basic Scientific Research of Central Colleges of China (Nos. 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