m6f THE TX 769 ^"^^ ^ THEOPtY AND ART BREAD-MAKING A NEW PROCESS WITHOUT THE USE OF FERMENT. E. N.HORSPORD, RUMFORD PROFESSOR IX HARVARD UNIVERSITT, CAMBRIDGE. CAMBRIDG E: WELCH, BIGELOW, AND COMPANY, PKIXTKKS TO THE UNIVERSITY. 18 6 1. fe^ Entered according to Act of Congress, in the year 1861, by E . N . H O R S F O 11 D in the Clerk's OfiSce of the District , Court of the District of Massachusetts. ^ THE THEORY AND ART OF BREAD-MAKING. Bread-making, in widest sense, consists in giving to the its flour of certain grains convenient What the form shall be is form for the purposes of food. determined by several considerations, the most important of which is the adaptation of the food to the In order requirements of digestion. most to this adaptation, the essential quality of the bread is surface for the action of the digest- ing fluids. Bread presenting great surface, so as to yield to the agents of digestion, is healthy, while that surface, so as to overtask the little case of heavy bread, is promptly which presents powers of digestion, as in the not healthy. Surface is gained most con- veniently by giving to the mass of flour the cellular structure of raised or light bread. of the This cellular structure permits the mouth and stomach to pass in by capillary action, fluids and by endosmosis and exosmosis to penetrate every part of the mass and accomplish the office of digestion. As experience has shown wheat to contain the elements of nutri- tious food in the best proportions for the wants of the human or- ganism, the discussion which follows will be devoted to the art of making bread from wheaten flour. In the broadest acceptation, bread-making might include the preparation of crackers, cake, and all the forms of light and heavy pastry in use but it is proposed ; to omit all these, and limit the application of the word bread to the plain, light, or raised wheaten fiour loaf, into which, beside the principle of leaven, only salt The from and water enter as great essential process of such bread-making flour of a permanent component is parts. the production cellular structure of convenient size and THE THEORY AND ART form, — to wit, tlie raised loaf, If the loaf the original flour. or aromatic hy with but inconsiderable changes of is made sweet by addition of sugar, addition of flavoring extracts, Or rich of eggs or butter or by addition cake or pudding or pastry, but not fruit, it is bread. Let us consider the material out of which this loaf is to be produced. Composition of the Wheat- Grain. Fig. 1. d ^ CD The crushed grain of wheat By white iwrtions. is removed. Of is a mixture of reddish-brown and bolting or sifting, most of the this the commonly though not coarser part much little of Careful examination shows it of the interior portion of the berry. true bran, or bark, grains and rubbing towel. brown portion Bran is called bran. universally supposed to contain but the nutritious part of the wheat. to contain is may The outer be partially removed by moistening the them lightly between the This hull or bark so separated is folds of a coarse chiefly composed of woody fibre, and contains little nutritious matter. Investigations made elsewhere, and confirmed in my laboratory, have shown the amount of the outer bran that may be so detached to be less than three and a half per cent of the weight of the un- Fig. 1 exhibits the wheat-grain or kernel of the natural size, presenting the grooved side and reverse, and cross section also a cross section magnified to ; 18 diameters, and displaying tlie bran-coats, gluten-coat, and starch-cells. OF BREAD-MAKING. Within branned berrj. as and constituting a continu- this bark, most important constituent of the contains the phosphates and nitrogenous ingre- ous inner wrapper, wheat, 5 it is the which the digesting and assimilating apparatus dients out of elaborate all the important tissues and organs of the bodj. is Within the gluten. to the centre of the berry, three portions, — It envelope of gluten, and extending this a mass of starch. is There are then the bran proper or outer envelope, the gluten or inner envelope, and the starch. They are exhibited in Fig. The bark 1. envelope, including also the portion next the gluten, consists of several layers, the of which outermost gluten and resembles very thin The cuts like the rind of cheese. loosely held together The starch by a coarse network of oil also is in cells, granular and is cellular tissue. its Gluten Its consumption, and that of the gum, sugar, present in small quantities in wheat-meal, contribute to maintain the ment of temperature of the body necessary to the is the name under which In an insoluble ; albumen ; fulfil- various functions. uents of the flour are grouped. portion, the fibrine the chief nitrogenous constitit there have been recognized a smaller, soluble portion, the and a portion not so well known, wdiich and is called is dite certain kinds of fermentation, these bodies have substantially the is The straw. starch belongs to a class of bodies specially related to the respiratory organs. and much not fibrous, like the hull or bran proper, but is said to expe- cerealine. same chemical As constitution, it conceivable that they differ from each other chiefly in the de- gree of degradation which the latter two have experienced, or in the degree in which they are susceptible of decomposition action of ferment, the fibrine being the most stable, aline the least stable of the group. envelope, there ble nitrogenous The is, Besides the gluten in the according to Mayer,^ a small amount of a soludistributed throughout the starch. compound gluten and starch may be separated from each other by kneading in a current of water. slightly elastic substance. The The former latter is is Aim. d. Chei-n. u. a tenacious, granular and loosely co- herent. 1 by the and the cere- Pharm., CI. Bd. 2, p. 163. THE THEORY AND ART Fig. 2. If a cross section of wheat be exposed for a short time to the action of a solution of ammonio-sulphate of copper, the gluten will be impregnated with a green compound. green compound, which is The extent of the coincident with that of the gluten, will be found to be limited to a thin envelope immediately within the bran proper. If another cross section be exposed for an instant which a few become deep violet to the action of a solution of iodide of potassium to drops of nitric acid have been added, it will wherever the starch granules occur, and the extent of the starch will be found to include the entire space within the thin envelope of gluten. Microscopic examination shows the gluten to be posed in one continuous layer of granules, and the chemical tests with no intervening starch show that the gluten cells pene- trate the starch but slightly, if at Fig. 3. dis- cells all. Miller^s Bran. Fig. 2 presents a portion of a transverse section of white wheat, magnified to 1, 1 are the coats of outer true bran 2 is the inner coat of true 150 diameters. ; bran; 3 gluten; Fig. 3 last. is 5, is a thin filmy coat covering the gluten cells; sacks of gluten; 6, starch-cells. cellulose containing a transverse section of commercial bran, upon the same scale as the of starch is sometimes twice or three times as thick as is here The layer exhibited. 4, OF BREAD-MAKING. Loss of Phosphates with A glance at these figures will explain much teen times as the Bran. why Mayer ^ found four- phosi^horic acid in commercial bran as he found in commercial superfine flour. The bran carried with it most of the layer of gluten in which the phosphates and the companion nitrogenous compounds sue — are starch, but little of the . gluten having been detached from the Mege-Mouries^ found the bran. — the sources of living tislodged; while the superfine flour consisted chiefly of Fig. 4. gluten coat to contain ten per cent of nitrogen, while the average of the whole berry from two is to three per cent. A glance at these figures will show why also from Graham the bread flour, made and the Pum- pernickel of Westphalia, which is also made from unbolted meal, and the black bread of like origin found in the sacks of Russian diers in the sol- Crimea, are so nu- tritious, in spite of their heaviness and sourness. They contain all the gluten as well as starch of the grain. All the phosphates and ni- trogenous compounds of the grain enter into the bread when the bran not separated from the flour, in- is stead of a small fraction only, as in bread made from superfine flour. Fig. 4 exhibits the arrangement of the successive coats, inchuling the ghiten or less of each coat being removed, so as to display the order of succession. It is also on a scale of 150 diameters. The coats 1, 1 are readily separated with a moist cloth.3 and ghiten-cells, more Ann. d. Chem. u. Pharm., CI. Bd. 2, p. 146. Compt. Rendus, XLVIIT. 4-31. 3 Mr. Thos. J. Hand, of New York, to whom I am indebted for these most detailed and elaborate original drawings, and who has in numerous ways aided 1 2 THE THEORY AND ART 8 Difficulties It is well known of Bread-making, that the best bread-makers find great diiR- of household cooks and of bakers bread This the production of uniformly good bread. cult}^ in sometimes good, more is times positively bad. employed true The frequently indifferent, and often- Sometimes the objectionable the bread are apparent to the touch, of smell and taste, and is in the shops. qualities of sometimes to the senses more frequently in their effects upon health through inferior assimilation. The may The flour which is excellence as well as in composition. in employed Some from winter wheat, some from spring wheat me in Some sources of this difficulty are various. be mentioned. my researches upou bread, is ; of of them is variable it is made sometimes the about to give to the public the results of his fresh microscopic examination of the structure of the kernel of wheat. which Mr. Hand has so successfully individualized under the mibe separated to some extent by chemical processes. If the berry, deprived of the two outer coats of true bran by friction with a moistened cloth, be treated with alum solution, then opened along the side opposite the groove, digested with warm water, and carefull}^ pressed, the starch may be quite successfully separated. The residue, consisting of gluten and the immediate investing coats, constitutes some twelve per cent of the Avhole berry. If the gluten coat be treated with acetic acid, it may, with care, be separated from the layers The parts croscope, may without. The extreme outer by friction with the moistened cloth, conand phosphate of, magnesia, besides silica and potassa. The ash which has been analyzed by my assistant, Mr. Brooks, is 6.64 per cent, of which 7.70 per cent is phosphoric acid. The coats next to the gluten contain also phosphates and alkalies. But the gi-eat magazine of phosphates, as well as of nitrogenous compounds, is in the coats separated tain phosphate of iron gluten layer. The ash of Vv'heat as a whole contains, — Potassa 29.97 Soda Magnesia 12.20 3.90 Lime 3.44 Phosphoric acid Sulphui'ic acid Silica Oxide of 46.02 .33 3.35 ii'on Chloride of sodium .79 trace 100.00 OF BREAD-MAKING. flour made from "grown" wheat; frequently it is damp and is grinding, it is 9 oftentimes it is heated in granular, and occasionallj sour. The ingredients of the leaven or yeast with which the ferment- ed "batch" bread prepared are not only variable, but the is changes which take place in the yeast are influenced by the by the volume of water employed, by the temperature to which the mixture is subjected from without, by the heat which is developed in the process of fermentation within, by the species of ferment which are added, by the degree of cleanliness maintained, and by the itself quality and condition of the ingredients, time during which the various changes are protracted. Effects of Fermentation. Among of which are beneficial, hurtful, — the effects which ferment produces in flour, — there body nearly some and others of which are more or less are the conversion of starch into dextrine (a allied to gum arabic), and this dextrine into sugar, and the changing of a portion of the sugar bonic acid, the production of and car- into alcohol lactic, acetic, butyric, succinic, and formic acids, the greater or less liquefaction of the gluten, the formation of ammonia, the production of a dark coloring matter, the development of microscopic vegetable organisms of various kinds, and, through the breaking or less deterioration of the down of nutritive the gluten, the greater properties In the use of recently prepared leaven there duced an ethereal to of the flour. sometimes pro- the pleasant taste of the In the use of old leaven the production of offensive bread. ethereal oil Of which adds oil is all is uniform. these effects, important, if of bread, is it is now generally conceded that the most not the only essential office of ferment in the making make give to it the requisite porosity, or to ''''lights This porosity is necessary, as already intimated, that tlie fluids taking part in digestion to may have it surface to act upon. accomplished by the evolution of carbonic acid from sugar, the alcohol from which exhales with the surplus moisture in the It is process of baking. The production of all other acids than carbonic acid can scarcely THE THEORY AND ART 10 The be other than hurtful. liquefoction of the gluten, due to their presence in excess, tends to deprive the bread of porosity. This extreme change causes the dough once distended and to collapse leaving the bread heavy, or displaying here and there fall, great cavities. Liebig proposed the use of lime-water in mixing the dough, a suggestion that met with great acceptance. vious. Its office was ob- neutrahzed the acid which was liquefying the gluten. lime also combined with the liquefied gluten (albumen) giv- The ing It — it The firmness. use of alum and sulphate of copper for the districts, quite universal. same end may Dr. Hassall examined twenty-four samples of London bread, and found alum in all. Dr. Muspratt remarks that what is true of be said to be, in some London may be Dumas land. said of Liverpool and all the larger towns of found that sulphate of copper (blue vitriol) Enghad been in use in Belgium from an indefinitely early period. The Kuhlmann found quantity employed, however, was very small. that one baker 250 employed only a pipe-bowl full of the solution for It was observed to have the effect to make of bread. lbs. inferior flour produce a bread that sold as well as bread from a more water better quality of flour, and, besides, the bread retained Alum and was whiter. produced the same of the alum, by virtue of derstood. It its qualities as a mordant, combines with albumen and renders so far aiTCSting the action of the ferment, way is much the combining with the albumen, by the ferment, is same to The it less soluble, in a twofold action of sul- as that of alum, in so far as form a compound concerned, and it may have less influenced a separate specific effect. It is said to increase the activity of the ferment, may be apparent only, as the gluten, and thus increase the ferment produces. though its action readily un- is and thus lessening the liquefaction of the gluten. phate of copper The results. effect may be capacity to hold simply to all It is conceivable that but this stiflTen the the bubbles which it acts somewhat, inferior in degree, as corrosive sublimate does to destroy some of the species of the yeast-plants. The excessive production of dextrine, with extreme porosity, makes the bread dry too rapidly, and gives and hardness which characterize the when lefl a short time exposed slice to the air. rise to the brittleness of most bakers' loaves OF BREAD-MAKING. Mould 11 poisonous. The mould, or the organic germs from which it arises, can only be hurtful. To this, it is well known, some of the most painful forms of dyspepsia are ascribed. The significance of this statement may not at first glance be fully appreciated. The existence of microscopic organisms in the various forms of yeast has been Whether they be regarded established. office to fulfil in the more or whether the as having an essential process of fermentation, as many that they are the incidental concomitants of decay, germs everywhere present in the decaying vegetable organisms, other be adopted, tion are — atmosphere finding a — whether the yeast fit soil in the one view or the admitted that the phenomena of fermenta- it is accompanied by the growth of microscopic vegetable It is well organisms.^ ble of reproducing those into which known it that each kind of ferment and communicates itself, the" tendency to break acetic, maintain, philosophical view of Liebig be accepted, up into bodies of the itself resolved. is to the This new is capa- substance same character is as true of lactic, and putrefactive fermentation, as well as of those attend- ing the successive changes of starch into dextrine, sugar, and When now we alcohol and carbonic acid. these doctrines, it is take into account not difficult to conceive that the ferments and their yeast-plants, having escaped destruction by the heat of baking, may produce ill effects when they reach the general circulation. As a class, microscopic fungi are poisonous. Some of the forms of mould in carelessly dried chestnuts are well known to be poisonous. The form of mould that appears on cheese has long been recognized as a malignant poison. appears on rye, and its ill effects, The fungus^ that The wheat- are well known. bread distributed among the troops in Paris in 1841 was found The rust of to contain in all its crevices a minute red hchen. wheat and smut of corn are 1 Blondeaii has indicated the particular fun^i that attend the different kinds of fermentation. With the acid, the Penicillium 2 varieties of these poisonous fungi. Ergot. alcoholic glaucum ; is the Torvula cererisice and with the ; with the lactic acetic, Torvula aceii. THE THEORY AND ART 12 Dr. Mitchel of Philadelphia long since called attention to the influence of these microscopic organisms on health, and the subject in this immediate connection has been discussed at considerable length ; among others, by an English author on hygiene, Dr. Lobb, in a series of articles in the Medical Circular of London, in which he advocates the aerated bread of Dr. Dauglish, made without bread and ; ferment, to the exclusion of by Dr. Hunt in an able paper fermented batch- all North Ameri- in the can Journal of Homoeopathy. These effects of ferment and the incidental deterioration of the flour by the incipient disintegration of the gluten are un- desired concomitants, which, or less extent, must accept we produce if to the a greater cellular structure we by means of ferment. Wliy Flour is mixed with Water and baked, The is great fact, as Yeast, and Tcneaded and Sfc. already remarked, in the art of bread-making, the jjroduction of surface for the action of the digesting fluids. It is the accomplishment of a permanent cellular structure. Let us trace the series of processes. The jlour is thoroughly the gluten, which, ticity that and tenacity, when bubbles may when dry, to That be intimately mixed with the starch, so an elastic and tenacious kneaded thoroughly with gas-bubbles the enough is ? water, possesses elas- of gas appear in the midst of the loaf they may everywhere have The yeast mixed with water for what when moistened with are coat. the Jiour for what'^ produced, their walls by exhalation of the water, may to the That, be thin consistency required for self-support before the outside burns in the process of baking. The dough is placed in the oven to he baked for what ? That by extreme drying, may become hard at the moment dough has attained its greatest porosity, and hold 02? the surface, when the the spongy interior while the surplus water is exhaled. The browning of the crust gives rise, by destructive distillation, to some essential oils, kindred with those produced in the roasting of corn or coffee, and agreeable to the senses of smell and taste. OF BREAD-MAKING. The coagulation of the albumen, and some of the starch produced by tiie 13 increased solubility of may bailing, be considered steps in the du'ection of disintegration. Are there other effects accomplished in ordinary bread-making Knapp Any remarks, that the starch may one on satisfy himself for the is ? most part unchanged. point by adding a drop of this will become blue. The by kneading Avith cold water. They have been simply mixed together, and the change produced in them has been inconsiderable. But is there not something mysterious in the action of ferment iodine water to a crumb of bread, which starch and gluten may be separated which gives the fermented bread decided superiority ? Let us consider this inquiry. Tlw Ideal Loaf. Every baker has in his mind an ideal loaf, —a loaf the ferment of which was quite fresh, and almost neutral or but slightly acid, and that with volatile acid ; the flour of which was not heated grinding, nor moistened just before nor after grinding, and in made from choice winter wheat containing a large proportion of gluten, which gluten was not removed with the bran, the mixing of rising of which all was with rich milk instead of water, the wliich was carefully watched so that the oven when the temperature of the might be placed in the loaf and the distension of what they should be, and now and then some of the numerous staff have had a loaf approaching latter — the former were precisely But that ideal. it the testimony of all one beset with innumerable is would be result ; so that whatever the careful baker other reasons, there difficulties difficulties the yeast, is and flour, have and that no one a given may this ideal loaf. trial as to its occasionally re- If there were no it. The intrinsic number of unknown quantities not good flour enough for of the problem in the yeast is that the task of attaining safe in prophesying with regard to joice in, the world cannot as if is difficulties, lie in the and the varying skill of the cook. These are so great that the baker speaks of the -vagaries of — its fitfulness, inconsistency, and untrustworthiness, they were almost entitled to the rank of moral qualities. known, for example, that a It sample of yeast that sometimes THE THEORY AND ART 14 work well on a lower refuses to floor will work admirably in the fourth story, and that a yeast working well at one bakery, carried with its fuses to fulfil its office. when it is when containing vessels to a neighboring bakery, re- These phenomena find some explanation considered that the germs of the yeast-plants are carried readily in the air. All attempts at establishing a method of making fermented batch-bread that shall be invariably good, from the days when unleavened bread was prescribed for use at sacred ceremonials, have resulted in but inconsiderable advancement. The process of Rollan, which attracted considerable attention in France, and the ingenious processes of Berdan, apply only to the mechanical arrangements connected with kneading and baking. made cess, Neither the slightest advance in the most essential part of the pro- — to wit, the production of the cellular structure. Mege-Mouries's Process. The most scientific Mouries. portions, considerable contribution knowledge on — in recent times subject has been this to our made by Mege- This experimenter divides wheaten meal into three jiour, groats, He and hran. steeps the groats with water, in the proportion of one of groats to four of water acidulated with tartaric acid, and It tation. is mixed with the lets it run through the alcoholic fermen- then strained, to separate any bran-flakes, and flour which is to be made into dough. The al- become dark-colored, as wheaten meal more frequently does, and as other bread occasionally does when made in the ordinary way, and that all the leged gain is the that loaf does not nitrogenous constituents of the flour are saved. is, that there which is to integration. fulfilled is by is Mouries's theory a nitrogenous body in the groats, the first action of produce a dark-colored compound as a result of dis- This function of the nitrogenous body having been letting it run through the alcoholic fermentation, it the ofl&ce of leaven upon the flour. in condition to perform Mouries's process is doubtless good ; though, in careful hands, has not invariably succeeded, and his reading of the results perfect. Bakers are familiar with the made with fact that is it im- dough which is brewers' yeast, set aside to rise one hour, for example, OF BREAD-MAKIXG. 15 • yields a dark -colored loaf, while, if permitted to and then baked, remain two hours before baking, it yields a white loaf. The coloring matter is, then, obviously a passing phase accompanying cer- The bread tain changes. than that of the whiter In the in the dough. and sugar stage ; of the darker loaf uniformly sweeter is The baking loaf. arrests the changes case the changes stop in the dextrine first in the second, they stop in the alcoholic stage. To comprehend this fully, let it be remembered that the best made in this direction, from Schwann and Liebig to researches Pasteur, go to prove that each change in the fermenting mass has its own special attendant ferment, that each ferment pable of reproducing each ferment Mouries itself, proportioned to the quantity present. is sets the groats aside to steep in water, great excess of gluten and a moderate he adds is ca- and that the transforming power of he amount of When • sets aside starch ; a when starch sugar already in ferment, he tartaric acid, or Exposure to the oxygen and the breaking introduces an agent which liquefies the gluten. by air is followed down the absorption of of the gluten compound. of the ferment that With comes the formation this change the starch is to to dextrine disintegration of the gluten gives the body that dextrine into sugar, and oxidation, the and carbonic still body that is further ; to convert the further disintegration, and perhaps to transform the Each of acid. is sugar into alcohol these transforming agents not only produces- the change in starch or dextrine or sugar which immediate office, but it reproduces itself, is its as already remarked, from the stock of nitrogenous matters at hand. Thus, when the decoction of the groats has run its course through the alcoholic fermentation, sugar, — but it it has has left left behind — no to the production of the dextrine, sugar, this starch, no dextrine, no the particular ferments that are essential magazine of ferments is mixed with bread, and a portion of the starch is and be wrought into transformed into dextrine by the aid of the appropriate ferment, another ferment convert the dextrine into sugar, and convert the sugar into alcohol. And when alcohol. flour to still is at hand to another ferment to These several ferments were produced from the groats by the preliminary process. Conceive now the supply of ferment required to effect any of THE THEORY AND ART 16 the changes in the series to be inadequate, — for example, the ferment necessary to produce the change from dextrine to sugar. Suppose the baking The bread reached. dextrine and sugar. and the change stage has this been by the presence of be dark-colored, and sweet and will be characterized It will new ferment to be produced and to act, be complete. The ferment that converts the But give time heavy. when take place to will for sugar into alcohol and carbonic acid being present in adequate quantity, the dark color and extreme sweetness and heaviness will disappear. of the gluten of commercial bran or groats, or " fine The saving feed," if only a ferment as gluten of the flour, to spare the disintegration of the desirable, but the certainty of obtaining is good fermented batch-bread by the process of Mouries, beside consuming much time, requires the same close attention that the Moreover, the ordinary process with brewers' yeast requires. usage of country does not contemplate the joint purchase this of flour and bran for home supplies. Can Fermentation he avoided'^ Since then fermented batch-bread and since the ties, sult attained cellular structure is is liable to these uncertain- the only important good re- by fermentation, the inquiry suggests ferment this desirable effect of may hazard of making the bread hurtful, itself whether not be attained without the — without the sustained care and watchfulness, and without the consumption of so much time. May it starch, not be attained without the use of decaying gluten, and sugar ? household supplies. This It was made by Henry ^ is manifestly the great problem of has been so recognized. This inquiry at the close of the last century, proposed the use of a carbonated alkali and muriatic when mixed with the flour and moistened, gives, by the evolution of carbonic acid, the requisite porosity, and produces common throughout the loaf at the same time. salt The mixture 1 when he acid, that, This plan 1837, is and Sewall, process. of saleratus (carbonate of potassa) and sour milk ordinarily ascribed to Dr. R, Thompson. Dr. Whiting, in in 1848, took out English patents for modifications of the ;; OF BREAD-MAKING. method of some extent throughout, and with flour was another answer, and (lactic acid) making 17 biscuit and short-cake this practised to is still but the imperfect distribution of the saleratus the imperfect neutralization of the potassa, because of the variable acidity of the sour milk employed, alkali in the bread, both discoloring brought this method it and the consequent and making into general disrepute. with sour milk has found more favor, it free have bitter, Bicarbonate of soda the less causticity of any remains without being neutralized by the lactic being less objectionable to the palate and less marked in this alkali, if acid, on the bread. its effects The mixture of dry tartaric acid and bicarbonate of soda with flour is well known to produce a light and palatable bread. Substituting cream of tartar — an acid tartrate of potassa — in place of pure tartaric acid, to be mixed with the bicarbonate of soda, is another and popular expedient for escaping the prolonged and m variously objectionable process of bread-making the use of yeast or sour dough. Dr. Dauglish has devised a method, recognizing based upon ments — the bread-making in He structure. — idea that the only desirable oflice of works indeed, all fer- to give to the loaf a certain cellular is into the flour a solution of carbonic acid in water, employing a closed kneading apparatus, so as to conduct To the process under pressure. this plan, which results in most excellent and acceptable bread, there can be no objection except that, although suited to the wants of extensive public bakeries, does not meet the wants of private families. it The use of bicarbonate of soda and sour milk has this objec- tion, that the proper adjustment of acid and soda attained, and the bread brown, from the excess of The lent is it alkali. resulting in tartrate of soda and tartrate of generally regarded as harmless, because these sub- stances are present in much of the most healthful fruit but there are eminent physicians by rarely if ever use of cream of tartar and bicarbonate of soda in equiva- proportions, potassa, is frequently bitter and portions of is who regard the use of these ingredients as injurious to organs. 2 we the bread eat made the alimentary THE THEORY AND ART 18 In these processes nothing useful all except the cellular texture. However mal constituents of the flour may supplied by any of these methods. is added deficient none of be, dough, to the any of the norwants are its THE NEW METHOD. In view of the foregoing, the question naturally suggests May it not be possible to return a wanting ingredient, or constituent to the bread, at the nutritive raising of the loaf is to experimental solution. to of the two ingredients, the acid and the base of a itself, present in the cereals and salt, essential the which directed the research was the production, idea each by normal that accomplished as an incidental effect? This problem has been subjected The same time itself. add a all healthful food, and the production of all the important organs of the body, in such form that the two mixed with flour would remain inert till the addition of water or the application of heat, and then unite to establish the normal salt, evolving incidentally car- bonic acid from the midst of the dough, to Of all make the bread porous. the salts taking part in vital processes, the most impor- They tant are the phosphates. enter into the composition of the boiles, the muscles, the nerves, the brain, higher tissue ; formed there nature has supplied a are present in and indeed of every and wherever an important function all to be per- store of phosphates. They the forms of substantial food. the great prominence now is Aside from given by the medical world to the use of the various forms of soluble hypoj^hosphites, known it that finely prepared phosphate of lime, eaten is greatly aids the growth and firmness of bones and teeth. tured bones are reunited much more promptly upon a which pulverized bone enters as a prominent well as such, Frac- diet into constituent. The excess of phosphates in the secretions of the kidneys consequent upon extreme mental exhaustion has led to the use of some form of phosphorus to renew the cerebral and nervous fibre.^ Food otherwise unobjectionable ingredients, and the imperfect diet is effect of is frequently deficient in these Hving too exclusively upon such conceived to lower the tone and diminish the 1 Sir Benjamin Brodie. OF BREAD-MAKING. vigor of the system as a whole. On 19 the other hand, suggested that pioneers and early settlers owe the osseous system, and the accompanying has been it the prominence of hardihood they so uniformly display, in no small degree to the abundant phosphates supplied by the virgin soil to the cereals and meats that constitute their food. This suggestion derives strength from the circum- stance that the effeminacy of comitant of a diet which is many Oriental nations This demand of the system for phosphates well-known many relish of is the con- relatively deficient in phosphates. inferior animals is illustrated in the for bones. Cattle, grazing in inferior pastures, eat ground bones with avidity. Superfine Wheat Flour is deficient in Phosphates. In the preparation of ordinary superfine wheaten flour we by all that are contained lessen the quantity of normal phosphates Fig. 5. Outline drawing of a portion of a longitudinal section of MiUer^s Fig. 5. Bran, upon a scale of 150 diameters. This is the companion drawing to Fig. This is an accurate 3, which presents a transverse section of miller's bran. drawing, under a camera lucida, and shows the great loss of nutritious mat- Bran. ters in ordinary Miller''s 1, outer true bran; 2, containing gluten cells; inner true bran; 5, 3, thin gluten sacks, in outline; membranous 6, 6, coat; 4, coat starch cells^ in outline. THE THEORY AND ART 20 in the gluten made upon which this is Mayer, who has sejDarated with the bran. subject the most detailed and comprehensive research, finds the percentage of phosphoric acid in bran to be 2.82, while the percentage in superfine flour is only 0.20 that ; the bran contains, weight for weight, as already remarked, i\\im fourteen times as that The much phosphoric separated from is acid as the superfine Jiour it. gluten which contains the phosphates distributed, as already coat of the berry. It is for the easy to see, therefore, why — why portionally of the nutritious portion of the grain it is is most part remarked, immediately within the bran should be so largely removed with the bran, a large part of is, more is the gluten also more pro- withdrawn, when separated as bran, in the effort to obtain a white Mege-Mouries recovered in part the nutritious matter when he employed the brari or groats extract as a ferment. superfine flour. He at least spared the gluten present in the flour, that would the process of Mouries, for reasons already mentioned, ticable, even if it is oth- But erwise have been sacrificed to the wants of fermentation. as imprac- promised good bread with greater certainty of fulfilment than the ordinary processes of fermented batch-bread, there remains, as the next best thing, the restoration of the phos- They phates. sometimes are, moreover, the deficient. It is salts, known which, with the gluten, are that the wheat-grain, grown under certain circumstances, has contained no gluten whatever.^ In many cases when it is imperfectly supplied with gluten, especially has been grown upon impoverished it troducing phosphates into bread, we soil. of restoring an ingredient sometimes deficient even berry employed, and always deficient in superfine is Thus, in shall fulfil the double if alkaline earths, lime To the whole flour. deficient phosphates are the phosphates of the alkalies, in- oflfice These and of the and magnesia. secure the more important of these in the bread, with the incidental evolution of carbonic acid, it is only necessary to mix together with the flour a dry, highly acid phosphate of lime, 1 This was the case with a sample of Algerian wheat analyzed l)y Millon. It contained soluble nitrogenous compounds. Compt. Rend., XXXVIII. 12. Mayer found less terior than phosphoric acid with the sohible nitrogenous compounds of the with the gluten of the envelope. in- OF BREAD-MAKING. which is 21 phosphoric acid and neutral phosphate of lime, and dry bicarbonate of soda, in such proportions as shall leave a neutral phosphate of lime and phosphate of soda after the dough has been thoroughly kneaded and baked. Preparation of The phosphoric source of it, acid Acid. prepared from the only practicable is the bones of beef and mutton. then calcined, after which the lime by the the action of a stronger acid, is in great They are boiled, measure withdrawn and the phosphoric an acid, as exceedingly acid phosphate of lime, extracted by leaching. The extract is then concentrated by boiling, and in this condition mixed with simple farinaceous matters, dried at a low heat to render it brittle, and pulverized. When now this pulverulent acid is mixed with dry flour, and to this mixture bicarbonate of soda added in such quantity as exactly to neutralize the free phosphoric acid, and in such quantity of both acid and carbonate that the carbonic acid evolved shall give to the loaf the requisite porosity, then it remains only intimately to incorporate these in- gredients with water and a production of bread. The of flour, acid phosphate little salt, and bake, in order to the addition of the water to the mixture of lime, and carbonate of soda, and especially the application of heat, causes the phosphoric acid to decompose the carbonate of soda, with the evolution of carbonic forming cavities throughout the dough, and producing at the same time phosphate of lime and phosphate of soda. Instead of mixing the acid separately with the flour and then acid, this mixture with the bicarbonate of soda, the acid phosphate and may the bicarbonate, thoroughly dried, this condition preserved dougii arises. flour, until be mixed together, and the occasion for preparing The mixture may in the then be incorporated with the and thoroughly kneaded with an adequate quantity of cold water. Scientijic Precision in By this process, preparation Bread-making. bread-making and most of the forms of pastry- may be reduced to scientific precision. tion of cellular structure will be a thing by itself. The producOther quali- THE THEORY AND ART 22 may be added ties aromatic fluids or Sugar or as taste or fancy suggests. fruits, any or butter or eggs, all, may acids, be incor- porated in specified quantities, without interfering with the agent which is None produce cellular structure. to of the flour, derived from its starch or its of the constituents gluten, are to be sacri- ficed in order to gain porosity, as in the ordinary process of fer- mentation. This method has enabled the writer to insulate, and impart at fermented will to the loaf, the peculiar properties of the baker's By batch-bread. adding a little wine the flour containing the cell-producing water with which to the powder (the mixed pulver- ulent phosphoric acid and bicarbonate of soda, or yeast-powder) is mixed, the baked loaf acquired some of the peculiar aroma of the wine, and a certain peculiar feel of the pile (cellular structure) recognized in good fermented bread, and due to to the presence By of alcohol. trine), the adding British gum (roasted recalling this common its By property of fermented bread. sugar, the peculiar sweetness of a loaf of fermentation was recognized. baked By adding in the sugar stage adding weak vinegar, the peculiar objectionable acidity of bread made from ferment passed into the acetic fermentation was imparted to the By or dex- starch baked loaf acquired a certain leathery toughness, adding to the mixture of yeast-powder, flour, loaf. and salt, before kneading, instead of water or milk wholly, a part of good ale, there were imparted all the desired qualities of the choicest loaf of fermented bread made from This pro- brewers' yeast. — aroma and faint, agreeable bitter of the hop, in addition to the dextrine, alcohol, and sugar of the beer, and to those who relish these qualities, the cellular structure due to beer, the method leaves nothing to desire. A few experiments will satisfy any baker or cook that the qualities he covets in bread or pastry may be imparted to it with certainty upon the cess insured the — ; principle here laid down. Is Bread made hy the Let us consider whether any New Method ill Healthy ? can result to health from the use of bread containing phosphates of lime and soda. tically this question has been settled in two ways. Prac- Bread has OF BREAD-MAKING. 23 always contained phosphate of lime and phosphate of potassa (nearly allied to phosphate of soda), and the article of phosphatic bread has been in extensive use for a series of years, to the great satisfaction of those who have employed it. But it may doubt be asked, — Does the question admit of a theoretical ? Both the articles are essential constituents of healthful food. The phosphate of soda the phosphate of lime combination, present as an indispensable ingredient of every is is a normal constituent of the blood, and phosphoric acid, in some form of or important tissue of the organism. wheaten fine fulfils The bread made from flour is deficient in the phosphates, a legitimate want.^ But it may al this inquiry, the fact that this super- supply be asked, Is there provis- ion for the healthful removal of phosphates, To and if there be a surplus ? nature has provided for the remov- of portions of the osseous system, especially in cases of frac- ture, is perhaps a emphatic. sufficient answer The French army was ; but there at is another, soup-cakes prepared from bones with the aid of Papin's The cakes prepared from bones ture dio-ester. liquefied at an elevated tempersL- and under pressure, supplied phosphates beyond the normal wants of the more one time supplied with soldiers' diet; in quantity greatly but nature appropri- ated such portion of the nutriment offered as she required, and the remainder was rejected. If the digestive system can thus easily dispose of this great surplus, the task which the phosphatic bread may impose is a light one. The supei-fine wheat-flour, constitutes generally less than three quarters, ces less than one half, of the and in some wheat from which it is has according to Mayer, already cited, phosphoric acid of the original wheat. bread made from flour of the which instan- prepared, only one fifteenth of the One hundred ounces latter quality contain of about three ounces of phosphates less than the whole wheat contained. This quantity greatly exceeds the amount restored in the use of phosphatic yeast-powder. 1 See the statement of Mayer, already quoted. Mouri6s's analysis of the gluten coat, taken in connection with the correlation of the nitrogenous ingi-edients and phosphates, amply confirms the tmth of this remark. THE THEORY AND ART 24 SUMMARY. The wlieat-grain consists of an outside coat, composed of sev- eral layers, and constituting the pericarp or bran proper, which contains but httle nutritious matter; an inner envelope, the gluten, which contains most of the nitrogenous constituents and phos- and an interior mass of starch. In the ordinary method of bolting to produce superfine white phates, most of the flour, called, or first In Graham two are separated. flour, so wheaten meal, the constituents are not separated from The Pumpernickel, or sour black bread of Westmade from flour of the latter kind. It contains, as does bread made from ordinary unbolted wheat-meal, all the nutritious each other. phalia, is ingredients of the wheat. Fermented or leavened bread differs from unleavened bread former has derived a porous structure from the gases in that the evolved in the greater or less decay of some of The its constituents. by leavened or porous bread is that it permits the ready admission of the juices of the mouth and stomach employed in digestion. Without this the bread would be chief advantage possessed The unhealthfuh the starch that, object in kneading and gluten of the when bubbles appear by an elastic The thoroughly to incorporate in the dough, they and tenacious to large cavities is flour with the leaven coat, and water, so may be surrounded and not run together, giving rise and making the bread heavy. object in baking is arch over the risen dough by sudden to drying or conversion of the starch into dextrine, so as to hold up the porous interior while the surplus water exhales, without which the digesting fluids could enter but slowly starch more soluble, while the ; and also to render the albuminous portion of the gluten is coagulated. To make uniformly good fermented bread a task beset with numerous The difficulties arise partly yeast employed, and more is well known to be difficulties. from the variable still qualities of the from the influence of time and temperature upon the action of the yeast on itself and on the flour. The yeast, beside conferring the cellular structure upon dough. OF BREAD-MAKING. deteriorates the flour It frequently gluten. The smell. are not all by the greater or makes the bread 25 less disintegration of the offensive to the taste and microscopic plants which attend on fermentation Each change destroyed by baking. whether yielding dextrine, sugar, acid, or acetic acid, has its of the starch, lactic acid, alcohol and carbonic own accompanying ferment and fungus or plant. These microscopic plants or To most persons warm fungi, as a class, are poisonous. fermented bread is injurious, possibly, it has been suggested, because the vitality of some of the yeastplants has escaped the destructive action of the oven. surviving plants, whose office compounds, their In ill upon the stale bread, the These the disintegration of albuminous after imperfect digestion, effects it is maintained, produce blood. prolonged drying has perhaps deprived the larger portion of the plants, ity, is and corresponding ferments, of vital- or has permitted them to exhaust their action in converting starch into dextrine and sugar, and the latter into lactic acid, so that fermented bread when cold is less injurious. If the fungi and ferment which accompany the changes from starch trine, sugar, alcohol, injurious to and carbonic dex- to acid, are relatively but slightly most healthy organisms, it cannot be doubted that the fungi and accompanying ferment that attend upon putrefactive fermentation, which are liable to be present in fermented bread, are objectionable in the last degree.^ to Numerous attempts have been made to give cellular structure dough without the aid of ferment. The method of carbonate of soda and hydrochloric acid, — — and sour milk (lactic acid), acid or cream of tartar, — that of carbonate of potassa that of carbonate of soda that of kneading and and tartaric dough under pres- sure with water chai'ged Avith carbonic acid, have all had their 1 Dr. Lobb (London Medical Cirmilar, Vol. XVI. No. 397, p. 90) remarks, that the vitality of the yeast in the centre of a loaf of fermented batch-bread wholly destroyed. is never have found that freshly-baked fermented bread, crumbled up and mixed with flour, mashed potatoes, and water, passes into putreAxctive fermentation. The reason why warm fermented bread is not healthful to persons whose digestive powers are not in full vigor, while stale bread is less so, invites further observation and experiment. I THE THEORY AND ART 26 Although objections have arisen advocates. to all these methods, But not one of the last two have met with great acceptance. them adds a nutritive ingredient to the bread. The method of Mege-Mouries, employing the extract of bran or groats as a source of ferment, commendable, as is save the nutritious constituents of the flour ; but it it is tends to time-con- suming, and, as experiment has shown, does not seem any more certain, without equivalent care and w^atchfulness, to produce good method of brewers' yeast or sour dough. new method of raising bread, which, at proposes a The writer bread, than the ordinary the same time that it adds a nutritious ingredient, or restores a wanting constituent of nutrition confer cellular structure the bread is made light, produced in the bread, to the flour, shall incidentally on the dough ; a method by which, while phosphates of hme and to take the place in soda shall be some degree of the phosphates withdrawn from the flour with the bran, or deficient in the original wheat. This method gives to the baker the successful bread-making requires. be produced by itself, scientific precision The cellular and any other desired which may may be structure qualities by employing the necessary agent for the For example, alcohol, dextrine, sugar, and flavoring purpose. extracts may be made to produce their specific effects upon the imparted, each by itself, itself. Or they may be employed, several of Or they may be all united, and the most prized qualities of home-made bread conferred on the loaf, by replacing a part of the water required for kneading with ale. Thus the dough, each by them together. qualities imparted by dextrine, sugar, alcohol, aroma of the hop, the faint trace of pleasant acidity, and slight agreeable bitterness, which are generally so much esteemed in bread, may be given without the hazard of the offensive results that frequently attend ordinary fermentation. The principle here laid down will make the preparation of all the forms of pastry a task of moderate skill and great certainty. OF BREAD-MAKING. 27 ADVANTAGES OF THE NEW METHOD. Among new method advantages which the the bread presents, are : — of making from Its saving of the nutritious constituents of the flour 1. consumption in the process of raising the bread. 2. Its restoration of the phosphates, which are in larger or measure removed with the bran lesser in the preparation of the finer quahties of flour. 3. Its ^Yhile ordinary fermented bread in- saving of time. volves as a general thing preparation over night, care for several hours before baking, and dependence on a variable supply of leaven or yeast, the phosphatic bread for the 4. It oven in secures a uniformly excellent with the process of fermentation household production 5. is prepared from the flour a few minutes. It furnishes is is result, more frequently a bread that retains while the result of doubtful issue, and in indifferent than good. its moisture much longer than equally porous fermented bread, and does not mould as readily as fermented bread does. 6. It provides a bread, from the use of which, even of delicate digestive apparatus, none of the mented bread follow. should lose tion of its may It while with most persons it freshness, or some objectionable is be eaten by persons ills peculiar to fer- warm with impunity, necessary that fermented bread become order to the destruc- stale, in qualities, before it may be eaten with safety. 7. It is a method which, by providing agents of known and strength, reduces the measure of minimum and secures, with a very small ties ; skill quali- required to a dorrree of care moderate expenditure of time, uniformly excellent bread. and APPENDIX The in common method of making bread practised method of Mege-Mouries, and the new method, details of the Paris, the are subjoined, to enable the reader to judge of their comparative simplicity. Common Method At is taken, composed of eight kilogrammes of This kilogrammes of water. main Eight kilogrammes more and constitutes the water are then added At flour and four until six o'clock in the is left morn- leaven. of flour and four kilogrammes of forms the first quality of leaven. two o'clock in the afternoon sixteen kilogrammes of flour : this and eight of water are added At mass of paste (leaven or sour eight o'clock in the evening a dough) ing, practised in Paris. five o'clock hundred pounds of this : is the the complete leaven flour and fifty-two kilogrammes of water, mixed with from two hundred to three hundred At seven o'clock a hundred and second quality of leaven. prepared by adding a is grammes of yeast. thirty-two kilogrammes of flour and sixty-eight kilogrammes of water, holding in solution two kilo- grammes of salt, and mixed with from three hundred to six hundred grammes of yeast, are added to the leaven, and made into well-kneaded dough. With made in \st this quantity of paste Batch. above, which oven. — is five or six batches of — manner Tliis is composed of moulded and left to the following : half the rise, bread are dough prepared as and then set into the 29 APPENDIX. The bread of this baking first is sour, rather brown, and not particularly light. — The 2d Batch. dough remaining of the first batch is mixed with a hundred and thirty-two kilogrammes more of flour and sixty-eight kilogrammes of water, mixed with the same proportion of salt and yeast as the preceding batch. forms the second baking, the bread of which than the Half of this dough whiter and better is first. — The same quantity of flour, water, and salt, with 3d Batch. three hundred grammes of yeast, are again added to the dough, of which half is baked as usual. 4:tk — Same proceeding — This prepared Batch. 5th Batch. what is is as for the third. and produces like the foregoing, called fancy bread, the finest quality of any. 3fethod of Mege-Mouries. It assumed is one hundred kilogrammes of that wheaten meal have given, 1. At 72 kil. 15 " 750 grammes finest white " 750 dark groats. 11 " 500 o'clock six " bran. afternoon the in flour. take 40 litres^ (kilo- grammes) of water at 18° R. (72J^° Fahr.), add 70 gram, of pure yeast, or 700 gram, common grocer's yeast, and 100 gram, starch-sugar. if necessary, 26 the mixture is (Instead gram, of of the tartaric yeast and acid.) sugar, The must be maintained nearly set aside take, place where at the tem- perature of 18° R. 2. The next morning, at six o'clock, rated with carbonic acid. groats. 3. Stir in the the fluid will be satu- 15 kil. 750 gram, of Fermentation will commence immediately. At two o'clock in the afternoon add 30 litres of water, and pass the whole through a very fine silk or silver-wire sieve, to separate the fine bran. 4. The 70 litres Avith which the groats have been treated, after passing through the sieve, will be reduced to about bb 1 A litre of water weiglis 1,000 grammes litres, = 1 kilogramme = 2.2 lbs. avoirdupois. 30 APPENDIX. with which the 72 kih 750 gram, of white flour and 700 gram, of salt are to be kneaded into a dough. (The bran is again extracted with 30 Htres of water and extract employed in the next batch.) tlie 5. The dough 6. When I. Self-raising flour then placed in baking-pans to ferment. is raised, placed in the oven. it is Tlie is bicarbonate of soda, and With proportions. knead in sufficient New common this flour, water Method, prepared, in which the phosphoric acid, to it salt are is make a present in the required only necessary thoroughly to slightly sticky dough, The time required in covered tins, in a quick oven. and bake for a single person to prepare four loaves of a pound each, does not exceed five minutes, The II. flour and the baking takes from acid is prepared by and bicarbonate of soda been put up quantities having itself, thirty to forty-five more. and at the may be mixed with the same time ; in separate parcels, the equivalent and with them the measure for each. III. Lastly, the dry acid in equivalent quantities, is and dry bicarbonate of may be added soda, mixed to the flour directly. This The method the most convenient form for household use. plied to making a quart of flour use, is as follows : — Provide a quick oven. from 350° to 450° Fahr.] 1. 2. dry Stir [This requires a temperature of a measure^ each of acid and soda into a quart of flour, to wliich a teaspoonful of timately with the hands. from a pint cup, stirring ap- into one loaf of bread for family salt has been added. Then add from time to time cold and kneading meanwhile, sifted Mix until just in- water a pint of water has been most thoroughly incorporated with the flour. 3. Shape the mass of dough into a loaf, place it in a deep tin bake-pan, with a cover so high as to be out of the reach of the risen dough, and set it immediately in the oven. 1 The acid measure should contain 140 grains (9 grammes), and the soda measure 62 grains (4 grammes), for one pound of flour. LIBRARY OF CONGRESS 014 636 088 9 LIBRARY OF CONGRESS n 014 636 088 9
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