Unregulated Contaminant Monitoring Rule Update This Presentation • General information about UCM and why it’s done • History of the program • How the monitoring program is set up • UCMR3 Contaminants • Findings through June 2015 • UCMR4 Timeline—possible considerations • Likely UCMR4 analytes and methodology • Possible differences in UCMR4 Unregulated Contaminant Monitoring Rule (UCMR)— amendment in 1996 SDWA • • • Monitors no more than 30 contaminants per 5year cycle selected from the Contaminant Candidate List (CCL)—7500 Chemical and microbial contaminants—these substances are not regulated but are known or anticipated to occur in public water systems Monitors representative sample of public water systems (PWSs) serving less than 10,000—EPA pays for these systems. Stores all data in National Occurrence Database (NCOD) History UCMR 3 (2012-2016) – Current regulation monitoring for 30 contaminants (28 chemicals and 2 viruses) from 20122015. UCMR 2 (2007-2011) - UCMR 2 monitoring was managed by EPA and established a new set of 25 chemical contaminants sampled during 2008-2010. UCMR 1 (2001-2005) – The SDWA Amendments of 1996 redesigned the UCM program to incorporate a tiered monitoring approach and required monitoring for 25 contaminants (24 chemicals and one bacterial genus) during 2001-2003. UCM-State Rounds 1 & 2 (1988-1997) – State drinking water programs managed the original program and required public water systems (PWSs) serving more than 500 people to monitor contaminants. http://water.epa.gov/lawsregs/rulesregs/sdwa/ucmr/ UCMR Program Basics Tiered Monitoring 3 Tiers of Potential Monitoring Assessment Monitoring (AM) – List 1—commonly used analytical techniques Screening Survey (SS) – List 2—more recently developed techniques Pre-screen Testing (PST) – List 3—new or specialized techniques (no List 3 monitoring—Pre-screen Testing for UCMR 3 in Alabama) In Alabama UCMR 3 Assessment monitoring (list 1)—all systems serving more than 10,000 and selected systems serving 10,000 or fewer (19 in Alabama) There are 21 list 1 contaminants Screening Survey (list 2)—systems greater than 100,000 plus 6 selected systems in the state There are 7 list 2 contaminants These contaminants will be monitored from January 2013 through December 2015 Samples collected at EP=entry point to the distribution system and MR=distribution system sample at maximum residence time for Chlorate and metals UCMR 3: Nationwide Monitoring Timeline 2013 2014 2015 Monitoring Activities Assessment Monitoring nationwide List 1 Contaminants All systems serving more than 10,000; 800 systems serving 10,000 or fewer ~1/3 systems (~1,400) ~1/3 systems (~1,400) ~1/3 systems (~1,400) *For UCMR3 most samples were collected during the middle year Timing of Monitoring Source Type Groundwater Monitor twice Sample 5 to 7 months apart Surface water or GUDI Monitor quarterly Sample 3 months apart Hormones by EPA method 539 (List 2) 17‐B‐estradiol 17‐a‐ethynylestradiol (ethinyl estradiol) 16‐a‐hydroxyestradiol (estriol) equilin estrone testosterone 4‐androstene‐3,17‐dione VOC’s by method 524.3 Volatile Organic Compounds by EPA method 524.3 1,2,3-trichloropropane 1,3-butadiene chloromethane (methyl chloride) 1,1-dichloroethane n-propylbenzene bromomethane (methyl bromide) sec-butylbenzene chlorodifluoromethane (HCFC-22) bromochloromethane (halon 1011) Synthetic Organic Compounds by EPA method 522 1,4-dioxane by method 522 Metals by EPA method 200.8 vanadium molybdenum cobalt strontium Environmental Working Group (EWG) On December 20, 2010, the Environmental Working Group released this 24 page document. http://static.ewg.org/reports/2010/chro me6/chrome6_report_2.pdf Environmental Working Group Document (cont.) EWG selected 35 cities from 23 states to analyze drinking water for hexavalent chromium. Large cities were selected as well as cities whose water utilities reported frequent detections of total chromium. Finished water samples were collected according to the same protocol from these 35 locations and analyzed by a California laboratory using EPA method 218.6. This method had a detection limit of 0.02 ppb. The table of results (right) was taken from EWG’s website. http://static.ewg.org/reports/2010/chrome6/chrome6_report_2.pdf Oxyhalide Anion by method 300.1 http://www.purate.com/common/PurateBrochure.pdf chlorate Method 522 Perfluorinated Compounds by EPA method 537 Perfluorooctane sulfonate (PFOS) Perfluorooctanoic acid (PFOA) Perfluorononanoic acid (PFNA) Perfluorohexane sulfonic acid (PFHxS) Perfluoroheptanoic acid (PFHpA) Perfluorobutane sulfonic acid (PFBS) http://water.epa.gov/lawsregs/rulesregs/sdwa/ucmr/upload/UCMR3_D ata-Summary_June-2015_508.pdf UCMR4 Schedule June 25, 2014UCMR 4 Stakeholder Meeting and Webinar July 2015 Published UCMR 4 Proposal July 2015 through October 2015 Public Comment Final Rule Drafted beginning October 2015 ending in 2016 December 2016 Final Rule Published 2017 Implementation of Rule—Laboratory Certifications UCMR 4 monitoring tentatively starting in Jan. 2018 http://www.amwa.net/sites/default/files/UCMR4StakeholderPresentations.pdf UCMR 4 Candidates (List 1) Assessment Monitoring Metals by Method 200.8 (ICP-MS) http://www.amwa.net/sites/default/files/UCMR4StakeholderPrese ntations.pdf Germanium Manganese (CCL4 nomination) UCMR 4 Candidates (List 1) Assessment Monitoring Pesticides by Method 525.3 (GC-MS) http://www.amwa.net/sites/default/files/UCMR4StakeholderPrese ntations.pdf Disulfoton Ethoprop Alpha-Hexachlorocyclohexane trans-Permethrin cis-Permethrin Tribufos Profenofos Oxyfluorfen Vinclozolin Dimethipin (Method 530) Tebuconazole UCMR 4 Candidates (List 1) Assessment Monitoring Semi-Volatile Organic Compounds by Method 530 (GC-MS)—Method in development as of June 2014 Quinoline o-Toluidine http://www.amwa.net/sites/default/files/UCMR4StakeholderPresentatio ns.pdf Butylated hydroxyanisole Dimethipin (Method 525.3) UCMR 4 Candidates (List 1) Assessment Monitoring Pesticides by Method 538 (DAI-LC/MS/MS) http://www.amwa.net/sites/default/files/UCMR4StakeholderPresentatio ns.pdf Dicrotophos methylOxydemeton Methamidophos Acephate UCMR 4 Candidates (List 1) Assessment Monitoring Alcohols by method 541 (GC/MS)—In development as of June 2014 http://www.amwa.net/sites/default/files/UCMR4StakeholderPrese ntations.pdf 1-Butanol 2-Propen-1-ol 2-Methoxyethanol UCMR 4 Candidates (List 1) Assessment Monitoring Pharmaceuticals by method 542 (LC/MS/MS)—In development as of June 2014 http://www.amwa.net/sites/default/files/UCMR4StakeholderPrese ntations.pdf Erythromycin Triclosan (CCL4 nomination) UCMR 4 Candidates (List 1) Assessment Monitoring Carbonyl/Aldehydes by method 556.1 (Fast GC) http://www.amwa.net/sites/default/files/UCMR4StakeholderPrese ntations.pdf Formaldehyde Acetaldehyde UCMR 4 Candidates (List 2) Screening Survey Cyanotoxins by Method 544 (LC/MS/MS) Microcystin-LR Cyanotoxins by Method 545 (LC/ESI/MS/MS) Anatoxin-a Cylindrospermopsin Both methods in development as of June 2014 Applies to Surface Water and GUDI, possibly targeting summer http://www.amwa.net/sites/default/files/UCMR4StakeholderPresentatio months ns.pdf Other Contaminants under Consideration Under Evaluation—possibly list 3?: • Legionella pneumophila Other contaminants under consideration: • Nitrate/Nitrite (currently regulated) sampled in distribution—not just entry point • 4 Unregulated brominated DBPs (bromochloroacetic acid, bromodichloroacetic acid, dibromochloroacetic acid, and tribromoacetic acid, monitored at stage 2 DBPR compliance locations http://www.amwa.net/sites/default/files/UCMR4StakeholderPrese ntations.pdf Potential Changes between UCMR3 and UCMR4? • Compress the monitoring period to 2 years to make data available to help with regulatory determinations or maintain the monitoring period at three years to provide temporal coverage and accommodate lab capacity? • Asssign analytes to specific months to ensure coverage of temporal vulnerability and variability? • Year and months of monitoring assigned to small systems? • Large systems may re‐define their year and month(s) http://www.amwa.net/sites/default/files/UCMR4StakeholderPrese of monitoring? ntations.pdf EPA Contacts UCMR Sampling Coordinator: 800‐949‐1581 [email protected] To upgrade current Central Data Exchange (CDX) to access Safe Drinking Water Accession and Review System (SDWARS): [email protected] or call 888‐890‐ 1995 www.epa.gov type UCMR 3 Remember that all passwords are purged every 90 days. At that time they must be upgraded to access SDWARS.
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