10/9/2012 Mid‐Term Review 22 OCTOBER 2012 MET 5016 Physics of Atmospheres Earth’s Equilibrium Black‐ Body Temperature At the Earth’s equilibrium temperature what goes out equals what comes in. Equate the solar heating to the infrared cooling globally πA2S0(1 – α) = 4πA2σT BB4 Or , TBB4 = S0(1 – α)/4σ This expression works out to TBB = 256 K for the Earth. The average emitted (or absorbed) radiation is 239 W m‐2 But TBB is much cooler than the Earth’s average observed temperature 288 K Why? 1 10/9/2012 The Greenhouse Effect • Atmosphere transmits Solar radiation, but • Absorbs all IR (ie BB) • May be grey, ie. ε < 1. • Upward emission from an ε Upward emission from an ε = = 1 atmosphere is equal to the solar heating • Which means that net surface and back radiation must also = solar heating • So Tsfc > TBB Intensity or Radiance a r2 • Radiance is the total a mount of energy per steradian propagating in a particular direction = Iυ(υ) • Solid angle (in steradians) g ( ) dω = da/r2= sin θ dθ dφ • Spectral radiance is per steradian per unit wavelength and also has a definite direction • I.e. a laser pointer beam 2 10/9/2012 Flux or Irradiance • Integrate all the radiances over a hemisphere above or below the surface. Fv I v ( , ) cos d , and hemisphere F Fv d • Irradiance is more useful • Can be spectral Plank’s Law Peak emission at λmax (μm) = 2897/T B (T ) 2hc 2 5 1 e hc / kT 1 Total emission (area under the curve) E = σT4 One‐Layer Black Atmosphere • Atmosphere is transparent to visible light and opaque to IR • Same surface Albedo and Solar Irradiance as before Surface heat balance: FSOL T04 T14 Atmosphere heat balance 0 T04 2 T14 The only radiation emitted from the planet as a whole is that from the top of the atmosphere, so 4 FSOL TBB T14 3 10/9/2012 Calculating the Surface Temperature • From the last relation, it is clear that the atmosphere must be at TBB = 255K, the blackbody temperature of the Earth‐Atmosphere system • It radiates the same amount of IR upward and downward. • From the energy balance for the Atmosphere: T04 2 T14 , or T0 4 2TBB 1.19255 K 305 K 31 C • Which is also consistent with the Surface energy balance. Vertical Profiles of Upwelling and Downwelling Radiation and of Blackbody Radiation in a Grey Atmosphere Black and Grey Bodies FBB T 4 FG T 4 Emissivity = ε = ratio of actual to blackbody < 1 4 10/9/2012 Static Stability How the Sounding Lets Us Predict Convective Clouds Global Radiative Balance 5 10/9/2012 Annual Mean Solar, IR & NET Radiation as a Function of Latitude Jeans Escape • H comes from photodissociation of H2O and CH4 • H2O vapor pressure at the tropopause is limited by cold temperatures • This COLD TRAP limits the Thi COLD TRAP li i h whole process • CH4 is a minor constituent • Upward eddy, then molecular diffusion • Final escape in Exosphere where mean free path > H • But only for atomic hydrogen on the tail of the Boltzmann Distribution 6 10/9/2012 I k ( z ) I k 0e z / H I , z cos cos Chapman Layer Integrating I k H 0e z / H ln I const., cos ρ As altitude approaches pp infinity, y, I I0 I - dI ln I 0 const. Eliminating the constant of integration and exponentiating k H 0e z / H I I 0 exp cos Sidney Chapman Chapman layers are also good models for spectral beam absorption in the ionosphere Beam essentially y constant,, absorption p increasing as density does z = H ln (kαHρ0)/cos θ Beam attenuation Ozone Photochemistry • Total Ozone measured in Dobson Units – 0.01 mm of gas at STP • Oxygen photodissociation: – O2 + hν 2O (J2, λ < 0.246 μ m) • Ozone formation: – O2 + O + M O3 + M ( k2) • Atomic Oxygen recombination: Atomic Oxygen recombination: G.M.B. Dobson – O + O + M O2 + M ( k1, SLOW) • Ozone recombination: – O3 + O 2O2 (k3) • Ozone photodissociation: – O3 + hν O2 + O (J3, λ < 0.310, 1.140 μ m) • Red equations recycle Odd Oxygen, blue equations convert it to molecular oxygen 7 10/9/2012 Brewer‐Dobson Circulation Strongest in winter hemisphere 8
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