Material Safety Data Sheet
Issue date: 2007-12-12
Revised date:2007-12-12
Page 1 of 5
MSDS S009-01-GB
Printout date: 2017-07-13
PRODUCT: ACRYLIC BATHTUBS SILICONE TYTAN PROFESSIONAL
Material Safety Data Sheet
(according to Directive 91/155/EC with further changes)
1.
Company and product identification
Product type:
Product description:
TYTAN INDUSTRY SILICONE
Supplier:
Selena Co. S.A.
Ul. Strzegomska 2-4
53-611 Wrocław, Poland
+48 (071) 78 38 290
+48 (061) 847 20 81 (toxicological information)
Phone number:
Emergency phone number:
2.
Composition/information on ingredients
Annex I Index
1.
Mixture of trimethoxysilanes, builders and
crosslinking agents
Ingredient name
Content
by weight
%
EC No
CAS No
-
trimethoxyvinylsilane
 5,0%
220-449-8
2768-02-7
2.
-
3-aminopropyl(methyl)
silsesquioxane,
ethoxy-termineret
 5,0%
-
128446-60-6
3.
-
trimethoxy(methyl)silane
 5,0%
214-685-0
1185-55-3
649-221-00-X
distillates (petroleum),
hydro-treated middle
 20%
265-148-2
64742-46-7
4.
Hazard classification
[Xn]; R10-20
[Xi]; R10-36/38
[F]; R11
[Xi] R38
[T]; R45
[F]; [T]; R11-23/24/2539/23/24/25
* hazard classification assigned on the basis of toxicity data (publications), this chemical substance is not classified in the
Annex I of Directive 67/548/EEC
** The classification as a carcinogen need not apply if the full refining history is known and it can be shown that the substance
from which it is produced is not a carcinogen (Note N).
methanol
3.
 1%
200-659-6
67-56-1
Hazard identification
ATTENTION! The vapours are generated by the curing process of silicone. Additionally the product
may cause sensitisation.
Exposed places:
Skin, eyes, inhalation.
Main exposure:
Agent irritating eyes and mucous membrane.
4.
Symptoms
Vapours may irritate nose and upper airways.
May cause local irritation, reddening, swelling.
Vapours may irritate eyes. For its adhesive feature, the silicone
contact with eyes may cause their physical damage.
Ingestion:
The silicone swallowing may cause digestive discomfort, could be
harmful.
The medical conditions, that may deteriorate through the contact with product: not known.
Action
Inhalation:
Transfer patient out to the fresh air place, free of exposure. If
necessary seek medical advice.
Skin contact:
Cured silicone may be removed by washing using soap and large
Inhalation:
Skin contact:
Eyes contact:
Selena Co. S.A. 53 611 Wrocław ul. Strzegomska 2-4Poland
Tel. +48 71 783 82 90 Fax. +48 71 783 82 91 e-mail:[email protected] www.selena.pl
Material Safety Data Sheet
Issue date: 2007-12-12
Revised date:2007-12-12
Page 2 of 5
MSDS S009-01-GB
Printout date: 2017-07-13
PRODUCT: ACRYLIC BATHTUBS SILICONE TYTAN PROFESSIONAL
Eyes contact:
Ingestion:
Caution:
5.
Fire-fighting measures
Respective extinguishing
measures:
Special fire hazard when
product is exposed during the
fire:
Special safety equipment used
in case of fire:
Other instructions:
6.
Natural environment protective
measures :
Cleaning methods:
Others:
Fire-fighters should wear self contained breathing apparatus in
addition to protective clothing. Be cautious using extinguishing
devices. Apply face guarding and respiratory mask.
-
Wear proper personal protective suit, used face guard. Avoid
contact with skin and eyes. Avoid vapours inhalation.
Avoid release to sewage systems, superficial and earth waters.
Absorb mechanically and dispose of according to regulations.
Cured product may be removing mechanically. When silicone is
uncured may be removed by concentrated cloth with ethyl alcohol.
Not applicable
Handling and storage
Handling:
Avoid contact with skin and eyes. Use only in adequate ventilated
area. Remove contact lenses before using sealant. Do not handle
lenses until all sealant has been cleaned from the fingertips, nails
and cuticles. Keep away from children.
Keep container tightly closed and store in well ventilated, dry and
protected against moisture and from freezing storage place. Store
in temperature not higher than 25oC keep away from strong
oxidizing compounds.
Storage:
8.
All standard fire-fighting media: dry chemical extinguisher, alcoholresistance foam, CO2 , water stream, sand.
During combustion is generating carbon dioxide, nitrogen oxide,
dioxide silicon, calcium dioxide.
Accidental release measures
Personal preventive measures:
7.
water quantity. If irritation develops, you will apply delicate cream.
Bath eye immediately with a lot of water for at least 15 minutes.
Contact for medical aid immediately.
Contact for medical aid immediately.
In case of accident or if you feel unwell, necessary seek medical
advice immediately (show the label if it will be possible).
Exposure control / personal protection
Exposure standards:
STEL - short term exposure limit (15 min exp. Limit)
trimethoxyvinylsilane
No available
3-aminopropyl(methyl)
silsesquioxane,
ethoxy-termineret
methanol
No available
250 ppm
distillates (petroleum), hydro- 10 mg/m3
treated middle
TWA - time-weighted average (8 hr exp. Limit)
trimethoxyvinylsilane
5 ppm
Selena Co. S.A. 53 611 Wrocław ul. Strzegomska 2-4Poland
Tel. +48 71 783 82 90 Fax. +48 71 783 82 91 e-mail:[email protected] www.selena.pl
Material Safety Data Sheet
Issue date: 2007-12-12
Revised date:2007-12-12
Page 3 of 5
MSDS S009-01-GB
Printout date: 2017-07-13
PRODUCT: ACRYLIC BATHTUBS SILICONE TYTAN PROFESSIONAL
Engineering measures:
Respiration protection:
Skin protection:
Eyes protection:
Ingestion:
9.
Physical and chemical properties
Physical state:
Colour:
Odour:
pH:
Boiling point temperature:
Melting point temperature:
Flash point temperature:
Auto flammability:
Explosion limits (propellant):
a) lower
b) upper
Vapour pressure:
Vapour density (air=1):
Specific gravity:
Water solubility:
Coefficient partition:
(n-octane / water)
Viscosity:
Volatile Organic Compounds:
(VOCs)
Other information:
10.
Paste
Transparent, white, grey, black, brown
Characteristic smell
None applicable
None applicable
None applicable
> 400 ºC
None applicable
Not explosive
12,3 kPa at 20OC (methanol)
1,01 (air-mixture at 20OC) (methanol)
1,01 g/cm3 at 200C
Insoluble
None applicable
No data available
No available
None
Stability and reactivity
Stability:
Conditions to be avoided:
Substances to be avoided:
Dangerous decomposition
products:
11.
3-aminopropyl(methyl)
No available
silsesquioxane,
ethoxy-termineret
methanol
200 ppm
distillates (petroleum), hydro- 5 mg/m3
treated middle
Ensure there is sufficient ventilation of the area.
Respiration protection must be applied rooms. In case of long term
staying in such a in poorly ventilated rooms, the compressed air
respiration mask should be applied.
Wear proper personal protective suit
Use the protective glasses.
Using the sealant you should not eat, not drink, no smoke. Wash
your hands and face every time after the work with chemical
substances.
Product chemically stable when is used in accordance with
instruction.
Stable in normal storing conditions. Avoid moisture.
Paste loading reacts with water. Avoid oxidizing agents.
Polymerisation may occur at elevated temperatures in the
presence of moisture.
Paste loading –In case of fire is possible formation of toxic gases
as: carbon monoxide, carbon dioxide, nitrogen oxides and other
substances product during decomposition
Toxicological information
Acute toxicity:
Methanol - Oral rat LD50: 5628 mg/kg
Selena Co. S.A. 53 611 Wrocław ul. Strzegomska 2-4Poland
Tel. +48 71 783 82 90 Fax. +48 71 783 82 91 e-mail:[email protected] www.selena.pl
Material Safety Data Sheet
Issue date: 2007-12-12
Revised date:2007-12-12
Page 4 of 5
MSDS S009-01-GB
Printout date: 2017-07-13
PRODUCT: ACRYLIC BATHTUBS SILICONE TYTAN PROFESSIONAL
Skin contact:
Eye contact:
Inhalation:
Irritating action:
Allergies:
Additional toxicological
information:
12.
Ecological information
Mobility:
Biodegradation:
Chemical degradation:
Bioaccumulation:
Agility:
Toxicity influence on
organisms:
Toxicity in water:
Other toxicity:
13.
Can irritate on prolonged or repeated contact. Methanol - Irritation
data-standard Draize test: skin, rabbit: 20mg/24 hr.
Vapours released during curing may cause eye irritation.
Methanol - Moderate; eye, rabbit: 100 mg/24 hr.
Methanol - rat LC50: 64000 ppm/4H
Vapours released when curing process may cause eye irritation.
Prolonged contact with skin may cause an allergic reaction.
Methanol - Investigated as a mutagen, reproductive effector.
No data available
Not biodegradable
No data available
No data available
No data available
No data available
No data available
No data available
Disposal consideration
Waste code number:
Cured product
080404
Uncured product
080402
Package
150102
The user’s attention is drawn to the possible existence of regional or national regulations regarding
disposal.
Product may be disposed of as normal waste. Do not allow product to reach ground water, water
courses or sewage systems.
14.
Transport information
Land transport:
ADR/RID
Warning board:
Marking not required
Sea transport:
IMDG: 2
Marking not required
Technical name:
Air transport:
ICAO/IATA
Technical name:
15.
Marking not required
Regulatory information
The product is labelled and described at the document according to European Union directives:
67/548/EEC; 91/155/EEC; 2001/60/EC; 2001/59/EC; 2001/58/EC; 2000/33/EC; 1999/45/EC
Precautionary phrases:
Not required
Symbols:
Not required
Hazardous ingredients:
Not required
Selena Co. S.A. 53 611 Wrocław ul. Strzegomska 2-4Poland
Tel. +48 71 783 82 90 Fax. +48 71 783 82 91 e-mail:[email protected] www.selena.pl
Material Safety Data Sheet
Issue date: 2007-12-12
Revised date:2007-12-12
Page 5 of 5
MSDS S009-01-GB
Printout date: 2017-07-13
PRODUCT: ACRYLIC BATHTUBS SILICONE TYTAN PROFESSIONAL
Risk phrases:
Safety phrases:
Air emission directive:
VbF:
Water hazard class:
16.
Not required
S2 Keep out of the reach of children
S23 Do not breathe vapour
S24/25 Avoid contact with skin and eyes
S36/37 Wear suitable protective clothing and gloves
S51 Use only in well ventilated areas.
Class:
None applicable
Item No:
None applicable
Amount m%:
None applicable
A III
WGK 1 (KBwS)
Other information
Risk phrases:
Safety phrases:
R10 Flammable
R11 Highly flammable.
R20 Harmful by inhalation.
R38 Irritating to skin.
R65 Harmful: may cause lung damage if swallowed.
R36/38 Irritating to eyes and skin.
None
See the product label and information about application placed on
Purpose of product:
High quality neutral curing silicone sealant especially
recommended for mildew resistant sealing of acrylic bath, shower
cabins, sinks, plumbing fixtures, sealing of water supply, PVC
pipes and for other sealing applications where mildew resistance
is required. It has excellent adhesion to acrylic surfaces, glass,
glazing substrates, ceramic tiles or PVC.
Directions of use :
Clean, degrease and dry the surface. Mask areas adjacent to the
joints with a masking tape. Apply the material with sufficient
pressure to the joint sides to ensure immediate adhesion. Smooth
immediately with a wet spatula, jointer or finger. Remove masking
tape after smoothing.
Contents of present card is compatible with EN ISO 11014-1 format
All information, recommendation or advice contained in this document or given by Selena Co. SA or
any of its subsidiaries, affiliates or authorised representatives, whether written or oral, is given in good
faith, to the best of its knowledge and based on current procedure in effect. Each user of the product
shall convince himself, through all available sources (including finished product testing in its
appropriate environment) of the suitability of the product supplied for its own particular purpose.
Selena Co. SA, its subsidiaries and affiliates cannot be held responsible for any loss incurred through
incorrect or faulty use of the product. The Material Safety Data Sheet related excessively to the
described product. In case of applying it as a component of the other product, the MSDS is no more
valid.
Selena Co. S.A. 53 611 Wrocław ul. Strzegomska 2-4Poland
Tel. +48 71 783 82 90 Fax. +48 71 783 82 91 e-mail:[email protected] www.selena.pl