Crystal Field Theory Molecular Orbital Theory: Donor- Acceptor Interactions Molecular Orbital Theory: Full ML6 Molecular Orbital Theory: Simplified Counting d-electron Configurations Counting d-electron Configurations How do we predict/explain transition metal structures? Colors and Spectroscopy of Transition Metal Complexes Sigma Interaction Strength Spectrochemical Series: I- < Br - < Cl- , F- < OH- < OH2 < NH3 < en < CN- < CO Pi Donor Ligands: Mainly oxides and halides Mn2+(aq) MnO 4 - Pi Acceptor Ligands: CO, CN-, pyridine Pi Acceptor Ligands and spectroscopy: CO, CN-, pyridine
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