Julie Levine January 25, 2012 The Mystery of the Missing Chocolate Chip Cookies/ Harry Potter Mystery Teacher’s Kit Time: 40 minutes Age: 10-14 **Use the chocolate chip cookie mystery for younger students and the Harry Potter mystery for older students. **Depending on the age of the students, the clues in the beginning can be made to point to two of the children rather than just one. This will make the mystery slightly more challenging. This lesson can also be made more difficult by including more suspects or adding more clues. **Students will use a chart to cross off suspects and determine who is guilty. I am providing two “mysteries” involving the same experiments and learning goals. Version 1: The Mystery of the Mission Chocolate Chip Cookies Three triplet brothers were all eating lunch in their kitchen. Their mom had made all three of them the same peanut butter and jelly sandwiches and given them the same Mentos candies for dessert. However, she had given each boy his favorite drink. Mark likes Kool-Aid, Walter likes Coca-ColaTM, and Sean likes bubbly water. The boys were troublemakers, and after eating their sandwiches, they began throwing their Mentos candies at each other. The Mentos ended up inside each of the boys’ cups. After the boys left the kitchen, their mom found out that one of them had stolen all of the cookies from the cookie jar! Use the following clues and experiments to determine who stole the cookies from the cookie jar. 1) Clue 1: Right next to the cookie jar was a big foamy puddle. Students will use an experiment (dropping Mentos candies into Kool-Aid,CocaColaTM, and seltzer/bubbly water to determine which boy’s or boys’ drink would create a foamy mess when a Mentos candy was dropped into it. Only the carbonated drink (the Coca-Cola or seltzer water) will create a foamy explosion. The Coca-ColaTM has sugar in it, which will create an even larger foam explosion. This evidence should incriminate Sean and Walter. 1 **Maine Learning Results: Inquiry and Problem Solving, Scientific Reasoning, Communication **This can be used to teach energy. The teacher could add to the worksheet questions about potential energy and kinetic energy. The Mentos and Coca-ColaTM have potential energy before they are placed together. Once they are added together, then the energy becomes kinetic as the reaction occurs. **Chemical vs. Physical reactions can also be discussed in relation to this experiment. 2) Clue 2: The boys’ mom noticed that one of her identical sons stayed behind after the two other boys left and enjoyed a bowl of cereal after their sandwich. The mom could not tell which one of the boys it was, but she did tell us her sons’ favorite cereals. Sean likes Total and Walter and Mark both like Fruit Loops. We have the cereal bowl that the boys left behind. Students will use an experiment to determine the iron level of the cereal in the bowl that was left behind as well as the iron levels of the boys’ favorite cereals. The iron level of Total should be much higher than the Fruit Loops, and Sean whose favorite cereal is Total should again look suspicious. ** Maine Learning Results: Inquiry and Problem Solving, Scientific Reasoning, Communication 3) Clue 3: A piece of shoelace was found on a nail on the floor next to the cookie jar. The way the fabric is dyed looks a certain way. All 3 boys were wearing shoes with blue shoelaces made of different materials. The students will dye the different “shoe laces” (yarn) blue with cool-aid. The students will then compare the dyed blue shoelaces with the one found to determine the thief. This evidence should point towards Sean. **Maine Learning Results: Inquiry and Problem Solving, Scientific Reasoning, Communication 4) Clue 4: The three brothers also like to write secret messages to each other on gold paper (goldenrod color changing paper) that their mother has seen them spray with blue liquid to reveal secret messages. One message must have fallen out because one seemingly blank gold paper was found on the floor near the cookie jar. Use an experiment to determine what the paper says. Use window cleaner to spray the paper and reveal the message. 2 The message should reveal a note from Mark to Sean: “Dear Sean, I don’t think you should steal the cookies! Mom will be mad! Love, Mark” This evidence should again point towards Sean. ** Maine Learning Results: Inquiry and Problem Solving, Scientific Reasoning, Communication Materials Needed: 1. 2. 3. 4. 5. 6. 7. 8. 9. Kool-Aid mix water Coca-ColaTM/seltzer cups for Mentos reactions bins to keep cups in Mentos Fruit Loops Total Cereal beakers (50 or 100 mL) (this can be replaced with small Dixie cups. The students can be told to fill the Dixie cups half way with cereal and to the top with water) 10. Magnetic wand 11. Magnifying glass 12. Method of crushing cereal (Plastic baggies and filled soda bottles) 13. Goldenrod color changing paper 14. Golden crayon 15. Window cleaner 16. 3 different types of white yarn that look fairly similar (stapled/taped to an index card and labeled by their owners) 17. Cups for dipping yarn into 18. Stirrer/plastic spoon 19. Paper towels Preparations (20-25 Minutes): Experiment 1: Have 3 cups set up inside a plastic bin, one with Kool-Aid, one with seltzer, and one with Coca-ColaTM. For each of the three cups, give the students six Mentos (they will put two Mentos in each cup and watch the reaction). Experiment 2: Have the two types of cereal at this station along with a 50 mL beaker or a Dixie cup and larger cup. Have the plastic bags and filled soda bottles available for crushing the cereal. Have the magnetic wands available as well. Experiment 3: Have a cup filled with water as well as Kool-Aid mix and a stirrer. Staple or tape the evidence yarn onto an index card and write evidence on the card. 3 Staple or tape the 3 types of yarn to another index card and label the yarn with the boys’ names. Sean’s shoelace should be the same as the sample. Experiment 4: For this experiment, write, “Dear Sean, I don’t think you should steal the cookies! Mom will be mad! Love, Mark” on goldenrod color changing paper. Have a window cleaner spray bottle available for the students to reveal the message. Version 2: Help Harry find who stole his Invisibility Cloak! Harry Potter, Hermione Granger, Ron Weasley, Draco Malfoy, Neville Longbottom and Luna Lovegood all enjoyed their dinner feast in the Great Hall together after Harry returned from a long and dangerous journey with Hagrid. However, after dinner, Harry realized that his invisibility cloak was missing! He decided to return to the Great Hall to see if he could find any clues that would help him determine who had stolen his cloak of invisibility. Can you help Harry use the clues he finds to determine who the thief is? 1) Clue 1: Right next to where Harry had left the cloak was a big foamy puddle. The Hogwarts house elves had made everyone the same roast beef sandwich and gave everyone the same Mentos candy for dessert. However, they had given each witch and wizard their favorite drink. Ron likes slug juice, Hermione likes salamander eye juice, and Luna likes dog saliva. This was a very happy evening at Hogwarts, and after eating their sandwiches they began playfully throwing their Mentos candies at each other. The Mentos ended up inside each of the students’ cups. Students will use an experiment to determine which drink would cause a foamy puddle to form when a Mentos candy is dropped into it. This will be the first clue to see who was near the cloak. Only the carbonated drink (the Coca-ColaTM or seltzer water) will create a foamy explosion. This clue will point to Hermione and Luna. **Maine Learning Results: Inquiry and Problem Solving, Scientific Reasoning, Communication **This can be used to teach energy. The teacher could add to the worksheet questions about potential energy and kinetic energy. The Mentos and Coca-ColaTM have potential energy before they are placed together. Once they are added together, then the energy becomes kinetic as the reaction occurs. 2) Clue 2: Near the cloak, Harry also found a bowl of kidney pudding. Ron likes his kidney pudding plain and Luna and Hermione like to add beetle bits to theirs. We have the bowl that was left near the cloak. 4 Use an experiment to determine if there are beetle bits in the bowl that was left behind. Students will crush the Total cereal that is labeled “Kidney Pudding” and soak it in water. They will use the magnetic wands to discover the “beetle bits” which are actually metallic iron in the cereal. This clue will point toward Hermione and Luna. ** Maine Learning Results: Inquiry and Problem Solving, Scientific Reasoning, Communication 3) Clue 3: The cloak thread of the witch or wizard who stole the cloak got stuck on a nail near where the cloak was hanging. However, Harry tripped when he found this clue and spilled his blue drink on the thread. We have samples of the cloak threads that everyone was wearing. Dye the samples blue to determine whose cloak the thread came from. Students will use Kool-Aid to dye the yarn blue. Ron and Hermione will have the same yarn as the evidence yarn. This clue will point to Ron and Hermione. **Maine Learning Results: Inquiry and Problem Solving, Scientific Reasoning, Communication 4) Clue 4: The magic world of Hogwarts also involves many secret messages. One message must have fallen out of the thief’s pocket because a seemingly blank gold paper was found on the floor near where the cloak was stolen. Students will use an experiment to determine what the paper says. The secret message will read, “Hermione, Did you get the invisibility cloak so that we can spy on Professor Snape?” This final clue will be the last piece of evidence used to incriminate Hermione. This can be used to explain acid-base indicators. The goldenrod color changing paper is made of a base indicator, and window cleaner is a base. The paper is protected where the wax from the crayon covers the paper but turns red everywhere else when sprayed with a basic solution. ** Maine Learning Results: Inquiry and Problem Solving, Scientific Reasoning, Communication Materials Needed: 1. Kool-Aid mix 2. Water 3. Coca-ColaTM 5 4. 5. 6. 7. 8. 9. Seltzer Cups for Mentos reactions Bins to keep cups in Mentos Total Cereal Beakers (50 or 100 mL) (this can be replaced with small Dixie cups. The students can be told to fill the Dixie cups with cereal and to the top with water) 10. Magnetic wand 11. Magnifying glass 12. Method of crushing cereal (sealable baggies and filled soda bottles) 13. Goldenrod color changing paper 14. Gold crayon 15. Window cleaner 16. 2 different types of white yarn that look fairly similar (stapled/taped to an index card and labeled by their owners) 17. Cups or bowls for dipping yarn into 18. Stirrer/plastic spoon 19. Paper towels Preparation (20-25 minutes): Experiment 1: Have 3 cups set up inside a plastic bin, one with Kool-Aid, one with seltzer, and one with Coca-ColaTM. The cups should be labeled: Liquid Kool-Aid Coca-ColaTM bubbly water/seltzer water Label Slug Juice Salamander Eye Juice Dog Saliva For the three cups, give the students six Mentos (they put two in each cup and watch the reaction). Experiment 2: Have the Total cereal labeled as “Kidney Soup.” For each group, have a plastic bag and a soda bottle filled with water available for crushing the cereal. Have the magnetic wands available as well. Dixie Cups or beakers should be here so that the students can measure the water and cereal. A larger cup for combining the cereal is also necessary. Experiment 3: Have a cup filled with water and Kool-Aid mix to stir in. Have stirrers available. Staple or tape the evidence yarn onto an index card and write evidence on the card. Staple at least 2 or 3 different types of yarn to another index card and label the yarn with the characters’ names. Hermione’s yarn should be the same as the evidence. 6 Experiment 4: For this experiment, write “Dear Hermione, Did you get the Invisibility Cloak so that we can spy on Snape?” on goldenrod color changing paper. Have a window spray bottle available for the students to reveal the message. This will be the last piece of evidence to incriminate Hermione. Science Behind the Clues: 1. The Mentos candies act as a catalyst for the carbon dioxide present in carbonated drinks to be released into the air. This is why only the carbonated drinks create the foamy reaction. 2. Total cereal is a cereal rich in iron. Once the cereal is crushed and soaked in water, the iron is released, and the magnetic wand can pick up the pieces of iron. The Fruit Loops are not an iron rich cereal, so the magnet will not pick up any metal. 3. The different threads are made of different materials, and each material absorbs dye differently. For example, acrylic material repels more dye than wool material. 4. This secret message is written on goldenrod color changing paper, which is made of an acid and base indicator with a gold crayon. Where the gold crayon wrote on the paper, the paper is protected from the window cleaner. The window cleaner is basic, so when it is sprayed, the paper turns to bright red except where the note was written, revealing the message. Learning Objectives: 1. This experiment involves combining multiple pieces of evidence to form a conclusion. Deductive reasoning can be taught in this experiment. 2. Using scientific evidence rather than previous biases can be discussed in relation to this experiment (especially the Harry Potter version). Many students initially assume that Draco Malfoy stole the invisibility cloak because he is the “bad guy,” but scientific evidence points to a different suspect. 3. The characteristics of metals can be discussed in terms of the iron being attracted to the magnet. 4. Different types of energy (potential and kinetic) can be discussed in reference to the experiment with the Mentos and different liquids as well as physical and chemical changes. 5. Properties of different materials can be discussed in terms of how different fabrics dye. 6. Acid and base red-ox reactions can be discussed with the goldenrod paper as well as indicators and color changes. 7 Clean Up (10 minutes): The cups and bins from the Mentos reaction can be rinsed out and re-used. The Mentos and liquids should be disposed of, as they cannot be reused for this experiment. The Magnetic Wands and cups used for the second experiment will need to be rinsed. The bottles and bags used for crushing can be reused if they were not damaged. The index cards with the dyed yarn cannot be re-used, and the cup used to dye the yarn will need to be rinsed. The table where the goldenrod paper was sprayed will need to be wiped down. The paper can be reused for the same experiment once it dries. References: Potential and Kinetic Energy, http://www.energyeducation.tx.gov/energy/section_1/topics/potential_and_kineti c_energy/index.html , January 6, 2012. Goldenrod color changing paper can be ordered from Flinn Scientific Inc. 8 Student Worksheet- Version 1 Name_____________________________________________________ The Mystery of the Missing Chocolate Chip Cookies Three triplet brothers were all eating lunch in their kitchen. Their mom had made all three of them the same peanut butter and jelly sandwiches and given them the same Mentos candy for dessert. However, she had given each boy his favorite drink. Mark likes Kool-Aid, Walter likes Coca-ColaTM, and Sean likes bubbly water. The boys were troublemakers, and after eating their sandwiches, they began throwing their Mentos candies at each other. The Mentos ended up inside each of the boys’ cups. After the boys left the kitchen, their mom found out that one of them had stolen all of the cookies from the cookie jar! Use the following clues and experiments to determine who stole the cookies from the cookie jar. 5) Clue 1: Right next to the cookie jar was a big foamy puddle. Use an experiment to determine which boy’s drink would cause a foamy puddle to form when a Mentos candy is dropped into it. Directions: Drop two Mentos candies into each of the three drinks, and fill in the chart as to whether you see a foamy reaction. Boy Favorite Drink Mark Walter Kool-Aid Coca-Cola Sean Bubbly Water Foaming Reaction? 9 Write/ explain which boy or boys this evidence you find points to. ________________________________________________________________________ ________________________________________________________________________ ________________________________________________________________________ This experiment demonstrated two different types of energy. Potential energy is stored energy. Kinetic energy is energy in motion. The Mentos and Coca-ColaTM each have potential energy at one point and kinetic energy at one point during the reaction. Explain when during the experiment the energy is transformed. ________________________________________________________________________ ________________________________________________________________________ ________________________________________________________________________ 6) Clue 2: The boys’ mom noticed that one of her identical sons stayed behind after the two other boys left and enjoyed a bowl of cereal after his sandwich. While he was alone in the kitchen, the boys’ mom believes he took the cookies. The mom could not tell which one of the boys it was, but she did tell us her sons’ favorite cereals. Sean and Mark like Total cereal and Walter likes Fruit Loops cereal. We have the cereal bowl that the boy who stayed behind left in the kitchen. The three boys are all lactose intolerant (which means they can not drink milk because their body can not digest it), so they all eat their cereal with water rather than milk. Use an experiment to determine the iron level of the bowl that was left behind as well as the iron levels of the boys’ favorite cereals. You can use these results to determine which cereal was the one left behind and which boy it belonged to. Directions: Pour 20 mL of each cereal into separate bags, so you have one bag with Total and one bag with Fruit Loops. Seal the bags trying to get all of the air out. Crush the cereals using your bottle filled with water. Measure 50 mL of water with a beaker and pour the cereal into the beaker with the water. Allow the cereal to soak in water for 5 minutes, stirring the whole time. During this time you should discuss who you think the thief will be. After 5 minutes, use a magnetic wand and swirl it through the cereal and water mixture; you will pick up iron on the wand if there is any in the cereal. This is because iron is a metal, which is attracted to the magnet (similar to why magnets stick to a metal refrigerator). Use a magnifying glass to compare the levels of iron (black specs on the magnet) in the bowl that was left by the cookie jar with the levels of iron in the boys’ favorite cereals. This will help you determine which boy the cereal bowl belonged to. Which of the two cereals have similar to or the same amount of iron as the mystery bowl? What can you conclude about the mystery bowl? What cereal is it? Who did it belong to? 10 Boy Favorite Cereal Sean and Mark Total Walter Fruit Loops Mystery Bowl Type of Cereal? Iron Present? Write/ explain who this evidence points to. ________________________________________________________________________ ________________________________________________________________________ ________________________________________________________________________ 7) Clue 3: The shoelace of the boy who stole the cookies got stuck on a nail in the kitchen. We have samples of the laces that each boy was wearing. Dye the samples blue to determine whose shoelace was found at the scene of the crime. Directions: Mix together 100 mL of water and 1 packet of cool-aid in the beaker provided. Then dip all of the strings into the cool-aid mixture one at a time for 10 seconds each. Pull the strings out, place them onto a paper towel, and determine which sample the shoelace found looks the most similar to. Write/ explain which boy this evidence you find points to. __________________________________________________________ __________________________________________________________ __________________________________________________________ 8) Clue 4: The three brothers also like to write secret messages to each other on gold paper that their mother has seen them spray with window cleaner to reveal secret messages. One message must have fallen out of one of the brothers’ pockets because a seemingly blank gold paper was found on the floor near the cookie jar. Use an experiment to determine what the paper says. Directions: Use window cleaner to spray the paper and reveal the message. 11 What does the message say? __________________________________________________________ __________________________________________________________ CONCLUSION: Based on all of your evidence, who do you think stole the cookies? __________________________________________________________ __________________________________________________________ 12 Directions: As a suspect is ruled out, put an x in that box. Boy Clue 1 Clue 2 Clue 3 Clue 4 Sean Mark Walter 13 Student Worksheet- Version 2 Name_____________________________________________________ Help Harry find who stole his Invisibility Cloak! Harry Potter, Hermione Granger, Ron Weasley, Draco Malfoy, Neville Longbottom, and Luna Lovegood all enjoyed their dinner feast in the Great Hall together after Harry returned from a long and dangerous journey with Hagrid. However, after dinner, Harry realized that his invisibility cloak was missing! He decided to return to the Great Hall to see if he could find any clues that would help him determine who had stolen his cloak of invisibility. Can you help Harry use the clues he finds to determine who the thief is? 9) Clue 1: Right next to where Harry had left the cloak was a big foamy puddle. The Hogwarts house elves had made everyone the same roast beef sandwich and given everyone the same Mentos candy for dessert. However, they had given each witch and wizard their favorite drink. Ron likes slug juice, Hermione likes salamander eye juice, and Luna likes dog saliva. This was a very happy evening at Hogwarts, and after eating their sandwiches they began playfully throwing their Mentos candies at each other. The Mentos ended up inside each of the students’ cups. Use an experiment to determine which drink would cause a foamy puddle to form when a Mentos candy is dropped into it. This will be the first clue to see who could have stolen the cloak. Directions: Drop two Mentos candies into each of the three drinks. Fill in the chart as to whether you see a foamy reaction. Character Favorite Drink Ron Hermione and Draco Malfoy Luna and Neville Slug juice Salamander eye juice Foaming Reaction? Dog Saliva 14 Write/ explain which student or students this evidence you find points to or who you can rule out as a suspect based on this evidence. ________________________________________________________________________ ________________________________________________________________________ ________________________________________________________________________ This experiment demonstrated two different types of energy. Potential energy is stored energy. Kinetic energy is energy in motion. Explain if and when during the experiment the energies were present and when the energy was transformed. Slug Juice _____________________________________________________________ Salamander Eye Juice________________________________________________ Dog Saliva____________________________________________________________ 10) Clue 2: Near the cloak, Harry also found a bowl of kidney pudding. Ron likes his kidney pudding plain and Luna and Hermione like to add beetle bits to theirs. We have the bowl that was left near the cloak. Use an experiment to determine if there are beetle bits in the bowl that was left behind. Directions: In order to see if there are beetle bits in the pudding left behind, we have to soak the pudding in water. Pour ½ of a Dixie cup of the pudding into a plastic bag. Seal the bag trying to get all of the air out. Crush the pudding using your bottle filled with water. Measure one full Dixie cup of water and pour the cereal and water into the larger cup. Allow the cereal to soak in water for 5 minutes, stirring the whole time. During this time you should discuss who you think the thief may be. After 5 minutes, use a magnetic wand and swirl it through the cereal and water, you will pick up the beetle bits on the wand if there is any in the pudding. Use a magnifying glass to determine if the beetle bits (black specs on end of wand) are present. Write/ explain who this evidence points to or who you can rule out based on this evidence. ___________________________________________________________________________________ ___________________________________________________________________________________ ___________________________________________________________________________________ 15 11) Clue 3: The cloak thread of the witch or wizard who stole the cloak of invisibility got stuck on a nail near where the cloak was hanging. However, Harry tripped when he found this clue and spilled blue dye on the thread. We have samples of the cloak threads that everyone was wearing. Dye the samples blue to determine whose cloak the thread came from. Directions: Mix together 1 Dixie cup of water and 1 packet of Kool-Aid in the cups provided. Then dip all of the threads into the Kool-Aid mixture and let sit for 2 minutes. Pull the strings out and lay them on a paper towel to determine which sample the thread found looks the most similar to. Write/ explain which character this evidence indicates might be the thief. ________________________________________________________________ ________________________________________________________________ ________________________________________________________________ 12) Clue 4: The magic world of Hogwarts also involves many secret messages. One message must have fallen out of the thief’s pocket because a seemingly blank gold paper was found on the floor near where the cloak was hanging. Use an experiment to chemically reveal what the paper says. Directions: Because we do not have magic, we will use window cleaner to spray the paper and reveal the message. What does the message say? __________________________________________________________ __________________________________________________________ __________________________________________________________ CONCLUSION: Based on all of your evidence, who do you think stole the magic cloak? __________________________________________________________ __________________________________________________________ 16 Directions: As a suspect is ruled out, put an x in that box. Suspect Clue 1 Clue 2 Clue 3 Clue 4 Luna Lovegood Ron Weasley Draco Malfoy 17 Neville Longbottom Hermione Granger 18
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