EUROPEAN COMMISSION ENVIRONMENT DIRECTORATE-GENERAL Green Economy Chemicals ENTERPRISE AND INDUSTRY DIRECTORATE-GENERAL Resources Based, Manufacturing and Consumer Goods Industries REACH Chemicals Industry Brussels, 12 February 2014 Follow-up to the 13th Meeting of Competent Authorities for REACH and CLP (CARACAL) 26 – 27 – 28 November 2013 Centre A. Borschette, Brussels, Belgium Concerns: List of opinions adopted by RAC-24, 25, 26 and 27 proposing new or revised classification in Annex VI, CLP for their potential inclusion in the 7th Adaptation to Technical Progress (ATP) Action Requested: Member States are requested to send their comments on the list of substances for their potential inclusion in the 7th ATP to CLP by 28th February 2014 by email to [email protected] and [email protected] Annex Table 1. Adopted by RAC-24, 25, 26 and 27 proposed new or revised classification in Annex VI, CLP Table 1.1 revised entries in Table 3.1 Annex VI, CLP Index No 00700400-1 01500300-2 05000800-3 International Chemical Identification nitric acid ... % calcium phosphide; tricalcium diphosphide tributyltin compounds, with the exception of those specified elsewhere in this annex EC No CAS No Classification Hazard Class and Category Code(s) 231-714-2 215-142-0 - Hazard statement Code(s) Ox. Liq. 2 Acute Tox. 1 Skin Corr. 1A H272 H330 H314 Water-react. 1 Acute Tox. 2 Acute Tox. 3 Acute Tox. 1 Eye Dam. 1 Aquatic Acute 1 Repr. 1B Acute Tox. 3 Acute Tox. 4* STOT RE 1 Skin Irrit. 2 Eye Irrit. 2 Aquatic Acute 1 Aquatic Chronic 1 H260 H300 H311 H330 H318 H400 H360FD H301 H311 H372** H315 H319 H400 H410 Labelling Pictogram , Signal Word Code(s) GHS03 GHS06 GHS05 Dgr Hazard statement Code(s) H272 H314 H330 Suppl. Hazard statement Code(s) EUH071 7697-372 1305-993 - GHS02 GHS06 GHS05 GHS09 Dgr GHS08 GHS06 GHS09 Dgr H260 H300 H311 H330 H318 H400 H360FD H301 H311 H372** H315 H319 H410 Specific Conc. Limits, Mfactors Note s Skin Corr. 1A; H314: C ≥ 20 % Skin Corr. 1B; H314: 5 % ≤ C < 20 % Ox. Liq. 2; H272: C ≥ 99 % Ox. Liq. 3; H272: 99 % > C ≥ 65 % B EUH029 EUH032 M=100 * STOT RE 1; H372: C ≥ 1 % STOT RE 2; H373: 0,25 % ≤ C<1% Skin Irrit. 2; C ≥ 1% Eye Irrit. 2; C ≥ A1 Index No International Chemical Identification EC No CAS No Classification Hazard Class and Category Code(s) Hazard statement Code(s) Labelling Pictogram , Signal Word Code(s) Hazard statement Code(s) Suppl. Hazard statement Code(s) Specific Conc. Limits, Mfactors 1% M=10 60310200-9 60319700-7 60605400-7 60719700-8 1,2-epoxybutane tebuconazole (ISO); 1-(4-chlorophenyl)4,4-dimethyl-3(1,2,4-triazol-1ylmethyl)pentan-3ol isoxaflutole (ISO); (5-Cyclopropyl-1,2oxazol-4-yl)[2(methylsulfonyl)-4(trifluoromethyl)phe nyl]methanone nonanoic acid 203-438-2 403-640-2 - 203-931-2 106-88-7 10753496-3 14111229-0 112-05-0 Flam. Liq. 2 Carc. 2 Acute Tox. 4* Acute Tox. 4* Acute Tox. 4* STOT SE 3 Skin Irrit. 2 Eye Irrit. 2 Aquatic chronic 3 H225 H351 H302 H312 H332 H335 H315 H319 H412 GHS02 GHS08 GHS07 Dgr H225 H351 H302 H312 H332 H335 H315 H319 H412 Repr. 2 Acute Tox. 4 Aquatic Acute 1 Aquatic Chronic 1 H361d*** H302 H400 H410 GHS08 GHS07 GHS09 Wng H361d*** H302 H410 Repr. 2 Aquatic Acute 1 Aquatic Chronic 1 H361d*** H400 H410 GHS08 GHS09 Wng H361d*** H410 Skin Irrit. 2 Eye Irrit. 2 Aquatic Chronic 3 H315 H319 H412 GHS07 Wng H315 H319 H412 3 M=1 M=10 M=10 M=100 Note s Index No 61304200-5 International Chemical Identification imazalil (ISO); 1-[2(allyloxy)-2-(2,4dichlorophenyl)ethyl ]-1H-imidazole 61305700-7 dodemorph (ISO); 4-cyclododecyl-2,6dimethylmorpholine 61313300-X etridiazole (ISO); 5ethoxy-3trichloromethyl1,2,4-thiadiazole 61314900-7 pyridaben (ISO); 2-tert-butyl-5-(4tertbutylbenzylthio)-4chloropyridazin3(2H)-one EC No CAS No Classification Hazard Class and Category Code(s) 252-615-0 216-474-9 219-991-8 405-700-3 3555444-0 1593-777 2593-159 9648971-3 Hazard statement Code(s) Labelling Pictogram , Signal Word Code(s) GHS08 GHS06 GHS05 GHS09 Dgr Hazard statement Code(s) Carc. 2 Acute Tox. 3 Acute Tox. 4 Eye Dam. 1 Aquatic Chronic 1 Repr. 2 STOT RE 2 Skin Corr. 1C Skin Sens. 1A Aquatic Acute 1 Aquatic Chronic 1 H351 H301 H332 H318 H410 H361d H373 (liver) H314 H317 H400 H410 GHS08 GHS05 GHS07 GHS09 Dgr Carc. 2 Acute Tox. 4 Skin Sens. 1 Aquatic Acute 1 Aquatic Chronic 1 Acute Tox. 3 Acute Tox. 3 Aquatic Acute 1 Aquatic Chronic 1 H351 H302 H317 H400 H410 GHS08 GHS07 GHS09 Wng H351 H302 H317 H410 H331 H301 H400 H410 GHS06 GHS09 Dgr H331 H301 H410 4 Suppl. Hazard statement Code(s) H351 H301 H332 H318 H410 H361d H373 (liver) H314 H317 H410 Specific Conc. Limits, Mfactors M=10 EUH071 M=1 M=1 M=1 M=1 M=1000 M=1000 Note s Table 1.2 new entries in Table 3.1 Annex VI, CLP Index No International Chemical Identification EC No CAS No Hazard Class and Category Code(s) 019003-003 potassium (E,E)-hexa2,4-dienoate 246376-1 2463461-5 082013-001 lead 231100-4 7439-921 604092-009 606148-008 phenol, dodecyl-, branched [1]; phenol, 2-dodecyl-, branched; phenol, 3-dodecyl-, branched; phenol, 4-dodecyl-, branched; phenol, (tetrapropenyl) derivatives [2] carvone (ISO); 2-methyl-5-(prop-1-en2-yl)cyclohex-2-en-1one; [1] d-carvone; (5S)-2methyl-5-(prop-1-en-2yl)cyclohex-2-en-1-one; [2] l-carvone; (5R)-2methyl-5-(prop-1-en-2yl)cyclohex-2-en-1-one [3] Classification 310154-3 [1] 202759-5 [1] 218827-2 [2] 229352-5 [3] 12115858-5 [1] 7449935-7 [2] Hazard statement Code(s) Labelling Pictogra m, Signal Word Code(s) GSH07 Wng Hazard statemen t Code(s) Eye Irrit. 2 H319 Repr. 1A Lact. H360FD H362 GHS08 Dgr H360FD H362 Repr. 1B Skin Corr. 1C Aquatic Acute 1 Aquatic Chronic 1 H360F H314 H400 H410 GHS05 GHS08 GHS09 Dgr H360F H314 H410 Skin Sens. 1 H317 GHS07 Wng H317 99-49-0 [1] 2244-168 [2] 6485-401 [3] 5 Suppl. Hazard statement Code(s) Specific Conc. Limits, Mfactors H319 Repr. 1A; H360D: C ≥ 0,03 % M=10 M=10 Note s Index No International Chemical Identification 606149-003 607707-009 607708-004 tembotrione (ISO); 2-{2chloro-4(methylsulfonyl)-3[(2,2,2trifluoroethoxy)methyl]b enzoyl}cyclohexane-1,3dione fenoxaprop-P-ethyl (ISO); ethyl (2R)-2-{4[(6-chloro-1,3benzoxazol-2yl)oxy]phenoxy}propano ate octanoic acid EC No CAS No Classification Hazard Class and Category Code(s) - - 204677-5 33510484-2 7128380-2 124-07-2 607709-00X decanoic acid 206376-4 334-48-5 607710-005 1,2-benzenedicarboxylic acid, dihexyl ester, branched and linear 271093-5 6851550-4 607711-000 spirotetramat (ISO); (5s,8s)-3-(2,5dimethylphenyl)-8methoxy-2-oxo-1azaspiro[4,5]dec-3-en-4- - 20331325-1 Repr. 2 STOT RE 2 Skin Sens. 1 Aquatic Acute 1 Aquatic Chronic 1 STOT RE 2 Skin Sens. 1 Aquatic Acute 1 Aquatic Chronic 1 Hazard statement Code(s) H361d H373 (eyes, kidneys, liver) H317 H400 H410 H373 (kidneys) H317 H400 H410 Labelling Pictogra m, Signal Word Code(s) GHS08 GHS07 GHS09 Wng Hazard statemen t Code(s) H361d H373 (eyes, kidneys, liver) H317 H410 GHS08 GHS07 GHS09 Wng H373 (kidneys) H317 H410 Skin Corr. 1C Aquatic Chronic 3 H314 H412 GHS05 Dgr H314 H412 Skin Irrit. 2 Eye Irrit. 2 Aquatic Chronic 3 H315 H319 H412 GHS07 Wng H315 H319 H412 Repr. 1B H360FD GHS08 Dgr H360FD Repr. 2 STOT SE 3 Eye Irrit. 2 Skin Sens. 1A Aquatic Acute 1 H361fd H335 H319 H317 H400 GHS08 GHS07 GHS09 Wng H361fd H335 H319 H317 H410 6 Suppl. Hazard statement Code(s) Specific Conc. Limits, Mfactors M=100 M=10 M=1 M=1 M=1 Note s Index No International Chemical Identification EC No CAS No Hazard Class and Category Code(s) yl ethyl carbonate 607712-006 607713-001 607714-007 607715-002 dodemorph acetate; 4cyclododecyl-2,6dimethylmorpholin-4-ium acetate fenpyroximate (ISO); tert-butyl 4-[({(E)-[(1,3dimethyl-5-phenoxy-1Hpyrazol-4yl)methylene]amino}oxy )methyl]benzoate triflusulfuron-methyl; methyl 2-({[4(dimethylamino)-6(2,2,2-trifluoroethoxy)1,3,5-triazin-2yl]carbamoyl}sulfamoyl)3-methylbenzoate bifenazate (ISO); Isopropyl 2-(4methoxybiphenyl-3yl)hydrazinecarboxylate Classification 250778-2 - - 442820-5 3171787-0 13409861-6 12653515-7 14987741-8 Hazard statement Code(s) Labelling Pictogra m, Signal Word Code(s) Hazard statemen t Code(s) Aquatic Chronic 1 H410 Repr. 2 STOT RE 2 Skin Corr. 1C Skin Sens. 1A Aquatic Chronic 1 H361d H373 (liver) H314 H317 H410 GHS08 GHS05 GHS07 GHS09 Dgr Acute Tox. 3 Acute Tox. 2 Skin Sens. 1B Aquatic Acute 1 Aquatic Chronic 1 H301 H330 H317 H400 H410 GHS06 GHS09 Dgr Carc. 2 Aquatic Acute 1 Aquatic Chronic 1 H351 H400 H410 GHS08 GHS09 Wng H351 H410 STOT RE 2 Skin Sens. 1 Aquatic Acute 1 Aquatic Chronic 1 H373 H317 H400 H410 GHS08 GHS07 GHS09 Wng H373 H317 H410 7 Suppl. Hazard statement Code(s) Specific Conc. Limits, Mfactors M=1 H361d H373 (liver) H314 H317 H410 H301 H330 H317 H410 EUH071 M=1 M=100 M=1000 M=100 M=10 M=1 M=1 Note s Index No International Chemical Identification 613319-000 613320-006 616213-002 616214-008 616215-003 imidazole lenacil (ISO); 3cyclohexy-6,7-dihydro1hcyclopenta[d]pyrimidine2,4(3h,5h)-dione mandipropamid (ISO); 2(4-chlorophenyl)-N-{2[3-methoxy-4-(prop-2yn-1yloxy)phenyl]ethyl}-2(prop-2-yn-1yloxy)acetamide metosulam (ISO); N(2,6-dichloro-3methylphenyl)-5,7dimethoxy[1,2,4]triazolo [1,5-a]pyrimidine-2sulfonamide dimethenamid-P (ISO); 2-chloro-N-(2,4dimethyl-3-thienyl)-N[(2S)1-methoxypropan-2yl]acetamide EC No CAS No Classification Hazard Class and Category Code(s) 206019-2 218499-0 - - - 288-32-4 2164-081 Hazard statement Code(s) Labelling Pictogra m, Signal Word Code(s) GHS08 GHS07 GHS05 Dgr Hazard statemen t Code(s) Repr. 1B Acute Tox. 4 Skin Corr. 1C H360D H302 H314 Carc. 2 Aquatic Acute 1 Aquatic Chronic 1 H351 H400 H410 GHS08 GHS09 Wng H351 H410 Aquatic Acute 1 Aquatic Chronic 1 H400 H410 GHS09 Wng H410 Carc. 2 STOT RE 2 H351 H373 (eyes, kidneys) H400 H410 GHS08 GHS09 Wng H351 H373 (eyes, kidneys) H410 H302 H317 H400 H410 GHS07 GHS09 Wng Suppl. Hazard statement Code(s) Specific Conc. Limits, Mfactors H360D H302 H314 M=10 M=10 M=1 M=1 37472662-2 13952885-1 16351514-8 Aquatic Acute 1 Aquatic Chronic 1 Acute Tox. 4 Skin Sens. 1 Aquatic Acute 1 Aquatic Chronic 1 8 H302 H317 H410 M=1000 M=100 M=10 M=10 Note s Index No International Chemical Identification 616216-009 flonicamid (ISO); N(cyanomethyl)-4(trifluoromethyl)pyridine3-carboxamide 616217-004 sulfoxaflor (ISO); [methyl(oxo){1-[6(trifluoromethyl)-3pyridyl]ethyl}-λ6sulfanylidene]cyanamide EC No CAS No Classification Hazard Class and Category Code(s) - - Hazard statement Code(s) Acute Tox. 4 H302 Acute Tox. 4 Aquatic Acute 1 Aquatic Chronic 1 H302 H400 H410 15806267-0 94657800-3 9 Labelling Pictogra m, Signal Word Code(s) GHS07 Wng GHS07 GHS09 Wng Hazard statemen t Code(s) Suppl. Hazard statement Code(s) Specific Conc. Limits, Mfactors H302 H302 H410 M=1 M=1 Note s Table 2. Adopted by RAC-24, 25, 26 and 27 proposed new or revised classification in Annex VI, DSD Table 2.1 revised entries in Table 3.2, Annex VI, DSD Index No 007-00400-1 015-00300-2 050-00800-3 603-10200-9 International Chemical Identification nitric acid ... % calcium phosphide; tricalcium diphosphide tributyltin compounds, with the exception of those specified elsewhere in this annex 1,2-epoxybutane EC No 231-7142 215-1420 - 203-4382 CAS No 7697-37-2 1305-99-3 Classification Labelling Concentration Limits Note s O; R8 C; R35 T+; R26 O; R8: C ≥ 65 % C; R35: C ≥ 20 % C; R34: 5 % ≤ C < 20 % B F; R15/29 T+; R26/28 Xn; R21 R32 Xi; R38-41 N; R50 O; T+ R: 8-26-35 S: (1/2-)26-2836/37/39-45-63 F; T+; N R: 15/29-21-26/2832-38-41-50 S:(1/2)-22-2836/37/39-43-45-6061-63 Repr. Cat. 2; R60-61 T; R25-48/23/25 Xn; R21 Xi; R36/38 N; R50-53 T; N R: 21-25-36/3848/23/25-50/53-6061 S: 45-53-60-61 T; R25: C ≥ 2,5 % Xn; R22: 0,25 % ≤ C < 2,5 % Xn: R21: C ≥ 1 % T; R48/23/25: C ≥ 1 % Xn; R48/20/22: 0,25 % ≤ C<1% Xi; R36/38: C ≥ 1 % N; R50-53: C ≥ 2,5 % N; R51-53: 0,25 % ≤ C < 2,5 % R52-53: 0,025 % ≤ C < 0,25 % F; R11 Carc. Cat. 3; R40 Xn; R20/21/22 Xi; R36/37/38 R52-53 F; Xn R: 11-20/21/2236/37/38-40-52/53 S: (2-)9-16-2936/37-46-61 - 106-88-7 10 N; R50: C ≥ 0,25 % A1 603-19700-7 606-05400-7 tebuconazole (ISO); 1-(4-chlorophenyl)-4,4dimethyl-3-(1,2,4triazol-1ylmethyl)pentan-3-ol isoxaflutole (ISO); 5-cyclopropyl-1,2oxazol-4-yl α, α,αtrifluoro-2-mesyl-p-tolyl ketone 607-19700-8 nonanoic acid 613-04200-5 imazalil (ISO); 1-[2(allyloxy)-2-(2,4dichlorophenyl)ethyl]1H-imidazole 613-05700-7 dodemorph (ISO); 4cyclododecyl-2,6dimethylmorpholine 613-13300-X etridiazole (ISO); 5ethoxy-3trichloromethyl- 1,2,4thiadiazole 403-6402 107534-963 - 141112-290 203-9312 112-05-0 252-6150 216-4749 219-9918 35554-44-0 1593-77-7 2593-15-9 Repr. Cat. 3; R63 Xn; R22 N; R50-53 Xn; N R: 22-50/53-63 S: (2-)22-36/37-6061 Repr. Cat. 3; R63 N; R50-53 Xn; N R: 50/53-63 S: (2-)36/37-60-61 Xi; R36/38 N; R51-53 Xi; N R: 36/38-51/53 S: (2-)46-61 Carc. Cat. 3; R40 Xn; R20/22 Xi; R41 N; R51-53 Repr. Cat. 3; R63 C; R34 R43 N; R50-53 Xn; N R: 20/22-40-4151/53 S: (2-)26-36/37/3946-61 C; N R: 34-43-50/53-63 S: (1/2-)26-2836/37/39-45-60-61 Carc. Cat. 3; R40 Xn; R22 R43 N; R50-53 Xn; N R: 22-40-43-50/53 S: (2-)36/37-46-6061 11 N; R50-53: C ≥ 25 % N; R51-53: 2,5 % ≤ C <25 % R52-53: 0,25 % ≤ C < 2,5 % N; R50-53: C ≥ 2,5 % N; R51-53: 0,25 % ≤ C < 2,5 % R52-53: 0,025 % ≤ C < 0,25 % C; R34: C ≥ 10 % Xi; R36/37/38: 5 % ≤ C < 10 % N; R50-53: C ≥ 25 % N; R51-53: 2,5 % ≤ C < 25 % R52-53: 0,25 % ≤ C < 2,5 % N; R50-53: C ≥ 25 % N; R51-53: 2,5 % ≤ C < 25 % R52-53: 0,25 % ≤ C < 2,5 % 613-14900-7 pyridaben (ISO); 2-tert-butyl-5-(4-tertbutylbenzylthio)-4chloropyridazin-3(2H)one 405-7003 T; R23/25 N; R50-53 96489-71-3 T; N R: 23/25-50/53 S: (1/2-)36/37-4560-61 N; R50-53: C ≥ 0,025 % N; R51-53: 0,0025 % ≤ C < 0,025 % R52-53: 0,00025 % ≤ C < 0,0025 % Table 2.2 new entries in Table 3.2, Annex VI, DSD Index No 019-00300-3 International Chemical Identification potassium (E,E)-hexa2,4-dienoate 082-01300-1 lead 604-09200-9 phenol, dodecyl-, branched [1]; phenol, 2-dodecyl-, branched; phenol, 3-dodecyl-, branched; phenol, 4-dodecyl-, branched; phenol, (tetrapropenyl) derivatives [2] EC No CAS No 246376-1 2463461-5 231100-4 7439-921 310154-3 [1] - [2] 12115858-5 [1] 7449935-7 [2] Classification Labelling Concentration Limits Xi; R36 Xi R: 36 S: (2-)46 Repr. Cat. 1; R60-61 R64 T R: 60-61-64 S: 45-53 Repr. Cat. 1; R61: C ≥ 0,03 % Repr. Cat. 2; R60 C; R34 N; R50-53 T; N R: 34-50/53-60 S: 45-53-60-61 N; R50-53: C ≥ 2,5 % N; R51-53: 0,25 % ≤ C < 2,5 % R52-53: 0,025 % ≤ C < 0,25 % 12 Notes Index No International Chemical Identification 606-14800-8 carvone (ISO); 2-methyl-5-(prop-1-en2-yl)cyclohex-2-en-1one; [1] d-carvone; (5S)-2methyl-5-(prop-1-en-2yl)cyclohex-2-en-1-one; [2] l-carvone; (5R)-2methyl-5-(prop-1-en-2yl)cyclohex-2-en-1-one [3] 606-14900-3 607-70700-9 607-70800-4 tembotrione (ISO); 2-{2chloro-4(methylsulfonyl)-3[(2,2,2trifluoroethoxy)methyl]b enzoyl}cyclohexane-1,3dione fenoxaprop-P-ethyl (ISO); ethyl (2R)-2-{4[(6-chloro-1,3benzoxazol-2yl)oxy]phenoxy}propano ate EC No 202759-5 [1] 218827-2 [2] CAS No 99-49-0 [1] Classification Labelling Concentration Limits R43 Xi R: 43 S: (2-)24-37 Repr. Cat. 3; R63 Xn; R48/22 R43 N; R50-53 Xn; N R: 43-48/22-50/53-63 S: (2-)36/37-46-6061 N; R50-53: C ≥ 0,25 % N; R51-53: 0,025 % ≤ C < 0,25 % R52-53: 0,0025 % ≤ C < 0,025 % Xn; R48/22 R43 N; R50-53 Xn; N R: 43-48/22-50/53 S: (2-)24-37-46-6061 N; R50-53: C ≥ 25 % N; R51-53: 2,5 % ≤ C < 25 % R52-53: 0,25 % ≤ C < 2,5 % C; R34 N; R51-53 C; N R: 34-51/53 S: (1/2-)26-36/37/3945-61 Xi; R36/38 N; R51-53 Xi; N R: 36/38-51/53 S: (2-)46-61 Repr. Cat. 2; R60-61 T R: 60-61 S: 53-45 2244-168 [2] 6485-401 [3] 229352-5 [3] 33510484-2 - octanoic acid 204677-5 607-70900-X decanoic acid 206376-4 607-71000-5 1,2-Benzenedicarboxylic acid, dihexyl ester, branched and linear 271093-5 7128380-2 124-07-2 334-48-5 6851550-4 13 Notes Index No International Chemical Identification 607-71100-0 spirotetramat (ISO); (5s,8s)-3-(2,5dimethylphenyl)-8methoxy-2-oxo-1azaspiro[4,5]dec-3-en-4yl ethyl carbonate 607-71200-6 dodemorph acetate; 4cyclododecyl-2,6dimethylmorpholin-4-ium acetate 607-71300-1 607-71400-7 607-71500-2 613-31900-0 fenpyroximate (ISO); tert-butyl 4-[({(E)-[(1,3dimethyl-5-phenoxy-1Hpyrazol-4yl)methylene]amino}oxy )methyl]benzoate triflusulfuron-methyl; methyl 2-({[4(dimethylamino)-6(2,2,2-trifluoroethoxy)1,3,5-triazin-2yl]carbamoyl}sulfamoyl)3-methylbenzoate EC No CAS No - 20331325-1 250778-2 3171787-0 - - bifenazate (ISO); Isopropyl 2-(4methoxybiphenyl-3yl)hydrazinecarboxylate 442820-5 imidazole 206019-2 13409861-6 Classification 288-32-4 Concentration Limits Repr. Cat. 3; R62-63 Xi; R36/37 R43 N; R50-53 Xn; N R: 36/37-43-50/5362-63 S: (2-)36/37-46-6061 Xi; R43: C ≥ 0,1 % N; R50-53: C ≥ 25 % N; R51-53: 2,5 % ≤ C < 25 % R52-53: 0,25 % ≤ C < 2,5 % Repr. Cat. 3; R63 C; R34 R43 N; R51-53 C; N R: 34-43-51/53-63 S: (1/2-)26-2836/37/39-45-61 C; R34: C ≥ 10 % Xi: R36/37/38: 5 % ≤ C < 10 % T+; R26 Xn; R22 R43 N; R50-53 T+; N R: 22-26-43-50/53 S: (1/2-)28-36/37-4560-61-63 N; R50-53: C ≥ 0,25 % N; R51-53: 0,025 % ≤ C < 0,25 % R52-53: 0,0025 % ≤ C < 0,025 % Carc. Cat. 3; R40 N; R50-53 Xn; N R: 40-50/53 S: (2-)36/37-60-61 N; R50-53: C ≥ 0,25 % N; R51-53: 0,025 % ≤ C < 0,25 % R52-53: 0,0025 % ≤ C < 0,025 % R43 N; R50-53 Xi; N R: 43-50/53 S: (2-)24-37-60-61 N; R50-53: C ≥ 25 % N; R51-53: 2,5 % ≤ C < 25 % R52-53: 0,25 % ≤ C < 2,5 % Repr. Cat 2; R61 Xn; R22 C; R34 T; C R: 22-34-61 S: 53-45 12653515-7 14987741-8 Labelling 14 Notes Index No 613-32000-6 616-21300-2 616-21400-8 616-21500-3 International Chemical Identification lenacil (ISO); 3cyclohexy-6,7-dihydro1hcyclopenta[d]pyrimidine2,4(3h,5h)-dione mandipropamid (ISO); 2(4-chlorophenyl)-N-{2[3-methoxy-4-(prop-2yn-1yloxy)phenyl]ethyl}-2(prop-2-yn-1yloxy)acetamide metosulam (ISO); N(2,6-dichloro-3methylphenyl)-5,7dimethoxy[1,2,4]triazolo [1,5-a]pyrimidine-2sulfonamide dimethenamid-P (ISO); 2-chloro-N-(2,4dimethyl-3-thienyl)-N[(2S)- EC No 218499-0 - - - CAS No 2164-081 Classification Labelling Carc. Cat. 3; R40 N; R50-53 Xn; N R: 40-50/53 S: (2-)36/37-60-61 N; R50-53 N R: 50/53 S: 60-61 Carc. Cat. 3; R40 Xn; R48/22 N; R50-53 Xn; N R: 40-48/22-50/53 S: (2-)36/37-46-6061 N; R50-53: C ≥ 0,025 % N; R51-53: 0,0025 % ≤ C < 0,025 % R52/53: 0,00025 % ≤ C < 0,0025 % Xn; R22 R43 N; R50-53 Xn; N R: 22-43-50/53 S: (2-)24-37-60-61 N; R50-53: C ≥ 2,5 % N; R51-53: 0,25 % ≤ C < 2,5 % R52-53: 0,025 % ≤ C < 0,25 % 37472662-2 13952885-1 16351514-8 1-methoxypropan-2yl]acetamide 616-21600-9 flonicamid (ISO); N(cyanomethyl)-4(trifluoromethyl)pyridine3-carboxamide 616-21700-4 sulfoxaflor (ISO); [methyl(oxo){1-[6(trifluoromethyl)-3pyridyl]ethyl}-λ6sulfanylidene]cyanamide - 15806267-0 94657800-3 Concentration Limits N; R50-53: C ≥ 2,5 % N; R51-53: 0,25 % ≤ C < 2,5 % R52-53: 0,025 % ≤ C < 0,25 % N; R50-53: C ≥ 25 % N; R51-53: 2,5 % ≤ C <25 % R52-53: 0,25 % ≤ C < 2,5 % Xn R: 22 S: (2-)46 Xn; R22 Xn; R22 N; R50-53 15 Xn; N R: 22-50/53 S: (2-)60-61 N; R50-53: C ≥ 25% N; R51-53: 2,5% ≤ C < 25% R52-53: 0,25% ≤ C < 2,5% Notes 16
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