SAFETY DATA SHEET
1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND COMPANY /
UNDERTAKING
Product Name:
Graffiti Safewipes
Company:
GraffitiAce / Worlds Best Products Pty Ltd
1203 Oakey Flat Road
Narangba
Queensland 4504
07 38866149
07 38866336
Phone Number:
Fax:
Revision:
22/02/2010
Replaces SDS:
Safety Data Sheet compiler:
2
Environmental Effects:
Combustible (See section 9 for flash point)
Harmful by prolonged inhalation and if swallowed – may
cause severe mouth irritation if swallowed
Irritating to skin.
Contains component classified environmentally harmful
COMPOSITION / INFORMATION ON INGREDIENTS
Hazardous Ingredients:
Workplace exposure limit values exist
for the following constituents:
4
[email protected]
HAZARDS IDENTIFICATION
Flammability:
Human Health Effects:
3
Intended use: paint removal from hard surfaces
Ethyl alcohol (EC200-578-6) F;R11, concn. 20-40%
Benzyl alcohol (EC202-859-9) Xn;R20/22, concn. 2040%
Docusate sodium (EC209-406-4) Xn;R22, concn. 5-10%
Orange Oil (EC232-433-8) R10 Xi;R38 N;R52/53 R65,
concn. 10-20%
Ethanol (see section 8)
FIRST-AID MEASURES
Inhalation
Skin Contact:
Eye Contact:
Ingestion:
Graffiti Safewipes
Remove from exposure; remove to fresh air. If breathing is
laboured, hold in a half-upright position; obtain medical
attention
Wash skin with soap and water and remove contaminated
clothing.
If towelling has contacted eyes, immediately wash out with
plenty of water, holding the eyelids apart, Obtain medical
attention.
Wash out mouth with water. Give water to drink (unless
patient is losing consciousness). Do not induce vomiting
Issue1
Feb 2010
5
FIRE-FIGHTING MEASURES
Extinguishing:
Exposure Hazards:
Protective Equipment for fire fighting:
6
ACCIDENTAL RELEASE MEASURES
Personal Precautions:
Environmental Precautions:
Methods for Cleaning Up:
7
Storage:
Use in well-ventilated area. Atmospheric levels should be
controlled in compliance with occupational exposure
limit. Do not breathe vapour and avoid contact with eyes,
skin and clothing. The usual precautions for handling
chemicals should be observed.
Keep packaging dry. Keep in a cool, well-ventilated place
and away from severe heat sources.
EXPOSURE CONTROLS / PERSONAL PROTECTION
Workplace Exposure limit values
Personal Protective Equipment:
9
Wear gloves, chemical goggles; overalls. Ventilate the
area to clear fumes
Prevent residue from entering drains and water courses
Sweep up damaged packaging and dispose of in
accordance with local regulations.
HANDLING AND STORAGE
Handling:
8
Extinguishers - Carbon dioxide, foam
Fumes may include carbon monoxide.
Self-contained breathing apparatus
Ethanol LTEL 1200 mg/m3 (8h. TWA)
Wear overalls and chemical goggles. Wear PVC or rubber
gloves for short-term exposure or PVA or Viton gloves
for prolonged exposure. Remove working clothes after
work.
Respiratory equipment approved for organic vapours and
mists if there is a risk of exposure to vapour
PHYSICAL AND CHEMICAL PROPERTIES
Typical values – does not constitute a specification
Physical State
Towelling Paper Wipe
Appearance
Odour
Boiling point/range (°C)
Flash Point (°C)(Abel closed cup)
Flammability – autoignition temp. (°C)
Explosive properties
Oxidising properties
Vapour pressure (mbar @ 20°C)
Relative Density (@15.5°C)
Solubility in water
Solubility in fat / solvent
Partition coefficient (log Pow)
Viscosity (mPa.s @ 20°C)
Evaporation rate
Graffiti Safewipes
Orange
Orange solvent
>85 °C
45
No data available
None
None
No data available
1.0
Disperses
Miscible
No data available
No data available
No data available
Issue1
Feb 2010
10
STABILITY AND REACTIVITY
Stability:
Conditions to avoid:
Materials to avoid
Hazardous decomposition products
11
TOXICOLOGICAL INFORMATION
Acute Toxicity
-oral
-inhalation
-dermal
Corrosivity/Irritation
-eye
-skin
-respiratory tract
Sensitisation
-skin
-respiratory
Repeated-dose toxicity
Mutagenicity
Carcinogenicity
Reproductive toxicity
12
Mobility
Persistence and degradability
Bioaccumulative potential
Other adverse effects
Irritating to eyes
Irritating to skin
May cause irritation
No evidence of sensitisation effects
No evidence of sensitisation effects
No data available on effects of repeated skin contact
No evidence of mutagenicity
No evidence of carcinogenicity
No evidence of reproductive toxicity
Contains component classified as harmful for the
environment
Disperses in water
Expected to be ultimately biodegradable
Not known
None known
DISPOSAL CONSIDERATIONS
Waste Residue:
Packaging:
14
Harmful if swallowed
Harmful by inhalation -note occupational exposure limits
in section 8 – inhalation of concentrations above the OEL
may lead to light-headedness, nausea and headache.
Can be absorbed through the skin
ECOLOGICAL INFORMATION
Ecotoxicity
13
Combustible.
Heat and hot areas.
Oxidising agents.
None known
Disposal should be in accordance with local or national
legislation via an authorised waste disposal contractor to
an approved waste disposal site.
Dispose of through normal waste collection methods
TRANSPORT INFORMATION
Transport Classification
UN Number
Hazard Class
Proper Shipping Name
Packing Group
Marine Pollutant
Limited Quantity
Graffiti Safewipes
Not Classified as dangerous goods for carriage
NA
NA
Packaged cleaning wipes
NA
No
Single packaged wipe
Issue1
Feb 2010
15
REGULATORY INFORMATION
CHIP3 Classification
CHIP Label
Label Name
Symbol
Classified as hazardous Xi
Graffiti Safewipes
Xi
Named component
Benzyl Alcohol
Risk Phrases
R20/22 Harmful by inhalation and if swallowed
R38 Irritating to skin
R65 Harmful: may cause lung damage if swallowed
Safety Phrases
S24/25 Avoid contact with skin and eyes
S37/39 Wear suitable gloves and eye/face protection
S23 Do not breathe vapour/spray
S62 If swallowed, do not induce vomiting: seek medical
advice immediately and show this container or label
EC Number
EC Directives
Statutory Instruments
16
None required for label
Dangerous Substances Directive 67/548/EEC as amended
by 1992/32/EEC; Dangerous Preparations Directive
1999/45/EC; Safety Data Sheets Directive 91/155/EEC.
The Chemicals (Hazard Information and Packaging for
Supply) Regulations 2002 (CHIP3)
The Hazardous Wastes Regulations 2005 and the List of
Wastes Regulations 2005
The Control of Substances Hazardous to Health Regulations
2002
OTHER INFORMATION
This product safety data sheet provides health and safety information. The product is to be used in applications
consistent with our product literature. Individuals handling this product should be informed of the
recommended safety precautions and should have access to this information. For any other uses, exposures
should be evaluated so that appropriate handling practices and training programs can be established to ensure
safe workplace operations
Further references:
Occupational exposure limits (EH 40)
COSHH essentials (HSG 193)
Definition of Risk phrases (section 2) not defined in section 15:
F;R11 Highly flammable
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment
All sections have been amended in this revision to comply with the requirements of CHIP3 2002 and SDS ACoP L130
Graffiti Safewipes
Issue1
Feb 2010