Self-Aligned Triple Patterning to Extend Optical Lithography for 1x Patterning Yijian Chen*, Ping Xu, Yongmei Chen, Liyan Miao, Xumou Xu, Chris Bencher, Chris Ngai *Email: [email protected] Maydan Technology Center Group (MTCG) Applied Materials, Inc. International Symposium on Lithography Extensions 10/21/2010 Public Presentation Outline § Self-aligned triple patterning as an evolutionary enhancement to double patterning § SATP material consideration § Preliminary results of SATP development - 21nm and 16nm lines/spaces § SATP challenges and potential solutions § Summary and future work 2 Public Presentation § Self-aligned triple patterning as an evolutionary enhancement to double patterning § SATP material consideration § Preliminary results of SATP development - 21nm and 16nm lines/spaces § SATP challenges and potential solutions § Summary and future work Public Presentation Looking Backward: Negative and Positive Tone SADP Processes for HP 37-20 nm ü Variable line width X Only one space X Only one line width ü Variable space § Two different design rules and restrictions § Both schemes co-existed in NAND flash manufacturing 4 Public Presentation Looking Forward: Should We Keep or Remove Cores for HP 19-13 nm? 37-20 nm 19-13 nm In post-SADP era (19-13nm), self-aligned multiple patterning (SAMP) will be needed for NAND flash, will the dual-track (keep & remove core) scenario remain the same for SAMP? Public Presentation Motivations for Self-Aligned Triple Patterning Nitride (300 A) Resist APF core BARC APF (880 A) APF (880 A) Substrate (1) Nitride (4) (3) (2) Nitride Spacer (5) Oxide Spacer Two Motivations: 1. Increase density (double à triple) 2. Different design rules/restrictions. (6) Wet Strip Nitride (7) (8) : APF : Nitride : Oxide Example: NAND 32-string with select lines § Ground select & string select by mandrel (wide) § 32-line array is mix of spacers and mandrels ü Keep both mandrels (cores) and (2nd) spacers ü Variable line width ü Variable space Public Presentation Self-Aligned Quadruple Patterning (SAQP) Limitations Film Stack (1) Quadruple Patterning Process 1 Litho/Spacer (2) Spacer & Core (3) & (4) Final Structure (5) APF 70 nm Ox 30 nm APF 70 nm Poly 60 nm Si Quadruple Patterning Process 2 APF 110 nm HTO 30 nm Poly 60 nm Si X Only one line width ü Variable space 3 Masks/critical layer : (1) core mask (2) cut mask (3) pad & peripheral mask Unlike spacer double patterning, SAQP does not even allow a “dual-track” (keep & remove core) scenario, it still can not do the NAND string with one mask. 7 Public Presentation SATP Reduces Number of Masks APF core Nitride Spacer (3) Oxide Spacer (5) Wet Strip Nitride (7) (6) (3) Core mask (5) 1st spacer (6) 2nd spacer : APF : Nitride : Oxide (7-a) 1st spacer etch (wet) (7-b) Cutting mask and etch SATP process keeps the core patterns, thus allowing less masks and more flexible design. Public Presentation § Self-aligned triple patterning as an evolutionary enhancement to double patterning § SATP material consideration § Preliminary results of SATP development - 21nm and 16nm lines/spaces § SATP challenges and potential solutions § Summary and future work Public Presentation Many Different SATP Material Combinations SATP First Candidate Other Candidates SATP Core / Spacer1 / Spacer2 Core/Mandrel Poly Si APF/ Oxide Scheme 1 Poly Si / Nitride / Poly Si 1 Spacer nitride Oxide/ Poly Si Scheme 2 Poly Si / Nitride / Oxide Hard-stop Layer oxide TBD Scheme 3 APF / Poly Si / Oxide Poly Si oxide Scheme 4 APF / Nitride / Oxide st 2 nd spacer Application example: use poly Si spacers as the hard mask to etch oxide for NAND flash STI patterning. § Post-etch profile of core lines. § Etch (wet/dry) selectivity when strip 1st (sacrificial) spacer. § Stress minimization to reduce line bending. § A relevant hard-stop layer is available. § Satisfactory final structures for continuous integration. SATP process flows with different film combinations can be used as hard mask for many different applications. Public Presentation § Self-aligned triple patterning as an evolutionary enhancement to double patterning § SATP material consideration § Preliminary results of SATP development - 21nm and 16nm lines/spaces § SATP challenges and potential solutions § Summary and future work Public Presentation SATP Process Development Using Dry Litho APF Core Oxide Nitride § SEM top views at different process steps: • Core Patterning (HP: 6x nm) • Nitride dep • Nitride spacer 21nm L/S Public Presentation • Oxide spacer • Wet etch nitride (HP: 2x nm) SATP Process Development Using Immersion Litho Poly Core Poly Nitride § SEM top views at different process steps: • Core Patterning (HP: 4x nm) • Nitride dep • Nitride spacer 16 nm L/S Public Presentation • Poly spacer • Wet etch nitride (HP: 1x nm) § Self-aligned triple patterning as an evolutionary enhancement to double patterning § SATP material consideration § Preliminary results of SATP development - 21nm and 16nm lines/spaces § SATP challenges and potential solutions § Summary and future work Public Presentation Challenges and Potential Solutions (1) Problem: poly core footing & sidewall of the 2nd spacers NOT vertical. Possible solution: CMP may be used to polish off rounding corner of core & 1st-spacers (at the price of extra trench-fill & etch-back steps). Poly Si mandrel 2nd spacer (poly) (2) Problem: LWR of poly Si core is NOT satisfactory. Possible solution: other core & hard-mask materials may be considered. APF mandrel LWR good Mandrel (APF) Poly mandrel LWR poor Spacer (Oxide) Mandrel (Poly) Public Presentation Spacer (Poly) Investigation of Core Line LWR Issue Resist (90nm pitch) core line CD/3σ : 33.0/1.3nm → Post BARC open line CD/3σ : 24.9/2.6nm → Post plasma treatment line CD/3σ: 14.4/2.0nm (LWR: 3.2nm) Final resist/BARC Top Final resist/BARC Center Final resist/BARC Left It remains a challenge to keep low LWR when we etch core lines from resist/BARC to substrate. Public Presentation Further Optimization of Mandrel Etch Needed MTC MTC 10 nm lines 16 nm lines § In our first try, we were not able to keep low LWR when etching mandrel lines from resist/BARC to substrate. § Our industry’s small-line patterning capability (e.g., FinFET) is quite mature, and we just need to implant it into SATP. § Mandrel etching should not remain a bottle-neck of SATP process. Public Presentation § Self-aligned triple patterning as an evolutionary enhancement to double patterning § SATP material consideration § Preliminary results of SATP development - 21nm and 16nm lines/spaces § SATP challenges and potential solutions § Summary and future work Public Presentation Summary and Future Work § Self-aligned triple patterning (SATP) to extend optical lithography for 1x patterning is proposed. § 21 nm and 16 nm HP lines/spaces based on dry and immersion litho are demonstrated, while LWR of core lines remains a challenge. § By keeping the core/mandrel lines, 2-mask SATP process may pattern dense lines/spaces with pads and peripheral circuits for each critical layer. § Potential solutions to overcome the technical barriers of SATP process are identified for future research. § Stay tuned for a whole packet of various SATP & SAQP process schemes and results in SPIE 11. Public Presentation Acknowledgement § We would like to thank MTCG operation team for process support. § Sincere thanks go to Raymond Hung for valuable discussion and revision of this presentation, and Bingxi Wood for providing the SEM pictures showing our small-line etching capability. § We appreciate your time and interest in this project. Public Presentation
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