002000028c_129.pdf

Structure Data of Free Polyatomic Molecules
459
MW
C3H11NS
Trimethylamine – hydrogen sulfide (1/1)
C3v
N,N-Dimethylmethanamine –
(effective symmetry class)
hydrogen sulfide (1/1)
(large-amplitude motion)
CH3
(weakly bound complex)
.
r0
Å
S...N 3.36(5)
The spectra are characteristic of a symmetric top,
and are indicative of free internal rotation of
H2S about the trimethylamine symmetry axis.
Tubergen, M.J., Flad, J.E., Del Bene, J.E.: J. Chem. Phys. 107 (1997) 2227.
Landolt-Börnstein
New Series II/28C
H3 C
N
H2 S
CH3