Structure Data of Free Polyatomic Molecules 459 MW C3H11NS Trimethylamine – hydrogen sulfide (1/1) C3v N,N-Dimethylmethanamine – (effective symmetry class) hydrogen sulfide (1/1) (large-amplitude motion) CH3 (weakly bound complex) . r0 Å S...N 3.36(5) The spectra are characteristic of a symmetric top, and are indicative of free internal rotation of H2S about the trimethylamine symmetry axis. Tubergen, M.J., Flad, J.E., Del Bene, J.E.: J. Chem. Phys. 107 (1997) 2227. Landolt-Börnstein New Series II/28C H3 C N H2 S CH3
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