Structure Data of Free Polyatomic Molecules
446
MW
C3H9ClFN
Trimethylamine – chlorine fluoride (1/1)
C3v or C3
N,N-Dimethylmethanamine –
(effective symmetry class)
chlorine fluoride (1/1)
(large-amplitude motion)
(weakly bound complex)
CH3
r0
N...Cl
Å a)
2.090(5)
H3C
N
CH3
The complex is of ionic form: [(CH3)3NCl]+F–, namely of the Mulliken inner type.
a
) Uncertainty was not estimated in the original paper.
Bloemink, H.I., Holloway, J.H., Legon, A.C.: Chem. Phys. Lett. 254 (1996) 59.
Landolt-Börnstein
New Series II/28C
. ClF