Innovative Polymeric Nano Materials for Unconventional Thermal Transport Control Tengfei Luo Assistant Professor Aerospace and Mechanical Engineering University of Notre Dame 11th US-Korea Forum on Nanotechnology September 29, 2014 Molecular-level Energy & Mass Transport 1 Thermal Transport in Polymers Molecular-level Energy & Mass Transport 2 Thermal Transport at Hard-Soft Interfaces Polymer nanocomposite Interfacial bonds: vdW -> G ~ O(1-10) MW/m2K Covalent -> G ~ O(100) MW/m2K* Vibration power Vibration coupling: hard soft Frequency Molecular thermal bridge: http://www.rsc.org Hard-soft interface * Luo and Lloyd, Advanced Functional Materials, 2012 Molecular-level Energy & Mass Transport 3 Manipulate Thermal Transport in Polymer Fibers Polyethylene: • Do other fibers have high(er) thermal conductivity? Thermal switch: Thermal diode: Molecular-level Energy & Mass Transport 4 *Shen et al., Nat. Nanotech., 2010 Thank you! Questions? Come to see poster: Innovative Polymeric Nano Materials for Unconventional Thermal Transport Control Molecular-level Energy & Mass Transport 5
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