JOURNAL OF GEOPHYSICAL RESEARCH, VOL. 105, NO. C5, PAGES 11,337-11,346, MAY 15, 2000 Deep and bottom water of the Bransfield Strait eastern and central Arnold basins L. Gordon and Manfred Mensch • Lamont-DohertyEarth Observatory,ColumbiaUniversity,Palisades,New York Zhaoqian Dong Polar ResearchInstitute of China, Shanghai William M. Smethie Jr. and Jose de Bettencourt Lamont-DohertyEarth Observatory,Columbia University,Palisades,New York Abstract. Temperature,salinity,oxygen,and chlorofluorocarbon (CFC) data obtainedin September1997 define the water typesventilatingthe deep easternand centralbasinsof the BransfieldStrait. Thesewater typesare observedadjacentto JoinvilleIsland and are clearly derivedfrom the Weddell Sea. The easternbasinbottom water characteristics closelymatch that of the bottom water at 310 dbar depth -50 km east of Joinville Island. The easternbasinbottomwater is a simplemixtureof low-salinityfreezingpoint shelf water (65%) and relativelywarm salineWeddell Deep Water (35%), with a CFC-113: CFC-11 ratio age of 8.5 years.The easternbasinbottom water sharesa commonorigin with a weak salinityminimumobservedat 1000 dbar within the centralbasin,though overflowfrom the central basinto the easternbasinfloor may also occur.The bottom water within the centralbasinis colderand saltierwith higher concentrations of oxygen and CFC-11 than that of the eastern basin. The central basin bottom water with a CFC ratio age of 7.5 yearsis composedof sameWeddell water typesthat form the eastern basinbottomwater plus a large contributionof high-salinityfreezingpoint shelfwater of the characteristics of water observed 10 km northeast of Joinville Island and a small amountof Pacificpycnoclinewater. The components(and their percentage)are Weddell Deep Water (11%), low-salinityshelf(24%), high-salinityshelf(60%), to Pacific pycnocline(5%). 1. bottom Introduction waters in the strait are different from those at corre- spondingdepthin adjacentareas.He speculatedthat the thermohalinecharacteristics of the deepwater fillingthe Bransfield are the three smalldeepbasinsof the BransfieldStrait (Figure Strait basinsare derivedat leastin part from winter water mass 1), eachwith uniquebottomwater propertiesrelativeto those conversionof Weddell shelfwater alongthe southernboundof the open SouthernOcean. Oceanographers havelong been ary of the BransfieldStrait. curiousas to the origin and fate of thesewaters.To the north The Bransfield Strait stratification is similar to that of the and west of the basins are topographicbarriers that isolate Antarctic continentalmargin,with a muchsubduedexpression BransfieldStrait water from the southernDrake Passageat of the warm salinedeepwater characteristic of the neighboring depths>600 dbar [Smithand Sandwell,1997]. To the east, openocean[Hofmannet al., 1996;Hofmannand Klinck, 1998]. BransfieldStrait is separatedfrom the Weddell Sea by a shal- No evidence of dense shelf water formation is observed within low plateau (labeled "plateau"on Figure 1), with a deepest the Bransfield Strait; rather the water over the western Antpassageof 750 dbar (at station79), stretchingfrom Joinville arcticPeninsulashelfis modified(cooledand freshened)PaIsland to -61øS and 52øW.A 1000 dbar passagebetweenthe cific Ocean derivedCircumpolarDeep Water (CDW) [Hofplateau and Elephant Island is referred to as the Northeast mann and Klinck, 1998;Smithet al., 1999] or drawnfrom the Channel (Figure 1). The Bransfield eastern basin depth Weddell Sea along the southernboundary of the Bransfield reachesa depth of 2700 dbar; the central basin reaches1700 Strait [Clowes,1934;Gordonand Nowlin, 1978].An eastward dbar; and the westernbasin reaches1200 dbar [Wilsonet al., flowing current at the southernDrake PassageintroducesPa1999]. cific water into the northern fringe of the BransfieldStrait Clowes[1934], usingdata from the Discovery,DiscoveryH, within the 500-600 dbar deep channelseparatingSmith and and William Scoresbyexpeditions,noted that the deep and SnowIslandsof the SouthShetlandIslandchain[Capellaet al., 1992;Hofmann et al., 1996;Hofmann and Klinck, 1998]. Ad1Nowat Institutffir Umweltphysik, Universitaet Heidelberg, Hei- ditional CDW is introduced,perhapsin episodicevents,over delberg,Germany. the shallowershelf (400-500 dbar sill) betweenSmith Island Copyright2000 by the American GeophysicalUnion. and Brabant Island (Brabant Island is situatedsouthof 64øS near 63øW,not includedwithin the area coveredby Figure 1 Paper number 2000JC900030. 0148- 0227/00/2000JC900030509.00 [Hofmannand Klinck, 1998;Yangand Zhao, 1989;Smithet al., Between the South Shetland Islands and Antarctic Peninsula 11,337 11,338 GORDON ET AL.: DEEP AND BOTTOM WATER OF BRANSFIELD STRAIT Northeast Channel g,')' 61' 60' 59' 58'' 57'' 56' 55''154'v..•, 53' 52' 5•.... 50'W I b 63' '-'"' 61' 61'S 62' 62' 63' 64' 64' Figure 1. Region of the BransfieldStrait. DOVETAIL stations68-97 used in this studyare shown.The three deepbasinsare denotedby E, eastern;C, central;andW, western."Ant Sound"is AntarcticSound.The isobaths[Smithgng $gngw½ll,1997] includedare 100, 200, and 500 dbar and at intervalsof 500 dbar to the deepestvalues.The shadedarea denotesoceandepths<500 dbar. 1999].CDW may alsoenter the BransfieldStrait betweenthe source of the Bransfield basin water is confirmed, and water massmixingrecipesconsistent in temperature,salinity,oxygen, King George and Elephant Islands,with a sill depth of 400600 dbar [Yangand Zhao, 1989]thoughHofrnannet al. [1996] and CFC are presented. find mainly export of Bransfieldwatersthroughthat passage. Smith et al. [1999] find that the relativelystronggeostrophic flow toward the northeast at 200 dbar relative the western end of Bransfield Strait coincides to 400 dbar at with a front markingthe polewardlimit of >0øC CDW. This may be considered the BransfieldCurrent and BransfieldFront, respectively [L6pezet al., 1999].There is little exchangebetweenthe BransfieldStrait and west Antarctic Peninsula[Smith et al., 1999]. Gordonand Nowlin [1978] studiedthe origin of the Bransfield basinwater usinga few deep-reachingstationsobtainedin 1975. From the potentialtemperature-salinity (0/S) relationship they find that the Bransfieldeasternbasin and adjacent northwest Weddell Sea share a common cold end-member: 2. DOVETAIL Data As part of the Deep Ocean Ventilation Through Antarctic IntermediateLayers(DOVETAIL) programthe northwestern Weddell, southern Scotia Sea, and Bransfield Strait were sam- pled from the polar researchvesselNathanielB. Palmer for temperature, salinity, oxygen,and CFCs during the austral winter seasonof August-September1997 [Gordonet al., 1998; Menschet al., 1998a]. Drift betweenthe precruiseand postcruisetemperaturecalibrationswas <0.0004øC,implyinga temperatureaccuracyof better than the manufacturer's stated value of 0.001øC. The averagedifference in readingsbetween the two conductivityfreezingpoint water with a salinityof 34.62. They suggestthat temperature-depth (CTD) temperaturesensorswas0.0005øC. this water is derived from the continental shelf at the tip of The CTD conductivitywas adjustedto conductivitiesderived Antarctic Peninsula.They surmisethat it is advectedfrom the from water samplesanalyzedfor salinityduringthe cruiseon a Weddell Sea by the northwarddrift along Antarctic Peninsu- Guildline 8400B laboratory salinometer.The same batch of la's easternmargin.The lack of a significantpresenceof warm, International Associationfor PhysicalSciencesof the Oceans saline deep water, in the form of CDW or of Weddell Deep (IAPSO) standardwaterwasusedthroughout(P131). A CTD Water (WDW) within the BransfieldStrait,explainsthe colder conductivitysensordrift correctionof •0.001 mmho/cmper form of the Bransfieldbasindeep and bottom watersrelative month was applied prior to adjustmentto the bottle data. to the neighboringopenocean.The centralbasindeepwater is Replicatesalinometersalinitymeasurements agreedto within substantiallycolder, more saline, and higher in oxygenthan _+0.002(two standarddeviations).Dissolvedoxygenconcenobservedin the easternbasin.They find that the westernbasin- tration was rrfeasffred with an automatedtitrator utilizingan bottom water is warmer than that of the other two basins, optical endpoint detector.Replicatevaluesagreed to within denoting much reduced accessof the cold shelf water end- 0.01 mL/L (two standarddeviations)or 0.2%. Measurement memberor, more likely, increasedmodifiedCDW input from accuracyof CFC is estimatedto be 0.005 pmol/kgor 1% with the west. a detectionlimit of 0.005 pmol/kg. Potentialtemperature,salinity,oxygen,and CFC-11 sections Whitworthet al. [1994]view both the Weddell-ScotiaConfluence and Bransfieldbasin renewal not as a convectivepro- composedof stations82 and 86-96 characterizethe waters cessbut rather asan isopycnalprocess.Mixturesof CDW with along the BransfieldStrait eastern and central basins,across somewhatcooler Weddell Deep Water (WDW) and near- the plateau,and into the northwestedgeof PowellBasin(FigfreezingpointAntarcticshelfwater spreadinto the deepwater ure 2). Stations68-84 samplethe watersover the crestof the along densitysurfaces. JoinvilleRidge (stations68-75) whichdefinethe WeddellSea In the present study the Weddell Sea shelf origin for the input, acrossthe plateauand NortheastChannel(stations75- GORDON ET AL.: DEEP AND BOTTOM 96 95 (a) o 94 500 93 92 ....0.1-" WATER OF BRANSFIELD 91 90 82 89 88 87 STRAIT 86 o D' 500 1000 1000 \ • 11,339 \ 1500 • 2000 13_2500 2500 13_ 3000 3000 3500 POT. TEMP. (øC) Bransfield 3500 Strait 4000 4000 400 350 300 250 200 150 100 50 0 Distance (km) (b) 96 95 94 93 92 91 90 82 89 88 87 86 0 0 500 ...... • 500 lOOO •.5• •1500 • 1500 2000 2000 13_2500 • • 2500 Q. 3000 3000 3500 SALINITY 3500 Id Strait 4000 4000 400 350 300 250 200 150 100 50 0 Distance (km) Figure2. (a) Potentialtemperature (øC),(b) salinity,(c) oxygen(mL/L), and(d) CFC-11(pmol/kg)along the central axisof the BransfieldStrait, composedof DOVETAIL stations86-89, 82, and 90-96. The referenceletterscorrespond to thosegivenon thescatterplots (Figure4): D denotestheWeddellDeepWater; D' andD" indicatethepositionof weakwarmdeepcorelayer(500-750dbar)in the easternandcentralbasin, respectively. Be andBc represent bottomwaterof the easternandcentralBransfield basins, respectively. Bc' is the weak salinityminimumnear 1000dbarwithin the centralbasin. 84) of the BransfieldStraiteasternboundary(Figure3). The potential temperatureversussalinity,oxygen,and CFC-11 scatterplots (Figure4) arereferenced to the sections byS,shelf water; D, deep water; and B, bottomwater. basin,the WDW 0ma x at 1000 dbar is only slightlyabove0øC (station86).At stations 87-89 (Figure2) and78-81 (Figure3) the warmest, most saline water is in contact with or close proximityto the shallowseafloor.Thiswater spansa temperature range of -0.4 ø to -0.7øC and salinityof 34.54-34.56, (D). The WDW potentialtemperaturemaximum0ma x core with oxygenlevelsof 6.0-6.3 mL/L and CFC-11 of 2.5-3.3 attenuatesas the continentalmarginis approached,as typical pmol/kg,and may be consideredas modifiedWDW. A weak0ma x (colderthan -0.6øC) near500 dbarwithinthe of Antarctic margins.At the northwesternfringe of Powell The warmest water in the Weddell Sea is that of the WDW 11,340 GORDON ET AL.: DEEP AND BOTTOM WATER OF BRANSFIELD STRAIT 96 (c) o 500 95 94 93 - -- _, . •),r' 6.3--. 92 91 90 82 89 88 87 86 o 500 ß "'--- '--'- -- '- ...'902'MIN ß ß 1000 . lOOO ß 1500 1500 2000 2000 2500 2500 3000 3000 OXYGEN ( mL/L ) 3500 3500 Bransfield Strait 4OOO 4OOO 4OO 350 300 250 200 150 100 0 50 Distance (km) (d) 096' 95 94 93 92 91 90 82 89 88 87 86 0 500 500 lOOO lOOO 1500 •1500 '0 '- 2000 2000 2500 o_ 2500 3000 3000 3500 3500 4OO0 4OOO 4OO 350 300 250 200 150 1O0 50 Distance (km) Figure 2. (continued) easternbasin(D'), closerto 700dbarin thecentralbasin(D"), are both coolerandfresherthanWDW (D). The easternbasin 0max (D') maybe explained bywestwardspreading of thewater observedslightlyoff the plateauseafloor to the east.The 0ma x at station90 is too warm for a perfectfit to D'. Thereforeit is likelythat southernDrake Passage pycnocline water,whichis warmerthanthat of the WeddellSeaat anygivensalinity(e.g., station84, Figure4a), infiltratesthe easternbasin. Over the central Bransfieldbasin the 0ma x (D") is deeper than that in the easternbasinwith highersalinity(34.570) and lower oxygenand CFC-11 concentrations (6.3 mL/L and 3.2 pmol/kg,respectively). The main differenceof D" from the near bottomwater of the plateauis that D" is saltier.While it is temptingto believethisis a reflectionof CDW enteringthe BransfieldStrait betweenSnowand Smith Islands,thismaynot be the situation.The Snow/SmithCDW intrusionis expected to advectalongthe northernboundaryof the BransfieldStrait, followingthe regionalcycloniccirculation,probablyexitingthe BransfieldStrait without entering the central basin [Clowes, 1934;Smithet al., 1999].It is suggested that the centralbasin 0max(D") is a simpletwo-pointmixtureof low-salinity shelf water, S1, which is observed east of Joinville Island, with WDW (D; along the dashedline connectingS1 and D on Figure4a). A slightlywarmerform of sucha mixtureis ob- GORDON ET AL.: DEEP AND BOTTOM WATER OF BRANSFIELD STRAIT (qp) e•nsse•cl (qp) o•nsso•cl (qp) e•nsse•cl m (qp) o•nsse•cl (qp)oJnssoJd (qp) oJnsso•cl (qp) e•nsse•cl •c• (qp)oJnssoJd 11,341 11,342 GORDON ET AL.: DEEP AND BOTTOM WATER OF BRANSFIELD STRAIT (b) 0.8 (a) 0.8 0.6 ,.,.,-73 -- /4t++?= . ' '•+.+D + 68-73 0.4 77-81 85 0.2 • 82, 86-89 • 90-93 94-96 • -o.4 (D / l;:-o.6 I- -o.8 / ..•.•'• / •x••, x 77-81,85 •oO.' +++x • . / • •;C(•,•;/. •.++.• ] o•0.0ß ' -5?•' /p•• ••f•? • •-0.2 ' *•'..••' ••- ß•• •(•;t • -4 ++•+ • • :$•;•/• •:• 1 • .•;,- i [-•. . ß 83,84 082, 86-89 • 90•93 c94-96 .o •-0.8 -1.0 -,-' -1.2 o -1.4 -1.4 -1.6 ..,•• •-•••.t:. + •?t ,{ / ] -•.• -1.8 [,34.3 -2.o 34.2 , ,/ ", 34.4 34.5 34.6 l 1 34.7 -2.o 5.0 Salinity 5.5 6.0 6.5 7.0 7.5 8.0 Oxygen (ml/I) (C) 0.8 0.6 +%++ + 68-73 0.4 J 74-76 + + + x 77-81, 85 ++ xx xo0 + x ß 0.2 ++ x ß 83, 84 x• ., *•, .•,p + o82, 86-89 ß E 90-93 x • -0.4 (D c 94-96 +++ ++,it ßß ßxxøX• E -0.6 ++lit ß •EE , i-- -0.8 -,-' -1.2 0 -1.4 -1.6 ß x•_o -1.8 I -2.0 1 , I 2 , I 3 , I , 4 rS'•, S21 5 6 CFC-11 (pmol/kg) Figure 4. (a) Potential temperature(øC) versussalinity,(b) potential temperature(øC) versusoxygen (mL/L), (c) potentialtemperature(øC) versuschlorofluorocarbon CFC-11 (pmol/kg)relationshipsfor the DOVETAIL stationsshownin Figure 1. The referenceletters correspondto those given on the sections (Figures2 and 3): D for deepwater; and Be and Bc for bottomwater of the easternand centralBransfield basins,respectively.Bc' is the weak salinityminimum within the deep water of the central basin. S1 and S2 are the freezingpoint shelfwatersfound adjacentto JoinvilleIsland. P is pacificpycnoclinewater observed at station 84 that may be form minor constituentof Bc. served at the 0ma x of station 79 near 600 dbar, the deepest minimum near 1000 dbar (Bc'), which may sharea common of the Weddell Sea to the Bransfield Strait within originwith the easternbasinbottomwater,discussed in section3. the plateauregion. Bottom water in the easternbasin (Be) is about -1.01øC, with salinity slightlyless than 34.558, oxygenof 6.55 mL/L 3. Discussion (81% of full saturation),and CFC-11 of nearly 3.67 pmol/kg. Bottom water within the central basin (Bc) is substantially 3.1. Bransfield Basin Deep Basin Source Waters With the eastern and central basin water characteristics in colder (-1.62øC) and saltier (34.580) with elevated oxygen concentrations (nearly7.08mL/L; 86% of full saturation),and mind, we can inspectthe Weddell water off the tip of Antarctic CFC-11 of 4.79 pmol/kg.The centralbasinhasa broad salinity Peninsula(Figure3) to locatethe potentialsourcewatersand connection GORDON ET AL.: DEEP AND BOTTOM WATER OF BRANSFIELD Table la. Characteristics of Bottom Waters of the Eastern and Central STRAIT Bransfield 11,343 Strait Basinsand of ContributingSourceWater Types DOVETAIL Potential Station Water Type Identifier Temperature Salinity Oxygen CFC-11 74 100 m lower-salinityshelf S1 -1.894 34.500 7.47 5.28 75 bottom 92 95 saline shelf eastern basin central basin S2 Be Bc -1.914 - 1.007 - 1.615 34.599 34.558 34.580 7.69 6.55 7.08 5.60 3.67 4.79 70 0max 96 1000 m Weddell Deep Water Sminin central basin D Bc' 0.564 -1.200 34.680 34.550 4.92 6.76 0.67 4.13 derivequantitative mixingrecipesconsistent with the DOVE- Remarkably,the O/S characteristicsof the bottom water observedat station 73 matchesthe temperature and salinity of the easternbasinbottomwater (Be; station73 bottomwater is 0.008øCcolder and 0.003 saltier than Be). Station 73 bottom water is slightlylower in oxygenconcentration(6.44 at station 73 versus6.54 mL/L of Be) and CFC-11 values(3.4 versus3.7 pmol/kg) than that of the easternbasin,but the oxygenand CFC-11 gradientsbetweenstations73 and 74 are quite large (Figure 3), and one can envisionwater slightlywestof station 73 more closelymatchingBe dissolvedgasconcentrationwithout producinga significantmismatchwith O/S characteristics. Comparing O/S properties east of Joinville Island with those north of the island(Figure 3) revealscontinuityof properties alongisobaths,implyingan isobathfollowinggeostrophicflow path aroundJoinvilleIsland into the easternbasin. The source of the eastern basin bottom water is clearly drawn from the inshore edge of the shelf-slopefront of the bottom water portraysa more complexrecipe than that of the easternbasin.The centralbasinsalinebottom water (Bc) requiresshelfwater componentmore salinethan that of S1. The water within the central basindeep water followsalong a O/S line connectingBc' and Bc. Extrapolatingthis O/S structureto the freezing line suggestsa shelf water componentof salinity 34.59 (S2), aboutwhat is neededas the cold end-memberfor the bottomwater of the westernWeddell Sea [Gordon,1998]. The salineshelfwater, S2, requiredby the centralbasinbottom water is observedadjacentto Joinville Island. Stations74-76 show near-freezing point shelf water, reaching a salinity of 34.60 at the sea floor. This water, proposedto be the cold end-membersourcefor Bc, spreadsinto the BransfieldStrait alongwith the over the Antarctic Peninsulaside of the Bransfield Strait, passingto the southof the easternbasin. Freezingpoint shelfwater is expectedto be high in oxygen and CFC owing to recent interaction with the atmosphere acrossthe sea-air-iceinterface. The Joinville Island regional shelfwater is indeed rich in theseproperties.The oxygenand CFC-11 of S1 are -7.5 mL/L and 5.3 pmol/kg, respectively, and thoseof S2 are slightlyhigherat 7.7 mL/L and 5.6 pmol/kg, respectively.The S2 propertiesare closeto that of the Weddell Sea high-salinityWestern Shelf Water, believed to be a product of the coastalpolynyas[GammelsrOd et al., 1994].That S2 is slightlymore ventilated than St may be explainedby its greater contactwith the atmosphereafforded by the polynya western Weddell environment. TAIL temperature,salinity, oxygen,and CFC data. Stations68-75 (Figure1) depictthe typicalcontinentalmargin stratificationof the westernWeddell Sea [Fahrbachet al., 1995;Gordon,1998].The WDW 0max core(D) isnear600dbar at stations68-70. The shelf-slopefrontal transition occurs between stations 70 and 73. Within this zone, traces of WDW form a weak temperature maximum at middepth over the continental shelf and at the 300 dbar sea floor at station 73. Sea off Joinville Island. The water mass mix- ture that eventuallyfills the easternBasinis alreadyachieved east of Joinville Island near 300 dbar. This water sinks into the eastern basin without further dilution, in what Whitworthet al. [1994]refer to asisopycnalspreading.A mixtureof WDW and low-salinityWeddell shelfwater rendersthe simplestexplanation for the eastern basin bottom further water mass modification water. within No need is seen for the Bransfield Strait. The centralbasin salinityminimum (Smin near 1000 dbar; Bc') is basicallythe same as the easternbasinbottom water (Be). The bottomwater of the easternbasinmay either share a commonorigin with the central basinSminof may be derived from overflowof the Sminwater into the easternbasin.As the match between Bc' and Be is best at station 96, at the western end of the central basin, while at station 94, located closer to the controllingsill is slightlytoo salineto match the Be water, the sharedcommonsourceis a favored explanation(though the two scenariosare not mutually exclusive).L6pez et al. [1999] present50 daysof direct current meter data collected during the austral summer of 1992-1993 at 700 dbar depth near the sill dividingthe easternand centralbasin.The current is weak and directed toward the south,with no evidenceof flow towardthe east,aswouldbe expectedif overflowwere present. The nonlinearO/Srelationshipof the centralbasindeep and 3.2. Bransfield Basin Deep Basin Mixing Recipes The water typeblendsinferred from propertycharacteristics are used to find a mixing recipe consistentwith the DOVETAIL temperature,salinity,oxygen,and CFC data. The percentagesof the Be buildingblocks,St, and D (Table la) are determinedfor each parameter (O/S, 02, and CFC-tt), assuming a simple linear mixture. The suggestedrecipe is the averageof the components(Table lb). The bottom water of the eastern basin, Be, is approximatelya 35:65 mixture of WDW (D) to low-salinityshelfwater (St). Temperature,salinity, oxygen,and CFC-11 all give essentiallythe samemixing ratios. That the time-dependent parameters of oxygen and CFC-11 yield the same ratio as temperature, and salinity implies a rapid ventilation timescale,10 years or less. As mentionedabove,the recipe of the centralbasinbottom water, Bc, is more complex than that of the eastern basin, clearly involvingmore than two end-members.We first investigate the possibilitythat the formation of Bc involvesonly threewater types:WDW (D), the low-salinityshelfwater (S1), and the higher-salinityshelfwater (S2). The percentageof the buildingblocksare calculatedas follows:first a linear mixture of D and S1 is used to produce the warm end-memberof the 11,344 GORDON ET AL.: DEEP AND BOTTOM WATER OF BRANSFIELD Table lb. Mixing Recipesfor Productionof Observed BottomWaters of Eastern(Be) and CentralBasin(Bc) Potential Identifier Temperature Salinity Oxygen CFC-11 Eastern Recipe for Be Recipe for Bc (Weddell Only) Basin S1 36 64 32 68 36 64 35 65 D S1 S2 Central Basin 12 30 58 11 28 61 18 47 35 14 41 45 D STRAIT agesfor D, S1, and S2 asP is increasedfrom 1% by increments of 1% (the aim was to minimizethe need for pycnoclinewater). The mostprobablerecipeis determinedwhen the resulting value for Bc is closestto the observedvalue for Bc. The resultrecipe leadsto more consistentinput of eachparameter than afforded by only a three componentmixture. A ratio D:Si:S2:P of 11:24:60:5yields a Bc of nearly the observed propertiesof Bc (Table lc). It appearsthat a smallamountof Pacificpycnoclineinput to Bc is likely, effectivelyreplacing someS1 water of a "Weddell-only"blend. Wilsonet al. [1999] present temperature and salinity data obtained in November 1995 from Nathaniel B. Palmer within Values are given in percentage. the BransfieldStrait.They investigatethewater massblendsof the bottomwater of the easternbasin,but lackingoxygenand CFC data, they had lesscontrolof the recipepercentagesthan mixturewith S2 formingBc (see the dashedline betweenS2 affordedby the 1997DOVETAIL data set.Direct comparison and its intersectionwith the dashedline denotingthe S1 and D of their recipe to ours is complicatedas they did not use the linear mixture producingBe, Figure 4a). This warm end- primarywater typesthat have accessto the BransfieldStrait. member is approximatelythe same as Bc', the Smin at 1000 They useWeddell Sea BottomWater (WSBW) as one of the dbarswithin the centralbasin.The percentagesof S1 and D to ingredientsrather than its buildingblocksof WDW and freezproducethe warm end-memberfor Bc are determinedfor each ing point shelfwater. WSBW is clearlyblockedby topography parameter. Calculation of the mixture of the warm end- from enteringthe BransfieldStrait,whereasthe buildingblock member and S2 to form Bc are determined in similar manner. water types have access.They do note this and say that the The averageof the mixturesindicatedby the four parameters convection of surface waters that form WSBW have access to are usedfor the final suggested recipe. the BransfieldStrait, but they do not explorethis quantitaThe percentagecomponentsof D:SI:S2 derived from tem- tively. Furthermore, their 1995 data do not include synoptic perature and salinityare 11:29:60(Tables la and lb). How- observationsat the eastern boundary of BransfieldStrait as ever, the ratios found from oxygenand CFC-11 are different obtained during the DOVETAIL 1997 expedition;instead, from thosebasedon thermohalineparameters,which are 18: they use 1976 data to representone of their three ingredients, 47:35 for oxygen and 14:41:45 for CFC-11. This implies a the Weddell Sea sill water (Weddell waterspassingover the slightlyslowerrate of ventilationfor the centralbasinthan for easternboundarysills).They saythat this representsthe largthe easternbasin,but the CFC ratios do not supportthis. The est uncertaintyin their calculations. bottom water in the central and eastern basin are estimated to Wilsonet al. [1999, p. 471] find that easternbasinbottom have CFC-113:CFC-11ratiosagesof 7.5 years(basedon five water is a mixture of "central basin sill water, Weddell Sea sill samplesfrom the lower 500 dbar at station 95, CFC-113: water, and Weddell Sea Bottom Water." The Weddell Sea sill CFC-11 ratio rangeof 0.084-0.086) and 8.5 years (basedon water composes40-60% of the easternbasin bottom water. the four samplesfrom the lower 500 dbar at station92, CFC- We agreethat the sill watersof the centralbasinmay overflow 113:CFC-11 ratio range of 0.077-0.078) years, respectively. into the easternbasin,but we alternativelystatethat they may This is similarto the ageof Weddell Sea Bottom Water, 7 +_2 share common origin involvinglow-salinityshelf water from years,observedin the northwestWeddell Sea [Menschet al., the Weddell Sea. In the eastern basin this water type can descend to the sea floor, but in the central basin, denser bot1998b]. We next explore a recipe for Bc, which requires a small tom water, enriched in a high-salinityshelf water from the contributionof Pacificpycnoclinewater (P). The Pacificpyc- Weddell Sea, prohibitsdescentto the seafloor. noclineis of lower oxygenand CFC-11 concentrationthan the Perhapsthe most significantcontrastin the 1995 and 1997 Weddellpycnocline.Thiswater mayenterthe BransfieldStrait from the west between Smith Island and Antarctic Peninsula alongwith PacificCDW [Hofmannand Klinck, 1998].Tracing Table lc. Mixing Recipe for Central Basin Bottom Water a straight line from S2 along the O/S scatter of the bottom InvolvingPacificPycnoclineContribution water in the centralbasinwould meet the pycnoclineof station Potential 84 near -0.3øC (point P on Figure 4). Specificpropertiesof Identifier Temperature Salinity Oxygen CFC-11 point P are given in Table l c, basedon the averageof water samplesat 200 and 250 dbar. Station 84 displaysthe warmest P -0.35 34.48 6.14 3.09 pycnoclinewater of the DOVETAIL data setwithin the Brans- Bc observed - 1.615 34.580 7.08 4.79 - 1.556 34.579 7.26 4.86 field Strait environs,reflectinginfluenceof Pacificwater. Using Bc calculated station84 pycnoclinepropertiesasthe warm end-membermixRecipe ing partnerwith S2 yieldsa P:S2of 19:81for temperatureand Components Percentage salinity but 40:60 for oxygenand 33:67 for CFC-11, no improvement over mixtures that involve only Weddell water D (Table la) 11 types. We find that mixturesinvolvingall four water types(D, S1, S2, and P) provide a more convincingrecipe.The four-point mixture involvingPacificpycnoclinewater to derive a recipe for Bc involvesa trial and error processof adjustingpercent- P (Table lc) S1 (Table la) S2 (Table la) 5 24 60 The DOVETAIL stationfor Pacificpycnoclinewater (P) is station 84 between 200 and 250 dbar. GORDON ET AL.: DEEP AND BOTTOM WATER OF BRANSFIELD Northeast STRAIT 11,345 Channel --,o 60ø 59ø 580 570 560 550 •54ø 53ø 5'"o • ," 630 62 ø t•" ""o'• 3,'/r• I'"•^•-•,..• I • I --•TM •• .... ß oDra,•ke•Passage/.•/' . , ,•:':•;:• • o •1 50ow 61 1øS o Figure 5. Schematicof the flow pathsinto the BransfieldStrait'seasternand centralbasins.Solid arrows denotemovementof Weddellwaters.Thesewatersare a combinationof freezingpoint low-salinity(S1) and high-salinity(S2) shelfwaterwith smalleramountsof WeddellDeep Water. The centralbasinreceivesa more salineform of shelf water. Dashed arrowstrace the pathwaysof CircumpolarDeep Water and pycnocline water from the Pacificsectorinto the BransfieldStrait. The pycnoclinewater may be a minor constituentof the central basinbottom water. The solid arrow drawn along the NortheastChannel is the expectedexport path for Bransfieldbasinwaters.The open arrow throughAntarcticSoundis pure conjecture,as no data are availablein that area,but it is deepenoughto providea pathwayfor shelfwater and henceis includedasonly a possibility. data setsis the warming seen in the bottom waters of the easternand centralbasinsduring the intervening2 years.The Wilsonetal. [1999]station7, whichcoincides with DOVETAIL station92, showsthat the bottom water in 1995 is nearly 0.2 colderthan that of 1997.Approximatelythe samedifferenceis the westernrim of the Weddell Sea composes--•65% of the bottom waters within the eastern basin and between 80 and 90% of the central basin bottom waters. On the basisof the distributionof water typesover Joinville Ridge and on the mixing recipesfor Be and Bc a flow path seen for the other stations in the eastern and central basins. schematic(Figure 5) is proposed.A mixtureof Weddell shelf Using a coldervalue for Be basedon the 1995 data requiresa water and deep water advectsnorthwardpast JoinvilleIsland WDW:S1 ratio of 28:72 rather than 36:64 (both based on to enter the BransfieldStrait. The saltierfreezingpoint shelf temperature)asfoundwith the 1997data. Salinitydifferences water (S2) turns into the Bransfield Strait very close to betweenthe 1995 and 1997 data are slight,as expectedfrom Joinville Island contributingto the central basin, bypassing the small salinity range of the componentwater types. It is the eastern basin. While a flow path of S2 water into the suggested that a slightreductionin shelfwater componenthas central basin passesaround the eastern edge of Joinville occurredin the intervening2 years. Island, the possibilitymustbe reservedfor an additionalflow Wilsonet al. [1999] investigatethe temporalchangesin the path passingwest of JoinvilleIsland, within Antarctic Sound BransfieldStrait deep and bottomwatersfor the last 30 years. (Figure 1). They find the changesin the easternbasinbottom water has The lower-salinityshelfwaters may enter the easternbasin been sporadicwith the warmest,saltiestwatersfound in 1963 directly or first enter the central basin forming a 1000 dbar (-0.84øC; 34.60), while the 1995 valuesare the coldestand deep salinityminimumwith subsequentoverflowinto the eastfreshest.The 1997 bottom water propertiesreversethe 1963- ern basin. Pacific water enters the Bransfield Strait from the 1995 trend (thoughwe do not have a completetime series west and throughpassages in the South ShetlandIslands.Enbetween1963 and 1995 to fully resolvehigher-frequency varitering from the west contributesto the bottom water of the ability);the 1997bottomwater wasstill muchcoolerthan the 1963 conditions. central basin. Where does the basin residencewater displacedby newly formed deep water go? Station 83 (the cooler of the two 4. Conclusions stationsshownas solid circlesin Figure 4, the other being station 84) within the Northeast Channel is the most likely The bottom waters of the Bransfield Strait's eastern and central basinsare primarily derived from the Weddell Sea candidate marking an export pathway. There is no obvious watersenteringthe BransfieldStrait from the region off Join- exportof concentrateddeepbasinwater. Rather it is suspected ville Island. The bottom waters of the central basin contain a that the basinwater is lifted into the pycnoclinelayer of the Weddell-Scotia Confluence,where it is rapidly exportedeastsmallamountof pycnoclinewater from the Pacificwater column. All of the deep water ingredientsare imported; there ward. The fate of this pycnoclinewater, as it spreadsinto the does not appear to be a need for water massmodification Scotia Sea, requirescareful study.Its densitymay allow it to within the BransfieldStrait. Freezing point shelfwater along eventuallyventilate the deep ocean. 11,346 GORDON ET AL.: DEEP AND BOTTOM WATER OF BRANSFIELDSTRAIT Acknowledgments. The researchis supported by NationalScience Hofmann,E. E., J. M. Klinck, C. M. Lascara,and D. A. Smith,Water mass distribution and circulation west of the Antarctic Peninsula and Foundation grantOPP95-28807andbya grant/cooperative agreement including Bransfield Strait,Foundations for Ecological Research west from NOAA (UCSIO P.O. 10075411).The tracerchemistry is supof theAntarcticPeninsula, Antarct.Res.Set.,vol.70, editedby R. M. portedbyNSFgrantOPP95-28806. ZhaoqianDongwasonleavefrom Polar Research Institute of China. His residenceat Lamont was sup- Ross,E. E. Hofmann, and L. B. Quentin, pp. 61-80, AGU, Wash- portedin partbytheChinese Commission onScience andTechnology ington,D.C., 1996. grant98-927-0101 and in part by OPP 95-28807.The DOVETAIL L6pez, O., M. Garcia,D. Gomis,P. Rojas,J. Sospedra,and A. CTD data collectiongroupwere B. Huber, P. Mele, A. Orsi, S. Ma, and R. Iannuzzi. S. Green and S. Peacockperformed the oxygen analysis. G. MathieuandS.MathieuperformedtheCFC analysis. The Palmerofficersand crewand the ASA groupprovidedexcellentsup- Sfinchez-Arcilla, Hydrographic andhydrodynamic characteristics of the easternbasinof BransfieldStrait (Antarctica),DeepSeaRes., Part I, 46, 1755-1778, 1999. Mensch, M., W. M. SmethieJr., and P. Schlosser,Tracer oceanogra- phyin the WeddellScotiaConfluence duringNBP 97-5, U.S.Antport. Particularthanksis givento the anonymous reviewers of this paper,whosedetailedcomments greatlyimprovedthe presentation. arct.J., in press,1998a. The viewsexpressed hereinare thoseof the author(s)and do not Mensch, M., W. Smethie Jr., P. Schlosser,R. Weppernig, and R. Bayer,Transienttracerobservations from the westernWeddell necessarily reflecttheviewsof NOAA or anyof itssubagencies. LDEO Contribution 5895. 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