Econom/cGeo/ogg Vol. 84, 1989, pp. 135-142 SCIENTIFIC COMMUNICATIONS PALEOZOIC HOT SPRING SINTER IN THE DRUMMOND BASIN, QUEENSLAND, AUSTRALIA RONALD CUNNEEN RGC ExplorationPty. Limited, 16 DouglasStreet,Milton, Queensland4064, Australia AND RICHARD H. SILLITOE 8 WestHill Park,HighgateVillage,LondonN6 6ND, England Introduction Sinter constructsterraced apronsaround the hot springdischargesitesof manyactive,high-temperature (>150øC) geothermalsystems,suchas thoseat SteamboatSpringsin Nevada,Yellowstonein Wyoming, and Wairakei in North Island, New Zealand. Recentprogressin the understanding of epithermal systemshasled to the recognitionthat identicalhot extensional grabens(Hutton, 1988) andare interbedded with volcanicrocks(Olgers, 1972). In the easternpart of the Drummond basin, east of the Anakieinlier (Fig. 1), the lower,volcanic-dominatedpart of the sequenceis representedby the Sil- verHillsVolcanics (Olgers,1972),whichin theMount Coolon area consistof rhyolitic ignimbrite and tuff interbedded with lithic and feldspathicsandstone, springsintercharacterizes the paleosurfaces above siltstone,and shale(Grimeset al., 1986). Sedimentation and volcanism in the Drummond severalshallowepithermal(or hot spring)gold-silver basin ceasedwith the onsetof widespreadmid-Cardeposits(e.g., White and Heropoulos,1983). Wellboniferous orogeny,duringwhichthe Late Devonianpreservedexampleshavebeen reportedaboveepiearly Carboniferous sequenceunderwentopenfoldthermalgold-silverdepositsof middleto late Cenozoicageat McLaughlinin California(Lehrman,1986), ing (Olgers, 1972). The late CarboniferousBulgoHasbrouckMountain (Graney, 1987) and Buckskin nunna Volcanics were deposited unconformably Mountain (Vikre, 1985) in Nevada, and elsewhere. acrossthe northeasternpart of the Drummondbasin (Fig. 1) andwere broadlycontemporaneous In this paper we report the discoveryof identical sequence with a number of felsic intrusions. pristinesinterfrom an epithermalsystemof Late Devonianage--to our knowledgethe onlypre-Mesozoic Local Geology exampleof unambiguous sinterdocumentedto date. The Verbena epithermalsystemwasdevelopedin The sinterand associatedhydrothermalproductsare located in the Drummond basin of east-central volcanicand sedimentaryrocksassignedby Olgers Queensland,Australia.The site, centered on latitude (1972) to the Silver Hills Volcanics.As depicted in three volcanicand 21 ø29'29"S, longitude147ø26'43•'E, is nearthe Ver- Figure 2, we have distinguished bena (syn.Glen Eva and Glenifer) homestead,some three sedimentaryunitsin andaroundthe mineralized 15 km southeastof Mount Coolonvillage and the area. The volcanicrocks are rhyolitic ignimbrites, which carryvariableproportionsof pumiceandlithic nearbygold deposit(Fig. 1). clasts,andunderwentlittle or no welding.The sediRegional Setting mentaryrocksare epiclasticand dominatedby lithThe Drummond basin is a structural remnant of a ofeldspathic sandstone,which is interbeddedwith largeintracratonicbasinthat developedafterthe mid- subordinatesiltstone,andlocally,with conglomerate. Devonian Tabberabberanorogeny in the northern The sedimentaryunits displayhigh-anglecrossbedpart of the Tasmanorogeniczone (Fig. 1) of eastern ding and ripple marks,and locallycarry poorly preAustralia(Olgers,1972). The Drummondisa foreland servedfossilsof plant stems.Two of the three sedibasinandprobablyoccupieda back-arcpositionwith mentary units contain sinter horizons,as described respectto a subaerial,Andean-typevolcanoplutonic below. The Late Devonian rocks which acted as hosts for arc farther east (Powell, 1984; Murray, 1986). The Drummondbasinsequence,of Late Devonianto early the Verbena epithermal systemunderwent gentle Carboniferousage, was depositedon a basementof foldingduringthe mid-Carboniferous to producetwo early and mid-Paleozoicmetamorphicand granitic synclinesand an interveninganticline(Fig. 2). The rocksandcropsout oversome25,000 km2 (Fig. 1; foldsare characterizedby limbsthat dip mostlyfrom Olgers, 1972). The sequencecomprisesat least 20ø to 30ø; the foldsplungesoutheast to east-south12,000 m of mainlyfiuviatilesedimentaryrocks,the eastat 20 ø. No otherrock deformationnor anyfabric lower, Late Devonianpartsof which accumulatedin developmentwasrecognized. 0361-0128/89/901/135-8 $3.00 13 5 136 SCIENTIFIC COMMUNICATIONS 146c' km 148o 200 100 .Bimurra BOWEN 220 BASIN variousdegreesof pervasivesilicification,especially of hostsandstone. Locally,stockworks are transitional to hydrothermalbrecciain whichsimilarchalcedony ispresentasa cementto clasts.The middlesandstone unit (Fig. 2) isextensivelysilicifiedevenwherestockworkingis poorly developed.Accompanying hydrothermaleffects,tentativelyconsideredto be marked by the introductionof illite andsmectite,are largely maskedby supergenealteration,whichgeneratedkaolinite and subordinatechalky alunite. The stockworksappearto havebeen overprinted by a west-northwest-striking set of steepchalcedony veins.They cropout poorly, andthosemapped(Fig. 2) aretraceableonlyasalignedfloattrains.Individual veinsdo not attainwidthsgreaterthan0.5 m andmay be followed at surface for distances of 5 to 50 m. The veins exhibit abundant crustification and carbonate- .,,._,,,I \ 24* I replacementtextures(Fig. 3), the latter producedby hydrothermaldissolutionof lameliarcalcite.More locally, the veinscontainopen spaces,someresulting fromcalcitedissolution, thatarelinedwith tiny quartz crystals. The sulfide content of veins and stockworks is judged to be low (say,3 vol %) on the basisof the paucity of supergenelimonite. However, limonite tendsto be moreabundantin the adjoininghostrocks. Bulgonunna Volcanics vQ Anakie Metamomhics • ß Gold depositor prospect O Drummond Basin sequence (outcrop) FIG. l. Locationsof the Verbena hydrothermal systemand selectedgold depositsin the Drummondbasin of east-central Queensland.Geologytaken with slightmodificationfrom Olgers (1972). Sinter The principalexposures of sinter(Fig. 4A) are in the middlesandstone unit (Fig. 2). Two discretesinter horizonsdip at about20ø southeastward, andthe up- permostistraceablealongstrikefor some600 m. Althoughdepositionaldipsof this order havebeen recorded from modern sinter terraces (e.g., Beowawe, Nevada;Rimstidtand Cole, 1983), the presentattitude of the Verbena sinter is attributed to the effects The sinter-bearingLate Devonian rocksunderlie of folding.The mostextensivesinterhorizonat surface a low hill whichis surroundedby lateritizedmesasof exceeds 10 m in thickness whereas the more resedimentary accumulations, mainlypaleotalus of local stricted,lower sinter is 5 m thick. The two are sepprovenance,andRecentalluvium(Fig. 2). The later- aratedby about 1.5 m of sandstoneand siltstone.A itized paleotalusis consideredas part of the Suttor thinner horizonof sinter,probablyi to 2 m thick, is unit andcropsout on Formation,a regionallyextensivedetrital sequence presentin the lowersandstone the axis of the anticline (Fig. 2). of mid-Tertiary age (e.g., Grimeset al., 1986). All three beds of sinter are identical texturally to Hydrothermal Products their Cenozoicchalcedonicanalogues. They are well Chalcedonic veins, stockworks,and sinter at Ver- bedded, composedof dense, laminated, vitreous benaarepresentin a northwest-trending zoneranging chalcedony,and displayabundantinterlayercavities from 400 to 600 m wide and exposedover a strike up to 4 cm long which, althoughirregular in shape, extent of 1,500 m (Fig. 2). Sinter horizonsoccur in are elongateparallelto the layering(Fig. 4B). Indithe lower and middle sandstone units whereas veins viduallayersrangein colorfrom white throughgray and stockworksare most widespread in the middle to tan and orange-brownand are partly translucent. anduppersandstones andthe intervening(upper)ig- Brown colorsare due to pigmentationby limonite, whichalsolinesmanyof the cavities.No sulfideswere himbrite (Fig. 2). observed.Thin, irregular intercalationsof silicified Stockworks and veins sandwere observedvery locally in the sinter, and Stockworkscompriseirregular, multidirectional sinterfragmentswere notedin sandstone abuttingthe veinletsof dense,massive,porcelaneous chalcedony, thickestsinter.The sinteris devoidof fragmentaltexup to about 5 cm wide, which are associatedwith tures and crosscuttingfeatures. SCIENTIFIC COMMUNICATIONS 137 Beddingplanesin the sinterexhibitexternalmoulds than for all the United States sinters listed in Table of lycopodstems(Fig. 4C andD), randomarraysof 1, and the As valuesare lower than all exceptthose circularto polygonalcavities(up to 0.5 cmacrossand in the Beowawe,Brady,Coso,and McGinnessHills 0.25 cmdeep)of uncertainorigin(Fig.4E), geyserite sinters,with whichthey are comparable. "pearls,"andsilicifiedfilamentous bacterialmats(Fig. The contentsof Au, Ag, As, and Hg in oxidized 4F). Severalexternalmoldsof lycopodstemswith ex- vein ore from the Wirralie golddepositare an order ceptionally well-preserved ovateleafscars,andin one of magnitudeor moregreaterthanthoserecordedfor example, leaf molds, too (Fig. 4D), were ex- sinterandvein chalcedonyfrom Verbena(Table 1). aminedby J. F. Rigbyof the Queensland Geological However, Sb valuesfrom the two localities are comSurvey.He concluded(writtencommun.,1988) that parable(Table 1). theyresembleknownDevonian-early Carboniferous Environment of Formation formsbut probablyrepresenta newspecies. The bacterial mats are not dissimilar to those described from Sinter precipitationduring the Late Devonianat modern sinters (e.g., Yellowstone;Walter et al., Verbena took place in a fiuviatile environmentin 1972). whichlycopodsflourishedat times.Sinterwasa local Sinterwasmoreextensivepreviouslyasevidenced facies of the fiuviatile sediments and is believed to by thepresence of abundant angularfragments ofsin- have accumulatedin drainage channels.Fluviatile ter, up to 0.5 m in length,in Suttorpaleotalus,es- sedimentationwas interrupted periodicallyby depyroclasticflows.The volpecially400 m westof the principalsinteroutcrops positionof small-volume (Figs.2 and5). Paleotalus 200 m northoftheprincipal cano-sedimentarypackagelacks featuresindicative sinter(Fig. 2) containsclastsof distinctivegray-and of proximity to a volcaniccenter. However, recogwhite-bandedsinterunlikeany of that observedin nition of a flow-bandedrhyolite plug and associated situ. lavaflowsonly2 km southeast of the Verbenasystem, albeit at a higherstratigraphiclevel, suggests that igLithogeoehemistry nimbriteeruptionandhydrothermal activitymayhave Representativesamplesof sinter from the lower been relatedto an unlocatedandprobablyconcealed and middle sandstoneunits and of 12 typical chal- rhyolite flow-domecomplex. The Verbenasintersconstitutea stackedsystem, cedonyveinsat Verbenawere analyzedfor Au, Ag, activityclearlyhavingbeenactive, Hg, As, Sb, andBa by TetchemLabsin Cairns,Aus- withhydrothermal tralia.Analyses forAu andAgwereby fire-assay fusion at least intermittently,during the accumulationof with an atomicabsorption finish,the analyticaltech- some600 m of volcanicandepiclasticrocks(Fig. 2). niquealsousedfor Hg. Arsenic,Sb, andBa were an- Much of the chalcedonyveiningis presentin sandalyzedby X-ray fluorescence. The resultsare pre- stoneandignimbritewhichare youngerthanthe outsentedin Table 1, whichalsosummarizes analytical croppingsinters,andit mayhavebeencappedby one data for epithermalgold-bearingchalcedonyveins or more higher sinter horizonswhich are now confrom Wirralie in the Drummond basin (Fig. 1; see cealedor havebeenerodedaway.Sinterclastsin the below)andfor severalhot springsintersunrelatedto Suttorpaleotalusmayhavebeenderivedin part from higher sinterhorizons. knownpreciousmetal depositsin the westernUnited stratigraphically Fluviatile sedimentsand ignimbrites were accuStates.These American hot spring sinters overlie geothermalsystemspromotedby both felsic mag- mulatingwhile the Verbenaepithermalsystemwas matism(SteamboatSprings,LongValley, Coso,Roo- active. In fact, construction of the individual sinter sevelt)and high heat flow in a nonmagmatic basin- apronswas probablycurtailedby influxesof riverbornesediments. The relativelyfine grainsizeof the and-rangesetting(Beowawe,Pinto,Brady). suggests that the Late Devonian Table i showsthatthe epithermalsuiteof elements fiuviatilesediments in existenceduringthe lifespanof the isnot stronglyanomalous in either sinteror vein chal- paleosurfaces cedonyfrom Verbena.In fact, the averageAu, Hg, Verbenahydrothermalsystemwere subduedtopoburial Ba, and probablyalsoAg valuesare lower than the graphically.Thisfactor,alongwith progressive correspondingcrustal averages(Krauskopf,1967, by sedimentsand pyroclasticflows,and during the appendixIII). The only lithogeochemical difference late Carboniferous,beneath the BulgonunnaVolcabetweensinterandveinchalcedony isthehigherbar- nics,were conduciveto preservationof near-surface hydrothermal productsat Verbena.The Verbenasysium valuesin someof the vein samples(Table 1). Preciousmetal valuesat Verbenaare appreciably tem islocatedonthe southernedgeof the Bulgonunna lower than those determined for sinters at Steamboat Volcanics(Fig. 1) and thereforemay have been exSprings,LongValley,Roosevelt,andMcGinness Hills humedasrecentlyasthe earlyTertiary. but comparableto thoseat Beowawe,Pinto, Brady, The stackedconfigurationof sinterat Verbenais Coso(Table 1), and severalother sinter localitiesin reminiscentof that in the upperpart of the Steamboat the westernUnited States(White and Heropoulos, Springsgeothermalsystem,where three principal 1983). The Sb and Hg valuesat Verbena are lower sinter horizons are interbedded with basaltic and 138 SCIENTIFICCOMMUNICATIONS VVVVV vvvi vv •vvv ooooo o oo•ooo o •. o meters •.f r 147"26'40"E. FIG. 2. Surfacegeologyand interpretative crosssectionsof the Verbena hydrothermal system, Queensland.Veins are schematizedon crosssectionA-A'. rhyolitic volcanic products and alluvial deposits (White et al., 1964). Using radiometricand stratigraphicdating,Silbermanet al. (1979) showedthat hydrothermalactivityat Steamboat Springshasbeen active, possiblyintermittently, for >2.5 m.y. However, suchlongevityis not required at Verbena, althoughit cannotbe excludedon presentevidence. The sinter,with a preservedaggregatethicknessof <20 m, could have accumulatedin 6,000 yrs if the long-term rates of sinter accumulationsummarized by Vikre (1987) are employed.Depositionof the interbeddedignimbritescouldhave taken aslittle asa few days,andfiuviatilesedimentsare unlikely to representprotracted time intervals. Regional Comparisons Volcano-sedimentary sequencesof Late DevonianCarboniferousage in the Drummond basin are the SCIENTIFICCOMMUNICATIONS 139 A A' vvv"•,•. - . .•....•vvvvvvvvvvvvvvvv•,,• 9•9v-'•'•-•v9vvvvvvvvvvvvvvvv• i• .-'•- • '• ' vvvvvvvvvvvvvvvvvvv -•,.:, ,', ,'= j, ,-, .-..:_•.- ..V•V V VY•'" '"-'• !oo 1 I O= ......... : ' meters I I .. 1 500 . LEGEND Recent • Alluvium Chalcedony vein with calcite-replacement texture (subcrop only) Miocene Sunor oø• Lateritized talus Formation .• Late 8 •- Devonian• • •, / with abundantsinletclasts Hydrothermal breccia Sandstone,siltstone Outer limitof chalcedonyveins &veinlets Ignimbrite Sandstone, siltstone /sinter Ignimbrite .•27 Strike &dipofbeds '• Antidinal axis, with plunge Sandstone, siltstone (dotted where concealed) --...•.•Syndinal axis, with plunge Ignimbrite I--.J LINE ofSECTION • Drainage /sinter FIG. •.. (Cont.) veins,whicharecharacterized by hosts foronepreviously exploited (MountCoolon;chalcedony-quartz Morton, 1935) and severalrecently discoveredepi- crustification and carbonate-replacementtextures thermalsystemsof 1ow-sulfidation, adularia-sericite closelysimilarto thoseat Verbena.Furthermore, sintershavebeenrecognizedtentatype (Fig. 1). Two of them, Pajingo (Porter, 1986; poorlyexposed Etminan et al., 1988) and Wirralie (Fellows and tively at both Pajingo(R. G. Porter, pers.commun., Hammond,1988), containeconomicgold deposits. 1987) andWirralie (FellowsandHammond,1988). The limitedwidthsandlengthsof the chalcedony In fact, Wirralie was developedin broadly similar volcanicandsedimentary lithologiesto thoseexposed veinsat Verbenaare attributedto repeatedburialof at Verbena. Gold mineralization at Mount Coolon, the hydrothermal systemduringits lifespanandthe Pajingo,andWirralie is presentin wide, multiphase absencefrom the systemof a singlemasterstructure. Asa result,hydrothermalfluidflowkept changingits position withinthesystem, especially aftereachmajor burial event, and was not focusedthrough a single conduitfor a prolonged period.Therefore,the small individualveinsat Verbenadid not undergorebrecciationand failed to experienceas many stagesof openingandfillingasthe wideveinsat Pajingoand Wirralie (Etminanet al., 1988; Fellowsand Hammond,1988). However,giventhe dosesimilarityof veintexturesandmineralogy at Verbena,Pajingo,and Wirralie, we believethat the totallybarrencharacter of the Verbenasystemultimatelyreflectsthe passage of hydrothermal fluidsdeficientin preciousmetals and other elementsof the epithermalsuite. FIG. 3. Carbonate-replacement texturesin chalcedonyvein, Verbena,Queensland. Finally,it shouldbe mentionedthat the nearest golddepositto Verbena,at'MountCoo!on(Fig. 1), differsmineralogically from the otherprincipalepi- INCH .! .4 CENTIMETER INCH FiG.4. Features ofthelower sinter inthemiddle sandstone unitatVerbena, Queensland. A. Outcropviewedfrom the west,pick for scale.B. Layeringandinteda¾.er cavities.C. Externalmold of !¾copod stem(middle)parallelto layering.D. Externalmoldof !¾copod stemand attachedleaveson beddingsurface.E. Arrayof circularto polygonalcavitiesof uncertainoriginon beddingplane.F. Filamentousbacterialmat on beddingsurface. 140 SCIENTIFIC COMMUNICATIONS 0 0 0 141 •0 0 0 0 0 0 aO 0 0 0 0 o I o I o o• • t:.: • • • II V II o o o 4• o o o o o o II II • II II ,-; v o V II II II II o r-., ot-- o o I o •' I o o , • , • ,:5 V .• • II • II • 44 • II • II • c• V II 142 SCIENTIFIC COMMUNICATIONS Queenslandlabs.l:Geol. Soc.AustraliaAbstracts,no. 23, v. 2, p. 434-435. Fellows,M. L., and Hammond,J. M., 1988, Geologyof the Wirralie gold deposit,Queenslandlabs.l:Geol. Soc.AustraliaAbstracts,no. 23, v. 1, p. 265-267. C¾ IN Graney,J. R., 1987, HasbrouckMountain,Nevada.Preciousmetal mineralizationin a fossilhot springsenvironment,in Johnson, J.L., ed., Bulkmineablepreciousmetaldepositsof the western United States.Guidebookfor field trips: Reno, Nevada, Geol. Soc. Nevada, p. 120-125. Grimes,K. G., Hutton, L. J., Law, S. R., McLennan,T. P. T., and Belcher,R. L., 1986, Geologicalmappingin the Mr. Coolon1: 250 000 sheetarea,1985: Queensland Geol.SurveyRec. 1986/ 56, 70 p. Hutton, L. J., 1988, Tectonicevolutionof the basalDrummond basinsequence andits relationship to goldmineralisation labs.I: FIG. 5. Blocksof sinterin paleotalusof the mid-TertiarySuttor Formation, 400 m west of the lower (middle sandstone)sinter outcropsat Verbena, Queensland. Geol. Soc.AustraliaAbstracts,no. 21, p. 196. Krauskopf,K. B., 1967, Introductionto geochemistry:New York, McGraw-Hi!l, 721 p. Lehrman, N.J., 1986, The McLaughlinmine, Napa and Yolo Counties,California: Nevada Bur. Mines GeologyRept. 41, p. 85-89. thermal gold depositsin the Drummondbasin.The entire Mount Coolon structure underwent introduc- Malone,E. J., 1969, Mount Coolon,Queensland.SheetSF/55-7, 1:250,000 geologicalseries:AustraliaBur. MineralResources, GeologyGeophysics ExplanatoryNotes, 17 p. Morton, C. C., 1935, The Mount Coolongoldfield:Queensland Govt. Mining Jour., v. 36, p. 196-200, 232-237. tionof bothdelicatelybandedchalcedony-adularia of Murray,C. G., 1986, Metallogenyandtectonicdevelopmentof theTasman foldbeltsystem in .Queensland: OreGeology Rev., typical epithermalcharacterand an irregularlydisv. 1, p. 315-400. tributed, coarse-grainedactinolite-biotite-epidote-O!gers, F., 1972, Geologyof the Drummondbasin,Queensland: magnetite-pyriteassemblage(R. H. Sillitoe and R. AustraliaBur. Mineral Resources,Geology GeophysicsBull. Cunneen, unpub. data; Morton, 1935). These two 132, 78 p. vein fillings,the relativetiming of which remainsto Porter,R', 1986, Pajingogoldproperty.The discoveryandgeologicalintroductionlabs.l:GoldExplorationandDevelopment be clarified,were overprintedby sericiticalteration North QueenslandConference,ChartersTowers,Queensland, andminorlatetourmaline.The-actinolite-bearing as1986, Australasian Inst. MiningMetallurgy,North Queensland semblageiscompatiblemineralogically with hornfels Branch,ExtendedAbstracts,4 p. and hydrothermalalterationdevelopedin the wall- Powell, C. McA., 1984, Late Devonianand early Carboniferous: Continentalmagmaticarc alongthe easternedgeof the Lachlan rockignimbrite,effectswhichmaybe attributedwith fold belt, in Veevers, J. J., ed., Phanerozoicearth history of confidenceto a nearbytonalitc pluton of late CarAustralia:Oxford, ClarendonPress,p. 329-340. boniferousage (280-290 m.y.; Malone, 1969). Rimstidt,J. D., andCole, D. R., 1983, Geothermalmineralization Acknowledgments Facilitiesand encouragement duringthis project were providedon behalfof RGC ExplorationPty., Ltd., by Keith Wellsand GeoffMoore.Early review commentswere contributedby Harold Bonhamand GregMorrison.Publicationis with the permissionof RenisonGoldfieldsConsolidated,Ltd. August11, September2 7, 1988 REFERENCES Casaceli,R. J., Wendell, D. E., and Hoisington,W. D., 1986, Geologyand mineralizationof the McGinnessHills, Lander County,Nevada:NevadaBur. MinesGeologyRept. 41, p. 93102. Etminan,H., Porter,R. G., Hoffman,C. F., Sun,S.-S.,andHenley, R. 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