Nanotechnology in Construction: A Roadmap for Development P.J.M. Bartos1 Abstract. Roadmaps were originally developed as tools for finding surface routes for getting from one place to another. Recently, the scope of a roadmap has been extended to cover tools used for indication of pathways for reaching predicted future developments, for assessing progress and indicating trends. This was applied to developments in application of Nanotechnology within the broad domain of Construction. The Roadmap for Nanotechnology in Construction (RoNaC) was first developed in 2003 as an aid for forecasting research and investment directions, with a timescale of 25 years. Five years have elapsed and progress has been achieved along a few pathways indicated in the original RoNaC. However, construction industry continues to lag behind in both the awareness of the potential and the expected commercial exploitation of nanotechnology. This paper provides an updated version based on the three original sectorial charts, indicating where tangible progress has been made, where research is active and where advance along the predicted pathways has slowed down or stopped altogether. 1 Introduction The purpose of a Roadmap is to chart trends and developments, which, in this case, link nanotechnology and construction. It provides a useful tool, a template, for their predictions. The Roadmap for Nanotechnology in Construction (RoNaC) has been aimed at facilitating identifications of desirable aims/destinations for construction RTD over a short-medium timescale (up to 25-years). The need for development of a Roadmap for Nanotechnology in Construction th arose during the 5 FP European project “NANOCONEX” (2002-2003) [1] as one of its deliverables. It reflected pioneering work exploiting early developments in application of nanotechnology to construction materials at the Advanced Concrete and Masonry Centre (1994-) and the attached Scottish Centre for Nanotechnology in Construction Materials (2000-) at the University of West of Scotland (formerly P.J.M. Bartos The Queen’s University of Belfast & University of West of Scotland e-mail: [email protected] 16 P.J.M. Bartos the University of Paisley) where the first State of the Art report [2,3] was also produced. The RoNaC was developed to aid forecasting RTD directions and to inform and guide not only the ‘end-users’ in construction industry but also investors and national / international bodies supporting research and development. The RoNaC showed the diverse pathways towards nanotechnology-linked expectations, aims and targets in the very large and economically very significant domain of construction, envisaged in 2004. The content of the RoNaC was also linked to work of the RILEM International Technical Committee TC 197-NCM on Nanotechnology in Construction Materials (2002-2007). The earliest version of the RoNaC had been presented at the ECORE & ECCREDI conference on “Building for a European Future – Strategies & Alliances for Construction Innovation”, held in Maastricht in October 2004. nd Subsequently it was presented and discussed at the 2 International Symposium on Nanotechnology in Construction (NICOM2) in Bilbao, in November 2005 and at the ACI Seminar on Nanotechnology of Concrete: Recent Developments and Future Perspectives in Denver in November 2006 [4]. Construction industry differs from many other sectors of manufacturing industry in that it adopts and exploits the new nano-scale tools, which have been developed in the more fundamental scientific rather than engineering domain. Compared to many other industrial sectors, instances where Nanotechnology has been already successfully exploited and a construction related major product has already reached open markets still remain few in numbers. Awareness of the potential for exploitation of Nanotechnology in construction has been improving over the last decade, but expectations of a more practical exploitation have not been fulfilled, much more remains to be done. Nano-related RTD in construction has been established in a few sectors; however, it can be still described overall as an ‘emerging’ trend, often concentrating on new knowledge rather than on an application. Advances are very non-uniform, leading to a particularly pronounced fragmentation and often to a distinct isolation of current centres of nano-related construction research and development. These are very important, constructionindustry specific circumstances, accounted for in this RoNaC. Detailed analysis of nano-related RTD in construction, which was published in the NANOCONEX / RILEM TC197-NCM State-of-the-Art report [2,3] and which has been updated in the final report from the TC 197 NCM (publication expected in early 2009) is still applicable. The report indicated two factors which severely impact on RFTD in construction inn general and on exploitation of nanotechnology in particular: (a) An inherently different nature of construction compared with other sectors of manufacturing industry. Final products of construction, tend to be very complex, non-mass produced and possess a relatively long service lives. This makes them very different from common products of microelectronics, IT or even aerospace/automotive industries. Construction generally acquires and adapts many inventions from other industries or from related sciences, rather than inventing them. Construction therefore tends to be much more an exploiter of ideas and inventions than their creator. Nanotechnology in Construction: A Roadmap for Development 17 (b) Historically very low levels of investment by construction industry into research represent a major hindrance in exploitation of nanotechnology. National levels of RTD investment in construction are often the lowest amongst all sectors of the manufacturing industry. This, together with the very high initial capital investment, invariably required in nano-related RTD, combines to generate a major obstacle for development of an adequate, essential research infrastructure. Overcoming such an obstacle is not helped by the very low margins of profitability within construction industry and the mid-long term timescale for any commercial returns to arise from such investments. Recent decline of economic activity worldwide is likely to worsen the situation. 2 Routes and Pathways The ‘quality’ and usefulness of existing and new, developing, roads and pathways for progress reflect the availability and ‘quality’ of relevant supporting infrastructure. The infrastructure has to be upgraded with passage of time if it were to fulfill its role in supporting research, development and practical exploitation of nanotechnology. The rate of advance towards highly desirable medium-long term goals would slow down, perhaps even stop entirely, if the necessary infrastructures were not adequately maintained and periodically improved. Nanotechnology related research infrastructures, which ‘pave the way’ include: • Instrumentation and associated methodologies for nano-scale investigations. (characterisation of properties at nano-scale, nano-assembly and nanofabrication, analytical techniques and imaging at molecular /atomic scale). • Descriptive, preferably also genuinely predictive, numerical models, which include a linkage across the whole scale, from nano-to-macro size. • Standardisation of basic nano-scale metrology equipment and provision of means for an assessment of their performance. Development of new, more effective tools for a meaningful nano-scale characterisation of materials. Instrumentation and metrology at nano-scale are developing at a very fast pace, which inevitably brings with it a rapid rate of obsolescence. The rate of obsolescence is comparable to that seen in the IST area, however ‘hardware’ costs of nano-scale instrumentation and costs of its maintenance / calibration / upgrading, even if only on a moderate scale, are higher than for IST research. It is impracticable to produce one, all-encompassing, single map for the whole of construction in which all the existing and potential routes and /pathways of progress linked with nanotechnology would be shown. A single comprehensive map would include a multitude of ‘pathways’, criss-crossing each other. To show them all in one chart/roadmap, with all the numerous possible intersections, interactions and feedbacks would lead to a tangled mass of connections resulting in an illegible and incomprehensible document. A solution has been found in the creation of a number of simpler charts in which the nano-related construction research pathways and / routes, heading 18 P.J.M. Bartos towards specific ‘destinations’, have been clustered. An example is the Chart 2: ‘Buildings of Future’, where the overall destination has been defined by a number of highly desirable goals/ and outcomes, presented in the chart. Some of the pathways shown may appear in another chart(s). This is to be expected, as Nanotechnology is fundamentally an ‘enabling technology’, where one advance, especially when it is a major advance, is very likely to underpin progress towards desirable goals in more sectors than the original one. Simplicity and ‘legibility’ of a chart restricted the scope for presentation. It was not practicable to indicate the current status of the routes/pathways, e.g. showing which roads were ‘under construction’ or just ‘planned’. Activities shown in the specimen charts have colour coding to indicate Existing pathways are shown in red. Many ‘connections’ are seen today as relatively ‘thin’, faint and indistinct routes, which is how they are perceived today, but which, in future, may (or may not!) become well-established, densely ‘trafficked’ wide principal routes / highways enabling a much faster progress towards the future goals indicated within the ‘destination’. 3 Benchmarks and Timescale Information and data from the State-of-the-Art report [2] helped to establish the benchmarks for the development of the RoNaC. The original survey had been to support European projects and gave priority to Europe. However this was extended to include an analysis of existing knowledge, proposed and current nano-related R&D activities applicable to any part of the construction sector on a global scale. st Contributions presented at the 1 International Symposium on Nanotechnology in Construction, Paisley, UK, June 2003 [5], active links with the TC-197 NCM on Nanotechnology in Construction Materials, established under the auspices of RILEM in 2002, and events organised and documents produced by the UK Institute of Nanotechnology [6] and other organisations were reviewed and their conclusions nd considered. The 2 International Symposium on Nanotechnology in Construction (NICON2) in Bilbao, Spain in November 2005 confirmed the emerging trends and indicated several new projects exploiting nanotechnology [7]. The RoNaC charts were plotted against a timescale, which provided a measure of how distant the required or desirable research and development destinations were from a ‘benchmark’ situation in 2004, its starting point. The timescale extends to 25+ years ahead, with the first five years already covered. It is important to note that the greater is the extension of the time interval into future, the greater are the potential errors and the lesser is the reliability of forecasts in this rapidly and unevenly developing field. There are three ‘specimen’ Charts shown. Sufficient information is already available from individual publications and reviews [1–4,7] and from the final documentation from the RILEM TC 197 NCM [8] and other sources, to enable production of new charts in a similar format. It is possible to re-define the baselines and destinations and focus on different aspects linked to nanotechnology. Nanotechnology in Construction: A Roadmap for Development 19 It is important to appreciate that the ‘routes/pathways’ shown in the charts are in many instances only now being formed or traced. Additional ones may develop in due course, and may not even exist as yet. 4 Vehicles, Drivers The choice and understanding of the research ‘vehicles’ needed to pursue specific goals and the capability of their ‘drivers’ to steer them along correct routes to desired outcomes and destinations, always require adequate prior knowledge of both Nanotechnology and the relevant sector(s) of construction industry. Inadequate knowledge, or its absence mean that not all of the pathways/routes (if any), including their intersections, as shown on the attached Charts, may be clear and recognisable to potential developers and exploiters – and any advance may be slow, sometimes taking wrong paths leading to ‘dead-ends’ (and wasted resources). If knowledge represented the ‘vehicle’, then the ‘drivers’, which represent the motivation to go ahead, can be also identified. The greatest impact on the construction industry and the economy within the timescale of the Roadmap is expected to come from an enhancement in performance of materials – a very strong driver of construction RTD. This, in turn, is likely to arise from an improved understanding and control of their internal structure on micro-to-nano-scale and from a potential improvement of their production processes. The eventual total impact in construction will be almost always very substantial, due not necessarily to radical technological leaps forward but mainly to massive quantities in which basic (‘bulk’) construction materials are used. Most of the advances along the specific research routes and pathways of RTD are predicted to be incremental, leading to a relatively steady progress related to existing, namely the ‘bulk’ materials and technologies. Such a relatively steady progress will be strongly influenced by developments in the research ‘infrastructure’ It may be that some of the expected improvements will not take place and there will be a waiting period with only a small or even zero advances, until a breakthrough occurs and the physical capability of the equipment (infrastructure) is instantly and significantly upgraded or there is a significant advance in interpretation/understanding of data/results obtained. An improved understanding of structure-properties relationships and an ability to control the structure of many materials on the nano-scale is expected to provide the greatest opportunities for major advances in construction materials science. Such breakthroughs will enable the ‘materials by design’ approach to replace the traditional one of a ‘trial and error’, enabling properties of a material to be tailored for optimum performance in a specific application. Additional, often mutually complementary drivers are market pull, venture capital involvement, competitiveness and prospects of higher financial returns. Their significance can vary, depending on the availability of the basic ‘vehicle’ – presence of an adequate knowledge & information. 20 P.J.M. Bartos 5 Business Environment Construction industry is a very substantial contributor to economic performance. In Europe alone, its annual turnover is estimated [9] at about 1000 billion Euro. At the same time, it is estimated that 97% of employees working within it are employed by enterprises with less than 10 staff. The Small and Medium size Enterprises in construction are generally not involved in RTD activities and acquisition of the required minimum knowledge, and awareness of opportunities brought by nanotechnology, is difficult. At present, such knowledge still appears to be inadequate if not entirely absent. The ‘vehicle’ for advance along the existing and potential pathways is therefore available only to large companies, as is confirmed by the appearance of the first practical, commercial, nano-related products on the market. The way ahead - an exploitation of the directions such as those shown in the specimen RoNaC charts is proving not to be easy and straightforward because the knowledge required at different levels of construction-related staff still tends to lag behind the continuing advances in nanotechnology achieved elsewhere. It is possible to conclude that in the absence of an environment conducive to acquisition of an adequate knowledge through education and training, many of the basic and most significant drivers of progress, such as market pull, venture capital involvement, competitiveness and prospects of higher financial returns, will be either weak or will not be established. Numbers of skilled research related personnel at both the scientific/supervisory level and at the supporting staff/technician level, who possess the required combination of knowledge related to construction and nanotechnology, continue to appear to be too low to provide the manpower required to steer and move efficiently forward the ‘vehicles’ for expansion of nanorelated RTD in construction and development of marketable products. Countries leading the development and exploitation of Nanotechnology, such as the USA, Japan and European Union [8,9], appreciated the necessity of providing major financial support from state/government sources The US government set up the National Nanotechnology Initiative in yr. 2000, which has committed an initial funding of more that one 700 million US$ of public funds to facilitate the additional commitment of private venture capital for specific developments through its different agencies [8]. As has been noted in the first RoNaC, all but a very small fraction of the public funding for nano-related RTD was channeled either into non-construction industries or into development of general nano-scale research infrastructure, which was then used primarily to support non-construction research, perceived to be more ‘high-tech’. Investment into research infrastructure can benefit construction and it can ‘smooth/pave’ some of the development paths shown in the Charts. However, this would require a significant change in management of such facilities, to enable a few construction-related ‘vehicles’ to squeeze into the densely trafficked RTD pathways, already crowded by nano-science related vehicles with no connection to Nanotechnology in Construction: A Roadmap for Development 21 construction. Unless there is such change, benefits to construction from such nanotechnology related infrastructure investments are likely to be disproportionately low compared with the economic significance of construction, which, in EU contributes approximately 10% of GDP. Other significant drivers are emerging, and are likely to gain significance in terms of construction and nanotechnology. These include climate change and the associated issues, both on a global scale and in local urban redevelopment. 6 Roadmap and Charts An overall roadmap covering the whole of construction would be so complicated to make it difficult to understand. The ‘scale’ would have to be adjusted to make it ‘legible’, but then the roadmap would become too ‘coarse’ to make it useful. As a result, such a roadmap would not reveal adequately details necessary for an appreciation and understanding of the links, relationships and dependencies of varied significance, which may exist between the pathways shown. Instead of a single roadmap, a ‘complete’ RoNaC would therefore become a ‘road-atlas’ comprising a collection of ‘sectorial’ charts such as the examples attached. Each chart would be focused on a coherent cluster of aims and destinations, depending on the purpose of each chart. Aims and destinations, which are expected to be of significance for construction in the medium-long term include: • Understanding basic phenomena (interactions, processes) at nanoscale: e.g. cement hydration and formation of nanostructures, origins of adhesion and bond, pore structure and interfaces in concrete, mechanisms of degradation, relevant modelling and simulation etc. • Bulk ‘traditional’ construction materials with a modified nano-structure: e.g. concrete, bitumen, plastics modified with nanoparticulate additives, special admixtures and new processing techniques modifying internal nanostructures etc. • New high performance structural materials: e.g. carbon nanotubes, new fibre reinforcements, nanocomposites, advanced steels and concrete/cement composites, biomimetic materials, etc. Materials with extended durability in extreme service conditions. • High performance new coatings, paints and thin films: e.g. wear-resistant coating, durable paints, self-cleaning/anti-bacteria and anti-graffiti coatings, smart thin films, etc. • New multi-functional materials and components: e.g. aerogel based insulating materials, efficient filters/membranes and catalysts,, self-sensing/healing materials, etc. • New production techniques, tools and controls: e.g. more energy efficient and environmental friendly production of materials and structures, novel processes with more intelligent and integrated control systems, etc. 22 P.J.M. Bartos • Intelligent structures and use of micro/nano sensors: e.g. nano-electromechanical systems, biomimetic sensors, paint-on sensors, and self-activating structures/ components, etc. • Integrated monitoring and diagnostic systems: e.g. for monitoring structure defects and reinforcement corrosion, environmental changes/conditions, and detecting security risks, etc. • Energy saving lighting, fuel cells and communication devices: e.g. efficient and cheap fuel cells and photovoltaics, photocatalytic materials etc. The Charts provided as examples show pathways emerge from a baseline to the left of the Chart. If appropriate, the baseline can be split into separate ‘blocks’, indicating different sub-areas of research. Each sub-area may consist of several recognised and related ‘research streams/directions. Progress forecast along each of the identified nano-related RTD activity paths is shown against a linear timescale from 0 to 25 (+) years. Activities, which are shown starting within the first five years, are already being pursued or about to commence. Aims/destinations, common to each of the charts, are shown on the right hand side and basic characteristics/parameters of the aims are also listed there. A simple elongated rectangular box represents each research activity. However, this does not indicate a very precise and sudden start and finish, and a uniform intensity of the activity throughout its expected duration. It is s a simplification, which has been adopted for the sake of clarity, and because it is impossible to predict variations in the intensity/magnitude of research which are inevitable during each of the activities. There may be ups and downs, and even breaks / discontinuities, when funding may drop below the level required to sustain advance. Unexpected and at that time perhaps temporarily insuperable technological problems may be encountered on the path followed, or even an unexpected dead end may be encountered, for example by discovery of a hitherto unknown ecological or health & safety threat or danger. Each ‘activity box’ is therefore presented in a simplified linear and parallel direction, with only major interactions indicated as ‘diagonal’ connecting lines. As mentioned before, some of the activities will be using common paths/routes and share the infrastructure. Many overall ‘integrating’ aspects therefore arise because of the commonality of some of the nano-scale approaches. This is a feature representing the inherent multi-disciplinarity of RTD, which exploits advances in nanotechnology. A general activity, which is beginning to be more appreciated, and which can be associated with any of the specific (‘boxed’) activities shown is an evaluation of health and safety, both during the process of research and development and regarding practical products / applications. It is now very urgent to provide an adequate national and international legislative cover and avoid potential health & safety problems undermining confidence in nanotechnology in general. Nanotechnology in Construction: A Roadmap for Development 23 7 Specimen Charts Original charts are provided; year 2009 equates to year 5 of the timescales shown. 7.1 Chart 1: Traditional Bulk Construction Materials TIMESCALE (years) Present 0 5 10 20 25+ Destination novel, non-traditional binders ductile cements & tougher concrete nano-layers/coatings Ceramics, bricks, glass bio-active surfaces tougher ceramics self-cleaning glass Bitumens, polymers nanofillers molecular assembly of new polymers Timber modified wood for construction, fast growing defect-free, dense/strong Advanced Bulk Materials Concrete low energy cement Negligible / zero / positive environmental impact, sustainable resources, pre-set grading of properties replaced by properties optimised for applications Steel corrosion resistant construction steel NANOCONEX ROADMAP: Chart 1 - Bulk Construction Materials Chart 1 reviews potential for exploitation of nanotechnology where even incremental improvements are likely to lead to big commercial and environmental / societal gains because of the extremely high ‘multiplying factors’ attached to such materials. Activities shown follow generally the ‘top-down’ approach, in which an existing material is improved through knowledge and modifications carried out down at the micro-nano level. Timescale of 5 years have been reached in 2009, with progress in knowledge being achieved in most of the activities but with products appearing only in the areas of steel (very limited) and ceramics (photocatalytic coatings, selfcleaning glass). Concrete coatings have only moved if the photocatalytic surfaces are concerned. 7.2 Chart 2: Buildings of Future The chart outlines the potential for exploitation nanotechnology leading to a much higher standard and much more environmentally acceptable, and eventually fully 24 P.J.M. Bartos TIMESCALE (years) Present 0 5 10 20 25+ Destination Active nano-coatings self-cleaning glass and bio-active surfaces BUILDINGS of TODAY High performance insulating materials High thermal mass materials Stronger, tougher, lighter and more durable composites Smart materials and components Safety and security Fibre-optic and microchip control systems Photovoltaic surfaces & solar cells – roofs & cladding Buildings of Future Zero or positive energy balance; maximum sustainability of resources; integrated lifespan of materials and components; minimum maintenance; healthy environment; recyclable materials & components Embedded sensors, condition monitoring and diagnostic devices NANOCONEX ROADMAP: Chart 2 – Buildings of Future sustainable, building construction. Achievements/destinations reached by routes shown in Charts 1 and 3 will be associated with or support activities shown in this Chart. TIMESCALE (years) Present 0 5 10 20 25+ Composites with self-adjusting interfaces Smart materials, shape memory, self-repairing, strain hardening Active nano-coatings Novel, controlled and durable fracture mechanisms Stronger, tougher, lighter and more durable composites Exploitation of nanoparticles, nanotubes, nanofibres Photovoltaic materials Safety and security NANOCONEX ROADMAP: Chart 3 – NOVEL MATERIALS Novel construction materials EXISTING CONSTRUCTION MATERIALS Bio-mimetic materials Construction materials ‘built’ from basic nano-scale basic components. Extreme strength and toughness; no health hazard; acceptable degree of sustainability of resources, environmentally harmless on local/global scale Unforeseen developments? Destination Nanotechnology in Construction: A Roadmap for Development 25 7.3 Chart 3: Novel Construction Materials The chart follows primarily the ‘bottom-up’ development process, where materials of substantially altered properties and a much high performance are ‘built’ or ‘assembled’ from the basic nano-scale constituents (molecular – atomic level). It is most important to note the ‘unforeseen developments’, an activity box that covers developments not even thought of at present. 8 Conclusions 1. Since the first issue of the RoNaC in 2004, the exploitation of the RTD potential in construction through nanotechnology in construction remains in an ‘emerging, / early development’ stage. 2. The RoNaC presented includes three specimen charts covering the most common ‘clusters’ of construction research activities, where nano-based research and development activities are already carried out and several routes/pathways are already established. Additional charts can be developed for specific activities or aims/destinations. 3. The uneven progress of exploitation of nanotechnology in construction and the specific nature of the construction industry limit the accuracy of the forecasts shown in the RoNaC. Reliability of predictions regarding commencement, duration and end of activity also decreases rapidly as the commencement time becomes more distant from present (year 5 from original time zero). 4. Integration of the currently fragmented nano-related research in construction and the use of common ‘vehicles’ at national or international levels would considerably speed up progress along the pathways outlined in the RoNaC. 5. Most of the overall construction output is through Small and Medium Enterprises. The SMEs in construction domain have negligible research and development capabilities. They cannot be therefore considered as effective vehicles for progress in exploitation of nanotechnology in construction, although they need to be associated with the RTD and their awareness of developments should be improved. 6. Activities concerned with monitoring and evaluation of ecological, environmental and health & safety aspects of materials and processes both during research at nanoscale and for development of marketable products are expected to become an essential part of all activities considered. 7. The RoNaC charts provide a ‘snapshot’ of the current situation in only three sub-sectors of construction, after five years from its first publication. It is suggested that similar ‘templates’ are used to develop further charts focused on different sub-sectors or topics, and the charts are updated every 3-5 years. 26 P.J.M. Bartos Acknowledgments. The author wishes to acknowledge the assistance provided by partners in the FP5 “Nanoconex” European Project and to thank colleagues in the RILEM Committee TC197 NCM “Nanotechnology in Construction Materials” for their collaboration. References 1. European 5th FP project: Towards setting up of a Network of Excellence on Nanotec nology in Construction - project NANOCONEX. 1.12.2002-30.11.2003; Contract No.G1MA-CT-2002-04016; project No. GMA1-2002-72160; Coordinator: Dr A Porro, Labein, Bilbao, Spain (2003) 2. Zhu, W., Bartos, P.J.M., Gibbs, J.: Application of Nanotechnology in Construction. State of the Art report. ACM Centre/Scottish Centre for Nanotechnology in Construction Materials. University of Paisley, Technical Report, Project “NANOCONEX”, 49 p. (March 2004) 3. Zhu, W., Bartos, P.J.M., Porro, A. (eds.): Application of Nanotechnology in Construction. Mater. Struct. 37, 649–659 (2004) 4. Sobolev, K., Shah, S.P.: Nanotechnology of Concrete: Recent Developments and Future Perspectives. ACI SP 254, 164 p. (2008) 5. Bartos, P.J.M., Hughes, J.J., Trtik, P.: Nanotechnology in Construction. The Royal Society for Chemistry, 374 p. (2004) ISBN 0-85404-623-2 6. Institute of Nanotechnology, http://www.nano.org.uk 7. Porro, A., de Miguel, Y., Bartos, P.J.M. (eds.): Nanotechnology in Construction. RILEM Publications s.a.r.l (2007) 8. Trtik, P., Bartos, P.J.M. (eds.): Final report of Rilem TC 197-NCM on Nanotechnology in Construction Materials (to be published) (2009)
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