Chemical and Biomolecular Engineering Department The University of Akron - Spring 2012 Newsletter Departmental Advisory Board Mr. Larry Allen Retired, Air Products and Chemicals, Inc. Mr. Chris Arrick Caterpillar, Inc. Mr. Charles A. Clerecuzio Bard Holding, Inc. Mr. Roger Cox The Goodyear Tire & Rubber Company Mr. Tom Flynn New Research Center for the College of Engineering The official ribbon-cutting ceremony is still months away, but thanks to the efforts of very determined project leaders and construction crews, the College of Engineering's newest building is partially open to faculty researchers and students as 2012 gets under way. Designated as the home of the National Center for Education and Research in Corrosion and Materials Reliability, the new building has been funded in part by the U.S. Department of Defense. It will contain laboratories and faculty offices supporting UA's undergraduate program in corrosion engineering, which is part of the Department of Chemical and Biomolecular Engineering. The building also will be home to the Timken Engineered Surfaces Laboratory, a unique industry-university open innovation model. The build-out of the labs was funded by The Timken Company, which also funded an endowed chair position in the College of Engineering. This article was printed in the UA January 3rd, 2012 E-mail Digest. Further Information can be found at http://www.uakron.edu/edigest/index.php?id=2816 Newsletter Supervisor: Gang Cheng Edited by: Miranda Mick The Babcock & Wilcox Company Mr. Robert Handelman Chemstress Consultant Company Mr. Karl Jacob (Chair) The Dow Chemical Company Dr. Jeffrey S. Kanel Renewable Algae Energy, LLC Dr. Brian Kocher Promerus LLC Dr. Jackie Laurich OMNOVA Dr. Tim Mallow Merck & Company, Inc. Mr. Robert M. Shemenski RMS Consulting Inc. Dr. W. Leigh Short Alternative Environment Strategies, LLC Mr. Dan Spak Firestone High School Mr. John Zuppo Emerald Performance Materials The office received a holiday greeting from Jason Keith. He was kind enough to submit a brief bio for this issue. Jason Keith (B.S. ChE. 1995) is currently Professor and Director and holder of the Earnest W. Deavenport, Jr. Chair in the Dave C. Swalm School of Chemical Engineering at Mississippi State University. Keith started his tenure as department head in August of 2011. Prior to joining Mississippi State, Keith was on the faculty at Michigan Technological University for 11 years as an Assistant Professor and Associate Professor. Keith’s research interests are in modeling of transport systems, alternative energy, and improving engineering education. Jason and his wife, Salvadora, live in Starkville, MS with their 3 children: Andrew (8), Maria (5), and Isabel (3), and their tenyear old chocolate Labrador retriever, Pennant. (We would like to hear from you. Send notes and e-mails to us at [email protected]) One of our Chemical and Biomolecular Engineering Advisory Board Members, Charles A. Clerecuzio, P.E., CPIP, has been selected as the 2012 Chemical Engineer of the Year for Delaware Valley by The American Institute of Chemical Engineers (AIChE). Clerecuzio was recognized at the AIChE’s CEO Night on March 29,2012 at the Union League of Philadelphia. This honor is awarded annually in recognition of career achievements in the field of chemical engineering by an active participant in AIChE. Professor and her Team Develop Safer Breast Implant with Healing Properties UA team among GE Healthymagination Cancer Challenge recipients. The University of Akron team consists of (from left): Kwang Su Seo, Andrea Charif, Matthew Luebbers, Judit Puskas, Marcela Castano, Balaka Barkakaty, Attila Gergely, Alejandra Alvarez Albarran and Chengching K. Chiang. Professor Judit Puskas is getting international attention for her efforts to develop a safer breast implant that can help detect and then destroy cancer cells. The work by Professor Puskas and her research partners at the university and Summa Health System is among five projects across the globe awarded $100,000 in seed money through the GE healthy magination Cancer Challenge. (Information taken from Universty of Akron E-Digest) College of Engineering Yearly Awards Presented at the April 19th Banquet Donald R. Burrowbridge Award: Mallory Barker AIChE Award: Marcus Grimm ChemStress Award UG: Kyle Platt ChemStress Award Grad: Qiuming Wang The Louis A. Hill Jr. Award: Professor George Chase CBE Faculty Award: Glenn Cormack Stephanie Lopina Memorial Endowed Scholarship: Jacob Kohl Larry Focht: Bradford Vielhaber Outstanding Administrative Staff Award: Mrs. Marcia Main Outstanding Senior Awards: Gurkamal Badyal, Mallory Baker, Robert Browne, Haley Carman, Glenn Cormack, Benjamin Garn, Marcus Grimm, Andrew Janish, Matthew Latterner, Michael Lembono, Tanya Miracle, and Andrew Thomas. New Lab During the move the students helped to carry boxes and arranged the new lab for days. Professor Chase and his team moved to the 5th floor of ASEC earlier this semester! Left to right: First Row: Vidya Raja, Hyeon Ung Shin, Dr. Chase, Gabe Manzo, Laila Shahreen, Goutham Viswananadam, Kristian Knudsen Second Row: Hesam Hassan Nejad, Kitchaporn Nartetamrongsutt, Jia Fang, Johnathan Rajala Dr. Chase invited the students to his home where they obtained carpenter skills by making shelves for their study room. Judy joined the office in November 2011 to be our new Administrative Secretary. She came to us by way of Wayne College/Holmes County Branch. Her enthusiasm and patience with our students, especially in working with the undergrads, is appreciated. She lives in Cuyahoga Falls with Ollie (English Bulldog) and Rosie (Pug). Miranda Mick is our new student assistant in the office. She joined the office in October 2011. Her major is Middle Level Education with a Science and Math concentration and hopes to be graduating in Spring 2014. Ashley Rastetter is a new student assistant working with Professor Evans. She joined the office in February 2012. Her major is Art History and hopes to be graduating in Spring 2013. The Akron ISPE Student Group received a $500 grant from the Great Lakes Regional Chapter of ISPE. This funding is greatly appreciated and will be used to assist in planned activities. In April, the students will be traveling to Eli Lilly and Company (Indianapolis, IN) for a tour of their Chemical Processing and Bioprocessing R&D facilities. The University of Akron’s Chem-E-Car Team preparing the chemicals prior to testing. The car is power by an Alkaline Fuel Cell and stopped using an electrochemical cell. From left to right, Adam Harrell, Christopher Denison, Kylie Trumpower, Evan Arnold, and Jordan Shaffer. The students will be competing with their car at the AIChE regional conference on April 21, 2012 at The Univer- Some of the AIChE Students at work planning the 2012 regional conference. From left to right: Andrew Janish, Marcus Grimm, Glenn Cormack, Lauren Best, Andrew Thomas, Robert Browne George G. Chase was awarded $5,000 from the Produced Water Society Homero Castaneda-Lopez was awarded $1,032,243 from the SENER CONACyT Dr. Edward Evans who was awarded a $10,000 summer fellowship by the University for faculty research. Proposal entitled “Infrared Analysis of Mixed Oxide Advanced Materials.” UA researcher to manage pipeline corrosion in Mexico with $1M grant Dr. Homero Castaneda-Lopez, assistant professor of Chemical and Biomolecular Engineering received a $1,032, 450.00 grant from the National Science and Technology Council (CONACyT) and Department of Energy in Mexico (SENER) for his proposal on Multiscale tools for corrosion science and Engineering applied to oil and gas pipelines over the next three years. Dr. Castaneda proposed mathematical deterministic and probabilistic models in different scales ranging from kilometers including the climate conditions up to micrometers describing and quantifying the degradation and performance mechanisms of corrosion of buried metallic pipelines. The models will build algorithms and describe mechanisms to quantify corrosion phenomena and suggest control actions. The new International grant create an opportunity for International collaboration with National Science Agencies, the highly competitive award includes the participation of International entities targeting different strategic areas open for participation, such as advanced materials, energy, biotechnology, among other. The grant includes different review panels from academia, department of Energy and oil and gas industry experts. CONACyT is the National Science and Technology council in Mexico which web link is: http:// www.conacyt.mx/en/Pages/default.aspx Louscher honored for contributions to e-learning corrosion website Susan Louscher, executive director of strategic partnerships and government programs at UA, received a Materials Performance Magazine Readers' Choice Corrosion Innovation of the Year Award for CorrConnect.org. The e-learning corrosion website combines corrosion courseware, videos and interactive simulators to provide an online resource center. Ten Innovation Awards were presented March 12 at CORROSION 2012 — NACE International's annual corrosion conference and exposition in Salt Lake City, Utah. “Our goal with this awards program is to provide a forum where anyone developing new and unique corrosion control technology can be showcased and recognized,” says Bob Chalker, NACE International executive director. “We received an impressive array of entries demonstrating important advances in the industry.” News from the research lab for Surface Modification and Materials: Submitted by Dr. Newby Mr. Hua Wang won the poster competition during the “Sink or Swim 2011” 54th Annual Technical Coatings Symposium (May 2011). The title of the presentation is “Developing slow flow systems for monitoring initial stages of biofilm formation on microbiologically induced corrosion”. Congratulations Hua! The research team led by Dr. Zhang Newby has been awarded a 18 months continuation funding from DOD on their microbiologically influenced corrosion (MIC) project. The project is to start in Fall of 2011. Dr. Pamela Pasetto, a Fulbright Scholar and an assistant professor from the University of Maine (Le Mans, France), visited us from July 15 to September 17, 2011 with the support from her Fulbright grant. She was investigating, using our flow chamber systems, the antifouling performance of functionalized isoprene oligomers derived from waste natural rubber (e.g. old tires). Ms. Suchata Kirdponpattara joined the group on September 12, 2011 as a visiting scholar under the support of The Royal Golden Jubilee of the Thai Government. She will be visiting us for one year to work on modifying the bacterial cellulose-alginate (BCA) composites for enhanced production of ethanol utilizing yeast cells immobilized in BCA. Welcome Suchata! The first refereed journal article by Mr. Hua Wang (first author) after he joined the group (in Fall 2009) is to appear in Colloid. Surf. B: Biointerfaces, on October 15th, 2011. Hua is also the first author for a refereed paper presented in the DOD Corrosion Conference (Palm Springs, CA, 2011). In addition, he is the presenter and first author for several conference presentations (241st ACS meeting – March 2011, NACE – March 2011, “Sink or Swim 2011” 54th Annual Technical Coatings Symposium – May 2011, DOD Corrosion Conference – August 2011) during Spring/summer of 2011. Keep up the good work. Class Notes From Project Management and Teamwork (PMT): Submitted by Professor Evans This past fall we completed our tenth Vertically Integrated Team Design Project which is now implemented as a separate class called Project Management and Teamwork. Fifteen teams of fifteen students developed prototype carbon dioxide adsorbers based on solid sorbent technology and evaluated the cost effectiveness of this technology; the solid sorbent technology used was developed in Professor Steven Chuang’s lab. The teams also surveyed the public about energy perceptions and use. We continue to emphasize leadership and structured management by bringing in experts on these topics and having the students use project management software to help them keep track of progress and report on resource allocation. Each team was mentored by a practicing chemical engineer. Some alumni who helped us in the mentoring role include: Danielle Cummings (’05), John Heaton (’92), Bryan Howdyshell (’82), Jeff Kasper (’92), and Gabe Rhoads (’05). The students really like to interact with alumni mentors and the mentors get a chance to share their experience and advice with the students. If you would like to get more information about this course or to participate as a team mentor (either in person or over a video connection) please let us know. Camacho-Alanis, F., Castaneda, H. , Zangari, G., Swami, N.S. (2011) Electrochemical impedance study of GaAs surface charge modulation through the deprotonation of carboxylic acid monolayers. Langmiur, 27(18), 11273-11277. Castaneda, H. (2012) Galicia, M. PROPOSED MODEL FOR QUANTIFICATION OF DISSOLUTION --AND EVOLUTION OF A STEEL-CO2 SOLUTION INTERFACE BY THE TRANSMISSION LINE APPROACH, Journal of Solid State Electrochemistry. Tobin, JS.; Turinske, AJ.; Stojilovic, N.; Lotus, AF.; Chase, GG. (2012) Temperature-induced changes in morphology and structure of TiO2-Al2O3 fibers. CURRENT APPLIED PHYSICS, 12(3), 919-923. Viswanadam, G.; Chase, GG.(2012) Contact angles of drops on curved superhydrophobic surfaces. JOURNAL OF COLLOID AND INTERFACE SCIENCE, 367, 472-477. PS Kulkarni, SU Patel, GG Chase.(2012) The effect of surface energy of woven drainage channels in coalescing filters. Sep Pur Tech, 87, 54-61. PS Kulkarni, SU Patel, GG Chase.(2012) Layered hydrophilic/hydrophobic fiber media for water-in-oil coalescence, Sep Pur Tech, 85, 157-164. Hassan, AM.; Vu, DT.; Bernard-Brunel, DA.; Elliott, JR.; Miller, DJ.; Lira, CT.(2012) Application of the Step Potential for Equilibria and Dynamics (SPEAD) Method to Bioderived Esters and Acetals. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 51(8),3209-3214. Ghobadi, AF.; Taghikhani, V.; Elliottt, JR.(2011) Investigation on the Solubility of SO2 and CO2 in Imidazolium-Based Ionic Liquids Using NPT Monte Carlo Simulation. JOURNAL OF PHYSICAL CHEMISTRY B, 115(46), 13599-13607. McCormick, AM.; Leipzig, ND. (2012) Neural Regenerative Strategies Incorporating Biomolecular Axon Guidance Signals. ANNALS OF BIOMEDICAL ENGINEERING, 40(3),578-597. AE Wilkinson, AM McCormick, ND Leipzig. “Central Nervous System Tissue Engineering: Current Considerations and Strategies.” Synthesis Lectures on Tissue Engineering. KA Athanasiou and JK Leach Eds., Morgan & Claypool Publishers. 1-120, 2011. Zhang, B.; Lalani, R.; Cheng, F.; Liu, QS.; Liu, LY.(2011) Dual-functional electrospun poly(2-hydroxyethyl methacrylate). JOURNAL OF BIOMEDICAL MATERIALS RESEARCH PART A, 99A (3), 455-466. Lalani, R.; Liu, LY.(2011) Synthesis, characterization, and electrospinning of zwitterionic poly(sulfobetaine methacrylate). POLYMER, 52(23), 5344-5354. Liu, QS.; Singh, A.; Lalani, R.; Liu, LY. (2012) Ultralow fouling polyacrylamide grafted on gold via surface-initiated atomtransfer radical polymerization. BIOMACROMOLECULES, In press. Spagnuolo, M.; Liu, LY. (2012), Fabrication and degradation of electrospun scaffolds from L-tyrosine based polyurethane blends for tissue engineering applications, ISRN NANOTECHNOLOGY, Article ID 627420, 1-11. Wang, H.; Sodagari, M.; Chen, YJ.; He, X.; Newby, BMZ.; Ju, LK.(2011) Initial bacterial attachment in slow flowing systems: Effects of cell and substrate surface properties. COLLOIDS AND SURFACES B-BIOINTERFACES, 87(2), 415-422. J. Ram, S. Purohit.;Newby BMZ.; T. Cutright.(2012) Evaluation of the natural product antifoulant, zosteric acid, for preventing the attachment of quagga mussels – A preliminary study. Natural Product Research, 26(6), 580-584. Rosenthal, EQ.; Puskas, JE.; Wesdemiotis, C.(2012) Green Polymer Chemistry: Living Dithiol Polymerization via Cyclic Intermediates. BIOMACROMOLECULES, 13(1), 154-164. Ouardad, S.; Kostjuk, SV.; Ganachaud, F.; Puskas, JE.; Deffieux, A.; Peruch, F.(2011) Cationation of Dimethylallyl Alcohols by B(C(6)F (5))(3) as Models of the (Re)initiation Reaction in the Bio-Inspired Cationic Polymerization of Isoprene. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 49 (23), 4948-4954. Faculty Publications Continued Puskas, JE.; Burchard, W.; Heidenreich, AJ.; Dos Santos, L.(2012) Analysis of Branched Polymers by High Resolution Multidetector Size Exclusion Chromatography: Separation of the Effects of Branching and Molecular Weight Distribution. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 50(1), 70-79. Rosenthal, EQ.; Puskas, JE.(2011) Light Scattering for the Masses Green Polymer Chemistry: Efficient Synthesis of Disulfide Polymers and Networks. LC GC EUROPE, SI, 30-30. Heidenreich, A.J.; Puskas, J.E.; Sappacher, M.; Ibarboure,E.; Deffieux, A.(2012) Visualization of Arborescent Architecture of Polystyrenes Prepared by RAFT-based Inimer Polymerization Using Atomic Force Microscopy. J. Polym. Sci. Chem., 50 (6), 1238-1247. Rosenthal, E.Q.; Puskas, J.E.; Wesdemiotis, C.(2012) Green Polymer Chemistry: New Living Dithiol Polymerization Via Cyclic Intermediates. Biomacromolecules, 13(1), 154-164. Puskas, J.E.; Burchard, W.; Heidenreich, A.J.; Dos Santos, L. (2012) Analysis of Branched Polymers by High Resolution Multidetector Size Exclusion Chromatography: Separation of the Effects of Branching and Molecular Weight Distribution. J. Polym. Sci. Chem., 50, 70-79. Puskas, J.E.; Luebbers, M.(2012) Breast Implants: the Good, the Bad and the Ugly. WIRE Interdisciplinary Reviews, 4(2), 153 -168. Kostjuk, S.V., Ouardad, S.; Peruch,F.; Deffieux, A.; Absalon, C.; Puskas, J.E.; Ganachaud, F.(2011) Carbocationic Polymerization of Isoprene Co-initiated by B(C6F5)3:2 An Alternative Route toward Natural Rubber Polymer Analogues? Macromolecules, 44, 1372-1384. Zhao, J.; Wang, Q.; Liang, G.; Zheng, J.(2011) Molecular Dynamics Simulations of Low-Ordered Alzheimer beta-Amyloid Oligomers from Dimer to Hexamer on Self-Assembled Monolayers. LANGMUIR, 27(24),14876-14887. Yu, Xiang; Wang, Qiuming; Lin, Yinan; Zhao, Jun; Zhao, Chao; Zheng, Jie, "Structure, Orientation, and Surface Interaction of Alzheimer Amyloid-ß Peptides on the Graphite", Langmuir (Accepted) Zhao, C.; Zheng, J.(2011) Synthesis and Characterization of Poly(N-hydroxyethylacrylamide) for Long-Term Antifouling Ability. BIOMACROMOLECULES, 12(11), 4071-4079. X. Yu, Y. Luo, P. Dinkel, J. Zheng, G. Wei, M. Margittai, R. Nussinov, and B. Ma.(2012) Cross-seeding and conformational selection between three- and four-repeat human tau proteins. J. Biological Chemistry, (in press) C. Zhao, L. Li, M. Guo, and J. Zheng(2012). Functional polymer thin films designed for antifouling materials and biosensors. Chemical Papers, (in press) (invited review). X. Yu.; J. Zheng(2012) Cholesterol promotes the interaction of Alzheimer β-amyloid monomer with lipid bilayer. J. Molecular Biology, (in press) (invited research article on a special issue: Amyloid Structure, Function, and Molecular Mechanisms) J. Yang, C. Zhao, I. Hsieh, S. Subramanian, L. Liu, G. Cheng, L. Li, S.Z.D. Cheng, and J. Zheng. (2012) Strong resistance of PEG-based L-tyrosine polyurethanes to protein adsorption and cell adhesion. Polymer International, 61: 616. Enjoy the rest of the spring semester! Send this newsletter to others who would be interested in seeing more about our department. It is always wonderful to hear from you. Please keep us up to date with news that you may want to share for inclusion in the fall issue! Please send your information to Marcia D. Main at [email protected]
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