Structure Data of Free Polyatomic Molecules
75
MW
CHF2N
r0
N–H
C=N
C–F(t)
C–F(c)
∆(C–F) a)
a
Difluoromethanimine
Difluoromethyleneamine
Carbonimidic difluoride
Imidocarbonyl fluoride
Å
1.0200(32)
1.2397(49)
1.3147(26)
1.3227(26)
0.008 b)
θ0
C=N–H
F–C–F
N=C–F(t)
N=C–F(c)
deg
110.23(22)
108.09(31)
123.13(14)
128.78(18)
) Difference between the C–F(c) and C–F(t) bond lengths.
) Assumed.
b
Groner, P., Durig, J.R., DesMarteau, D.D.: J. Chem. Phys. 105 (1996) 7263.
Landolt-Börnstein
New Series II/28B
Cs
F
H
N
F