Structure Data of Free Polyatomic Molecules
330
IR
C 2O 2S 2
r0
C…C
Carbon dioxide – carbon disulfide (1/1)
C2v
(weakly bound complex)
(effective symmetry class)
(large-amplitude motion)
CO2 ⋅ CS2
Å a)
3.392(10)
θ0
O=C⋅⋅⋅C=S
deg
90 b)
The nonplanar X-shaped structure was determined
from the rovibrational band of the asymmetric stretch
of the CO2 moiety. The geometries of the monomer subunits were assumed to be unchanged
upon complexation.
a
) Uncertainty was not estimated in the original paper.
) Assumed according to the absence of b-type transitions.
b
Dutton, C.C., Dows, D.A., Eikey, R., Evans, S., Beaudet, R.A.: J. Phys. Chem. A 102 (1998)
6904.
Landolt-Börnstein
New Series II/28B