Structure Data of Free Polyatomic Molecules
19
MW
CClFO
Isotopic species
O12C · 35ClF
16 12
O C · 37ClF
16 13
O C · 35ClF
18 12
O C · 35ClF
16
a
Carbon monoxide – chlorine fluoride (1/1)
C∞v
(weakly bound complex)
(effective symmetry class)
(large-amplitude motion)
CO · ClF
r0(Rcm) [Å] a) r0(C...Cl) [Å] kσ b) [N m–1]
3.391(3)
2.770(3)
7.02
3.970(3)
2.770(3)
7.05
3.968(3)
2.771(3)
7.05
4.022(3)
2.769(3)
7.03
) Derived by assuming αav = 15(3)° and βav = 10(3)°.
) Intermolecular stretching force constant.
b
Hinds, K., Holloway, J.H., Legon, A.C.: Chem. Phys. Lett. 242 (1995) 407.
Landolt-Börnstein
New Series II/28B