Structure Data of Free Polyatomic Molecules
159
MW
COPd
Carbonylpalladium
Palladium monocarbonyl
r0
Pd–C
C≡O
Å
1.8447(1)
1.1374(2)
rIε a)
Pd–C
C≡O
Å
1.8438(2)
1.1380(2)
rm(1) b) Å
Pd–C 1.8434(3)
C≡O 1.1378(1)
rm(2) c)
Pd–C
C≡O
Å
1.84127(4)
1.14034(4)
rz
Pd–C
C≡O
Å
1.8454(2)
1.1370(2)
re
Pd–C
C≡O
Å
1.8401(2)
1.1360(2)
a
) ε = 0.06 u Å2 included in the fit.
) c = 0.01 u½ Å included in the fit.
c
) c = –0.024 u½ Å, d = 0.13 u½ Å2 included in the fit.
b
Walker, N.R., Hui, J.K-H., Gerry, M.C.L.: J. Phys. Chem. A 106 (2002) 5803.
Landolt-Börnstein
New Series II/28B
C∞v
Pd–C≡O