Structure Data of Free Polyatomic Molecules
88
MW
BrClH3P
Isotopic species
H3P · 79Br35Cl
H3P · 81Br35Cl
H3P · 79Br37Cl
H3P · 81Br37Cl
D3P · 79Br35Cl
D3P · 81Br35Cl
Bromine chloride – phosphine (1/1)
(weakly bound complex)
r0(Rcm) [Å]
3.6071(5)
3.5955(5)
3.6336(5)
3.6218(5)
3.6484(5)
3.6374(5)
r0(P...Br) [Å]
2.8692(5)
2.8692(5)
2.8697(5)
2.8697(5)
2.8537(5)
2.8541(5)
C3v
(effective symmetry class)
(large-amplitude motion)
BrCl · PH3
The intermolecular stretching force constant is 11.5 N m–1.
Legon, A.C., Thumwood, J.M.A., Waclawik, E.R.: J. Chem. Phys. 113 (2000) 5278.
Landolt-Börnstein
New Series II/28A