Structure Data of Free Polyatomic Molecules
148
MW
Cl2O2
a
Chloryl chloride
θ0
r0
Cl–Cl
Cl=O
Å
2.1966(15)
1.4367(8)
Cl–Cl=O
O=Cl=O
rz
Cl–Cl
Cl=O
Å
2.1987(14)
1.4390(7)
Cl–Cl=O
O=Cl=O
re a)
Cl–Cl
Cl=O
Å b)
2.1921(20)
1.4368(10)
deg
104.14(9)
114.96(10)
θz
deg
104.02(8)
114.63(9)
θe a)
deg b)
104.02(10)
114.63(15)
Cl–Cl=O
O=Cl=O
) Approximate equilibrium parameters derived from rz.
) Uncertainties were not estimated in the original paper.
b
Müller, H.S.P., Cohen, E.A., Christen, D.: J. Chem. Phys. 110 (1999) 11865.
Landolt-Börnstein
New Series II/28A
Cs
Cl
O
Cl
O