NATIONAL ADVISORY COMMITTEE FORAERONAUTICS _—. TECHNICALNOTE cm C2 m cm No.1380 , THE 1350° F STRESS-RUPTURE PROPERTIESOF TWO WROUGHT ALLOYSAND THREE CASTALLOYS ByE.E.Reynolds, J.W. Freeman, andA.E.White University ofMichigan wl!!v Washington November 1947 . -7 ..-r’“- 4’ -, — .. . .. -. .-,--...~TIONAL~SORY . . COWV .,”’ -., ---- ● -,. . ,- ., . ✎ ✎✎ —’ .,. TBE1350°F STRE~ - . ‘ ‘“. ‘.,~CHNIC& NOTkNO. l@Q ,, . FORAERONAUTICS .,. . z . .. ,, . X!ROFERTIXS 03’ TWOWROUG3T =s.,.-~ + ‘(MST ALLOYS .-. .’.. ByE.E.’ Reynolds, J,W.Freemanz andA.E.White . . . .,. ,“ ,. s“a4MAiY . . . . . . . ........+ ,. . -....:-=. ,-. “ , . .. . ..:-.. ., :. ..’ :..,”,..:-. . The&pture-test ch~acteristics a~13506F oftwo’ &o~;~,a~o~s; NR-82(605g “modif ied-lqw tiarbon) andNR-84(N-155 -smdified.-low .,carbq$~, andthethreeprecisiom-cast ailoys, NR-71 (X-ko), N%87(~~=~. :.,:, base+io ) ad NR+O (Co-Cr-Ni bas6-5Mo, m) hew.beendel%rmi’~d~’, ~~” twowrou@talloys were“tested in *8 solution-treated m-dagedconilly tionandthecastalloys wereagedbefore testing. Theprincip&i -“ resuitsobtained were: #- .,y,r,:: . . -. ,: -.. . . .’ ,. ,. >1 ,., ,. ,,, ‘ ~ :~~~e?y~;h at1350°!~,; . ,: ., . ..-. j~.~r~ - ?..”:” “’loohr .,, . . ,, ... . 32, >oo.,, ;.24,000. I’iro,ught NR-Q2 ‘. , .’. , .,. . ,. ,. .>.,.’, 24,000 ~m”tl@t’ NR+34 32,500 “’ ‘..:. ,L ,Ailoy ,, .. .. . .. . ,, 1“ Castmqi ,“ .,-. .,‘ ‘Ca6t ,“.NR+” Cimt“m-go . * * ,. ..-. . 45,000. ‘ 33,000 36,000 “““ 4b, 500 .,, 41,”&o‘“ .’34,000 ‘‘, ,,.,. .- . . . ., Theseproperties compare favorabl.y withthoseofthestrongest similar alloys previousl&. M*e8tiiBate&. “‘Ecm@v@r, coqmjed+itha 60Cr+me-15140 alloy, thethreecobal+chromium—m *ckelcast&illoys are inferior. ,. 2 . .... .. NACATNNO.1330 — .. A correlation ofNAw andOSRD(Pj.*o~ect NRC-8) dataispresente~ showi~~ thevariaticm ofrupture strengths withtemperatuz% inthe qe of 1350° to2000° 1?forthealloys. iNTRoDucmoN ““ A pro~rsm ofresearch, whichhasasitsaimthedevelopment of better alloys foruseat theelevated teqmmturesenoomt-ered inthe present-day-air’craft. powerp@nts,isinprdgress underwe sponsorship andwith’ thefinancial assistmce oftheNational AdvisowCcmmit~e for@mma@ics at the‘Wnive&sity of?iichigan. As partofthisirkvesttgatioll, ther@ture-t@ t cha~acterfs%iti~ oftwo“new wrought alloys andthreenewcastalloys werestudied at13X*3?.Thisworkwasbegun because tie1~00°and1600°F propm’ties, detmmincd intheCSRDresearch’ program (references 1 &d 2) show&d these‘to bepromising — alloys. . TEST141n!ERrALs Fivealloys, twointhe wrought for?+ andthree. aScastings, were submitted as testspecimens intheheat-treated condition by the National Research Council (Project NW-8). Qnlymaterial sufficient forthe1350° F rupture testswa8supplied. Chemical analyses of‘the ‘five alloys are2ivenintable1. The twowrought alloys, NR-82andN%84,aremodif Ications .oftwoalloys previously j.nvestigated, NR42 isAlloy60Z in whichthecarbGn was lowered from0.h6to0.i7yercent andone4mlfofthe. 6 percent molybdenumreplaced by 2 percent” tungsten and2 percent cokmbium.NR-8k isa modification ofallo~~ ~-1~~inwluchthqcarbon is. 0.14peroent instead of0.35percent; “chromium, nickel, @ cobalt eachraised from 20to23-24@ticent; and. theno~bdeqbv~=tin<olwbilmratio changed from 3:2:1to 4:1:2.mo c@Btalloys, NR-71(X-40), NR-87, basaalloys xLthvarying amounts andNIL90,arecobaltihromimmai.ckel of. molybdenum, andtun@ten. Manufacturing procedure andheattreatment ofthefivealloys aro as f01.lows : ● A -. .- 3 NACATNNO.13@ * .. — Alloys NR-52andNR-8b wereproduced by theUnionCWbideand C-arbon Corporation. Tney’wexe melted as3.00-pound basic induction heatsj hot-f urgedfrom2100°@ 1400°F from >inch-equare ingots tol-inch-square bars.Bothalloys weresolutio~treat+ 1 how at2200°X’$yate~uencheilj and. aged5dhoursa% 1350°F. Testspecimens 0.250 .anch in dhmeterwbremachined. fromthel-inch bars. ,. ‘ Alloys I@-71, l&87y ’and. NR+Owbreproduc@by the Ha~es-Stellite Company. Theyweremelted asZ&-pound heats inan $ndirect arc-rob~+~ furngioe ~d’precision-cast as O.250-inch-diameter testepe&[email protected]?lne spec~.mms werewed 50ho~s at2350°F lefore t~sting. --— PmmmtE ., “ . . . Stress-lwptum tests at 1350° F wereruntoat least1000hours to determine tierupture stren@hs forthefivealloys.Thelongestitim3rupture-test specimen ofeachalloywasexeui~ed metallo@a@~ ically and. itshardness d.etemuinbd. Therupture testswereconducted. asfolZows: Thestress wasap~liedtothespecitin byweights acting through a simple beamana system ofknifeedges.Thespecimefi wereheldattesttemperature fcmapproximately 24hcturs before application oftheloadtoallowfor tempe=tmre-distribution” aajustments., Tim elon$ati.on datawereobtained forthetestsbymeasuring i+ie dropof.theload,ing beamduring “ thetest, Thelcmgest-tims rupture-test speilmen ofeacla material wassectioned longitudlna.lly adJacent tothe” fracture. Phototicrographs ata 100-diemeter magnification wergtakenofthefractured. portion ofthe sgecimen andata 1000-diarcetey ma&ification oftheinterior 6trUCtUXe ofthesp43cimen nearthefracture .Vickers hardness testsweremadeon themetallographic specimens. .. .. “REsuw’s The1350° F rupture-test “results forthef~veallays s%~tidare givenintsbleIT. Thesedataareplotted infigure 1 onlox thmic coordinates ofstress aga~nst timeforrupture.me rupt~ s@er&hs and. theestimated rupture-test ductilities at 100,50Q>andWOO hours areg$.ven intable111. .- . 4 . NAC?A TNNo.13@ The’ twosolutio.&treated andagedwro~hta.lloYs, NR-82(6059 modified-low carbon) ~ NRg4 (N-155 modified-low carbon), gaveidum ticalrupture strengths Of 32, fjoo pf3~ “fOr ru t~ inlm h-# and 24,000 psifor30Q0-in~ rupture. 3 2,however, ~lqy“RR haaan~stimatedelongation to rupwe in10QOhotisof9 permnt,comparGd with 30percent foralloyNR-84. F ‘I’he threecastalloys hads@z@hs ranging ‘from .$1,000 tok5, OM psiforrupture in100hoursand33,000 to36@O0p~i’ forrupture in 1000hours.At‘1OO hours, alloyNR-71 (X-hO) hadthehighest stre@h, W% forlowertimepe~i~de ~Qy NR-87 wasthe&fnxmget3t. Comparative estimated elon@ztons torupture in1000hourewere40,1$,and8 percentforalloys IW-71 (X-M)j NRA? (CO-CZ+’W hase+fo ),andNR+O (Co-C*Ni base+lqo, al),rea~ctively. Fhotcmicro~raph6 ofthelongest-time r~@lu?cH7Gst specigmn ofeach alloy” “at% showninfigimes 2 and3. Inasmuch 5SOtiY‘kid-f iciont m&ti3rialfor‘the rujpture te~tswassupplied, nome+%llographic [email protected] of theori&inal materials couldbeprbpared. Represmtative original microstruc turesof soxw ofthesealloys canbefotidInr9fexwnco8 1 and2. ,. Vickeys hardness values determ’l~d ODthemot~lographlc ipoctmns aregivenunderthecorresponding pho+mmimogrcphD infigures 2 and3. , .,, * ‘% DISOWSION OFREEWIZ!S .. Thefivealloys in~estigated hadre~tively highrupture strem@hs at1350°F on thebasisofa comparison wi& fiveotheralioye previously investigated (reference 3). (Sac @ble’HZ.) “Thesefive alloys whiohhaveshowrl excellent properties ‘kre:~-1~~andcast6059, . alloys ofwhichthetWO: kiought alloys &de modifications; thestandard low-carbcn K-1>5; cast4.22-19; ad [email protected]~1~lo.o .. >.+oy. ,. ’t,.. ;..”. .. kkmghtalloyNR-8k(N-155 Wmfied-lowcarbon) hadrupture StZWD@@at~3500F approxi,~te~ ko~ psi@@er th~ thes~t~d wZou@talloyN-1~~whenhot-woik~d, tiecontition whichgavethehigheststrengti forN-155 at1350° F. Ztwasalso somxdmt @r0nf3er than low-carbon 11-1~~ wi,th a heat&?ea*nt sw~ ~ mat of wrcught alloy NR~4. Itthere foti’ beems,”: froma strength stc=d&oint, fiat~@ cow position modification ofI@/-8k waetenefici~.AI.~cu@~ble 11~ shdw-s that Westiengti ofk~ioyNI+84 WaStich” l“m& thestrongestcondition (h-r fo&od)~portedfor” ldii%ar~on ~“l~!% th’is Wtictiw heatwasworkedflo~tO 13500 F andhadexcessively high hotioldwork. strengths “due tothie . k .. . . . ‘.” NACATNNo.1380 .: 5 No comparison ona similar treatment basisispossible f’or wrought alloyNR-82(6059 modified-low c~bon),because theunmodified 60~ alloyhas” notbeentested inthewrought condition. It d.oes. have“lower streQ&th ,% castetandard 6059.Howeverj castings usually haveJ higher rupture strengti,s at 13500 ? than .wrougQt maisrials. . “Thbcast alloyshad slxisikr. rupturestrengths. Vsxiations in rupture thws frcrn. those~redicta@ by the. ruytux% curve, whichwere yossibly duetovarying c~stalorientation between specimens, makeit impossible toattributm theslight streng~Ufferences obs&vedto .. chemical” composition. . . . .. ,., ,. Thestrengths of,thesethreealloys areofthe,sameor&r ofrmg~“‘ nitudeas“that of-thebestca&’c“bbalt-chrom~ickel base@lox (422-19) ‘@?evibusly tested. at 13500 F. They have rmzch lowerstren@h, howeverl than‘cast 6oCr-2~e-l~:j whichisoneOfthehighest-streng~. ,... alloys . .. . .,., ., .. k.hti’, .,., T@-elongation curves from thempturatests on. thetwo. tio@hk alloy-s .s~owed thatthealloywithlo~r“d~~tility, NR-82(6059 modifi&ilowcarbqti~, hada lowerdeformation &l@ thandidalloyNR-84(N-155. modified-low earbori). Thiswastruealsoforthelowest-ducttli~ cast” alloyNR-~O,,compared with NR-7L a@ I&&/.Attention iecalled to, t@, factthatthespecitin ofalloyI!&71 (X-40) under32,500 psi hadexceesively h$gh elongation. Thefracture of thisspecimnwasof the single-crystal type,namely, anoval-shayed .f ormation ofthecryetal ad~acent tothefracture. This.explaim thehighductility. -. Metallographic examination ofthelonges%time rupture-test’ specimensrevealed. a matrix filledwithfinsparticle E ofexcess constituent. Thisistheusual appearem,ce of long-time rupture-test specimens ofalloys ofthistyye,thefineparticles precipitating during thetestandincreasing thehardness ofthematerial. This precipitation isconsidered tole an influential factor inthedsvQl~mentoftheoutstanding properties ofthesemterials. . . A correlation, whichshowsthevariation inrupture strength with temperature, “obtained! fromtheresearch program at1500°, 1600°, and 2000°F 4references 1,2, -a 4)w$th theNACAdata at1350°1700°, Aceml1800F,isshown infigure 4 ~ort~erivedd,oysstudie~. tually theonlyalloyforwhichruptmestrengths areava~lable over the, complete temperaiyme rangeisNR-~1(X-kO).Onthebasisofthe dataavaflable, theothertwocastalloys wtthstrengths of thesame orderofmegnj.tude wouldbe expected tovaryinstre~th@th te& perature toaboutthesameextent @s~.-7l.AlloyNR-71, incident-, wasthestrongest ofa groupofcast’ alioys tested..at 17@ and1800° F. (Seereference 4.) Thetiowrought~loyp, NR~2 a7@NR-8k, had practically identical rupture .stre@hsat both1350°and1500°F. Higher-temperature datahavenotbeen@termined onthesetwoalloys. NACATNNO.1380 .. CONWUSIONS ‘ ‘ , ,’ .“ Fromanitive~tig~t~on,qf ‘f&Strqss--rupf%re ptiperties at1350°F of twowrouglit alloys + thmO p~c:sion-c@ial loys,”thefollowing conolusj.ons weremade: Thetwowx%ugh$ alloy6~” @82 {6059modified-low carbon) &dl&84 (N-155 modified-low carbon),, had~dentioql 1350°F rupture strengths, althou@, al.loy N&8khad, muchhigher ductility, Thestrengtia ofthese aLloy8 arescmmwhat higher thanthoqeofstandard N-155, al@, butit is~&herdoubtfql whether thig~eqefit Issufficient towarrant the necessary increasein alloy content. TM @reeprecision-cast. a.llqw$ NR-’71”(X40)j NR~7(C~~i , b~e-~Mo,5W)had1350°F rupture base+lo)j andNR-$10. (CQ-CY+U streng~s whichqopqyared favorably with,tho$e ofalloy422-19, thebest cobeJ.~.@o?yi-c~el.base +loy previously investigated at1350°F. Thbghwe much lower Strengths however, thantheUestchromiw+base alloy@. Although’ there wem some difference inrupture strengths among the. thz%e.cast alloys, thereme nota co~sistent .variation.. Other f~tors,suchas”vti~tlons poesibly duetova~Ji~cryetal orientattonsbetweefi s~cinlens, makei-t i?npoqsible’ to”attribwt.e strength differences obsezwed tochemical composition. , . .. ‘% University ofMichtgan 15, 1946 ~&?bor, ~ch.,~ovember ., . .. . .. . ,. , . ,. .,..’ -. ,,, .. .’ . . ,.., r ‘. . . “....’ . . . NACA~ NO,1380 ‘7 .* IUWERENCES 1. Cross, HowardC.,andSinunonsj Warcl F.: Progress ReportonEeatResisting Xeta,ls furGasTMxinoParts(N-102). NWRCOSRDRep. No.b~l~,Ser. -No.. *477,Feb.20,1945. 2. Cross,Howard C.,andSimmons, WardF.:FinalReTort onHeatResistingMetals for~asTurbine l?~ts(N--102). NIIRCJ OSRDRep. NO,6563,Ser.No.1&636, Jan.21,1946, 3.Freeman, J.V.,Rote, )?. B.,andWhite, A.E.:HighTemperature Characteristics of17Alloys at1200° F and1350°F. NM2AACJ3 No.4C22, 19hb. h.Freeman, J.W., Reynolds, E.E.,[email protected], A,E.: TheRup~ TestCharacteristics ofSixPrecision-Cast andThreeWrought Alloys at 1700°and1800°F. NACAARRNo.5J16,1945. ~. . .-’ . . . E.E.,andWhite, A.E.: Weernan,J.W,,Reynoltls, AnInvestigation oftheHigh-Teraperature Properties ofChromiu&Base Alloys at 1350°F. NACATNNQ.1314, 1947. AIJm’IwEm AT133PF CEmfmL CCMWXTI oi’icw chemical Composition (percent) c lb SI m Cr 0.17 1.20 0.69 25.29 9.0 (60f@xm3&ie&low (w+5T&&fwOw co n m (n lb 30.83 3.35”.2.23 1.03 — ‘2 0.03 carbcm) ER+l (X4) 24.38 4.25 1.26 1.10 — 9.69 95.23 — 7.23 — 0.55 — 22.9 19.17 ml. .9.09 — — .9 — =.60 S.23 al. 5.qJ 5.1.8 — .8 “— .14 1.11 .48 .64 .’f%? S.I.2 .52 .-(0 .69 .44 .76 .m Cal-blm) .57 23.08 23.82 ,14 (bG+Ji M’m+b) T&l baea+!b, 5n) lrAmmAL Amtsm CQMTI!EE m AERmmrxcs 9 NACA TN No.1380 — -c .;. stress (Psi) Kuoy wrcn@tIm432 (@g m?dfied-low mbcm) wrought m-ah (%155 @fled-low oarbon) cast NR+l(X*) Rupture tim (w) 44.5 229 291.5 25,000 725 9 10.5 10.9 12.5 12 33,000 lM. 26 26.5 30,000 27,009 25,000 196.5 338 718 33 a30 39.0 2L2 28.2 35,0@3 32,5-00 Castm&87 J (~ bsse+b) 37,~ 35,000 34,000 i &Stm-go (w+h+f~b~, 45, Oco 40,000 X) k5,000 ., 40,00a 37,500 35,@3f3 34,0Q0 . x 32,500 %ksctmd~ 9 a8 a29 100 232 816 lug x 18 27 u 84 20 17 22 13 33 27.0 %3 8.5 IQ 15 8 2Q.i’ 7.0 378 775 918 lgao 53 84 542 639 960 1630 gs&s mrk. NATIONALAnvmoRY ccMal’lmFORAERoNmHc2 ... 10 Reduction of area (peroant) 35,000 30,000 28,000 45,0fM 40,000 . Elongation In 1 inoh (prcent) 7 40.7 37.7 35.0 45.6 27.4 31.8 33.1 35.0 13.3 16.5 10.2 6.4 10 NAC!ATN No.1380 TABL2. 111 ..-’ - .— -— . RuPrumPRoPERrIsS cFcAsTAm#KxMsT mOYs AT13500FAND CCWAR4TIW moPERImsOF0m2sAIuJx8 TrOa*nt w (6@gmdifiecl-lcw c*) +SObrat13w° F (yi) Sswmsted elcms&ion to rupture inMoati& tinu ~riode (peme.t) 100br SOOhr lm hr 100b 5oohr MOO h’ 32,500 26,000 24, W 10 9 9 32,54XI 26,m 24, COO 29 30 30 25 40 2200° F 1 hr V.Q. Wwughtm-8k modified-lew -es) cut m+ Streils forruptuxe in InMoatell timperiode E&30° 3’1hr U.Q. L&ought !!s-82 (%15S . +YOhrat1350°F (x-b’o) F 50hrat1350° 45,0C0 36,500 33,@3fJ31 50hrat 1350°~ 44,500 38,0CW 36, 0@2 20 20 18 5ohrat13500r u,m 36, oco 34,Cm 10 10 8 Cae-b IB87 (Ce-&-Ni bas~) Caet S&go Ims+5M, 5’.0 (O’=+J+Ni . mO@ltN-155* Eot%mrkwl 28,000 22,000 20, Oixl . Hrooght I.OwOarblm &l!& lf-~c F to1350°3’ 36,000 w,Ooo 30, CKKl 25, %@ Zast60na 501mat1500° F 36,m 32,500 :aet42s19= 50b at l~” F 47, m 39,5Q3 L b n,w 17 3.2 --- 26 3S a, 18 23 --- 36*OW 28 la 10 ----- ----- - 69, OCM ‘56,500 52,009 4 5 ‘i 22,800 b30, XQ %ta t9ken ~ reference 3. bobtidby atrapOld.iOB 6 2200°1?1 hru.% +f0bxat13x° F ifm-fma-l%bd 6 Eamwr fe.rgd frmo =Cd’ ~rm@t~mben 10 Of StlW3~p~ 1 . OKWW . x ‘I&ta taken fmm Uiohifpn for unreported Invewtlgatien en&piealI.ow-earben W155 bareteokinprogrees at theUniversity of theNACA. %atataken fromreference p. IwmXiALAImscRY CCWITUEFOSAESCKAVI’ICS . ,. . 1 I #!-%%-l Type chemical Heattreatment Alloy IWw 1 4* 1 0 a r at 0.1726 3; 31 4 2:2 1.0 0.;2 220 ❑ WroughtHR-82 at 4.2 1.3 1.1 .1423 24 24 220WW 1 hr %.&+50 hr 14 A WrouihtNR-84 .48: 2510557.250 hr at 135@F o castNR-71(Xao) .52! 2319 9 - - 50 hr at 1350°F x CastNR-f17 .441231181B~5 [5.21- I - 150hr at 1350°F ● Caet NR-90 ● I Lad 60,00( ~ 50,00( G .40,01X : *:30,()()( 01 20,00( 2 ) 4 6 8 100 2 4 6 8 1000 2 Time, hr Figure l.- Ourvesof streseagainstrupturetimeat 1350°F forwroughtalloyshlR-82 and NR-84and castalloysllR-71, NR-87,and NR-90. . + . . .- NACA TN No. 13 1380 6 Fracture, 100X . J Interior, 1000X under 25,000 psi; (a)AlloyNR-82 . 725hoursforrupture Vickers hardness 294. u alloys of specimens of wrought Figure2a,b.-Microstructures NR-82(6059modifi cd-lowcarbon) andNR-84(li155modified-low carbon) aftercompletion of 1350°F rupture test.Electrolytic chromic acidetch. . . . 15 NACA TN NO.1380 Fracture, 100X . .> ----- Interior, 1000X (b)Al:;:r:R--:$-::: ~~s . forrupture under25,000 psi; Figure2.-Concluded. ?- . . . ● NACA TN No. 1380 “-l -b PL- .— y, r Fracture, 100X C-&iz –-— . %? .,..>-● ,.:-. > 2;.-. .> . “-.?..”” +-. .-.,. ~,<. .,-. “—. .“ . J . ,-..-..-4 . + ,.-.20-.. .. -. . +’ . . ,.. . i, .>: “:-L?- .-. <<,-* ,.. ,,. . . .s.: . . ..;.j ... . ..+ .“, . . .4 .“. .l. ‘---.& . . * Interior, 1000X under32,500 psi; (a)AlloyNR-71.1189hoursforrupture Vickers hardness 466. of specimens of recisionFigure3 (a-toc).- Microstructures castalloysNR-71(X-40), NR-87YCo-Cr-Ni base- 5M0,5W)aftercomplebase- 9Mo),andNR-90(Oo-Cr-Ni acid etch. Electrolytic chromic tionof 13500F rupture test. ● . . . NACA TN No. 19 1380 -, .* Fracture, 100X Interior,1000X (b) AlloyNR-87.1980hoursfor ruptureunder34,000psi; Vickershardness 412. Figure3.-Continued. . . . . . . NACA TN No. 21 1380 Fracture, 100X . -“4 Interior, 1000X (c) AlloyNR-90.1630 hours for ruptureunder 32,500Rsi; Vickershardness405. Figure3.- concluded~ — . . . “ . NR-71., Rupturestrenuth Referenoefor 100 hr 1000 hr dataabove1350°1 Alloy 2 WroughtNR-82 c1 m Wr.,, vhk NR-R4 ,. WN3t-m-71 I1A -. .— . . :aB,NM+, Cast NR-90 NR-90” -v-%-. ! 4 a * @ . . ;$b \ E 5 20.00 .-.,= A 2 A , -, o II ● 11,2, 1 --- v I : I Q 6and4 2 I I 7 \ ,.\ -. . } \ \ > . ‘. . \ NATIONALADVISORYCOMMITTEE Ji’OR AERONAUTICS I I .& \ 1500 1700 1600 Temperature, ‘F 10, 1;00 1400 1800 1900 2000 for wrought . l?igure 4.- Variation of rupture etrengths with temperature alloysNR-82and NR-84and caetalloysNR-71,NR-87and X?R-90. t
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