Supplementary Material for
Neolignans from Selaginella moellendorffii
Jing-Xian Zhuo  Yue-Hu Wang  Xing-Li Su  Ren-Qiang Mei  Jun Yang  Yi
Kong  Chun-Lin Long
Jing-Xian Zhuo and Yue-Hu Wang contributed equally to this work.
J.-X. Zhuo  Y.-H. Wang  R.-Q. Mei J. Yang
Key Laboratory of Economic Plants and Biotechnology, and Yunnan Key Laboratory
for Wild Plant Resources, Kunming Institute of Botany, Chinese Academy of
Sciences, Kunming 650201, China
C.-L. Long ()
Key Laboratory of Economic Plants and Biotechnology, and Yunnan Key Laboratory
for Wild Plant Resources, Kunming Institute of Botany, Chinese Academy of
Sciences, Kunming 650201, China, or College of Life and Environmental Sciences,
Minzu University of China, Beijing 100081, China
e-mail: [email protected]
X.-L. Su  Y. Kong ()
School of Life Science & Technology, China Pharmaceutical University, Nanjing
210009, China
e-mail: [email protected]
Contents
Figure S1. 1H NMR spectrum of 1 (CD3OD, 600 MHz).
Figure S2. 13C NMR spectrum of 1 (CD3OD, 150 MHz).
Figure S3. HSQC spectrum of 1.
Figure S4. 1H‒1H COSY spectrum of 1.
Figure S5. HMBC spectrum of 1.
Figure S6. ROESY spectrum of 1.
Figure S7. HRESIMS spectrum of 1.
Figure S8. 1H NMR spectrum of 2 (CD3OD, 600 MHz).
Figure S9. 13C NMR spectrum of 2 (CD3OD, 150 MHz).
Figure S10. HSQC spectrum of 2.
Figure S11. 1H‒1H COSY spectrum of 2.
Figure S12. HMBC spectrum of 2.
Figure S13. ROESY spectrum of 2.
Figure S14. HREIMS spectrum of 2.
7.0
6.5
HO
OMe
6.0
5.5
5.0
4.5
4.0
f1 (ppm)
3.5
3.0
2.5
2.06
HO
2.27
H
1.02
1.02
3.14
2.70
6.05
2.04
1.04
1.00
0.98
1.99
Figure S1. 1H NMR spectrum of 1 (CD3OD, 600 MHz).
OMe
OH
OH
OMe
2.0
1.5
1.7632
1.7522
1.7392
1.7271
1.7161
2.9966
2.9871
2.8992
2.8838
2.5458
2.5337
2.5203
3.8174
3.7670
3.7573
3.7476
3.7405
3.6974
3.5207
3.5099
3.4991
3.4141
3.3150
3.3124
3.3100
3.3098
3.3071
3.3043
4.9101
6.6298
6.6269
6.4724
6.4698
6.3026
49.14
49.00
49.00
48.86
48.72
37.94
35.83
32.83
56.51
56.43
62.22
65.88
110.57
107.28
121.96
134.21
133.72
132.88
129.32
148.69
148.66
143.70
Figure S2. 13C NMR spectrum of 1 (CD3OD, 150 MHz).
HO
OMe
H
HO
OH
OH
OMe
OMe
155
150
145
140
135
130
125
120
115
110
105
100
95
90
85
80
75
f1 (ppm)
70
65
60
55
50
45
40
35
30
25
20
15
10
5
Figure S3. HSQC spectrum of 1.
HO
H
HO
OMe
OH
OH
OMe
OMe
Figure S4. 1H‒1H COSY spectrum of 1.
HO
H
HO
OMe
OH
OH
OMe
OMe
Figure S5. HMBC spectrum of 1.
HO
H
HO
OMe
OH
OH
OMe
OMe
Figure S6. ROESY spectrum of 1.
HO
H
HO
OMe
OH
OH
OMe
OMe
Figure S7. HRESIMS spectrum of 1.
HO
H
HO
OMe
OH
OH
OMe
OMe
Figure S8. 1H NMR spectrum of 2 (CD3OD, 600 MHz).
HO
H
HO
OMe
OH
OGlc
OMe
OMe
150
140
130
120
H
HO
OMe
110
HO
100
90
80
f1 (ppm)
70
60
50
42.72
39.58
35.69
33.14
49.00
56.52
56.29
77.99
77.81
75.92
71.12
67.13
62.37
62.16
111.63
107.03
105.56
120.24
153.15
148.62
143.53
140.39
138.52
134.13
132.51
Figure S9. 13C NMR spectrum of 2 (CD3OD, 150 MHz).
OMe
OH
OGlc
OMe
40
30
20
10
Figure S10. HSQC spectrum of 2.
HO
H
HO
OMe
OH
OGlc
OMe
OMe
Figure S11. 1H‒1H COSY spectrum of 2.
HO
H
HO
OMe
OH
OGlc
OMe
OMe
Figure S12. HMBC spectrum of 2.
HO
H
HO
OMe
OH
OGlc
OMe
OMe
Figure S13. ROESY spectrum of 2.
HO
H
HO
OMe
OH
OGlc
OMe
OMe
Figure S14. HREIMS spectrum of 2.
HO
H
HO
OMe
OH
OGlc
OMe
OMe