Global and Planetary Change 54 (2006) 225 – 238 www.elsevier.com/locate/gloplacha Contrasting conditions preceding MIS3 and MIS2 Heinrich events Elsa Jullien a,⁎, Francis E. Grousset a,b , Sidney R. Hemming b , Victoria L. Peck c , Ian R. Hall c , Cédric Jeantet a , Isabelle Billy a a EPOC, UMR 5805, Université Bordeaux I, Avenue des Facultés, 33405 Talence, France Lamont-Doherty Earth Observatory of Columbia University, Palisades, NY 10964, USA School of Earth, Ocean and Planetary Science, Cardiff University, Cardiff CF10 3YE, UK b c Received 4 August 2005; accepted 15 June 2006 Available online 3 October 2006 Abstract This paper presents an integrated multi-tracer study performed on piston cores recovered in the glacial ice-rafted detritus belt, stretching from Newfoundland to the Irish margin across the North Atlantic (40–55°N), in order to compare in detail the internal structure of each Heinrich event (HE). These tracers are IRD counts (quartz, dolomite, volcanic grains), their Nd isotopic composition and Ar–Ar datings of individual hornblende grains. A focus on the detailed structure of HE confirms that all intervals of massive sediment flux, specifically Heinrich layers HL1-to-5 (HLs), were dominated by North American, Laurentide ice-sheet surges from Hudson Strait, that are evident as far east as the Bay of Biscay (European margin). The sequences of events leading up to the HLs, however, present significant dissimilarities. One important difference is that HL2 and HL1 were preceded by “precursor events” (increases in the number of lithic grains per gram from non-Laurentide sediment sources). Sediment debris derived from near-simultaneous iceberg releases originating from the European ice-sheet are only detectable close to the European margin. In contrast there are no comparable precursor events before HL5 and HL4. This observation implies that precursor events are unlikely to be mechanistically linked to the triggering of HEs. The similarity of the HLs, against contrasting background conditions, is a significant observation that should add constraints to their origin. © 2006 Elsevier B.V. All rights reserved. Keywords: Heinrich events; ice-rafted detritus; Nd isotopes; 40 Ar/39Ar; Last glacial; North Atlantic 1. Introduction Over the last fifteen years or so, more than twohundred articles have been published on the so-called “Heinrich events” (HE) and their apparent global correlatives in oceans and continental climate archives (Heinrich, 1988 and see reviews by Andrews et al., 1998; Broecker and Hemming, 2001; Voelker, 2002; Hem⁎ Corresponding author. Tel.: +33 540 008 438; fax: +33 556 840 848. E-mail address: [email protected] (E. Jullien). 0921-8181/$ - see front matter © 2006 Elsevier B.V. All rights reserved. doi:10.1016/j.gloplacha.2006.06.021 ming, 2004). These events are characterized by abrupt collapses of the Laurentide ice-sheet, which delivered armadas of icebergs to the North Atlantic. Their melting resulted in ice-rafted detritus accumulation, the Heinrich layers (HL), identified by horizons rich in coarse lithic grains (N150 μm). The large bibliography and references therein mentioned above attest to the importance of these events for understanding mechanisms of rapid climate change; however, it is frustrating that a consensus conclusion on their origin has yet to be reached. A few theories concerning the origin of Heinrich layers have been proposed, but it must be admitted that none of them 226 E. Jullien et al. / Global and Planetary Change 54 (2006) 225–238 is entirely satisfactory. In particular, the question of the process(es) that produced HEs is still a matter of debate, and of particular importance is the question of whether they are internally or externally driven. A summary of the main hypotheses for HEs, glaciological binge-purge (MacAyeal, 1993), including earthquake induced destabilization, Hudson Bay jökulhlaups (Johnson and Lauritzen, 1995) and ice shelf break-up, was recently reviewed by Hemming (2004). A more recent external forcing mechanism, destabilizing the Laurentide icesheet rim with exceptionally high tides has been proposed by Arbic et al. (2004). The events following seem to be implied for each HE: (i). something (internal or external?) generated the iceberg armadas from Hudson Strait, (ii). iceberg armadas invaded the North Atlantic and melted in a west–east latitudinal band (40– 55°N) delivering their ice-rafted detritus; (iii). Atlantic meridional overturning circulation (MOC) shoaled dramatically or shut down, (iv). atmospheric teleconnections spread the climatic signal across the Northern Hemisphere, and perhaps the globe. However, Heinrich events are not identical. Before HL1 and HL2, precursor events are identified (Snoeckx et al., 1999; Grousset et al., 2001). From correlations of ice core and marine core data, the pattern of occurrences strongly implies climate con- trol on the origin of Heinrich layers, and thus a purely internal mechanism is unlikely. However, the sequence of events is not clear and requires further attention for interpretation of linkages. For example: 1) asynchronous surges of both Fennoscandian and Icelandic icesheets reveal that these European ice-sheets may have independently responded to their own internal dynamics (Dowdeswell et al., 1999; but see Elliot et al., 1998); 2) in the western side of the North Atlantic, the Laurentide could have generated its own precursors with very similar Nd and Sr isotope compositions to European sources (Farmer et al., 2003); 3) Timing of the meridional overturning circulation shutdown does not clearly postdate arrival of icebergs (fresh water) (Vidal et al., 1997). There are several important questions that have not been satisfactorily answered concerning the origin and impacts of Heinrich events. Among them are: (1) what were the ambient conditions associated with them and were they the same for all of them? (2) how much freshwater was released? (3) what was their duration, was it the same for each? (4) did they lead to a shutdown in MOC or did that come first? In this study, we attempt to better constrain the first question with regard to the behaviour of ice-sheets as captured by Ice Rafted Debris (IRD) composition. The goal is to test if the different Fig. 1. Core locations across the IRD (ice-rafted detritus) belt: main core SU90-11 (closed circle), other cores already studied (open circles) and cores mentioned in the text (crosses). Dotted line represents the extension of the ice-sheets during HE4 and HE5, whereas the thin continuous line represents the maximum extension of the Laurentide ice-sheet at LGM (− 130 m). E. Jullien et al. / Global and Planetary Change 54 (2006) 225–238 HEs have exactly the same precursory structure. Multiple parameters are documented from the same core, including magnetic susceptibility, X-radiography, isotopic (Nd and Sr composition of bulk coarse fraction as well as some quartz separates, 40Ar/39Ar of individual hornblende grains) tracers, and coarse fraction counts of mineral/rock fragment abundance (quartz, tephra, dolomite, etc). This study is focused on core SU90-11, a core recovered from a seamount located near the western end of the Ruddiman belt (preferential accumulation zone of IRD between 40° and 55°N; Ruddiman, 1977), close to the Laurentide ice-sheet (LIS), which should have recorded a particularly pure Laurentide source signal. Nd isotope results are compared to a series of cores exclusively located within the Ruddiman belt, along a W–E transect from close to the Laurentide iceberg source (≈ 40°W) to the Bay of Biscay (≈ 10°W). 2. Materials and methods Piston-core SU90-11 (Fig. 1) was recovered from the top of the Milnes Seamount located on the western part of the Mid-Atlantic Ridge (44°04′N, 40°2′W, 3645 m water depth). This site is located near the western end of the IRD belt (Ruddiman, 1977), and is about 1000 m above the surrounding abyssal plain (≈4700 m). Accordingly, the site is not likely to have received sediment from the Canadian margin by bottom current advection, and the site can be assumed to have collected only surfacederived particles in the coarse fraction, such as planktic microfossils and ice-rafted detritus. δ18O isotopic analysis on the planktic foraminifera Neogloboquadrina pachy- 227 derma (left coiling), along with AMS-14C ages are previously published (Labeyrie et al., 1995), allowing us to constrain the age model (Fig. 2, Table 1). Five other cores are used for comparison: SU90-08 (43°50′N, 30°40′W, 3080 m water depth) and SU90-09 (43°08′N, 31°08′W, 3375 m water depth) were recovered from the Mid-Atlantic Ridge and they have been extensively studied (Grousset et al., 1993; Revel et al., 1996; Cortijo et al., 1997; Vidal et al., 1997; Elliot et al., 1998; Huon et al., 2001; Grousset et al., 2000, 2001). Three cores located at the eastern extent of the IRD belt (around 15°W), were also studied: MD01-2448 (44°77′ N, 11°27′W, 3460 m water depth) from the top of the Biscay Seamount, MD95-2002 (47°45′N, 8°53′W, 2174 m water depth, on the Celtic margin) (Grousset et al., 2000) and MD01-2461 (51°45′N, 12°55′W, 1153 m water depth, on the Porcupine Bank) (Peck et al., 2006). The present study focuses on the upper three meters of core SU90-11 (covering the last 60 kyr), which contain the six most recent Heinrich Layers. Whole-core low-field magnetic susceptibility was measured aboard ship with a pass-through Bartington magnetometer. This instrument integrates the sediment section within the coil (12.5 cm ∅). Resolution is of the order of 2 cm. The sedimentary sequences, lithologic facies, and the geometry of physical and biological structures were observed using a digital SCOPIX X-ray device, coupling a high-energy brightness amplifier and a digital camera (Migeon et al., 1999). The sediment core was sliced at 1 cm intervals. For each slice a 2-cm3 aliquot was washed and sieved to Fig. 2. Age model for core SU90-11. The accumulation rate was dramatically greater during HLs (≈ 12 cm/ky) (grey lines), whereas between HLs, accumulation rate was three times lower (≈4 cm/ky) (dark lines). 228 E. Jullien et al. / Global and Planetary Change 54 (2006) 225–238 Table 1 Age constraints used for building the SU90-11 age model. Sources: 1. this work; 2. Labeyrie et al. (1995); 3. Grousset et al. (2001). Calendar ages, after Bard (1988) Depth (cm) 14 C ages (kyr) Pointers Source Calendar ages (kyr) 12 14 11.1 11.6 1 2 12.938 13.549 17 13.4 3 15.735 42 15 3 17.661 45 16.4 2 19.334 65 20 3 23.582 89 22 3 25.908 93 22.3 2 26.255 105 23.7 3 27.866 110 26.4 3 30.941 115 27.3 2 31.956 124 29.2 2 34.083 135 33.8 3 39.142 3. Results 166 36.1 3 41.516 195 44 3 44.934 220 46 3 46.387 239 54 Ash Zone I AMS-14 C dating Tuned on SU90-09/08 Tuned on SU90-09/08 AMS-14 C dating Tuned on SU90-09/08 Tuned on SU90-09/08 AMS-14 C dating Tuned on SU90-09/08 tuned on SU90-09/08 AMS-14 C dating AMS-14 C dating Tuned on SU90-09/08 Tuned on SU90-09/08 Tuned on SU90-09/08 Tuned on SU90-09/08 Ash Zone II the Toulouse University. Standard results for the period of these analyses are 0.710245(20) (n = 6) for Sr standard NBS987 and 0.511846(15) (n = 5) for Nd standard La Jolla. For convenience, Nd isotopic ratios are presented as follows: εNd(o) = (( 143 Nd/ 144 Nd) / 0.512636 − 1) ⁎ 104 , where 0.512636 is the Chondritic Uniform Reservoir value (Jacobsen and Wasserburg, 1980). Hornblende grains were picked from the N150 μm fraction and processed as reported in Gwiazda et al. (1996a), Hemming et al. (1998, 2000) and Hemming and Hajdas (2003). An effort was made to select at least 15 hornblende grains per sample; however in some cases this was not possible, and all the grains were picked and analysed. Samples were co-irradiated with a monitor standard of known age in the Cd-lined in core facility (CLICIT) at the Oregon State reactor. Ages of hornblende grains are consistent with 525 Ma for hornblende monitor standard Mmhb (Samson and Alexander, 1987). Analyses were made in the Ar geochronology laboratory and Lamont-Doherty Earth Observatory. Individual grains were fused with a CO2 laser, and ages were calculated from Ar isotope ratios corrected for mass discrimination, interfering nuclear reactions, procedural blanks and atmospheric Ar contamination. 1 analyse the coarse fraction (N150 μm); IRD (including quartz, carbonate and volcanic particles) were counted under a binocular microscope (Table A1, accessible through the electronic supplement). Counts were made at each centimeter between 5 and 104 cm, and 144 and 235 cm, every other sample was counted between 104 and 144 cm depth. For each sample, more than 300 grains were counted. Samples with large numbers were split to yield (300–1300) grains. Nd and Sr isotopic compositions were measured on the carbonate-free, coarse (N150 μm) fraction. Carbonate was removed by HCl 1 N. Samples were processed in a “US class-1000” clean laboratory at Université Bordeaux. The coarse fraction was dissolved with acid solutions (HCl, HF, HClO4). Sr and Nd were separated through cationic and anionic chromatographic columns following the procedure of Grousset et al. (2001). Samples were analysed on a Finnigan MAT 261 mass spectrometer at 3.1. Stratigraphy In addition to the δ18O and AMS-14C results from Labeyrie et al. (1995), there are some specific markers that allow greater age constraints on core SU90-11. At 12– 13 cm depth, abundant translucent-to-light yellow, bubble-wall glass shards reveal the presence of the well known Ash Layer 1. The maximum occurrence of these tephra was observed at 13 cm depth, providing thus a well defined age: 11,100 years BP (Lacasse et al., 1996 and references therein). Translucent tephra characterizing the Ash Zone II were identified at a 239 cm depth, providing another age control: 54 ka (Lacasse et al., 1996 and references therein). Along with these two tephrachronologic dates, six AMS-14 C ages were obtained on foraminifera N. pachyderma (lc) (N 150 μm) (Labeyrie et al., 1995). These ages have to be considered with care, as a constant age-reservoir correction could be inaccurate, especially for levels close to the HLs (Waelbroeck et al., 2001). They are, however, consistent with ages classically attributed to HL boundaries (see review in Hemming, 2004). The apparent age at the core top is ∼8000 years BP and thus we assume that upper Holocene sediments might have been destroyed during coring or that Holocene sedimentation rates were very low. E. Jullien et al. / Global and Planetary Change 54 (2006) 225–238 229 Fig. 3. Core SU90-11: a. X-radiograph (HL: Heinrich Layers; p: precursor); b. magnetic susceptibility (10− 6 emu); IRD counts (grains/g. of dry sediment): quartz grains (c), dolomite grains (d), volcanic grains (e); (f). Nd isotopic composition (εNd(o)) of the carbonate-free, coarse (N150 μm) IRD fraction; (g). δ18O (PDB) of planktonic foraminifera Neogloboquadrina pachyderma (left coiling) (from Labeyrie et al., 1995). HLs are highlighted by light grey bands and dark grey bands for precursors (p). 230 E. Jullien et al. / Global and Planetary Change 54 (2006) 225–238 Fig. 4. IRD counts (grains/g. of dry sediment) of quartz (thin grey line), dolomite (thin black line), volcanic grains (dotted line) in cores SU90-11, SU90-09 and MD01-2448. Heinrich layers and precursors are highlighted by light and dark grey bands, respectively. Whereas HL3 and HL6 are barely visible on bulk sediment measurements, the main HLs (HL1, HL2, HL4 and HL5) can be easily identified, based on magnetic susceptibility and X-ray density records (Fig. 3). The less apparent presence of HL3 is consistent with the early survey of HLs (Grousset et al., 1993). Using the positions of their boundaries and the age model developed from tephra and 14C, the following approximate 14 C ages are implied for the Heinrich events: HL1: 13,095–15,000 yrs; HL2: 20,360–22,380 yrs; HL3: 25,950–27,260 yrs; HL4: 34,050–36,310 yrs; HL5: 44,050–46,900 yrs (Table 1, Fig. 2). The age range implied is greater than the duration of the events because a linear sedimentation rate is used to make the estimates. Whereas the mean accumulation rate of the ambient sediment is 4 cm/ky, during the most prominent HLs (HL1, 2, 4, 5) it is multiplied by at least a factor of 3 (≈12 cm/ky). This increase of the accumulation rate during the HEs is confirmed by a parallel systematic decrease by a factor 5 of the 230 Thexcess (C. Lalou, unpublished data, pers. comm.). In the ambient sediments, however, such low accumulation rates prevent the identification of abrupt, secondary lithic peaks – if any – , such as IRD events previously observed in contourite drifts (Bond and Lotti, 1995) or in deep sea fan systems (Knutz et al., 2001, 2002). 3.2. Petrology, geochemistry, isotopic composition and proxy meanings The goal of this study is to combine multiple compositional parameters in order to better determine the geographic origin of the IRD, and therefore to identify the ice-sheet(s) responsible for their transport (Fig. 3). In the coarse fraction (N 150 μm) quartz grains are 5 to 7 times more abundant during the HLs than in the ambient sediments, along with the increase in accumulation rate, suggesting a substantial increase in the IRD flux delivered to the site. Quartz is a ubiquitous mineral in continental sources, and thus it is a measure of the quantity of IRD delivered, but does not constrain the origin except to eliminate basaltic sources. The dolomite (CaMg(CO3)2) grain record parallels the quartz record. Dolomite grains comprise up to 12% of HLs and are very sparse in between. Dolomite is an important sedimentary and metamorphic mineral found in limestones, marbles and serpentinites. Although dolomitic limestone is a relatively common component of sedimentary E. Jullien et al. / Global and Planetary Change 54 (2006) 225–238 Table 2 Nd isotope data expressed as εNd(o) and mean Ar–Ar ages (My) Cores Depth (cm) Events εNd (o) SU90-11 " " " " " " " " " " " " " " " " MD01-2448 " " " " " " " " " " " 12 20 35 40 43 50 73 88 94 97 100 110 142 160 163 168 172 125 129 131 136 140 142 184 199 202 204 206 216 Ash Zone 1 HL1 HL1 Precursor Precursor Precursor HL2 HL2 HL2 Precursor Precursor HL3 HL4 HL4 HL4 HL4–HL5 HL4–HL5 HL2 HL2 HL2 HL2 Precursor Precursor HL3–HL4 HL4 HL4 HL4 HL4 HL4–HL5 −16.3 −36.6 −26.2 −14.12 − 4.9 −13.9 −29.2 −30.5 −16 − 9.5 −12.8 −24.1 −29.4 −31.5 −31.2 −24 −21.5 −12.9 −24.1 −18.9 −22.12 − 8.66 −12.4 −15.9 −26.3 −33.36 −34.23 −29.57 −14.02 Ar–Ar ages (My) 2373 2581 710 937 1668 1750 outcrops (Bond et al., 1992), the increase in detrital carbonate in Heinrich layers is coincident with a Hudson Strait source of icebergs (Andrews and Tedesco, 1992). Thus, these grains are inferred to reflect the erosion of dolomite-rich limestones, located in the Baffin Island and Hudson Bay area. The maximum concentration of dolomite is reached later, a few cm after the quartz maximum, consistent with the deposition sequence reported by Grousset et al. (2001) for core SU90-09 (Fig. 4). Micas and rock fragments (e.g. granite, gneiss, schist) are also observed within the IRD assemblage and are counted as other grains as they are not discriminant enough versus sources (Table A1). The abundances of quartz and detrital carbonate grains clearly mimic the magnetic susceptibility record and X-ray image (Fig. 3), which reflect the abundance of magnetite associated with feldspars through the core (Grousset et al., 1993). Sharp basal contacts are apparent in the X-ray images for HL1, HL2, HL4 and HL5 (Fig. 3). HL3 is visible, but the basal contact is not as clear and the layer is no more than 3 cm thick. The increase in IRD content begins before the onset of the 231 Hudson Strait (sharp basal contact and detrital carbonate) flux during HL1 and HL2. The precursory interval prior to HL2 is visible approximately 3 cm below the sharp contact with the dark X-ray image for HL2. The increase in IRD content for HL4 and HL5 is very sharp, and quartz and volcanic grains increase together at the beginning of HLs and decrease abruptly at the end, whereas dolomite is restricted to the inner part of the IRD layers. The abundance of volcanic grains (pumice, dark obsidian and basaltic fragments) displays a different behaviour to the crustal fragments. Before HL3 and after HL1, the abundance of volcanic grains follows those of quartz and dolomite (Fig. 3). In between, the abundance of volcanic grains increases significantly (×2) just prior to HL2 and HL1. A similar pattern was reported for core SU90-09 (Fig. 4) and considered as “European precursor events” (Grousset et al., 2001). In the North Atlantic province, the volcanic grains may be sourced from Iceland, the Thulean province of the Eastern Greenland, the Faeroes and even by British Isles (Knutz et al., 2002). The isotopic signatures of these different volcanic provinces are too similar and thus cannot be distinguished. Considering its significant size and location, the Icelandic province seems to be the most credible source for volcanic particles. Some of these volcanic grains were isolated in the neighbour core SU90-09 (Grousset et al., 2001) and their isotopic composition (87Sr/86Sr = 0.70367; εNd(o) = + 7.4) matches the composition of the Cenozoïc basaltic rocks of Iceland and Eastern Greenland: (87Sr/86Sr ≈ 0.7035; εNd (o) ≈ + 7.6, Revel et al., 1996). During the last glacial period, Iceland was entirely covered by an ice-sheet that extended across the shelf, at least down to − 120 m (Siddall et al., 2003). Thus, the volcanic grain record is interpreted to reflect the temporal behaviour of the Icelandic ice-sheet. The Sr and Nd isotopic composition of IRD may help to fingerprint sediment sources: basically, when 87Sr/ 86 Sr ≈ 0.704 and 0 b εNd(o) b +10, sediments are derived from young volcanic rocks (≈ 0–1 Ga); on the other hand, when 87Sr/86Sr N 0.72 and − 40 b εNd(o) b − 10, sediments are derived from older crustal rocks (≈ 1– 3 Ga). Around the northern North Atlantic Ocean, such old outcrops only exist on the North Canadian Shield. Our isotopic data are consistent with results from other cores (Grousset et al., 1993; Revel et al., 1996; Hemming et al., 1998; Snoeckx et al., 1999; Grousset et al., 2000, 2001). Within the HEs most of the εNd(o) values range from −20 to − 40, along with radiogenic Sr ratios (0.72 b 87Sr/86Sr b 0.73), reflecting Archean heritage. However, just prior to H2 and H1 – within the precursor 232 E. Jullien et al. / Global and Planetary Change 54 (2006) 225–238 Fig. 5. Mean Ar–Ar ages (Ga) of hornblendes compared to the εNd(o) values (both measured in the same carbonate-free, coarse (N150 μm) IRD fraction). Inset histograms show the distributions of ages, where: a. b50 Ma indicates Icelandic (broadly, including the hotspot in general); b. 200– 600 Ma indicates Appalachian/Caledonian ages; c. 0.8–1.2 Ga indicates Grenville ages; d. 1.6–1.9 Ga indicates “Churchill” (this is the Canadian Shield term) or contemporaneous crystalline sources from e.g., Greenland; e. 2.4–2.8 Ga indicates “Superior” (this is the Canadian Shield term) or contemporaneous crystalline sources from e.g., Greenland; f. “other” indicates grains that fall outside of these groupings, and could be derived from crustal provinces not included here, partially reset grains from the provinces listed, or complex systematics such as excess Ar. The apparent ages of the “other” grains are listed above that bar on the histograms. events – εNd(o) range from − 5 to − 15 and 87Sr/86Sr ratios range from 0.715 and 0.72. Such high εNd(o) values were interpreted as reflecting a European origin (Grousset et al., 2000, 2001). A radiogenic εNd(o) value of − 16.1 at 12–13 cm depth represents the signature of Ash Zone I (Table 2). Ar–Ar ages of hornblendes were measured from the same levels for which we obtained εNd(o) values. Individual data are reported in a supplementary table. Results presented in Fig. 5 are the averaged value of the measurements made in each sample, and histograms are included to show the age populations represented. The oldest mean ages were obtained for HL2 (≈ 2.5 Ga) and HL3 (≈ 1.75 Ga). They correspond to the most unradiogenic εNd(o) values, which is consistent with a Canada/Greenland origin. HL3 could also be derived from Europe: in Scandinavia, Early Proterozoic crust is observed but samples from the Bear Island “trough mouth fans” have only few hornblendes and are clearly dominantly derived from sedimentary sources. Along the Norwegian margin, the crystalline crust is dominated by Caledonian ages with the possible exception of the very southern tip of Norway which has Grenville outcrops. So, in this core, it is reasonable to exclude a European source. The Laurentide-derived origin of HL3 challenges an entirely European origin for HL3 and HL6 (e.g., Snoeckx et al., 1999); however, the geographical and spatial distribution of Sr isotopes compiled by Hemming (2004) is consistent with a European origin in the eastern basin and a Laurentide (and Greenland) origin in the western basin. Both precursor events and embedding sediments display more radiogenic εNd(o) and youngest ages (≈0.5 to ≈1.5 Ga) that are consistent ages previously observed in the North Atlantic sediment background (Huon and Jantschik, 1993) (Table 3). 4. Discussion 4.1. HL1 and HL2 The internal structure of HL1 and HL2 is similar (Fig. 3): a rapid increase in IRD associated with a sudden decrease of the δ18O composition of planktic foraminifera. The interval with lighter δ18O is shown to have a classic Hudson Strait signature of high magnetic susceptibility, high IRD content, dominated by quartz and detrital carbonate and very unradiogenic Nd. These two main layers are characteristic of the typical Heinrich layers, extensively described in the North Atlantic since 1988, especially within the IRD belt (e.g., Bond et al., 1992; Grousset et al., 1993; Hemming, 2004 and references therein). E. Jullien et al. / Global and Planetary Change 54 (2006) 225–238 Table 3 Individual Ar–Ar ages (My) obtained on single hornblende grains. 12, 17, 17, 6, 9, 12 grains were analysed at 73 cm, 88 cm, 94 cm, 97 cm, 100 cm and 110 cm, respectively Depth (cm) Ar–Ar age (My) of single grains 73 " " " " " " " " " " " 88 " " " " " " " " " " " " " " " " 94 " " " " " " " " " " " " " " " " 97 " " " " " 100 " 1282.9 1664.5 1716.5 1731.5 1752.5 1881.5 2358.3 2570.1 2847 2907 3096.4 4664.3 1441.8 1661.9 1668.8 1718.6 1726.7 1730.5 1747.5 1782.9 1883.4 2579.1 5216.3 3894.4 2091.9 1915.1 3012.4 6634.2 3172.1 25.1 302.9 383.6 391.2 403.4 411.2 452.5 463.2 488.7 510.2 988.4 1484.1 1723.7 1945 498.3 675.4 917.1 4.3 16.0 455.4 1603.1 1719.9 1823.1 18.3 1647.1 Ar–Ar age (My) mean value 2373 233 Table 3 (continued) Depth (cm) Ar–Ar age (My) of single grains " " " " " " " 110 " " " " " " " " " " " 4520.6 1861.6 970.8 1750.7 2073.2 1573.9 592.2 1307.2 1395.1 1626.9 1749.9 1753.1 2232.3 2272.6 2529.9 1503.8 1980.4 2342.9 306.0 Ar–Ar age (My) mean value 1668 1750 Prior to the major Laurentide surges during HL1 and HL2, precursor events are observed in many cores from the IRD belt: 2581 710 937 – In the northeastern Atlantic basin, it has been clearly shown that precursor events reflected early discharge of icebergs by the European ice-sheets. For example, such early emissions of icebergs coming from British Isles ice-sheet have been described in cores MD012448 (this work), MD95-2002 (Grousset et al., 2000), OMEX-4K (Scourse et al., 2000), DAPC2 (Knutz et al., 2002) and MD01-2461 (Peck et al., 2006) (Fig. 1). – In the northwestern Atlantic basin, precursor events occurring prior HL1 and HL2 are revealed by thin volcanic-rich layers, displaying more radiogenic Nd compositions (εNd(o) N − 17; Grousset et al., 2001). This is the case in both SU90-09 and SU90-11 cores, where these characteristics suggest a significant increase of iceberg release from the Icelandic icesheet and/or from other volcanogenic provinces such as western Greenland or even the southeastern Canadian Monteregian Hills province. How can we explain the geographic pattern of these precursors? Along the 45°N latitude, the thickness of the HL1-2 precursors decreases eastward: 7–9 cm in SU90-11, 4–5 cm in SU90-09 and they are barely visible in MD01-2448 (Figs. 1 and 4). Off the Irish margin, however, at about 52°N (core VM23-81), 234 E. Jullien et al. / Global and Planetary Change 54 (2006) 225–238 precursor events are still visible prior to HL1 and HL2 (Bond and Lotti, 1995). Furthermore, in the ambient sediments separating HL3, HL2 and HL1, a few distinct, discrete IRD pulses were also identified by these authors. These precursors are enriched in basaltic grains which may come from the British Tertiary Province (Knutz et al., 2001) or from Iceland (most likely), and increases in hematite stained grains in these intervals have been attributed to a Laurentide (Gulf of St. Lawrence) origin (e.g., Bond and Lotti, 1995). Additionally, their Nd isotope composition allow a Gulf of St. Lawrence source (Farmer et al., 2003) and the Ar–Ar ages measured in hornblendes deposited right before HL2 in SU90-11 (Fig. 5) have a large Paleozoic (Appalachian/Caledonian) signature. Indeed, during ambient glacial conditions preceding HL1 and HL2, the different pan-Atlantic ice-sheets released icebergs that melted close to their borders: the British Isles ice-sheet along the European margins, the Laurentide/Greenland over the western Atlantic basin. However, the Laurentide IRD supply during HL1 and HL2 is clearly dominant. LIS sourced icebergs were presumably distributed by the prevailing westerly winds and eastward currents, as far east as the European margin. Such a supply has been identified in the eastern Atlantic basin: for example, in core VM23-81 (Bond and Lotti, 1995), in core MD95-2002 (Grousset et al., 2000), in core DAPC2 (Knutz et al., 2002) or in core MD01-2461 (Peck et al., 2006). Along the European margins, whereas HL1 and HL2 are dominated by European IRD, the central section of these Heinrich layers is dominated by a Canadian imprint. During these two HLs, Laurentide surges became so massive, that icebergs invaded the entire surface of the IRD belt, as far east as the Bay of Biscay (Grousset et al., 2000). 4.2. The “atypical” HL3 event Because previous works on HL3 have been mostly conducted on cores located on the eastern side of the North Atlantic, it had been claimed that HL3 was different from the other events and that its origin was more likely European (Grousset et al., 1993; Gwiazda et al., 1996b; Snoeckx et al., 1999). In fact, this statement has to be tempered. In cores DSDP-609 and VM23-81, H3 clearly reveals a succession of pulses of 1) hematite-coated grains that could be derived from the “red beds” in the Gulf of St. Lawrence and 2) detrital carbonate grains from the Hudson Strait (Bond and Lotti, 1995). We may argue that there are several possible hematite-grained sources around the North Atlantic Ocean and thus, hematite-grained does not appear to be a reliable tracer for the LIS origin. A North American signature is confirmed, however, by our findings in core SU90-11: in this western core, HL3 displays a Laurentide-derived isotopic composition (εNd (o) = − 24.1). Although HL3 remains an “atypical” HL (Snoeckx et al., 1999), it is clear that it cannot be considered as an HL solely derived from Europe (Fennoscandia and/or British Isles). We suggest that, HL3 was probably generated by reduced iceberg releases concerning all the different pan-Atlantic icesheets, their respective influence being recorded only on a regional scale. This is reflected in the map pattern of Sr isotope compositions (Hemming, 2004). As HE3 and HE6 present very similar characteristics (Huon and Jantschik, 1993; Gwiazda et al., 1996b; Grousset et al., 2000), they might have been generated by similar processes. Thus, in order to check its resemblance to HE3, HE6 should be better studied in the future. 4.3. HL4 and HL5 Like HL2, both HL4 and HL5 in core SU90-11 are characterized by a sharp basal contact of the IRD deposits and the underlying glacial sediments (Fig. 3), implying a very sudden onset of IRD deposition. Before HL2, the ice volume of all North Atlantic ice-sheets was considerably reduced, compared to the HL2–LGM– HL1 interval. Accordingly, during HL1 and HL2, the contribution of IRD and probably fresh water were approximatively equal to those during HL4 or HL5. It implies that ice-sheets do not need to be fully developed to create “typical” Heinrich events but presumably the collapse of the smaller ice-sheets present at that time was probably larger during HL4 or HL5. It would also seem to place constraints on the volume of ice that could be assumed to have been purged from the Laurentide ice-sheet. The late appearance of dolomite in HL4 may indicate a precursory event as well, but the Nd composition indicates ancient sources, unlike before HL1 and HL2. The dolomite content of HL5 is very low compared to the other layers. In core V28-82, HL4 and HL5 contain similar percents of detrital carbonate, 15% and 16% (Hemming et al., 1998). Thus the lesser content at SU90-11 might reflect a more northern iceberg melting path during HL5, more like that followed by HL2 and HL1, as traced by magnetic susceptibility patterns (Grousset et al., 1993). As suggested by the X-ray image (clearer sections on Fig. 3), it appears that before, between and after HL5 and HL4, the ambient sediments contain finer E. Jullien et al. / Global and Planetary Change 54 (2006) 225–238 terrigenous components. Prior to HL4, we do not observe any precursor event similar to the precursors observed prior to HL1 and HL2. Instead, a very small increase of quartz and volcanic grains can be observed (Fig. 3): such a pattern cannot be interpreted as a typical precursor event. Some IRD are present between HLs at a very low level, revealing that pan-Atlantic ice-sheets (especially Laurentide and Greenland) released icebergs continuously. Because they could have been incorporated into the anticlockwise surface current gyre suggested by Ruddiman (1977), during these intermediate periods, icebergs discharged from the European ice-sheets could have also reached the western part of the IRD belt. If so, their abundance was very limited and thoroughly diluted by the Laurentide/Greenland inputs. Moreover, the low accumulation rate characterizing this core might preclude any identification of secondary IRD events previously observed in high accumulation rate cores (Bond and Lotti, 1995; Elliot et al., 1998). A similar scenario is observed in other cores from across the North Atlantic within the IRD belt, the HL thickness during both HL4 and HL5 decreases from west to east: 30 cm in SU90-11, 20 cm in SU90-09 and 10–12 cm (only for HL4) in MD01-2448 (Fig. 4) and increases again along the European margin (Grousset et al., 1993). On the eastern side of the IRD belt (core MD01-2448), the isotopic composition of the glacial background is typically European (εNd(o) N − 16 / − 17). The contrast between HL4–HL5 and HL1–HL2 has also been suggested by other studies. For example, the Nd–Sr isotopes in core ODP-609 show variations consistent with those reported here (Vance and Archer, 2002). Additionally, both the δ13C and δ15N of the organic matter (Huon et al., 2001) and biomarker distribution (Kornikova et al., pers. comm.) in core SU90-09 show profoundly different character in HL1– HL2 and HL4–HL5. What is the origin of the difference between HL1/ HL2 different from HL4/HL5? During the LGM (between 25 and 14 ka), the sea level was particularly low (oscillating then between −80 and − 130 m; Siddall et al., 2003) and the Northern Hemisphere ice-sheets were extended to their maximum positions, with many terminating at the shelf–slope boundary. 4.4. Spatial and temporal variability Two aspects of the LGM were more favourable for depositing IRD with distinctive composition into the North Atlantic. One is that the termination of the ice at the shelf–slope boundary would have made it more 235 likely for the IRD of icebergs to survive melting until they were carried into the open ocean currents (e.g., Syvitski et al., 1996; Hemming et al., 2002). The second is that the ice covered regions with different geological ages. This is particularly clear off Nova Scotia and Newfoundland (Fig. 1) and could explain the particular composition of sediments imbedding HL1, HL2 and HL3 in core SU90-11. Hemming et al. (2000) and Hemming and Hajdas (2003) have showed that in the interval between the end of HL3 and the end of HL1, the non-Heinrich layer IRD has a very large fraction of hornblende grains with 40Ar/39Ar ages reflecting erosion of Appalachian/Caledonian and Grenville age provinces. In contrast, after HL1 and before HL3 and down to HL5 (the end of the studied interval), there is little evidence of icebergs derived from terrains with such ages, and instead the ages are dominated by Paleoproterozoic grains (Hemming and Hajdas, 2003). These authors have interpreted the variations in hornblende ages from these cores near the Laurentide margin to reflect the evolution of ice advancing to the ocean on Laurentide. Specifically, the results would imply that the LIS expanded to the Gulf of St. Lawrence region at about 30,000 years BP (∼ HL3) and remained there until about 17,000 years BP (∼ HL1). Before HL3, it is likely that Greenland and possibly northern Laurentia were the dominant sources of hornblende grains, and after HL1 it is likely that the importance of Greenland sources increased again (Hemming et al., 2000; Hemming and Hajdas, 2003). We would suspect a similar progression for Iceland and European ice-sheets and this is consistent with studies of the abundance of IRD in the Nordic Seas (see references in Hemming, 2004). In parallel, around the LGM, the simultaneous change in surface circulation associated with the southward shift of the polar front, could have modified the iceberg trajectories, explaining thus the change in their IRD load composition. It is clear that in all sites studied in the North Atlantic Ocean, a LIS signal is identified for typical HLs (− 40 b εNd(o) b − 17) (Fig. 6). For HL3, it seems to be more complex because we observe limited evidence of a LIS contribution based on Sr and Nd isotopes and Ar/Ar. Close to the source of icebergs at the western entrance of the IRD belt, HLs are exclusively represented by debris of Canadian origin. In this region, the HL thickness may reach 50 cm (Grousset et al., 1993). Further east, as icebergs melted progressively, the Laurentide sourced IRD became progressively less prominent: about 10 cm thick on the Mid-Atlantic Ridge and only a few centimeters along the European margin (Scourse et al., 2000; Grousset et al., 2000). The eastward transport of 236 E. Jullien et al. / Global and Planetary Change 54 (2006) 225–238 Fig. 6. Spatial variability of the εNd(o) values measured on the carbonate-free, coarse (N150 μm) IRD fractions of the Heinrich layers in five different cores (see location on Fig. 1). Records are aligned along a west–east transect, inside the IRD belt. εNd(o) values more negative than − 17 (right side of the dotted vertical lines) point to a Canada/Greenland origin (sub-horizontal grey bands). Laurentide-derived icebergs was driven by the oceanic and atmospheric circulations. Thus, the Greenland and Labrador currents brought them through the entrance gate of the IRD belt. Stronger westerlies transported them eastward (Keefer et al., 1988), as far east as the European margin (e.g. core MD95-2002). Based on AMS-14C datings from within HL2 in core SU90-09 (Grousset et al., 2001), we could suggest that the Hudson Strait-derived icebergs crossed the Mid-Atlantic Ridge eastward, for only one to a few centuries, consistent with the compilation of Hemming (2004) as well as modelling results to simulate the δ18O anomaly generated by the melting of icebergs during HE4 (Roche et al., 2004). Unfortunately, due to great uncertainties in reservoir age corrections applied to these AMS-14C ages, it is clear that the dating uncertainties could be as great as 1000 years (Waelbroeck et al., 2001). In the eastern North Atlantic, Hudson Strait Heinrich events are embedded within IRD of European origin (Fig. 6). It is clear that the European icesheets (McCabe et al., 1998; Bowen et al., 2002) released their own icebergs during the entire duration of the HEs (1-to-2 thousand years). The Laurentide surge thus appears to have occurred briefly within this period of release of European icebergs, as already suggested for HL1 along the Irish margin (Knutz et al., 2002). The absence of precursors prior to HL4 and HL5 is an important observation. It suggests that precursor events are not a necessary step required for triggering the main Laurentide surges. Rather, the precursory intervals near HL2 and HL1 are more likely simple periods of intensified releases of icebergs by all the panAtlantic ice-sheets. 5. Conclusions The accumulation of IRD forming the Heinrich Layers that are observed within the Ruddiman IRD belt is mostly due to anomalous contributions from the Hudson Strait portion of the Laurentide ice-sheet. During Heinrich events, broadly defined, European ice-sheets (Fennoscandia, British Isles) released icebergs too. Their contribution, however, is only clearly identifiable near their margins due to a combination of lesser flux, greater required transport distance to the IRD belt and prevailing E. Jullien et al. / Global and Planetary Change 54 (2006) 225–238 surface circulation. Icelandic-derived icebergs deposited a distinctive IRD assemblage and thus can give an indication of the extent of movement of icebergs within the surface currents of the North Atlantic. Icelandic icebergs seem to have been transported over a much broader area and are thus visible within the entire IRD belt; however, their spatial and temporal pattern of deposition is complex, because they could have been incorporated in the anticlockwise surface currents. It is also clear that the HLs are not similar to each other in detail. It was understood very early that HE3 and HE6 were different and less dramatic (e.g., Bond et al., 1992, 1993; Grousset et al., 1993). But the large Heinrich events also have some key distinctions that may be crucial for constraining their origin. For example, HE2 and HE1 are more similar to each other and occur against different background conditions compared to HE5 and HE4. However, HE1 is different in detail from HE2 due to its occurrence at the termination of the LGM. Precursory iceberg discharges precede the occurrence of the major Hudson Strait sediment pulse of HE2 and HE1. In contrast, there is no precursory increase in IRD before H4 and H5. This distinction is important and allows us to claim that precursors, as originally conceived, must not have been a necessary initial step for triggering the major Laurentide surges. The fact that precursor events occur only prior to HE1 and HE2 could be attributed to the fact that, during that period (≈13.5 to ≈28 kyr B.P.), the sea level was much lower (between −80 and −130 m) and the ice-sheets were accordingly much more extended, with many terminations at the shelf–slope boundary. Acknowledgements The cores studied here were collected by the IFRE MER R/V Le Suroit and IMAGES cores were recovered by the N/V Marion-Dufresne (French Polar Institute). J. Saint-Paul, O. Weber and P. Brunet provided invaluable technical assistance. Laurent Labeyrie kindly provided AMS-14C ages and δ18O records. We have benefited from the fruitful reviews of Paul Knutz and Jens Bischof. 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