Implementation and Verification of BMPs for Reducing P Loading from the Everglades Agricultural Area: Floating Aquatic Vegetation Impact on Farm Phosphorus Load 2012 Annual Report Submitted to the Everglades Agricultural Area Environmental Protection District And The South Florida Water Management District By Samira H. Daroub, Timothy A. Lang, Manohardeep S. Josan, and Jehangir H. Bhadha University of Florida, Institute of Food and Agricultural Sciences Everglades Research and Education Center, Belle Glade, FL 33430 July 2012 2 Acknowledgments This project is primarily funded by the Everglades Agricultural Area (EAA) Environmental Protection District, a special district representing landowners within the EAA Basin, that was created for the purpose of ensuring environmental protection by means of conducting scientific research on environmental matters related to air and water and land management practices and implementing the financing, construction, and operation of works and facilities designed to prevent, control, abate or correct environmental problems and improve the environmental quality in the EAA. The collaboration and cooperation of the growers in the Everglades Agricultural Area is duly appreciated. The expert advice from members of the Water Resources and BMP Advisory Committee has been of great value. Researchers, extension personnel, and SFWMD staff who assisted with BMP trainings were major contributors to the success of those trainings and to the continuing excellent results of the EAA basin’s BMP program. This project is also supported by the Florida Agricultural Experiment Station. 3 4 Project Personnel Name Title Samira Daroub, PhD Principal Investigator Timothy Lang, PhD Project Manager Manohardeep Josan, PhD QA/QC Officer and Lead Scientist Jehangir Bhadha, PhD Lead Scientist Vivianna Nadal, MS Head Chemist Irina Ogelvich, BS Chemist Suzanna Gomez, BS Grad Student/Laboratory Technician Michael Korbly, AA Field and Laboratory Technician Abbreviations BMP DDb WDb DOP EAA ENP EPA EPD EREC FAV FLREC IFAS LOI OM PP SAV SFWMD SOP SRP STA TDP TP TSS UF WCA Best Management Practice Dry Bulk Density Wet Bulk Density Dissolved Organic Phosphorus Everglades Agricultural Area Everglades National Park Environmental Protection Agency Environmental Protection District Everglades Research and Education Center Floating Aquatic Vegetation Fort Lauderdale Research and Education Center Institute of Food and Agricultural Sciences Loss on Ignition Organic Matter Particulate Phosphorus Submerged Aquatic Vegetation South Florida Water Management District Standard Operating Procedure Soluble Reactive Phosphorus Stormwater Treatment Area Total Dissolved Phosphorus Total Phosphorus Total Suspended Solids University of Florida Water Conservation Area 5 6 Table of Contents Acknowledgments ............................................................................................................................. 3 Project Personnel ............................................................................................................................... 5 Abbreviations .................................................................................................................................... 5 Summary ......................................................................................................................................... 13 Introduction ..................................................................................................................................... 15 Farm Descriptions ........................................................................................................................... 20 Farm Canal Sediment Surveys ........................................................................................................ 24 Materials and Methods ................................................................................................................ 24 Results ......................................................................................................................................... 25 Physical and Chemical Characterization of Canal Sediments ........................................................ 35 Sediment Analyses ...................................................................................................................... 35 Results ......................................................................................................................................... 35 Floating Aquatic Vegetation: Speciation, Coverage and TP Content ............................................. 38 FAV Sampling Procedure and Analyses ..................................................................................... 38 Results ......................................................................................................................................... 39 Assessment of FAV in Farm Canal Pairs ........................................................................................ 45 Water Quality Monitoring ............................................................................................................... 50 Water Sampling Procedures ........................................................................................................ 50 Laboratory Analyses .................................................................................................................... 50 Ambient Farm Canal Water Monitoring Results ......................................................................... 55 Farm Canal In Situ Monitoring ....................................................................................................... 62 Farm Canal In Situ Monitoring Results ....................................................................................... 62 Farm Drainage Water .................................................................................................................. 64 BMP Training Workshops .............................................................................................................. 71 References ....................................................................................................................................... 75 Appendix ......................................................................................................................................... 77 List of Appendix Tables .............................................................................................................. 77 List of Appendix Figures ............................................................................................................. 78 7 8 List of Tables Table 1. Summary of farm canal sediment depths in meters surveyed in November 2011. ........ 26 Table 2. Physical and chemical properties of sediments collected on November 2011 from the eight farms.................................................................................................................... 37 Table 3. FAV sample composition, water content, TP concentration, and mass of TP in farm canal FAV for May 2011. ............................................................................................ 39 Table 4. FAV sample composition, water content, TP concentration, and mass of TP in farm canal FAV for June 2011. ............................................................................................ 40 Table 5. FAV sample composition, water content, TP concentration, and mass of TP in farm canal FAV for August 2011. ........................................................................................ 41 Table 6. FAV sample composition, water content, TP concentration, and mass of TP in farm canal FAV for October 2011. ....................................................................................... 42 Table 7. FAV sample composition, water content, TP concentration, and mass of TP in farm canal FAV for January 2012. ....................................................................................... 43 Table 8. FAV sample composition, water content, TP concentration, and mass of TP in farm canal FAV for April 2012. ........................................................................................... 44 Table 9. Summary statistics of phosphorus species concentrations of ambient canal waters for farm pairs in S5A sub-basin from November 2010 through April 2012. .................... 56 Table 10. Summary statistics of phosphorus species concentrations of ambient canal waters for farm pairs in S6 sub-basin from November 2010 through April 2012. ....................... 58 Table 11. Summary statistics of ambient canal water pH, calcium, and total suspended solids for S5A and S6 sub-basin farm pairs from November 2010 to April 2012. ...................... 61 Table 12. Summary statistics of hourly in situ water quality measurements collected from October 2011 through April 2012. ............................................................................... 63 Table 13. Summary statistics of drainage water phosphorus concentrations of farm pairs in the S5A sub-basin from November 2010 through April 2012. .......................................... 65 Table 14. Summary statistics of drainage water phosphorus concentrations of farm pairs in the S6 sub-basin from November 2010 through April 2012.............................................. 66 Table 15. Summary statistics of drainage water pH, calcium, and total suspended solids in S5A and S6 basin farms from November 2010 to April 2012. ............................................ 67 Table 16. Spearman correlation coefficients of biweekly farm drainage data. ............................ 68 Table 17. Speakers, affiliations, and presentations for BMP training workshops held in WY 2012. ............................................................................................................................. 71 List of Photos Photo 1 Floating aquatic vegetation (duck weed) being collected from one of the farm canals. . 38 Photo 2. Datalogger, auto-sampler, refrigerator, and drainage water composite sample collection. ........................................................................................................................................... 52 Photo 3. Orthophosphate (top) and total phosphorus (bottom) analyses being conducted on SEAL® Auto Analyzer. .................................................................................................... 53 Photo 4. Calibration of Hydrolab MiniSonde® left, and Ca analyses using atomic absorption spectrophotometer, right. .................................................................................................. 54 Photo 5. Images of selected speakers from BMP training sessions held at the EREC in September 2011 and April 2012. ........................................................................................................ 74 9 10 List of Figures Figure 1. Map of the Everglades Agricultural Area and farm locations. ...................................... 19 Figure 2. Aerial map of farms 0401 and 2501 with pumphouse and canal transect locations. .... 20 Figure 3. Aerial map of farms 1813 and 6117 with pumphouse and canal transect locations. .... 21 Figure 4. Aerial map of farms 3102 and 3103 with pumphouse and canal transect locations. .... 22 Figure 5. Aerial map of farms 4701 and 4702 with pumphouse and canal transect locations. .... 23 Figure 6. Sediment profile of main canal of farm 0401 at three transects, A, B, and C, surveyed in November 2011. (Note: 1 m = 3.12 ft) ......................................................................... 27 Figure 7. Sediment profile of main canal of farm 2501 at three transects, A, B, and C, surveyed in November 2011. (Note: 1 m = 3.12 ft) ......................................................................... 28 Figure 8. Sediment profile of main canal of farm 1813 at three transects, A, B, and C, surveyed in November 2011. (Note: 1 m = 3.12 ft) ......................................................................... 29 Figure 9. Sediment profile of main canal of farm 6117 at three transects, A, B, and C, surveyed in November 2011. (Note: 1 m = 3.12 ft) ......................................................................... 30 Figure 10. Sediment profile of main canal of farm 3102 at three transects, A, B, and C, surveyed in November 2011. (Note: 1 m = 3.12 ft) ......................................................................... 31 Figure 11. Sediment profile of main canal of farm 3103 at three transects, A, B, and C, surveyed in November 2011. (Note: 1 m = 3.12 ft) ......................................................................... 32 Figure 12. Sediment profile of main canal of farm 4701 at three transects, A, B, and C, surveyed in November 2011. (Note: 1 m = 3.12 ft) ......................................................................... 33 Figure 13. Sediment profile of main canal of farm 4702 at three transects, A, B, and C, surveyed in November 2011. (Note: 1 m = 3.12 ft) ......................................................................... 34 Figure 14. Comparison of FAV in main canals of farms 3102 and 3103. (Left) Changes in mass of dried FAV and average TP concentration of FAV over time. (Right) Changes in percent FAV coverage and mass of P in FAV over time. ................................................. 46 Figure 15. Comparison of FAV in main canals of farms 4701 and 4702. (Left) Changes in mass of dried FAV and average TP concentration of FAV over time. (Right) Changes in percent FAV coverage and mass of P in FAV over time. ................................................. 47 Figure 16. Comparison of FAV in main canals of farms 0401 and 2501. (Left) Changes in mass of dried FAV and average TP concentration of FAV over time. (Right) Changes in percent FAV coverage and mass of P in FAV over time. ................................................. 48 Figure 17. Comparison of FAV in main canals of farms 6117 and 1813. (Left) Changes in mass of dried FAV and average TP concentration of FAV over time. (Right) Changes in percent FAV coverage and mass of P in FAV over time. ................................................. 49 Figure 18. Distribution of total P (TP) concentrations in canal water grab samples collected from November 2010 through April 2012. ................................................................................ 59 Figure 19. Ambient canal water average P speciation concentrations and percent total P by farm from November 2010 through April 2012. ....................................................................... 60 Figure 20. Drainage water average P speciation concentrations and percent of total P by farm from November 2010 through April 2012. ....................................................................... 70 11 12 Summary This document is the second annual report which presents the status of work completed up to April 31, 2012 for the project titled “Implementation and verification of BMPs to reduce Everglades Agricultural Area farm P loads: floating aquatic vegetation impact on farm P load”. This project report describes the eight project farms (four farm pairs) that are being monitored within the S5A and S6 sub-basin. Under the approved 2010 scope of work modification, the following activities have been conducted: (1) bathymetric surveys of farm main canals conducted in November 2011, (2) dry season sediment analyses of farm main canals collected in November 2011, (3) water quality analyses of ambient main canal and farm drainage water monitoring: total P (TP), total dissolved phosphorus (TDP), particulate phosphorus (PP), soluble reactive phosphorus (SRP), dissolved organic phosphorus (DOP), total suspended solids (TSS), total dissolved calcium (Ca), and pH, (4) bimonthly qualitative and quantitative assessment of floating aquatic vegetation biomass from each farm’s main canal, (5) monitoring of farm canal drainage flow rates, canal elevations, rainfall, and farm drainage volume during drainage events, and (6) monitoring of additional water quality parameters using in situ multi-parameter sondes: canal water temperature, oxidation reduction potential, and specific conductivity. In addition to these activities, regular maintenance and calibration of field and laboratory equipment, along with quality control and assurance are also conducted by our team. Preliminary investigations into simple regression relationships between paired farms for parameters associated with farm P load revealed that correlations were high for rainfall, drainage volume, and P load. The highest correlations were observed when data was compiled at the biweekly time scale. More complete regression models will be developed once the current wet season ends and the collected data are compiled. An important aspect of the EAA Master Permit SOW is the training of farm personnel in BMP implementation techniques. Two BMP training workshops were conducted last year: October 2011 and April 2012 for growers in the EAA with a total of over 200 participants. Feedback received via evaluations collected after trainings was positive and was used to modify and improve training topics, content, and speaker selections. 13 14 Introduction Located in the geographic center of the South Florida watershed, the Everglades Agricultural Area (EAA) basin comprises approximately 250,000 ha of farms and several small communities south and east of Lake Okeechobee. The EAA has highly productive agricultural land comprised of rich organic muck soils. Sugarcane, vegetables, sod, and rice are grown in the EAA and annually provide south Florida with jobs and over one billion dollars to Florida’s economy (Florida Department of Agriculture and Consumer Services, 2004). The EAA plays an important role in the Everglades water supply, either directly through agricultural drainage runoff or indirectly by serving as a conduit for large water transfers from Lake Okeechobee to the Water Conservation Areas (WCAs). The primary mode of drainage in the EAA is by shallow subsurface flow, which may be by capillary action through the organic soils, or through fractures in the marl-soil interface. On-farm water management is achieved by using this subsurface flow and the water level in open field ditches to raise or lower field water tables. Rainfall is highly seasonal and frequently intense. Drainage discharge is achieved by pumping with high volume, low head, axial-flow pumps. Drainage water from the EAA, after treatment in Stormwater Treatment Areas, is ultimately discharged to the downstream WCAs, Everglades National Park (ENP), or the South Florida coastal estuaries. The EAA basin as a whole is required by the Everglades Forever Act (1994; 2003) to achieve phosphorus (P) load reductions of 25% or greater relative to a baseline P load average (derived from 1979 to 1988 monitoring data) that is adjusted for rainfall distribution and amount. Since January 1, 1995, BMP implementation has been mandatory for all farms that discharge drainage water into South Florida Water Management District (SFWMD) conveyance canals. The SFWMD monitors EAA basin P load via a network of monitoring stations, i.e. pump stations and control structures that border the EAA. During the sixteen years since BMP program initiation, the EAA basin’s annual P load reduction has averaged nearly 50%; the highest being recorded in 2011 at 79% TP load reduction compared to the baseline period (SFER, 2012). Some of the BMPs that are currently implemented are divided into three categories: nutrient control, water management, and sediment control. Within each of these three categories there are numerous individual practices that farmers can implement to either minimized movement of P off-site, minimize the volume of drainage water discharge, or minimize the movement of particulate matter and canal sediments. 15 Further reductions in farm P loads can be achieved by targeting P containing sediments and particulates that are generated in farm canals and transported off-farm during drainage events. Particulate P comprises 40-60% of the P loads discharged from EAA farms (Stuck, 1996, Daroub et al., 2005). A major portion of the particulate P in EAA farm canals originates from in-stream biological growth rather than from soil erosion (Stuck, 1996, Daroub et al., 2005). Particulate P that contributes significantly to farm P export has been determined to be, for the most part, recently deposited biological material such as settled plankton, filamentous algae, and macrophyte detritus. There are several sediment control practices in the SFWMD-EAA BMP table from which EAA farmers are able to choose and employ on their farms (SFER, 2012). One of the sediment control practices is the control of aquatic vegetation in farm canals. In addition, most growers control to varying degrees the growth of floating aquatic vegetation (FAV) in their canals. However there is inadequate scientific knowledge regarding this practice’s efficacy and its proper implementation methods. Limiting the growth of FAV in farm canals is a practice that has the known benefit of improving the conveyance of drainage and irrigation waters throughout the farm. Control of FAV biomass growth may lead to further reductions in farm P load by changing the physical and chemical properties (and transportability) of sediments generated in a farm canal (Murphy et al., 1983; Reddy et al., 1987; Danen-Louwerse et al., 1995). It is hypothesized that with better light penetration into the canal water column more P will be co-precipitated with Ca and Mg carbonates and form cohesive, denser sediments that are less likely to be re-suspended and transported off the farm during drainage events. In addition, lower P loads from EAA farms should help the performance of Stormwater Treatment Areas (STAs), more so for those STAs performing at less than expected outflow concentrations. This project titled “Implementation and verification of BMPs to reduce Everglades Agricultural Area farm P loads: Floating aquatic vegetation impact on farm P load”, which started in Fall 2010 will quantify changes in sediment composition and drainage water P speciation in EAA sugarcane farms associated with FAV management. It will determine changes in the composition of the P species in canal waters and overall total P loads as influenced by FAV. This report is the second annual report document since the inception of this project, and focuses on the activities conducted by the IFAS/UF during the time period from May 1st 2011 to April 30th, 2012. 16 The specific objectives of the project are: 1. Evaluate FAV management practices in the Everglades Agricultural Area farm canals for impact on farm drainage water phosphorus load. 2. Evaluate the effect of FAV management practices on P speciation of farm drainage water and on farm canal sediment physical and chemical properties. 3. Use the information from the research for the development of a BMP for managing FAV to further lower farm P loads. The goal is to provide growers an additional tool in their efforts to reduce off-farm P loading in the Everglades Agricultural Area. Several research projects involving EAA farms have identified FAV as a source of readily transportable sediments and particulate P. No studies have been conducted to isolate and measure the effects of limiting FAV growth in farm canals on sediment properties and farm P load. In addition, several studies in the Everglades have found that sediments accumulated in newly constructed wetlands are organic with low bulk density, but that calcium phosphates may play a significant role in P storage. Studies have shown that precipitation of P with Ca may occur in hard waters when FAV is eliminated and SAV and other algal species are present in the water column (Reddy et al., 1987; Danen-Louwerse et al., 1995). This research project attempts to quantify the effects of two different canal FAV management practices on farm P load, drainage water P speciation, and canal sediment physical and chemical properties. The scope of work for this project was approved by the SFWMD in January 2010. Farms included in the project were selected by project personnel and the Water Resources and BMP advisory committee, an advisory committee comprised of representatives of EAA growers. Selection of three farm pairs was approved by the SFWMD in August 2010, while the final farm pair was approved by SFWMD in September 2010. Statistical analysis of the study data will be conducted using SAS (SAS, 2008). The main study is a paired watershed design with repeated measures over time (USEPA, 1993). Incorporation of multiple covariates into ANCOVA models has been suggested for paired watershed data analysis (Hewlett and Peinaar, 1973; Loftis et al., 2001; Bishop et al., 2005). Drainage flow, canal level, canal head difference, velocity, rainfall and other data collected will be included in the regression analysis as covariates if significant. Covariates will be used to explain the significance of the treatment regression equation, the significance of the overall regression (calibration and treatment period), the difference in the slopes of the calibration and 17 the treatment regressions, and the difference between the intercepts of the calibration and treatment regressions (if the slopes are the same). At a minimum a bivariate plot of paired observations together with the calibration and treatment regression equation, and a plot of deviations as a function of time during the treatment will be presented. An estimate of the percentage change based on the mean TP predicted and TP observed values will be estimated as an approximate of performance. There are two treatments: nearly complete FAV management and typical FAV management in farm canals. The analyses will use regression to compare P load parameter responses to treatment between paired farms. The data may also be pooled and analyzed by sub-basin. 18 1813 4702 4701 6117 2501 0401 3103 3102 Map courtesy of SFMWD. Figure 1. Map of the Everglades Agricultural Area and farm locations. 19 Figure 2. Aerial map of farms 0401 and 2501 with pumphouse and canal transect locations. Farm Descriptions Farm Pair 1 comprises two sugarcane farms located in the S5A sub basin: Farm 0401 and farm 2501 (Figure 2). The farms are adjacent to one another and are located on the southwest side of the West Palm Beach canal approximately 12 miles from the Lake Okeechobee outflow structure S-352. Both farms receive irrigation water from and discharge their drainage waters directly into the West Palm Beach canal. Farm 0401 is a 908 acre sugarcane farm with a single exit discharge pump station that contains one electric and one diesel pump. The majority of the drainage pumping is achieved via the electric pump. The diesel pump is utilized only after extreme rainfall events and in case of electrical failure. In the spring of 2011 Farm 0401 grew sweet corn in approximately 40% of the cropping area; in the spring of 2012 Farm 0401 grew sweet corn on approximately 16% of the farm. After harvest of spring sweet corn acreage remained fallow (Appendix Table A1). 20 Farm 2501 is an 824 acre sugarcane farm that lies adjacent north and west to Farm basin 0401. It has a single discharge station containing two diesel pumps. In the spring of 2011 Farm 2501 grew sweet corn in approximately 16% of the cropping area; in the spring of 2012 Farm 2501 grew sweet corn on approximately 4% of the farm. After harvest sweet corn acreage remained fallow during the summer (Appendix Table A1). Figure 3. Aerial map of farms 1813 and 6117 with pumphouse and canal transect locations. Farm Pair 2 consists of two sugarcane farms in the S5A sub-basin: farm 1813 and farm 6117 (Figure 3). The farms are adjacent to one another and located on the northeast side of the West Palm Beach canal approximately 12 miles from Lake Okeechobee outflow structure S-352. Farm 1813 receives irrigation water from and discharges drainage water directly into the West Palm Beach canal; farm 6117 receives irrigation water from and drains excess water into a north south tertiary canal that is connected to the West Palm Beach Canal approximately one mile south of farm 6117 discharge structure. 21 Farm 1813 is a sugarcane farm of 594 acres with a single exit pump station containing a single diesel powered pump. Sweet corn was grown on approximately 16% of the farm’s cropped area in the spring of 2011. After harvest the sweet corn acreage was kept fallow until sugarcane was planted in November 2011(Appendix Table A2). Farm 6117 is a sugarcane farm of 800 acres; it is drained by a single diesel pump, which discharges into a secondary canal that connects to the West Palm Beach canal. The distance from the pump station to the West Palm Beach canal is approximately one mile. Sugarcane occupied all the cropped fields in this farm from November 2010 through March 2012; snap beans were planted in 10% of the acreage in spring of 2012(Appendix Table A2). Figure 4. Aerial map of farms 3102 and 3103 with pumphouse and canal transect locations. Farm Pair 3 is located in the S6 sub-basin just north of the intersection of Airport Road and Sam Center Road. The pair consists of two sugarcane farms: Farm 3102 and farm 3103 (Figure 4). Both farms receive irrigation water from and discharge into a tertiary district canal that eventually connects with the Hillsboro Canal via the Ocean Canal. 22 Farm 3102 is a 1387 acre sugarcane farm that is bordered to the south by the Airport road extension and to the north by SR80. This farm has a single exit pump station containing three diesel pumps for drainage. Sweet corn was planted on approximately 53% of the acreage during the spring season 2011; beans and leaf vegetables were planted in 10 to 20% during spring 2012 (Appendix Table A3). Farm basin 3103 is a 602 acre sugarcane farm that is located west across the canal from farm basin 3102 and has Hatton Highway as a western boundary and Airport Road as its southern boundary. It has a single exit pump station containing one diesel powered pump. Leaf vegetables were planted on 25% of the cropped acreage from January through May 2011. Vegetable acreage was fallow for the month of May 2011 and was flooded starting in June of 2011. In fall of 2011 beans and corn were planted on approximately 25% of the farm. In Spring 2012 sweet corn was planted on approximately 25% of the farm (Appendix Table A3). Figure 5. Aerial map of farms 4701 and 4702 with pumphouse and canal transect locations. 23 Farm Pair 4 is located in the S6 sub-basin near its northern boundary and consists of two sugarcane farms: farm 4701 and farm 4702 (Figure 5). Both farms receive irrigation water from and discharge into an east-west tertiary district canal that eventually connects with the Hillsboro Canal via the Ocean Canal. Farm 4701 is a 640 sugarcane farm with a single discharge pump station with a single diesel powered pump that discharges drainage water into a tertiary canal that feeds into the secondary district canal that runs north from Sam Center road, and eventually discharges into the Ocean canal at Sam Center Road and SR880. Sugarcane occupied all the cropped fields on this farm from November 2010 through April 2012 (Appendix Table A4). Farm 4702 is a 640 acre sugarcane farm which is located one-half mile east of farm basin 4701. Farm 4701 has a single pump station with a single diesel pump for drainage discharge. Sugarcane occupied all the cropped fields on this farm from November 2010 through March 2012. In April 2012 rice was planted on 50% of the farm (Appendix Table A4). Farm Canal Sediment Surveys Farm canal surveys are conducted to assess individual farm canal dimensions (length, width, area), the thickness of sediments present in the canals, and their physical and chemical characteristics. Surveys are conducted twice a year to monitor changes in sediment thickness or composition. This report summarizes results from the survey conducted in November 2011. In the past survey was conducted in February 2011, which has been reported in last year’s Annual Report. The next canal survey will be conducted in August 2012. Materials and Methods Water depth to sediment surface was measured by a neutral buoyancy water column measuring pad. Sediment thickness at each 2 ft lateral increments within each transect of individual canals was measured by subtracting the water column measuring pad value from its corresponding calibrated penetrometer value. Three separate transect locations were selected within a single canal, and sediment thickness was measured along a transect across the canal width. Transect A was closest to the pump station, transect B was in the middle of the canal, while transect C was confined at the back end of the canal. These three locations were adjacent to where grab water samples are collected. At each transect location two iron rebars were 24 installed at the edge of the water on each side of the canal. During surveying, a steel cable is attached to the rebar to anchor a boat used during measurements. Along a transect measurements were recorded at 2 ft (0.61 m) intervals. A measuring pad was used to record the depth of the water column; a graduated penetrometer was used to record the depth of the water column + sediment. The average thickness of sediment along each transect from all three locations was reported as the thickness of the individual farm canal. Results The overall average thickness of canal sediments for all eight farms and along all three transects was 0.61 m (2.0 ft; summarized in Table 1). As expected the thickest section of sediment accumulation was confined to the center of the canals. In general, no differences in sediment thickness were observed between the three transects A, B, C (or from closest to the pump station to furthest away from the pump station). Farm 1813 had the highest mean sediment thickness of 0.75 m (2.3 ft) while 2501 had the least mean sediment thickness 0.51 m (1.7 ft) (Table 1). In transect A the highest sediment thickness was observed in farm 6117 at 1.95 m (6.4 ft), while in transect B the highest sediment thickness was observed in farm 1813 at 1.55 m (5.1 ft), and in transect C the highest thickness was also observed in farm 6117 at 2.57 m (8.4 ft). Schematics of sediment profiles for all transects are shown in Figures 6 to 13. The underlying canal sediment can potentially adsorb or release P depending on canal water P concentration and water-sediment interface conditions. 25 Table 1. Summary of farm canal sediment depths in meters surveyed in November 2011. Farm ID Mean Std Dev N Minimum Overall 36 0.08 36 0.05 51 0.03 52 0.05 37 0.00 37 0.00 38 0.05 36 0.13 Transect A 16 0.08 13 0.05 18 0.10 18 0.10 14 0.00 14 0.02 19 0.05 13 0.18 Transect B 9 0.13 12 0.20 17 0.03 15 0.05 11 0.15 12 0.00 10 0.10 14 0.13 Transect C 11 0.13 11 0.08 16 0.18 19 0.05 12 0.08 11 0.23 9 0.08 9 0.15 Maximum Median 1.83 1.30 1.55 2.57 1.42 1.19 1.53 1.12 0.50 0.36 0.68 0.34 0.41 0.61 0.85 0.42 1.83 1.30 1.48 1.95 0.79 0.74 1.53 0.92 0.31 0.63 0.67 0.89 0.25 0.43 0.90 0.33 0.76 0.43 1.55 0.53 0.92 1.19 1.32 1.12 0.28 0.28 0.94 0.26 0.61 0.61 0.51 0.36 0.86 0.87 1.17 2.57 1.42 0.91 1.22 1.09 0.64 0.54 0.61 0.41 1.04 0.81 0.56 0.53 1 1 0401 2501 1813 6117 3102 3103 4701 4702 0.57 0.51 0.75 0.74 0.54 0.55 0.71 0.50 0.49 0.38 0.47 0.75 0.43 0.34 0.42 0.32 0401 2501 1813 6117 3102 3103 4701 4702 0.66 0.73 0.69 0.95 0.34 0.42 0.86 0.49 0.68 0.48 0.46 0.75 0.28 0.27 0.38 0.31 0401 2501 1813 6117 3102 3103 4701 4702 0.40 0.29 0.86 0.30 0.54 0.66 0.59 0.44 0.25 0.07 0.58 0.15 0.34 0.41 0.48 0.32 0401 2501 1813 6117 3102 3103 4701 4702 0.58 0.48 0.68 0.89 0.76 0.61 0.54 0.60 0.24 0.31 0.35 0.90 0.56 0.30 0.38 0.34 Overall= average of three transects (A,B,C) 26 3.5 channel bottom sediment surface thickness (m) 3.0 2.5 2.0 1.5 1.0 0.5 0401-A 0.0 0 1 2 3.5 4 5 6 canal width (m) channel bottom 3.0 thickness (m) 3 7 8 9 10 8 9 10 sediment surface 2.5 2.0 1.5 1.0 0.5 0401-B 0.0 0 1 2 3.5 3 4 5 6 canal width (m) channel bottom 7 sediment surface thickness (m) 3.0 2.5 2.0 1.5 1.0 0.5 0401-C 0.0 0 1 2 3 4 5 6 canal width (m) 7 8 9 Figure 6. Sediment profile of main canal of farm 0401 at three transects, A, B, and C, surveyed in November 2011. (Note: 1 m = 3.12 ft) 27 10 2.5 channel bottom sediment surface thickness (m) 2.0 1.5 1.0 0.5 2501-A 0.0 0 1 2.5 2 3 4 canal width (m) 6 7 8 4 5 6 canal width (m) channel bottom sediment surface 7 8 7 8 channel bottom 5 sediment surface thickness (m) 2.0 1.5 1.0 0.5 2501-B 0.0 0 1 2 2.5 3 thickness (m) 2.0 1.5 1.0 0.5 2501-C 0.0 0 1 2 3 4 canal width (m) 5 6 Figure 7. Sediment profile of main canal of farm 2501 at three transects, A, B, and C, surveyed in November 2011. (Note: 1 m = 3.12 ft) 28 3.0 channel bottom sediment surface thickness (m) 2.5 2.0 1.5 1.0 0.5 1813-A 0.0 0 2 3.0 4 6 canal width (m) channel bottom 8 10 12 sediment surface thickness (m) 2.5 2.0 1.5 1.0 0.5 1813-B 0.0 0 2 3.0 4 6 canal width (m) channel bottom 8 10 12 10 12 sediment surface thickness (m) 2.5 2.0 1.5 1.0 0.5 1813-C 0.0 0 2 4 6 canal width (m) 8 Figure 8. Sediment profile of main canal of farm 1813 at three transects, A, B, and C, surveyed in November 2011. (Note: 1 m = 3.12 ft) 29 3.5 channel bottom thickness (m) 3.0 sediment surface 2.5 2.0 1.5 1.0 0.5 6117-A 0.0 0 1 2 3 3.5 4 5 6 canal width (m) channel bottom 7 8 9 10 11 9 10 11 sediment surface thickness (m) 3.0 2.5 2.0 1.5 1.0 0.5 6117-B 0.0 0 1 2 3.5 4 5 6 canal width (m) channel bottom 3.0 thickness (m) 3 7 8 sediment surface 2.5 2.0 1.5 1.0 0.5 6117-C 0.0 0 1 2 3 4 5 6 canal width (m) 7 8 9 10 Figure 9. Sediment profile of main canal of farm 6117 at three transects, A, B, and C, surveyed in November 2011. (Note: 1 m = 3.12 ft) 30 11 2.5 channel bottom sediment surface thickness (m) 2.0 1.5 1.0 0.5 3102-A 0.0 0 1 2 2.5 3 4 5 canal width (m) channel bottom 6 7 8 9 7 8 9 7 8 9 sediment surface thickness (m) 2.0 1.5 1.0 0.5 3102-B 0.0 0 1 2 2.5 3 4 5 canal width (m) channel bottom 6 sediment surface thickness (m) 2.0 1.5 1.0 0.5 3102-C 0.0 0 1 2 3 4 5 canal width (m) 6 Figure 10. Sediment profile of main canal of farm 3102 at three transects, A, B, and C, surveyed in November 2011. (Note: 1 m = 3.12 ft) 31 2.5 channel bottom sediment surface thickness (m) 2.0 1.5 1.0 0.5 3103-A 0.0 0 1 2 2.5 3 4 5 canal width (m) channel bottom 6 7 8 9 7 8 9 sediment surface thickness (m) 2.0 1.5 1.0 0.5 3103-B 0.0 0 1 2 2.5 3 5 4 canal width (m) channel bottom 6 sediment surface thickness (m) 2.0 1.5 1.0 0.5 3103-C 0.0 0 1 2 3 4 5 canal width (m) 6 7 8 Figure 11. Sediment profile of main canal of farm 3103 at three transects, A, B, and C, surveyed in November 2011. (Note: 1 m = 3.12 ft) 32 9 2.5 channel bottom sediment surface thickness (m) 2.0 1.5 1.0 0.5 4701-A 0.0 0 2 4 6 8 10 12 10 12 10 12 canal width (m) 2.5 channel bottom sediment surface thickness (m) 2.0 1.5 1.0 0.5 4701-B 0.0 0 2 2.5 4 6 canal width (m) channel bottom 8 sediment surface thickness (m) 2.0 1.5 1.0 0.5 4701-C 0.0 0 2 4 6 8 canal width (m) Figure 12. Sediment profile of main canal of farm 4701 at three transects, A, B, and C, surveyed in November 2011. (Note: 1 m = 3.12 ft) 33 2.5 channel bottom sediment surface thickness (m) 2.0 1.5 1.0 0.5 4702-A 0.0 0 1 2 2.5 3 4 5 canal width (m) channel bottom 6 7 8 9 sediment surface thickness (m) 2.0 1.5 1.0 0.5 4702-B 0.0 0 1 2 2.5 3 4 5 canal width (m) 6 7 8 9 7 8 9 sediment surface channel bottom thickness (m) 2.0 1.5 1.0 0.5 4702-C 0.0 0 1 2 3 4 5 canal width (m) 6 Figure 13. Sediment profile of main canal of farm 4702 at three transects, A, B, and C, surveyed in November 2011. (Note: 1 m = 3.12 ft) 34 Physical and Chemical Characterization of Canal Sediments Sediment characterization of the eight farms was conducted in November 2011. Intact sediment cores (approximately 25 cm depth) were collected from the three transects along main farm canal of each farm. The sediments were collected on November 2-3, 2011 using a piston type, in-house constructed, sediment sampling device. The sediment sampler used polycarbonate tubes of 7.0 cm diameter and 50 cm length. Sample cores were transported to the laboratory on the same day of collection, sectioned into 0-2.5cm and 2.5-5.0 cm core lengths respectively, and stored at 4⁰C. Sediment sampling locations were recorded using a hand held GPS device. Sample preparation and analyses were conducted at the Soil Quality laboratory located at the Everglades Research and Education Center located Belle Glade, FL. Properties analyzed were sediment, organic matter (OM), total P (TP), wet bulk density (WDb) and dry bulk density (DDb). Sediment Analyses Sediment core sections were mixed thoroughly before taking any sub-samples for chemical analyses. All of the material present in the sediment cores was included in the analyses. For TP analyses, known weights of wet sample were ashed at 550oC for four hours in a muffle furnace and were grounded in a pestle and mortar before analyses (Andersen, 1974). Results are reported on an oven dry-weight basis. Both wet and dry bulk densities were performed on the sediments without any sieving or pre-treatments using EREC-SOP Bulk Density (adapted from Soil Survey Laboratory Methods Manual, 2004). Organic matter and ash content was determined using EREC-SOP Organic Matter (adapted from Soil Survey Laboratory Methods Manual, 2004). Total P was determined using EPA method 365.1 (EPA, 1993). Results A summary of the results are reported in Table 2. Overall the mean OM and TP content of the sediments from all eight farms were 42.9 ±11 % and 1075 ±395 mg/kg respectively. Both, OM and TP concentrations were similar to those observed during the February 2011 sampling event. While comparing the two depth horizons (0-2.5 and 2.5-5.0 cm) we found that the mean OM was similar in the 0-2.5 cm and the 2.5-5 cm layer at 43.2 ±10 % and 42.6 ±12% respectively; while TP was slightly higher in the 0-2.5 cm horizon at 1149 ±482 mg/kg, compared to 995 ±272 mg/kg observed at 2.5-5.0 cm depth. Over the entire 5 cm sediment 35 profile (regardless of depth horizons), Farm 3103 had a mean OM and TP concentration of 37.2 % and 1380 mg/kg respectively; Farm 3102 had 40.9 % and 979 mg/kg; Farm 2501 had 36.9 % and 925 mg/kg; Farm 0401 had 41.8 % and 956 mg/kg; Farm 4702 had 57.0 % and 928 mg/kg; Farm 4701 had 34.5 % and 939 mg/kg; Farm 6117 had 46.5 % and 1188 mg/kg; Farm 1813 had 48.5 % and 1280 mg/kg. 36 Table 2. Physical and chemical properties of sediments collected on November 2011 from the eight farms. Farm ID1 Transect 0401 0401 0401 0401 0401 0401 2501 2501 2501 2501 2501 2501 1813 1813 1813 1813 1813 1813 6117 6117 6117 6117 6117 6117 3102 3102 3102 3102 3102 3102 3103 3103 3103 3103 3103 3103 4701 4701 4701 4701 4701 4701 4702 4702 4702 4702 4702 4702 A A B B C C A A B B C C A A B B C C A A B B C C A A B B C C A A B B C C A A B B C C A A B B C C 1 Depth (cm) 0-2.5 2.5-5 0-2.5 2.5-5 0-2.5 2.5-5 0-2.5 2.5-5 0-2.5 2.5-5 0-2.5 2.5-5 0-2.5 2.5-5 0-2.5 2.5-5 0-2.5 2.5-5 0-2.5 2.5-5 0-2.5 2.5-5 0-2.5 2.5-5 0-2.5 2.5-5 0-2.5 2.5-5 0-2.5 2.5-5 0-2.5 2.5-5 0-2.5 2.5-5 0-2.5 2.5-5 0-2.5 2.5-5 0-2.5 2.5-5 0-2.5 2.5-5 0-2.5 2.5-5 0-2.5 2.5-5 0-2.5 2.5-5 OM (%) 18.2 19.9 60.2 74.0 41.8 36.6 33.9 33.3 42.2 40.6 35.3 36.3 47.4 47.4 49.4 51.3 49.1 46.6 43.8 39.4 51.1 32.7 55.8 56.0 43.1 51.1 36.5 34.2 39.7 40.5 40.7 32.6 42.9 33.2 38.5 35.5 27.3 39.1 35.5 29.6 36.1 39.8 47.3 49.7 62.0 62.5 60.3 59.9 WDb (g/cm3) 1.26 1.20 1.15 1.08 1.03 1.05 1.07 1.11 0.97 1.08 0.99 1.05 0.92 1.05 0.96 1.03 1.06 1.04 1.03 1.12 0.99 1.09 1.06 1.04 1.19 1.21 1.13 1.23 1.05 1.10 1.00 1.17 1.12 1.09 1.05 1.05 1.22 1.16 0.92 1.19 1.02 1.11 0.96 1.03 0.94 0.98 1.03 0.95 DDb (g/cm3) 0.91 0.88 0.79 0.72 0.65 0.65 0.69 0.76 0.62 0.67 0.62 0.69 0.60 0.71 0.67 0.70 0.73 0.73 0.69 0.83 0.69 0.78 0.74 0.70 0.83 0.85 0.75 0.87 0.69 0.74 0.67 0.74 0.63 0.61 0.59 0.56 0.87 0.78 0.65 0.89 0.70 0.80 0.62 0.65 0.59 0.61 0.61 0.60 TP (mg/kg) 1097 880 897 772 1029 1061 951 960 1071 964 866 734 1577 1022 1335 1246 1270 1231 2130 1069 754 1897 650 630 643 700 1201 850 1370 1112 1148 904 1280 942 2827 1177 691 627 924 974 1029 1386 955 802 951 1019 924 915 OM = organic matter; WDb = wet bulk density; DDb = dry bulk density; TP = total phosphorus 37 Floating Aquatic Vegetation: Speciation, Coverage and TP Content An overall assessment of FAV was conducted approximately every two months with the intention of identifying the species composition, coverage within the main canals, and the TP content of the plant biomass. In this report we include the data collected from May 2011 to April 2012 (total six sampling events). Two representative samples were collected from each farm. Sampling locations were selected at each farm based on spatial coverage of FAV. FAV Sampling Procedure and Analyses A one-meter-square floating PVC retainer is placed on the FAV biomass to be sampled. All FAV within the square is harvested and placed in mesh bags to drain. Total fresh weight is recorded after draining. The entire sample mass is air dried to constant weight with forced air at 50° C. The weight of the dry sample mass is recorded, and the mass is ground to less than 1 mm in a cyclone mill. The ground material is blended well and stored in an airtight container until analysis. Samples were analyzed for water content and TP. Percent moisture content was calculated based on difference between wet mass of FAV versus oven dry mass, while the dry grounded biomass was analyzed for TP using method 200.7 (USEPA, 2003) on an Inductively Coupled Plasma Mass Spectroscope (IFAS, Analytical Research Lab, Gainesville, FL). The total P in individual farm FAV biomass was calculated as the product of the dry FAV biomass P concentration (mg/kg) times the mass of FAV (kg) present in the canals based on the percent coverage. Photo 1 Floating aquatic vegetation (duck weed) being collected from one of the farm canals. 38 Results Following is a summary of the FAV characterization and TP content of FAV biomass from six sampling trips (May 2011 and April 2012): May 2011 Farm 0401: Overall 70% cover, mostly water lettuce and a bit of filamentous algae and duckweed. Farm 2501: Overall 50% cover mostly filamentous algae and water lettuce. Farm 1813: Overall very clear canal. No appreciable FAV. Farm 6117: Overall 30% mostly duck-weed and little water lettuce. Farm 3102: Overall about 40% of the canal was covered with FAV, dominated by water-lettuce mostly confined to the pump area and in the E-W section of the canal. N-S canal was clean. Farm 3103: Overall 10% of the canal showed presence of FAV, mostly confined to the canal edges, including filamentous algae, torpedo grass, and water lettuce. Farm 4701: Overall 30% cover of filamentous algae and torpedo grass. Farm 4702: Overall 5% confined mostly along the canal edges comprising of water lettuce. Table 3. FAV sample composition, water content, TP concentration, and mass of TP in farm canal FAV for May 2011. Farm Water [TP] of P in Farm Sample description ID content dry FAV FAV Mass (%) (mg/kg) (kg) 0401 2501 6117 3102 3103 4701 4702 92 89 66 92 87 90 77 2880 2168 1923 2519 1782 1311 1405 9.3 5.8 2.4 17.9 0.7 1.3 0.6 water lettuce and filamentous algae filamentous algae duck-weed and water lettuce water lettuce water lettuce, F. algae and torpedo grass filamentous algae and torpedo grass water lettuce 39 June 2011 Farm 0401: Overall 40% cover mostly water lettuce and a bit of filamentous algae and duckweed. Farm 2501: Overall 5% cover mostly filamentous algae and water lettuce. Farm 6117: Overall 40% mostly duck-weed and little water lettuce. Farm 1813: Overall very clear canal. No appreciable FAV present. Farm 3102: Overall about 40% of the canal was covered with FAV, dominated by water-lettuce mostly confined to the pump area and in the E-W section of the canal. N-S canal was clean. Farm 3103: Overall 10% of the canal showed presence of FAV, mostly confined to the canal edges, including filamentous algae, and torpedo grass. Farm 4701: Overall 1% cover of filamentous algae and torpedo grass. Farm 4702: Overall 5% confined mostly along the canal edges comprising of water lettuce and torpedo grass. Table 4. FAV sample composition, water content, TP concentration, and mass of TP in farm canal FAV for June 2011. Farm Water [TP] of P in Farm Sample description ID content dry FAV FAV Mass (%) (mg/kg) (kg) 0401 2501 6117 3102 3103 4701 4702 91 86 92 94 65 85 83 1461 1463 1465 1451 1453 1456 1458 3.8 3.0 3.1 4.3 4.3 2.3 3.0 water lettuce and filamentous algae filamentous algae and water lettuce duck-weed water lettuce and torpedo grass water lettuce, and torpedo grass filamentous algae, and torpedo grass water lettuce and torpedo grass 40 August 2011 Farm 0401: Overall 60% cover mostly water lettuce (70%) and a bit of filamentous algae (30%) Farm 2501: Overall 40% cover mostly water lettuce and filamentous algae. Farm 6117: Overall 10% mostly duck-weed and little water lettuce. Farm 1813: Overall very clear canal. No appreciable FAV. Farm 3102: Overall about 40% of the canal was covered with FAV, dominated by water lettuce. Farm 3103: Overall 40% of the canal showed presence of FAV, dominated by water lettuce. Farm 4701: Overall 10% cover of filamentous algae. Farm 4702: Overall 15% confined mostly along the canal edges comprising of water lettuce. Table 5. FAV sample composition, water content, TP concentration, and mass of TP in farm canal FAV for August 2011. Farm Water [TP] of P in Farm Sample description ID content dry FAV FAV Mass (%) (mg/kg) (kg) 0401 2501 6117 3102 3103 4701 4702 86 89 87 93 88 91 85 2014 951 1473 4251 3222 876 928 9.9 2.2 1.9 11.4 3.1 0.4 1.2 water lettuce and filamentous algae filamentous algae duck-weed and water lettuce water-lettuce water lettuce filamentous algae water lettuce 41 October 2011 Farm 0401: Overall 40% cover mostly water lettuce (50%) and a bit of filamentous algae (50%) Farm 2501: Overall 15% cover mostly filamentous algae. Farm 6117: Overall 10% mostly duck-weed and little water lettuce. Farm 1813: Overall very clear canal. No appreciable FAV. Farm 3102: Overall about 30% of the canal was covered with FAV, dominated by waterhyacinth. Farm 3103: Overall 10% of the canal showed presence of FAV, mostly water hyacinth. Farm 4701: Overall 10% cover of filamentous algae. Farm 4702: Overall 15% confined mostly along the canal edges comprising of water lettuce. Table 6. FAV sample composition, water content, TP concentration, and mass of TP in farm canal FAV for October 2011. Farm Water [TP] of P in Farm Sample description ID content dry FAV FAV Mass (%) (mg/kg) (kg) 0401 2501 6117 3102 3103 4701 4702 92 91 90 91 91 90 93 1941 1237 3491 4103 4425 1426 1268 6.9 0.9 2.4 7.2 1.6 1.0 0.5 water lettuce and filamentous algae filamentous algae duck-weed and water lettuce water hyacinth water hyacinth and duckweed filamentous algae water lettuce 42 January 2012 Farm 0401: Overall 20% cover mostly water lettuce (50%) and a bit of filamentous algae (50%) Farm 2501: Overall 15% cover mostly filamentous algae. Farm 6117: Overall 30% mostly duck-weed and little water lettuce. Farm 1813: Overall very clear canal. No appreciable FAV. Farm 3102: Overall about 30% of the canal was covered with FAV, dominated by water-lettuce. Farm 3103: Overall 40% of the canal showed presence of FAV, mostly water lettuce. Farm 4701: Overall 15% cover of filamentous algae. Farm 4702: Overall 10% confined mostly along the canal edges comprising of water lettuce. Table 7. FAV sample composition, water content, TP concentration, and mass of TP in farm canal FAV for January 2012. Farm Water [TP] of P in Farm Sample description ID content dry FAV FAV Mass (%) (mg/kg) (kg) 0401 2501 6117 3102 3103 4701 4702 95 90 93 93 95 83 94 3131 2222 1663 2377 2790 1205 2533 0.5 2.1 1.7 5.9 2.7 1.7 0.9 filamentous algae and water lettuce filamentous algae duck-weed and water lettuce water lettuce and filamentous algae water lettuce filamentous algae water lettuce 43 April 2012 Farm 0401: Overall 50% cover mostly water lettuce (50%) and a bit of filamentous algae (50%) Farm 2501: Overall 70% cover mostly filamentous algae. Farm 6117: Overall 75% mostly duck-weed and little water lettuce. Farm 1813: Overall very clear canal. No appreciable FAV. Farm 3102: Overall about 30% of the canal was covered with FAV, dominated by water-lettuce. Farm 3103: Overall 30% of the canal showed presence of FAV, mostly water lettuce. Farm 4701: Overall 30% cover of filamentous algae. Farm 4702: Overall Clean canal Table 8. FAV sample composition, water content, TP concentration, and mass of TP in farm canal FAV for April 2012. Farm Water [TP] of P in Farm Sample description ID content dry FAV FAV Mass (%) (mg/kg) (kg) 0401 2501 6117 3102 3103 4701 92 92 82 92 89 90 1928 3216 2040 2193 2725 1300 4.4 10.2 6.5 3.5 9.7 1.3 water lettuce and filamentous algae water lettuce and filamentous algae water lettuce and duckweed water lettuce and filamentous algae water lettuce filamentous algae 44 Assessment of FAV in Farm Canal Pairs An assessment of FAV was conducted on farm canal pairs for all the data collected from the beginning of this project to present. Changes in dried mass (kg) of FAV were compared to the average TP concentration contained in the FAV (mg/kg). In addition, the percent FAV coverage in individual farm canals was compared to the total mass of P associated with FAV, (Figures 14 to 17). Between farm pair 3102 and 3103, the highest mass of dried FAV was observed in Farm 3102 in May 2011 at 7013 kg, compared to only 478 kg observed in farm 3103 during the same time (Figure 14). The highest TP concentration contained in the FAV was 4425 mg/kg observed in farm 3103 during October 2011. The % coverage of FAV was generally higher in 3102 and the highest mass of P associated with FAV was observed during May 2011 at 18 kg. We expect to see significant changes in % coverage and corresponding mass of FAV, in addition to reduction in mass of TP in individual canals once the treatments have been put into practice following the end of the second year. 45 3102 3103 2000 1500 1000 500 4/3/2012 1/23/2012 10/6/2011 8/9/2011 6/27/2011 5/9/2011 3/14/2011 1/11/2011 0 4/3/2012 1/23/2012 10/6/2011 8/9/2011 10.0 8.0 6.0 4.0 2.0 0.0 4/3/2012 2500 12.0 1/23/2012 3000 45 40 35 30 25 20 15 10 5 0 10/6/2011 Mass of dried FAV (kg) 3500 Mass of P Mass of P in canal (kg) 5000 4500 4000 3500 3000 2500 2000 1500 1000 500 0 Average TP conc. in FAV (mg/kg) 4000 FAV coverage 8/9/2011 Ave. TP conc. 6/27/2011 4/3/2012 1/23/2012 10/6/2011 8/9/2011 6/27/2011 Mass of dried FAV 3/14/2011 3103 5/9/2011 3/14/2011 1/11/2011 0 6/27/2011 1000 5/9/2011 3000 2000 5/9/2011 4000 20.0 18.0 16.0 14.0 12.0 10.0 8.0 6.0 4.0 2.0 0.0 1/11/2011 5000 45 40 35 30 25 20 15 10 5 0 1/11/2011 Mass of dried FAV (kg) 6000 Mass of P Mass of P in canal (kg) 4500 4000 3500 3000 2500 2000 1500 1000 500 0 Average TP conc. in FAV (mg/kg) 8000 7000 FAV coverage 3/14/2011 Ave. TP conc. % FAV coverage Mass of dried FAV % FAV coverage 3102 Figure 14. Comparison of FAV in main canals of farms 3102 and 3103. (Left) Changes in mass of dried FAV and average TP concentration of FAV over time. (Right) Changes in percent FAV coverage and mass of P in FAV over time. 46 500 4/3/2012 1/23/2012 10/6/2011 0 8/9/2011 0 4/3/2012 1/23/2012 10/6/2011 8/9/2011 2.5 10 2.0 8 1.5 6 4 1.0 2 0.5 0 0.0 4/3/2012 500 3.0 12 1/23/2012 1000 14 10/6/2011 1000 3.5 3/14/2011 1500 Mass of P 16 1/11/2011 1500 FAV coverage 8/9/2011 4/3/2012 1/23/2012 2000 6/27/2011 0.0 Mass of P in canal (kg) 2500 Average TP conc. In FAV (mg/kg) 2000 5/9/2011 0.5 4702 3000 3/14/2011 1.0 10 0 Ave. TP conc. 2500 1/11/2011 15 5 % FAV coverage Mass of dried FAV 10/6/2011 8/9/2011 6/27/2011 5/9/2011 3/14/2011 1/11/2011 0 1.5 6/27/2011 500 20 6/27/2011 1000 2.0 25 5/9/2011 1500 30 5/9/2011 2000 2.5 3/14/2011 2500 Mass of P 35 1/11/2011 3000 FAV coverage Mass of P in canal (kg) 1800 1600 1400 1200 1000 800 600 400 200 0 4702 Mass of dried FAV (kg) 4701 Ave. TP conc. % FAV coverage Mass of dried FAV Average TP conc. in FAV (mg/kg) Mass of dried FAV (kg) 4701 Figure 15. Comparison of FAV in main canals of farms 4701 and 4702. (Left) Changes in mass of dried FAV and average TP concentration of FAV over time. (Right) Changes in percent FAV coverage and mass of P in FAV over time. 47 0401 Ave. TP conc. 1500 1500 1000 1000 500 500 4/3/2012 1/23/2012 10/6/2011 8/9/2011 6/27/2011 5/9/2011 0 3/14/2011 0 4/3/2012 1/23/2012 10/6/2011 8.0 50 40 6.0 30 4.0 20 2.0 10 0 0.0 4/3/2012 2000 1/23/2012 2000 10.0 60 10/6/2011 2500 3/14/2011 2500 12.0 70 1/11/2011 3000 Mass of P Mass of P in canal (kg) 3000 FAV coverage 80 Average TP conc. In FAV (mg/kg) 3500 1/11/2011 0.0 2501 Ave. TP conc. 3500 Mass of dried FAV (kg) 0 8/9/2011 4/3/2012 1/23/2012 10/6/2011 8/9/2011 6/27/2011 Mass of dried FAV 2.0 10 % FAV coverage 2501 5/9/2011 3/14/2011 1/11/2011 0 4.0 20 8/9/2011 500 6.0 30 6/27/2011 1000 40 6/27/2011 1500 8.0 50 5/9/2011 2000 10.0 60 5/9/2011 2500 12.0 70 3/14/2011 3000 Mass of P 80 1/11/2011 3500 FAV coverage Mass of P in canal (kg) 5000 4500 4000 3500 3000 2500 2000 1500 1000 500 0 % FAV coverage Mass of dried FAV Average TP conc. In FAV (mg/kg) Mass of dried FAV (kg) 0401 Figure 16. Comparison of FAV in main canals of farms 0401 and 2501. (Left) Changes in mass of dried FAV and average TP concentration of FAV over time. (Right) Changes in percent FAV coverage and mass of P in FAV over time. 48 6117 0.0 Mass of P 1 0.9 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0 Clean Canal (No appreciable FAV) 3/14/2011 % FAV coverage 1 0.9 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0 1/11/2011 4/3/2012 FAV coverage 4/3/2012 4/3/2012 1/23/2012 1 0.9 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0 1/23/2012 10/6/2011 8/9/2011 6/27/2011 5/9/2011 3/14/2011 0 1813 Ave. TP conc. Clean Canal (No appreciable FAV) 1/11/2011 1.0 Mass of P in canal (kg) 1 0.9 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0 10/6/2011 8/9/2011 6/27/2011 Mass of dried FAV Average TP conc. In FAV (mg/kg) Mass of dried FAV (kg) 1813 5/9/2011 3/14/2011 0 1/11/2011 0 10 4/3/2012 500 2.0 1/23/2012 500 20 1/23/2012 1000 10/6/2011 1000 3.0 30 10/6/2011 1500 8/9/2011 1500 4.0 40 8/9/2011 2000 5.0 50 6/27/2011 2000 6.0 60 6/27/2011 2500 7.0 70 5/9/2011 2500 3000 80 5/9/2011 3000 3500 1/11/2011 4000 Mass of P Mass of P in canal (kg) 3500 FAV coverage 3/14/2011 Ave. TP conc. % FAV coverage Mass of dried FAV Average TP conc. In FAV (mg/kg) Mass of dried FAV (kg) 6117 Figure 17. Comparison of FAV in main canals of farms 6117 and 1813. (Left) Changes in mass of dried FAV and average TP concentration of FAV over time. (Right) Changes in percent FAV coverage and mass of P in FAV over time. 49 Water Quality Monitoring The eight farms (four pairs) are being monitored for water quality since November 2010. There are two conditions when canal waters that are sampled: (i) ambient condition (canal water grab samples), and (ii) drainage condition (flow-composited, drainage water samples). Grab water samples are collected regularly from all eight farms’ main canals at three locations per main farm canal, i.e., A, B, and C. The three grab sampling locations are in proximity of sediment sampling transect locations as shown in the aerial farm maps (Figures 2-5; see Farm Description section for more detail). The sampling location A is located halfway between the main canal length midpoint and the pumphouse, location B is located at the halfway point of the main farm canal reach, and location C is located halfway between location B and the end of the main canal reach. The periodicity of grab water sampling was at least two times per month. However, grab water samples are not collected during weeks when a farm was actively discharging drainage water. Drainage water samples were collected on a flow-weighted basis by auto-sampler during drainage events (active pumping of water off the farm). Water Sampling Procedures Ambient canal water samples are collected using an in-house grab sampling technique, which uses a 1.25 L Nalgene bottle harnessed by insulated wire to one end of an aluminum pole. The pole is gently immersed approximately 0.5 m below the canal surface while the sample bottle fills with water. The bottles are labeled and preserved on ice while being transported to the EREC lab for analyses. Field blanks and field duplicates are collected at every sampling event as per QA-QC guidelines (Quality Manual ver. 7.1, Josan et al., 2010). Drainage water samples are collected daily as a flow-composite sample (Photo 2). The composite sample is collected by auto-sampler using a solar power that is triggered by a data logger set at farm-specific flow discharge volume intervals. Drainage water samples are stored on-site in refrigerated containers until sample collection. Sample collection occurs within 24-36 hours of the initial drainage water sample collection. Laboratory Analyses All water samples are analyzed for total P (TP; Photo 3), total dissolved P (TDP), soluble reactive P (SRP; Photo 3), total suspended solids (TSS), pH, and dissolved calcium (Ca; photo 50 4). Particulate P (PP) was calculated as the difference between TP and TDP, whereas dissolved organic P (DOP) was calculated as a difference between TDP (after digestion) and SRP. The water samples were filtered through 0.45 µm filter and the filtrate were analyzed for TDP and SRP. For TP and TDP analysis water samples were digested in the presence of concentrated sulfuric acid, ammonium persulfate using method 365.1 (USEPA, 2003). All samples were analyzed for ortho-P using ascorbic acid method (Murphy and Riley, 1962) using an automated air segmented continuous flow analyzer, Auto Analyzer 3 (AA3) manufactured by Seal. Samples were analyzed in a range between 0.00 and 0.50 mg/ l. Samples with a concentration greater than 0.50 mg/l were diluted to fall in the applicable range. For the WY2012, the respective method detection limits for TP, TDP, and SRP were 0.005, 0.005, and 0.001 mg/l respectively. Detailed analytical procedures are contained in the Standard Methods for the Examination of Water and Wastewater (APHA, 1998), and EREC Quality Manual Ver. 7.1. (Josan et al. 2010, SOP 28 Rev. 1). For the TSS analysis, a well-mixed water sample (minimum 500 ml, equilibrated to controlled room temperature) was filtered through a pre-weighted standard glass fiber filter and the residue retained on the filter was dried to a constant weight at 105°C. The increase in weight of the filter was recorded and TSS concentrations were calculated on per liter basis. The practical range of the determination is 1 mg/l to 20,000 mg/l. The outlined procure is based on method 160.2 (USEPA, 2004) and details of the method are available in EREC Quality Manual Ver. 7.1 (SOP 13 Rev. 3). The total suspended solid were calculated using the following equation: TSS (mg / L ) = ( weightofdryfilter + residue + dish − weightofdryfilter + dish ) × 1000000 Samplevolume The pH of the water samples were determined using a combination glass electrode. The total dissolved Ca levels, hereafter referred as Ca, were analyzed using an atomic absorption spectrophotometer. 51 Photo 2. Datalogger, auto-sampler, refrigerator, and drainage water composite sample collection. 52 Photo 3. Orthophosphate (top) and total phosphorus (bottom) analyses being conducted on SEAL® Auto Analyzer. 53 Photo 4. Calibration of Hydrolab MiniSonde® left, and Ca analyses using atomic absorption spectrophotometer, right. 54 Ambient Farm Canal Water Monitoring Results The P species’ concentrations during the ambient canal conditions at three set locations on each farm are summarized in Tables 9 and 10. Additionally, the box-plots of TP with matching farm pairs are presented in Figure 18. The boxplots provide the exploratory data analysis along with visual summaries about P concentrations of ambient canal water during the monitoring period. Complete detailed lists of grab water samples results have been presented in Tables A5A12 in the appendix section. These tables present water quality parameters at each farm location for individual sampling dates for each of the three transects per farm. For example, Table A5 shows the water quality parameters of grab canal water samples collected during each sampling event from November 2010 through April 2012 from the farm 0401. For farm pair 0401 and 2501 the average TP values were 0.048 (± 0.043) mg/l and 0.060 (±0.052) mg/l respectively (Table 9). The highest TP values of 0.207 and 0.264 mg/l were observed on 2/23/2011 and 3/16/2011 for the farms 0401 and 2501 respectively. For farm pair 1813 and 6117 the average TP concentration was 0.074 (± 0.035) mg/l and 0.093 (± 0.040) mg/l respectively (Table 9). The maximum TP values of 0.242 and 0.258 mg/l were observed on 3/12/2012 and 1/4/2011 for the farm 1813 and 6117 respectively. For the farm pair 3102 and 3103 the average TP concentrations vales were 0.102 (± 0.073) and 0.078 (± 0.049) mg/l respectively. Amongst all of the farms, the farm 3102 showed wide variability in TP (Figure 18). The maximum TP values of 0.341 and 0.348 mg/l were observed on 3/16/2011 and 4/23/2012 for the farm 3102 and 3103 respectively (Table A9). Farm 3102 had higher average SRP concentration (0.059 ± 0.049 mg/l) than the farm 3103 (0.035 ± 0.046 mg/l). Farm 4701 had the lower average TP (0.040 ± 0.025) concentrations than that of 4702 (0.056 ± 0.026 mg/l) (Table 10). Total P concentrations of the grab water samples collected from the farm 4701 exhibited less variability than that of farm 4702 (Figure 18). The maximum TP values of 0.149 and 0.140 mg/l were observed on 3/16/2011 and 2/27/2012 for the farm 4701 and 4702 respectively. Farm 4701 had the lowest average SRP (0.005 ± 0.001 mg/l) concentrations amongst the entire farms, with a maximum value of 0.031mg/l observed on 12/6/2011. Bar graphs of ambient canal water average P speciation concentrations and percent total P fraction by farm showed that PP fraction was the dominant fraction observed in ambient canal 55 water with the exception of Farm 3102 (Figure 19). The average contribution of PP to the TP in the grab water samples ranged from as low as 31% (0.03 mg/l) for the farm 3102 to as high as 59% ( 0.025 mg/l) for the farm 4701. This behavior resulted in a high SRP contribution (56%) to the TP for the farm 3102 and a lower SRP contribution (16%) for the farm 4701 respectively. Table 9. Summary statistics of phosphorus species concentrations of ambient canal waters for farm pairs in S5A sub-basin from November 2010 through April 2012. Farm N Variable Mean Std. Minimum Maximum Median ID (mg\ l) dev. (mg\ l) (mg\ l) (mg\ l) 78 TP 0.048 0.043 0.003 0.207 0.034 77 TDP 0.030 0.033 0.002 0.192 0.016 77 PP 0.021 0.027 0.000 0.173 0.015 0401 76 SRP 0.021 0.027 0.001 0.183 0.009 62 DOP 0.013 0.024 0.000 0.165 0.005 78 TP 0.060 0.052 0.011 0.264 0.045 77 TDP 0.037 0.043 0.004 0.238 0.023 2501 77 PP 0.024 0.027 0.000 0.220 0.019 81 SRP 0.027 0.035 0.000 0.225 0.015 77 DOP 0.010 0.018 0.000 0.154 0.007 78 TP 0.074 0.035 0.028 0.242 0.068 77 TDP 0.032 0.022 0.010 0.118 0.021 77 PP 0.043 0.027 0.000 0.229 0.037 1813 76 SRP 0.022 0.021 0.001 0.104 0.015 65 DOP 0.012 0.013 0.000 0.065 0.010 78 TP 0.093 0.040 0.038 0.258 0.085 77 TDP 0.048 0.032 0.014 0.160 0.037 77 PP 0.044 0.025 0.007 0.167 0.041 6117 74 SRP 0.033 0.027 0.004 0.124 0.025 65 DOP 0.015 0.013 0.000 0.085 0.013 1 TP = total phosphorus, TDP = total dissolved phosphorus; PP = particulate phosphorus; SRP = soluble reactive phosphorus, DOP = dissolved organic phosphorus, and Std. dev. = standard deviation; PP = TP – TDP and DOP = TDP – SRP. The average PP concentrations of the ambient water samples for the farm pair 0401 and 2501 averaged 0.021 (± 0.027), and 0.024 (± 0.027) mg/l, representing 38 and 39% of the TP in the water column respectively. For the farm pair 1813 and 6117, the average PP concentrations were 0.043 (± 0.027) and 0.044 (± 0.025) mg/l respectively and representing 55 and 48% of the TP. For the farm pair 3102 and 3103 the average PP concentrations were 0.033 (± 0.055) and 0.028 (± 0.019) mg/l respectively and representing 32 and 36% of the TP. 56 Average DOP concentrations were similar among all the farms with values ranging from 0.010 to 0.015 mg/l. The average contribution of the DOP to total P varied from 12% (Farm 3102) to 23% (Farm 0401). A summary of ambient canal water pH, dissolved Ca and TSS is presented in Table 11. For the entire ambient canal water data set, the pH values ranged from 6.9 to 8.9 with an overall average of 8.0 (± 0.4). The Ca concentrations varied from 28.8 to 164 mg/l with an overall average of 71.5 (± 28.8) mg/l. The TSS content ranged from 0.2 to 137.8 mg/l, with an overall average of 8.6 (± 9.6) mg/l. The TSS content of the farm 6117 was more variable than the other monitored farms (Figure A5), whereas Ca concentrations of the farm 4702 were more variable for the farm 4702 (Figure A6). 57 Table 10. Summary statistics of phosphorus species concentrations of ambient canal waters for farm pairs in S6 sub-basin from November 2010 through April 2012. Farm N 1Variable Mean Std. Minimum Maximum Median ID (mg\ l) Dev. (mg\ l) (mg\ l) (mg\ l) 78 TP 0.102 0.073 0.025 0.341 0.078 77 TDP 0.070 0.051 0.015 0.291 0.054 3102 76 PP 0.033 0.055 0.000 0.281 0.019 76 SRP 0.059 0.049 0.008 0.269 0.044 69 DOP 0.013 0.013 0.000 0.077 0.011 78 TP 0.078 0.049 0.024 0.348 0.068 77 TDP 0.050 0.047 0.010 0.322 0.039 76 PP 0.028 0.019 0.004 0.102 0.024 3103 79 SRP 0.035 0.046 0.004 0.318 0.019 74 DOP 0.015 0.014 0.000 0.078 0.011 78 TP 0.040 0.025 0.018 0.149 0.032 78 TDP 0.018 0.015 0.005 0.090 0.014 78 PP 0.025 0.025 0.005 0.137 0.018 4701 80 SRP 0.007 0.005 0.001 0.031 0.005 76 DOP 0.011 0.015 0.000 0.087 0.009 78 TP 0.056 0.026 0.020 0.140 0.048 78 TDP 0.032 0.027 0.008 0.130 0.020 75 PP 0.027 0.019 0.000 0.092 0.023 4702 80 SRP 0.022 0.023 0.003 0.133 0.014 66 DOP 0.012 0.014 0.000 0.068 0.008 1 TP = total phosphorus, TDP = total dissolved phosphorus; PP = particulate phosphorus; SRP = soluble reactive phosphorus, DOP = dissolved organic phosphorus, and Std. dev. = standard deviation; PP = TP – TDP and DOP = TDP – SRP. 58 Figure 18. Distribution of total P (TP) concentrations in canal water grab samples collected from November 2010 through April 2012. The ‘◊’ sign in the box is the mean, horizontal line in the box is the median, the top and bottom of the box represents 75th and 25th percentile, whereas the whiskers define the 5th and 95th percentile observations, and ‘o’ sign outside the boxes are outliers. 59 0.12 PP SRP DOP 0.10 P (mg/l) 0.08 0.06 0.04 0.02 0.00 0401 2501 1813 6117 3102 3103 4701 4702 0401 2501 1813 6117 3102 3103 4701 4702 100 % P Fraction 80 60 40 20 0 Farm ID Figure 19. Ambient canal water average P speciation concentrations and percent total P by farm from November 2010 through April 2012. 60 Table 11. Summary statistics of ambient canal water pH, calcium, and total suspended solids for S5A and S6 sub-basin farm pairs from November 2010 to April 2012. Farm N Variable1 Mean Std Minimum Maximum Median ID Dev 78 pH 8.1 0.4 7.2 8.7 8.2 81 Ca 58.8 14.4 33.2 98.4 58.2 0401 81 TSS 7.8 12.0 0.2 88.2 4.8 78 pH 8.3 0.3 7.1 8.9 8.3 81 Ca 53.3 13.0 28.8 79.5 53.7 2501 81 TSS 8.8 15.2 0.7 137.8 6.7 78 pH 8.2 0.3 7.5 8.8 8.2 81 Ca 70.9 20.4 33.8 128.0 68.2 1813 81 TSS 10.4 5.8 3.1 32.6 9.3 78 pH 7.9 0.3 7.2 8.8 7.8 81 Ca 71.4 18.1 33.7 114.9 71.2 6117 80 TSS 12.0 7.5 0.5 44.4 10.3 78 pH 7.7 0.3 6.9 8.4 7.7 81 Ca 74.5 27.0 35.5 132.6 71.1 3102 81 TSS 9.2 13.5 0.5 110.3 5.6 78 pH 7.8 0.3 7.3 8.3 7.7 81 Ca 90.0 28.0 38.2 144.5 84.3 3103 81 TSS 6.5 4.6 0.4 24.0 4.8 78 pH 8.1 0.2 7.6 8.7 8.1 81 Ca 63.3 18.8 36.1 106.5 58.2 4701 81 TSS 7.0 3.2 1.0 19.3 6.4 78 pH 7.9 0.3 7.1 8.7 7.9 81 Ca 90.0 32.2 39.1 163.7 90.5 4702 81 TSS 6.9 5.6 0.5 31.4 5.6 1 Ca = dissolved calcium (mg\ l), TSS = total suspended solids (mg\ l) and Std. dev.= standard deviation. 61 Farm Canal In Situ Monitoring A monitoring program was established in November 2011 to measure water quality parameters that may influence P cycling within farm canals. Hydrolab MiniSonde® Series 5 multi-parameter water quality data loggers were used to measure and record temperature, pH, specific conductance (conductivity), and oxidation-reduction potential (ORP) and depth in situ. The MiniSonde® units were calibrated according to company specifications and programmed for a seven-day run (programmed to record a measurement every hour). The units were deployed in the center of each of the farm’s main canal at transect B at a depth of 0.25 meter above the sediment surface. After the MiniSonde® programmed seven day run ends, it was retrieved from the field, and the data were downloaded to a computer and stored in electronic format. A postrun assessment for drift of the instrument’s sensors was also immediately conducted. The instruments were then cleaned, maintained, and re-calibrated in the laboratory. The units were returned to the field for deployment during the following week’s monitoring cycle. All field and laboratory activities strictly follow relevant Standard Operating Procedures and the National Environmental Laboratory Accreditation Program (NELAP) approved quality manual. Quality control criteria regarding sensor drift and biofouling were as follows: pH <0.2 at pH=7.0 (Fisher Certified Standard: SB108-20 6.99 – 7.01 @ 25° C); conductivity < 100 µS/cm at 1413 µS/cm (0.01 M KCl); and redox < 20 mv of Zobell Solution (APHA-Redox Standard: 9880-1, + 428 mV against standard Hydrogen reference electrode at 25° C). Farm Canal In Situ Monitoring Results The summary statistics of hourly in situ water quality measurement are presented in Table 12. In addition, a more detailed summary of in situ monitoring results has been presented in Figures A7-A14 in the appendix section. These figures summarize water quality parameters at the selected farm canal location (B) for individual deployments. For example, Figure A7 shows the daily average water quality parameters measured from October 2011 through May 2012 for the farm 0401. The ambient canal water temperature ranged as low as 11.9°C for the farm 4701 to as high as 30.6°C for the farm 2501 (Table 12). The pH values varied from as low as 6.5 in farm 2501 to as high as of 9.7 in the farm 0401. The conductivity values ranged from as low as 485 µS/cm in farm 0401 to as high as 1814 µS/cm. The lowest ORP value of -349 mV was observed 62 in the farm 3102, whereas the maximum ORP value of 687 mV was observed in the farm 4702. The in situ data will be further examined for diurnal and seasonal variations once the monitoring period is over. Additionally these data values can also be used as covariates while conducting the regression studies. Table 12. Summary statistics of hourly in situ water quality measurements collected from October 2011 through April 2012. 1 Farm Statistical Temperature pH SpCond1 ORP2 Parameter (°C) (µS/cm) (mV) Mean 22.8 7.9 855 471 Minimum 13.9 6.9 485 -181 0401 Maximum 30.0 9.7 1814 636 Mean 22.7 8.2 771 510 Minimum 13.0 6.5 492 205 2501 Maximum 30.6 9.0 1299 668 Mean 22.7 8.0 859 470 Minimum 13.0 6.7 517 271 1813 Maximum 29.2 8.6 1218 656 Mean 22.9 7.7 889 517 Minimum 13.3 6.9 520 -36 6117 Maximum 28.8 8.6 1528 675 Mean 21.7 7.7 1181 424 Minimum 13.0 7.1 528 -349 3102 Maximum 31.2 9.0 1634 665 Mean 21.8 7.6 1227 495 Minimum 12.9 7.0 173 -93 3103 Maximum 31.2 8.2 2176 669 Mean 22.4 8.1 1013 452 Minimum 12.1 7.3 544 60 4701 Maximum 29.1 9.3 1400 607 Mean 21.5 7.7 1245 475 Minimum 11.9 6.8 658 -30 4702 Maximum 29.8 8.7 1509 687 1 SpCond= specific conductivity 2 ORP = oxidation reduction potential 63 Farm Drainage Water Drainage water concentrations of P species, pH, Ca, and TSS levels are presented in Tables 13 and 14. Overall, the TP concentrations ranged from a minimum of 0.032 mg\l at farm 4701 to a maximum of 0.748 mg\l at farm 3102 (Tables 13 and 14). Farm pairs matched well for comparison of drainage water TP with the largest differences in mean TP (0.104 mg\l) observed between farms 3101 and 3102. The least difference in mean TP between farm pairs (0.018 mg\l) was observed between farms 4701 and 4702. Summary statistics of other P species in farm drainage water are also presented in Tables 13 and 14. Secondary water quality parameter data for farm drainage waters are presented in Table 15. Farm drainage water means for pH Ca, and TSS were similar for all farm pairs; farm pair 0401 and 2501 had the largest difference in mean TSS concentration (12.2 mg\ l) compared to the other three farm pairs. Other differences between farms of a pair were negligible. Initial compilation of farm drainage data was conducted at daily, weekly, biweekly, and monthly time intervals. Higher correlation coefficients and better fitting regression models were observed with the biweekly time interval data set. Biweekly correlation coefficients for rainfall, drainage volume, and P load are presented in Table 16. The lowest correlation coefficients were observed for farm pair 4701 and 4702. This was also the farm pair with the least number of drainage events. The other three farm pairs had promising correlation coefficients for all three parameters. Additional regression investigations are being conducted to evaluate additional parameters (ambient canal water data) that may be utilized to develop more robust P load regression models. Additionally visual comparisons of daily load data suggest that for most drainage events, farm pairs had similar TP concentrations of drainage water, rainfall, and drainage volumes. Graphs of daily rainfall, drainage volume, and P load by farm pair are presented in Appendix Figures A16 through A26. Drainage water TP concentration variation by farm is presented in box plot format in Figure 19. The greatest variation in drainage water TP was observed at farms 3102 and 3103; the least variation in TP concentration was observed at farms 4701 and 4702. (Box plots of drainage water TDP, SRP, PP, DOP and TSS are presented in Appendix Figures A27 through A31). The P speciation of farm drainage water is affected by many factors. In this study we are investigating possible relationships between P speciation and FAV and canal management. Plots of average drainage water P speciation and percent contribution to total P are presented in Figure 64 20. For all farms the contribution of DOP to total P was minimal. Both PP and SRP contributed similarly to total P on the majority of the farms, with TDP contributing slightly more to total P export. Table 13. Summary statistics of drainage water phosphorus concentrations of farm pairs in the S5A sub-basin from November 2010 through April 2012. Farm ID N Variable1 Mean Std. Minimum Maximum Median (mg\ l) dev. (mg\ l) (mg\ l) (mg\ l) 35 TP 0.101 0.045 0.046 0.193 0.089 35 TDP 0.039 0.012 0.020 0.072 0.038 35 PP 0.062 0.041 0.013 0.163 0.042 0401 35 SRP 0.036 0.015 0.019 0.070 0.032 27 DOP 0.007 0.005 0.000 0.019 0.008 27 TP 0.076 0.025 0.042 0.135 0.072 27 TDP 0.040 0.018 0.016 0.083 0.034 28 PP 0.035 0.022 0.000 0.084 0.032 2501 28 SRP 0.032 0.015 0.011 0.065 0.027 27 DOP 0.007 0.010 0.000 0.034 0.007 29 TP 0.083 0.036 0.036 0.176 0.068 29 TDP 0.044 0.036 0.012 0.150 0.037 29 PP 0.039 0.016 0.017 0.084 0.036 1813 29 SRP 0.041 0.033 0.006 0.129 0.034 24 DOP 0.008 0.006 0.000 0.022 0.006 23 TP 0.141 0.052 0.070 0.310 0.129 23 TDP 0.069 0.037 0.026 0.153 0.068 23 PP 0.072 0.046 0.033 0.242 0.061 6117 23 SRP 0.056 0.038 0.012 0.145 0.043 21 DOP 0.015 0.012 0.001 0.060 0.013 1 TP = total phosphorus, TDP = total dissolved phosphorus; PP = particulate phosphorus; SRP = soluble reactive phosphorus, DOP = dissolved organic phosphorus, and Std. dev. = standard deviation; PP = TP – TDP and DOP = TDP – SRP. 65 Table 14. Summary statistics of drainage water phosphorus concentrations of farm pairs in the S6 sub-basin from November 2010 through April 2012. Farm ID N Variable1 Mean Std. Minimum Maximum Median dev. (mg\ l) (mg\ l) (mg\ l) (mg\ l) 35 TP 0.282 0.119 0.126 0.748 0.274 3102 35 TDP 0.171 0.057 0.023 0.270 0.177 36 PP 0.107 0.099 0.000 0.564 0.076 36 SRP 0.161 0.055 0.059 0.273 0.160 26 DOP 0.015 0.017 0.000 0.032 0.017 40 TP 0.178 0.077 0.070 0.380 0.166 3103 40 TDP 0.101 0.053 0.018 0.257 0.094 41 PP 0.076 0.043 0.000 0.193 0.069 41 SRP 0.091 0.055 0.011 0.235 0.081 36 DOP 0.009 0.036 0.000 0.118 0.010 20 TP 0.045 0.019 0.029 0.115 0.040 4701 20 TDP 0.020 0.014 0.006 0.064 0.015 19 PP 0.027 0.011 0.002 0.051 0.027 20 SRP 0.016 0.013 0.004 0.064 0.012 13 DOP 0.008 0.009 0.000 0.032 0.005 23 TP 0.063 0.018 0.032 0.104 0.059 4702 23 TDP 0.034 0.016 0.012 0.062 0.033 23 PP 0.029 0.010 0.012 0.049 0.027 23 SRP 0.037 0.016 0.007 0.070 0.036 8 DOP 0.009 0.006 0.001 0.020 0.007 1 TP = total phosphorus, TDP = total dissolved phosphorus; PP = particulate phosphorus; SRP = soluble reactive phosphorus, DOP = dissolved organic phosphorus, and Std. dev. = standard deviation; PP = TP – TDP and DOP = TDP – SRP. 66 Table 15. Summary statistics of drainage water pH, calcium, and total suspended solids in S5A and S6 basin farms from November 2010 to April 2012. Farm ID N 1Variable Mean Std. Minimum Maximum Median dev. 35 pH 7.8 0.2 7.4 8.2 7.8 35 Ca 114.9 25.9 36.2 148.0 116.9 401 34 TSS 25.8 18.4 4.3 76.9 20.6 28 pH 7.8 0.2 7.4 8.2 7.8 28 Ca 119.7 32.4 37.1 148.0 130.1 2501 27 TSS 13.6 9.0 2.4 30.6 12.5 29 pH 7.9 0.2 7.4 8.3 7.9 29 Ca 115.6 11.7 83.6 135.6 117.0 1813 28 TSS 12.8 5.4 4.1 24.0 11.6 23 pH 7.7 0.2 7.4 8.2 7.7 23 Ca 123.2 12.9 81.6 141.8 123.2 6117 23 TSS 12.9 31.3 4.3 38.2 10.3 36 pH 7.7 0.2 7.4 8.6 7.7 36 Ca 111.9 24.2 47.9 136.1 121.8 3102 33 TSS 27.1 23.0 1.8 93.2 22.1 41 pH 7.7 0.4 5.6 8.2 7.8 41 Ca 119.5 24.6 56.3 146.2 127.1 3103 40 TSS 21.7 59.2 2.4 86.9 14.8 20 pH 7.8 0.2 7.5 8.2 7.8 20 Ca 100.6 21.5 44.7 142.2 103.3 4701 20 TSS 9.6 6.6 2.4 23.1 6.6 23 pH 7.7 0.2 7.4 8.1 7.7 23 Ca 135.6 22.0 46.6 155.2 140.8 4702 21 TSS 10.7 10.7 2.8 52.1 7.5 1 Ca = dissolved calcium (mg\ l), TSS = total suspended solids (mg\ l) and Std. dev. = standard deviation. 67 Table 16. Spearman correlation coefficients of biweekly farm drainage data. Drainage Rainfall FWTP P Load Farm Pair1 Volume S5A Sub Basin 0.789 0.876 0.844 0401 vs. 2501 (<0.0001) (<0.0001) (<0.0001) 0.828 0.898 0.795 1813 vs. 6117 (<0.0001) (<0.0001) (<0.0001) S6 Sub Basin 0.764 0.833 0.900 3102 vs. 3103 (<0.0001) (<0.0001) (<0.0001) 0.820 0.659 0.625 4701 vs. 4702 (<0.0001) (<0.0001) (<0.0001) 1 Number of observations N=37; values in parentheses are significance values. 68 0.885 (<0.0001) 0.879 (<0.0001) 0.920 (<0.0001) 0.691 (<0.0001) Figure 19. Distribution of total P (TP) concentrations in drainage water samples collected from November 2010 through April 2012. The ‘◊’ sign in the box is the mean, horizontal line in the box is the median, the top and bottom of the box represents 75th and 25th percentile, whereas the whiskers define the 5th and 95th percentile observations, and ‘o’ sign outside the boxes are outliers. 69 0.35 PP SRP DOP 0.30 P (mg/l) 0.25 0.20 0.15 0.10 0.05 0.00 0401 2501 1813 6117 3102 3103 4701 4702 0401 2501 1813 6117 3102 3103 4701 4702 100 % P Fraction 80 60 40 20 0 Farm ID Figure 20. Drainage water average P speciation concentrations and percent of total P by farm from November 2010 through April 2012. 70 BMP Training Workshops Two BMP training sessions were conducted in the past year. Sessions were held on September 29, 2011 and April 19, 2012 respectively. On both occasions there was an excellent turnout of attendees; over 200 participants attended counting both training sessions. Both workshops lasted for over 4 hours and included talks by experts on topics pertinent to the EAA basin and South Florida ecosystem restoration. The evaluations received from participants at the conclusion of both sessions were very positive. The speakers and their presentation titles are listed in Table 17 below. Table 17. Speakers, affiliations, and presentations for BMP training workshops held in WY 2012. Speaker Affiliation Presentation Title Samira Daroub, PhD EREC/UF/IFAS Timothy Lang, PhD EREC/UF/IFAS Manohardeep Josan, PhD EREC/UF/IFAS Everglades Program Chapter 40E-63, F.A.C. BMP Research Update: Management of Floating Aquatic Vegetation Sediment and Particulate Control Practices Jehangir Bhadha, PhD Mabry McCray, PhD EREC/UF/IFAS Regional Agronomic Extension Agent II EREC/UF/IFAS BMP Program and Performance Overview Wise Use of Pesticides With Emphasis on Atrazine and Ametryn Nutrient Application and Control Practices Doug Pescatore, MS SFWMD EAA Basin Phosphorus Loads Bill Donovan, PhD SFWMD Sugarcane and Rice Extension Agent IV FLREC/UF/IFAS BMP Verification Methodology Managing Aquatic Weeds in EAA Farm Canals Managing Aquatic Weeds in Farm Canals Private Consultant USDA/ARS Canal Point What’s Going On With Lake Okeechobee? Les Baucum, MS Ron Rice, PhD Lyn Gettys, PhD Tom MacVicar, MS Barry Glaz, MS Sugarcane Production and BMPs The BMP Regulatory Program (Rule 40E-63) was explained in detail by Samira Daroub, Professor at EREC. Dr. Daroub covered the history of the BMP rule and the development of its many regulations and requirements. Specific requirements and terms of the rule regarding EAA 71 farming operations were explained and discussed with the participants. In addition a synopsis of Everglades restoration and the state of the current efforts was provided. The wise use of Atrazine and Ametryn, two commonly applied sugarcane herbicides was covered by Les Baucum, Hendry County Extension Agent II with IFAS/UF. The importance of safe handling and application of all pesticides, but especially these two indicator pesticides was explained in terms and consequences that the participants could identify. Techniques to minimize risks to environment and applicators were stressed which included anti-siphon check valves, setbacks from water bodies, importance of pesticide labels, meaning of LD50 and half-life, and others. Dr. Timothy Lang, Research Scientist and Project Manager for the FAV impact on farm P loads project, presented an overview of the various undertakings with respect to the ongoing project with the EAA-EPD and the SFWMD, and plans for future work. The final scope of work was presented along with farm selection criterion and some preliminary findings. Dr. Jehangir Bhadha, Research Associate in Soil and Water Science at EREC provided an in depth review of the BMP Program and its recent performance. He reviewed annual EAA basin P loadings and related them to their associated parameters of annual rainfall amount and distribution and rainfall effects on farm drainage water volume and P concentration. Phosphorus fertilizer application and control practices in the EAA were presented by Dr. Mabry McCray, Associate Scientist of Agronomy at EREC. Dr. McCray discussed methods to reduce the negative environmental impacts of P fertilizer application that included calibrated soil testing, banding of P fertilizers, effects of different P sources on P solubility, recommended fertilizer spill prevention protocols, and soil pH and P availability relationships, and sugarcane leaf P analysis and the Diagnostic Recommendation Integrated System (DRIS) was explained. Sediment and particulate control practices were described by Dr. Josan Manohardeep Singh, Research Associate in Soil and Water Science at EREC. Twelve techniques that are commonly employed on EAA farms to minimize sediment generation and transport were presented and discussed. Proper implementation of each technique was emphasized. A thorough presentation of the requirements for the successful verification of BMPs implemented at the farm level was provided by Dr. William Donovan, Senior Scientist at the SFWMD Everglades Regulation Division. Bill covered the methodology that the SFWMD uses 72 to verify proper BMP implementation on EAA farms, which included the rationale and documentation requirements for BMP verification. First-hand experience of implementing rainfall detention practices was provided by Mark Howell, environmental and water resources manager of Florida Crystals Corporation®. Mark explained the practices and requirements for successful implementation of this integral BMP. He thoroughly discussed pump log requirements, rainfall determinations for pump operations, canal level start and stop elevations, and recognized exception events. The management of aquatic weeds in EAA farm canals was presented by Dr. Ron Rice, Palm Beach County Extension Agent II with the UF/IFAS. The five most prevalent floating aquatic weeds found in EAA farm canals were reviewed and their control practices discussed. Dr. Rice presented methods to minimize the negative impacts of floating aquatic vegetation on water quality and Farm P loads. The critical management of water tables and sugarcane production was clarified by Barry Glaz, Research Agronomist with the USDA at Canal Point, Florida. The relationships between sugarcane water management practices and their effects on crop yield, drainage waters, and soil were presented. Barry’s research results from high water table and flooded sugarcane experiments were discussed. Possible management practices for field implementation were suggested and discussed with participants. Mr. Douglass Pescatore, Senior Programmer/Project Manager, SFMWD, gave us an in depth review of annual EAA basin, sub-basin, and farm P loads. Associated parameters were also presented and discussed along with strategies to improve BMP performance at the farm and sub-basin levels. Dr. Lyn Gettys, Weed Scientist at the Fort Lauderdale, UF/IFAS discussed the five most prevalent floating aquatic weeds found in EAA farm canals and also reviewed control practices. Her presentation highlighted some of the methods used to minimize impacts on water quality and farm P loads. Mr. Tom MacVicar, Hydrologist with MFL Associates discussed the relationships between Lake Okeechobee and its surrounding inflow and outflow basins. He also spoke about the historical and future trends of water quality and stage level within Lake Okeechobee, and explored potential treatment options to reduce P levels in the Lake. 73 Photo 5. Images of selected speakers from BMP training sessions held at the EREC in September 2011 and April 2012. 74 References American Public Health Association. 1998 Standard methods for the examination of water and wastewater. 20th ed. APHA, Washington, DC. Andersen, J.M. 1974. An ignition method for determination of phosphorus in lake sediments. Water Research. 10: 329-331. Bishop, P.L., W.D. Hively, J.R. Stedinger, M.R. Rafferty, J.L. Lojpersberger, and J.A. Bloomfield. 2005. Multivariate analysis of paired watershed data to evaluate agricultural best management practice effects on stream water phosphorus. J. Environ. Qual. 34:1087–1101. Danen-Louwerse, H.J., L. Lijklema, and M. Coenraats. 1995. Coprecipitation of phosphate with calcium carbonate in Lake Veluwe. Water Resources. 29:1781-1785. Daroub, S.H., T.A. Lang, O.A. Diaz, M. Chen, and J.D. Stuck. 2005. Annual Report submitted to Florida Department of Environmental Protection. Everglades Research and Education Center. Institute of Food and Agricultural Sciences. University of Florida. June 2005. Josan M.S., S. Daroub., T.A. Lang, and M. Chen. 2010. Quality Manual Ver. 7.1. Soil and Water Quality Laboratory, Everglades Research and Education Center, University of Florida. Hewlett, J.D., and L. Peinaar. 1973. Design and analysis of the catchment experiment. p. 88–106. In E.H. White (ed.) Proc. Symp. Use of Small Watersheds in Determining Effects of Forest Land Use on Water Quality. 22–23 May 1973. Univ. of Kentucky, Lexington. Loftis, J.C., L.H. MacDonald, S. Streett, H.K. Iyer, and K. Bunte. 2001. Detecting cumulative watershed effects: The statistical power of pairing. J. Hydrol. (Amsterdam) 251:49–64. Murphy, J., and J.P. Riley. 1962. A modified single solution method for determination of phosphate in natural waters. Anal. Chim. Acta. 27:31-36. Murphy, T., K. Hall, and I. Yasaki. 1983. Coprecipitation of phosphate and calcite in naturally eutrophic lake. Limnol. Oceanogr. 28:28-67. Reddy, K.R., J.C. Tucker, and W.F. DeBusk. 1987. The role of Egeria in removing nitrogen and phosphorus from nutrient enriched waters. J. Aquat. Plant Manage. 25:14-19. SAS Institute. 2008. SAS System for Windows. Version 9.2. SAS Institute, Cary, NC. Soil Survey Laboratory Methods Manual. Soil Survey Investigation Report No. 42, Version 4.0, November 2004. South Florida Environmental Report. 2012. South Florida Water Management District, West Palm Beach Florida. 75 Stuck, J.D. 1996. Particulate phosphorus transport in the water conveyance systems of the Everglades Agricultural Area. Ph.D. dissertation submitted to the University of Florida Department of Agricultural and Biological Engineering, Gainesville, Fla. United States Environmental Protection Agency.1993. Paired watershed study design. USEPA Fact Sheet 841-F-93-009 United States Environmental Protection Agency. 2003. Index to EPA Test Methods. April 2003 revised edition. United States Environmental Protection Agency. 2004. 9045D. Soil and Waste pH. Revision 4, November 2004. 76 Appendix List of Appendix Tables Table A1. Crop acreages by month for farm 0401 and 2501.............................................................. 80 Table A2. Crop acreages by month for farms 1813 and 6117. ........................................................... 81 Table A3. Crop acreages by month for farms 4701 and 4702. ........................................................... 82 Table A4. Crop acreages by month for farms 3102 and 3103. ........................................................... 83 Table A5. Detailed water quality parameters of grab canal water samples collected from Farm 0401 from November 2010 through April 2012. ................................................................................... 84 Table A6. Detailed water quality parameters of the grab canal water samples collected from Farm 2501 from November 2010 through April 2012. .......................................................................... 86 Table A7. Detailed water quality parameters of the grab canal water samples collected from Farm 1813 from November 2010 through April 2012. .......................................................................... 88 Table A8. Detailed water quality parameters of the grab canal water samples collected from Farm 6117 from November 2010 through April 2012. .......................................................................... 90 Table A9. Detailed water quality parameters of the grab canal water samples collected from Farm 3102 from November 2010 through April 2012. .......................................................................... 92 Table A10. Detailed water quality parameters of the grab canal water samples collected from Farm 3103 from November 2010 through April 2012. .......................................................................... 94 Table A11. Detailed water quality parameters of the grab canal water samples collected from Farm 4701 from November 2010 through April 2012. .......................................................................... 96 Table A12. Detailed water quality parameters of the grab canal water samples collected from Farm 4702 from November 2010 through April 2012. .......................................................................... 98 Table A13. Detailed water quality parameters of drainage water samples collected from farm 0401 from February 2011 through April 2012. ................................................................................... 114 Table A14. Detailed water quality parameters of drainage water samples collected from farm 2501 from February 2011 through April 2012. ................................................................................... 115 Table A15. Detailed water quality parameters of drainage water samples collected from farm 1813 from February 2011 through April 2012. ................................................................................... 116 Table A16. Detailed water quality parameters of drainage water samples collected from farm 6117 from February 2011 through April 2012. ................................................................................... 117 Table A17. Detailed water quality parameters of drainage water samples collected from farm 3102 from February 2011 through April 2012. ................................................................................... 118 Table A18. Table A18. Detailed water quality parameters of drainage water samples collected from farm 3103 from February 2011 through April 2012. .................................................................. 119 Table A19. Detailed water quality parameters of drainage water samples collected from farm 4701 from February 2011 through April 2012. ................................................................................... 120 Table A20. Detailed water quality parameters of drainage water samples collected from farm 4702 from February 2011 through April 2012. ................................................................................... 121 77 List of Appendix Figures Figure A1. Distribution of total dissolved P (TDP) concentrations in canal water grab samples collected from November 2010 through April 2012................................................................... 100 Figure A2. Distribution of soluble reactive P (SRP) concentrations in canal water grab samples collected from November 2010 through April 2012................................................................... 101 Figure A3. Distribution of particulate-P (PP) concentrations in canal water grab samples collected from November 2010 through April 2012. ................................................................................. 102 Figure A4. Distribution of dissolved organic P (DOP) concentrations in canal water grab samples collected from November 2010 through April 2012................................................................... 103 Figure A5 Distribution of total suspended solids (TSS) concentrations in canal water grab samples collected from November 2010 through April 2012................................................................... 104 Figure A6. Distribution of dissolved calcium (Ca) concentrations in canal water grab samples collected from November 2010 through April 2012................................................................... 105 Figure A7. Daily average of in situ measurements of canal water quality parameters recorded with MiniSonde® in farm 0401. ......................................................................................................... 106 Figure A8. Daily average of in situ measurements of canal water quality parameters recorded with MiniSonde® in farm 2501. ......................................................................................................... 107 Figure A9. Daily average of in situ measurements of canal water quality parameters recorded with MiniSonde® in farm 1813. ......................................................................................................... 108 Figure A10. Daily average of in situ measurements of canal water quality parameters recorded with MiniSonde® in farm 6117. ......................................................................................................... 109 Figure A11. Daily average of in situ measurements of canal water quality parameters recorded with MiniSonde® in farm 3102. ......................................................................................................... 110 Figure A12. Daily average of in situ measurements of canal water quality parameters recorded with MiniSonde® in farm 3103. ......................................................................................................... 111 Figure A13. Daily average of in situ measurements of canal water quality parameters recorded with MiniSonde® in farm 4701. ......................................................................................................... 112 Figure A14. Daily average of in situ measurements of canal water quality parameters recorded with MiniSonde® in farm 4702. ......................................................................................................... 113 Figure A15. Daily rainfall for farms 0401 and 2501 for WY 2012. ................................................. 122 Figure A16. Daily rainfall for farms 1813 and 6117 for WY 2012. ................................................. 122 Figure A17. Daily rainfall for farms 3102 and 3103 for WY 2012. ................................................. 123 Figure A18. Daily rainfall for farms 4701 and 4702 for WY 2012. ................................................. 123 Figure A19. Daily drainage volume for farms 0401 and 2501 for WY 2012................................... 124 Figure A20. Daily drainage volume for farms 1813 and 6117 for WY 2012................................... 124 Figure A21. Daily drainage volume for farms 3102 and 3103 for WY 2012................................... 125 Figure A22. Daily drainage volume for farms 4701 and 4702 for WY 2012................................... 125 Figure A23. Daily P export for farms 0401 and 2501 for WY 2012. ............................................... 126 Figure A24. Daily P export for farms 1813 and 6117 for WY 2012. ............................................... 126 Figure A25. Daily P export for farms 3102 and 3103 for WY 2012. ............................................... 127 Figure A26. Daily P export for farms 4701 and 4702 for WY 2012. ............................................... 127 Figure A27. Distribution of total dissolved P (TDP) concentrations in drainage water samples collected from November 2010 through April 2012................................................................... 128 Figure A28. Distribution of soluble reactive P (SRP) concentrations in drainage water samples collected from November 2010 through April 2012................................................................... 129 78 Figure A29. Distribution of particulate-P (PP) concentrations in drainage water samples collected from November 2010 through April 2012. ................................................................................. 130 Figure A30. Distribution of dissolved organic-P (DOP) concentrations in drainage water samples collected from November 2010 through April 2012................................................................... 131 Figure A31. Distribution of total suspended solids (TSS) concentrations in drainage water samples collected from November 2010 through April 2012................................................................... 132 Figure A32. Distribution of dissolved calcium (Ca) concentrations in drainage water samples collected from November 2010 through April 2012................................................................... 133 79 Table A1. Crop acreages by month for farm 0401 and 2501. Farm ID 0401 0401 0401 0401 0401 0401 0401 0401 0401 0401 0401 0401 0401 0401 0401 0401 0401 0401 2501 2501 2501 2501 2501 2501 2501 2501 2501 2501 2501 2501 2501 2501 2501 2501 2501 2501 Month/Year Jan-2011 Feb-2011 Mar-2011 Apr-2011 May-2011 Jun-2011 Jul-2011 Aug-2011 Sep-2011 Oct-2011 Nov-2011 Dec-2011 Jan-2012 Feb-2012 Mar-2012 Apr-2012 May-2012 Jun-2012 Jan-2011 Feb-2011 Mar-2011 Apr-2011 May-2011 Jun-2011 Jul-2011 Aug-2011 Sep-2011 Oct-2011 Nov-2011 Dec-2011 Jan-2012 Feb-2012 Mar-2012 Apr-2012 May-2012 Jun-2012 Cane Acres 498 557 586 644 557 557 557 557 557 557 849 762 615 762 762 762 762 762 691 691 691 658 658 658 658 658 658 658 593 691 428 691 790 790 790 790 % 55 61 65 71 61 61 61 61 61 61 94 84 68 84 84 84 84 84 84 84 84 80 80 80 80 80 80 80 72 84 52 84 96 96 96 96 Fallow Acres 410 205 59 0 0 234 234 351 351 351 59 146 293 0 0 0 146 146 132 132 0 33 33 165 165 165 165 165 230 132 395 99 0 0 0 0 % 45 23 6 0 0 26 26 39 39 39 6 16 32 0 0 0 16 16 16 16 0 4 4 20 20 20 20 20 28 16 48 12 0 0 0 0 Flooded/Rice Acres % 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 Corn Acres 0 88 205 205 351 117 117 0 0 0 0 0 0 146 146 146 0 0 0 0 132 132 132 0 0 0 0 0 0 0 0 33 33 33 33 33 80 % 0 10 23 23 39 13 13 0 0 0 0 0 0 16 16 16 0 0 0 0 16 16 16 0 0 0 0 0 0 0 0 4 4 4 4 4 Beans Acres 0 59 59 59 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 % 0 6 6 6 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 Leaf Acres 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 % 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 Total Acres 908 908 908 908 908 908 908 908 908 908 908 908 908 908 908 908 908 908 823 823 823 823 823 823 823 823 823 823 823 823 823 823 823 823 823 823 Table A2. Crop acreages by month for farms 1813 and 6117. Farm ID 1813 1813 1813 1813 1813 1813 1813 1813 1813 1813 1813 1813 1813 1813 1813 1813 1813 1813 6117 6117 6117 6117 6117 6117 6117 6117 6117 6117 6117 6117 6117 6117 6117 6117 6117 6117 Month/Year Jan-2011 Feb-2011 Mar-2011 Apr-2011 May-2011 Jun-2011 Jul-2011 Aug-2011 Sep-2011 Oct-2011 Nov-2011 Dec-2011 Jan-2012 Feb-2012 Mar-2012 Apr-2012 May-2012 Jun-2012 Jan-2011 Feb-2011 Mar-2011 Apr-2011 May-2011 Jun-2011 Jul-2011 Aug-2011 Sep-2011 Oct-2011 Nov-2011 Dec-2011 Jan-2012 Feb-2012 Mar-2012 Apr-2012 May-2012 Jun-2012 Cane Acres % 594 100 500 84 500 84 500 84 500 84 500 84 500 84 500 84 500 84 500 84 500 84 594 100 594 100 594 100 594 100 594 100 594 100 594 100 720 90 800 100 800 100 800 100 800 100 800 100 800 100 800 100 800 100 580 73 560 70 560 70 60 8 720 90 720 90 720 90 720 90 720 90 Fallow Acres 0 94 0 0 0 94 94 94 94 94 94 0 0 0 0 0 0 0 80 0 0 0 0 0 0 0 0 220 240 240 740 80 0 0 80 80 % 0 16 0 0 0 16 16 16 16 16 16 0 0 0 0 0 0 0 10 0 0 0 0 0 0 0 0 28 30 30 93 10 0 0 10 10 Flooded/Rice Acres % 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 Corn Acres 0 0 94 94 94 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 81 % 0 0 16 16 16 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 Beans Acres 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 80 80 0 0 % 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 10 10 0 0 Leaf Acres 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 % 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 Total Acres 594 594 594 594 594 594 594 594 594 594 594 594 594 594 594 594 594 594 800 800 800 800 800 800 800 800 800 800 800 800 800 800 800 800 800 800 Table A3. Crop acreages by month for farms 4701 and 4702. Farm ID 4701 4701 4701 4701 4701 4701 4701 4701 4701 4701 4701 4701 4701 4701 4701 4701 4701 4701 4702 4702 4702 4702 4702 4702 4702 4702 4702 4702 4702 4702 4702 4702 4702 4702 4702 4702 Month/Year Jan-2011 Feb-2011 Mar-2011 Apr-2011 May-2011 Jun-2011 Jul-2011 Aug-2011 Sep-2011 Oct-2011 Nov-2011 Dec-2011 Jan-2012 Feb-2012 Mar-2012 Apr-2012 May-2012 Jun-2012 Jan-2011 Feb-2011 Mar-2011 Apr-2011 May-2011 Jun-2011 Jul-2011 Aug-2011 Sep-2011 Oct-2011 Nov-2011 Dec-2011 Jan-2012 Feb-2012 Mar-2012 Apr-2012 May-2012 Jun-2012 Cane Acres 630 630 630 630 630 630 630 630 630 630 630 630 630 630 630 630 630 630 640 640 640 640 640 640 640 640 640 640 640 320 320 320 320 320 320 320 Fallow % 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 50 50 50 50 50 50 50 Acres 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 320 320 320 320 0 0 0 Flooded/Rice % 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 50 50 50 50 0 0 0 Acres 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 320 320 320 % 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 50 50 50 Corn Acres 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 Beans % 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 82 Acres 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 Leaf % 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 Acres 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 Total % 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 Acres 630 630 630 630 630 630 630 630 630 630 630 630 630 630 630 630 630 630 640 640 640 640 640 640 640 640 640 640 640 640 640 640 640 640 640 640 Table A4. Crop acreages by month for farms 3102 and 3103. Farm ID 3102 3102 3102 3102 3102 3102 3102 3102 3102 3102 3102 3102 3102 3102 3102 3102 3102 3102 3103 3103 3103 3103 3103 3103 3103 3103 3103 3103 3103 3103 3103 3103 3103 3103 3103 3103 Month/Year Jan-2011 Feb-2011 Mar-2011 Apr-2011 May-2011 Jun-2011 Jul-2011 Aug-2011 Sep-2011 Oct-2011 Nov-2011 Dec-2011 Jan-2012 Feb-2012 Mar-2012 Apr-2012 May-2012 Jun-2012 Jan-2011 Feb-2011 Mar-2011 Apr-2011 May-2011 Jun-2011 Jul-2011 Aug-2011 Sep-2011 Oct-2011 Nov-2011 Dec-2011 Jan-2012 Feb-2012 Mar-2012 Apr-2012 May-2012 Jun-2012 Cane Acres 1206 89 313 625 670 670 536 536 536 536 491 536 536 491 1251 1251 1251 1251 452 301 151 452 452 452 452 452 452 452 452 301 301 301 452 452 452 452 % 75 6 19 39 42 42 33 33 33 33 31 33 33 31 78 78 78 78 75 50 25 75 75 75 75 75 75 75 75 50 50 50 75 75 75 75 Fallow Acres 402 1161 357 45 89 938 670 670 1072 536 491 893 849 804 0 223 268 268 0 151 301 0 151 0 0 151 151 0 0 263 301 301 0 0 0 151 % 25 72 22 3 6 58 42 42 67 33 31 56 53 50 0 14 17 17 0 25 50 0 25 0 0 25 25 0 0 44 50 50 0 0 0 25 Flooded/Rice Acres % 0 0 0 0 0 0 0 0 0 0 0 0 402 25 402 25 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 151 25 151 25 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 Corn Acres 0 357 849 849 849 0 0 0 0 536 491 89 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 38 38 38 0 0 151 151 151 0 83 % 0 22 53 53 53 0 0 0 0 33 31 6 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 6 6 6 0 0 25 25 25 0 Beans Acres 0 0 89 89 0 0 0 0 0 0 134 89 134 223 268 45 0 0 0 0 0 0 0 0 0 0 0 113 113 0 0 0 0 0 0 0 % 0 0 6 6 0 0 0 0 0 0 8 6 8 14 17 3 0 0 0 0 0 0 0 0 0 0 0 19 19 0 0 0 0 0 0 0 Leaf Acres 0 0 0 0 0 0 0 0 0 0 0 0 89 89 89 89 89 89 151 151 151 151 0 0 0 0 0 0 0 0 0 0 0 0 0 0 % 0 0 0 0 0 0 0 0 0 0 0 0 6 6 6 6 6 6 25 25 25 25 0 0 0 0 0 0 0 0 0 0 0 0 0 0 Total Acres 1608 1608 1608 1608 1608 1608 1608 1608 1608 1608 1608 1608 1608 1608 1608 1608 1608 1608 602 602 602 602 602 602 602 602 602 602 602 602 602 602 602 602 602 602 Table A5. Detailed water quality parameters of grab canal water samples collected from Farm 0401 from November 2010 through April 2012. Sampling Date 11/9/2010 11/9/2010 11/9/2010 11/23/2010 11/23/2010 11/23/2010 1/4/2011 1/4/2011 1/4/2011 1/19/2011 1/19/2011 1/19/2011 2/2/2011 2/2/2011 2/2/2011 2/9/2011 2/9/2011 2/9/2011 2/23/2011 2/23/2011 2/23/2011 3/2/2011 3/2/2011 3/2/2011 3/16/2011 3/16/2011 3/16/2011 3/30/2011 3/30/2011 3/30/2011 4/13/2011 4/13/2011 4/13/2011 4/25/2011 4/25/2011 4/25/2011 5/4/2011 5/4/2011 5/4/2011 5/19/2011 5/19/2011 5/19/2011 6/7/2011 6/7/2011 6/7/2011 6/22/2011 6/22/2011 6/22/2011 8/17/2011 8/17/2011 8/17/2011 12/6/2011 12/6/2011 12/6/2011 Transect TP1 TDP PP SRP DOP TSS Ca (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) A B C A B C A B C A B C A B C A B C A B C A B C A B C A B C A B C A B C A B C A B C A B C A B C A B C A B C nd nd nd 0.046 0.028 0.028 0.025 0.007 0.022 0.050 0.011 0.003 0.127 0.034 0.016 0.173 0.020 0.023 0.207 0.059 0.013 0.124 0.059 0.045 0.070 0.020 0.021 0.052 0.036 0.019 0.119 0.072 0.011 0.090 0.048 0.013 0.070 0.032 0.011 0.086 0.037 0.012 0.063 0.019 0.004 0.049 0.024 0.027 0.054 0.044 0.024 0.077 0.047 0.014 nd nd nd 0.038 0.010 0.006 0.013 0.005 0.005 0.041 0.005 0.002 0.067 0.005 0.016 0.167 0.009 0.006 0.192 0.043 0.005 0.106 0.018 0.024 0.044 0.009 0.009 0.030 0.016 0.005 0.087 0.069 0.011 0.056 0.034 0.009 0.042 0.016 nd 0.046 0.027 0.004 0.047 0.006 0.004 0.071 0.053 0.048 0.041 0.029 0.011 0.046 0.025 0.008 nd nd nd 0.008 0.018 0.022 0.012 0.002 0.017 0.009 0.006 0.001 0.060 0.029 0.000 0.006 0.011 0.017 0.015 0.016 0.008 0.018 0.041 0.021 0.026 0.011 0.012 0.022 0.020 0.014 0.032 0.003 0.000 0.034 0.014 0.004 0.028 0.016 nd 0.040 0.010 0.009 0.016 0.013 0.001 0.049 0.024 0.027 0.013 0.015 0.013 0.031 0.022 0.006 0.030 0.011 0.010 0.033 0.008 0.007 0.012 0.001 0.001 0.002 0.002 nd 0.004 nd 0.002 0.002 0.007 0.004 0.183 0.049 0.005 0.085 0.006 0.006 0.041 nd 0.003 nd nd 0.005 0.069 0.052 0.008 0.051 0.029 0.004 0.035 0.032 0.004 0.037 0.008 0.005 0.013 0.002 0.001 0.018 0.002 0.001 0.032 0.018 0.004 0.048 0.021 0.006 nd nd nd 0.005 0.002 0.000 0.002 0.004 0.004 0.039 0.003 nd 0.063 nd 0.014 0.165 0.002 0.002 0.009 0.000 0.000 0.022 0.012 0.018 0.003 nd 0.006 nd nd 0.000 0.018 0.017 0.003 0.006 0.005 0.005 0.007 nd nd 0.009 0.019 nd 0.034 0.005 0.002 0.054 0.051 0.047 0.009 0.011 0.007 nd 0.004 0.002 0.5 6.9 0.5 2.0 15.7 1.2 2.2 1.2 1.8 2.4 4.8 2.8 6.6 10.2 4.2 3.8 3.6 3.6 0.2 5.8 4.8 6.2 2.4 88.2 20.0 3.0 4.0 29.0 4.8 2.4 9.5 8.0 55.9 11.2 2.3 1.9 7.1 2.3 4.7 2.7 3.0 7.6 4.4 2.9 2.8 5.6 13.6 1.8 4.4 3.3 4.5 8.4 8.8 7.4 60.4 64.4 56.7 37.3 47.3 47.9 34.6 36.2 39.1 62.3 62.3 42.4 70.6 67.5 55.2 74.6 69.8 69.0 73.8 68.2 63.8 46.8 45.6 50.0 39.2 39.8 33.2 55.9 59.1 66.1 36.3 63.6 65.3 38.1 39.4 38.5 54.9 56.7 50.8 53.7 64.7 44.6 57.8 56.5 44.6 54.6 56.7 56.0 84.9 79.5 78.7 54.0 65.1 86.3 84 pH 7.2 8.1 8.5 7.9 8.1 8.5 8.3 8.4 8.2 8.3 8.4 8.3 8.5 8.3 8.3 8.5 8.4 8.4 8.6 8.4 8.4 8.5 8.3 8.3 8.3 8.1 8.0 8.3 8.2 8.3 8.0 8.1 8.2 8.6 8.6 8.7 7.4 7.3 8.2 7.7 7.6 8.6 7.9 7.4 8.0 7.5 7.3 7.3 7.9 8.2 8.3 Sampling Date 12/20/2011 12/20/2011 12/20/2011 1/11/2012 1/11/2012 1/11/2012 1/25/2012 1/25/2012 1/25/2012 2/8/2012 2/8/2012 2/8/2012 2/27/2012 2/27/2012 2/27/2012 3/12/2012 3/12/2012 3/12/2012 3/28/2012 3/28/2012 3/28/2012 4/9/2012 4/9/2012 4/9/2012 4/23/2012 4/23/2012 4/23/2012 1 Transect TP1 TDP PP SRP DOP TSS Ca (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) A B C A B C A B C A B C A B C A B C A B C A B C A B C 0.067 0.038 0.017 0.042 0.019 0.012 0.053 0.034 0.007 0.082 0.068 0.016 0.056 0.033 0.015 0.059 0.087 0.182 0.028 0.018 0.181 0.110 0.030 0.011 0.031 0.024 0.010 0.054 0.024 0.011 0.042 0.008 0.005 0.027 0.007 0.002 0.051 0.038 0.007 0.037 0.015 0.010 0.036 0.066 0.009 0.013 0.009 0.013 0.057 0.014 0.009 0.017 0.011 0.004 0.013 0.014 0.006 0.000 0.011 0.007 0.026 0.027 0.005 0.031 0.030 0.009 0.019 0.018 0.005 0.023 0.021 0.173 0.015 0.009 0.168 0.053 0.016 0.002 0.014 0.013 0.006 0.048 0.013 0.048 0.030 0.003 0.002 0.029 0.014 0.002 0.052 0.035 0.003 0.034 0.007 0.003 0.039 0.067 0.006 0.013 0.010 0.006 0.054 0.009 0.005 0.0170 0.0092 0.0039 0.007 0.011 nd 0.012 0.005 0.003 nd nd 0.000 nd 0.003 0.004 0.003 0.009 0.007 nd nd 0.003 0.000 nd 0.008 0.003 0.005 0.004 0.000 0.002 0.000 3.4 3.8 3.4 5.8 3.6 3.2 6.9 6.4 5.7 10.0 10.0 5.8 8.0 6.1 2.3 7.7 6.8 9.3 4.5 4.4 36.2 19.1 4.8 3.5 6.2 9.0 5.2 60.4 58.9 52.1 78.2 71.0 66.5 58.2 58.3 59.3 57.5 58.3 62.7 66.5 73.3 62.4 94.0 78.4 76.6 88.1 98.4 56.4 52.5 74.7 38.9 52.8 44.7 40.9 TP=total-P; TDP=total dissolved-P; PP=particulate-P; SRP=soluble reactive-P; DOP=dissolved organic-P; TSS=total suspended solids; Ca=total dissolved calcium. nd = not determined. 85 pH 8.1 8.4 8.5 8.1 8.2 8.1 7.9 8.2 8.2 7.7 7.7 7.7 8.0 8.2 8.0 7.5 7.7 7.6 7.8 8.3 8.1 7.9 7.7 7.7 7.7 8.4 8.4 Table A6. Detailed water quality parameters of the grab canal water samples collected from Farm 2501 from November 2010 through April 2012. Sampling Date 11/9/2010 11/9/2010 11/9/2010 11/23/2010 11/23/2010 11/23/2010 1/4/2011 1/4/2011 1/4/2011 1/18/2011 1/18/2011 1/18/2011 2/2/2011 2/2/2011 2/2/2011 2/9/2011 2/9/2011 2/9/2011 2/23/2011 2/23/2011 2/23/2011 3/2/2011 3/2/2011 3/2/2011 3/16/2011 3/16/2011 3/16/2011 3/30/2011 3/30/2011 3/30/2011 4/13/2011 4/13/2011 4/13/2011 4/25/2011 4/25/2011 4/25/2011 5/4/2011 5/4/2011 5/4/2011 5/19/2011 5/19/2011 5/19/2011 6/7/2011 6/7/2011 6/7/2011 6/22/2011 6/22/2011 6/22/2011 8/17/2011 8/17/2011 8/17/2011 12/6/2011 12/6/2011 12/6/2011 Transect TP1 TDP PP SRP DOP TSS Ca (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) A B C A B C A B C A B C A B C A B C A B C A B C A B C A B C A B C A B C A B C A B C A B C A B C A B C A B C nd nd nd 0.069 0.057 0.045 0.033 0.058 0.035 0.045 0.050 0.029 0.200 0.073 0.041 0.254 0.129 0.038 0.261 0.135 0.073 0.120 0.068 0.081 0.264 0.112 0.091 0.048 0.040 0.034 0.092 0.073 0.031 0.067 0.035 0.021 0.067 0.034 0.011 0.064 0.055 0.020 0.047 0.013 0.014 0.032 0.015 0.013 0.040 0.026 0.026 0.077 0.035 0.017 nd nd nd 0.049 0.025 0.017 0.018 0.017 0.007 0.035 0.018 0.012 0.200 0.036 0.005 0.235 0.094 0.012 0.238 0.109 0.058 0.073 0.058 0.036 0.044 0.022 0.013 0.027 0.019 0.021 0.062 0.045 0.013 0.047 0.023 0.013 0.048 0.033 nd 0.048 0.033 0.011 0.033 0.007 0.004 0.024 0.004 0.013 0.021 0.014 0.010 0.043 0.013 0.011 nd nd nd 0.020 0.032 0.028 0.015 0.041 0.028 0.010 0.032 0.017 0.000 0.037 0.036 0.019 0.035 0.026 0.023 0.026 0.015 0.047 0.010 0.045 0.220 0.090 0.078 0.021 0.021 0.013 0.030 0.028 0.018 0.020 0.012 0.008 0.019 0.001 nd 0.016 0.022 0.009 0.014 0.006 0.011 0.008 0.012 0.000 0.019 0.012 0.016 0.034 0.022 0.006 0.035 0.009 0.009 0.042 0.015 0.013 0.019 0.018 0.006 0.022 0.007 0.005 0.167 0.015 0.003 0.225 0.084 0.007 0.084 0.094 0.049 0.070 0.044 0.030 0.042 0.015 0.006 0.015 0.012 0.013 0.056 0.039 0.009 0.046 0.017 0.004 0.040 0.013 0.004 0.040 0.024 0.005 0.026 0.004 0.001 0.011 0.003 0.002 0.010 0.005 0.004 0.043 0.006 0.006 nd nd nd 0.007 0.010 0.004 0.000 0.000 0.002 0.013 0.011 0.007 0.033 0.021 0.002 0.010 0.010 0.005 0.154 0.015 0.009 0.003 0.014 0.006 0.002 0.007 0.007 0.012 0.008 0.008 0.007 0.006 0.004 0.001 0.006 0.009 0.009 0.020 nd 0.008 0.009 0.007 0.007 0.003 0.003 0.013 0.000 0.011 0.011 0.009 0.007 0.000 0.008 0.005 3.7 4.0 2.8 14.1 5.5 6.4 8.2 7.0 4.0 4.8 8.6 3.6 6.0 8.8 16.0 4.4 7.2 7.2 5.4 13.0 7.2 13.6 137.8 9.4 36.0 7.8 1.4 11.3 8.0 8.0 13.2 9.9 9.5 6.9 2.9 4.3 3.1 3.1 5.7 7.0 8.6 6.7 10.3 13.7 13.0 9.7 2.1 0.7 3.9 5.9 5.3 7.0 10.0 12.3 58.3 56.2 55.0 32.4 32.9 33.8 31.6 31.4 32.4 60.2 55.3 47.0 70.7 59.6 50.9 77.5 71.3 55.0 69.8 65.0 63.7 34.5 36.2 49.4 35.7 34.7 32.5 41.1 41.4 42.4 40.5 66.9 62.2 38.3 36.4 28.8 53.3 50.3 43.9 52.0 55.5 56.4 54.4 50.3 40.9 50.2 50.9 40.8 77.9 73.4 71.0 52.4 51.7 75.6 86 pH nd nd nd 8.5 8.6 8.5 8.3 8.1 8.5 8.2 8.4 8.2 8.0 8.6 8.5 8.1 8.8 8.6 8.1 8.8 8.7 8.3 8.9 8.7 8.4 8.6 8.8 7.1 8.2 8.0 8.5 8.5 8.5 8.5 8.6 8.8 7.9 7.8 7.9 8.2 8.5 8.3 8.1 8.1 8.4 8.7 8.4 8.6 7.7 7.7 7.8 8.0 8.3 8.4 Sampling Date Transect TP1 TDP PP SRP DOP TSS Ca (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) 12/20/2011 A 0.074 0.057 0.017 0.000 0.057 5.5 59.8 12/20/2011 B 0.042 0.028 0.014 0.016 0.012 6.8 54.9 12/20/2011 C 0.021 0.018 0.003 0.004 0.015 4.8 54.8 1/11/2012 A 0.023 0.015 0.008 0.006 0.009 4.7 63.4 1/11/2012 B 0.032 0.017 0.015 0.011 0.006 4.2 62.5 1/11/2012 C 0.049 0.031 0.018 0.027 0.004 3.3 74.3 1/25/2012 A 0.073 0.040 0.033 0.036 0.004 7.3 54.9 1/25/2012 B 0.045 0.019 0.026 0.018 0.001 5.3 51.8 1/25/2012 C 0.020 0.006 0.014 0.005 0.001 4.6 53.7 2/8/2012 A 0.091 0.057 0.034 0.057 0.000 7.8 65.3 2/8/2012 B 0.073 0.045 0.028 0.045 0.000 8.0 57.2 2/8/2012 C 0.028 0.016 0.012 0.011 0.006 7.1 57.0 2/27/2012 A 0.064 0.043 0.021 0.038 0.005 6.0 52.4 2/27/2012 B 0.032 0.020 0.012 0.007 0.013 4.9 66.2 2/27/2012 C 0.026 0.015 0.011 0.004 0.011 4.8 58.1 3/12/2012 A 0.078 0.053 0.025 0.049 0.004 8.5 75.3 3/12/2012 B 0.076 0.057 0.019 0.052 0.005 7.7 79.5 3/12/2012 C 0.046 0.031 0.015 0.025 0.006 6.2 71.1 3/28/2012 A 0.084 0.044 0.040 0.047 5.7 53.7 3/28/2012 B 0.029 0.021 0.008 0.011 0.010 4.3 51.4 3/28/2012 C 0.021 0.008 0.013 0.004 0.004 4.8 64.5 4/9/2012 A 0.087 0.052 0.035 0.051 0.001 9.8 53.5 4/9/2012 B 0.043 0.023 0.020 0.021 0.002 5.5 52.3 4/9/2012 C 0.018 0.008 0.010 0.003 0.005 4.1 49.7 4/23/2012 A 0.076 0.049 0.027 0.0423 0.007 8.6 64.7 4/23/2012 B 0.027 0.014 0.013 0.0063 0.008 5.6 46.2 4/23/2012 C 0.014 0.009 0.005 0.0023 0.007 4.5 39.3 1 TP=total-P; TDP=total dissolved-P; PP=particulate-P; SRP=soluble reactive-P; DOP=dissolved organic-P; TSS=total suspended solids; Ca=total dissolved calcium. nd = not determined. 87 pH 8.1 8.6 8.5 8.1 8.1 8.5 8.0 8.3 8.4 7.7 7.8 8.0 7.9 8.4 8.3 7.6 7.6 7.7 7.9 8.3 8.5 7.8 8.1 8.6 8.0 8.2 8.6 Table A7. Detailed water quality parameters of the grab canal water samples collected from Farm 1813 from November 2010 through April 2012. Sampling Date 11/9/2010 11/9/2010 11/9/2010 11/23/2010 11/23/2010 11/23/2010 1/4/2011 1/4/2011 1/4/2011 1/19/2011 1/19/2011 1/19/2011 2/2/2011 2/2/2011 2/2/2011 2/10/2011 2/10/2011 2/10/2011 2/23/2011 2/23/2011 2/23/2011 3/2/2011 3/2/2011 3/2/2011 3/16/2011 3/16/2011 3/16/2011 3/30/2011 3/30/2011 3/30/2011 4/13/2011 4/13/2011 4/13/2011 4/25/2011 4/25/2011 4/25/2011 5/4/2011 5/4/2011 5/4/2011 5/19/2011 5/19/2011 5/19/2011 6/7/2011 6/7/2011 6/7/2011 6/23/2011 6/23/2011 6/23/2011 8/17/2011 8/17/2011 8/17/2011 12/6/2011 12/6/2011 12/6/2011 Transect TP1 TDP PP SRP DOP TSS Ca (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) A B C A B C A B C A B C A B C A B C A B C A B C A B C A B C A B C A B C A B C A B C A B C A B C A B C A B C nd nd nd 0.070 0.065 0.047 0.039 0.063 0.043 0.068 0.064 0.067 0.108 0.106 0.141 0.154 0.126 0.082 0.132 0.113 0.091 0.101 0.109 0.088 0.060 0.073 0.057 0.076 0.072 0.114 0.040 0.044 0.034 0.042 0.044 0.040 0.069 0.095 0.048 0.046 0.042 0.045 0.048 0.041 0.028 0.075 0.085 0.079 0.048 0.040 0.041 0.081 0.086 0.069 nd nd nd 0.049 0.033 0.016 0.017 0.015 0.020 0.060 0.040 0.016 0.060 0.040 0.073 0.118 0.041 0.082 0.066 0.061 0.033 0.071 0.041 0.071 0.018 0.017 0.021 0.021 0.016 0.051 0.013 0.013 0.016 0.019 0.017 0.017 0.029 0.035 0.013 0.013 0.011 0.014 0.017 0.015 0.010 0.056 0.055 0.046 0.017 nd 0.017 0.033 0.035 0.027 nd nd nd 0.021 0.032 0.031 0.022 0.048 0.023 0.008 0.024 0.051 0.048 0.066 0.068 0.036 0.085 0.000 0.066 0.052 0.058 0.030 0.068 0.017 0.042 0.056 0.036 0.055 0.056 0.063 0.027 0.031 0.018 0.023 0.027 0.023 0.040 0.060 0.035 0.033 0.031 0.031 0.031 0.026 0.018 0.019 0.030 0.033 0.031 nd 0.024 0.048 0.051 0.042 0.021 0.016 0.016 0.043 0.028 0.010 0.006 0.007 0.015 0.031 0.016 0.009 0.055 0.032 0.061 0.104 0.048 0.017 nd 0.048 0.017 0.048 nd 0.009 nd 0.005 0.004 0.021 0.004 0.036 0.009 0.005 0.003 nd nd 0.005 0.021 0.053 0.005 0.003 0.052 0.006 0.006 0.014 0.001 0.013 0.016 0.009 0.005 0.007 0.005 0.024 0.021 0.009 nd nd nd 0.006 0.005 0.006 0.011 0.008 0.005 0.030 0.024 0.007 0.006 0.008 0.012 0.014 0.000 0.065 nd 0.013 0.016 0.023 nd 0.062 nd 0.012 0.018 0.000 0.012 0.015 0.004 0.008 0.013 nd nd 0.012 0.008 0.008 0.010 0.009 0.011 0.002 0.009 0.043 0.039 0.037 0.012 nd 0.012 0.009 0.014 0.018 6.0 6.6 4.3 16.8 13.3 9.3 15.0 16.0 13.6 4.4 5.0 9.6 5.8 10.4 11.0 3.4 9.8 7.8 7.0 5.0 12.4 6.4 14.0 18.2 9.6 17.8 7.2 24.8 22.2 22.0 9.2 10.6 9.3 6.3 8.0 5.0 7.7 9.7 3.6 6.2 8.0 6.8 7.7 10.7 4.9 7.2 7.3 3.9 11.2 19.9 17.5 11.9 6.5 12.0 82.8 80.9 85.3 33.8 42.8 61.5 77.2 74.8 75.6 90.6 87.0 84.8 86.3 81.2 79.2 82.5 87.4 87.6 83.8 80.6 81.8 59.6 62.1 68.2 44.8 44.5 53.9 52.3 53.2 57.4 77.1 75.2 67.9 39.4 40.0 43.9 57.0 54.9 56.3 59.5 57.5 70.8 54.2 55.3 59.3 54.7 54.9 57.3 86.9 88.2 96.6 98.5 101.5 111.8 88 pH nd nd nd 8.1 8.1 8.3 7.9 8.2 7.8 7.8 7.9 8.1 8.0 8.3 8.2 8.0 8.3 8.3 8.6 8.6 8.7 8.5 8.5 8.5 8.5 8.6 8.6 8.1 8.0 8.0 8.4 8.4 8.4 8.7 8.7 8.5 7.9 8.3 8.3 8.8 8.8 8.5 8.6 8.5 8.5 8.2 8.2 8.3 7.8 7.9 7.9 8.0 8.2 8.3 Sampling Date Transect TP1 TDP PP SRP DOP TSS Ca (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) 12/20/2011 A 0.111 0.060 0.051 0.063 10.5 98.5 12/20/2011 B 0.147 0.068 0.079 0.055 0.013 13.3 115.3 12/20/2011 C 0.154 0.091 0.063 0.080 0.011 18.2 118.5 1/11/2012 A 0.060 0.012 0.048 0.011 0.001 32.6 110.2 1/11/2012 B 0.089 0.014 0.075 0.012 0.003 29.0 114.7 1/11/2012 C 0.079 0.019 0.060 0.009 0.010 5.1 128.0 1/25/2012 A 0.068 0.021 0.047 0.033 7.1 56.5 1/25/2012 B 0.068 0.027 0.041 0.033 3.1 55.8 1/25/2012 C 0.067 0.010 0.057 0.009 0.001 8.2 76.8 2/8/2012 A 0.069 0.038 0.031 0.036 0.002 8.0 84.0 2/8/2012 B 0.073 0.044 0.029 0.041 0.003 9.6 62.0 2/8/2012 C 0.068 0.021 0.047 0.012 0.009 19.3 60.8 2/27/2012 A 0.052 0.024 0.028 0.019 0.005 7.1 69.3 2/27/2012 B 0.043 0.015 0.028 0.005 0.010 5.7 74.7 2/27/2012 C 0.038 0.016 0.022 0.003 0.014 6.8 72.6 3/12/2012 A 0.242 0.013 0.229 0.004 0.009 4.5 66.9 3/12/2012 B 0.058 0.015 0.043 0.005 0.010 4.0 67.6 3/12/2012 C 0.039 0.014 0.025 0.003 0.011 4.9 69.8 3/28/2012 A 0.081 0.035 0.046 0.033 0.002 9.8 53.8 3/28/2012 B 0.071 0.031 0.040 0.031 0.000 9.5 55.2 3/28/2012 C 0.051 0.014 0.037 0.004 0.010 7.1 81.7 4/9/2012 A 0.113 0.052 0.061 0.054 16.1 52.2 4/9/2012 B 0.101 0.044 0.057 0.047 14.2 52.4 4/9/2012 C 0.056 0.019 0.037 0.012 0.007 10.7 56.9 4/23/2012 A 0.064 0.021 0.043 0.0187 0.002 11.8 46.8 4/23/2012 B 0.059 0.019 0.040 0.0141 0.005 9.5 46.7 4/23/2012 C 0.044 0.014 0.030 0.0033 0.011 8.1 51.4 1 TP=total-P; TDP=total dissolved-P; PP=particulate-P; SRP=soluble reactive-P; DOP=dissolved organic-P; TSS=total suspended solids; Ca=total dissolved calcium. nd = not determined. 89 pH 7.5 7.8 7.6 8.0 8.0 8.2 7.9 7.9 8.0 7.8 7.8 7.9 8.2 8.4 8.3 8.7 8.5 8.2 8.1 8.1 8.3 8.0 8.0 8.2 8.2 8.2 8.3 Table A8. Detailed water quality parameters of the grab canal water samples collected from Farm 6117 from November 2010 through April 2012. Sampling Date 11/9/2010 11/9/2010 11/9/2010 11/23/2010 11/23/2010 11/23/2010 1/4/2011 1/4/2011 1/4/2011 1/19/2011 1/19/2011 1/19/2011 2/2/2011 2/2/2011 2/2/2011 2/10/2011 2/10/2011 2/10/2011 2/23/2011 2/23/2011 2/23/2011 3/2/2011 3/2/2011 3/2/2011 3/16/2011 3/16/2011 3/16/2011 3/30/2011 3/30/2011 3/30/2011 4/13/2011 4/13/2011 4/13/2011 4/25/2011 4/25/2011 4/25/2011 5/4/2011 5/4/2011 5/4/2011 5/19/2011 5/19/2011 5/19/2011 6/7/2011 6/7/2011 6/7/2011 6/22/2011 6/22/2011 6/22/2011 8/18/2011 8/18/2011 8/18/2011 12/6/2011 12/6/2011 12/6/2011 Transect TP1 TDP PP SRP DOP TSS Ca (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) A B C A B C A B C A B C A B C A B C A B C A B C A B C A B C A B C A B C A B C A B C A B C A B C A B C A B C nd nd nd 0.078 0.075 0.124 0.258 0.235 0.193 0.120 0.113 0.084 0.092 0.117 0.078 0.088 0.092 0.088 0.097 0.213 0.134 0.161 0.082 0.127 0.095 0.094 0.074 0.084 0.090 0.085 0.081 0.117 0.074 0.072 0.065 0.073 0.098 0.054 0.054 0.073 0.095 0.058 0.076 0.061 0.101 0.081 0.083 0.066 0.107 0.100 0.087 0.096 0.074 0.090 nd nd nd 0.046 0.032 0.100 0.160 0.156 0.138 0.081 0.064 0.037 0.081 0.064 0.037 0.061 0.047 0.023 0.052 0.046 0.022 0.060 0.055 0.055 0.056 0.052 0.027 0.035 0.026 0.028 0.056 0.071 0.025 0.048 0.033 0.023 nd 0.028 0.014 0.022 0.032 0.018 0.025 0.020 0.024 0.074 0.072 0.059 0.026 0.022 0.024 0.073 0.037 0.040 nd nd nd 0.032 0.043 0.024 0.098 0.079 0.055 0.039 0.049 0.047 0.011 0.053 0.041 0.027 0.045 0.065 0.045 0.167 0.112 0.101 0.027 0.072 0.039 0.042 0.047 0.049 0.064 0.057 0.025 0.046 0.049 0.024 0.032 0.050 nd 0.026 0.040 0.051 0.063 0.040 0.051 0.041 0.077 0.007 0.011 0.007 0.081 0.078 0.063 0.023 0.037 0.050 0.060 0.034 0.016 0.037 0.034 0.047 0.076 0.106 0.120 nd nd 0.035 0.051 nd 0.014 0.051 nd 0.014 0.045 0.041 0.009 0.039 0.033 0.010 0.046 0.037 0.012 0.024 0.012 0.013 0.043 0.050 0.005 0.036 0.020 0.005 0.026 0.018 0.005 0.006 0.015 0.005 0.009 0.004 0.004 nd nd nd 0.007 0.008 0.006 0.062 0.024 0.012 nd nd nd 0.009 0.000 0.053 0.085 0.050 0.018 nd nd 0.002 0.030 nd 0.024 0.010 nd 0.010 0.007 0.005 0.013 0.021 0.022 0.045 0.010 0.016 0.015 0.011 0.014 0.015 0.013 0.021 0.020 0.012 0.013 0.018 nd 0.010 0.009 0.016 0.017 0.014 0.016 0.016 0.020 nd nd nd 0.019 0.014 0.018 0.011 0.013 0.028 0.5 7.4 6.9 10.8 9.9 5.2 12.6 11.8 18.4 4.4 15.6 4.0 9.8 10.2 4.8 7.6 10.2 12.0 11.6 12.4 36.4 6.6 9.2 44.4 6.2 2.2 15.4 19.2 20.4 10.4 8.5 7.7 8.2 7.9 10.6 21.9 7.2 5.7 12.4 12.3 15.1 11.3 13.2 12.0 23.4 8.7 13.7 10.7 7.1 16.3 16.3 9.8 11.5 14.8 73.7 70.6 78.4 78.8 79.9 76.7 83.7 90.1 114.9 71.0 71.2 83.5 71.2 73.2 77.0 73.5 73.9 77.4 67.4 71.2 73.0 59.2 62.0 66.6 38.6 35.2 33.7 51.9 49.5 46.4 62.5 62.5 63.5 39.2 36.8 50.6 55.1 58.0 64.7 77.3 70.9 71.2 82.5 82.2 83.2 67.5 65.9 58.7 102.5 96.1 96.1 99.2 99.0 110.8 90 pH nd nd nd 8.0 8.2 8.0 7.7 7.6 7.7 7.7 7.6 8.1 8.0 7.9 8.3 7.6 7.8 8.1 7.7 7.7 8.2 7.4 7.6 8.0 7.9 7.9 8.2 7.5 7.7 7.7 7.7 7.8 7.5 7.8 8.2 8.3 8.7 8.8 8.7 8.4 7.5 8.0 7.9 8.2 8.2 7.8 8.0 8.3 7.2 7.4 7.4 7.6 8.0 8.3 Sampling Date Transect TP1 TDP PP SRP DOP TSS Ca (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) 12/20/2011 A 0.110 0.077 0.033 0.064 0.013 6.4 95.8 12/20/2011 B 0.108 0.081 0.027 0.072 0.009 8.5 96.3 12/20/2011 C 0.084 0.031 0.053 0.010 0.022 13.3 96.0 1/11/2012 A 0.133 0.089 0.044 0.093 9.3 101.6 1/11/2012 B 0.104 0.065 0.039 0.068 25.8 102.1 1/11/2012 C 0.092 0.028 0.064 0.016 0.012 25.5 102.8 1/25/2012 A 0.066 0.039 0.027 0.042 5.2 54.2 1/25/2012 B 0.066 0.033 0.033 0.038 4.5 54.0 1/25/2012 C 0.053 0.029 0.024 0.023 0.006 8.3 56.4 2/8/2012 A 0.163 0.138 0.025 0.124 0.014 7.2 83.7 2/8/2012 B 0.129 0.116 0.013 0.094 0.022 9.4 81.2 2/8/2012 C 0.087 0.028 0.059 0.007 0.021 16.6 84.5 2/27/2012 A 0.055 0.038 0.017 0.030 0.008 6.6 74.4 2/27/2012 B 0.056 0.034 0.022 0.026 0.008 7.2 77.2 2/27/2012 C 0.045 0.023 0.022 0.012 0.011 14.2 79.5 3/12/2012 A 0.091 0.031 0.060 0.019 0.012 13.8 72.0 3/12/2012 B 0.075 0.033 0.042 0.021 0.012 32.2 70.8 3/12/2012 C 0.090 0.035 0.055 0.022 0.013 27.7 75.0 3/28/2012 A 0.069 0.041 0.028 0.042 4.6 54.9 3/28/2012 B 0.068 0.041 0.027 0.040 0.001 4.5 53.6 3/28/2012 C 0.069 0.036 0.033 0.036 0.000 18.3 53.7 4/9/2012 A 0.060 0.032 0.028 0.030 0.002 54.1 4/9/2012 B 0.061 0.036 0.025 0.033 0.003 8.0 57.8 4/9/2012 C 0.067 0.028 0.039 0.025 0.003 14.8 55.4 4/23/2012 A 0.039 0.016 0.023 0.0107 0.005 6.0 57.9 4/23/2012 B 0.038 0.014 0.024 0.0108 0.003 8.7 53.5 4/23/2012 C 0.054 0.022 0.032 0.0171 0.005 10.6 53.7 1 TP=total-P; TDP=total dissolved-P; PP=particulate-P; SRP=soluble reactive-P; DOP=dissolved organic-P; TSS=total suspended solids; Ca=total dissolved calcium. nd = not determined. 91 pH 7.5 7.7 8.1 7.5 7.7 8.0 7.7 7.8 7.8 7.4 7.6 8.0 7.8 7.9 8.0 7.7 7.6 7.7 7.9 7.9 7.8 7.5 7.6 7.8 7.9 7.7 7.9 Table A9. Detailed water quality parameters of the grab canal water samples collected from Farm 3102 from November 2010 through April 2012. Sampling Date 11/9/2010 11/9/2010 11/9/2010 11/23/2010 11/23/2010 11/23/2010 1/4/2011 1/4/2011 1/4/2011 1/18/2011 1/18/2011 1/18/2011 2/2/2011 2/2/2011 2/2/2011 2/9/2011 2/9/2011 2/9/2011 2/23/2011 2/23/2011 2/23/2011 3/2/2011 3/2/2011 3/2/2011 3/16/2011 3/16/2011 3/16/2011 3/30/2011 3/30/2011 3/30/2011 4/13/2011 4/13/2011 4/13/2011 4/25/2011 4/25/2011 4/25/2011 5/4/2011 5/4/2011 5/4/2011 5/19/2011 5/19/2011 5/19/2011 6/7/2011 6/7/2011 6/7/2011 6/22/2011 6/22/2011 6/22/2011 8/17/2011 8/17/2011 8/17/2011 12/6/2011 12/6/2011 12/6/2011 Transect TP1 TDP PP SRP DOP TSS Ca (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) A B C A B C A B C A B C A B C A B C A B C A B C A B C A B C A B C A B C A B C A B C A B C A B C A B C A B C nd nd nd 0.036 0.063 0.047 0.025 0.034 0.025 0.128 0.116 0.053 0.110 0.216 0.118 0.097 0.099 0.106 0.055 0.122 0.090 0.050 0.058 0.092 0.297 0.340 0.341 0.127 0.141 0.115 0.058 0.053 0.057 0.028 0.041 0.044 0.066 0.060 0.065 0.030 0.035 0.039 0.245 0.049 0.043 0.157 0.123 0.130 0.319 0.163 0.199 0.088 0.083 0.075 nd nd nd 0.030 0.055 0.047 0.018 0.015 0.016 0.027 0.059 0.042 0.097 0.214 0.099 0.087 0.080 0.087 0.046 0.099 0.059 0.043 0.046 0.088 0.055 0.059 0.096 0.107 0.120 0.092 0.045 0.041 0.040 0.023 0.021 0.025 0.060 0.054 nd 0.019 0.022 0.027 0.029 0.024 0.029 0.132 0.093 0.105 0.291 0.141 0.168 0.080 0.073 0.064 nd nd nd 0.006 0.008 0.000 0.007 0.019 0.009 0.101 0.057 0.011 0.013 0.002 0.019 0.010 0.019 0.019 0.009 0.023 0.031 0.007 0.012 0.004 0.242 0.281 0.245 0.020 0.021 0.023 0.013 0.012 0.017 0.005 0.020 0.019 0.006 0.006 nd 0.011 0.013 0.012 0.216 0.025 0.014 0.025 0.030 0.025 0.028 0.022 0.031 0.008 0.010 0.011 0.060 0.038 0.040 0.023 0.043 0.041 0.024 0.013 0.015 nd 0.036 0.031 0.087 0.194 0.085 0.077 0.079 0.086 nd 0.087 0.054 0.029 0.043 0.053 0.044 0.053 0.080 nd 0.121 0.030 nd 0.030 0.028 0.017 nd 0.014 0.048 0.034 0.045 0.011 0.038 0.013 0.015 0.014 0.008 0.107 0.017 0.075 0.269 0.131 0.149 0.079 0.072 0.063 nd nd nd 0.007 0.012 0.006 0.000 0.002 0.001 nd 0.023 0.011 0.010 0.021 0.014 0.011 0.001 0.001 nd 0.012 0.005 0.014 0.003 0.035 0.011 0.006 0.016 nd 0.000 0.062 nd 0.011 0.012 0.006 nd 0.011 0.013 0.020 nd 0.008 nd 0.014 0.014 0.010 0.021 0.025 0.077 0.030 0.022 0.010 0.019 0.001 0.001 0.002 1.9 5.4 2.9 8.5 10.8 11.5 0.5 0.5 1.2 4.0 3.8 5.8 2.4 10.6 18.0 2.8 2.4 4.8 2.4 9.0 19.8 2.4 4.2 7.2 3.6 4.2 6.0 7.4 8.6 14.0 8.2 9.4 10.6 5.4 4.9 4.0 2.3 3.7 8.6 10.3 5.7 4.0 110.3 3.7 9.7 4.3 3.7 1.7 3.6 4.7 4.3 9.2 6.7 24.3 68.0 57.5 58.3 78.6 83.0 82.1 40.1 38.9 40.4 72.9 71.1 74.0 69.5 76.0 74.8 70.7 70.5 73.7 66.1 74.4 73.2 35.5 37.3 38.8 41.9 40.5 48.2 48.6 43.3 51.1 41.3 41.5 42.8 40.6 39.0 38.2 57.2 56.4 54.1 53.3 52.6 53.4 58.8 54.6 55.7 95.5 101.3 100.9 113.4 132.6 106.5 118.9 116.2 113.2 92 pH nd nd nd 8.1 8.4 8.4 8.1 8.2 8.1 7.6 8.4 8.1 7.6 8.0 8.0 8.0 8.1 8.1 7.8 8.2 8.2 8.0 8.1 8.0 7.7 8.2 8.0 7.5 7.6 7.7 7.8 7.8 7.7 7.4 8.1 8.0 8.0 7.8 7.8 7.4 7.8 7.6 7.2 7.6 7.7 7.2 7.5 7.5 6.9 7.0 7.0 8.0 8.0 8.0 Sampling Date Transect TP1 TDP PP SRP DOP TSS Ca (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) 12/20/2011 A 0.137 0.116 0.021 0.115 0.001 5.6 121.1 12/20/2011 B 0.041 0.030 0.011 0.027 0.003 3.4 122.9 12/20/2011 C 0.069 0.056 0.013 0.058 4.8 117.4 1/11/2012 A 0.081 0.085 nd 0.065 0.020 4.2 104.4 1/11/2012 B 0.049 0.033 0.016 0.032 0.001 6.0 114.2 1/11/2012 C 0.066 0.045 0.021 0.047 6.0 115.0 1/25/2012 A 0.103 0.092 0.011 0.075 0.017 5.1 99.6 1/25/2012 B 0.036 0.031 0.005 0.017 0.014 7.8 100.4 1/25/2012 C 0.052 0.029 0.023 0.030 9.5 122.1 2/8/2012 A 0.124 0.088 0.036 0.080 0.008 8.4 79.3 2/8/2012 B 0.056 0.041 0.015 0.017 0.024 3.8 81.2 2/8/2012 C 0.075 0.047 0.028 0.045 0.002 17.0 110.5 2/27/2012 A 0.142 0.106 0.036 0.087 0.019 6.0 113.7 2/27/2012 B 0.128 0.047 0.081 0.027 0.020 48.0 86.1 2/27/2012 C 0.049 0.041 0.008 0.025 0.016 4.9 87.2 3/12/2012 A 0.131 0.084 0.047 0.063 0.021 27.4 102.6 3/12/2012 B 0.181 0.023 0.158 0.008 0.015 27.0 84.1 3/12/2012 C 0.111 0.070 0.041 0.051 0.019 26.3 105.4 3/28/2012 A 0.065 0.046 0.019 0.045 0.001 3.4 56.9 3/28/2012 B 0.070 0.048 0.022 0.048 0.000 8.9 55.4 3/28/2012 C 0.055 0.036 0.019 0.036 0.000 3.1 57.0 4/9/2012 A 0.074 0.051 0.023 0.042 0.009 9.4 56.6 4/9/2012 B 0.030 0.021 0.009 0.013 0.008 5.6 68.4 4/9/2012 C 0.080 0.050 0.030 0.036 0.014 16.6 65.2 4/23/2012 A 0.172 0.159 0.013 0.1510 0.008 9.2 89.5 4/23/2012 B 0.249 0.222 0.027 0.2145 0.008 9.4 88.6 4/23/2012 C 0.189 0.176 0.013 0.1688 0.007 5.1 91.6 1 TP=total-P; TDP=total dissolved-P; PP=particulate-P; SRP=soluble reactive-P; DOP=dissolved organic-P; TSS=total suspended solids; Ca=total dissolved calcium. nd = not determined. 93 pH 7.6 7.7 8.0 7.5 7.7 7.8 7.7 7.7 7.9 7.4 7.2 7.7 7.8 7.4 7.4 7.8 7.1 7.7 7.7 7.8 7.6 7.5 7.1 7.6 7.5 7.5 7.7 Table A10. Detailed water quality parameters of the grab canal water samples collected from Farm 3103 from November 2010 through April 2012. Sampling Date 11/9/2010 11/9/2010 11/9/2010 11/23/2010 11/23/2010 11/23/2010 1/4/2011 1/4/2011 1/4/2011 1/18/2011 1/18/2011 1/18/2011 2/2/2011 2/2/2011 2/2/2011 2/9/2011 2/9/2011 2/9/2011 2/23/2011 2/23/2011 2/23/2011 3/2/2011 3/2/2011 3/2/2011 3/16/2011 3/16/2011 3/16/2011 3/30/2011 3/30/2011 3/30/2011 4/13/2011 4/13/2011 4/13/2011 4/25/2011 4/25/2011 4/25/2011 5/4/2011 5/4/2011 5/4/2011 5/19/2011 5/19/2011 5/19/2011 6/7/2011 6/7/2011 6/7/2011 6/22/2011 6/22/2011 6/22/2011 8/17/2011 8/17/2011 8/17/2011 12/6/2011 12/6/2011 12/6/2011 Transect TP1 TDP PP SRP DOP TSS Ca (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) A B C A B C A B C A B C A B C A B C A B C A B C A B C A B C A B C A B C A B C A B C A B C A B C A B C A B C nd nd nd 0.051 0.034 0.024 0.072 0.049 0.042 0.073 0.075 0.044 0.090 0.076 0.081 0.108 0.083 0.066 0.047 0.044 0.042 0.067 0.047 0.044 0.071 0.067 0.052 0.163 0.170 0.080 0.079 0.077 0.057 0.042 0.039 0.042 0.058 0.073 0.070 0.057 0.078 0.074 0.045 0.075 0.059 0.125 0.143 0.126 0.098 0.072 0.125 0.078 0.062 0.075 nd nd nd 0.038 0.016 0.014 0.058 0.023 0.019 nd 0.061 0.036 0.076 0.063 0.041 0.076 0.063 0.041 0.010 0.010 0.015 0.020 0.020 0.040 0.049 0.039 0.028 0.135 0.130 0.040 0.018 0.019 0.019 0.020 0.018 0.021 0.028 0.051 0.062 0.016 0.059 0.043 0.018 0.025 0.015 0.036 0.041 0.030 0.066 0.050 0.098 0.041 0.037 0.029 nd nd nd 0.013 0.018 0.010 0.014 0.026 0.023 nd 0.014 0.008 0.014 0.013 0.040 0.032 0.020 0.025 0.037 0.034 0.027 0.047 0.027 0.004 0.022 0.028 0.024 0.028 0.040 0.040 0.061 0.058 0.038 0.022 0.021 0.021 0.030 0.022 0.008 0.041 0.019 0.031 0.027 0.050 0.044 0.089 0.102 0.096 0.032 0.022 0.027 0.037 0.025 0.046 0.042 0.018 0.016 0.038 0.015 0.014 0.028 0.018 0.013 0.011 0.027 0.015 0.010 0.047 nd 0.052 0.061 0.037 0.010 0.009 0.011 0.015 0.012 0.014 0.038 0.018 0.008 0.096 0.053 nd 0.012 0.012 0.010 0.008 0.008 0.009 0.013 0.036 0.049 0.007 0.015 0.023 0.007 0.014 0.009 0.013 0.016 0.014 0.049 0.042 0.088 0.034 0.030 0.026 nd nd nd 0.000 0.001 0.000 0.031 0.006 0.006 nd 0.035 0.021 0.066 0.016 nd 0.024 0.002 0.004 0.000 0.001 0.004 0.005 0.008 0.026 0.011 0.021 0.021 0.039 0.078 nd 0.006 0.007 0.009 0.012 0.010 0.013 0.015 0.015 0.013 0.009 0.044 0.020 0.011 0.011 0.006 0.023 0.025 0.016 0.017 0.008 0.010 0.007 0.007 0.003 2.6 2.8 4.6 4.3 4.7 5.8 1.6 2.0 1.0 2.8 2.8 3.2 7.6 4.8 2.4 7.6 4.8 2.4 21.0 8.2 5.4 18.2 7.4 4.0 13.8 6.6 2.0 7.4 6.2 4.8 13.5 12.3 9.6 9.3 6.4 4.2 7.0 3.1 3.3 1.9 3.0 3.4 10.3 11.1 4.1 14.0 0.4 7.6 3.2 3.1 5.2 6.5 6.5 5.8 87.9 84.3 88.0 61.4 55.7 72.1 61.6 62.5 62.4 63.8 70.3 72.8 70.7 82.0 87.1 71.9 72.0 72.3 65.2 65.5 67.1 61.0 63.0 65.2 61.4 64.2 59.6 78.9 72.2 74.6 61.9 62.9 65.6 39.6 38.2 39.1 54.1 56.6 56.2 66.9 72.3 70.2 111.4 118.4 135.0 129.3 144.5 135.4 108.0 108.7 111.8 122.6 124.2 109.4 94 pH nd nd nd 7.7 8.1 8.2 7.8 8.1 8.2 7.7 8.1 8.3 7.6 7.8 7.8 8.1 8.1 8.1 7.9 8.3 8.3 8.1 8.3 8.2 7.7 8.0 8.2 7.6 7.6 7.6 7.7 8.0 8.1 7.9 8.1 8.2 7.8 7.8 7.8 7.8 7.7 7.6 7.5 7.5 7.3 7.8 7.7 7.6 7.4 7.3 7.3 8.0 8.1 7.8 Sampling Date Transect TP1 TDP PP SRP DOP TSS Ca (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) 12/20/2011 A 0.131 0.118 0.013 0.111 0.007 6.8 116.1 12/20/2011 B 0.143 0.120 0.023 0.110 0.010 3.2 114.6 12/20/2011 C 0.046 0.038 0.008 0.032 0.006 3.4 115.4 1/11/2012 A 0.056 0.046 0.010 0.036 0.010 2.2 117.8 1/11/2012 B 0.042 0.034 0.008 0.032 0.003 3.8 117.7 1/11/2012 C 0.042 0.025 0.017 0.024 0.002 4.2 115.8 1/25/2012 A 0.078 0.054 0.024 0.042 0.013 8.0 116.2 1/25/2012 B 0.046 0.037 0.009 0.030 0.007 8.2 120.0 1/25/2012 C 0.031 0.024 0.007 0.019 0.005 4.3 117.9 2/8/2012 A 0.137 0.107 0.030 0.096 0.011 24.0 120.0 2/8/2012 B 0.093 0.071 0.022 0.060 0.011 7.8 117.4 2/8/2012 C 0.045 0.033 0.012 0.024 0.009 10.0 117.1 2/27/2012 A 0.062 0.049 0.013 0.035 0.014 3.5 113.3 2/27/2012 B 0.051 0.040 0.011 0.026 0.014 4.0 116.2 2/27/2012 C 0.048 0.024 0.024 0.012 0.012 11.7 124.4 3/12/2012 A 0.134 0.054 0.080 0.030 0.024 22.4 118.5 3/12/2012 B 0.050 0.042 0.008 0.014 0.029 9.3 114.4 3/12/2012 C 0.052 0.038 0.014 0.016 0.022 7.0 122.1 3/28/2012 A 0.073 0.037 0.036 0.019 0.018 4.1 113.4 3/28/2012 B 0.087 0.049 0.038 0.027 0.023 4.8 123.6 3/28/2012 C 0.069 0.043 0.026 0.018 0.025 4.8 140.8 4/9/2012 A 0.054 0.057 nd 0.013 0.044 9.8 93.4 4/9/2012 B 0.044 0.022 0.022 0.008 0.014 5.3 78.6 4/9/2012 C 0.040 0.016 0.024 0.004 0.012 9.6 62.6 4/23/2012 A 0.220 0.183 0.037 0.1872 4.8 109.6 4/23/2012 B 0.348 0.322 0.026 0.3183 0.004 6.5 106.4 4/23/2012 C 0.184 0.173 0.011 0.1631 0.010 4.3 109.2 1 TP=total-P; TDP=total dissolved-P; PP=particulate-P; SRP=soluble reactive-P; DOP=dissolved organic-P; TSS=total suspended solids; Ca=total dissolved calcium. nd = not determined. 95 pH 7.6 7.7 7.6 7.5 7.7 7.7 7.6 7.8 7.7 7.4 7.6 7.6 7.6 7.8 7.6 7.5 7.7 7.7 7.8 7.8 7.8 7.6 7.6 7.7 7.5 7.5 7.5 Table A11. Detailed water quality parameters of the grab canal water samples collected from Farm 4701 from November 2010 through April 2012. Sampling Date 11/9/2010 11/9/2010 11/9/2010 11/23/2010 11/23/2010 11/23/2010 1/4/2011 1/4/2011 1/4/2011 1/18/2011 1/18/2011 1/18/2011 2/2/2011 2/2/2011 2/2/2011 2/9/2011 2/9/2011 2/9/2011 2/23/2011 2/23/2011 2/23/2011 3/2/2011 3/2/2011 3/2/2011 3/16/2011 3/16/2011 3/16/2011 3/30/2011 3/30/2011 3/30/2011 4/13/2011 4/13/2011 4/13/2011 4/25/2011 4/25/2011 4/25/2011 5/4/2011 5/4/2011 5/4/2011 5/19/2011 5/19/2011 5/19/2011 6/7/2011 6/7/2011 6/7/2011 6/22/2011 6/22/2011 6/22/2011 8/17/2011 8/17/2011 8/17/2011 12/6/2011 12/6/2011 12/6/2011 Transect TP1 TDP PP SRP DOP TSS Ca (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) A B C A B C A B C A B C A B C A C B A B C A B C A B C A B C A B C A B C A B C A B C A B C A B C A B C A B C nd nd nd 0.045 0.036 0.040 0.081 0.069 0.111 0.035 0.030 0.031 0.024 0.018 0.028 0.032 0.040 0.027 0.033 0.039 0.025 0.045 0.044 0.051 0.149 0.131 0.132 0.018 0.020 0.021 0.038 0.040 0.043 0.040 0.035 0.026 0.032 0.024 0.023 0.038 0.027 0.031 0.023 0.029 0.031 0.028 0.075 0.080 0.031 0.030 0.025 0.041 0.040 0.045 nd nd nd 0.012 0.013 0.011 0.017 0.031 0.029 0.005 0.005 0.005 0.005 0.005 0.005 0.006 0.005 0.009 0.006 0.005 0.005 0.033 0.026 0.027 0.012 0.013 0.012 0.011 0.011 0.015 0.013 0.017 0.016 0.023 0.017 0.011 0.018 0.016 0.015 0.023 0.011 0.010 0.016 0.016 0.011 0.060 0.089 0.090 0.011 0.008 0.011 0.033 0.034 0.030 nd nd nd 0.033 0.023 0.029 0.064 0.038 0.082 0.030 0.025 0.026 0.019 0.013 0.023 0.026 0.035 0.018 0.027 0.034 0.020 0.012 0.018 0.024 0.137 0.118 0.120 0.007 0.009 0.006 0.025 0.023 0.027 0.017 0.018 0.015 0.014 0.008 0.008 0.015 0.016 0.021 0.007 0.013 0.020 0.028 0.075 0.080 0.020 0.022 0.014 0.008 0.006 0.015 0.015 0.008 0.011 0.009 0.008 0.007 0.001 0.002 0.003 0.005 0.004 0.005 0.006 0.004 0.005 0.005 0.004 0.007 0.007 0.005 0.006 0.006 0.007 0.010 0.002 0.003 0.003 0.003 0.003 0.013 0.004 nd 0.005 0.011 0.006 0.005 0.008 0.008 0.005 0.006 0.010 0.010 0.006 0.005 0.002 0.004 0.004 0.003 0.008 0.008 0.010 0.031 0.031 0.026 nd nd nd 0.003 0.005 0.004 0.016 0.029 0.026 0.000 0.001 0.000 0.000 0.001 0.000 0.001 0.001 0.003 0.000 0.000 0.000 0.027 0.020 0.018 0.010 0.010 0.009 0.008 0.008 0.002 0.009 nd 0.011 0.012 0.011 0.007 0.010 0.008 0.010 0.017 0.001 0.010 0.011 0.009 0.056 0.085 0.087 0.003 0.000 0.002 0.002 0.003 0.005 9.5 5.3 6.4 9.8 7.1 5.6 4.4 1.0 1.8 6.4 4.4 6.0 11.6 9.6 9.8 6.6 8.0 7.0 11.8 11.0 8.4 11.0 8.6 9.6 6.2 5.6 13.0 5.0 3.8 3.2 10.7 8.7 19.3 5.4 4.1 5.7 2.5 10.8 1.7 4.1 5.3 6.3 6.7 8.7 9.0 4.6 12.0 1.0 4.6 4.0 4.2 5.7 9.5 7.5 46.5 56.2 52.1 50.3 51.7 45.3 36.8 38.0 40.6 68.7 53.8 59.2 65.3 55.1 57.8 73.5 59.4 63.9 68.4 57.7 60.7 58.2 55.2 56.4 37.5 38.6 45.7 37.9 41.9 43.4 46.8 46.6 47.1 36.1 38.6 40.6 56.2 56.4 59.4 50.5 52.9 53.6 49.8 51.0 51.3 51.9 50.4 54.7 78.6 84.5 86.4 103.0 104.3 106.5 96 pH nd nd nd 8.5 8.5 8.4 8.7 8.5 8.3 7.6 7.7 7.6 8.1 8.2 8.2 8.1 8.3 8.3 8.1 8.2 8.2 8.1 8.3 8.3 8.1 8.1 8.1 7.7 7.9 7.9 7.9 7.8 8.1 7.8 7.9 8.0 7.7 7.6 8.3 8.1 8.0 8.1 8.1 8.0 7.9 8.2 8.0 8.0 7.9 7.9 7.9 8.1 8.0 8.1 Sampling Date Transect TP1 TDP PP SRP DOP TSS Ca (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) 12/20/2011 A 0.022 0.015 0.007 0.007 0.008 1.0 92.3 12/20/2011 B 0.045 0.019 0.026 0.007 0.012 10.5 98.7 12/20/2011 C 0.058 0.020 0.038 0.009 0.011 9.8 103.0 1/11/2012 A 0.019 0.014 0.005 0.006 0.008 3.8 97.4 1/11/2012 B 0.030 0.019 0.011 0.007 0.012 5.8 103.4 1/11/2012 C 0.029 0.012 0.017 0.006 0.006 10.0 102.3 1/25/2012 A 0.028 0.019 0.009 0.004 0.015 7.5 86.8 1/25/2012 B 0.034 0.016 0.018 0.004 0.012 4.8 85.5 1/25/2012 C 0.046 0.032 0.014 0.003 0.029 6.6 93.6 2/8/2012 A 0.028 0.014 0.014 0.003 0.011 7.4 66.2 2/8/2012 B 0.030 0.014 0.016 0.003 0.011 8.8 76.2 2/8/2012 C 0.036 0.018 0.018 0.003 0.015 6.2 84.9 2/27/2012 A 0.028 0.017 0.011 0.003 0.014 5.7 64.2 2/27/2012 B 0.034 0.020 0.014 0.003 0.017 6.3 69.5 2/27/2012 C 0.043 0.021 0.022 0.004 0.017 8.0 81.8 3/12/2012 A 0.024 0.012 0.012 0.003 0.009 9.6 64.6 3/12/2012 B 0.035 0.016 0.019 0.004 0.012 11.5 74.4 3/12/2012 C 0.045 0.017 0.028 0.004 0.013 10.0 75.4 3/28/2012 A 0.023 0.008 0.015 0.003 0.005 3.3 66.3 3/28/2012 B 0.026 0.011 0.015 0.004 0.008 3.2 67.3 3/28/2012 C 0.027 0.013 0.014 0.004 0.009 5.3 68.6 4/9/2012 A 0.036 0.022 0.014 0.014 0.008 10.2 57.1 4/9/2012 B 0.021 0.010 0.011 0.003 0.007 6.4 57.5 4/9/2012 C 0.026 0.012 0.014 0.003 0.009 5.6 63.4 4/23/2012 A 0.029 0.011 0.018 0.0089 0.002 4.3 61.0 4/23/2012 B 0.028 0.014 0.014 0.0119 0.002 7.7 63.7 4/23/2012 C 0.032 0.012 0.020 0.0119 0.000 5.7 66.3 1 TP=total-P; TDP=total dissolved-P; PP=particulate-P; SRP=soluble reactive-P; DOP=dissolved organic-P; TSS=total suspended solids; Ca=total dissolved calcium. nd = not determined. 97 pH 8.4 8.2 8.0 8.2 8.2 8.2 8.1 8.1 8.2 8.3 8.0 8.0 8.4 8.2 8.1 8.6 8.1 7.9 8.3 8.2 8.0 8.1 8.4 8.2 7.6 7.7 7.7 Table A12. Detailed water quality parameters of the grab canal water samples collected from Farm 4702 from November 2010 through April 2012. Sampling Date 11/9/2010 11/9/2010 11/9/2010 11/23/2010 11/23/2010 11/23/2010 1/4/2011 1/4/2011 1/4/2011 1/18/2011 1/18/2011 1/18/2011 2/2/2011 2/2/2011 2/2/2011 2/9/2011 2/9/2011 2/9/2011 2/23/2011 2/23/2011 2/23/2011 3/2/2011 3/2/2011 3/2/2011 3/16/2011 3/16/2011 3/16/2011 3/30/2011 3/30/2011 3/30/2011 4/13/2011 4/13/2011 4/13/2011 4/25/2011 4/25/2011 4/25/2011 5/4/2011 5/4/2011 5/4/2011 5/19/2011 5/19/2011 5/19/2011 6/7/2011 6/7/2011 6/7/2011 6/22/2011 6/22/2011 6/22/2011 8/17/2011 8/17/2011 8/17/2011 12/6/2011 12/6/2011 12/6/2011 Transect TP1 TDP PP SRP DOP TSS Ca (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) A B C A B C A B C A B C A B C A B C A B C A B C A B C A B C A B C A B C A B C A B C A B C A B C A B C A B C nd nd nd 0.028 0.033 0.057 0.040 0.020 0.021 0.063 0.070 0.059 0.046 0.065 0.053 0.077 0.066 0.065 0.050 0.046 0.039 0.067 0.047 0.048 0.103 0.104 0.102 0.037 0.034 0.025 0.041 0.041 0.033 0.040 0.035 0.032 0.029 0.032 0.030 0.037 0.040 0.029 0.035 0.033 0.032 0.046 0.043 0.036 0.034 0.031 0.030 0.067 0.072 0.072 nd nd nd 0.018 0.017 0.012 0.008 0.010 0.010 0.021 0.047 0.041 0.021 0.020 0.009 0.022 0.018 0.014 0.015 0.013 0.010 0.018 0.047 0.044 0.014 0.012 0.015 0.024 0.018 0.016 0.020 0.016 0.016 0.020 0.018 0.019 0.020 0.017 0.017 0.016 0.016 0.015 0.012 0.014 0.015 0.0510 0.061 0.054 0.015 0.011 0.010 0.061 0.063 0.065 nd nd nd 0.010 0.016 0.045 0.032 0.010 0.011 0.042 0.023 0.018 0.025 0.045 0.044 0.055 0.048 0.051 0.035 0.033 0.029 0.049 0.000 0.004 0.089 0.092 0.087 0.013 0.016 0.009 0.021 0.025 0.017 0.020 0.017 0.013 0.009 0.015 0.013 0.021 0.024 0.014 0.023 0.019 0.017 0.046 0.043 0.036 0.019 0.020 0.020 0.006 0.009 0.007 0.015 0.010 0.009 0.014 0.014 0.008 0.004 0.003 0.004 nd nd nd 0.004 0.003 0.004 0.004 0.007 0.006 0.041 0.041 0.014 0.010 0.010 0.013 0.011 0.011 0.015 0.014 0.013 0.021 0.014 0.013 0.004 0.006 0.006 0.021 0.013 0.014 0.006 0.005 0.005 0.011 0.010 0.007 0.005 0.006 0.007 0.011 0.005 0.005 0.007 0.009 0.008 0.016 0.032 0.013 0.013 0.013 0.012 0.060 0.050 0.062 0.006 0.000 0.007 0.010 0.000 0.009 0.007 0.003 0.000 0.000 0.000 0.000 0.033 0.031 0.010 0.006 0.009 0.003 0.005 0.002 0.014 0.011 0.011 0.009 0.008 0.012 0.015 0.011 0.010 0.005 0.011 0.011 0.005 0.005 0.008 0.035 0.029 0.041 0.002 0.002 0.013 0.003 2.7 3.4 3.0 3.9 5.9 6.0 1.0 1.0 0.5 1.8 1.0 2.2 31.4 2.6 4.0 1.8 2.2 2.2 2.6 2.8 7.6 9.6 9.4 8.4 5.8 5.6 5.6 3.6 5.6 4.4 8.2 7.9 8.1 6.5 11.4 6.3 6.5 2.8 3.7 4.1 5.0 1.6 5.2 5.6 4.8 3.2 2.9 3.7 9.9 5.5 3.7 5.8 7.5 3.9 53.0 54.1 51.3 54.6 52.6 45.4 39.1 39.7 40.1 56.8 55.8 53.8 73.4 71.0 69.0 85.8 81.6 80.9 88.6 82.2 78.8 79.1 79.3 80.5 52.8 61.0 65.9 47.2 43.4 42.4 58.5 57.8 53.8 39.3 59.8 50.6 67.0 79.7 91.6 104.1 105.3 95.3 95.7 117.9 106.4 123.9 135.6 123.9 130.2 135.5 131.5 112.0 113.2 116.3 98 pH nd nd nd 8.0 7.9 8.3 8.1 8.0 8.2 8.0 7.9 8.5 7.6 8.0 8.4 7.8 8.3 8.2 8.1 8.3 8.5 7.8 8.1 8.5 7.7 8.0 8.7 7.5 7.6 7.9 8.3 8.1 8.4 8.2 7.9 8.3 8.3 8.1 7.1 7.8 7.9 7.9 7.9 8.0 8.1 7.9 7.9 7.9 7.5 7.9 8.0 7.8 7.8 7.6 Sampling Date Transect TP1 TDP PP SRP DOP TSS Ca (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) 12/20/2011 A 0.082 0.044 0.038 0.028 0.016 3.8 115.2 12/20/2011 B 0.064 0.038 0.026 0.020 0.018 3.9 113.4 12/20/2011 C 0.039 0.030 0.009 0.015 0.015 1.3 110.8 1/11/2012 A 0.109 0.113 0.045 0.068 22.0 105.1 1/11/2012 B 0.112 0.082 0.030 0.040 0.042 18.2 103.5 1/11/2012 C 0.108 0.078 0.030 0.036 0.042 11.0 102.9 1/25/2012 A 0.090 0.074 0.016 0.045 0.029 5.4 81.0 1/25/2012 B 0.067 0.064 0.003 0.028 0.036 2.6 84.9 1/25/2012 C 0.074 0.083 0.030 0.053 9.0 90.5 2/8/2012 A 0.063 0.045 0.018 0.053 10.2 134.0 2/8/2012 B 0.064 0.046 0.018 0.057 17.8 137.7 2/8/2012 C 0.079 0.049 0.030 0.063 24.2 140.6 2/27/2012 A 0.140 0.130 0.010 0.133 11.2 140.2 2/27/2012 B 0.125 0.127 0.114 0.014 9.5 138.8 2/27/2012 C 0.079 0.054 0.025 0.056 17.5 139.8 3/12/2012 A 0.080 0.038 0.042 0.036 0.002 21.2 119.3 3/12/2012 B 0.051 0.022 0.029 0.015 0.008 8.5 113.9 3/12/2012 C 0.045 0.015 0.030 0.012 0.003 9.1 114.6 3/28/2012 A 0.060 0.026 0.034 0.024 0.002 3.1 98.8 3/28/2012 B 0.045 0.015 0.030 0.011 0.004 5.1 95.5 3/28/2012 C 0.049 0.017 0.032 0.014 0.003 5.9 106.6 4/9/2012 A 0.063 0.018 0.045 0.023 8.5 140.3 4/9/2012 B 0.065 0.019 0.046 0.023 13.5 142.0 4/9/2012 C 0.077 0.023 0.054 0.031 14.1 163.7 4/23/2012 A 0.045 0.022 0.023 0.0225 4.8 99.6 4/23/2012 B 0.039 0.027 0.012 0.0141 0.013 7.7 92.6 4/23/2012 C 0.041 0.021 0.020 0.0131 0.008 10.2 103.6 1 TP=total-P; TDP=total dissolved-P; PP=particulate-P; SRP=soluble reactive-P; DOP=dissolved organic-P; TSS=total suspended solids; Ca=total dissolved calcium. nd = not determined. 99 pH 7.9 8.0 8.0 7.8 7.8 7.9 7.7 7.8 7.9 7.4 7.3 7.2 7.3 7.5 7.9 7.7 8.0 8.0 7.9 7.9 8.0 7.2 7.2 7.2 7.5 7.6 7.7 Figure A1. Distribution of total dissolved P (TDP) concentrations in canal water grab samples collected from November 2010 through April 2012. The ‘◊’ sign in the box is the mean, horizontal line in the box is the median, the top and bottom of the box represents 75th and 25th percentile, whereas the whiskers define the 5th and 95th percentile observations, and ‘o’ sign outside the boxes are outliers. 100 Figure A2. Distribution of soluble reactive P (SRP) concentrations in canal water grab samples collected from November 2010 through April 2012. The ‘◊’ sign in the box is the mean, horizontal line in the box is the median, the top and bottom of the box represents 75th and 25th percentile, whereas the whiskers define the 5th and 95th percentile observations, and ‘o’ sign outside the boxes are outliers. 101 Figure A3. Distribution of particulate-P (PP) concentrations in canal water grab samples collected from November 2010 through April 2012. The ‘◊’ sign in the box is the mean, horizontal line in the box is the median, the top and bottom of the box represents 75th and 25th percentile, whereas the whiskers define the 5th and 95th percentile observations, and ‘o’ sign outside the boxes are outliers. 102 Figure A4. Distribution of dissolved organic P (DOP) concentrations in canal water grab samples collected from November 2010 through April 2012. The ‘◊’ sign in the box is the mean, horizontal line in the box is the median, the top and bottom of the box represents 75th and 25th percentile, whereas the whiskers define the 5th and 95th percentile observations, and ‘o’ sign outside the boxes are outliers. 103 Figure A5 Distribution of total suspended solids (TSS) concentrations in canal water grab samples collected from November 2010 through April 2012. The ‘◊’ sign in the box is the mean, horizontal line in the box is the median, the top and bottom of the box represents 75th and 25th percentile, whereas the whiskers define the 5th and 95th percentile observations, and ‘o’ sign outside the boxes are outliers. 104 Figure A6. Distribution of dissolved calcium (Ca) concentrations in canal water grab samples collected from November 2010 through April 2012. The ‘◊’ sign in the box is the mean, horizontal line in the box is the median, the top and bottom of the box represents 75th and 25th percentile, whereas the whiskers define the 5th and 95th percentile observations, and ‘o’ sign outside the boxes are outliers. 105 10/14 10/21 10/28 11/4 11/11 11/18 11/25 12/2 12/9 12/16 12/23 12/30 1/6 1/13 1/20 1/27 2/3 2/10 2/17 2/24 3/2 3/9 3/16 3/23 3/30 4/6 4/13 4/20 4/27 5/4 5/11 5/18 ORP (mV) 10/14 10/21 10/28 11/4 11/11 11/18 11/25 12/2 12/9 12/16 12/23 12/30 1/6 1/13 1/20 1/27 2/3 2/10 2/17 2/24 3/2 3/9 3/16 3/23 3/30 4/6 4/13 4/20 4/27 5/4 5/11 5/18 Temp (°C) 10/14 10/21 10/28 11/4 11/11 11/18 11/25 12/2 12/9 12/16 12/23 12/30 1/6 1/13 1/20 1/27 2/3 2/10 2/17 2/24 3/2 3/9 3/16 3/23 3/30 4/6 4/13 4/20 4/27 5/4 5/11 5/18 pH 10/14 10/21 10/28 11/4 11/11 11/18 11/25 12/2 12/9 12/16 12/23 12/30 1/6 1/13 1/20 1/27 2/3 2/10 2/17 2/24 3/2 3/9 3/16 3/23 3/30 4/6 4/13 4/20 4/27 5/4 5/11 5/18 EC (uS/cm) 2400 1900 1400 900 400 10.0 9.0 8.0 7.0 6.0 30 25 20 15 10 800 600 400 200 0 -200 -400 Figure A7. Daily average of in situ measurements of canal water quality parameters recorded with MiniSonde® in farm 0401. 106 10/14 10/21 10/28 11/4 11/11 11/18 11/25 12/2 12/9 12/16 12/23 12/30 1/6 1/13 1/20 1/27 2/3 2/10 2/17 2/24 3/2 3/9 3/16 3/23 3/30 4/6 4/13 4/20 4/27 5/4 ORP (mV) 10/14 10/21 10/28 11/4 11/11 11/18 11/25 12/2 12/9 12/16 12/23 12/30 1/6 1/13 1/20 1/27 2/3 2/10 2/17 2/24 3/2 3/9 3/16 3/23 3/30 4/6 4/13 4/20 4/27 5/4 Temp. (°C) 10/14 10/21 10/28 11/4 11/11 11/18 11/25 12/2 12/9 12/16 12/23 12/30 1/6 1/13 1/20 1/27 2/3 2/10 2/17 2/24 3/2 3/9 3/16 3/23 3/30 4/6 4/13 4/20 4/27 5/4 pH 10/14 10/21 10/28 11/4 11/11 11/18 11/25 12/2 12/9 12/16 12/23 12/30 1/6 1/13 1/20 1/27 2/3 2/10 2/17 2/24 3/2 3/9 3/16 3/23 3/30 4/6 4/13 4/20 4/27 5/4 EC (uS/cm) 2400 1900 1400 900 400 9.0 8.5 8.0 7.5 7.0 6.5 6.0 30 25 20 15 10 800 600 400 200 0 Figure A8. Daily average of in situ measurements of canal water quality parameters recorded with MiniSonde® in farm 2501. 107 10/14 10/21 10/28 11/4 11/11 11/18 11/25 12/2 12/9 12/16 12/23 12/30 1/6 1/13 1/20 1/27 2/3 2/10 2/17 2/24 3/2 3/9 3/16 3/23 3/30 4/6 4/13 4/20 4/27 5/4 ORP (mV) 10/14 10/21 10/28 11/4 11/11 11/18 11/25 12/2 12/9 12/16 12/23 12/30 1/6 1/13 1/20 1/27 2/3 2/10 2/17 2/24 3/2 3/9 3/16 3/23 3/30 4/6 4/13 4/20 4/27 5/4 Temp (°C) 10/14 10/21 10/28 11/4 11/11 11/18 11/25 12/2 12/9 12/16 12/23 12/30 1/6 1/13 1/20 1/27 2/3 2/10 2/17 2/24 3/2 3/9 3/16 3/23 3/30 4/6 4/13 4/20 4/27 5/4 pH 10/14 10/21 10/28 11/4 11/11 11/18 11/25 12/2 12/9 12/16 12/23 12/30 1/6 1/13 1/20 1/27 2/3 2/10 2/17 2/24 3/2 3/9 3/16 3/23 3/30 4/6 4/13 4/20 4/27 5/4 EC (uS/cm) 2400 1900 1400 900 400 9.0 8.5 8.0 7.5 7.0 6.5 6.0 30 25 20 15 10 800 600 400 200 0 Figure A9. Daily average of in situ measurements of canal water quality parameters recorded with MiniSonde® in farm 1813. 108 10/14 10/21 10/28 11/4 11/11 11/18 11/25 12/2 12/9 12/16 12/23 12/30 1/6 1/13 1/20 1/27 2/3 2/10 2/17 2/24 3/2 3/9 3/16 3/23 3/30 4/6 4/13 4/20 4/27 5/4 ORP (mV) 10/14 10/21 10/28 11/4 11/11 11/18 11/25 12/2 12/9 12/16 12/23 12/30 1/6 1/13 1/20 1/27 2/3 2/10 2/17 2/24 3/2 3/9 3/16 3/23 3/30 4/6 4/13 4/20 4/27 5/4 Temp (°C) 10/14 10/21 10/28 11/4 11/11 11/18 11/25 12/2 12/9 12/16 12/23 12/30 1/6 1/13 1/20 1/27 2/3 2/10 2/17 2/24 3/2 3/9 3/16 3/23 3/30 4/6 4/13 4/20 4/27 5/4 pH 10/14 10/21 10/28 11/4 11/11 11/18 11/25 12/2 12/9 12/16 12/23 12/30 1/6 1/13 1/20 1/27 2/3 2/10 2/17 2/24 3/2 3/9 3/16 3/23 3/30 4/6 4/13 4/20 4/27 5/4 EC (uS/cm) 2400 1900 1400 900 400 9.0 8.5 8.0 7.5 7.0 6.5 6.0 30 25 20 15 10 800 600 400 200 0 Figure A10. Daily average of in situ measurements of canal water quality parameters recorded with MiniSonde® in farm 6117. 109 10/14 10/21 10/28 11/4 11/11 11/18 11/25 12/2 12/9 12/16 12/23 12/30 1/6 1/13 1/20 1/27 2/3 2/10 2/17 2/24 3/2 3/9 3/16 3/23 3/30 4/6 4/13 4/20 4/27 5/4 ORP (mV) 10/14 10/21 10/28 11/4 11/11 11/18 11/25 12/2 12/9 12/16 12/23 12/30 1/6 1/13 1/20 1/27 2/3 2/10 2/17 2/24 3/2 3/9 3/16 3/23 3/30 4/6 4/13 4/20 4/27 5/4 Temp (°C) 10/14 10/21 10/28 11/4 11/11 11/18 11/25 12/2 12/9 12/16 12/23 12/30 1/6 1/13 1/20 1/27 2/3 2/10 2/17 2/24 3/2 3/9 3/16 3/23 3/30 4/6 4/13 4/20 4/27 5/4 pH 10/14 10/21 10/28 11/4 11/11 11/18 11/25 12/2 12/9 12/16 12/23 12/30 1/6 1/13 1/20 1/27 2/3 2/10 2/17 2/24 3/2 3/9 3/16 3/23 3/30 4/6 4/13 4/20 4/27 5/4 EC (uS/cm) 2400 1900 1400 900 400 9.0 8.5 8.0 7.5 7.0 6.5 6.0 30 25 20 15 10 800 600 400 200 0 -200 -400 Figure A11. Daily average of in situ measurements of canal water quality parameters recorded with MiniSonde® in farm 3102. 110 10/14 10/21 10/28 11/4 11/11 11/18 11/25 12/2 12/9 12/16 12/23 12/30 1/6 1/13 1/20 1/27 2/3 2/10 2/17 2/24 3/2 3/9 3/16 3/23 3/30 4/6 4/13 4/20 4/27 5/4 ORP (mV) 10/14 10/21 10/28 11/4 11/11 11/18 11/25 12/2 12/9 12/16 12/23 12/30 1/6 1/13 1/20 1/27 2/3 2/10 2/17 2/24 3/2 3/9 3/16 3/23 3/30 4/6 4/13 4/20 4/27 5/4 Temp. (°C) 10/14 10/21 10/28 11/4 11/11 11/18 11/25 12/2 12/9 12/16 12/23 12/30 1/6 1/13 1/20 1/27 2/3 2/10 2/17 2/24 3/2 3/9 3/16 3/23 3/30 4/6 4/13 4/20 4/27 5/4 pH 10/14 10/21 10/28 11/4 11/11 11/18 11/25 12/2 12/9 12/16 12/23 12/30 1/6 1/13 1/20 1/27 2/3 2/10 2/17 2/24 3/2 3/9 3/16 3/23 3/30 4/6 4/13 4/20 4/27 5/4 EC (uS/cm) 2400 1900 1400 900 400 9.0 8.5 8.0 7.5 7.0 6.5 6.0 30 25 20 15 10 800 600 400 200 0 Figure A12. Daily average of in situ measurements of canal water quality parameters recorded with MiniSonde® in farm 3103. 111 10/14 10/21 10/28 11/4 11/11 11/18 11/25 12/2 12/9 12/16 12/23 12/30 1/6 1/13 1/20 1/27 2/3 2/10 2/17 2/24 3/2 3/9 3/16 3/23 3/30 4/6 4/13 4/20 4/27 5/4 ORP (mV) 10/14 10/21 10/28 11/4 11/11 11/18 11/25 12/2 12/9 12/16 12/23 12/30 1/6 1/13 1/20 1/27 2/3 2/10 2/17 2/24 3/2 3/9 3/16 3/23 3/30 4/6 4/13 4/20 4/27 5/4 Temp (°C) 10/14 10/21 10/28 11/4 11/11 11/18 11/25 12/2 12/9 12/16 12/23 12/30 1/6 1/13 1/20 1/27 2/3 2/10 2/17 2/24 3/2 3/9 3/16 3/23 3/30 4/6 4/13 4/20 4/27 5/4 pH 10/14 10/21 10/28 11/4 11/11 11/18 11/25 12/2 12/9 12/16 12/23 12/30 1/6 1/13 1/20 1/27 2/3 2/10 2/17 2/24 3/2 3/9 3/16 3/23 3/30 4/6 4/13 4/20 4/27 5/4 EC (uS/cm) 2400 1900 1400 900 400 9.0 8.5 8.0 7.5 7.0 6.5 6.0 30 25 20 15 10 700 600 500 400 300 200 100 0 Figure A13. Daily average of in situ measurements of canal water quality parameters recorded with MiniSonde® in farm 4701. 112 11/11 11/18 11/25 12/2 12/9 12/16 12/23 12/30 1/6 1/13 1/20 1/27 2/3 2/10 2/17 2/24 3/2 3/9 3/16 3/23 3/30 4/6 4/13 4/20 4/27 5/4 ORP (mV) 11/11 11/18 11/25 12/2 12/9 12/16 12/23 12/30 1/6 1/13 1/20 1/27 2/3 2/10 2/17 2/24 3/2 3/9 3/16 3/23 3/30 4/6 4/13 4/20 4/27 5/4 Temp (°C) 11/11 11/18 11/25 12/2 12/9 12/16 12/23 12/30 1/6 1/13 1/20 1/27 2/3 2/10 2/17 2/24 3/2 3/9 3/16 3/23 3/30 4/6 4/13 4/20 4/27 5/4 pH 11/11 11/18 11/25 12/2 12/9 12/16 12/23 12/30 1/6 1/13 1/20 1/27 2/3 2/10 2/17 2/24 3/2 3/9 3/16 3/23 3/30 4/6 4/13 4/20 4/27 5/4 EC (uS/cm) 2400 1900 1400 900 400 9.0 8.5 8.0 7.5 7.0 6.5 6.0 30 25 20 15 10 700 600 500 400 300 200 100 0 Figure A14. Daily average of in situ measurements of canal water quality parameters recorded with MiniSonde® in farm 4702. 113 Table A13. Detailed water quality parameters of drainage water samples collected from farm 0401 from February 2011 through April 2012. Sampling Date TP1 TDP PP SRP DOP TSS Ca (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) pH 3/29/2011 0.097 0.028 0.069 0.021 0.007 27.6 36.2 7.7 3/31/2011 0.084 0.020 0.064 0.026 20.5 52.3 8.1 7/5/2011 0.087 0.052 0.035 0.042 0.010 17.1 99.1 7.9 7/6/2011 0.055 0.042 0.013 0.031 0.011 4.3 112.5 7.5 7/8/2011 0.064 0.028 0.036 0.019 0.009 10.3 148.0 7.9 7/9/2011 0.059 0.034 0.025 0.025 0.009 7.0 147.5 7.7 7/10/2011 0.085 0.050 0.035 0.043 0.007 15.6 148.0 7.7 7/11/2011 0.095 0.029 0.066 0.032 37.1 143.6 7.8 7/15/2011 0.053 0.026 0.027 0.022 0.004 6.7 124.3 7.9 7/19/2011 0.059 0.027 0.032 0.020 0.007 8.2 113.7 8.0 7/22/2011 0.162 0.029 0.133 0.022 0.007 24.3 100.8 7.9 7/23/2011 0.124 0.031 0.093 0.022 0.009 49.3 96.1 8.0 8/19/2011 0.046 0.029 0.017 0.021 0.009 7.5 84.4 7.4 8/20/2011 0.096 0.029 0.067 0.025 0.004 31.0 121.9 7.5 8/22/2011 0.190 0.027 0.163 0.026 0.001 76.9 123.7 7.7 8/24/2011 0.084 0.043 0.041 0.024 0.019 20.4 129.9 7.8 8/26/2011 0.059 0.031 0.028 0.021 0.010 26.9 132.1 7.7 8/29/2011 0.178 0.048 0.130 0.040 0.009 62.5 103.6 7.7 9/2/2011 0.065 0.038 0.027 0.033 0.005 6.8 129.9 7.7 9/5/2011 0.052 0.032 0.020 0.022 0.010 5.7 131.5 8.1 9/9/2011 0.148 0.055 0.093 0.042 0.013 14.8 115.0 7.8 9/12/2011 0.063 0.028 0.035 0.019 0.010 13.9 137.8 7.8 9/19/2011 0.158 0.050 0.108 0.042 0.009 18.1 106.8 7.8 9/26/2011 0.175 0.044 0.131 0.045 33.9 92.3 7.8 9/29/2011 0.092 0.040 0.052 0.039 0.001 29.2 100.5 7.9 10/1/2011 0.123 0.044 0.079 0.041 0.003 46.4 98.9 7.9 10/9/2011 0.162 0.037 0.125 0.043 56.4 106.0 8.1 10/19/2011 0.084 0.047 0.037 0.0464 0.001 12.4 112.8 7.7 10/24/2011 0.123 0.051 0.072 0.049 0.002 31.2 132.2 7.8 10/31/2011 0.193 0.072 0.121 0.064 0.008 59.3 116.9 7.9 11/2/2011 0.098 0.066 0.032 0.067 14.6 143.0 7.8 11/4/2011 0.127 0.044 0.083 0.070 20.8 137.4 7.9 11/7/2011 0.057 0.043 0.014 0.058 nd 138.8 8.2 11/8/2011 0.089 0.047 0.042 0.064 39.9 127.5 7.9 11/22/2011 0.058 0.023 0.035 0.024 21.7 74.9 7.9 1 TP=total-P; TDP=total dissolved-P; PP=particulate-P; SRP=soluble reactive-P; DOP=dissolved organic-P; TSS=total suspended solids; Ca=total dissolved calcium. nd = not determined. 114 Table A14. Detailed water quality parameters of drainage water samples collected from farm 2501 from February 2011 through April 2012. Sampling Date TP1 TDP PP SRP DOP TSS Ca (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) pH 3/29/2011 0.060 0.071 nd 0.065 0.006 23.8 37.1 7.8 3/30/2011 nd nd nd 0.030 11.2 43.8 8.0 3/31/2011 0.067 0.038 0.029 0.020 0.018 12.9 40.1 8.1 7/5/2011 0.072 0.038 0.034 0.028 0.010 16.3 93.6 8.0 7/6/2011 0.046 0.033 0.013 0.018 0.015 3.2 114.3 7.6 7/7/2011 0.057 0.033 0.024 0.025 0.008 3.8 137.3 7.8 7/8/2011 0.052 0.037 0.015 0.031 0.006 4.5 128.0 7.7 7/10/2011 0.057 0.031 0.026 0.026 0.005 2.4 140.1 7.8 7/11/2011 0.042 0.025 0.017 0.022 0.003 3.2 143.9 8.0 7/14/2011 0.053 0.020 0.033 0.013 0.008 3.1 125.9 8.0 7/15/2011 0.064 0.016 0.048 0.014 0.002 18.7 121.6 8.2 8/20/2011 0.085 0.033 0.052 0.021 0.012 29.9 98.3 7.4 8/24/2011 0.135 0.083 0.052 0.049 0.034 30.6 136.5 7.6 8/25/2011 0.061 0.042 0.019 0.033 0.009 8.0 142.7 7.4 8/26/2011 0.046 0.034 0.012 0.034 0.001 5.1 136.4 7.5 9/2/2011 0.061 0.030 0.031 0.023 0.007 20.2 127.4 7.7 9/9/2011 0.074 0.017 0.057 0.011 0.006 6.7 136.1 7.8 9/10/2011 0.109 0.052 0.057 0.044 0.008 14.5 126.4 8.0 9/12/2011 0.070 0.029 0.041 0.026 0.003 21.0 142.9 7.9 9/30/2011 0.088 0.026 0.062 0.018 0.009 19.5 114.5 7.8 10/20/2011 0.115 0.031 0.084 0.0262 0.005 24.7 126.2 7.6 10/21/2011 0.073 0.038 0.035 0.033 0.005 12.5 139.9 7.7 10/31/2011 0.101 0.026 0.075 0.019 0.007 30.2 132.2 7.8 11/1/2011 0.109 0.073 0.036 0.059 0.014 14.5 81.8 7.7 11/2/2011 0.080 0.052 0.028 0.052 0.000 5.3 146.5 7.7 11/3/2011 0.084 0.058 0.026 0.0558 0.002 11.5 145.2 7.7 11/4/2011 0.121 0.069 0.052 0.052 0.017 10.9 144.6 7.8 11/7/2011 0.072 0.043 0.029 0.050 nd 148.0 8.1 1 TP=total-P; TDP=total dissolved-P; PP=particulate-P; SRP=soluble reactive-P; DOP=dissolved organic-P; TSS=total suspended solids; Ca=total dissolved calcium. nd = not determined. 115 Table A15. Detailed water quality parameters of drainage water samples collected from farm 1813 from February 2011 through April 2012. Sampling Date TP1 TDP PP SRP DOP TSS Ca (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) pH 7/5/2011 0.123 0.089 0.034 0.076 0.013 9.7 106.4 7.8 7/8/2011 0.134 0.100 0.034 0.081 0.019 5.8 135.6 7.8 7/10/2011 0.157 0.118 0.039 0.103 0.015 4.9 120.7 8.0 7/11/2011 0.127 0.060 0.067 0.051 0.009 4.1 121.9 8.0 7/15/2011 0.077 0.020 0.057 0.011 0.010 9.5 113.8 8.1 8/19/2011 0.063 0.017 0.046 0.006 0.011 8.9 102.8 7.5 8/24/2011 0.056 0.019 0.037 0.008 0.012 11.6 117.0 7.7 8/27/2011 0.045 0.013 0.032 0.008 0.005 21.0 122.5 7.8 8/30/2011 0.051 0.012 0.039 0.006 0.006 18.9 120.8 8.0 9/2/2011 0.038 0.012 0.026 0.009 0.003 9.9 119.5 7.9 9/8/2011 0.063 0.015 0.048 0.009 0.006 11.5 114.5 7.9 9/12/2011 0.046 0.017 0.029 0.013 0.004 8.4 113.5 7.7 9/13/2011 0.080 0.037 0.043 0.032 0.005 5.6 114.3 8.0 9/27/2011 0.067 0.020 0.047 0.015 0.005 24.0 109.6 8.1 10/9/2011 0.064 0.015 0.049 0.012 0.003 21.8 104.4 8.1 10/20/2011 0.068 0.032 0.036 0.0315 0.001 11.3 108.0 7.7 10/21/2011 0.067 0.039 0.028 0.034 0.005 17.3 117.4 7.8 10/24/2011 0.079 0.057 0.022 0.035 0.022 9.4 117.2 7.9 10/25/2011 0.071 0.045 0.026 0.041 0.004 15.6 118.9 7.9 10/31/2011 0.093 0.037 0.056 0.032 0.005 12.8 100.7 7.6 11/1/2011 0.176 0.150 0.026 0.129 0.021 8.2 135.2 7.4 11/2/2011 0.122 0.092 0.030 0.086 0.006 14.1 110.5 7.8 11/3/2011 0.101 0.081 0.020 0.08 0.001 17.1 121.2 7.8 11/7/2011 0.059 0.042 0.017 0.055 14.9 134.3 7.9 11/8/2011 0.057 0.037 0.020 0.053 16.5 125.9 8.0 11/18/2011 0.127 0.043 0.084 0.049 19.0 132.6 8.3 11/23/2011 0.068 0.021 0.047 0.053 16.0 111.9 8.1 12/15/2011 0.103 0.036 0.067 0.048 nd 97.3 7.9 3/26/2012 0.036 0.013 0.023 0.013 0.000 9.5 83.6 8.0 1 TP=total-P; TDP=total dissolved-P; PP=particulate-P; SRP=soluble reactive-P; DOP=dissolved organic-P; TSS=total suspended solids; Ca=total dissolved calcium. nd = not determined. 116 Table A16. Detailed water quality parameters of drainage water samples collected from farm 6117 from February 2011 through April 2012. Sampling Date TP1 TDP PP SRP DOP TSS Ca (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) pH 7/5/2011 0.093 0.043 0.050 0.031 0.013 5.3 111.9 7.8 7/6/2011 0.112 0.072 0.040 0.059 0.013 5.4 124.0 7.6 7/10/2011 0.133 0.042 0.091 0.030 0.013 4.7 123.2 7.7 7/15/2011 0.102 0.041 0.061 0.029 0.012 5.8 117.3 7.9 8/19/2011 0.114 0.026 0.088 0.012 0.014 4.7 105.6 7.4 8/24/2011 0.129 0.087 0.042 0.059 0.028 25.8 119.3 8.0 8/27/2011 0.120 0.031 0.089 0.018 0.013 10.0 116.4 7.7 9/2/2011 0.115 0.039 0.076 0.026 0.014 25.3 121.3 7.8 9/3/2011 0.103 0.048 0.055 0.031 0.017 11.2 132.1 8.0 9/5/2011 0.104 0.062 0.042 0.041 0.022 4.3 137.6 8.2 9/8/2011 0.118 0.043 0.075 0.027 0.017 10.3 130.4 7.8 9/12/2011 0.137 0.071 0.066 0.059 0.012 9.8 134.0 7.6 9/25/2011 0.132 0.030 0.102 0.020 0.010 18.8 121.4 7.8 10/1/2011 0.310 0.068 0.242 0.070 33.3 118.5 7.7 10/10/2011 0.147 0.078 0.069 0.075 0.004 13.1 116.2 7.6 10/20/2011 0.140 0.093 0.047 0.0794 0.014 5.4 125.8 7.5 10/21/2011 0.179 0.141 0.038 0.138 0.003 8.4 131.7 7.5 10/28/2011 0.221 0.068 0.153 0.043 0.025 38.2 125.7 7.7 10/31/2011 0.173 0.108 0.065 0.048 0.060 10.0 122.6 7.5 11/1/2011 0.175 0.136 0.039 0.128 0.008 12.6 140.7 7.5 11/2/2011 0.203 0.153 0.050 0.145 0.008 10.9 133.9 7.5 11/7/2011 0.108 0.072 0.036 0.090 11.5 141.8 7.9 3/26/2012 0.070 0.037 0.033 0.037 0.001 13.1 81.6 7.5 1 TP=total-P; TDP=total dissolved-P; PP=particulate-P; SRP=soluble reactive-P; DOP=dissolved organic-P; TSS=total suspended solids; Ca=total dissolved calcium. nd = not determined. 117 Table A17. Detailed water quality parameters of drainage water samples collected from farm 3102 from February 2011 through April 2012. 1 TP TDP PP SRP DOP TSS Ca Sampling pH (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) Date 3/30/2011 nd nd nd 0.060 nd 1.8 56.8 7.8 3/31/2011 0.153 0.106 0.047 0.093 0.013 33.1 47.9 8.1 4/1/2011 0.151 0.101 0.050 0.085 0.016 nd 51.5 8.6 7/5/2011 0.274 0.207 0.067 0.184 0.023 91.2 129.1 7.8 7/7/2011 0.259 0.187 0.072 0.162 0.026 15.5 123.6 7.7 7/12/2011 0.200 0.166 0.034 0.146 0.021 5.6 98.0 7.8 7/15/2011 0.311 0.211 0.100 0.193 0.018 18.3 109.7 7.8 7/16/2011 0.297 0.131 0.166 0.143 24.7 113.2 7.9 7/19/2011 0.130 0.083 0.047 0.089 8.5 121.4 7.7 8/20/2011 0.193 0.163 0.030 0.146 0.017 10.5 127.0 7.6 8/23/2011 0.289 0.215 0.074 0.194 0.021 6.7 123.3 7.6 8/24/2011 0.261 0.203 0.058 0.172 0.031 19.4 124.6 7.5 8/25/2011 0.216 0.165 0.051 0.151 0.014 22.1 127.2 7.6 8/26/2011 0.230 0.152 0.078 0.121 0.031 21.5 123.8 7.6 8/27/2011 0.255 0.023 0.232 0.121 28.5 123.9 7.8 9/3/2011 0.181 0.156 0.025 0.139 0.017 6.0 121.9 7.6 9/5/2011 0.172 0.150 0.022 0.142 0.008 33.8 129.3 7.8 9/8/2011 0.292 0.149 0.143 0.134 0.015 25.0 120.6 7.4 9/9/2011 0.403 0.264 0.139 0.248 0.016 28.7 126.4 7.7 9/10/2011 0.481 0.270 0.211 0.245 0.025 27.9 136.1 7.9 9/12/2011 0.429 0.234 0.195 0.210 0.024 40.0 124.1 7.9 9/13/2011 0.748 0.184 0.564 0.162 0.022 93.2 126.0 8.3 9/27/2011 0.321 0.177 0.144 0.190 29.1 103.7 7.8 9/29/2011 0.416 0.244 0.172 0.273 16.1 108.1 7.6 9/30/2011 0.231 0.181 0.050 0.195 21.7 121.3 7.7 10/11/2011 0.295 0.195 0.100 0.202 26.6 119.6 7.8 10/20/2011 0.329 0.243 0.086 0.2545 11.2 121.7 7.4 10/21/2111 0.256 0.212 0.044 0.180 0.032 28.4 130.7 7.5 10/24/2011 0.323 0.212 0.111 0.214 93.2 132.6 8.0 10/31/2011 0.378 0.231 0.147 0.213 0.018 26.5 119.6 7.5 11/1/2011 0.312 0.207 0.105 0.196 0.011 34.8 130.6 7.4 11/2/2011 0.305 0.150 0.155 0.147 0.003 nd 134.3 7.8 2/10/2012 0.302 0.105 0.197 0.088 0.017 nd 81.4 7.8 4/21/2012 0.126 0.066 0.060 0.0594 0.007 11.8 67.3 7.6 4/23/2012 0.189 0.152 0.037 0.1576 15.8 84.1 7.5 4/30/2012 0.151 0.104 0.047 0.0873 0.017 16.8 88.5 7.7 1 TP=total-P; TDP=total dissolved-P; PP=particulate-P; SRP=soluble reactive-P; DOP=dissolved organic-P; TSS=total suspended solids; Ca=total dissolved calcium. nd = not determined. 118 Table A18. Table A18. Detailed water quality parameters of drainage water samples collected from farm 3103 from February 2011 through April 2012. Sampling Date TP1 TDP PP SRP DOP TSS Ca (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) pH 2/11/2011 0.081 0.069 0.012 0.066 0.003 8.0 58.8 8.1 3/28/2011 0.097 0.044 0.053 0.057 23.8 56.3 7.8 3/29/2011 0.115 0.063 0.052 0.046 0.017 15.2 60.6 8.1 3/30/2011 nd nd nd 0.166 14.4 77.4 7.7 3/31/2011 0.198 0.137 0.061 0.122 0.015 16.6 76.0 8.1 6/20/2011 0.083 0.018 0.065 0.015 0.003 32.9 126.2 7.8 6/29/2011 0.133 0.056 0.077 0.041 0.016 6.5 136.1 7.0 7/5/2011 0.146 0.127 0.019 0.113 0.014 3.8 141.4 8.0 7/7/2011 0.154 0.115 0.039 0.110 0.005 5.5 146.2 5.6 7/12/2011 0.118 0.086 0.032 0.081 0.005 2.4 132.2 7.6 7/14/2011 0.142 0.094 0.048 0.087 0.007 6.9 127.1 7.7 7/15/2011 0.105 0.077 0.028 0.073 0.005 10.2 131.2 7.5 7/23/2011 0.110 0.041 0.069 0.038 0.003 22.8 123.2 7.7 7/27/2011 0.075 0.030 0.045 0.022 0.008 10.7 114.5 7.6 8/6/2011 0.070 0.026 0.044 0.013 0.013 12.8 132.8 7.8 8/12/2011 0.125 0.038 0.087 0.011 0.027 10.9 113.8 7.7 8/19/2011 0.128 0.094 0.034 0.081 0.013 14.1 105.8 7.6 8/20/2011 0.147 0.071 0.076 0.059 0.012 22.5 119.9 7.8 8/23/2011 0.136 0.069 0.067 0.055 0.014 7.8 124.8 7.7 8/25/2011 0.083 0.042 0.041 0.032 0.010 19.4 136.7 7.6 8/27/2011 0.198 0.132 0.066 0.014 0.118 76.3 138.1 7.5 9/2/2011 0.174 0.068 0.106 0.060 0.009 20.5 131.1 7.6 9/5/2011 0.146 0.096 0.050 0.091 0.005 14.4 127.7 8.1 9/6/2011 0.271 0.153 0.118 0.132 0.021 14.0 140.0 7.9 9/7/2011 0.217 0.110 0.107 0.097 0.013 28.6 136.6 7.9 9/8/2011 0.187 0.089 0.098 0.079 0.011 34.5 140.6 7.8 9/9/2011 0.257 0.114 0.143 0.087 0.027 20.8 142.2 7.8 9/10/2011 0.206 0.061 0.145 0.051 0.010 33.9 115.0 7.9 9/12/2011 0.227 0.123 0.104 0.101 0.022 32.4 140.5 7.7 9/27/2011 0.214 0.145 0.069 0.151 5.5 123.6 7.8 9/29/2011 0.271 0.168 0.103 0.183 30.7 127.5 7.7 9/30/2011 0.308 0.143 0.165 0.149 86.9 138.9 7.6 10/10/2011 0.179 0.104 0.075 0.101 0.003 30.8 130.4 7.8 10/20/2011 0.242 0.186 0.056 0.1787 0.007 7.8 123.1 7.6 10/24/2011 0.159 0.129 0.030 0.132 7.3 143.2 7.9 10/31/2011 0.380 0.234 0.146 0.213 0.021 12.4 125.0 7.6 11/1/2011 0.377 0.257 0.120 0.235 0.022 12.0 132.8 7.7 2/10/2012 0.173 0.102 0.071 0.082 0.020 nd 120.2 8.2 4/21/2012 0.193 0.085 0.108 0.0792 0.006 22.6 71.3 7.8 4/23/2012 0.217 0.141 0.076 0.1459 25.7 107.5 7.8 4/30/2012 0.276 0.083 0.193 0.0753 0.008 82.5 102.8 7.9 1 TP=total-P; TDP=total dissolved-P; PP=particulate-P; SRP=soluble reactive-P; DOP=dissolved organic-P; TSS=total suspended solids; Ca=total dissolved calcium. nd = not determined. 119 Table A19. Detailed water quality parameters of drainage water samples collected from farm 4701 from February 2011 through April 2012. 1 TP TDP PP SRP DOP TSS Ca Sampling pH (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) Date 2/11/2011 0.115 0.064 0.051 0.064 0.000 23.1 70.5 7.9 3/31/2011 0.038 0.036 0.002 0.004 0.032 6.5 44.7 8.0 7/5/2011 0.041 0.014 0.027 0.007 0.007 3.9 99.9 7.8 7/6/2011 0.029 0.015 0.014 0.010 0.005 3.3 103.6 7.5 7/12/2011 0.053 0.035 0.018 0.017 0.018 10.9 87.4 8.2 7/15/2011 0.034 0.010 0.024 0.013 3.9 93.1 7.8 7/16/2011 0.047 0.015 0.032 0.011 0.004 12.0 99.9 8.1 8/23/2011 0.036 0.009 0.027 0.008 0.001 5.4 96.7 7.7 8/24/2011 0.058 0.020 0.038 0.011 0.010 14.2 103.9 7.5 9/5/2011 0.034 0.008 0.026 0.010 19.7 97.3 7.7 9/7/2011 0.034 0.010 0.024 0.011 7.5 106.0 7.6 9/10/2011 0.048 0.006 0.042 0.013 6.6 142.2 8.0 9/30/2011 0.058 0.012 0.046 0.012 0.000 17.7 106.2 7.9 10/20/2011 0.052 0.023 0.029 0.0172 0.006 5.3 111.5 7.7 10/31/2011 0.046 0.018 0.028 0.016 0.002 6.4 114.9 7.6 11/1/2011 0.033 0.014 0.019 0.019 5.2 120.5 7.5 11/2/2011 0.032 0.039 nd 0.026 0.014 2.9 121.6 7.6 11/3/2011 0.049 0.020 0.029 0.0288 22.0 121.0 7.8 4/23/2012 0.030 0.009 0.021 0.0080 0.001 2.4 67.6 7.8 10/21/2011 0.037 0.014 0.023 0.018 12.7 103.0 7.8 1 TP=total-P; TDP=total dissolved-P; PP=particulate-P; SRP=soluble reactive-P; DOP=dissolved organic-P; TSS=total suspended solids; Ca=total dissolved calcium. nd = not determined. 120 Table A20. Detailed water quality parameters of drainage water samples collected from farm 4702 from February 2011 through April 2012. 1 TP TDP PP SRP DOP TSS Ca Sampling pH (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) Date 3/31/2011 0.050 0.012 0.038 0.007 0.005 11.3 46.6 8.1 7/5/2011 0.061 0.049 0.012 0.031 0.018 2.8 154.0 7.6 7/6/2011 0.070 0.052 0.018 0.032 0.020 4.5 148.5 7.4 7/7/2011 0.077 0.062 0.015 0.053 0.009 10.0 149.9 7.9 7/8/2011 0.068 0.043 0.025 0.046 8.6 155.2 7.8 7/12/2011 0.053 0.022 0.031 0.025 4.2 144.5 8.0 7/15/2011 0.051 0.017 0.034 0.023 3.7 141.3 7.7 7/16/2011 0.051 0.021 0.030 0.020 0.001 3.8 148.4 7.7 8/23/2011 0.036 0.019 0.017 0.012 0.007 4.8 122.6 7.5 9/5/2011 0.049 0.022 0.027 0.026 6.2 127.9 7.6 9/8/2011 0.045 0.023 0.022 0.026 6.9 133.2 7.7 10/20/2011 0.093 0.052 0.041 0.0578 21.4 125.3 7.5 10/21/2011 0.061 0.028 0.033 0.036 136.1 7.8 10/31/2011 0.068 0.035 0.033 0.037 7.5 130.9 7.5 11/1/2011 0.084 0.045 0.039 0.050 16.8 144.0 7.7 11/2/2011 0.057 0.017 0.040 0.054 5.4 151.0 7.7 11/3/2011 0.048 0.033 0.015 0.0535 6.5 148.4 7.7 11/4/2011 0.087 0.040 0.047 0.033 0.007 52.1 145.6 7.6 2/10/2012 0.104 0.055 0.049 0.048 0.007 132.9 7.9 2/13/2012 0.059 0.036 0.023 0.048 10.0 138.5 7.8 2/15/2012 0.051 0.027 0.024 0.041 16.0 137.8 8.0 2/22/2012 0.084 0.058 0.026 0.070 13.0 140.8 7.6 3/26/2012 0.032 0.012 0.020 0.017 8.4 116.5 7.9 1 TP=total-P; TDP=total dissolved-P; PP=particulate-P; SRP=soluble reactive-P; DOP=dissolved organic-P; TSS=total suspended solids; Ca=total dissolved calcium. nd = not determined. 121 Farm 0401 Daily Rainfall 2.50 Inches 2.00 1.50 1.00 0.50 0.00 05/01/11 07/01/11 09/01/11 11/01/11 01/01/12 03/01/12 05/01/12 01/01/12 03/01/12 05/01/12 01/01/12 03/01/12 05/01/12 01/01/12 03/01/12 05/01/12 Farm 2501 Daily Rainfall 2.50 Inches 2.00 1.50 1.00 0.50 0.00 05/01/11 07/01/11 09/01/11 11/01/11 Figure A15. Daily rainfall for farms 0401 and 2501 for WY 2012. Farm 1813 Daily Rainfall 2.50 Inches 2.00 1.50 1.00 0.50 0.00 05/01/11 07/01/11 09/01/11 11/01/11 Farm 6117 Daily Rainfall 2.50 Inches 2.00 1.50 1.00 0.50 0.00 05/01/11 07/01/11 09/01/11 11/01/11 Figure A16. Daily rainfall for farms 1813 and 6117 for WY 2012. 122 Farm 3102 Daily Rainfall 2.50 Inches 2.00 1.50 1.00 0.50 0.00 05/01/11 07/01/11 09/01/11 11/01/11 01/01/12 03/01/12 05/01/12 01/01/12 03/01/12 05/01/12 01/01/12 03/01/12 05/01/12 01/01/12 03/01/12 05/01/12 Farm 3103 Daily Rainfall 2.50 Inches 2.00 1.50 1.00 0.50 0.00 05/01/11 07/01/11 09/01/11 11/01/11 Figure A17. Daily rainfall for farms 3102 and 3103 for WY 2012. Farm 4701 Daily Rainfall 3.00 Inches 2.50 2.00 1.50 1.00 0.50 0.00 05/01/11 07/01/11 09/01/11 11/01/11 Farm 4702 Daily Rainfall 3.00 Inches 2.50 2.00 1.50 1.00 0.50 0.00 05/01/11 07/01/11 09/01/11 11/01/11 Figure A18. Daily rainfall for farms 4701 and 4702 for WY 2012. 123 Farm 0401 Daily Drainage Volume 25.0 MGals 20.0 15.0 10.0 5.0 0.0 05/01/11 07/01/11 09/01/11 11/01/11 01/01/12 03/01/12 05/01/12 03/01/12 05/01/12 Farm 2501 Daily Drainage Volume 20.0 MGals 15.0 10.0 5.0 0.0 05/01/11 07/01/11 09/01/11 11/01/11 01/01/12 Figure A19. Daily drainage volume for farms 0401 and 2501 for WY 2012. Farm 1813 Daily Drainage Volume 25.0 Mgals 20.0 15.0 10.0 5.0 0.0 05/01/11 07/01/11 09/01/11 11/01/11 01/01/12 03/01/12 05/01/12 03/01/12 05/01/12 Farm 6117 Daily Drainage Volume 30.0 MGals 25.0 20.0 15.0 10.0 5.0 0.0 05/01/11 07/01/11 09/01/11 11/01/11 01/01/12 Figure A20. Daily drainage volume for farms 1813 and 6117 for WY 2012. 124 Farm 3102 Daily Drainage Volume 60.0 Mgals 50.0 40.0 30.0 20.0 10.0 0.0 05/01/11 07/01/11 09/01/11 11/01/11 01/01/12 03/01/12 05/01/12 03/01/12 05/01/12 Farm 3103 Daily Drainage Volume 35.0 30.0 Mgals 25.0 20.0 15.0 10.0 5.0 0.0 05/01/11 07/01/11 09/01/11 11/01/11 01/01/12 Figure A21. Daily drainage volume for farms 3102 and 3103 for WY 2012. Farm 4701 Daily Drainage Volume 25.0 Mgals 20.0 15.0 10.0 5.0 0.0 05/01/11 07/01/11 09/01/11 11/01/11 01/01/12 03/01/12 05/01/12 03/01/12 05/01/12 Farm 4702 Daily Drainage Volume 25.0 Mgals 20.0 15.0 10.0 5.0 0.0 05/01/11 07/01/11 09/01/11 11/01/11 01/01/12 Figure A22. Daily drainage volume for farms 4701 and 4702 for WY 2012. 125 Farm 0401 Daily P Export 10.0 P Load (kgs) 8.0 6.0 4.0 2.0 0.0 05/01/11 07/01/11 09/01/11 11/01/11 01/01/12 03/01/12 05/01/12 01/01/12 03/01/12 05/01/12 01/01/12 03/01/12 05/01/12 01/01/12 03/01/12 05/01/12 Farm 2501 Daily P Export P Load (kgs) 10.0 8.0 6.0 4.0 2.0 0.0 05/01/11 07/01/11 09/01/11 11/01/11 Figure A23. Daily P export for farms 0401 and 2501 for WY 2012. Farm 1813 Daily P Export 10.0 P Load (kgs) 8.0 6.0 4.0 2.0 0.0 05/01/11 07/01/11 09/01/11 11/01/11 Farm 6117 Daily P Export P Load (kgs) 10.0 8.0 6.0 4.0 2.0 0.0 05/01/11 07/01/11 09/01/11 11/01/11 Figure A24. Daily P export for farms 1813 and 6117 for WY 2012. 126 Farm 3102 Daily P Export P Load (kgs) 80.0 60.0 40.0 20.0 0.0 05/01/11 07/01/11 09/01/11 11/01/11 01/01/12 03/01/12 05/01/12 01/01/12 03/01/12 05/01/12 01/01/12 03/01/12 05/01/12 01/01/12 03/01/12 05/01/12 Farm 3103 Daily P Export P Load (kgs) 50.0 40.0 30.0 20.0 10.0 0.0 05/01/11 07/01/11 09/01/11 11/01/11 Figure A25. Daily P export for farms 3102 and 3103 for WY 2012. Farm 4701 Daily P Export 10.0 P Load (kgs) 8.0 6.0 4.0 2.0 0.0 05/01/11 07/01/11 09/01/11 11/01/11 Farm 4702 Daily P Export P Load (kgs) 10.0 8.0 6.0 4.0 2.0 0.0 05/01/11 07/01/11 09/01/11 11/01/11 Figure A26. Daily P export for farms 4701 and 4702 for WY 2012. 127 Figure A27. Distribution of total dissolved P (TDP) concentrations in drainage water samples collected from November 2010 through April 2012. The ‘◊’ sign in the box is the mean, horizontal line in the box is the median, the top and bottom of the box represents 75th and 25th percentile, whereas the whiskers define the 5th and 95th percentile observations, and ‘o’ sign outside the boxes are outliers. 128 Figure A28. Distribution of soluble reactive P (SRP) concentrations in drainage water samples collected from November 2010 through April 2012. The ‘◊’ sign in the box is the mean, horizontal line in the box is the median, the top and bottom of the box represents 75th and 25th percentile, whereas the whiskers define the 5th and 95th percentile observations, and ‘o’ sign outside the boxes are outliers. 129 Figure A29. Distribution of particulate-P (PP) concentrations in drainage water samples collected from November 2010 through April 2012. The ‘◊’ sign in the box is the mean, horizontal line in the box is the median, the top and bottom of the box represents 75th and 25th percentile, whereas the whiskers define the 5th and 95th percentile observations, and ‘o’ sign outside the boxes are outliers. 130 Figure A30. Distribution of dissolved organic-P (DOP) concentrations in drainage water samples collected from November 2010 through April 2012. The ‘◊’ sign in the box is the mean, horizontal line in the box is the median, the top and bottom of the box represents 75th and 25th percentile, whereas the whiskers define the 5th and 95th percentile observations, and ‘o’ sign outside the boxes are outliers. 131 Figure A31. Distribution of total suspended solids (TSS) concentrations in drainage water samples collected from November 2010 through April 2012. The ‘◊’ sign in the box is the mean, horizontal line in the box is the median, the top and bottom of the box represents 75th and 25th percentile, whereas the whiskers define the 5th and 95th percentile observations, and ‘o’ sign outside the boxes are outliers. 132 Figure A32. Distribution of dissolved calcium (Ca) concentrations in drainage water samples collected from November 2010 through April 2012. The ‘◊’ sign in the box is the mean, horizontal line in the box is the median, the top and bottom of the box represents 75th and 25th percentile, whereas the whiskers define the 5th and 95th percentile observations, and ‘o’ sign outside the boxes are outlier. 133 Samira Daroub University of Florida/IFAS Everglades Research and Education Center Belle Glade, FL 33430 T: 561-9931593 | [email protected] http://erec.ifas.ufl.edu
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