st 21 International Symposium on Plasma Chemistry (ISPC 21) Sunday 4 August – Friday 9 August 2013 Cairns Convention Centre, Queensland, Australia Reduction of Heat Flux on the Hafnium Cathode Surface by Changing the Cathode Holder Shape in Plasma Arc Cutting Torch Nguyen Phi Long1, Y. Tanaka2, Y. Uesugi2, and Y. Yamaguchi3 1 Applied Laser Technology Institute, Japan Atomic Energy Agency Division of Electrical Engineering and Computer Science, Kanazawa University 3 Komatsu Industries Corporation, Japan 2 Abstract: The aim of this work is to investigate the effects of cathode holder shape, not the cathode insert, on hafnium (Hf) cathode evaporation by a developed two-dimensional numerical model for oxygen arc plasma in a torch. Results showed that the heat flux on the Hf cathode surface decreased markedly with the higher protrusion of the convex cathode holder by a rapid clockwise rotation of gas flow. Keywords: Plasma arc cutting, Hafnium evaporation, Shape of holder cathode. C 4 Radial position [mm] The plasma arc cutting (PAC) process is a technique widely used for cutting different metals with high-speed and high-accuracy in the industrial fields. Arc plasma is established between the electrode in the plasma torch and a work-piece. A summary of several investigations related to plasma arc cutting processes can be found in topical review [1]. During operation of a plasma arc cutting torch, the molten material is ejected from the surface of cathode insert. Thus, the shape of insert surface changes rapidly until reaching the preferred concave shape at steady state. As for the cathode with concave surface insert used in a plasma arc torch, it has been shown in patent literature [2, 3] that the curvature of this preferred concave shape is a function of the current level of the torch, and the diameter of the insert and the gas flow pattern in the torch. Use of this concave insert reduces deposition of the cathode material on the nozzle, and it thereby reduces nozzle wear in the torch. As discussed above, the geometry of the electrode including cathode insert has a marked effect on the characteristics of arc plasma. It is, however in general, too much complicated to investigate the interaction between thermal plasma and surface cathode insert shape such as evaporation of the cathode material. Experimental investigations of a plasma arc cutting torches with different shapes of the Hf cathode insert are very difficult because of the high running cost of plasma arc cutting. Another approach for the geometry of the electrode is to investigate the shape of a cathode holder, not a cathode insert. This holder structure may affect the characteristics of arc plasma, especially gas flow pattern. Thus, this can also control the amount of cathode material evaporation. The aim of this work is to investigate effects of cathode holder shape on Hf cathode evaporation by a developed two-dimensional numerical model for oxygen arc plasma. This paper paid attention to steady state evaporation of cathode material during arc cutting because it is also important for long operation of PAC torch. 185 divide inlet O2gas D 3 Electrode Swirl gas 20 divide Cu-nozzle F 2 Hf insert O2 gas E Current source Cu I 1 Hf 0 O K 10 divide G L Gas/plasma 0 H 2 68 divide 4 6 Axial position [mm] B Nozzle outlet A 8 Arc Work-piece plate Fig.1 Schematic diagram of a plasma cutting torch Radial position [mm] 1. Introduction 4 holder O 4 holder A 3 3 2 2 1 1 0 0 0 0 2 4 4 holder B 3 l=0.4 mm 2 l=0.5 mm 1 2 4 0 0 2 4 Axial position [mm] Fig.2 Shape of the cathode holder 2. Mathematical model 2.1. Calculation space and assumptions Fig.1 illustrates the schematic diagram of the arc model and the calculation space of the DC plasma cutting arc torch used in this work. The electrode is made of copper with Hf tip insert of 1.27 mm in diameter. Oxygen is used for plasma gas and is supplied from inlet by swirling gas flow. Arc plasma is constricted by copper nozzle with a nozzle outlet of 1.33 mm in diameter. The calculation is performed for different the shapes of the cathode holder shape, which are shown in Fig.2. In this figure, holder O is the original flat surface holder, which is usually used in the experiments. The holders A and B indicate two of convex cathode holder, which has a protruded. The shape of these holders is defined by a distance (l) from the flat surface of the cathode and top of the convex cathode holder at radial position of 1.6 mm. The holder A has the distance l of 0.4 mm, while holder B st 21 International Symposium on Plasma Chemistry (ISPC 21) Sunday 4 August – Friday 9 August 2013 Cairns Convention Centre, Queensland, Australia has distance l of 0.5 mm. The convex shape of holders A and B are formed as a part of an arc of an ellipse. the thermal conductivity of the solid/liquid, and represents the electrical conductivity of the solid/liquid. In this paper, the developed two dimensional numerical model assumes the followings: the gas flow is laminar, the plasma is in steady state and axisymmetric, the plasma is in the local thermodynamic equilibrium and optically thin, the effect of swirl gas flow is considered. In this model, the following additional heat flux is added to energy conservation equation for Hf: (10) 2.2. Governing equations for gas and plasma On the basis of assumptions described above, the gas and arc plasma are governed by following equations: The thermionic emission current density was given by the Richardson-Dushmann equation with Schottky effect: (11) (1) (12) - Mass conservation: (2) (3) (4) - Energy conservation: In these equations: , heat flux between the surface cathode and the plasma; , temperature of the plasma contacting with the cathode; , temperature of the surface cathode contacting with the plasma; , ambient temperature, here 300K as the wall temperature of nozzle; e, elementary charge; k, Boltzmann’s constant; , Stefan–Boltzmann’s constant; A, thermionic emission constant; , vacuum permittivity; , work function of Hf and Cu; , ionization energy of oxygen ion; , solid emissivity; , material factor for thermionic emission; , thermionic emission current density of electron; , ion current density; , electric field at the cathode surface; , thermal conductivity of the cathode; and , distance between surface cathode and the centre of control volume. (5) 2.4. Governing equations for evaporation flux - Mass conservation for Hf vapor: (6) The mass production rate attributable to evaporation is calculable approximately as - Ohm's law: (7) - Ampere's law: (8) In these equations, radiation loss; , radial coordinate; , electric field in the axial direction; , magnetic field in the azimuthal direction; , mass fraction of Hf vapour; , effective diffusion coefficient of Hf vapour in O2; , latent heat for evaporation; , the mass production rate because of evaporation; and I, the total electric current. 2.3. Governing equations for electrode Inside the solid and liquid, the energy conservation equation is established as follows: (9) where signifies the enthalpy of the solid/liquid, denotes the specific heat of the solid/liquid, stands for (13) Here, is the effective mass of Hf vapour, is the mass flux of evaporated vapour, is the mass flux of redeposition, is the surface of evaporated Hf and is the volume of the control volume. The mass flux of the evaporated vapour was calculated using the following Hertz–Knudsen relation as (14) where is the saturation vapour pressure of hafnium vapour. The saturation vapour pressure was evaluated using the Clausius–Clapeyron. The mass flux of redeposition vapour was calculated as (15) The governing equations were used to obtain the simulation results which have been set up in the previous works [4, 5] in more detail. st 21 International Symposium on Plasma Chemistry (ISPC 21) Sunday 4 August – Friday 9 August 2013 Cairns Convention Centre, Queensland, Australia Table 1. Thermodynamic properties of the solid material. Solid Cu Hf s (kgm-3) 8930 13310 Cps (Jkg-1K-1) 385.62 140 s (Wm-1K-1) 381 23 Tmelt (K) 1356 2506 Tboil (K) 2855 4876 2.5. Thermodynamic and transport properties Lv (MJkg-1) 4.815 3.211 [K] 35000 K 25995 K 19306 K 14339 K 10650 K 10000 1 7909 K 5874 K 4363 K 0 3000 3240 K 2407 K 1787 K 1 1328 K 1000 986 K 732 K 3 544 K holder B 2.6. Boundary conditions 404 K 300 300 K 0 2 4 6 Axial position [mm] 8 Fig.3 Temperature distributions of arc plasma 300 2 Heat flux [W/mm ] holder O 250 holder A 200 holder B 150 100 50 0 0.0 0.1 0.2 0.3 0.4 0.5 Radial position [mm] 0.6 Fig.4 Heat flux on the Hf cathode surface 3. Results 3.1. Effects of heat flux on cathode surface by the convex cathode holder 5.0 Temperature [kK] Fig.3 portrays the temperature distributions of the arc plasma with the shapes of the cathode holder of O and B. The isothermal color fringe for temperature is indicated in logarithm scale. The arc temperature profiles at axial position z>3 mm are almost the same to the three shapes of the cathode holder. On the other hand, it is apparent that the arc root near the cathode has expanded in the radial direction with the effect of the convex cathode holder. The arc root behaviour tends to move to the surface of the cathode holder with the higher protrusion of the convex cathode holders A and B. Another noticeable point is that the temperature inside the copper cathode holder is decreased in cases of the convex holders compared to the holder O. Fig.4 shows the radial distribution of the heat flux on cathode surface. In cases of the holder A and B, the heat flux at the radial position r<0.4 mm is lower compared with that for holder O. An increase in the protrusion of 33000 holder O 2 2 Fig. 1 also shows the computational domain used in this work. On the axis OA, axial symmetry condition is applied. Non-slip condition was considered on all the boundary wall between solid and gas GH, HI, EI and BD. The velocity inside the solid was fixed at 0 m/s. At copper wall around inlet OD and CD, temperature was fixed at 300 K. At the outlet AB, the axial gradients of physical parameters such as enthalpy and velocity were set to zero. The oxygen gas is injected from the inlet ED with a swirl component which can be expressed by the swirl gas angle. The boundary shape is assumed not to change by melting and evaporation. The SIMPLE method after Patankar [6] was used for the calculation scheme to solve the governing equations described in the previous section. In this paper, the operating parameters are that the swirl gas angle is fixed at 15 deg. The arc current of 100 A, and gas flow rate of 20 slm are fixed in this calculation model. Pressure at the inlet is also fixed at 0.9 MPa. W (eV) 4.65 3.53 3 Radial position [mm] Table 1 shows the thermodynamic properties of solid material for Hf and Cu. Thermodynamic and transport properties of oxygen thermal plasma with Hf vapor were calculated using the equilibrium composition and the collision integrals between species. These transport properties of Hf vapor were obtained by the first order approximation of the Chapman-Enskog method. Lm (MJkg-1) 0.206 0.1347 holder O 4.5 holder A 4.0 3.5 holder B 3.0 2.5 2.0 1.5 0.0 0.1 0.2 0.3 0.4 0.5 Radial position [mm] 0.6 0.7 Fig.5 Radial temperature of Hf cathode surface the convex cathode holder induces the expansion of the arc root resulting in a low current density in the immediate vicinity of the cathode, which decreases the efficient heating of the cathode surface. st 0.10 3 2 1 0 0 2 4 Axial position [mm] 0 2 4 Axial position [mm] Fig.6 Distributions of gas flow field -0.5 -0.3 -0.1 0.06 0.3 Radial position [mm] W-redeposition W/O-redeposition Holder B Holder O 0.4 0.6 0.8 Amount of mass loss [mg/s] Radial position [mm] 21 International Symposium on Plasma Chemistry (ISPC 21) Sunday 4 August – Friday 9 August 2013 Cairns Convention Centre, Queensland, Australia 6 0.08 0.06 0.04 0.02 1 [10 /s] 3 holder B holder O 0.00 O 2 -0.5x10 1 0 0 2 4 Axial position [mm] 0 2 4 Axial position [mm] Fig.7 Distributions of vorticity The radial distribution of the surface temperature of the Hf cathode for different the shapes of the cathode holder is presented in Fig.5. The Hf cathode surface temperature is decreased markedly around radial position r<0.4 mm with the effect of convex cathode holder. The higher protrusion of the convex cathode holder results in the lower Hf surface temperature. This decrease in the surface temperature is related mainly to arc behaviour, which decreases the heat flux on the surface of the Hf cathode by the effect plasma gas flow. Furthermore, there is no significant change in the holder surface temperature, which remains lower than the melting temperature of copper even though the effect of the convex cathode holder. 3.2. Gas flow pattern affected by convex cathode holder Fig.6 depicts a comparison of gas flow fields obtained with the shapes of the cathode holder of O and B. As a result holder O, the gas flow in front of the Hf cathode surface moves away from the cathode by effect of swirling gas flow. In the holder B case, it is noteworthy that a circular vortex appears in front of the Hf cathode in which the flow direction is mainly toward the cathode and moves in the direction against that of swirling gas flow. Fig.7 presents the spatial distribution of vorticity. Near the Hf cathode, the value of the vorticity is low for holder O. It appears a clockwise rotation in the vicinity of the Hf cathode with convex cathode holder B. 3.3. Effects of the convex cathode holder on evaporation amount of hafnium cathode Fig.8 shows the calculated total amount of mass loss of the hafnium cathode different the shapes of the cathode holder comparing with no redeposition of Hf vapour. The effect of the convex holder cathode reduces the amount of A B The shape of cathode holder 6 Fig.8 Amount of mass loss of Hf evaporation mass loss of the Hf cathode evaporation. The higher protrusion of the convex cathode holder induces the lower amount of mass loss, although this progress decreases slowly in comparison of convex cathode holder A and B. The reason for a decrease in the amount of mass loss is that the gas flow vortex close to the cathode surface is present to move in the clockwise direction. This gas flow vortex motion toward to the Hf cathode surface reduces the probability of evaporated Hf escaping from the cathode surface, and also facilitates the evaporated atoms returning to cathode surface. In addition, the redeposition of Hf vapour decreases the mass loss of Hf cathode. 4. Conclusions Numerical simulations were performed to study the influence of the shape of the cathode holder on Hf cathode evaporation for oxygen plasma cutting arc torch in this paper. The simulated results show that the convex holder cathode not only reduces the gas flow velocity from the cathode surface, but also makes a vortex in the vicinity of the cathode surface moving in the opposite direction. The heat flux on the Hf cathode surface decreases markedly with the higher protrusion of the convex cathode holder, resulting in a rapid clockwise rotation of gas flow. In addition, the total amount of mass loss of Hf cathode was predicted to decrease significantly with the effect of convex cathode holder. 5. References [1] V. A. Nemchinsky et al., J. Phys. D: Appl. Phys., 39, R423-R438 (2006). [2] L. Luo et al., Patent US 5,601,734 (1997). [3] S. Sakuragi et al., Patent US 5,177,338 (1993). [4] Nguyen Phi Long et al., J. Phys. D: Appl. Phys., 46, 224012 (2013). [5] Nguyen Phi Long et al., J. Phys. D: Appl. Phys., 45, 435203 (2012). [6] S. V. Patankar, Numerical Heat Transfer and fluid flow, Hemisphere Publishing (1980).
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