Calculation of the radiation emitted by isothermal arc plasmas in air and air-metal mixtures. Y. Cressault1, A. Gleizes1,2, G. Riquel3 1 Université de Toulouse, UPS, INPT, LAPLACE (Laboratoire Plasma et Conversion d'Energie), 118 route de Narbonne, F-31062 Toulouse Cedex 9, France 2 3 CNRS, LAPLACE, F-31062 Toulouse, France EDF France, Les Renardières, 77818 Moret-Sur-Loing Cedex Abstract: In order to evaluate the radiation received by workers located near accidental high intensity arcs we have performed the calculation of the radiation emitted along isothermal segments of air and air-metal thermal plasmas in seven spectral intervals corresponding to the classical domains defined as visible, infrared A to C and ultraviolet A to C. Two kinds of calculation have been developed: local emission (i.e radiation emitted by a point and escaping the segment) and total intensity integrated along the segment. The results show that for pure air the relative contributions of the various intervals depend on the temperature and that the absorption of radiation is almost negligible. In presence of metallic vapors the contribution of the UV parts is enhanced but can be largely attenuated by line self absorption. Keywords: radiation, electric arc, air, air-metal 1. Introduction The operators working on electrical installations of low, medium and high voltages can be accidentally exposed to short-circuit arcs ranging from a few kA to several tens of kA. In order to protect them from the thermal and glowing effects of these devices, the protections have to be optimized so as to respect the exposure limits. In order to do so, we need to characterize more precisely the electric arc, to consider it as a source of radiation and to evaluate the radiated power in order to estimate the radiation received by the workers and to limit the risks (Erythema, cataract, conjunctivitis, retinal burn, corneal burn, skin cancer). The maximum permissible exposure (MPE) values for the exposure of the human eye and skin to incoherent optical radiation from artificial sources are defined for seven wavelengths ranges : the UV radiations UVA (315-400nm), UVB (280-315nm) and UVC (100-280nm) that we have reduced to (200-280nm) because the radiation before 200nm is absorbed in ambient air; the visible radiations (380780nm) ; and the IR radiations IRA (780-1400nm), IRB (1400-3000nm) and IRC (3000nm-1mm) that we have limited to (3000nm-4500nm). These MPE depend on the duration of exposure and on the minimum angular subtense (visual angle subtended by the apparent source at the eye of an observer). The main objective is then to quantify, for spectral ranges, the energy radiated by a plasma arc of length between 0.1m and 2m and high intensity (4kA < I < 40kA) in order to compare it to the exposure limits. Three structures (EDF Renardieres, GREMI of Orleans and LAPLACE of Toulouse) have collaborated in this work. While EDF and GREMI are characterizing experimentally the arc and its environment (temperature, plasma compositions, local emission, radiated power, electrical parameters), LAPLACE is realizing a numerical model of such a device. First, we have to calculate the total radiation escaping from the plasma to compare it to the measurements. This work requires preliminary properties like the emission coefficients in this interval: λj ε Δ (T , X ) = ∫ κ λ' (T ) ⋅ L0λ (T ) ⋅ exp (κ λ' (T ) X )dλ (1) λi With κ λ' the total absorption coefficient, L0λ the black body intensity, and X the plasma's size. This first calculation gives us two indications: the spectral intervals where the radiation is the most important; and its absorption through the plasma. Then, we can simplify the calculation of the radiative transfer by separating the non-absorbed and absorbed radiations. Figures 1 and 2 present the emission obtained for pure air plasmas, different thicknesses, and the 7 spectral intervals defined earlier. 10 9 10 7 R p=10cm R p=0m R p=1mm R p=5mm R p=10mm 3 In this paper, we present one of the first steps of this large study corresponding to the calculation of required data which is the local emission (and absorption). We applied these calculations in the case of air plasmas at atmospheric pressure, with or without metallic vapours (Cu/Fe/Al), for temperatures between 300K and 30000K, for several thicknesses of plasma inferior to 10cm and the 7 spectral regions defined before. All radiative processes were considered: the molecular and atomic continua, lines and molecular bands of O2, N2 and NO. For Air-Cu mixtures and for each spectral interval, we present the net emission, the contribution of each wavelength range on the total radiation, and the influence of metallic vapours. Finally, we present a first calculation of the intensity L(X) obtained for pure air plasmas and for several distances X from the luminous source. Δ = λ j − λi is obtained by the sum of all the εΣΔ ( W/m /sr) temperature field, the local emission, the shape of the arc and the concentration of the metallic vapours issued from the erosion of the electrodes (iron, copper or aluminium). 5 P = 1 atm Pure Air Total of spectral intervals 10 3 5 10 15 20 25 30 Tem perature (kK) Figure 1. Net emission for air plasma and several thicknesses (200nm < λ < 4.5μm) 3 To calculate the net emission, we first have to estimate the different population number densities (versus temperature) and the spectral distribution. We then considered the radiation of the continuum spectrum (atomic and molecular continuum), of the molecular bands (O2, N2, NO) and of the atomic lines (6267 lines for Oxygen, 9313 lines for Nitrogen, 5180 lines for Copper and 95027 lines for Iron). The lines broadenings were taken into account but the influence of their overlapping on the radiative transfer was neglected. More information is available in a recent publication [1]. We calculated the net emission for the 7 spectral intervals according to the net emission coefficient (NEC). This coefficient preserves the spectral dependence (according to the wavelength) but simplifies the geometrical dependence of the plasma. It is also often used in the numerical models since it gives a good estimation of the net radiation of the plasma (by considering the absorption in the medium) in the hottest regions and its use is very simple. For homogeneous, isothermal and spherical plasmas (radius Rp), the NEC for each spectral interval 10 εΔ ( W/m /sr) 2. Net emission by spectral intervals 10 9 10 7 10 5 10 3 ΣΔ R p=0mm P = 1 atm Pure Air IRC 10 UVA UVB UVC Vis IRA IRB IRC Total 1 5 10 15 20 25 30 Temperature (kK) Figure 2. Emission of the 7 spectral intervals for air plasma. We observe that any wavelength range is negligible : the Visible radiation is systematically a significant 10 3 Figure 3 shows the emission obtained for optically thin Air-Cu plasmas. When a small concentration of vapours (<1%) is added to the plasma, this emission is strongly increased in Visible and UV. This behaviour can be explained by the presence of metallic resonance lines in these spectral regions. increases in the plasma, the Visible and IR contributions are weaker than the UVC radiation as shown in Figure 5. The same behaviour can be observed for Air/Fe mixtures in Figure 6. εΔ ( W/m /sr) contribution to the total radiation, the IRA part plays a role only for T<25kK (since the IRB and the IRC intensities are always ten times inferior to the maximum value); the UV part becomes more important for high temperatures. 10 9 10 7 10 5 10 3 10 5 10 15 20 25 30 Temperature (kK) 3 Figure 4. Net emission for the 7 spectral intervals, 99%Air-1%Cu mixture ans Rp=1cm. UVA UVB UVC Vis IRA IRB IRC Total 5 IRC Rp=0mm P = 1 atm 99% Air - 1% Cu Mass proportions 10 10 10 8 ΣΔ 1 5 10 15 20 25 30 3 10 1 ΣΔ εΔ ( W/m /sr) 3 εΔ ( W/m /sr) 10 7 UVA UVB UVC Vis IRA IRB IRC Total R p=1cm P = 1 atm 99% Air - 1% Cu Mass proportions IRC 9 10 10 ΣΔ Compared to Figure 3 (Rp=0), Figure 4 (Rp=1cm) shows that the total radiation of the 7 intervals is mainly absorbed in the temperature range 3000K17000K. The emissions of the IR parts are lower than the UVC part and are weakly absorbed. We also observe that the behaviour of the UVB and UVA emission is almost the same with a maximum emission and absorption around 7000K but the values are one order less than the UVC part. The lines are strongly emissive and partially absorbed in the UVC band which represents the major part of the total emission at high temperature. This behaviour was not remarked for pure air plasma and can be explained by the radiation of the Iron lines and specially the resonance lines which are more intensive and localised in UV spectral range. Consequently, the UVC part which does not play a significant role in air plasma becomes very important when iron, copper or alumina vapours exist inside. When the proportion of metal vapours 10 6 10 4 10 UVA UVB UVC Vis IRA IRB IRC Total R p=1cm P = 1 atm 90% Air - 10% Cu Mass proportions IRC 2 5 10 15 20 25 30 Temperature (kK) Figure 5. Net emission for the 7 spectral intervals, 90%Air-10%Cu mixture and Rp=1cm 3 Figure 3. Emission for the 7 spectral intervals, 99%Air-1%Cu mixture and Rp=0mm. εΔ ( W/m /sr) Temperature (kK) 10 9 10 7 10 5 10 3 ΣΔ IRC 10 UVA UVB UVC Vis IRA IRB IRC Total R p=1cm P = 1 atm 99% Air - 1% Fe Mass proportions 1 5 10 15 20 25 Temperature (kK) Figure 6. Net emission for the 7 spectral intervals, 99%Air-1%Fe and Rp=1cm. 30 30 28 24 22 2 4 3. Intensity by spectral intervals At a position x, the local emission is given by κ λ Lλ . This emission is then absorbed along a distance (Xx), X being the length of the segment. For an isothermal segment, at the exit X, the intensity is: ' [ X ] 0 U VC U VB IRC 26 L(X) ( 10 W/m /sr) Contrarily to Air/Cu and Air/Fe mixtures which present a similar shape for the emission (higher emission with iron), the results obtained with aluminium vapours are slightly different. without absorption pure air 10000 K 20 18 16 without absorption IRA 14 12 10 Vis 8 6 IRB 4 UVA 2 0 0 20 40 60 80 100 distance X (m m ) [ ( )] Lλ ( X ) = ∫ L0λ Kλ' exp − ( X − x)Kλ' dx = L0λ 1 − exp − Kλ' X (2) Figure 7. Influence of the distance X on the intensity L(X) for pure air plasmas. O We can write this expression for a given spectral interval Δ: LΔ ( X ) = λ2 ∫λ [ ( L0λ 1 − exp − K λ' X )] dλ (3) 1 In the introduction of this paper, we indicated that the overlapping of the lines was neglected. The radiative transfer of each line was then calculated by the use of the escape factor defined by Drawin and Emard [2]. This factor Λλ represents the ratio between the radiation flux (including absorption) escaping from the plasma and the radiation flux escaping from the plasma without absorption. Consequently, the escape factor allows us to calculate the part of the radiation of a line which is emitted at a point x and absorbed along a distance (X-x). We can then write the expression (3) with the use of the escape factor: λ2 X LΔ ( X ) = ∫ ε λ ∫ Λ λ ( x ) dx dλ λ1 ' (4) 0 For each line, we must integrate the escape factor for different distances X. This integration is not trivial because it depends on the temperature and the plasma’s size. We have tabulated this integration for temperature between 300 and 30000K, distances from 0 to 10 cm, and for several proportions of metal vapours. Figure 7 presents the intensity obtained for pure air plasmas. The dashed curve is obtained according to the relation (4) by considering the absorption whereas the full curve represents this intensity supposing any absorption in the plasma. 4. Conclusion We showed that the emission of air plasma is weakly absorbed whatever the spectral interval between 200nm and 4.5μm. Nevertheless, in presence of metallic vapours, the emission increases in the Visible and UV parts because of the metallic lines and of the increase of the electron number density at small temperatures. These lines are partially absorbed. We showed that metallic vapours in the plasma strongly modify the emission in the UVC part which becomes dominant for high temperatures. These results will be coupled with experimental measurements and with the numerical modelling of the arc. They will be used to estimate the radiative transfer for a real arc in order to calculate the radiative flux received by an observer positioned at various distances from the arc (for each spectral band UVC, UVB, UVA, Visible, IRA, IRB, IRC). The results also constitute a database which can either be used for the calculation of the radiative transfer or be directly used in numerical modelling to take into account the thermal properties of pure Air, pure metallic vapours (copper, aluminium or iron) or mixtures Air/vapours (for processes like arc circuit breakers or arc welding for example). This work has been supported by RTE-France Company (EDF transport). References [1] Y. Cressault, R. Hannachi, Ph. Teulet, A. Gleizes, J.-P. Gonnet, J.-Y. Battandier, Plasma Sources Sc. Technol. 17, 2008, 035016 [2] Drawin H.W., Emard F. Beitr Plasma Physik, 13, 143, (1973)
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