22nd International Symposium on Plasma Chemistry July 5-10, 2015; Antwerp, Belgium Comparison of plasma jets generated by a dielectric barrier discharge (DBD) and discharge with bare electrodes (DBE) by double probe measurements E.R. Ionita1, M. Bazavan2, M. Teodorescu1 and G. Dinescu1 1 National Institute for Laser, Plasma and Radiation Physics, 077125 Bucharest-Magurele, Romania 2 Physics Department, University of Bucharest, 077125 Bucharest-Magurele, Romania Abstract: In the present work we present estimated values of electron densities and temperatures using double probe measurements technique for two planar atmospheric pressure plasma jets. The plasma jets are generated in argon by a Dielectric Barrier Discharge (DBD) and Discharge with Bare Electrodes (DBE) plasma sources, powered by radiofrequency. Keywords: DBD, DBE, plasma jet, double probe 1. Introduction Recently, we have developed two atmospheric pressure plasma jet sources based on different discharge types but working in similar conditions. One of these two is Dielectric Barrier Discharge (DBD), uses a dielectric barrier at both electrodes, while the other one, Discharge with Bare Electrodes (DBE), has both electrodes in contact with the discharge. Both sources (Fig. 1) have the same geometry, the same discharge space respectively and have the same operating range in respect with the radiofrequency (RF) power and gas (argon) flow rate. Investigation of atmospheric pressure plasma with electrical probes is a difficult problem, due the collisional regime. Still, there are a few reports on this problem [1, 2]. Herewith we attempted to obtain and compare data on DBD DBE Fig. 1. Image with atmospheric pressure plasma jets DBD and DBE (Pfwd = 12 W, 5000 sccm argon flow) electron densities and temperature in the two plasma jets using double probe measurements. 2. Experimental Set-up Fig. 2 presents the experimental set-up designed for double probe measurements on both DBD and DBD plasma sources. The radiofrequency (RF) power supply used to generate the discharge in DBD and DBE sources, was a RF generator type Advanced Energy 136 CESAR C3 (13.56 MHz). The matching of the discharge impedance to the generator output impedance (50 Ω) was achieved through an automatic matching network type Advanced Energy Match Network. The RF forward P-I-2-15 power value investigated was 12 W (the reflected RF power value was 0 W). The DBD and DBE jet plasma sources were fed with gas (argon) by a mass flow controller type Bronkhorst High-Tech series EL FLOW. The double probe was inserted perpendicular to the plasma jet plane with equal distance from electrodes to the nozzle line. The probe consisted of two electrodes that penetrate the plasma jet. The electrodes are cylindrical, made of copper coated with gold, with a diameter of 0.45 Fig. 2. The experimental set-up used for double probe measurements on both DBD and DBE plasma sources. mm and a length of 15 mm. The distance between the electrodes is 2.54 mm. The electrodes were connected to a Source Measure Unit (SMU) Keithley 2410. The SMU was programed to sweep with 1000 steps the voltage range -175...175 V. 3. Results and Discussion To determine the temperature and the electron density were acquired current-voltage curves corresponding to the simple Langmuir probe and double probe with experimental system described above. In Fig. 3(a) are shown graphically, two current-voltage curves corresponding for the simple probe, in the DBD and DBE discharge, obtained at a flow rate of 2500 sccm of argon 1 2 ⋅ I1+ ⋅ I 2 + I1+ + I 2 + Ne ≈ k BTe T λ p A⋅ ⋅e⋅ ⋅ e ⋅ + M Tg R p 2 and 1.5 mm distance from the nozzle. Since both electrodes are isolated in DBD discharge, they are not being in electric contact with the plasma, simple probe characteristic cannot be evaluated similarly to the case of DBE discharge, where there is reference electrode. Consequently, in the present study were analysed only curves obtained with the double probe (Fig.3 (b)). 300.0µ 800.0n DBD, 12 W, 1.5 mm, Ar 2500 sccm DBE, 12 W, 1.5 mm, Ar 2500 sccm 600.0n DBD, 12 W, 1.5 mm, Ar 2500 sccm DBE, 12 W, 1.5 mm, Ar 2500 sccm 1.0µ 400.0n 200.0µ 200.0n 150.0µ 0.0 100.0µ 50.0µ -400.0n 0.0 Ip (A) Ip (A) Ip (A) 500.0n -200.0n 0.0 -500.0n -600.0n (a) -1.0µ -50.0µ (b) -100.0µ -800.0n -200 -150 -100 -50 0 50 100 150 -1.5µ -200 200 -150 -100 -50 0 50 100 150 200 Up (V) Up (V) T ⋅ 1 + g Te 1 ⋅ Λ where: A is the probe area in contact with plasma, M is the mass of an argon ion, Tg is the temperature of gas 1.5µ 250.0µ (2) Fig.3 Simple Langmuir probe curves (a) and double probe curves (b) for DBD and DBE discharge, obtained at 1.5 mm from nozzle and with 2500 sccm (400 K), R p is the radius of the electrode, λ+ is the mean free path of ions due to elastic collisions. Λ is a dimensionless parameter that takes into account the influence of the ionic current plasma cooling [4]; Λ ≈ 1 in the centre of the plasma and Λ ≈ 2 at the edge of plasma. In the present case we have Tg ≈ Tambient , and it was considered Λ = 1 . For the calculation of electronic temperature ( Te ) we used the relationship (1) [1, 2]: 1.40E+017 1.20E+017 0 ⋅ FD (1) 1.00E+017 Ne (m-3) 1 e I ⋅I Te = ⋅ 1+ 2 + ⋅ k B I1+ + I 2 + dI S dU S DBD, 12 W, 1.5 mm DBE, 12 W, 1.5 mm 8.00E+016 6.00E+016 where: e is the elementary charge, k B is the Boltzmann's constant, I1+ and I 2+ are ion saturation currents, I S current probe, U S the voltage applied to the probe and FD is electronic correction factor corresponding to Knudsen number; this factor expresses the influence of particle collisions in space charge layer around the probe [3]. 4.00E+016 2.00E+016 0 4000 6000 8000 10000 Flow Rate (sccm) Fig. 5 Electron density depending on the flow of argon, the double probe was placed at 1.5 mm nozzle. The obtained dependences of electron temperature upon the flow of argon obtained by applying relation (1) are shown graphically in Fig. 4. In the case of DBE discharge 68000 64000 Te increases DBD, 12 W, 1.5 mm DBE, 12 W, 1.5 mm 60000 Te (K) 2000 with gas flow, but having smaller values in the case of DBD discharge. The dependences of electron density (from (2)) upon the flow rate of argon, are shown graphically in Fig. 5. In both cases, DBD and DBE discharge, we have almost a linear increase of N e with gas flow increase. The N e 56000 52000 values for DBD discharge are lower than for the DBE discharge. 48000 0 2000 4000 6000 8000 10000 Flow Rate (sccm) Fig. 4. Electron temperature depending on the flow of argon, the double probe was placed at 1.5 mm nozzle. Electron density ( Ne ) was determinated For a DBD-DBE comparative representation of electronic temperatures, in Fig. 6 are presented the ratios of DBD and DBE and as well the ratio curves for electron densities. with relation (2): 2 P-I-2-15 22nd International Symposium on Plasma Chemistry July 5-10, 2015; Antwerp, Belgium Previous OES measurements of excitation temperatures (T exc ), based on Ar lines in a axial DBE source, performed on other atmospheric pressure jet plasma sources [5] indicated a result of T exc ≈1.5 eV The results obtained with the double probe in the present study indicated 3<T e <6.5, therefore systematically greater. [3] S. Klagge and M. Tichý, Czech Journal of Physics B, 35, 9 (1985). [4] X. M. Zhu, Y. K. Pu, N. Balcon and R. Boswell, Journal of Physics D: Applied Physics, 42, 14 (2009). [5] M. Teodorescu, M. Bazavan, E. R. Ionita and G. Dinescu, Plasma Sources Sci. Technol. 21, 055010 (2012). TDBD /TDBE , NeDBD/NeDBE e e 1.4 1.2 , 12 W, 1.5 mm /TDBE TDBD e e 1.0 NeDBD/NeDBE, 12 W, 1.5 mm 0.8 0.6 0 2000 4000 6000 8000 10000 Flow Rate (sccm) Fig. 6 DBD and DBE Ratio of electron density and temperatures for upon gas flow rate. In addition, when comparing the electron densities determined with the double probe (1016-1017 m-3) with those obtained from OES measurements (1020-5x1021 m-3) we noticed that the first are values systematically lower. A possible explanation could be given by a non-Maxwell distribution. Electron temperature and electron density obtained by double probe in such a case would be appropriate only for fast electrons group from plasma (higher temperature and lower density). 4. Conclusions We tentatively applied probe methods to investigate by probe methods DBD and DBE plasma jets. A comparison of results by single probe was not possible, the single probe measurements in DBE jets being inadequate. Instead, double probe measurements produced characteristics suitable for interpretation. However, the obtained values for electron densities and temperatures are different from the results produced by OES, difference which is assigned to the fact that in double probe techniques the tail of the distribution function is investigate. 5. Acknowledgements The financial support of the Romanian Ministry of National Education, UEFISCDI-CNCS, in the frame of the contract: PN-II-RU-PD-2012-3-0583 is gratefully acknowledged. 6. References [1] M. Čada, Z. Hubička, M. Šı́cha, Churpita, L. Jastrabı́k, L. Soukup and M. Tichý, Surface and Coatings Technology, 174–175, 530–534, (2003). [2] L. Prevosto, H. Kelly and B. R. Mancinelli, Review of Scientific Instruments 85, 053507 (2014). P-I-2-15 3
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