Hazardous Substances Emergency Events Surveillance (HSEES) Report for 2006 Minnesota Department of Health This report is supported by funds from the Comprehensive Environmental Response, Compensation and Liability Act (CERCLA) trust fund and the Office of Terrorism Preparedness and Emergency Response of the Centers for Disease Control and Prevention (CDC), provided to Minnesota Department of Health under a cooperative agreement by the Agency For Toxic Substances and Disease Registry, Public Health Service, U.S. Department of Health and Human Services. Minnesota Department of Health ♦ Division of Environmental Health ♦ P.O. Box 64975, St. Paul, MN 55164 651-201-4899, TTY 651-201-5797 Contents List of Tables List of Figures Executive Summary Introduction Methods Results Industries Substances Victims Nearby populations Evacuations Decontamination Response Prevention Activities in Minnesota Additional Use of MN HSEES data Summary of Results, 1995-2006 References Appendix Page iii iv 1 2 3 3 5 5 5 7 7 7 8 8 8 9 10 ii List of Tables Table 1. Number of events meeting the surveillance definition, by county and type of event—Minnesota Hazardous Substances Emergency Events Surveillance, 2006 Table 2. Number of substances involved per event, by type of event—Minnesota Hazardous Substances Emergency Events Surveillance, 2006 Table 3. Industries involved in hazardous substance events, by category— Minnesota Hazardous Substances Emergency Events Surveillance, 2006 Table 4. Substances most frequently involved in events – Minnesota Hazardous Substances Emergency Events Surveillance, 2006 Table 5. Number of substances involved, by substance category and type of event—Minnesota Hazardous Substances Emergency Events Surveillance, 2006 Table 6. Number of victims per event, by type of event—Minnesota Hazardous Substances Emergency Events Surveillance, 2006 Table 7. Frequency of substance categories in all events and events with victims— Minnesota Hazardous Substances Emergency Events Surveillance, 2006 Table 8. Frequencies of injuries/symptoms, by type of event—Minnesota Hazardous Substances Emergency Events Surveillance, 2006 Table 9. Distribution of personnel who responded to the event—Minnesota Hazardous Substances Emergency Events Surveillance, 2006 Table 10. Cumulative data by year—Minnesota Hazardous Substances Emergency Events Surveillance, 1995–2006 iii List of Figures Figure 1. Areas of fixed facilities involved in events—Minnesota Hazardous Substances Emergency Events Surveillance, 2006 Figure 2. Distribution of transportation events, by type of transport—Minnesota Hazardous Substances Emergency Events Surveillance, 2006 Figure 3a. Primary factors reported as contributing to events—Minnesota Hazardous Substances Emergency Events Surveillance, 2006 Figure 3b. Secondary factors reported as contributing to events—Minnesota Hazardous Substances Emergency Events Surveillance, 2006 Figure 4. Number of victims, by population group and type of event—Minnesota Hazardous Substances Emergency Events Surveillance, 2006 Figure 5. Distribution of injured responders, by type of responder— Minnesota Hazardous Substances Emergency Events Surveillance, 2006 Figure 6. Injury disposition—Minnesota Hazardous Substances Emergency Events Surveillance, 2006 Figure 7. Number of victims, by category and year—Minnesota Hazardous Substances Emergency Events Surveillance, 1995-2006 iv EXECUTIVE SUMMARY The Hazardous Substances Emergency Events Surveillance (HSEES) system, maintained by the Agency for Toxic Substances and Disease Registry (ATSDR), collects information to describe the public health consequences of acute releases of hazardous substances in participating states. This report summarizes events reported in Minnesota in 2006. Information collected about acute events involving hazardous substances includes the substance(s) and quantity released; time, place, and cause of the event; number of victims and injuries sustained; response; and public health protective actions taken. A total of 546 events were reported. In 518 (94.9%) events, one substance was released. The most commonly reported categories of substances were volatile organic compounds, ammonia, inorganic substances, and acids. During this reporting period, 31 events (5.7%) resulted in 68 victims (one death). The most frequently reported injuries were respiratory irritation, eye irritation, and trauma. Evacuations were ordered for 58 (10.6%) events. Prevention outreach efforts for 2006 involved providing HSEES information to emergency planners and the public through conferences, the Minnesota Department of Health (MDH) web site, and written materials. Because anhydrous ammonia is the most frequently released substance and often involves a public health impact, two activities were related to this substance. 1 INTRODUCTION The Centers for Disease Control and Prevention defines surveillance as the “ongoing, systematic collection, analysis, and interpretation of health data essential to the planning, implementation, and evaluation of public health practice, closely integrated with the timely dissemination of these data to those who need to know. The final link of the surveillance chain is the application of these data to prevention and control. A surveillance system includes a functional capacity for data collection, analysis, and dissemination linked to public health programs”[1]. Since 1990, the Agency for Toxic Substances and Disease Registry (ATSDR) has maintained an active, state-based Hazardous Substances Emergency Events Surveillance (HSEES) system to describe the public health consequences of releases of hazardous substances. The decision to initiate a surveillance system of this type was based on a study published in 1989 about the reporting of hazardous substances releases to three national databases: the National Response Center Database, the Hazardous Material Information System (HMIS), and the Acute Hazardous Events Database [2]. A review of these databases indicated limitations. Many events were missed because of specific reporting requirements (for example, the HMIS did not record events involving intrastate carriers or fixed facility events). Other important information was not recorded, such as the demographic characteristics of victims, the types of injuries sustained, and the number of persons evacuated. As a result of this review, ATSDR implemented the HSEES system to more fully describe the public health consequences of releases of hazardous substances. HSEES has several goals: ● To describe the distribution and characteristics of acute hazardous substances releases; ● To describe morbidity and mortality among employees, responders, and the general public that resulted from hazardous substances releases; and ● To develop strategies that might reduce future morbidity and mortality resulting from the release of hazardous substances. For a surveillance system to be useful, it must not only be a repository for data, but the data must also be used to protect public health. In the past few years, the last goal of the HSEES system has been emphasized; i.e., to develop strategies to reduce subsequent morbidity and mortality by having each participating state analyze its data and develop appropriate prevention outreach activities. These activities are intended to provide industry, responders, and the general public with information that can help prevent hazardous substances releases and reduce morbidity and mortality if a release occurs. 2 This report summarizes acute hazardous substance release events and associated public health consequences for 2006 in Minnesota and describes prevention activities to protect public health. METHODS In 2006, fourteen state health departments participated in HSEES: Colorado, Florida, Iowa, Louisiana, Michigan, Minnesota, New Jersey, New York, North Carolina, Oregon, Texas, Utah, Washington, and Wisconsin. Minnesota has participated in the HSEES program since 1995. While a few datacollection questions have been adjusted by ATSDR over time, information collected has consistently included substance(s) released, quantity released, event type, location, event cause, number of victims, injuries (adverse health effects and symptoms), evacuations, and other key data. Principal sources used to obtain information about these events included the Minnesota Duty Officer, the National Response Center, and the U.S. Department of Transportation Hazardous Materials Incident Reporting System. U.S. census data were used to estimate the number of residents in the vicinity of most of the events. Data were stored using a Web-based data entry system provided by ATSDR. HSEES defines hazardous substances emergency events as acute uncontrolled or illegal releases or threatened releases of hazardous substances. Events involving releases of petroleum only are excluded. Events are included if (a) the substance released could cause adverse human health effects or (b) the release of a substance was threatened, but the threat led to an action (for example, evacuation) to protect public health. All hazardous substances are included in quantities of a least one gallon or 10 pounds, unless the substance has been designated for inclusion at any amount. HSEES defines victims as persons who experience at least one documented adverse health effect within 24 hours after the event or who die as a consequence of the event. Victims who receive more than one type of injury or symptom are counted once in each applicable injury type or symptom. Events are categorized as transportation if they occur (a) during surface, air, pipeline, or water transport or (b) before being unloaded from a vehicle or vessel. All other events are considered fixed-facility events. For data analyses, the substances released were categorized into 16 groups. The category “Mixture” comprises substances from different categories that were mixed or formed from a reaction before the event; the category “Other inorganic substances” comprises all inorganic substances except acids, bases, ammonia, and chlorine; and the category “Other” comprises substances that could not be included in one of the other existing categories. A complete list of substance categories is available in the Appendix. RESULTS For 2006, 546 events were documented by Minnesota HSEES (MN HSEES): Three (0.5%) of these events were threatened releases and two (0.4%) were events in which 3 substances were both threatened to be released and actually released. The counties with the most events were Dakota (80 [14.7%]) and Hennepin (80 [14.7%]) (Table 1). A total of 342 (62.6%) events were in fixed facilities. For fixed facilities involving mining, utilities, or manufacturing, one or two types of area or equipment involved in the event could be selected. Among the 138 (40.4%) events with one type of area reported, the main areas were classified as follows: 39 (28.3%) ancillary process equipment, 22 (15.9%) process vessel, 18 (13.0%) material handling area, and 17 (12.3%) above ground storage. Seventeen fixed-facility (5.0%) events involved two locations. Many of these events involved ancillary process equipment (8 events) and/or piping (8 events) in combination with material handling areas, dump/waste areas, process vessels, storage areas, or transport within fixed facility. Percentages of area type for all reported locations (172) are shown in Figure 1. Of the 204 (37.4%) transportation events, 185 (90.7%) occurred during ground transport (e.g., truck, van, or tractor) and 12 (5.9%) involved rail transport. Five events involved pipeline transport and two involved air transportation (Figure 2). Most ground transportation events involved trucks (171, [92.4%]). The largest proportions of transportation events occurred en route and were discovered later at a fixed facility (82, [40.2%]) or during unloading of a stationary vehicle or vessel (66 [32.4%]). Primary factors contributing to events were reported for all 546 events (Figure 3a). Of the reported primary factors, equipment failure was the most frequently reported primary factor in (176 [51.5%]) fixed-facility events, and human error was most frequently reported in (148 ([72.5%]) transportation events. Secondary factors were reported for 389 (71.2%) events (Figure 3b). Of the reported secondary factors, equipment failure was most frequently reported for fixed-facility events (48 [22.4%]) and improper filling, loading or packing (108 [61.7%]) was most frequently reported for transportation events. More than 90% of all events involved release of only one substance. Two substances were released in approximately 4% of the events, and approximately 1% involved the release of more than two substances (Table 2). Fixed-facility events were more likely than transportation events to have two or more substances released in an event (7.0% vs. 2.0%). By month, number of events ranged from 32 (5.9%) in January to 71 (13.0%) in April, with over one third of all events occurring from April through June (196 [35.9%]). By day of week, proportion of weekday events ranged from 15.0% (Thursday) to 20.5% (Wednesday). For weekend days, 6.8% occurred on Saturdays and 6.2% on Sundays. The time of day or time category of event occurrence was reported for all 546 events. A majority of events, 332 (60.8%), occurred between 6:00 a.m. to 5:59 p.m., while 108 (19.8%) occurred from 6:00 p.m. to 11:59 p.m. and 106 (19.4%) events occurred from 12:00 a.m. to 5:59 a.m. 4 Industries The largest proportions of HSEES events were associated with transportation and warehousing (187 [34.2%]) and manufacturing (131 [24.0%]) industries (Table 3). The largest number of victim events occurred in the manufacturing industry (6 [19.4%]). Although manufacturing had a large number of events with victims, only 4.6% of 131 events resulted in victims. Some industries had a high percentage of events with victims, such as real estate (50.0%) and arts, entertainment, and recreation (28.6%), but overall number of events in these categories was small (2 and 7, respectively). The category with the most victims was the “Not an Industry” category (26, [38.2]), which often involved illegal acts or mishaps not related to an industry, such as inappropriate disposal of pepper spray. Wholesale trade, which includes farm cooperatives, had the next highest number of victims (10 [14.7%]). Substances A total of 584 substances were involved in all events, of which five (0.9%) substances were threatened to be released. The individual substances most frequently released were anhydrous ammonia; paints, coatings, inks, and dyes; and mercury (Table 4). Substances were grouped into 16 categories. The substance categories most commonly released in fixed-facility events were other inorganic substances (70 [18.7%]), ammonia (62 [16.5%]), and acids (46 [12.3%]). In transportation events, the most common substance categories released were paints and dyes (45 [21.5%]), volatile organic compounds (43 [20.6%]), acids (28 [13.4%]) and pesticides and fertilizers (28 [13.4%]) (Table 5). Two types of releases for each of the 584 substances released could be reported (e.g., spill and air release). Only one type of release was associated with the following: spills (422 [72.3%]), air releases (103 [17.6%]), fire (6 [1.0%]), threatened release (5 [0.9 %]), and explosion (3 [0.5%]). Of events with two types of releases, the following combinations were reported: spill and air release (25 [4.3%]), air release and fire, (7, [1.2%)], spill and fire (6 [1.0%]), spill and explosion (5 [0.9%]), and air release and explosion (2 [0.3%]). All substances had release types reported. Victims A total of 68 victims were involved in 31 (5.7%) events (Table 6). Of these, 22 (71.0%) events involved only one victim, and four (12.9%) involved two victims. Of all victims, 53 (77.9%) were injured in fixed-facility events. In events with victims, fixed-facility events were more likely to have three or more victims per event (18.2%) than were transportation events (11.1%). Additionally, seven persons in four events (0.7%) were observed at a hospital but did not have symptoms. They did not sustain injuries and were not counted as victims. To determine if type of substance(s) released in an event was related to number of victims in the event, substances released and victim totals were compared. In events that involved substances from the same substance category, substances were counted once in that category. In events that involved substances from different categories, substances were counted once in the multiple substance category. 5 The comparison showed that substances released most often were not necessarily the most likely to result in victims (Table 7). For example, events categorized as volatile organic compounds constituted 13.0% of all events but none of the victim events. Conversely, events in the multiple substances category were 4.0% of all events, but accounted for 22.6% of the victim events. Employees constituted the largest proportion of the population groups injured (36 [52.9%]), followed by general public (14 [20.6%]), responders (5 [7.4%]), student (1 [1.5%]), and unknown classification (12 [17.6%]) (Figure 4). All responder, student, and 11 of the unknown category victims were in fixed-facility events. Responder victims included 4 (80.0%) firefighters, and one (20.0%) police officer (Figure 5). Victims sustained a total of 78 injuries or symptoms (Table 8). Some victims had more than one injury or symptom. The most common injuries/symptoms in fixed-facility events were respiratory irritation (27 [43.5%]) and eye irritation (9 [14.5%]). In transportation events, trauma (6 [37.5%]) and eye irritation (6 [37.5%]) were reported most frequently. The trauma injuries in transportation events were not substance-related; these injuries resulted from a chain of events, such as a motor vehicle accident that involved release of a hazardous substance, and not from exposure to the substance itself. The median age of the 43 (63.2%) victims for whom exact age was reported was 39 years (range: 2─77 years). For the 14 (20.6%) injured persons for whom an age category was reported, 10 (71.4%) were 20-44 years of age, and two (14.3%) were 45-64 years of age, one (7.1%) was 15-19 years of age and one (7.1%) was less than 12 months. For the 11 injured persons for whom age was not reported, five (45.5%) were members of the general public and six (54.5%) were an unknown victim category. Sex was known for 58 (85.3%) victims: 38 (65.5%) were males. Of the 41 employees and responders, 30 (73.2%) were males. Severity was known for 66 (97.1%) of victims. The severity ranged from minor injury to death (Figure 6). One (1.5%) was observed at a hospital but did not require treatment. Eleven (16.2%) victims required only on scene first aid. Nine (13.2%) experienced adverse health effects that were reported by an official. Five (7.4%) victims were seen by a private physician and 37 (54.4%) were treated at a hospital but not admitted. Two (2.9%) victims required admission to hospital and one death (1.5%) related to trauma was reported. The status of personal protective equipment (PPE) use was reported for 34 (94.4%) employee-victims and for three (60.0%) responder-victims. Of these, most of the employee-victims (29 [85.3%]) and one (33.3%) of the responder-victims had not worn any form of PPE. Among the five employee-victims who wore PPE, two wore “level D” protection, three wore eye protection and one used gloves. The two injured emergency responders known to have worn PPE wore fire fighter turnout gear with respiratory protection. 6 There were two events that involved more than five people: one involving a large acid spill and one involving a pepper spray release. The first event involved a train tank car that spilled about 5000 gallons of hydrochloric acid in a rail yard. Vapor was emitted, resulting in respiratory irritation or eye irritation for at least seven persons. An evacuation was ordered for nearby areas and a shelter-inplace order was given for other surrounding areas. Most, if not all, victims were treated and released. The second event involved an unidentified chemical, thought to be pepper spray, release in an airport terminal. The cause of the release was not determined, but believed to have been unintentional. An area of the terminal was evacuated. Twenty-two persons were reported to have experienced eye irritation and/or respiratory irritation. Seventeen were transported for treatment at a hospital, while five others self-reported to the hospital or refused treatment. Nearby populations The proximity of the event location in relation to selected populations was determined using geographic information systems (GIS). There were 471 (86.3%) events with persons living within one fourth mile of the event; 537 (98.4%) events with persons living within one half mile; and 544 (99.6%) events with persons living within one mile. Additionally, there were industries or other businesses within ¼ mile of 464 (85.0%) events; recreational areas within ¼ mile of 133 (24.4%) events; licensed daycares within ¼ mile of 125 (22.9%) events; schools within ¼ mile of 108 (19.8%) events; nursing homes within ¼ mile of 14 (2.6%) events; and hospitals within one fourth mile of 6 (1.1%) events. Evacuations Evacuations were ordered in 58 (10.6%) events. Of these evacuations, 79.3% occurred in buildings or affected parts of buildings; 8.6% were of defined circular areas surrounding the event locations, 6.9% were downwind or downstream of the event, and 5.2% were in a circle and downwind/downstream from the event. The number of persons evacuated was known for 40 (69.0%) events and an estimate range was known for an additional 17 (29.3%) events. The number evacuated ranged from two to 1500 persons, with a median of 17.5. (Two events evacuated zero persons: the evacuation was ordered after no one was in the area). The median length of evacuation was 4.0 hours (range: 0.2 to 240 hours). Evacuation length was available for 54 (93.1%) events. Of all 546 events, 273 (50.0%) had restricted access to the area. In-place sheltering ordered by an official was reported for four events. Decontamination Of the 56 (82.4%) victims for whom decontamination status was known, 46 (82.1%) were not decontaminated, six (10.7%) were decontaminated at the scene, one (1.8%) was decontaminated at a medical facility, and three (5.4%) were decontaminated at both the scene and a medical facility. 7 In the 17 (3.1%) events where uninjured persons were decontaminated, the median number of uninjured decontaminated individuals was four persons per event (range: 1 – 110 persons). No decontaminations were done at a medical facility. Decontamination at the scene was done for 119 uninjured employees, 70 uninjured responders, seven uninjured members of the general public, and one uninjured student. Response Information on who responded to the event was available for all events. The category of No Response was reported in 28 (5.1%) events. Two or more responder categories were reported for 141 (25.8%) events, 73 (13.4%) reported three or more categories, and 49 (9.0%) reported four or more categories. Company response team (84.1%) responded most frequently to events, followed by fire department (16.5%), law enforcement (16.3%), and third party clean up contractor (11.4%) (Table 9). PREVENTION ACTIVITIES IN MINNESOTA During 2006, the MN HSEES program performed several prevention activities. These activities included: ● Creating a clickable map of MN HSEES events by county and posting it on the Internet. ● Evaluating the impact of the 2005 meth precursor laws on the number of meth labs in the state. This was an evaluation of the 2005 “Meth Day at the Capitol” activity. ● Providing a resource table, which included HSEES information about releases by county, at a community health conference in Brainerd, MN. ● Compiling a 2005 HSEES data report and posting it on the Internet. ● Coordinating a workshop session about ammonia releases for an environmental health conference. A presentation of meth-related ammonia releases was done at the conference. Of the above activities, one that seemed to capture the most interest was the evaluation of meth precursor laws. Two separate reports were completed as part of this project. The evaluations showed a drop in labs of about 66% after the meth precursor law implementation. The first report is posted http://www.health.state.mn.us/divs/eh/meth/ordinance/mnmethlabs2005.pdf. The second report was posted in late December 2006 at http://www.health.state.mn.us/divs/eh/meth/ordinance/mnmethlabs2006.pdf. ADDITIONAL USE OF MN HSEES DATA The MN HSEES program continues to receive requests for data for a variety of uses. Because the HSEES system has a comprehensive collection of unplanned hazardous substance release events and the associated impact on public health, emergency planners, response trainers, and health care facilities have requested the data for planning and training exercises. The data are often requested to determine patterns of hazardous substances releases within certain areas or to review trends in certain types of releases. Data continue to be available upon request by contacting the program. 8 SUMMARY OF RESULTS: 1995–2006 From 1995-2006, the largest proportion of events occurred in fixed facilities (Table 10). In recent years, however, transportation events have represented an increasing proportion of the total events. During 1995-2001 and 2003, transportation events were about one fourth or less of the total events. In 2002, 2004, 2005, 2006, transportation events were about one third or more of the total events. The cause for the increase is unknown, but could be related to more complete reporting from transportation companies to the U.S. Department of Transportation. It could also be related to a true increase in releases during shipping. The number of substances released per event has remained fairly constant, with an average of about one substance released per event for all years except 1995 and 2004. In 1995 and 2004, there were fires at a chemical manufacturer and a laboratory, respectively, which released many chemicals and increased the overall number of chemicals per event in these years. Overall, the majority of events (93.6%) involve only one substance. The percentage of events with victims from 1995-2006 is about 6.2%. The highest number of victims (172), as well as the highest percentage of events with victims (10%), occurred in 1995. The lowest percentage of events resulting in victims occurred in 2002 (4.5%) with a total of 16 victims. Respiratory irritation has consistently been the most frequently reported injury. The most frequently reported category of victims continues to be employees. However, members of the general public constitute a large proportion of the victims as well (Figure 7). The number of injured responders has generally remained low, though in 2005 an unexpected chemical reaction at a crash scene resulted in respiratory irritation and eye irritation for several responders. The number of deaths per year associated with acute hazardous substances events varied between zero and three from 1995-2006. Many of these deaths were attributed to circumstances surrounding the events that lead to chemical release (e.g., vehicle crash), and were not directly related to the chemical release. The MN HSEES program continues to strive toward conducting activities that will help reduce hazardous substance releases and associated public health effects. The HSEES program also works to provide quality data to agencies engaged in emergency planning and training, and continues to seek new opportunities for outreach. 9 REFERENCES 1. Centers for Disease Control and Prevention. Comprehensive plan for epidemiologic surveillance. Atlanta: US Department of Health and Human Services; 1986. 2. Binder S. Death, injuries, and evacuations from acute hazardous materials releases. Am J Public Health 1989;70:1042–4. Acknowledgements The MN HSEES program would like thank the Agency for Toxic Substances and Disease Registry for support and technical review; the Minnesota Duty Officer program, the National Response Center, and the U.S. Department of Transportation for hazardous substances release data; and representatives of public and private entities for assistance with HSEES data verification. 10 Appendix Table 1.─Number of events meeting the surveillance definition, by county and type of event— Minnesota Hazardous Substances Emergency Events Surveillance, 2006 Type of event Fixed facility County No. events All events Transportation %* No. events %* Total no. events (%) Aitkin 0 0 0 0 Anoka 23 54.8 19 45.2 42 (7.7) Becker 1 50.0 1 50.0 2 (0.4) Beltrami 1 100.0 0 0 1 (0.2) Benton 3 75.0 1 25.0 4 (0.7) Big Stone 0 0 0 0 Blue Earth 5 50.0 5 50.0 Brown 0 0 0 0 0 (0) Carlton 2 100.0 0 0 2 (0.4) Carver 3 50.0 3 50.0 6 (1.1) Cass 1 100.0 0 0 1 (0.2) Chippewa 2 100.0 0 0 2 (0.4) Chisago 1 100.0 0 0 1 (0.2) Clay 0 0 0 0 0 (0) Clearwater 0 0 1 100.0 Cook 0 0 0 0 0 (0) Cottonwood 0 0 0 0 0 (0) Crow Wing 2 100.0 0 0 2 (0.4) Dakota 48 60.0 32 40.0 80 (14.7) Dodge 6 85.7 1 14.3 7 (1.3) Douglas 0 0 0 0 Faribault 5 50.0 5 50.0 Fillmore 0 0 0 0 0 (0) Freeborn 4 100.0 0 0 4 (0.7) Goodhue 7 87.5 1 12.5 8 (1.5) Grant 0 0 0 0 Hennepin 60 75.0 20 25.0 Houston 0 0 0 0 0 (0) Hubbard 2 100.0 0 0 2 (0.4) Isanti 1 100.0 0 0 1 (0.2) Itasca 5 83.3 1 16.7 6 (1.1) Jackson 0 0 1 100.0 1 (0.2) Kanabec 0 0 0 0 Page 1 of 3 0 (0) 0 (0) 10 (1.8) 1 (0.2) 0 (0) 10 (1.8) 0 (0) 80 (14.7) 0 (0) Table 1.─Number of events meeting the surveillance definition, by county and type of event— Minnesota Hazardous Substances Emergency Events Surveillance, 2006 Type of event Fixed facility County No. events All events Transportation %* No. events %* Total no. events (%) Kandiyohi 3 75.0 1 25.0 4 (0.7) Kittson 2 100.0 0 0 2 (0.4) Koochiching 3 100.0 0 0 3 (0.5) Lac Qui Parle 0 0 0 0 0 (0) Lake 2 100.0 0 0 2 (0.4) Lake of the Woods Le Sueur 0 0 0 0 0 (0) 0 0 0 0 0 (0) Lincoln 0 0 1 100.0 1 (0.2) Lyon 7 100.0 0 0 7 (1.3) Mahnomen 0 0 0 0 0 (0) Marshall 0 0 0 0 0 (0) Martin 2 50.0 2 50.0 4 (0.7) McLeod 13 92.9 1 7.1 14 (2.6) Meeker 3 100.0 0 0 3 (0.5) Mille Lacs 0 0 3 100.0 3 (0.5) Morrison 0 0 1 100.0 1 (0.2) Mower 4 80.0 1 20.0 5 (0.9) Murray 1 100.0 0 0 1 (0.2) Nicollet 3 60.0 2 40.0 5 (0.9) Nobles 0 0 0 0 Norman 0 0 1 100.0 1 (0.2) Olmsted 9 90.0 1 10.0 10 (1.8) Otter Tail 5 71.4 2 28.6 7 (1.3) Pennington 3 100.0 0 0 3 (0.5) Pine 0 0 1 100.0 1 (0.2) Pipestone 0 0 1 100.0 1 (0.2) Polk 3 75.0 1 25.0 4 (0.7) Pope 1 100.0 0 0 1 (0.2) 19 39.6 29 60.4 48 (8.8) Red Lake 0 0 0 0 0 (0.) Redwood 0 0 0 0 0 (0) Renville 1 50.0 1 50.0 2 (0.4) Rice 3 60.0 2 40.0 5 (0.9) Ramsey Page 2 of 3 0 (0) Table 1.─Number of events meeting the surveillance definition, by county and type of event— Minnesota Hazardous Substances Emergency Events Surveillance, 2006 Type of event Fixed facility County No. events All events Transportation %* No. events %* Total no. events (%) Rock 1 100.0 0 0 1 (0.2) Roseau 4 80.0 1 20.0 5 (0.9) St. Louis 13 100.0 0 0 13 (2.4) Scott 3 75.0 1 25.0 4 (0.7) Sherburne 6 75.0 2 25.0 8 (1.5) Sibley 0 0 1 100.0 1 (0.2) Stearns 4 80.0 1 20.0 5 (0.9) Steele 8 53.3 7 46.7 15 (2.7) Stevens 0 0 0 0 0 (0) Swift 2 100.0 0 0 2 (0.4) Todd 1 33.3 2 66.7 3 (0.5) Traverse 0 0 0 0 0 (0) Wabasha 1 100.0 0 0 1 (0.2) Wadena 0 0 0 0 0 (0) Waseca 2 (0.4) 2 100.0 0 0 Washington 20 30.8 45 69.2 65 (11.9) Watonwan 2 50.0 2 50.0 4 (0.7) Wilkin 0 0 0 0 0 (0) Winona 3 100.0 0 0 3 (0.5) Wright 3 100.0 0 0 3 (0.5) Yellow Medicine 0 0 0 0 0 (0) 342 62.6 204 37.4 546 Total† * Percentage = (number of events by type of event per county ÷ total number of events in that county) x 100 Total may not equal 100% as a result of rounding. † Page 3 of 3 Table 2.─Number of substances involved per event, by type of event, Minnesota Hazardous Substances Emergency Events Surveillance, 2006 Type of event Fixed facility No. substances No. events % All events Transportation Total substances No. events Total No. substances events % % Total substances 1 318 93.0 318 200 98.0 200 518 94.9 518 2 19 5.6 38 3 1.5 6 22 4.0 44 3 2 0.6 6 1 0.5 3 3 0.5 9 4 2 0.6 8 0 0 0 2 0.4 8 1 0.3 5 0 0 0 1 0.2 5 342 100.1 375 204 100.0 209 546 100.0 584 ≥5 Total* *Percentages may not total 100% as a result of rounding. Table 3.─Industries involved in hazardous substance events, by category— Minnesota Hazardous Substances Emergency Events Surveillance, 2006 Industry category Accommodation and Food Services Total events Events with victims No. No. % Percentage of events with victims % Total no. victims Number (maximum)* 2 0.4 0 0 0 0 (0) Administration and Support and Waste Management and Remediation Services 15 2.7 1 3.2 6.7 1 (1) Agriculture, Forestry, Fishing and Hunting 34 6.2 4 12.9 11.8 6 (3) Arts, Entertainment, and Recreation 7 1.3 2 6.5 28.6 3 (2) Construction 4 0.7 0 0 0 0 (0) 16 2.9 3 9.7 18.8 5 (3) Finance and Insurance 0 0 0 0 0 0 (0) Health Care and Social Assistance 8 1.5 0 0 0 0 (0) Information 0 0 0 0 0 0 (0) 131 24.0 6 19.4 4.6 8 (2) Mining 11 2.0 0 0 0 0 (0) Other (includes residences) 19 3.5 0 0 0 0 (0) Professional services, Scientific and Technical Services 0 0 0 0 0 0 (0) Public administration 4 0.7 1 3.2 25.0 3 (3) Real Estate, Rental and Leasing 2 0.4 1 3.2 50.0 2 (2) Retail trade 0 0 0 0 0 0 (0) 187 34.2 3 9.7 1.6 3 (1) Utilities 22 4.0 0 0 0 0 (0) Wholesale trade 54 9.9 4 12.9 7.4 10 (7) Not an industry 20 3.7 5 16.1 25.0 26 (22) Not identified 10 1.8 1 3.2 10.0 1 (1) 546 99.9 31 100.0 5.7 68 (22) Education Services Manufacturing Transportation and Warehousing Total * † Minimum number of victims per event = 1. Percentages may not total 100% as a result of rounding. † Table 4.─Substances most frequently involved in events— Minnesota Hazardous Substances Emergency Events Surveillance, 2006 Rank Substance Number of releases and release threats 1 Anhydrous ammonia 73 2 Paints, Coatings, Inks and Dyes 54 3 Mercury 35 4 Sodium Hydroxide 28 5 Hydrochloric Acid 24 6 Sulfuric Acid 21 7 Nitrogen Fertilizer 15 8 Chlorine 14 9 Polychlorinated Biphenyls 12 10 Ethylene Glycol 11 10 Isopropyl Alcohol 11 Table 5.─Number of substances involved, by substance category and type of event— Minnesota Hazardous Substances Emergency Events Surveillance, 2006 Type of event Fixed facility Substance category No. substances Transportation % No. substances All events No. substances % % Acids 46 12.3 28 13.4 74 12.7 Ammonia 62 16.5 13 6.2 75 12.8 Bases 19 5.1 23 11.0 42 7.2 Chlorine* 15 4.0 0 0 15 2.6 Formulations 1 0.3 0 0 1 0.2 Hetero-organics 2 0.5 0 0 2 0.3 Hydrocarbons 2 0.5 3 1.4 5 0.9 Mixture 17 4.5 2 1.0 19 3.3 Other‡ Other inorganic substances¶ 27 7.2 8 3.8 35 6.0 70 18.7 5 2.4 75 12.8 Oxy-organics 30 8.0 4 1.9 34 5.8 9 2.4 45 21.5 54 9.2 Pesticides and fertilizers 19 5.1 28 13.4 47 8.0 Polychlorinated biphenyls 11 2.9 1 0.5 12 2.1 8 2.1 6 2.9 14 2.4 37 9.9 43 20.6 80 13.7 375 100.0 209 100.0 584 100.0 † Paints and dyes Polymers Volatile organic compounds Total * Includes one release of sodium hypochlorite (bleach). † Substances from different categories that were mixed or formed from a reaction before the event. ‡ Not belonging to one of the existing categories. ¶ All inorganic substances except for acids, bases, ammonia, and chlorine Table 6.─Number of victims per event, by type of event— Minnesota Hazardous Substances Emergency Events Surveillance, 2006 Type of event Fixed facility No. victims No. events Total victims % All events Transportation No. events Total victims % No. events Total victims % 1 14 63.6 14 8 88.9 8 22 71.0 22 2 4 18.2 8 0 0 0 4 12.9 8 3 3 13.6 9 0 0 0 3 9.7 9 4 0 0 0 0 0 0 0 0 0 5 0 0 0 0 0 0 0 0 0 ≥6 1 4.5 22 1 11.1 7 2 6.5 29 22 99.9 53 9 100 15 31 100.1 68 Total* * Percentages do not total 100% as a result of rounding. Table 7.─Frequency of substance categories in all events and events with victims— Minnesota Hazardous Substances Emergency Events Surveillance System, 2006* All events Substance category No. Events with victims % Percentage Percentage of events of all with releases victims in with substance victims category No. Acids 70 12.8 4 12.9 5.7 Ammonia 70 12.8 6 19.4 8.6 Bases 40 7.3 2 6.5 5.0 Chlorine 15 2.7 2 6.5 13.3 Formulations 1 0.2 0 0 0 Hetero-organics 1 0.2 0 0 0 Hydrocarbons 1 0.2 0 0 0 Mixture 18 3.3 2 6.5 11.1 Multiple substance category 22 4.0 7 22.6 31.8 25 4.6 2 6.5 8.0 Other inorganic substances 62 11.4 2 6.5 3.2 Oxy-organics 31 5.7 1 3.2 3.2 Paints and dyes 53 9.7 0 0 0 Pesticides and fertilizers 45 8.2 3 9.7 6.7 Polychlorinated biphenyls 12 2.2 0 0 0 9 1.6 0 0 0 71 13.0 0 0 0 546 99.9 31 100.3 N/A † Other ‡ § Polymers Volatile organic compounds Total¶ * Substances in events that involved multiple substances were counted only once in a substance category when all the substances were associated with the same category. If events involved multiple substances from different substance categories, they were counted only once in the multiple substance category. † Substances from different categories that were mixed or formed from a reaction before the event. ‡ Not classified. § All inorganic substances except for acids, bases, ammonia, and chlorine. ¶ Percentages do not total 100% because of rounding. Table 8.─Frequencies of injuries/symptoms, by type of event*— Minnesota Hazardous Substances Emergency Events Surveillance, 2006 Fixed facility Injury/symptom No. injuries Transportation No. injuries % All events Total no. % % Chemical burns 4 6.5 0 0 4 5.1 Dizziness/central nervous system symptoms 6 9.7 0 0 6 7.7 Eye irritation 9 14.5 6 37.5 15 19.2 Gastrointestinal system problems 2 3.2 0 0 2 2.6 Headache 1 1.6 0 0 1 1.3 Heart problems 0 0 0 0 0 0 Heat stress 0 0 0 0 0 0 Other 0 0 0 0 0 0 27 43.5 4 25.0 31 39.7 Shortness of breath 2 3.2 0 0 2 2.6 Skin irritation 3 4.8 0 0 3 3.8 Thermal burns 3 4.8 0 0 3 3.8 Trauma 5 8.1 6 37.5 11 14.1 Total‡ 62 99.9 16 100.0 78 99.9 Respiratory irritation † * The number of injuries is greater than the number of victims (68) because a victim could have had more than one injury. † Of the 11 trauma injuries, none were chemical-related. ‡ Percentages do not total 100% as a result of rounding. Table 9─Distribution of personnel who responded to the event— Minnesota Hazardous Substances Emergency Events Surveillance, 2006 Responder category No. %* Certified HazMat team Department of works/ utilities/ transportation Emergency medical services 33 6.0 11 2.0 40 7.3 Environmental agency/ EPA† response team 27 4.9 Fire department 90 16.5 Health department/health agency 5 0.9 Hospital personnel 0 0 Law enforcement agency 89 16.3 Other 3 0.5 459 84.1 4 6 0.7 1.1 62 11.4 Response team of company where release occurred Specialized multi-agency team State, county, or local emergency managers/coordinators/planning Committees Third party clean up contractors *Percentages total greater than 100% because multiple responder categories could be reported per event. † Environmental Protection Agency. Table 10.─ Cumulative data by year— Minnesota Hazardous Substances Emergency Events Surveillance, 1995-2006* Events with victims Type of event Year 1995 1996 1997 1998 1999 2000 2001 2002 2003 2004 2005 2006 Total Fixed facility 193 224 194 341 287 346 338 230 323 325 271 342 3414 Transportation 36 77 71 36 61 73 76 126 115 143 136 204 1154 Total 229 301 265 377 348 419 414 356 438 468 407 546 4568 No. substances released 386 340 283 440 370 459 472 376 499 740 456 584 5405 No. victims 172 73 19 66 62 83 50 85 83 64 52 68 877 No. deaths 0 0 1 0 0 1 0 1 3 1 0 1 8 No. 23 21 16 22 24 29 19 16 30 26 26 31 283 * Numbers in the table might differ from those reported in previous years because of adjustments in HSEES qualification requirements for events. † Percentage of events with victims. %† 10.0 7.0 6.0 5.8 6.9 6.9 4.6 4.5 6.8 5.6 6.4 5.7 6.2 Figure 1. Areas of fixed facilities involved in events, * Minnesota Hazardous Substances Emergency Events Surveillance, 2006 Ancillary process equip. 27.3% (47 events) Transformer/capacitor 5.2% (9 events) Other 1.7% (3event) Transport in facility 3.5% (6 events) Dump/waste area 7.6% (13 events) Process vessel 15.1% (26 events) Storage area 12.8% (22 events) Piping 13.4% (23 events) *Seventeen of the 155 events with areas reported involved two locations, for a total of 172 areas. Material handling 13.4% (23 events) Figure 2. Distribution of transportation events, by type of transport, Minnesota Hazardous Substances Emergency Events Surveillance, 2006 Rail 5.9% (12 events) Pipeline Air 2.5% 1.0% (2 events) (5 events) Ground 90.7% (185 events) Figure 3a. Primary factors reported as contributing to events, Minnesota Hazardous Substances Emergency Events Surveillance, 2006 Intentional Fixed Facility Transportation Primary factor Illegal Weather/Natural Disaster (includes temperature fluctuation) Equipment failure* Human error 0 50 *Eighteen events classified as "equipment failure" involved small ammonia releases caused by outdoor temperature fluctuation. They are included here in the "Weather/ Natural Disaster." 100 150 Number of events 200 250 300 Figure 3b. Secondary factor reported as contributing to events, Minnesota Hazardous Substances Emergency Events Surveillance, 2006 Power failure/electrical problems Overspray/misapplication Loadshift Fixed Facility Transportation Vehicle or Vessel collision Improper mixing Human error Secondary factor Explosion System startup/shutdown System/process upset Illicit drug production Fire Improper dumping Other Performing maintenance Vehicle or Vessel derailment/rollover/capsizing Forklift puncture Equipment failure Improper filling, loading, or packing No secondary factor 0 20 40 60 80 100 Number of events 120 140 160 180 Figure 4. Number of victims, by population group and type of event, Minnesota Hazardous Substances Emergency Events Surveillance, 2006 30 28 Fixed facility Transportation 25 Number of victims 20 15 11 10 8 8 6 5 5 1 0 1 0 0 Employees General Public Responders Population group Student Unknown Figure 5. Distribution of responder injuries, by type of responder, Minnesota Hazardous Substances Emergency Events Surveillance, 2006 Police Officer 1 Firefighters 4 Figure 6. Injury disposition, Minnesota Hazardous Substances Emergency Events Surveillance, 2006 40 37 35 Number of victims 30 25 20 15 11 9 10 5 5 2 2 1 1 Death Hospital observation (no treatment) 0 Treated at hospital Treated on scene (not admitted) (first aid) Injuries reported by an official Seen by private Treated at hospital (admitted) physician within 24 hours Injury disposition Unknown Figure 7. Number of victims, by category and year, Minnesota Hazardous Substances Emergency Events Surveillance, 1995-2006 90 85 81 Employees 80 General public Responders 70 Students 65 63 Number of victims 60 52 50 44 42 40 36 35 33 31 30 30 26 21 19 20 10 27 15 19 15 14 9 10 11 9 9 7 6 0 25 1 2 2 1996 1997 3 0 0 0 0 1 0 4 3 0 3 0 5 1 1 0 0 1995 1998 1999 *Category could not be obtained for 12 victims in one 2006 event. 2000 2001 Year 2002 2003 2004 2005 2006*
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