CP620, Shock Compression of Condensed Matter - 2001 edited by M. D. Furnish, N. N. Thadhani, and Y. Horie © 2002 American Institute of Physics 0-7354-0068-7/02/$ 19.00 THE DYNAMIC STRENGTH OF CEMENT PASTE UNDER SHOCK COMPRESSION K. Tsembelis, W. G. Proud and I.E. Field PCS, Cavendish Laboratory, Madingley Road, Cambridge, CBS OHE. UK. Abstract. A series of plate impact experiments on cement paste (grout) has been performed to assess the dynamic strength of this material. Lateral stresses have been directly measured by means of embedded manganin stress gauges. In combination with longitudinal stresses, measured previously [1], these results have been used to obtain shear strength under shock loading. Results indicate that the material is behaving in an inelastic manner with the shear strength increasing with increasing pressure. INTRODUCTION EXPERIMENTAL PROCEDURE Considerable interest in characterising the dynamic loading of concrete under impact conditions exists because of its extensive use as a structural material [2-5]. Concrete is a heterogeneous material containing aggregates in a cement matrix. Therefore, characterisation under dynamic conditions is complicated compared to homogeneous materials. For instance, impedance differences inside the concrete emanating from its different constituents lead to variations in the particle velocities, longitudinal and lateral stresses. One way to study this material is to average these variations using a plate reverberation technique, where a disc-shaped concrete specimen is mounted on the projectile and undergoes planar impact on a stationary target (PMMA, copper, tantalum) which is fitted with diagnostics [2-5]. However, only the Hugoniot curve (longitudinal behaviour) can be found using this technique. For this reason, the material understanding has been gradually built up starting from studies of the matrix (cement paste) and individual aggregates. In this paper, results are presented on the lateral behaviour of the matrix material, which are combined with published longitudinal data under the same impact conditions to determine the shear strength of the cement paste. All the impact experiments were carried out in the plate impact gun facility at the University of Cambridge [6], which consists of a single stage 50mm bore, light gas gun. The gun is capable of achieving velocities up to 1200 ms"1. The impactor materials consisted of Polymethylmethacrylate (PMMA), aluminium, or copper. Impact velocities were measured to an accuracy of 0.5% using a sequential pin-shorting method and tilt was fixed to be less than 1 mrad by means of an adjustable specimen mount. The cement paste specimen were 20 mm thick by 50 mm x 50 mm. Yr&asvwse stress Target Figure 1. Target configuration 1414 Backing plate (target material or FMMA) 9TCu and lOTCu respectively (for impact conditions, see Table 1). The solid trace corresponds to the longitudinal stress while the dotted trace corresponds to the lateral stress as obtained in [1]. It can be seen that the longitudinal stresses have higher values than the lateral ones and their difference leads to the shear stress inside the material according to equation 1. Each sample was sectioned in two, and commercial stress gauges (MicroMeasurements type J2M-SS580SF-025) were introduced at fixed distances between 2 mm and 7 mm from the impact surface of the sample. Samples were then assembled using a low viscosity epoxy with a curing time of approximately 24 hours. Lateral gauge data was reduced using the analysis of Rosenberg and Partom [7]. The gauge mounting positions and sample configurations are shown in figure 1. The shear strength ( ) of a material under one-dimensional shock loading can be calculated from knowledge of the longitudinal (ax) and lateral stresses (ay) through the relation, (1) Our method of determining the shear stress has the advantage over previous calculations of being direct since no computation of the hydrostat is required. 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 Particle Velocity (mm ps1) MATERIAL DATA Figure 2. Cement Paste Hugoniot Cement paste tested in this study was prepared and supplied by Concrete Structures Section (CSS), Department of Civil & Environmental Engineering, Imperial College, London, UK. The paste had a water-to-cement ratio of 0.35 by weight. Specimens were cured for 21 days in a water-bath at 20 °C. Density and ultrasonic measurements were performed after grinding samples from different batches. The density was 2.0 ± 0.2 g cm"3, while the longitudinal and shear elastic wave velocities, were 3.7 ± 0.2 and 2.2 ± 0.2 km s"1, respectively. Density variations resulted from different initial porosity. The density variations were in agreement with independent measurements performed by CSS. 0. o Time (ps) Figure 3. Stress Wave Profiles for experiment 9TCu. The results are presented in Figure 5. The shear stress data calculated from equation 1 are plotted against longitudinal stress. As a comparison, the data are also fitted to the assumed elastic behaviour given by equation, RESULTS AND DISCUSSION Table 1 summarises the impact conditions and lateral stresses as obtained from the gauges. In addition, the corresponding longitudinal stresses (Hugoniot curve) taken from [1] are also given and illustrated in Figure 2. Figures 3 and 4 illustrate some typical stress wave profiles for experiments 0 = - a 1415 x , (2a) Table 1. Experimental Parameters, Lateral Stresses and corresponding Hugoniot Data Shot no. Impactor material and thickness (mm) Impact Velocity (m s"1) Lateral Stress (GPa) 1TA1 2TA1 3TA1 4TA1 5TA1 6TCu 7TCu 8TA1 9TCu lOTCu 11TPMMA 12TCu lOmmAl lOmmAl lOmmAl lOmmAl lOmmAl lOmmCu lOmmCu lOmmAl lOmmCu 6 mmCu lOmmPMMA lOmmCu 352 1.00 ±0.03 2.00 ± 0.06 0.52 ±0.02 1.39 ±0.04 1.35 ±0.03 2.28 ±0.05 2.66 ± 0.08 1.64 ±0.14 2.94 ±0.1 5 3.75 ±0.15 0.09 ±0.01 4.69 ± 0.40 512 261 438 440 499 569 514 635 724 229 846 Corresponding Longitudinal Stress (GPa) 1.34 ±0.06 2.25 ±0.12 0.84 ±0.04 1.92 ±0.06 1.92 ±0.06 2.64 ±0.1 6 3.30 ±0.20 2.25 ±0.12 4.05 ±0.20 5.00±0.15 0.47 ±0.01 6.20 ±0.19 1-2V ——— 1-v (2b) where is the Poisson's ratio of the material (0.23). It can be seen that, within the data scatter due to the nature of the cement paste, the material behaviour deviates from the purely elastic behaviour around the HEL, which has previously [1] been measured to be 0.30 ± 0.05 GPa. In addition, the shear stress increases with increasing impact stress. Therefore, there must be some process such as fracture, or pore collapse, which reduces the strength, while the shear stress exhibits pressure dependence, which is indicative of the brittle nature of the material. Similar behaviour has also been observed in certain filled glasses [8] where the shear stress of the damaged material deviates from the elastic loading line and also increases with pressure. Time (MS) Figure 4. Stress Wave Profiles for experiment lOTCu. o. o CONCLUSIONS 2 3 4 Plate impact experiments have been presented to assess the shear behaviour of the cement paste. It is observed that above its HEL the material behaves inelastically indicating a process such as fracture or pore collapse reducing the strength. In addition, the shear stress increases with increasing pressure. 5 Longitudinal Stress (GPa) Figure 5. Cement Paste Shear Response 1416 8.Radford, D.D., Proud, W.G. and Field, I.E., To appear in: Proc. Of SHOCK 2001 - APS 12th Topical Conference on Shock Compression of Condensed Matter, Atlanta, 24-29 June, 2001. ACKNOWLEDGEMENTS The Defence and Evaluation Research Agency, UK has sponsored this work, under contract WSS/U3257. Dr. A. Pullen from Imperial College provided the cement samples. Dr J. Sheridan, C. O'Carroll, I.G. Cullis and P.D. Church are thanked for their interest. Finally, we thank D.L.A. Cross and R. Flaxman for technical support. REFERENCES 1.Tsembelis, K, Millett, J.C.F., Proud, W.G. and Field, J.E.. "The Shock Hugoniot Properties of Cement Paste up to 5 GPa",. in Shock Compression of Condensed Matter - 1999, (Edited by M.D. Furnish, L.C. Chhabildas and R.S. Hixson), pp. 1267-1270. 2. Grady, D. E., "Impact Compression Properties of Concrete", in Proceedings of the Sixth International Symposium on Interaction of Nonnuclear Munitions with Structures, Panama City Beach, Florida, pp. 172-175, May 3-7 (1993) 3.Hall, C. A., Chhabildas, L. C., and Reinhart, W. D., "Shock Hugoniot and Release States in Concrete Mixtures with Different Aggregate Sizes from 3 to 23 GPa," in Shock Compression in Condensed Matter-1997, edited by S. C. Schmidt et al., AIP Conference Proceedings 429, New York, 1998, pp. 119-122. 4. Grady, D. E., "Shock Equation of State Properties of Concrete," in Structures under Shock and Impact IV, edited by N. Jones et al., Computational Mechanics Publications, Southampton, 1996, pp. 405-414. 5.Kipp, M. E., Chhabildas, L. C., and Reinhart, W. D., "Elastic Shock Response and Spall Strength of Concrete," in Shock Compression in Condensed Matter-1997, edited by S. C. Schmidt et al., AIP Conference Proceedings 429, New York, 1998, pp. 557-560. 6. Bourne, N. K., Rosenberg, Z., Johnson, D. J., Field, J. E., Timbs, A. E., and Flaxman, R. P., Meas, Sci. Technol 6, 1462-1470 (1995). 7.Z. Rosenberg, and Y. Partom., J. Appl. Phys., 58, 3072-3076(1985). 1417
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