Facilities and Campus Services – EHS/RMS 3101 Science Circle CPISB Room 102B Anchorage, AK 99508 Solvent Explosive Limits Explosive Limits and Flammable limits are often used interchangeably to specify the lower and upper concentration ranges (in percent by volume) of a substance vapor in air that a flame will propagate. Concentrations below the lower explosive limit will not allow a flame to propagate and above the upper explosive limits a flame will not propagate. (i.e. Concentrations of the substances vapor below the lower limit are to lean to burn while those concentrations above the upper limit are to rich to burn.) CHEMICAL NAME EXPLOSIVE LIMITS Lower ← % → Upper Solubility H2O Liquid Density Water = 1 Vapor Density Air = 1 Acetaldehyde or Ethanal 4.0 60 Yes 0.785 1.5 Acetic Acid or Ethanoic Acid 4.0 19.9 Yes 1.049 2 Acetic Anhydride 2.7 10.3 Yes 1.08 3.5 Acetone or 2-Propanone 2.5 12.8 Yes 0.791 2 Acetonitrile or Methyl Cyanide 3.0 16.0 Yes 0.786 1.4 Acrolein or 2-Propenal 2.8 31 Yes 0.839 1.9 Allylamine 2.2 22 Yes 0.761 2 Amyl Acetate 1.1 7.5 Slight 0.876 4.5 Benzene 1.2 7.8 No 0.874 2.8 Butyl Alcohol or 1-Butanol 1.4 11.2 Yes 0.81 2.6 2-Butanol 1.7 9.8 Slight 0.808 2.6 Butyl Chloride or 1-Chlorobutane 1.8 10.1 No 0.886 3.2 Carbon Disulfide 1.3 50 No 1.266 2.6 Cyclohexane 1.3 8 No 0.799 2.9 Cyclohexanone 1.1 9.4 No 0.947 3.4 Denatured Ethanol 0.8 1.6 Yes 0.789 1.6 CD-5, CD-5A, CD-10, SD-1, SD-2B, SD-3A, SD-13A, SD-17, SD-23A, SD-30, SD-39B, SD-39C, SD-40M Dibutyl Ether or Butyl Ether 1.5 7.6 No 0.764 4.5 Cis-Dichloroethylene or Cis-1,2-Dichloroethylene 3 15 No 1.284 3.4 Trans-Dichloroethylene or Trans-1,2-Dichloroethylene 6 13 No 1.257 3.4 Diethylamine 1.8 10.1 Yes 0.707 2.5 Diethyl Ether or Ethyl Ether 1.9 36 Slight 0.706 2.6 Diisopropyl ether 1.4 7.9 Slight 0.725 3.5 2,2-Dimethyl Butane or Neohexane 1.2 7.0 No 0.649 3.0 N,N-Dimethylformamide 2.2 15.2 No 0.944 2.5 2,3-Dimethyl Pentane 1.1 6.7 No 0.695 3.5 Dimethylsulfoxide or DMSO 2.6 42 Yes 1.10 2.7 p-Dioxane 2.0 22 Yes 1.034 3.0 Divinyl Ether or Vinyl Ether 1.7 27 No Ethyl Acetate 2.0 11.5 Slight 0.902 3 Ethyl Alcohol or Ethanol in Water 96 % 0.8 1.6 Yes 0.789 1.6 95 % 0.8 1.6 Yes 80 % 0.8 1.6 Yes 70 % 0.8 1.6 Yes 60 % 0.8 1.6 Yes 50 % 0.8 1.6 Yes 40 % 0.8 1.6 Yes 30 % 0.8 1.6 Yes 20 % 0.8 1.6 Yes 10 % 0.8 1.6 Yes 5% 0.8 1.6 Yes 0.8 1.6 Yes 0.689 1.6 Ethylamine 2.4 Ethylbenzene 0.8 6.7 No 0.867 3.7 Ethyl Chloride 0.9 2.2 No 0.921 2.2 Ethylene Glycol 3.2 22 Yes 1.113 2.1 Ethylene Oxide 0.9 1.5 Yes 0.882 1.5 Formaldehyde 7.0 73 Yes 1.09 1 Formic Acid 18 57 Yes 1.22 1.6 Gasoline 1.4 7.6 No 0.71 - 0.77 4 Glycerol 3 19 Yes 1.25 3.1 1,4-Hexadiene 2.0 6.1 No 0.71 2.8 Hexane 1.1 7.5 No 0.672 3 Isoamyl Acetate 1.0 7.5 Slight 0.876 4.5 Isopentane or 2-Methylbutane 1.4 7.6 No 0.62 2.6 Isopropyl Alcohol or 2-Propanol 2 12 Yes 0.785 2.1 Kerosene 0.7 5 No 0.78 – 0.81 4.5 Methyl Alcohol or Methanol 6.7 36 Yes 0.791 1.1 Methyl Cyclohexane 1.2 6.7 No 0.77 3.4 Methyl Ethyl Ether 2 10.1 Yes 0.711 2.1 Methyl Ethyl Ketone or 2-Butanone 1.4 11.4 Yes 0.805 2.5 Naphtha 0.9 6 No 0.75 – 0.79 3 Nitromethane 7.3 ??? Slight 1.127 2 Paraldehyde 1.3 ??? Slight 0.994 4.5 Paraformaldehyde 7.0 73 Slight 0.88 1 Pentane 1.5 7.8 No 0.626 2.5 Petroleum Ether or Ligroine 1.1 5.9 No 0.64 2.5 Phenol 1.8 8.6 Yes 1.071 3.2 Propionaldehyde or Propanal 2.9 17 Slight 0.805 2 1-Propanol or Propyl Alcohol 2.2 13.7 Slight 0.804 2 Propylene Oxide 2.8 37 Yes 0.83 2 Pyridine 1.8 12.4 No 0.978 2.7 Tetrahydrofuran or THF 2 11.8 Yes 0.889 2.5 Toluene 1.1 7.1 No 0.865 3.2 Triethanolamine 1 10 Yes 1.124 5.1 Triethylamine 1.2 8.0 Yes 0.726 3.5 Triethylene Glycol Turpentine 0.9 9.2 Yes 1.124 5.2 0.8 ??? No 0.87 4.7 Vinyl Ethyl Ether m-Xylene 1.7 28 No 0.753 2.5 1.1 7.0 No 0.868 3.7 o-Xylene 0.9 6.7 No 0.879 3.7 p-Xylene 1.1 7.0 No 0.861 3.7 LAST UPDATE 7/28/2014 9:59:24 AM
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