Electronic Supplementary Material (ESI) for RSC Advances. This journal is © The Royal Society of Chemistry 2017 Supporting Information Table S1 The inhibitive efficiency (η) comparison of our studied inhibitors with other benzimidazole derivatives that previously reported elsewhere. Inhibitor structure Medium Concentration η (%) References 0.1 M H2SO4 1×10−3 M 34.3 This work 0.1 M H2SO4 1×10−3 M 62.8 This work 0.1 M H2SO4 1×10−3 M 88.5 This work 0.1 M H2SO4 1×10−3 M 99.8 This work 1.0 M HCl 1×10−4 M 95.0 [1] 1.0 M HCl 200 ppm 94.8 [2] 2.0 M HCl 100 mg/L 90.2 [3] 2.0 M HCl 100 mg/L 93.5 [3] 0.5 M HCl 200 ppm 80.1 [4] 0.5 M HCl 200 ppm 86.5 [4] 1.0 M HCl 1×10−3 M 96.0 [5] H N N H N NH2 N H N N H N O N S CH2 N H3CO CH3 H 3C OCH3 N O N H CH2 CH3 12 H N CH2CH3 N Ph N S N NH N Tol N S N NH N H N N Br CH3 N N Br N N N N H N H Inhibitor structure N η (%) References 1.0 M HCl 1×10−3 M 92.0 [5] 1.0 M HCl 1×10−3 M 91.0 [5] 1.0 M HCl 1×10−3 M 89.0 [5] HN N CH2 O H2C NH N HN N CH2 NH C N CH2 S H2C NH Medium H2C N HN References [1] D. Q. Zhang, Y. M. Tang, S. J. Qi, D. W. Dong, H. Cang and G. Lu, Corros. Sci., 2016, 102, 517-522. [2] R. Mohan, K. Ramya, K. K. Anupama and A. Joseph, J. Mol. Liq., 2016, 220, 707-717. [3] N. Esmaeili, J. Neshati and I. Yavari, Res. Chem. Intermed., 2016, 42, 5339-5351. [4] I. B. Obot, A. Madhankumar, S. A. Umoren and Z. M. Gasem, J. Adhes. Sci. Technol., 2015, 29, 2130-2152. [5] A. Dutta, S. K. Saha, P. Banerjee and D. Sukul, Corros. Sci., 2015, 98, 541-550. 2
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