Lehigh University Lehigh Preserve Theses and Dissertations 1993 Geotechnical aspects of sinkholes Mark J. Morrison Lehigh University Follow this and additional works at: http://preserve.lehigh.edu/etd Recommended Citation Morrison, Mark J., "Geotechnical aspects of sinkholes" (1993). Theses and Dissertations. Paper 211. This Thesis is brought to you for free and open access by Lehigh Preserve. It has been accepted for inclusion in Theses and Dissertations by an authorized administrator of Lehigh Preserve. For more information, please contact [email protected]. AUTHOR~ MOli'rison~ Mark J. T~TlE: Geotechnica~ Sinkho~es Aspects of Geotechnical Aspects of Sinkholes by Mark J. Morrison A Thesis Presented to the Graduate and Research Committee of Lehigh University . in Candidacy for the Degree of Master of Science In Civil Engineering I ~. __ I i I . Leliigh University -September 1,1993- Table of Contents [ Page Abstract Chapter 1 Chapter 2 Chapter 3 Chapter 4 Chapter 5 Chapter 6 1 Introduction 1.1 General Discussion 1.2 Lehigh Valley Sinkholes 1 2 History of Lehigh Valley Sinkholes 2.1 Sinkhole Formation 2.2 Prerequisites for Limestone Solution 2.3 Recent Increase in Activity of Sinkholes 5 5 11 3.1' 3.2 3.3 3.4 Geology of Lehigh County Pennsylvania Background Origin Limestone Formations in the Lehigh Valley Karstic Features in the Lehigh Valley 16 16 18 20 4.1 4.2 4.3 4.4 4.5 4.6 4.7 Pollution and its' Effects on Sinkholes Solid Waste Classification of Hazardous Wastes Landfills Waste Disposal Sites in Lehigh County Pollution in Carbonate Waste Decomposition Acid Rain 24 24 25 26 26 27 30 Landfills and Leachate 5.1 Landfill Liners 5.2 Landfill Testing and Design 5.3 Chemical Effects on Clay Liners 5.4 Movement Through a Clay Liner 5.5 Flexible Membrane Liner 33 33 35 35 36 Testing and Correcting Sinkholes 6.1 Introduction 6.2 Soils Investigation - 6:3- Foundation Design------ - -6.4 Recommendation~ to Prevent Accelerating Sinkhole Formation iii 39 39 41 44 ·0 Chapter 7 Use of Soil-Cement-Tire Aggregate as a Construction Fill Introduction 46 Laboratory Study 49 51 Materials , 52 Results Conclusion 53 Discussion of Test Results 54 Summary 55 7.1 7.2 7.3 7.4 7.5 7.6 7.7 References 64 Appendix 67 Vita 102 ~~-._-- iv --- :J:~ TABLES Page Table 2.1 Chemical Reactions for Solution of Limestone 7 Table 2.2 Solubility of C02 vs. Temperature 9 Table 2.3 Typical Wastes Generated in Pennsylvania 15 Table 3.1 Chemical Percentages of Lehigh Valley Limestones 17 Table 3.2 Limestone Formations of the Lehigh Valley 18 Table 4.1 Sources of Groundwater Pollution 29 Table 5.1 Parameters of Various Organic Compounds 34 Table 5.2 Chemical Compatibility of F.M.L. 38 v Page FIGURES Figure 2.1 Solubility of CaC03 vs. Partial Pressure of CO2 9 Figure 3.1 Geological map of the Lehigh Valley 22 Figure 3.2 Columnar section of the Lehigh Valley 23 Figure 4.1 Second Phase of Decomposition 29 Figure 7.1 Testing Apparatus Layout 49 Figure 7.2 Ultimate Load vs. Curing Period 58 Figure 7.3 Ultimate'Load vs. Modulus of Rupture 58 Figure 7.4 Ultimate Load vs. Slump 59 Figures A-1 Load / Stress vs. Deflection 67 -101 thru A-35 ---- ---- vi PHOTOS ;" Page Photo 7-1 Sinkhole in Lehigh Valley 60 Photo 7-2 Sinkhole in Lehigh Valley 60 Photo 7-3 Sinkhole in Lehigh Valley 61 Photo 7-4 Testing Apparatus 61 Photo 7-5 Typical cracking pattern 62 Photo 7-6 Typical failure surface 62 Photo 7-7 Cross section of soil-cement-tire sample 63 Photo 7-8 Soil-cement-tire interaction 63 --- vii - -----I I ABSTRACT The Lehigh Valley has been subjected to the formation of sinkholes in the regional limestone formations throughout it's history. In recent years sinkholes are more common due to the changes and increased demands on the local envirnoment. Some of the demands discussed include construction, dewatering and different types of pollution such as landfill leachate, air pollution, and acid rain. The formation of sinkholes is very dependent on the chemistry and dynamics of the groundwater. Correction of the sinkholes il]volves more than just filling in the void with a construction fill. Before any sinkhole is filled there needs to be an investigation into the magnitude of the problem as well as how to prevent it from reoccuring. A fill material composed of soil-cement and a tire aggregate was subjected to a third point loading tests to find the ultimate load and determine if the material possessed the strength required to be used as a fill for sinkholes. The testing was performed on test beams that had various initial moisture contents. The method used to determine the moisture content was through the use of a standard concrete slump cone. The slumps used were 0", 3", 5", 7" and 8". The purpose behind using the rubber tire as an aggregate was to find a way to fill a sinkhole with an aggregate to increase the volume of the soil-cement and at the same time find a way to relieve the increasing waste disposal stream of automobile tires. : - - - - - - -- IheJesults~howed ~hat the materiQldoes possess the properties required to u properly support the loads above the materialand on the surface. The highest strengths were obtained in the area of 7 to 8" slumps. I / CHAPTER 1 INTRODUCTION 1.1 ? GENERAL DISCUSSION The Lehigh Valley is an area subjected to unusual localized subsidence and settling of the ground surface called sinkholes. Sinkholes are depressions that have formed in the surface of the earth over a period of time in an area which is underlain by soluble carbonate formations. The frequently used geological phrase for a layer of soluble rock undergoing a _/ process of solution is called a "karst formation". The term karst refers to a / terrain which is underlain by limestone, dolomite, or gypsum that has sinkholes, closed surface depressions, cavities, and subsurface drainage. Within this formation are a series of faults, fractures and openings which permit water to freely move along the geological formation. Underlying the Lehigh Valley are layers of limestone approximately 800 to 1000 feet thick which are considered karstic in nature. The solution process occurs typically when the groundwater comes in contact with a soluble limestone allowing a chemical reaction to take place. The calcium carbonate (CaC0 3) present in the limestones is dissolved by the slightly acidic groundwater. The groundwater dissolves only the CaC0 3 and leaves the nonsoluble limestone and miscellaneous impurities found in the formation. The simplified chemica/reaction for the this process can be written as: CaC0 3 (solid) + H20 + CO2(dissolved) <-> Ca 2+ + 2HC0 3- (Eq 1-1) t CO 2 (air) 2 With the movement of water, the soluble carbonate rock slowly but continuously goes into solution via the chemical reaction. The reaction will continue to occur until the groundwater is completely saturated with the bicarbonate (HC0 3) and equilibrium is reached. This reaction involves more than just following the simplified chemical equation shown above. All of the reactions from dissolving the CO2 to the CaC0 3 going into solution are subject to many variables such as temperature, pressure, reactants available, reversible reactions and ionic dissolutions. The period over which the ground subsidence occurs is on a timetable of seconds to hundreds of years depending on how the solution has eroded the formation which is present below. 1.2 LEHIGH VALLEY SINKHOLES Sinkholes are occurring with greater frequency in recent years due to changes in the local environment of the Lehigh ValleY. The relatively recent growth of the Lehigh Valley has brought with it many changes. changes include, local construction activity, These changing the natural flow pattern of surface water, changes in the elevation of the water table, air pollution through incineration and water pollution through disposal of municipal and industrial wastes in landfills. New construction impacts the local environment in a number of significant ways. The first is that it applies new surface loads. The new loads include the addition of soil or the compaction of unconsolidated soil --deposits-to-aeh1eve-GHaAges-iA~the-gradaBlevatjon~QLto __cceJ:3JE:l. a stable foundation system upon which to build. Other loads include the weight of construction equipment such as cranes and bulldozers, or the weight of the 3 new structure being erected. Other considerable impacts that construction has on the environment include the 10.YJering of the water table while installing foundation work, changing the flow paths of s.urface and groundwater due to the increase in the runoff and grade changes, and shock loads from blasting operations. The increase in development in the area has brought with it an -. increase in the regions' population. As of 1986 the current population of Lehigh County stood at 282,000 with the growth rate increasing at approximately 4% per year. With the areas' increase in population follows an increase in of households. The rate of increase in the number of homes is running at 7%. During the 1970's alone there was a 24% increase in the number of houses in the County[1]. Disposal of the domestic and industrial wastes generated in the area also impacts sinkhole activity. Each additional person, on the average, generates 3.4 pounds of garbage each day and over 90% of that waste is I disposed of in landfills. This growing waste stream has a strong impact on the local environment depending on how the wastes are disposed of[2]. In the past sinkholes were filled with garbage ser:ving a double purpose. This filled the hole while at the same time it eliminated the wastes. The use of sinkholes and a sinkhole prone areas for disposing of solid and liquid wastes is no longer considered a viable option and is now strongly discouraged by most regulatory agencies. The problem is that the limestone --------fmoFFRatigR--PW\lides--surface~wateLalIlo[8_d.iLect path from the surface to the aquifers below. Normally surface water must move through the surface soil layers to get to the aquifers below which provides a filtration effect on the 4 water attenuating the water-borne pollutants. Rather than moving through the layers of soil the water flows to the aquifer with a minimum of soil interaction through the openings in the limestone formation. This presents the problem of easily contaminating the groundwater resources. If landfills must be placed in an area that is prone to sinkholes than the design of that landfill must take into account how the leachate affects both the containment liner and the limestone found below. Approximately 30 % of the drinking water for the Valley is drawn from the groundwater aquifers resources and is growing along with the population. Once again this increased water demand creates changes in the movement, or flow pattern, of the groundwater affecting the fragile subsurface equilibrium. Limestone regions in general are very susceptible to changes in the environment. Anyone of the changes that were listed above could hasten the formation of the sinks or any other karstic features. The following chapters look at the geology of the area, how the different problems impact the sinkhole formation process and, the correction of the sinkhole problems. -------- 5 CHAPTER 2 HISTORY OF LEHIGH VALLEY SINKHOLES 2.1 SINKHOLE FORMATION The term karst has long been used to define the sum of the phenomena limestones, characterizing regions where carbonate rocks, mainly are subject to the chemical reactions causing erosion of the formation. The process results in the development of surface and subsurface '" features that are distinctive to carbonate terrain. The most common karstic feature found in the Lehigh Valley is the sinkhole. Photos 7-1, 7-2,and 7-3 found in chapter 7 show sinkholes measuring 6' in diameter and approximately 6' in depth found in the Lehigh Valley. There are basically two different types of sinkholes; the collapse sinkhole and the solution sinkhole. The collapse sinkhole is formed by the collapse of the roof structure support over a solution opening. With the collapse of the roof the overburden soils will drop rather suddenly causing the surface to subside. This occurs normally over a period of seconds to months. The solution sinkhole occurs as the soil moves through the solution opening by means of the water movement through the region. This type of sinkhole has a much longer formation period in comparison to the collapse sinkhole and usually ranges from weeks to years. 2.2 PREREQUISITES FOR LIMESTONE SOLUTION The following prerequisites must be met in order for the sinkhole 6 \ o formation process to become active. 2.2-1 OPENINGS IN THE ROCK (POROSITY) There are two different types of porosity found in limestone formations, primary and secondary. Primary. porosity is a function of the pores or voids between the solid particles present within the rocks. The pores vary in size from microscopic to a few inches. Primary porosity is related to the sedimentary origins and diagenisis of the limestone. These initial pores are usually filled by lime, mud or calcite cement which decreases the primary porosity. Secondary porosity is a function of the cracking that occurs within the bedding planes of the formation. The cracks or fractures are theorized to occur from crustal warping, changes in stress, and desiccation. The cracks cause the bedding planes to form cubes of limestone ranging in size from one foot up to tens of feet. Groundwater will move through the entire volume of the rock by means of the primary porosity but the majority of groundwater flow will be through the formations secondary porosity. The water moves much quicker from the surface to the underlying aquifers when traveling along the fractures. The water movement through the limestone gradually increases both the primary and secondary porosity of the formation as the solution reaction occurs. Increasing porosity allows the water table to move down to greater --- ------ ~ ----- - - - - - - - - - - ------ depths below the surface. This causes the more common problems found in karst regions such as: scarcity and poor predictably of groundwater supplies, \ 7 ./ scarcity of surface streams, instability of cavernous ground, leakage of surface reservoirs, and-unreliable waste disposal environments. 2.2-2 THE PRESENCE OF CO2 IN SOLUTION FORMING CARBONIC ACID Groundwater is a slightly acidic solution within a pH range of 6 to 7 under normal conditions; The acidity is mainly a function of the dissolved c~ CO2 from the atmosphere and to a smaller degree of the biologic activity with which the water interacts. The acidic groundwater causes the carbonate rock to go into solution until the pH of the environment reaches equilibrium in the ~. range of 7 - 9. It is felt by most geochemists that the acidity from the CO 2 in the ground water, rather than other naturally occurring acids, is responsible for a large majority of solution of minerals in the soil environment. The sequence of chemical reactions for solution of limestone is as shown in table 2.1 below TABLE 2.1 CHEMICAL REACTIONS FOR SOLUTION OF LIMESTONE CO2 < H20> C020 Description Diffusion of CO into water (Eq 2-1) 2 C020 + H20 <->H 2C0 3 Formation of carbonic acid (Eq 2-2) H2C0 3 <-> H+ + HC03- Dissociation of carbonic acid (Eq 2-3) CaC0 3 <-> Ca 2+ + C0 32- Dissociation of calcite (Eq 2-4) Chemical Reaction H+ + col- <-> HC03- Association of C0 3 with H (Eq 2-5) The above system of reactions will go back and forth until equilibrium is reached. Once that point is reached no more calcite will go into solution. The chemical makeup of groundwater changes as it moves through 8 the sedimentary soil environment. The soil environment is separated into three zones. The highest zone, nearest the surface, is made up of water that is low in dissolved solids but high in bicarbonates with water movement causing solution of mineral salts from the rocks. The middle zone has the groundwater moving slower and picking up more minerals by solution. The deep zone has water moving very slowly and therefore leaching a great deal of dissolved solids. Limestone formations prone to sinkhole formation are generally found in the two upper zones. The concentration of CO 2 in the top zone and the solubility of the calcium carbonate are typically the constraining factors in the quantity of total dissolved solids present in the groundwater [3]. The concentration of CO 2 will vary with -changes in both the temperature and the pressure of the atmosphere. An upswing in the temperature increases the rate at which the limestone solution reaction occurs. The solution of limestone will increase from 0.015 gil at 25°C to 0.03-0.04 gil at approximately 100°C in a closed system. If the reaction is occurring in an open system, as is normally the case, the temperature rise will also cause a decrease in the partial pressure of CO 2 which slows down the reaction. Table 2-2 shows how 'the solubility of CO2 varies over different tem peratures using 10°C as the baseline solubility TABLE 2.2 - SOLUBILITY of COZ VS. TEMPERATURE[4] 10 20 30 40 TEMPERATURE(oC ) 0 FACTOR 1.28 1.00 0.78 0.64 0.43 (After Fookes, P.G. and Vaughn,P.R) Figure 2.1 shown below indicates solubility of CaC0 3 will vary with the 9 change in the partial pressure of CO2 , Normally the partial pressure of CO2 found in the soil is approximately 0.01 to 0.03 bar. From the chart it is apparent that if there is an increase in the pressure of CO 2 there will be an increase in the rate of solution of the limestone. For example, if the groundwater doubles the partial pressure from 0.01 to 0.02 bars there will be an twofold increase in solution of CaC0 3. 600 500 400 ~ 300 0' E r-r-, o '-6 200 u 100 o o 2 4 6 8 10 Partial Press. C02 (bar x 10·2) FIGURE 2.1 Solubility of CaC03 VS. Partial Pressure of C02[4] (After Fookes, P.G. and Vaughn,P.R) The degree of contact between CO 2 and the.rock material also effects the degree of solubility of the rock. The extent of contact ranges from an open system which is in contact with the atmosphere or some source of CO 2 to a closed system which is not in contact with a source of C02. The closed 10 - --------------------------- --- ~ - - - ~ ~ - - - - - - - - - -- - - ~ - system is normally found below the water table. As can be seen in the graph there is a much greater eroding effect near the surface with the open system than with the closed system. The temperature and pressure have opposite effects on the solution of the limestone. Since the reaction rate will increase with an increase in the temperature and decrease with the associated drop in the partial pressure the solubility of the rock will mainly be a function of the groundwater chemistry. 2.2-3 FAVORABLE TOPOGRAPHIC AND STRUCTURAL SETIINGS Topographic and structural setting that influence the development of sinkholes and other karst features include some of the following items: the permiability of the overlying soils which governs the supply of water interacting with the limestone formation, the thickness of the formations may not possess an adequate amount of soluble limestone to create a cavity, joints or fissures allowing water movement within the formation, presence of clay or shale beds which separate the limestone layers, and the strength of the rock, 2.2-4 ADEQUATE PRECIPITATION AND AN ABILITY FOR THE WATER TO KEEP MOVING THROUGH THE ROCK FORMATION The Lehigh Valley receives on the average 43" of precipitation a year and ranges from 29" to 58". The distribution of the precipitation is fairly uniform throughout the year. This provides an adequate amount of runoff to subject the limestone in the area to the solution process. 11 --- .-_._-- --------- --~---- 2.2-5 THE PRESENCE OF SOLUBLE ROCK WITH AN APPROXIMATE CALCIUM CARBONATE PERCENTAGE OF AT LEAST 50% The limestone found in the Lehigh Valley has approximately 51 to 52% calcium carbonate percentage. See Chapter 5 for a complete chemical makeup of limestone in this area. 2.3 RECENT INCREASE IN ACTIVITY OF SINKHOLES 2.3-1 POPULATION GROWTH The relative increase in the formation of sinkholes is due to a number of factors being imposed on the environment by society. In recent years the Lehigh Valley has been subjected to a growth industry bases. environment. in both the population and These two factors play very heavily on the Valley's The increase required that more homes and industrial buildings be constructed to support the new growth. This changed the land usage from what was once a rural farm area into a suburban community with homes, business and supporting infrastructure. These changes have an impact on the special limestone environment of the Lehigh Valley. The karst environment is created largely by the movement of water through the local limestone formations over millions of years. The structure of the formations and karstic features are slow in forming and changing under natural undisturbed conditions. With the increase in development of the area the balance of nature has been changgd. There is an increase in water consumption, for household use, waste disposal, and industrial needs. Many of these requirements are filled by obtaining water from the local aquifers. ground and directed as required. The water is pumped out of the This draw on the aquifer changes the 12 ------~. __ .-._._--~-~--"--~----._----_._------------------"-------_. -~-~-_. __ ._--- dynamics of the water table and the geology with which it interacts. '. Sinkholes develop in residual or alluvial deposits overlying openings in the subsurface limestone. The downward migration of the soil deposits into the openings of the underlying limestone formation and the collapse ofthe roofs of the cavities are accelerated by a decline in the water table. For example, the soils which were once supported by the buoyant forces of the water are now bearing their full weight on the underlying structures. The additional weight may put the underground structures under greater stresses causing a collapse of the structure. The change in the water table dynamics also involves increasing the drawn down which accordingly increases the hydraulic gradient. It should be noted that if the water table is allowed to return to its level than there is a drastic decrease or cessation in sinkhole development. The increase in development in the area changed not only the subsurface water flow but also the surface water flow. The increased runoff due to the reduced permiability of the surface from pavement, and houses increases the amount of water being disposed of. The rerouting of storm water runoff is probably the most common cause of. increased sinkhole formation due to the leakage of water from the underground piping. One example of a sinkhole forming due to improperly drained surface runoff occurred in the borough of Macungie in 1986. Macungie was growing and new homes and apartment complexes were being built. The new residences caused an increase in the surface water runoff due to reduced permiability of the ground surface. The additional runoff was directed into the storm sewer system was to be directed 13 -~-----------------------~---------- out oi the area but due to poor sewer construction the water entered the local subsurface environment. The problems of the storm water runoff was compounded by the newly installed septic systems for each of the homes. These factors increased the amount of water moving through the sinkhole prone formation and sped up the rate of sinkhole formation. The sinkhole that formed due to these changes was 125 ft. wide and 45 ft. deep.[3] 14 FIGURE 2.3 - TYPICAL WASTES GENERATED IN PENNSYLVANIA.[6] Sources Types of Waste Approximate Composition Food and Food Products Food Additives Sludges Organics & Acids Meat Residues Grain Mills Trimming Wastes Textile Products Cotton, Wool, Synthetics Sludges Acids, Alkalis, Metal Salts and Solvents Paper and Paper products Sludges, Pulping Sulfates, Organics, Soaps Mercaptans Soaps, Detergents SlUdges Surfactants, Polyphosphates Aluminum-capper-oxides Chemicals, Fertilizers Sludges Sulfuric acids, Organic Phosphorus, Copper Sulfate Mercury Arsenates Paints, Varnish Sludges Metal Salts, Liquid Toxics Petrole.um Refining Sludges, Fly Ash Acids, Hydrocarbons, ME:tallic salts Leather and Products Sludges Chrome Salts, Oils, Dyes, Organic Acids Metals and Fabricated Metals Sludges Sulfur, Ammonia Chlorides Phenols, Oils, Chrome, Alkalis Acids, Metallic Salts (After Fang, H.Y.) 15 CHAPTER 3 GEOLOGY OF LEHIGH COUNTY 3.1 BACKROUND The geology of Lehigh County Pennsylvania according to the US geological survey is made up of a small part of the Appalachian Highlands which covers an area from Canada to central Alabama and from the coastal plain on the east to the interior plains on the west. This area is then divided into provinces and then the provinces into sections. The sections in the Lehigh area are the Triassic Lowlands, the Reading Prong, the Appalachian Valley, and the Lehigh Valley. The overburden above these formations is made up of residual soils, alluvial granular and colluvial soil types deposited by water flow as well as gravity during the movements of the geologic structures. 3.2 ORIGIN Most of the surface rocks in the Lehigh Valley are sedimentary in origin. They were originally placed as loose sediments composed of sand - --_.~----_.~-----~_._ .. _----_.. _- - - - - ---~._~ - - - - - - ---- ----- pebbles, mud and calcareous ooze. The sedimentswere orougflCtcQfjeif final resting place by the streams and rivers flowing from an adjacent land mass locc:ited to the southeast. The sediments were compacted by great pressures and eventually formed the sandstones, shales, conglomerates and limestones which are currently found in the Valley. Limestone found in this area varies greatly in terms of its purity, color, and texture. The variations are due to the manner in which the sediments 16 ---------------- ------~---- were deposited as well as what other materials were physically present during deposition. Limestone is organically and chemically derived and is composed mainly of calcium carbonate wLtP lesser amounts of impurities. The most common impurities found in limestone are magnesia, silica, clay, iron, and bituminous of organic matter. The color of the limestone changes according to what impurities are present in the rock. Pure limestone is composed of only calcium carbonate and is white. As the percentage of impurities increases the color will vary from many shades of gray to black. The composition of some samples of limestone are shown in Table 3.1. TABLE 3.1 - CHEMICAL PERCENTAGES OF LEHIGH L1MESTONES[7] ~ Sample CaCo 3 CaO MgCo 3 MgO Si0 2 AI20 3 Fe 20 3 1_ _2_ _3_ _4_ _5_ _6_ 52.08 51.60 51.73 27.8 18.23 28.33 41.29 42.60 45.35 18.01 19.20 19.79 8.97 3.80 3.30 1.20 6.40 3.89 1.12 1.75 0.65 1.39 1.40 0.79 0.52 0.66 (After Miller, Benjamin L) ---1) Tomstown L:imestone ~-Center Valley2) Tomstown Limestone - East Allentown 3) Tomstown Limestone - Lehigh River 4) Allentown Limestone - Allentown 5) Beekmantown Limestone - Friedensville 6) Beekmantown Limestone - Freidensville The variations in limestone is also reflected in the texture, and strength. The texture varies from fine grained compact rocks to course pieces of shells and coral. The bearing strength of the limestone ranges from 3,500 to 12,000 pounds per square inch and occasionally higher. The weight 17 of limestone runs between 120 to 170 pounds per cubic foot. 3.3 LIMESTONE FORMATIONS IN THE LEHIGH VALLEY Within the Lehigh· Valley there is a series of limestone layers approximately 4000 feet thick which belongs to the Cambrian and the Ordovician periods. The layers are distributed throughout the various townships in Lehigh county located within the Great Valley. The Great Valley cuts across the towns of Allentown, Bethlehem, Fogelsville, Macungie and Emmaus. The limestones found in the Lehigh area and their thic~nesses are shown in the table below. TABLE 3.2 - LIMESTONE FORMATIONS OF LEHIGH COUNTY[7] Ordovician Period Thickness Martinsburg shales and slates overlying the limestones Jacksonburg low-magnesium argillaceous limestone. 600 ft Beekmantown limestone composed of alternating high and low-magnesium beds 1000 ft Cambrian Period .. ~.ConocQc;heaRuE3{I\I~!l!g~Q}SlgJolTljtic limestone Tomstown dolomitic limestone Hardyston sandstone and quartite under the limestone. 1500 ft 1Do-dfC-·~···_····· (After Miller, Benjamin L) See Map-3.1 (21) and Figure 3.2 for illustrations of the geology of the Lehigh Valley, and a columnar section of rocks of this area respectively. In the Lehigh Valley the Pre Cambrian formations are the oldest. These formations are very highly metamorphosed igneous rocks and are usually overlain unconformably by Cambrian rocks of the Hardyston, 18 Leithsville, and Allentown, formations. Some of the characteristics of the different formations listed in the table above are detailed in the following sections. 3.3-1 ALLENTOWN FORMATION The Allentown Formation overlies the Leithsville Formation. It is composed of heterogeneous dolomites. The coloring is medium light gray to dark gray and will usually be found as a weatliered light gray. The formation is interspersed with beds of bedded chert, quartz and sandstone. This is the most widespread limestone formation found in the Lehigh Valley and it is most predominate in the southern half of the limestone valley 3.3-2 BEEKMANTOWN FORMATION The Beekmantown Formation is the beginning of the Lower Ordovician rocks an,d overlies the Conocochague Formation.The formation is composed of two layers of limestone. The first is Rickenbach dolomite which is made up of thinly laminated to thickly laminated crystalline dolomite, nodular chert with \lE;ry_~hi~ __layers of quartz and sand. The second layer is made up of ---- --~?_----- interbedded limestone, argillaceous limestone and dolomite with nodularchert. These limestone are generally laminated gray to medium dark gray. This formation is generally found in the northern part of the valley. 3.3-3 JACKSONBURG FORMATION The formation is made up of cement limestone and cement rock facies. The cement limestone is medium to dark gray and if properly treated 19 ---~---_._- it can be used as a hydraulic cement. The cement rock facies are high calcium argillaceuos limestone which comes to a mediulTIlight gray to pale yellow brown. The Jacksonburg rocks contain up to 30% clay. This layer is the most impure of the limestones in the Lehigh Valley. 3.3-4 MARTINSBURG FORMATION This formation is made up of three different units. Ramseyburg, the Bushkill, and the Pen Argyl. They are the The formation is a medium dark to dark thin bedded claystone slate which contains small beds of quartzose, graywacke sandstone and siltstone. 3.3-5 LEITHSVILLE FORMATION The formation consists of a series of interbedded series of light to dark gray dolomite, and tan phyllite with small stringers of quartz sand. 3.4 KARSTIC FEATURES IN THE LEHIGH VALLEY The Allentown, Beekmantown, and ../ Leithsville formations are considered very prone to solution enlargement of their joints and cavernous rock zones. The primary porosity of these formations is very small but the solution enlargements, or secondary porosity, creat~ a condition that greatly influences the movement of the groundwater. The Jacksonburg and Martinsburg formations are generally considered to impede the flow of the groundwater. The Lehigh Valley limestones started undergoing the sinkhole causing solution process at the end of the Mesozoic period. 20 The results of the solution has left a series of sinkholes, solution cavities, and other karst type features through out the Valley. solution process. These features are still undergoing the Most of the surface features that are associated with "- sinkholes have been filled or covered up by the thick residual soil present in the county. <' 21 iP,.t.p.~ - '_J . -~.,~.: 't,. "jV "~, 1-,",-_,~ \ ...~, .11 GJ )I ~~+-:c~" _____ :;..1..- c JJ m t'-' \....J w ~ -. ONTELAUNEE fORMATION Medium:dark-oray. finely crystalline dolomite, massive 10 finely lamlnaj,d: weather, grayish y,llow: thick-bedded. dar1<-gray chen ----I _J...E.HIGJ::i y"t'--b.!:::_~,~_.. _~.,:::._~~~_~~. 0 .... Qs 1 -.- - .~ Om MARTINSBURG FORMATION ,:·n , Gray to dar\(-gray shale and slate 0rnys-snale containing conspicuous graywacke: includes autochthonous sandstone and shale 01 Shochary Ridge, Of'T1I-locallimestone masses '(wildflysch). JACKSONBURG FORMATION Dark-gray stlaly limestOne (cement rock} having slaty cleavage basal medium- 10 thick-bedded limestone (cement limestone) in· creases in thickness eastward '."",",,",,""==~ --~---'"'- /--'::Qe:--C" 'I ~ • Os . EPLER FORMATION Thick·bedded, medium- 10 medium-dark-gray. Iinety crystalline limestone, waalheringlighl gray; yellow dolomitic laminae; jnt.ar. --.Ilbllleddl4llledl.JDm~~Iy_~ryS~lIlnedOIOmite. h~~DI:~~~s~ray: wealhenng edlJBWise cono omara : "fOSSII-mmmtml dlld 00- RICKENBACH fORMATION Medium-to dark-Qr~. coarsely crystalline (Jolomiteln lower pan. medlum-Io medlum-lIghli1ray.lin,lycrystanlnodolom~oln upper ' part: cJtort lonses. bods. and nodules --~ , I i ______ J STONEHENGE fORMATION Medium~1ioht·gray to medium-gray, finely crystalline. IhiCkbedded limestone. conlaining dal1o; sillc80US laminae, edgewise' cOflglomerat, beds. and los.il-fragmont I,n...: dolomil' beds Incmse in number lIi1stward. , ....., ---"------ ~nozol J Glacial unconform;.y Plclstocene Brunswick TriassIc unconform'" Tuscarom Silurian unconformltu ~100' _- 1500' Upper Martinsburg 900' f- c Lower Martinsburg III u ~ Cll iii 0- 13 ;; 0 5 " unconform'" Jacksonburg unconform lh ' --- ---------------------------------------- ----. -- -- -- --- ---- --- - -- 3100' I 700' II I I N\ N I-l Beelanantown I- \t- N \ t I-l N 1200' I- 1600' Allentown i "I: .Q E a -- Tomstown 1000- Hardyston unconformity 200- ~-- , . Byram and Pegmatite J . Pochuck Moravian Helght8 ., Columnar Section of Rocks in lehigh County FIGURE 3.2 23 \.;-. . ~ - . ----------_._---------~---------------~._----------_.-_._--~._-_._----~~ CHAPTER 4 POLLUTION AND ITS' EFFECT ON SINKHOLES 4.1 SOLID WASTE Tremendous amounts of pollution are generated each year which will eventually interact with the environment. Today there are approximately 6500 solid waste landfills that are operating in this country most of which are not environmentally acceptable by EPA standards.The E.P.A. predicts that half of them will be closed in the next 5 years and 70 percent will be filled up within the next 15 years. The rate at which we generate solid waste is expected to increase by 20% by the year 2000. Approximately eleven and a half billion tons .of solid waste is generated in the United States each year. This includes all municipal waste, assorted industrial wastes, oil and gas wastes, mining wastes, and all hazardous wastes. The waste is disposed of by incineration, ocean dumping, waste ponds, waste piles and landfilling. Landfills currently receive 92 percent of all the solid wastes that are generated[2]. Once the waste is free to interact with the environment it is considered pollution. 4.2 CLASSIFICATION OF HAZARDOUS WASTES Hazardous waste can be classified into six different categories by the strength of the hazard[8]. The categories are: 1) Inert or relatively inert substances which could include municipal waste, gardening wastes, street cleaning, various construction trash, 24 '._"'-'~_. .J •• ,. _ _ ~ ~ • __._.r . .,, ...._ abandoned vehicles and excavated fill. 2) Nonpoisonous chemicals and strong, unstable organic wastes such as digested sewage sludge, some municipal refuse and nontoxic industrial wastes. 3) More hazardous organic wastes composed of raw sewage sludge, cesspool waste, dead animals, hospital wastes, and the more caustic industrial wastes. 4) Oils, solvents and volatile sludges that can be burned if properly regulated. 5) Pesticides, herbicides, and other poisons, solid chemical wastes, and low grade radioactive wastes. I.. 6) Moderate to strong radioactive wastes Out of the six groups of hazardous waste the first three are usually disposed of in sanitary landfills. 4.3 LANDFILLS The generally accepted definition of a landfill that is used comes from ASCE's__ ."-text Landfill M'!nuaL9f pr~:Lctlc~e_."~Jtstates~'Sanjtar:yJandfill -----_ "Sanitary---_ _ . _.~_. ... .-_~._---~ .. ~~-- .. ... _.--.,---~---_.- --._- .. ------. - is a method of disposing of refuse on land without creating nuisances of hazards to public health or safety, by utilizing the principles of engineering to~. confine the refuse to the smallest practical area, to reduce it to the smallest practical volume , and to cover it with a layer of earth at the conclusion of each day's operation or at such intervals as may be necessary. "[8] The landfill should also be constructed in an area such that it does not intercept the ground water table or have a means through which the leachate will affect 25 th,e quality of the groundwater. constituents of wastes. Leachates are the liquid or flowable as aqueous organic and They are classified inorganic, organic and sludges. A survey of over 700 cities showed that only 5 % of those cities were aware that their landfills were in some way responsible for part of the ground water pollution they were experiencing.[9] Other surveys conducted indicated that 9% of the landfills had serious pollution problems. Most of this can be attributed to placing the landfill anywhere from a to 5 feet above the water table. 4.4 WASTE DISPOSAL SITES IN LEHIGH COUNTY In January of 1980 Lehigh County officials along with the Pennsylvania Department of Environmental Resources inventorized the land disposal sites, auto salvage yards, and other waste impoundment facilities in the county. They found approximately 70 land disposal sites, 56 auto junkyards, and over 100 waste impoundment yards in the county. There were also additional uncontrolled dumping locations, discontinued landfills, over 5d~ active and .. - inactive quarries-and over 200.0 __do_G.wme.nted sinkholes. All of these items -------------------------._. ----.---~--- represent openings through which the pollution can migrate through to the groundwater and to the subsurface limestone formations. 4.5 POLLUTION AND CARBONATE REGIONS In general carbonate regions are not considered to be good waste dis~sal sites. If the permeability of the rock is low then they do not accept an adequate rate of waste and if the permiability is to high then the waste 26 does not have adequate time to decompose, oxidize or otherwise be purified. The karst regions are also worsened because of the thin layers of soil that are inadequate at filtering the pollutants. Once the leachate gets into the ground waterit can be get into the drinking water in surrounding areas. 4.6 WASTE DECOMPOSITION Landfills are filled with organics, chemicals metals, paper and many other items that are hazardous to the environment. These materials are not the only wastes that must be accounted for when investigating the leachate. The hazardous wastes go through chemical and biological changes after being deposited in the landfill. This decomposition occurs in two different phases, the aerobic phase, and the anaerobic phase. The first phase covers the period when the oxygen present within the solid wastes reacts with the wastes and forms carbon dioxide and water. This reaction causes an increase in the temperature of the landfill by approximately 30° Fahrenheit as well as the growth of the biological organisms responsible for the decomposition. Part of the carbon dioxide formed in this stage dissolves in the water and forms a weakly acidic solution. 6( CH 20 )x + 502 -----> (CH20)x + 5COi + 5H2 + Energy (Eq 4-1) The aerobic phase is complete once all the oxygen is expended. The second phase of decomposition of the waste is made up of two parts, an acid producing phase as well as a , carbon dioxide and methane gas producing phase. The reactions for the two parts of phase two 27 respectfully are: . 5( CH 20 )x -----> (GH2~x + 2CH3COOH + Energy (Eq 4-2) (organics) (organic acids) 2.5CH3COOH -----> (CH20 )x + 2CH4 + 2C02 + Energy (Eq 4-3) (organic acids) (bacterial acids) Figure 4-1 indicates the change in levels of C02, pH and methane as the breakdown moves through the two phases. In the. first part of the anaerobic stage the anaerobic organisms are maturing and breaking down various solids such as food and paper from rather cOmPlex molecules into small and simpler ones such as hydrogen gas, ammonia, inorganic acids, and carbon dioxide. During this period the carbon dioxide that is released represents up to 90% of the gases that are generated in the landfill. The acids generated are basically water soluble and formed by hydrolysis of the complex organic solLds. In the second part the methane producing microorganisms expfoit the ca-rbOnaioxitle,hydrogen~-and--acidsio-form methanegas;..-Although-this __ phase is the slowest it is very efficient in decomposing th~ available wastes. The by-products of the chemical reactions that are formed need to be contained in the landfills to prevent interaction with the subsurface environment. If interaction did occur the increase in pollutants could seriously pollute the aquifer and increase the solution rate of the limestone that it comes in contact with. 28 ~ _ GAS COMPo pH I-----~ _ _ TIME ~----_+_-------- L..- AEROBIC PHASE FIRST STAGE SECOND STAGE ANAEROBIC PHASE FIGURE 4.1 - Second Phase of Decomposition [10] (After Robinson, William D.) Landfills are not the only pollution source responsible for groundwater pollution. The other major sources are listed below in Table 4.1. TABLE 4-1 - SOURCES OF GROUNDWATER PDLLUTION [3] Waste Disposal Sources Landfills, dumps, and surface impoundments Mining wastes On-lot wastewater disposal systems Radioactive wastes -----~- _5Iudge_mal"LCW!=llIH~nlYLa ICin_<:l?RreaQ.illg__ . _ Injection wells Abandoned sites / Nondisposal Sources Abandoned wells Accidental spills Agricultural chemical practices Artificial recharge Highway deicing compounds ~, 29 Petroleum exploration Underground storc;lge tanks and pipelines Depletion Increased salinity Saltwater encroachment (After Driscoll, Fletcher G;) 4.7 ACID RAIN One form of pollution greatly affecting the environment is acid rain. Acid rain is primarily caused by the burning of fossil fuels by the power industry in generating electricity. The by-products of the spent fossil fuels causing the acid rain to form are sulfuric, nitric, and hydrochloric acids. These pollutants once released into the atmosphere can be carried thousands of miles from the source by prevailing winds. The widespread transport of the acids causes acid rain to be a regional problem rather' than a local phenomenon. 4.7-1 CHEMISTRY OF ACID RAIN Sulfur, naturally occurring in coal, is released into the environment when the coal is burned. The sulfur reacts with atmospheric oxygen and forms sulfur dioxide. The sulfur dioxide is further transformed into sulfLJricacid as a result of the reaction between sulfur dioxide and nitrogen oxides which are also released into the atmosphere by the power industry. The acids once formed are then tra'nstrorted to the surface by falling rain. In the Lehigh Valley the pH of the rain is approximately 4.3 versus a "pure rain" which being slightly acidic measures approximately 5.6 . Since the pH scale is logarithmic this represents an increase in acidity over t~n fold. 30 ~ The value of 5.6 was set based on the pH of distilled water which is in equilibrium with atmospheric C02. 4.7-2 EFFECTS OF ACID RAIN The disintegrating effect of acid rain on limestone is readily apparent on the limestone building facades,and statues exposed to the weather. Although these are the most obvious examples of limestone affected by acid rain an unseen but potentially serious problem is the increased rate of ,. sinkhole formation due to the greater acidity. The normal solution rate for limestone is very slow but with an increase in the acidity of the groundwater the rate of solution.grows. Testing was performed to determine the weathering rate of soils due to the acid rain in Norway[11]. The results obtained from these experiments indicated that there is a increased rate of weathering of the cations present in the soil. The test "rained" 4 different pH levels(2.5, 3.0, 4.0, 5.3) of sulfuric acid on to soil column sampT~s. The inflow and outflow of the base cations was measured to determine what cations which originally present in the soil had leached out due to the addition of the acid. The results show&l that there was a slight increase of movement of cations in the pH solutions in the range of 3.0 - 5.3 but at the 2.5 level there was a significantly higher rate of -- - ---------- -_. "-caiiOns"m6vingOuCofthe' soil'e'rlvironmenC'Tnese-results indicate that-the' .. '.,-,..._-- .....acid rain is capable of eroding limestone by chemical decomposition. The entire pH range used in the experiment has been found to be occurring in various parts of the world. Values even lower than 2.5 were recorded in the mid 1970's in Europe. During that period some rainstorms had pH levels as low as 2.4. 31 The system of reactions for the limestone/groundwater solution process will normally move back and forth until an equilibrium point is reached. Once that point is reached no m~re calcite will go into solution. Under natural conditions this is a very slow process, however, once another acid such as sulfuric acid is added to the groundwater additional hydrogen ions (H+) will be added to the process. This forces the reaction process to bring more calcite into solution in attempting to reach its' equilibrium position once more. Therefore the solution rate of limestone should increase as the acid rain drops the pH level of the groundwater to stronger acidic values. The pollution that is now being generated has the ability to seriously impact the limestone environment of the Lehigh Valley. The limestone is being subjected to an increased level of attack by acidic solutions that are stronger than the naturally occurring acidic groundwater. This is creating " conditions that will hasten the formation of sinkholes. 32 CHAPTER 5 LANDFILLS AND LEACHATE 5.1 LANDFILL LINERS Landfills are currently designed using liner systems as barriers to contain the I,eachate that forms for a design life of normally 20 to 30 years. The different liner systems use clay, geomembrane fabrics, concrete, asphalt, and soil-cement as barriers. The most common system being used presently is one that uses Clay and geomembrane fabrics liners. The system is good but there are problems that must be accounted for in determining what materials will perform the best. Although landfills are tightly regulated there are still problems that occur due to design shortfalls and poor maintenance. 5.2 LANDFILL TESTING AND DESIGN Landfill design is based on the performance of a liner in containing a standard permeant when tested under laboratory conditions. The chemical p!operties of the standard permeant versus the wastes to be. contained may ~--- ------ - - -- - -- - - -~ --- be very different in how they react with the liner system. The standard permeant may be nonreactive giving positive results while the wastes may react with the liner causing a breach in the liner. Laboratory testing may also not adequately model the field conditions that the liner is installed under which again may give inaccurate results. The parameters the design is based on effect what happens in situ once the landfill is in operation. The wastes to be stored in the landfill must - \ 33 be identified as closely as possible since different liner systems are compromised by different chemical wastes. Table 5.1 below shows five different properties of various organic compounds that may be stored in a landfill. The parameters include: hydraulic conductivity, dielectric constant, viscosity, unit weight, and dipole moment The compounds listed include acids, bases, neutral polar, and neutral nonpolar concentrated organic compounds. TABLE 5.1 PARAMETERS OF VARIOUS ORGANIC COMPOUNDS[12] /-~ Hydraulic Organic Compound Conductivity Viscosity Dielectric Constant Unit Weight Dipole Moment Water 1.00E-8 80.4 0.98 1.00 1.83 Methanol 1.05E-6 33.62 0.79 0.54 1.66 Ethanol 1.07E-6 24.2 0.79 0.20 1.69 Acetone 5.00E-6 20.7 0.79 0.33 2.90 Aniline 1.00E-5 6.90 1.02 4.40 1.55 Benzene 4.00E-4 2.28 0.88 0.65 Xylene 9.00E-4 2.50 0.87 0.81 Cyclohexane 3.00E-3 2.02 0.78 1.02 0.40 (After Fang H.Y) Dielectric constant at 20° Celsius, Viscosity centipoises at 20° C Unit weightgms/cc, Dipole moment debyes The first parameter, hydraulic conductivity, is a measure of the rate of flow with which a fluid moves through a material and is the most important indictor of how well a liner will contain the leachate. In regards to landfills this refers to the quantity of flow of leachate passing through the liner. The hydraulic conductivities listed for the different compounds in Table 5.1 are based on a typical clay liner. 34 \ 5.3 CHEMICAL EFFECTS ON CLAY LINERS Comparing the hydraulic conductivity of the compounds to the other four parameters listed indicates that the value of the dielectric constant of the fluid follows the same general pattern as the hydraulic conauctivity of t~e liner while the others show no discernible pattern. The hydraulic conductivity increases as the dielectric constant decreases. For example, the compound xylene has a "hydraulic conductivity of 10-3 cm/s with a dielectric constant of 2.50. Water with '(3 much higher dielectric constant, of 80.4 should have a hydraulic conductivity significantly lower than xylene. Water's hydraulic conductivity is 10- 8 cm/s which is 5 orders of magnitude less than xylene's. ~ The E.P.A. standard hydraulic conductivity value of 10-7 cm/s for a liner is verified by using standard permeants such as calcium chloride (CaCI 2) or calcium sulfate (CaS04) at set temperatures. The above information suggests that the clay liner should not be tested using standard permeants to determine the hydraulic conductivity but rather should take into account all of the physical properties of the compounds that will actually interact with the liner. The dielectric constant could also be used as an indicator as to how the hydraulic conductivity would vary for different '. _chemicals. 5.4 MOVEMENT THROUGH A CLAY LINER The chan'ge in hydraulic conductivity due to the dielectric constant is attributed to the negative electrical charge on the surface of the clay and is 'consistent with results predicted by the Gouy-ChagJ]Jan model. The GouyChapm<:ln model ,basically states that a diffuse ion layer of negatively charged particles will form in the presence of ions on the surface of the clay layer. 35 This layer forms a boundary through which a charged compound must pass. > Since the dielectric constant is an indirect measure of the strength of the electric charge of a material it will indicate how easily that material can move through the 'charged field. The electrical properties can also cause an interaction to occur between the clay and the chemical compounds. The interaction can cause the clay to swell or shrin~ creating cracks in the liner. Recent research (Madsen and Mitchell, 1987[lil} has also shown that organic compounds in a concentrated solution' may adversely affected the clay liners being tested, while a diluted acid (high water content) showed no adverse effects. The concentrated acids caused shrinkage cracks which dissolved the components of the clay causing the fabric of the liner to breakdown and move out of the landfill with the flowing leachate. 5.5 FLEXIBLE MEMBRANE LINER \.- ( The "flexible membrane liner" (FML) is another type of liner that is currently used in landfills. The liner has to be carefully designed if it is to be effective in containing the leachate. Different types of FML's commonly used include the following: polyvinyl chloride (PVC), hi.gh-density polyethylene (HPDE), chlorinated polyethylene (CPE), chlorosulfonated polyethylene - --.---_._----_.- -_ .... --- -_.- ---. -- . - --_ :_---- -.. _.- (CSPE)" and ethylene propylene diene monomer (EPDM). Characteristics that must be accounted for in selecting a FML include: flexibility, intended ---/ usage, chemical ~ compatibility with the leachate, impermeability, nondecaying, durability, easily constructed, and cost effectiveness. Table 5.2 lists five different manufacturers' recommendations on what their products can be used for. The capabilities of each material is good at containing many of the 36 chemical wastes but not the entire scope of wastes being generated today. This is important for the designers to realize since it will require that there is a system set up to protect the liner from the destructive chemicals. FML's are also subject to leaking from other hazards just as the clay liners are. Landfill liners are subjected to problems which occur during . construction and in the maintenance of the landfill. The installing contractors [--. may not follow proper installation techniques causing openings and leaks to form in the liner during construction. Poor maintenance of the landfill causes problems due to items such as storing waste products that the liner was not meant to contain, careless filling operations, and not providing protection for the liner from the elements. All of these problems create conditions that limit the effectiveness of the liner at containing the leachate. Generally the liners are protected from these types of damage by using an earth cover, soiL cement, or rip rap. The USEPA and state governments are in a constant state of trying to keep up with the latest information on how to best contain all of the leachate which is generated in landfills.There is a goal of "no migration" that is set but this is not praCtical.- 'Currently:--the~EPA-wiIra"bv\r' an--infiltration -rate of approximately 20 gallons/day/acre. Depending on the chemical compounds present this amount of leachate could be detrimental. to a sensitive local environment such as the Lehigh Valley's limestone formations. 37 .' .----- TABLE 5.2 CHEMICAL COMPATABILITY OF FML Chemical Compatible Plausible Inorganic Acids 1,2,3 2,5 Organic Acids 1,2,5 3,4 Inorganic Bases 1-5 Inorganic Salts 1-5 Alcohols 1,2,3,5 Incom patible 4 3 Hydrocarbons [13] 1,2,4,5 Halogenated Hydrocarbons 1-5 Ketones 3 Detergents 3,4 Oils and Food 3,4 2,5 1 Hydraulic Foods 4 2,3,5 1 1,2,4,5 1,2,5 (After Fang, H.Y.) Materials legend 1 - PVC 2 - Hypalon 3 - HOPE 4 - XR-5 5 - Neoprene i 38 ,/ CHAPTER 6 TESTING AND CORRECTING SINKHOLES 6.1 INTRODUCTION Sinkhole prone areas create many serious problems for the Civil Engineer when designing a project. The problems are usually encountered when designing a foundation or sewage system. In the process of designing the ,. engineer needs to be aware of all the inherent problems of a karstic formation to intelligently resolve all of its shortcomings. The information required should be obtained by performing an extensive soils investigation to pin-point the problem areas. 6.2 SOILS INVESTIGATION A complete soils investigation includes many different studies. Some examples are: reviewing the area topography, taking soil borings, or using . aerial phototones. All of the information obtained in the investigation is used to adequately locate any subsurface features. 6.2-1 SURFACE FEATURES The soils investigation should begin by first analyzing the topography in the area. This would include reviewing the surface drainage characteristics, the landform which includes the sinks, depressions and hills in the area, and finally a photo tone. Photo tone uses photography to reveal the nature of the geology below the ground surface. The photographs use the moisture content present to reveal the existence of subterranean'\...· 39 /irr-egularities such as karstic features. Once the subgrade topogra~hy is mapped out a more intensive exploration can be started. 6.2-2 EXPLORATION TESTS The exploration tests may include using seismic refraction, cross hole surveys, electrical resistivity tests, gravimeter surveys, and ground probing radar. These methods are fairly good at showing the depths and magnitudes of the karstic formations but are not specific enough to adequately design a foundation system. This leads to the final phase in the testing exploration stage of drilling test borings. 6.2-3 TEST BORINGS Test borings are located based on the information obtained in the previous two stages. The borings are the most expensive part of the testing procedure which is why it is necessary to pin down as closely as possible the actual dimensions of the karst features. The boring are used to show the usual information required for design but they are also useful in showing the __detected_since _ location of any voids.. that are present. Thevoids9re_.~_asity --- . "---_ .. "-_._- ... _--_. -- ---------_ __ .. ------ -- --- --------- ------_.~ -.- ..•. _ ~ - - - ..... - there is a sudden drop of the drilling equipment or the loss of the drilling fluid. If a significant number of voids are detected in the first two stages it may be necessary for the engineer to require test boring at all locations of important footings and possibly at all of the footings if warranted by the projects' intended usage. Once the investigation phase is complete the information is interpreted and the information is used to start designing the foundations. / 40 ----6.3 FOUNDATION DESIGN During the preliminary phase of design the following items need to be considered. What is the thickness of the overburden soil on top of the cavity and what properties does it possess? If rock is encountered in the borings; is it a sound rock, a weathered rock, or if cracks are detected; will they have an impact on the design? If a cavity was found will the roof arch continue to support the overburden with the change in conditions? And finally, will the groundwater elevation change in any way either once construction is started or at any time in the future? The design in an area of sinktJoles should allow for a greater factor of safety due to the larger amount of unknowns. If any of the above items present a problem that can not be easilylsolved it may be wiser to move to a new location. I· I 6.3-1 SINKHOLE CORRECTIONS If the karst formation is not to severe there are a number of remedies that can be used to alleviate therproblem. The first, a procedure called _._~--------- "dental concretfng" In\;olvescleaningout~thecavity as-mucllas~~possibleof __ ~ the loose soil and rock p·articles. Then pour or pump a lean concrete mixture into the cavity to fill the voids. This will usually provide an adequate bearing surface for shallow foundations. concrete grouting. Another procedure commonly used is This is used for cavities that are to deep to get to by excavation. The voids are filled by injecting a grout mixture. The problem with this procedure is that there is a degree of uncertainty as to how effectively the voids have actually been filled by the grout since it is all done 41 from the surface above the void. Test borings are used to check the grouting procedure but there is still the possibility of having not completely filled the voids. One of the added benefits of grouting is that the movement of water through that sinkhole area is greatly reduced and this will slow or stop the reformation of the sinkhole. One other material which could be used in filling or grouting the karstic features as a fill or grout material is a soil/cement / rubber tire mixture.-The mixture is basically a soil cement mix with rubber tire pieces used as an aggregate. The mix and its strength are shown in more detail in chapter 7. 6.3-2 DEEP FOUNDATIONS Another popular method used to solve the karstic problems is to use a deep foundation system such as piles or caissons. This would provide support from a more sound bedrock below the problem area. The deep foundation structures should be proof tested once in place to assure the capacity of the underlying bedrock. 6.3-3 SINKHOLE PLUG .. . _-~.- -- ~~~- - - In some cases a sinkhole is first fille-a Wlfh verylafgeaggreate such as broken up concrete or large boulder and then a very lean high slump concrete is poured into the aggregate to bind it together. Then a concrete plug is poured on top of the large aggregate to prevent further settling of the surface above. On top of the plug is finally placed a fill with a very low permiability. This method has been used with great success in the Lehigh Valley during the last 20 years. Some examples of this was for the Vera 42 ·Cruz sinkhole which formed in 1983 and the Macungie sinkhole that formed in 1986. Sinkholes that need to be fixed quickly such as in a busy parking lot, a roadway, or foundation of an building that needs to keep functioning are usually repaired by filling the hole with some inexpensive fill material. In these cases the sinkhole is excavated down to a sound material, bedrock if possible. Then the depression is filled with alternating layers of well-graded gravel and an impervious material to choke off the flow The final layer of material should always be impervious so that there is no flow of surface water into the subsoils. .J 6.3-4 SOIL REINFORCING One other method successfully being used is a heavily reinforced foundation. The foundation is designed to bridge over the weak zones in the subsurface so that no parts of the foundation are subjected to large differential settlements. One case of using a mat foundation to alleviate a problem area was along Route 202 in Norristown, Pennsylvania. In May of 1970 asinkhole started forming along Route 202 and in a period of one hour grew from a crack-]n-tne pavelifEfriCto--aAO foot diameter hole. Over the next 6 months the sinkhole grew to 75 feet in diameter and to a depth that the bottom eQuid not be seen from the surface. The de~igners came up with two solutions to the problem. The first solution was installing a 3 foot thick heavily reinforced slab with concrete beams supporting all adjacent slab sections and tbe slab ---- edges. This slab had the capacity to span a 50 foot sink if it were to develop >( 43 and still be capable of handling the traffic on the roadway. The second solution and the one that was ultimately used was reinforced earth. The reinforced earth uses sections of a metal as reinforcing to act as tensile restraint. The friction of the soil provides the restraining force which provides the capacity to support the loads from the roadway and soils above the reinforced section. These were the only two suggestions deemed acceptable since it was felt that trying to fill a void as large as the one that developed could be a very timely and expensive operation. There are other solutions to filling up or preventing the formation of the sinkholes that are not as common as the ones detailed above. They include use of gabions, geotextile reinforcing and filling with a very large aggregate material such as broken up concrete or boulders. All have been economically successful but may not be the best solutions to the problems. When filling sinkholes with soil or some non-concreted material you must be aware of the underground water movement, If there is water movement then the material placed in the sinkhole must have the ability to stay in place and not be washed away. . I - -~6,4- REGOMMENDATIONSrClALLIEVATE_SINKHOLEEORMAIIQN . . Some recommendations which help alleviate future problems from occurring when building in a sinkhole prone area are as follows: 1 - Provide positive drainage systems away from disturbed land surfaces in known limestone areas or suspected sinkhole terrain. 2 - Do not allow storm water to pond in suspicious depressions or swales for extended periods of time. 44 3 - Maintain paved areas by sealing all openings, seams, and cracks 4 - Do not use old sinkholes or abandoned limestone excavations as repositories for rubbish, debris, garbage, or storm water. 5 - Minimize blasting as a means of removing limestone pinnacles in excavating operations; use air hammers or rock splitters instead. 6- Be alert for broken water pipes or leaky drains in the subsurface.[14] ( 45 CHAPTER 7 USE OF SOIL-CEMENT-TIRE AGGREGATE AS A CONSTRUCTION FILL 7~~j INTRODUCTION / Sinkholes and other karst features are responsible for many foundation problems that occur in the Lehigh Area. Photos 7-1 r 2 and 3 show a problem area where two sinkholes were found during April of 1993 in the Lehigh Valley. These sinkholes are typical of the area and can be corrected using any of the different methods previously outlined in chapter 6. The most common method of correcting a sinkhole is to remove all the loose material from the cavity and the replace it with a lean concrete mixture. This provides a fill material that has the ability to span over soft spots due to it ability to act like a slab and provide support to the loading above. Another benefit of the material is that it has a lower hydraulic conductivity which reduces the amount of water that can move through the area. Another common construction material that has been used successfully as a structural fill for sinkholes with properties similar to lean concrete is soil cement. Cement added to soil, commonly referred to as soil-cement, changes the soil properties through the hydration of the cement. This increases the ~- bearing ------ - capacity ---- and -~ - - - - - --- decreases --- -- - the -~ -------- - - - - - - - - . permiability. ------ Soil-cement can successfully be used with soils that are made up of many different components including clays, silts, gn3Vel, sand and many other granular r" -, le,_ materials. Generally the material is placed with a consistency of plastering mortar which is approximately a 4 inch slump. 46 Since filling a sinkhole and the other karstic features generally require a large volume of material it is cost efficient to use locally available materials that can be easily handled by the local contractors. Soil cement is a commonly used low cost material that can be designed to serve its function with various local soils. The material that is capable of generating the strength required to adequately fill the voids and provide the support required to prevent further subsidence from occurring. The soil/cement mixture is usually designed to perform as a base course for roadways and parking lot. Other successful uses of soil-cement include stabilizing subgrades and linings for reservoirs and drainage ditches. Soil cement normally consists of water, soil, and cement. In this research small pieces of rubber tires were added to the soil-cement as an aggregate. The rational behind the addition of tires to the soil cement is to find a way to remove scrap tires from the waste stream while at the same time developing a structural fill using the lightweight aggregate. There are literally millions of tires that need to ,be disposed of each year. Based on a United States Environmental Protection Agency survey the production of automobile tires increased by 42% between 1960 and 1988. _.~-~_. __.- _.- ~- .. There are 280 million tires disposed of each year in ~- ~ - _. ~_._~- ~ - ---- -------_. -- the,UI1It~d ._. ,_ .. --.-- States alone and of this only a small pe'rcentage is being recycled. 5.6% of the tire waste , stream was recycled in 1988. It is also becoming harder to actually dispose of the tires. The regulations governing disposal of the tires is growing more strict and 'in some states such as Ohio, they will only be allowed in single use landfills after 1995[15]. Additionally, landfills are not being opened at the same rate as they are being closed so space in landfills is getting smaller. 47 Therefore the tires need to be recycled for other u~es to keep them out of the waste stream. Current methods for reuse of scrap/waste tires can be grouped into three general categories: (1) fuel source as a raw material in the production of other polymeric material; (2) additive as a part of asphalt-rubber mixtures for use as a sl,Jbstitute in asphalt pavement material mixtures; and (3) lightweight aggregate for concrete mixtures or as a soil reinforcement element, either cut into small pieces, shredded, or as whole tires. If the waste tires are used as described in categories (1) and (2), additional refining processed are needed, consequently requiring additional investment and creating additional environmental problems. To utilize large amounts of waste scrap tires within a short duration , category (3) has obvious economic and environmental benefits. The use of scrap rubber tires as an aggregate provides a low cost alternative t6 other more commonly used aggregates-such as-stone. In manycases there is no need to obtain high strengths from a soil-cement mixture so the tires can successfully be used as.an aggregate to increase the volume of the mixture. The purpose of this research was to determine if the addition of the tires to the soil-cement will create a fill material that possesses an adequate level of strength to perform as a structural fill for sinkholes. 48 ,. 7.2 LASORATORY STUDY The laboratory study was performed in Fritz Engineering Lab and the following sections outline the testing and results. 7.2-1 TEST EQUIPMENT AND PROCEDURE Based "ali previous study [16,17,18], the flexural strength test is suitable for the performance- evaluation of fill materials. The test equipment and test procedure used in this study followed American Society of Testing and Materials Standard (ASTM 01635-87) entitled "Flexible Strength of SoilCement Using Simple Beam with Third-Point Loading". This test requires slowly loading a simple beam specimen at it's third points to determine the flexural strength of the beam. Figure 7-1 shown below illustrates the layout of the testing apparatus used in testing the samples. LOADING U3 U3 W3 So jJ-Cement-Tire Briele Sample Figure 7-1 Testing Apparatus Layout 49 7.2-2 PREPARATION OF TEST SPECIMENS The size of the specimen is 8.25" long by 4" high by 2.25" wide. The specimen is composed of soil, cement, scrap tire and water. The test used one set of percentages by weight of the solid components, (80% soil, 12% tire and 8% cement) and varied the amount of water used to obtain the desired slump. The slump of mixture was used since it is a common construction control method to determine the amount of water used. The percentage of cement recommended by the Portland Cement Association [19] is based on a percentage of the dry unit weight of soil. For silty soils the range of cement recommended is between 7 to 12%. The amount of cement used in the specimens was 10% of the dry weight of soil alone and 9% of the total soil and scrap rubber weight. The percentage of rubber tire aggregate used in the test was based on the results obtained previously [16]. The amount of water added was determined based on the slump of the mixture desired. In this experiment, the slumps used were 0", 3", 5" 7" and 8" determined by a standard concrete slump cone. The soil-cement was mixed together with scrap tire~(0.5" diameter) then set into beam molds. The molds were then covered with moist burlap and placed in large plastic container to prevent evaporation. The samples were allowed to stand for three days in the mold and then removed and again placed back in the moisture controlled environment with the burlap covers. Each test beam was then tested at 7-day intervals to determine the ultimate flexural strength. 50 - ---------- 7.3 MATERIALS 7.3-1 SOIL The soil used in this procedure was obtained in the Lehigh Valley area. It is classified by the Unified Soil Classification (ASTM 02488-84) as "ML" and is a silty clay with a liquid limit of 38. The optimum moisture content was determined to be 15. This soil was selected since it is a soil commonly found in the Lehigh Valley area and therefore the results could be applied to a site in this area. 7.3-2 TIRES The tires used were obtained from various gas stations and tire stores in the vicinity of Lehigh University. All of the tires had been worn beyond the wear indicators on the tire tread. Only the sidewalls of the tires were used to obtain the tire. material added to the mixture. The tread was not used since the punch used to obtain the tire pieces could not penetrate the steel belts. The diameter of the rubber pieces was 1/2:' in size. The size was determined to be as large as was practical based previous investigation [16], indications are that the 0.5" diameter of scrap tire is most effective in determining the ultimate strength of the test samples 51 7.3-3 CEMENT The cement used was type I portland cement. Type I was chosen since it is recommended by the peA and is used in soil-cementing operations[19]. Type I was also chosen since it is the cheapest cement available. 7.3-4 WATER The water use was obtained from the tap in Fritz Laboratory and should therefore be free from any deleterious matter. 7.4 RESULTS The summary of test results are shown in graphical form in figures 7-2, 7-3 and 7-4. The results are shown as ultimate load versus time, modulus of rupture versus time and ultimate load versus slump. Individual test results of samples with tire aggregate were obtained for 0" slump (25% water content) at 7,14, and 21 days (figures A1-A4); 3" slump at 7,17 and 24 days (figures A5-A9)); 5" slump at 7,14,24 and 31 days (figures A10-A14); 7" slump at 10 and 17 days (figures A15-A17),initial run of 7" slumps (figures A18, A19) The initial run of 7" slump tests were questionable so a second run was , performed, 8" slump at 7, 14,28 and 35 days (figures A20-A27) .. Results for the 8" slump without tire aggregate were obtained at 7, 14, 28, and 35 days . (figures A28-A35). All of the figures are in the appendix. 52 7.5 CONCLUSION The results of the testing show that the soil-cement/tire mixture can be used for many of the same uses as regular soil-cement. These include performing as a subbase for low volume roadways, parking lots, linings of ditches and reservoirs as well as a fill material for sinkhole problems that are found in the Lehigh Valley. The strength of the soil-cement/tire mix has the flexural strength capacity to(act as a slab once it has cured. This strength is '.. necessary to provide an adequate subbase for roadways and parking lots and sinkholes. The modulus of rupture, (shown in figure 7-3) has been shown by the P.C.A. to be approximately 20% of the compressive strength.[19]. Therefore the estimated compressive strength for the soil-cement/tire mixture reached 250-300 psi at the end of the 35 day testing period. Prior research done by the P.C.A. indicates a significant increase in the strength of soil-cement over a period of years can be expected and will provide an additional factor of safety for any additional loads that may 'come about in the future. [18]. In sinkhole grout filling operations the strength of the material is not as important as in normal grouting operations since the material functions mainly as a fill. Strengths in the range of 200 to 500 psi are normally required to provide the ability to adequately support the surrounding materials. It is not normally advisable to introduce a material with strengths higher than the surrounding soil and rock as it only increases the cost without giving any significant additional benefits[20]. 53 7.6 DISCUSSION OF TEST RESULTS Figure 7-2 shows the ultimate load determined from beam test versus curing period, and figure 7-4 shows the ultimate load versus slump. Some important points of test results are presen~ed as follows: (1) The 0" slump had the lowest strength (failure load) of all the test specimens. The strengths were on the order of 40 to 50% less than the three other slumps tested after the first week (7-day) of curing. The deficiency in strength continued throughout the entire testing period. The strength of all the samples should continue to increase as the cement continues to hydrate. (2) The test results showed an increase in strength to approximately a 6" to 8" slump which is the range considered ideal to obtain the highest strength for the fill. (3) The test beams all broke within the middle third of the beam (see photos 5 and 6) .. The fracture plane was basically straight through the beam perpendicular to the top of the beam. One of the main factors responsible for the bonding between the soil-cement and tire particles is the absorption of the soil-cement by the tire particles. The bonding strength increases with the increase in absorption. 54 (4) The failure surface of the samples was inspected to determine if any bonding did take place between the tire and the soil cement. The surface did show some bonding between the two materials. The sample beams were photographed by a magnifying lens (8 times actual size) to view the interface of the two materials (see photos 7-3, 7-4, 7-5). The photos show there is good contact between the materials which would allow maximum bonding to occur. Failure of the sample was along the surface of the exposed tire surfaces as would be expected indicating that the absorption bond between the tire and soil-cement (see photos 7-6, 7-7, and 7-8) is smaller than the cernent bond between adjacent soil particles. 7.7 SUMMARY (1) The results of the testing show that the soil-cement-tire mixture can be used for a variety of uses similar to regular soil-cement including performing as a subbase for low volume roadways [8], parking lots, linings of. ditches and reservoirs. (2) This Ipw strength mixture can be used to fill empty spaces such as I sinkholes or around bridge abutments, retaining walls, and building foundations. (3) In using the mix for sUbbasing a parking lot or roadways a low slump of 3" to 4" would be used so that the mix placed could be graded as the design required. The higher sluITJPs could be used in grouting sinkholes since the material must be ftowable enough to move through the sinkhole and plug up the subterranean cavities that may be associated with the sinkh.0le. 55 Normal pumps used in concreting operations use slumps in the range of 7" to 9". (4) Future study into the use of tires in soil-cement should determine ,how the hydraulic conductivity varies with addition of the tire particles. The tire aggregate should also be changed physically to determine the effects that size and shape of the aggregate may have on the flexural strength. (5) If the mix is to be used to fill sinkholes additional studies need to be undertaken to determine the ability of the mixture to resist breaking down or . washing out due to groundwater movement. The results of testing also indicate that higher slumps should be investigated to determine at what point the soil-cement-tire mix still achieves acceptable strength and still be easily pumped or injected. There were some problems that were encountered during the running of the tests. The first involved setting the head of the test apparatus on the sample. While attempting to seat it correctly a load was applied to some of the sample beams before deflection readings could be recorded. The beams that were subjected to this pretest loading did not record any additional deflection until the pretest load was exceeded during the recorded testing period. SeeJraphs A5, A7 and A9 for illustration of the problem and the associated results. The second problem was observed during the testing of the initial 7" slump specimens. It appears that the initial 7" samples never developed any strength from hydration of the cement. The samples remained plastic up to 31 days and developed a minimal strength of approximately 5 pounds. It was determined that the soil/cement mixture was improperly prepared. 56 -_._-------------- Future study into the use of tires in soil-cement should determine how the hydraulic conductivity varies with addition of the tire particles. If the mix was to be used to fill sinkholes additional studies need to be undertaken to determine the ability of the mixture to resist breaking down or washing out due to groundwater movement. The results of testing also indicate that higher slumps should be investigated to determine at what point the soil-cement-tire mix still achieves acceptable strengths and at the same time can easily be pumped or injected. The mixture must be fluid enough to allow filling of all of the voids of the sinkhole prone area and also to allow a pump to be used to place the mixture. 57 250-.----------3" SLUMP 7" SLUMP en ---------. 8" SLUMP OJ "::! 200 ---- -- ---------- ------------------ o : 150~------ __ ~:::~::UMPd _ ~ 100 - ---- ----------------- _ ::> 30 35 CURING PERIOD (DAYS) ULTIMATE LOAD VS. TIME FIGURE 7-2 _ 50 - . - - - - - - - - - - - ~ . 7" SLUMP 3" SLUMP w a: 40 ----- ::> ---------- -, Ii: ::> a: u. --, 8" SLUMP ------------------ 5" SLUMP 30 o Cf) 3::> 20 o o :2 10 ---+--~-.-----.-----.-----,---,----------1 5 10 . 15 20 25 30 CURING PERIOD (DAYS) RUPTURE MODULUS VS. TIME FIGURE 7-3 58 35 300 275 - 250 -' 225 0 200 ------------ -------- 0 -' 175 CD - - - - - - - - - - - - - - - - - - - - - - - - -d2:- (J) OJ <X: w --------- - - ---------------- X 150 - - - - - - - - - - - - - .- 125 - - - - - - - - - - - :J 100 ~ ~ ..J ~ - - - - - ~ - - - - - - - 1LtJ- - ~ - - - - - - - - - - - - ~...J -~- - - W - - - - - - _. - - - - - - - - - - - - - - - - - -0.~ 75 6 012345 SLUMP (IN) 789 ULTIMATE LOAD VS. SLUMP FIGURE 7-4 59 SINKHOLE IN LEHIGH VALLEY '~ .j.~- .. .., \,.:',L- If(T ,-. a1 ,~ PHOTO 7- '1 SINKHOLE IN LEHIGH VALLEY ~';i, ,\t." , It '.;~ ,·-t~··;· .. PHOTO 7-2 SINKHOLE IN LEHIGH VALLEY 60 -------~--------- PHOTO 7-4 TESTING APPARTUS 6\ - - · ,"..;, ~. ~, .:;.. .. ~r~'" PHOTO 7-3 SINKHOLE IN LEHIGH VALLEY PHOTO 7-4 TESTING APPARTUS 6\ :--# PHOTO 7-5 ~, TYPICAL CRACKING PATTERN .' PHOTO 7-6 TYPICAL FAILURE SURFACE 62 PHOTO 7-5 TYPICAL CRACKING PATTERN . - \ TYPICAL FAILURE SURFACE 62 PHOTO 7-7 CROSS SECTION OF SOIL-CEMENT-TIRE SAMPLE SOIL-CEMENT-TIRE INTERACTION 63 PHOTO 7-7 CROSS SECTION OF SOIL-CEMENT-TIRE SAMPLE ~.;:.:.~Il. :: ".' HI' . ' .• ! • J ~ ,Ill SOIL-CEMENT-TIRE INTERACTION 63 L REFERENCES 1. County and City Data Book (1988) U.S. Department of Commerce, Bureau of Census, Data User Services Division, Washington D.C. 2. Forester, W.S, (1988) Solid Waste: There's A/ot More Coming" E.P.A Journal May 1988 pages 11,12 3. Driscoll, F.G.,(1987) "Groundwater and Wells" Johnson DivisionSt. Paul MN 4. Fookes, P.G. and Vaughn,P.R.,(1986) "A Handbok of Engineering Geomorphology" Chapman and Hall NY 1986 5. Beck, B. F. Wilson, W., (1987) "Karst Hydrogeology Engineering and Environmental Applications" The Macungie Sinkhole, Lehigh Valley, PA Cause and Repair. AA Balkema, Boston, MA 6. Fang, H.Y.,(1993) personal notes 7. Miller, Benjamin L.,(1941) ,"Lehigh County Pennsylvania Geology and Geography" Dept. of Internal Affairs Harrisburg, Pa 8. Perlovy, M., Schadl,S.M., Kugelman, !.J., Fang, H.Y. , (f983) "Waste Disposal Considerations in Lehigh Valley Carbonate Formations" Conference on the Disposal of Solid, Liquid and Hazardous Wastes AS.C.E. Lehigh University 1983 9. Liptak, B G.,(1974) "Environmental Engineer's Handbook" Vol. 1, Water Pollution Chilton Book Company, Radnor, PA 10. Robinson, WD.,(1986) "The Solid Waste Handbook: A Practical Guide" John Wiley and Sons NY 11. Lerman, A , Maybeck~ M.,(1988) "Physical and Chemical Weathering in Geochemical Cycles" Kluwer Academic Publishers, Boston, MA 12. Fang H.Y.,(1991) "Foundation Engineering Handbook" Van Nostrand Reinhold NY 13. Fang, H.Y.,(1986)lnternational Symposium on Environmental Geotechnology Envo Publishing, Bethlehem PA 64 14. American Society of Civil Engineers,(1976) "Engineering, Construction and Maintenance Problems in Limestone Regions", The Geotechnical Group, Lehigh Valley Section PA 15. Phillips,Mark,(1993) "The State of Scrap Tires" Tire Review,March 1993 pp.28-40 16. Fang, H, Y., Hitchens, D. and Hontz, D. (1992). "Use of Scrap Rubber Tires for Construction Materials, Proceedings, 24th Mid-Atlantic Industrial Waste Conference, West Virginia University, July, pp. 263-275. 17. Hausmann, M. (1990). Engineering Principles of Ground Modification, McGraw Hill Book Co., NY 18. ASCE, (1978). Soil Improvement History, Capabilities and Outlook, The Committee on Placement and Improvement of Soils, American Society of Civil Engineers, NY 19. Portland Cement Association, (1979). Soil-Cement Construction Handbook, Portland Cement Association, IL 20. Beck, B F. (1984) "Sinkholes: Their Geology, Engineering & Environmental Impact" A.A.Balkema Boston MA 21.Geological Map of Pennsylvania, Map 1 (1980) Pennsylvania Department of Environmental Resources, Commonwealth of 22. Highway Review Board, (1979). Low-Volume Road, Transportation Research Record 702. 23. Mathewson, C. C. (1981) "Engineering Geology" Charles E. Merrill Publishing Company, Columbus OH 24. Jennings, J. N.,(1971) "Karst" M.I.T. Press, Cambridge MA 25. Trudgill, S,T., (1986) "Solute Processes", Chapter 9 John Gunn "Solute Processes and Karst Landforms" John Wiley & Sons NY 26. Portland Cement Association, (1988) "Soil-cement, Inspectors Manual",Portland Cement Association IL 65 27. Hunt, R. E. 1984 "Geotechnical Engineering Investigation Manual" McGraw Hill Book Company, NY 28. Yong, R. N. and Warith, M. A. (1989) "Leaching Effects of Organic Solutions on Geotechnical Properties of Three Clay Soils", Second ~nternational Symposium on Environmental Geotechnology Envo Publishing Company, Inc. ; Bethlehem, PA 29. Richardson, M., Acar, Y., B. and Edil, T. B. (1989) "Geotechnical Aspects of Landfill Lining Regulations and Hazardous Waste Regulations in USA", Proceedings of the Second International Symposium on Environmental Geotechnology, Envo Publishing Company, Inc Bethlehem, PA 30. Freeman, H., M.,(1988) "Standard Handbook of Hazardous Waste Treatment & Disposal, McGraw Hill Book Co. NY 31. United States Environmental Protection Agency,(1~89) "Remedial Action, Treatment and Disposal of Hazardous Waste" Proceedings of the Fifteenth Annual Research Symposium U.S.E.P.A., Cincinnatti OH 32. United States Environmental Protection Agency,(1981) "Land Disposal: Hazardous Waste", Proceedings of the Seventh Annual Research Symposium U.S.E.P.A., Cincinnatti OH 33. Todd, D. K., (1980), "Groundwater Hydrology" John Wiley & Sons, 34. Freeze, R. A., Cherry, J. A., (1979) "Groundwater, Prentice Hall, Inc.,NJ 35. Kirk-Othmer, (1967) "Encylopedia of Chemical Technology" 2nd Edition, Volume 12 Lime and Limestone John Wiley &Sons NY 36. Legget, R. F.,(1973) "Cities and Geology"McGraw Hill Book Company NY 37. American Society of Civil Engineers, (1979) "Preceedings of the National Convention" Boston April 2-6,"Acid Rain" ASCE NY 38. Howard, R, Perley, M.,(1980) "Acid Rain The North American Forecast" House of Anansi Press Limited Toronto, Ontario L 66 LO . C\I 1 ~ o 0 C. E -o C\I ::J 0 0 (J) ,.. Z I Q <C LO~ W --0 ""'--""'" ~ ··: ····: · ···· ·· · ···: en w r- ~ <t: ClI en S ~ w 0: ti3 q 0 LO 8 0 · · : I-----t----+---+----+------.O o 00000 o LO V LL -- ··: · :··: c.o W" 0_ t ·:• ·: I'- a: qw o r:C ::J t:::"- C") C\I -- (lsd)SS3CJ1S ~ (sql)aVOl 67 7-DAY TEST(O" slump) ~, .......... ·en a. ......... Cf) Cf) ~ 40 35 w 30 a: ~ 25 ~~ ~ .0 ::::::... o i ---- LOAD(lbs) 20 15 « 10 9 512:' --":""""" ~ o --- --- o 0.002 • : --- - - • .: S~'§~(~~"""""'''''''''''''''''''''''''I ~........... i 0.008 0.004 0.006 DEFORMATION FIGURE A-2 0.012 0.01 14-DAY TEST(O"slum-PJ 140 ~ i i 120 Cf) S (J) (J) w a: b5 mod 'Ci) .0 100 80 ......-..- -.- - _ _ ---_ -.- _._ . - . 60 ~ o « 9 40 - + - STRESS{ps~ 20 o~ ~ . .,. • o 1 ~ .. ~ til 0.004 0.002 :11.: 7 •.. 0.008 0.006 0 , 0.01 DEFLECTION t ~ FIGURE A·3 .:. 0.012 . . 0.014 I 0.016 21-DAY TEST(O"slump} 120T'- - - - - - - - - - - - - - - - - - - . , 'Ie C'- B en en w a: len 1oat···················································...............•.......••...............................---r:-.•••••.••••. -- -------- , 801········~···································~····=:=··LOAD(;b~)······································ ~JIlT 601 CJ~ .••••.••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••• '(j)' .0 ::::::... 0 40 J « 9 --+- STRESS{psij 20 0 a 0.004 0.002 0.012 0.008 0.006 DEFLECTION FIGURE A-4 0.01 0.01~ 7-DAY TEST(3"slump) 1~1 ~ c~ ~ 120 ·················································· i . CJ) S C/) C/) 100 J .;. . W 0: 80-·· ~~ 601-. ~ 'Cii' . ._- . . - ~... .............................. --- LOADObs) -_ . -_ . .0 ;::::... o ~ ...J . 401····· .:.::;;;- ·····=:smE~;,;·············- 2O J ..........................•................................................................................................. oJ ..~. ,., 0.4 . ~. ~. ~.: 0.402 0.401 0.404 0.403 =· : · I 0.406 0.405 DEFLECTION FIGURE A·5 0.408 0.407 0.409 1-7--DAY TEST(3"SLUMP) 180 -·00 0......... 140 (j) (j) 120 J- 100 w a: (j) ;j 160 c?S - -R-:............ - .. - _ - .. _ .. - - _ .........., - _ .. - - - - - _ - - - - .. - - - - _ .. - - ;'.,.:-~~- ;.-.; --.;.. ,;,; LOAD(lbs) -.-;; .. - -- --_ __ - .. _ .. - - - - - - - - - - .. -'!'_ -- _ .. '!- 80 ( /) ..0 ......... 0 60 0 40 « -I 20 - ~ O:r o un u - - - __ - - - __ - - - II I I I I - - - n - I I - __ u - u I - - '-f-STRESS(psi)r ---_.-__--.....- . - - - - - __ - - - - - - - - - - __ n I I __ n I.. I __ - - __ n _ _ I I I I I 0.002 0.004 0.006 0.008 0.01 0.012 0.014 0.016 0.018 0.02 DEFLECTION(inches) FIGURE A-6 . ,j' C\I ~ ·· ·: ·:: : · · ·· .c· 0 · «0 ..J ·· I ··· · 0 0 0 0 0 0 ~ 0 0 0 0 0 0 0 ~ O C- 0 0 ! ! :E b 0 0 : ···· w 0 0 0 0 0 0 en --en : ·· ·· · 0 0 ~ 0 r(J) 0 0 0 0 0 0 0 0 W 0 ··· ·,, ·,, 0 r- 0 0 0 0 ~ 0 , 0 0 0 0 0 0 0 tJ) 0 ! 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 - , CO 0 0 0 - "(j) 0- -enen (0 a:: ··· · ···· ·, ·: ·· 0 0 0 I- t 0 0 ~ 0 0 0 i\ , , 0 0 0 ·,, 0 0 0 0 0 0 0 B , ~ ·· ·, ··, ·,, 0 , 0 C\I 0 0 0 0 0 to C\I 0 C\I 0 0 0 0 0 0 ···, ·: ,, 0 0 0 , 0 0 0 0 0 0 0 0 lO 0 0 C\I ~ ~ 0 lO (!sd)SS381S '1» (Sql)OVOl 73 - <Cr-Z 0 I 0 ...J LL 0 0 Q) 0 i= 0 w en 0 tJ) .r:. u c: w 0 - W 0 w a: :::> - Cl LL 24-DAV~TEST(3I1SLOI\llP) 250 i i ....... 200-J..·..·.·--.--.--.-.- --..,e; --.----.._.--..-._._ '(j) - _..- (f) (f) -R- LOAD(lbs) w a: 150 t- (f) ~~ W --« .0 100 o o-1 501".---....._._---..__._---._..-.__._-._-------.----._- .. -_ OT o I 0.001 I I -- I -_ .. ------- -- --_ I - I ~ - - SIRESS(psi) -- .. -.. _ --_ .. ----- ---- --- I I I 0.002 0.003 0.004 0.005 0.006 0.007 0.008 0.009 DEFLECTION(inches) FIGURE A-a· 24-DAY TEST(3 SLUMP) I1 300. c- , 250 (fJ ---0000a. w ---- '" 200 . . . -----------------------------------------------------------------------------.------ a: -III- t- oo U\ ~ LOAD(lbs) 150 -t -. -"-- -- - -- --- -- -- - ---- -- - - - -- - --. - - - -- -- - -- - - - -- -- - - - -- -, - ----- -- -- - -- - -- - - - - - - - - - .---- --------._._----- •••••-- ---.--.-•• -.----- ........ (fJ :: 100 o « o ...J 50 ~ OT o .________ I 0.001 ..... --- -- _ I I I -_ --.- .. -- -- -- I -- -_ _ I STRESS- (psi) --+.. _-_ _------- .. _ ----- _.. -_ .. _- I I I 0.002 0.003 0.004 0.005 0.006 0.007 0.008 0.009 DEFLECTION(inches) FIGURE A-9 V T""" o d C\I T""" o d ""....,..... c.. ,.- o E ::J. d -....Wi ~ LU o z ..... co o 8 LO d '-""'" I ~« Ow co ~ a: Ow ~ °qo L"-L I- ~ o 8d I I'- 8 d o o T""" Qsd)SS31:J1S ~ (sq\)OV01' 76 14-DAY TEST(5 SLUMP) I1 160, I 14 a-+----- --- -- ----- ---.--.------------------------------.-- ---.----- --.--------------..---.-----------...,-::------ --.~ --.-.---- --------~~~ Cf) 0.. 120 -+- .--.- -- -- -------- --------.--- ----- --- ----- -- ----- --- ------------ -- ------- --- ---.-.... ---.--------------------.--.----- •• -._----.---- • ......... (j) (j) ) J • •• _. ._._. • _ 100 i-----------.-.--.------------------------------.-- --·------------~-··-~·-LO-A-D-(ibs a: ..... (j) 80 1__---- -~- ---..----.--.-------------------------- ~---- .----.------------------------------------.---.-.----------.---------- ill :j06 ......... ~. 60 -t -- ----------------------------- - - - - -- -- --- - - -- -- --------- ---- ---. -- - - - -- -- --- --- -.---.---.-- •••-.---------------- -------- .----~--.-- ......... o <t: g 4 a.~---- -------------------------------------------------------------------.-..--....-.-------------.-----.-------.-... -+- STRESS(psi) : ' 2 a III ------- -- -.- --.-- -- -- ----- ---------- --------------.-.--- ---------- -- ------------- ------.•--.-.•--.------------ --------------.------- 0= a .t 0.001 ~ 0.002 I : I : .': 0.003 0.004 0.005 DEFLECTION(inches) FIGURE A·11 : 0.006 ~ : 0.007 0.008 24.. DAY TEST(5 SLUM-P) U 160 -a. ... - 140 -_ -_ --_ .. -_ -_ .. -_ .. -- ------_ --_ - -- -_ _ --_ --- . ~;.-.;" .;;;._--..,:.;;; .. -- _ _... (f) .....Cf) Cf) w ex: 120 100 -------------_ .. _--_ -.. -- -_ -- _ --- -_ - - ------ - .. -- -------- -_ _ _--_ .. -.. -.---_ .. _ -_ _--_ __ -_ .. __ - _- t- Cf) ~ o?:S (f) 80 -0 60 « 40 ----------- --- ---- .-- ------_ ... _. ---- _.. .....0 0 --- ----- --- -------------- --- -- --------- -.-------.- -----~--- -- -+=--sTRESS(psir- ....J 20 J ----+ , ., o 0.018 0.02 .: ----- ----------------- ----- : · I : , mI 0.022 0.024 0.026 0.028- --O~oS DEFLECTION (inches) FIGURE A-12 I ~; ::::: r 0.032 0.034 0.036 31-DAY TEST(5 I1 SLUMP) 180 -(a./) 160 140 .......... ~120_ w "0: t(/) ~ ~ - 100 80 ( /) ..a .......... Q 60 -----"- --------------- --------- ---- ---- ---.- -------------- ----- ------- ----- -----------------------_._-"---_:------------------- 0 40 « ..J ........ 00- .. _ _ ..-_ _ _ .. __ .. __ - - .. - - - --- -- : __ - .. _;,;; -; __ - .. - _ .. __ .. _ _ .. _ .. ~ .. _ _ _ -+- STRESS(psi) 20 0.002 0.004 0.006 0.008 DEFLECTION(inches) FIGURE A-13 . 0.01 0.012 31-DAY TEST(5 I1 SLUMP) 140 ::=- 120 (/) Q.. Cii 100 (f) -, --- LOAD(fbs) w ~CE 8U I- ................... _ _ .. - - --- -- -- -- -;.,..,;. --_ --..-- - -- - -.. ""iIII'JllIllIl-.-" .__.•._ _~ _.•''''.__ _.~ (f) ~~ - 60 0 40 fI) --« ..Q ~ 0 -J STRESS(psi) 20 J~o ~ I I I 0.002 0.004 : I : : : : I 0.006 0.008 0.01 0.012 0.014 0.016 0.018 DEFLECTION(inches) FIGURE A-14 1O-DAY TEST(7 SLU'MP) I1 180 160 ::=- en 140 (J) (J) 120 t- 100 0.. --w a: (/) ~~ - "' --- LOAD(lbs) 80 (1) ..0 --- 60 0 40 0 « --J -+- STRESS(psi) 20 OTl o 0.001 I 0.002 I I I 0.003 0.004 0.005 DEFLECTION (inches) I I I 0.006 0.007 0.008 FrGURE A·15 ~ 17-DAY TEST(7"SLUMP) 300. e- 250 - 200 L- rn Q. ( J) (J) i .. .-::::: - - .. -- -- ---_ .. - .. _ - -_ ----LOAD(Ibs) --_ .. --- _.. __-- .. _.. -.. _---.. .. --.. - --_ - --- - w a: t- (J) ~ 150 .... ---------- ----- ---------~----- ------- ----- --------------------------- ------- ----- ------- ---------------------------------------- ci!S -« rn ..Q 0 0 .-J 1001------ ---1-----------------------------------------------------------------=--;;;~ii~;.;;_:_:-:_:_:-:: 5 a-t---------- -T----------------------------------------------------------------------------- at- o r I I I , I I , , I 0.001 0.002 0.003 0.004 0.005 0.006 0.007 0.008 0.009 0.01 DEFLECTION(inches) FIGURE A-16 , 17-DAY TEST(7 SLUMP) I1 25 0 T'- - - - - - - - - - - - - - - - - - - - . , -'w - n.. 200 ~lOAD(lbs) ( j) (Jj ill a: 150 r(j) .. ~~ (i) .0 -«o o ~ 100.....--------------------------------------------------------..... -- ------------------------------------------------------------------L -+- STRESS(psi) .. -- _.... -- ----_ ........ _......... --_ .. ---- -_ .... ---------------_ .. -_ ....... _.... -.... -_ .. ------ -... ------ .. _.... ---- ... --_ .. " 50 or., o I, I : I " : ': : : I 0.002 0.004 0.0'06 0.008 0.01 0.012 0.014 0.016 0.018 0.02 DEFLECTION(inches} FIGURE A·17 - 7-DAY TEST(7"slump) 4. C'" • i 3.5 rJ) ..e, en en w 3 a: 2.5 ~ 2 ~~ "ii) .c 1.5 ~ o « 9 1 --.- STRESS(psij O~I Q5 o 0.005 : I 0.01 I I • 0.02" 0.015 0.025 DEFLECTION FIGURE A-18 +. 0.03 I 0.04 0.035 ··t 14-DAY TEST(7"slump) 5. • . - 4.5-+·················································· t:=" en 4 CJ) CJ) 3.5 a: 3 .B w t;) ......................................~ I11III • _._ •• - ~ ---- LOAD(lbs) 2.5 'ii) 2 .0 ;:::, o 1.5 i . . ~~ « 9 -e- 1 0.5 0"- o , 0.005 , 0.01 i i 0.02 0.015 i i 0~03 0.025 DEFLECTION FIGURE A-19 STRESS(psO i i Q.Q~I I 0.04 0.045 7 -DAY TEST(8"SLUMP) SAMPLE 1 140, t::" (I) ~ 0> -!l; ~~ -6 ~ ~ 120-----··.. ·· ··········· ·..· ·..··············..···· - -..- - - - -..- ..--.. 1OOJ-----·-·· --········..··..······..···· ··········-·· _ --._-.-:':.:_ _ -- . -----7--·LOAD(lbs) ~,. 80j-----------------------------------L 60 - - __ _ __ - _............................ . - -.-- .__._ - . ( I) «0 -I 40 -._-_ -._ - _ _ _._ -._.._ ] 20 -------------- I-----~- o : _ _ : I ---.~ STRESS(psi) .._. : I ._.._._ _ _.._ . : I : _ i i i 0.014 0.016 0.018 0.02 0.022 0.024 0.026 0.028 :J<,DEFLECTION(in) FIGURE A-20 0.03 0.032 7-DAY TEST(8 11 SLUMP) SAMPLE 2 200 ~ .9: Ql -..j 180J..-.~~~ ~_ m · m . . ·: · .. . . ·.· · 160 _·--·..··..·..· ·..·..- · ·..·· · · ~ 140]--.-~ ··· · ~ . ..._--__,11 _ __ _._. L.. J--_. - -_ -.. _ _ - _ _. ·-2··-=-.- LO""A-D{lbs) ·..· . · · · · · ·. ·. · · . · · · · ·. · · ·.. ! ~EJ-=---:~==--=~:=--:==:==:-=-=-:~::=-~-=-=Z=-=~=~~~ -= ..0 . :.. ---- -- - - - . ~ :1-_-._.~~~:~~~~::~:::~::~:~:~~~~~~:~:~::::::::~::. · . : : :~: : : : : ._ __ __ ~ _ . ~ ~_T~.~~~Jp..~.~L_. 9 2~t----------: :-----~-,---;-----~-~-!:-;-+I-,-: 0.005 0.01 0.015 . 0.02 DEFLECTION(inches) FIGURE A-21 0.025 0.03 14-DAY TEST(SII SLUMP) SAMPLE 1 .140 :'=" (/) ~ ~ ~ CJ) CD CD ~ .. i I 120 1OO-l----· ·· ·..- · 80 · ·· · ·· - _ -- - ~--- J-,--_ _-_._- - __ _.. . . . . . . . . . . .L. - -..- - - - - - - - - - - - . -.-------- -LOA~_ _.__._--- -.2 _ __. ._. . _._ . _ . ~ ::]--===----~-----==~~----C-------- . -. -_~----. -.-. :_-~-~- ~-~-~ _.-~. ,. .!.~ -.. 60 S...-+ o o 0.002 0.004 0.006 0.008 0.01 0.012 0:014 0.016 0.018 ,. DEFLECTION (in) FIGURE A-22 14-DAY TEST(8 11 SLUMP) SAMPLE 2 -------------------:=;-1' 200""'-, 1 80 -.-----..-cfI) 0- 1 60 ------.-- - - -..- - - - - -..--.-.-- -.. - --- '-" (J) (J) 00 CO w a: 1401·--·-·-·-··········-···············_·············· -..... -.-- -----..- ····-·-=;=··-L:.OAD(lbs)--·--- - ~:~j~~~~-~~-~~::~=~-~==-~~-=~~~:~~~=_:-:==-==~~~ ~= f- (J) ~ f I) .a ::::::0 « 0 -J :~j=~::_::;;::=:_==:::::::::;::_===:=-~~!~~~~I 2~~-;----:-----~----:--i----~--r: ,,. o 0.002 0.004 0.006 ·0.008 0.01 DEFLECTION (in) FIGURE A-23 0.012 0.014 0.016 28..DAY TEST(8 I1 SLUMP) SAMPLE 1 180. c:- I 160 ·---··-··-···················.. ·················-·· - --..-.-..- -- - - . fI) .8:' 140...· rn <0 o ~ 120 a: ~ 1OOl·---··_··.._·_·······-··_..·························· - ~ 80~---·_-····-- . ··········-··························· ~ :::::.. 60 -·---·..· ·-·················-············_········· _ « o 40,.- o -' ._ - _- .....__. -.················-7-=t.- LOAD(lbs) - . - _ ~..- _------ --.._.-.-.._-------.. - - _-._.-.~····-···_·_····-··············· -.-..----.-.---..- -.---. ..···---······=+--·siRES-S'Cpsi) o .-._.-.. . . . . . . ! . : : 20!~---------~-------------~------~~ o 0.001 0.002 0.003 0.004 0.005 0.006 0.007 0.008 0.009 0.01 DEFLECTION(in) FIGURE A·24 J '28-DAY TEST(8"S LUMP) SAMPLE 2 , ~Oi :=- - II) a. 200-1-------··-··-··-····-···--·-···-·-····-··--·····--- I ~ .... CD ~ -.-..-- - ----.-.------. :--- LOAD(lbs) 150 CJ) ~ (j) 100 4------······-··········---····-··-·-··-···-·········· , - _-..-.-.-.-....•-..-_..-.-----'.- .a ~ o I 50~---·_··-··-··_·············-··-----~·-·_·····-·····-..- - ..J ~~ O ~ o 0.002 0.004 0.006 I L -+- STRES~(psi) ,..-.-- - ..-.- --.-.--------.--.---..-.. I : I : I: +-:Ir\ " 0.008 0.01 DEFLECTION(in) FIGURE A~25 0.012 -- 0.014 0.016 35.. DAY TEST(8 SLUMP) I1 SAMPLE 1 250 I I r.=- [ ........ 200+--' en en w 150 4·_·---,·_ ~ (J:) I\) ---- LOAD(lbs) · _.._..· · · ·_· ·· ··· ··..··· _ __ ~ . en ~ (j) .a 1 OO~·.._·_.._..· _..· _ ..·_..·..·..·..· ·· :..· - _·_ O J ' ,_ 50 .-.__.__ ~ -oJ ~' 0 a 0.002 0.004 ~ ~ ~ ~...: : 0.006 _ _ __..:......_--_._ . ... -+- STRESS(psi) -..-- .--._ --._._._- . +:11 I: . 1 : 0.008 0.01 DEFLECTION (in) FIGURE _ _- A~26 0.012 j .. 0.014 'I 0.016 35.. DAY TEST(8 SLU_MP) I1 SAMPLE 2 250 i i ~ [ 200 j ·-·----··--..- · · ..-···-····· C!) (,J ····.. · ..·· ..······· __ - .-",.-... ( f) (f) w a: 150-1 -II- _..- - - - - -... - -...... - . - .- _ - _. LOAD(lbs) l(f) ~ (i) 100-\.---- - - - - - .0 -=::;. -+- STRESS(psi) o o« ._-_ -._.._.--. 50-1- ..J o~ o I' 0.005 I : + 0.01 I I I :' 0.015 DEFLECTION{in) FIGURE A-27 I 0.02 . ~ I 0.025 <"'- 7-DAY TEST(8" SLUMP) NO TIRES SAMPLE 1 0- ~ 180j 160- ~ I ------.---.-------------.---------.-.-------~ [ 140 _ . _ ~ 12" o· w -4 __ -........................................................................................................... . __ - _-.- ..- - - ..- -.__._ -. -.-.----.- . ~.-. ~~-~_---~~~~~~:~~~=~=~~~:~~::~-~:~~~~::==--===,) ] Z 1 ~ ~ o « o-I 60·.. .:.;:~~ _ - - -.._.--.-..-.-_ _-_ , ..-................................................. . 401--·-- ·..·..···..·· ·····..· ~ ·· · . ·..· ·..· · · =;=.-STRE·SS(p;·i)·_·-.._.·-.. · ·..···.. - 2 0t::==:::---------------------------.-----~---:-l-I o I o 0.01 0.02 I ~ I I I I 0.03 0.04 0.05 DEFLECTION (in) FIGURE A-28 I 0.06 0.07 0.08 7-DAY TEST(8 11 SLUMP) NO TlRES SAMPLE 2 250 I ~ 200 w (/) 150-1 ! 1 O~-J·_ _·-_··-·_·····-··..·······-·-·················-··· -.- , .- ~ co 0'1 _ . ~ ~ J_ ._._. -.-.-- L --- . _._ ...J o 0.005 __ _.........................._.....•..........••.•.....•.__.. ._...._-----_ LOAD(Ibs) .. ._._._--_.. _.._ _.. _ O J' (§ 50-----------------L---0 ........--- I 0.01 ~ -- .........•.....• _._-_.__._--_ - -.-------..- _--_._ _------ - . -+- STRESS(psij - -..- -..- . -..----.---.-.--.,...---.---.. -0.015 0.02 . 0.025 DEFLECTION(in) FIGURE A-29 '0.03 0.035 14-DAY TEST(811 SLUMP) NO TIRES SAMPLE 1 250Ti--------------------~i :=~ ...... CD (j) 200 ~_.--..--.- - -- -..-- -- - _ _. Cf) Cf) w 150-1 a: .- ---..- .... - - _-._ _ _.._ -_ _-_.. ~ Cf) ~ (j) .c --_._---_._- 100+---' :::::;.. ~ ..J ~' 50J-.__ __ _ ok::::;::::, o 0.002 L _._._ _ 0.004 I : _. . I: _ . -+STRESS(psO - _.__. _.._._.._-..-._. - ~._ : 0.006 0.008 0.01 DEFLECTION(in) FIGURE A-30 I : 0.012 I : 0.014 I T 0.016 14-DAY TEST(8 SLUMP) NO TIRES 11 - SAMPLE2 250 r.:::rJ) "'.l I _- _-_ _.._ _ __.._ - - I ~ 200~----'--"-'-""-'--"-"""-"'-""-""""'-' ~ 150- Cf) co I -------- ~ -II- LOAD(lbs) Cf) «S (j) 100+ .0 :::::.. -+- STRESS{psi) o « o....J 0% o : 0.002 I : 0.004 I : I : 0.006 0.008 .DEFLECTION{in) FIGURE-A-31 I r I 0.01 0.012 'C ~8-DAYTEST(8nSLUMP)NO TIRES SAMPLE 1 300 ! ~ co 00 I i ---- -------T:---------~-"~Z LOA~(lbS) 250] 200 .-.-._ _ - _................ .,_. a: .-en 1501..- -~ 1 ......-............................................ _ . _--_._.._-_.._--_ . _ ~ ~ -.oJ OOl-.._·--· · . · -· · -..· . · - · · · · · · . ·.. ·.· · 7····-· ·.· -_·_ ~_._-_._-----STRESS(psi) 50 -o ..c. __ O~~I o 0.005 0.01 _ _ ---.-.- - - - - . - .1 , : +1 :1- 1 I:: 0.015 0.02 0.025 DEFLECTION (in) FIGURE A~32 0.03 .' 0.035 -- I 0~04 28-DAY TEST(8 SLUMP)NO TIRES 11 SAMPLE 2 300 :g i _ i ~ 250t---·-·······-··········_···············-·200i----·----------~-----------:::~~~;;(~b~-)--~~·---·---_ .. .: _ _ _ __ _-_..-,------.. . en [ •.... ~ ~ Iii' 150 - _.- ~ --.- _ - :9 100 . - - - -.. --------------- «o...J '"-" 50. _ _ _ __ .. _ -..--- -.-----.-.--.--.. _ :_ _ .. . . -+- STRESS(psij ~ . .:...... .. . . _._..__ -.....................------------_.. _ . .__.:. . .__..__._+ . o.. ..=:::;::::: o 0.005 I I 0.01 i 0.015 i I i I 0.02 : ..,..,.- . 0.025 0.03 DEFLECTION (in) FIGURE. A~33 i I i 0.035 . 0.04 0.045 - 35-DAY TEST(SUSLUMP) NO TIRES SAMPLE 1 300T'- - - - - - - - - - - - - - - - - - - - - " .... 8 i _--_... 250r---------------------------.::;::::- .................................... LOAD(lbs) ~ 200 1--------··-······-··-···················-·..·········· ~ 150 w ~ I I) (5 .0 9 J--·--_·-········ -·-· · · · · · · · · · -· · · · · 100 ------.- -- - - _ _ o i 0.005 . _._-..- --.._- _ - -._ _--_ , __._-------_..- __ -_., - i:: 0.01 _ __ - - -.- _ - - ... -~ES;;~~I~: .. I 501----------------0------------------£-------_ I -.._-o~ ~ - . --_._-_ ", I 0.015 0.02 DEFLECTION (in) FIGURE A-34 _ _ _ _ ~. i 0.025 0.03 0.035' I1 35-DAY TE$T(8 SLUMP) NO TIRES . - , SAMPLE 2 250 ' :=en a. ..... o ..... '\ en 2001----- - w ....a: :.... ~ ---- lOAD(rbs) ~ (f) 150-----..·-·..··..·-· -··..···..··-·..-·..···..-·..····..··· . --.. -.----- . (f) ~ (i) .a o (§ ~ i 1 00 -- - - -.----..-- V-' 50 !.- --.- - -..--- . -+- STRESS(psi) _ _- _ --_._- _ _- ..J Oliilil o I I I I I I I I 0.005 0.01 0.015 0.02 0.025 0.03 0.035 0.04 DEFlECTION(in) FIGURE· A-3S VITA Mark Morrison Personal Information Date of Birth Place of Birth Parents February 26, 1961 Montclair , NJ William James Morrison Patricia Helen Morrison Institutions Attended High School Parsippany Hills High School Parsippany, NJ Graduated June 1979 Undergraduate Manhattan College Bronx, NY Bachelors of Engineering Graduated May 1983 cum laude Professional Experience William L. Crow Construction Company 1983-1986 Field Engineer American Telephone and Telegraph 1986-present Structural Engineer Licences State of New Jersey, Professional Engineer 102
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